KR20190021414A - Method and system for producing safe, high calorific fuel gas - Google Patents

Abstract

FIELD OF THE INVENTION The present invention relates to a method and a system for producing fuel gas, which belong to the new energy field, and in particular to a method and system for producing a safe, high calorific fuel gas. In the present invention, hydrogen, oxygen, and water produced by electrolysis are molecularly coupled by hydrogen bond resonance in water molecules to form molecular stages, and the reforming is performed on the molecular ends using a reformate, . The high calorific value fuel gas produced in the present invention has excellent safety, is easy to store, has a high calorific value, and does not pollute the environment.

Description

Method and system for producing safe, high calorific fuel gas

FIELD OF THE INVENTION The present invention relates to a method and a system for producing fuel gas, which belong to the new energy field, and in particular to a method and system for producing a safe, high calorific fuel gas.

Today, the world is in the fossil energy economy era where oil, natural gas and coal are the main energy sources. This fossil energy economy era will soon be over and an unprecedented new energy revolution will soon begin. The new energy economy that replaces the fossil energy economy, or the new energy economy in the post-oil era, will be called "hydrogen economy", "low carbon economy" and its various energy sources such as nuclear energy, solar energy, wind energy, hydro energy, biomass energy, It will be a new energy economy that complicates the use of modernization.

The net hydrogen form is typically hydrogen composed of dicarboxylic molecules, hydrogen is the lighterest gas and is only 0.09 grams per liter of hydrogen at zero degrees and atmospheric pressure. Equivalent to 1 / 14.5 of the air weight of the same volume. Hydrogen is extremely easy to burn and has the lowest flash point of all materials (flash point <-253 ° C, no flash point). Hydrogen has the lowest ignition energy and is only 0.021 mJ (milliseconds) = 0.005 mcal (milli-calories), which is 1/14 of the gasoline ignition energy 0.30 mJ. Hydrogen has the largest combustible range in the air and has a volumetric content of 4% to 75% (gasoline is 1.3% to 7.6%). Hydrogen is the fastest burning rate in the air and 250 cm / s (45 cm / s for gasoline). The boiling point of hydrogen is -252.9 ° C, the melting point is -259.1 ° C, and the thermodynamic temperature is close to -273 ° C. The mass calorific value (low calorific value) of the water vapor formed by the combination of hydrogen and oxygen is the highest among all combustible materials, reaching 120 MJ / kg, 2.76 times the low calorific value of gasoline 43.5 MJ / kg. Hydrogen and oxygen have many special characteristics and can be the most desirable environmentally friendly energy for energy.

However, many technical barriers exist, especially in terms of storage, transportation and safety.

First, the cost of producing hydrogen by electrolysis of water is relatively high. The theoretical electricity quantity to produce 1 kg of hydrogen and 0.5 kg of oxygen under standard conditions is 2390 Ah and the theoretical electric energy consumption W = I * E = 2390/1000 * 1.23 = 2.95 KWh (1.23 V is the water decomposition voltage) The actual consumption of electricity in the electrolytic cell and the actual decomposition voltage are both larger than the theoretical values. Actual operating voltage is usually 1.5 - 2 times the decomposition voltage depending on the structure and operating conditions of the electrolysis bath. Currently, the actual electrical energy consumption to generate 1 standard cubic meter hydrogen and 0.5 standard cubic meter oxygen is 5 KWh, which is larger than the theoretical value. Thus, it can be seen that the cost of producing hydrogen by electrolysis of water is relatively high, and that there is no benefit of the original fuels compared to other fuels in terms of economy.

Second, the safety of hydrogen is relatively low. Because hydrogen is an extremely volatile, burning, and explosive material, unsafe factors are also a major problem limiting its application. Experimental Results: (1) Maximum combustion of hydrogen in the air is very large. If the hydrogen content reaches 4% ~ 70% according to the volume ratio, it can burn and is much wider than 1.3 ~ 7.6% of maximum gasoline combustion; (2) The minimum energy required for hydrogen ignition is 0.005 mcal; (3) High pressure hydrogen and low temperature liquid hydrogen easily leak and storage requirement is relatively high.

From this, it can be seen that hydrogen energy still has many problems in terms of low-cost production, safe storage and transport technologies, but it also shows that hydrogen energy has an excellent advantage. First, it is clean and environmentally friendly; Second, a wide range of raw materials for production can deviate from dependence on petroleum energy, and therefore, methods for manufacturing, storing, transporting and applying hydrogen energy safely and efficiently have become urgent problems in the world today.

The object of the present invention is to provide a generator for generating a mixed gas of hydrogen and oxygen by electrolysis of water, which has a high cost and low safety, and its object is to provide a gas- And to provide a safe and reliable reliable high-calorie fuel gas production method and system with reduced energy consumption. The high calorific value fuel gas produced by the method and system is excellent in safety, is easy to store, has a high calorific value, and does not pollute the environment.

In one aspect of the present invention for solving the above problem, there is provided a method for manufacturing a safe flash heating amount.

Hydrogen, oxygen and water produced by electrolysis are molecularly bonded by hydrogen bond resonance in water molecule to form a molecular end, and the molecular end is represented by the general formula (H ₃ O ⁺ -O ₂ -OH ^- -H ₂ ) _n , where 1 &lt; = n &lt; = 36,

The reforming is performed on the molecular end by using the reforming liquid to obtain a mixed-type highly-heating fuel gas containing H ₂ and O ₂ .

Preferably, in the method of the present invention, the reforming is a mixed reforming in which a contact reaction and a compounding reaction are carried out with respect to the vapor phase liquid phase interface.

Preferably, in the method of the present invention, the reforming liquid is a reformate containing a hydrocarbon compound C _x H _{2x + 2} and / or a carbon hydrogen oxygen compound C _x H _{2x + 2} O.

Preferably, in the method of the present invention, the reformate further comprises a quantum carbon additive, wherein the quantum carbon is a graphene liquid of 0.3 nm - 1.0 nm and the parameter of the quantum carbon solution is The pH is 1.8 - 2.2, the ORP is 280 mv - 380 mv, the electrical conductivity is 1.2 ms / cm - 5.0 ms / cm and the solids content is 0.1% - 0.8%.

Preferably, in the method for producing a stable high-calorie fuel gas, the natural frequency of the excitation device used here satisfies the following formula,

Where f is the natural frequency of the excitation device, h is the thickness of the excitation device, L is the length of the excitation device, E is the modulus of elasticity of the excitation device, and P is the density of the excitation device.

Preferably, in the method of the present invention, the mixed pyrex fuel gas includes C _n H _{2n + 2} gas, wherein 15>n> 0.

Preferably, in the method for producing a high-calorie fuel gas, the high calorific value fuel gas may include 20% to 60% of H ₂ ; O ₂ : 10% to 30%; C _n H _{2n + 2} (5 > _n &gt; = 1): 15% to 30%; C _n H _{2n + 2} (n ≥ 6): 5% to 25%.

In order to solve the above problems, a system for manufacturing a high-boiling-point high-calorie fuel gas according to an embodiment of the present invention includes a water ion-electrolytic apparatus in which a rotary electrode plate is installed, a fuel connected to the water ion- And a gas reforming device, wherein an excitation device is installed in the rotary electrode plate.

Preferably, in the above-mentioned safety high-calorie fuel gas production system, the natural frequency of the excitation device satisfies the following formula,

Where h is the thickness of the excitation device mm, L is the length of the excitation device mm, E is the modulus of elasticity of the excitation device, and P is the density of the excitation device.

Preferably, in the above-mentioned safety high-calorie fuel gas production system, the gas-liquid exchange layer is provided in the fuel gas reforming apparatus, the gas-liquid exchange layer is installed in the reformate, The gas is drawn back through the gas-liquid exchange layer.

Thus, compared to the prior art, the present invention has the following advantages:

(1) Excellent safety: Through this principle, a single molecule hydrogen oxygen gas and water molecules are again constituted by hydrogen bonds and a new molecular stage. The combustion temperature is more than 3,500 degrees Celsius, belongs to the wide axial combustion, It is relatively safe and stable compared to explosive combustion in space;

(2) Easy to store: liquefied to a liquid fuel at one temperature point between -90 ° C and -190 ° C of new molecules, able to withstand pressures of more than 200 kg / cm ^3, No change occurs.

3 greener is: sulfur (S) and does not contain nitrogen (N) component, heating value is 11000 ~ 51000 kcal (Kcal / m ³⁾ may amount to, the general fuel more than 50% energy saving and economical efficiency compared , Clean, environmentally friendly, high calorific value, and many uses.

BRIEF DESCRIPTION OF THE DRAWINGS FIG.
2 is a high-calorie fuel gas production control system.
3 is an explanatory diagram of a high heat amount fuel gas production system equipped with a gas compression device.
4 is an explanatory diagram of connection of a water ion electrolysis apparatus and a compressed fuel gas apparatus.
5 is an explanatory diagram of a high heat amount fuel gas production system having a fuel gas reforming apparatus.
6 is a connection explanatory view of a water ion electrolysis apparatus, a fuel gas reforming apparatus and a combustion apparatus.
Fig. 7 is an explanatory diagram of one of two DC generating apparatuses and a combination of water ion electrolytic apparatuses.
Fig. 8 is an explanatory diagram of a combination of one DC generator and one of the water ion electrolysis apparatuses.
9 is an explanatory diagram of a water ion electrolysis apparatus.
10 is a partial explanatory view of a water ion electrolysis apparatus.
11A is a front view of the rotary electrode plate of the water ion electrolysis apparatus.
11B is a side view of the rotating electrode plate of the water ion electrolysis apparatus.
11C is an explanatory view showing the connection of the excitation device of the rotating electrode plate of the water ion electrolysis apparatus.
12A is a front view of a cathode electrode plate and a cathode electrode plate of a water ion electrolysis apparatus.
12B is a side view of the anode electrode plate and the cathode electrode plate of the water ion electrolysis apparatus.
13 is a diagram for explaining a DC power generation device.
14A is a front view of the rotor magnet of the direct current power generation device.
14B is a side view of the rotor magnet of the direct current power generation device.
15A is a front view of the stator metal disk of the direct current power generation device.
15B is a side view of the stator metal disk of the direct current power generation device.
16 is an explanatory diagram of the results of chromatographic analysis of Example 1. Fig.
17 is a chromatographic analysis record of Example 1. Fig.

Hereinafter, the technical solution of the present invention will be described more specifically with reference to examples and accompanying drawings.

1. Manufacturing Method

As shown in Fig. 1, the principle of the manufacturing method of the present invention is shown. Hydrogen and oxygen gas produced by a generator that generates a gas mixture of hydrogen and oxygen by electrolysis of existing water is a mixture of pure gas and there is a certain safety risk of mixing hydrogen and oxygen gas.

In the process of producing hydrogen and oxygen gas by ionizing electrolyzed water, the method of the present invention forms a new molecular stage by molecular bonding of three single molecules of water, hydrogen and oxygen, Bound to the molecular end. Therefore, the ratio of hydrogen oxygen molecules in the new molecular stage is very stable, reduced to water during combustion, belongs to wide-axis combustion, and wide-axis combustion is more safe than explosive combustion in closed space.

Combustion temperature of the new molecular end is at least 3500 ° C, can be liquefied to a liquid fuel, and can withstand at least 200 kg / cm ³ pressure, and does not have any characteristic variation occurs even after long storage.

In carrying out the process, the electrolytic solution may be selected from KOH at a concentration of 5% to 30%, and the general formula of the molecular end produced by the bond (H ₃ O ⁺ -O ₂ -OH ^- -H ₂ ) _n , where 1? n? 36.

The reformate is a reformate comprising a hydrocarbon compound C _x H _{2x + 2} and / or a carbon hydrogen oxygen compound C _x H _{2x + 2} O. Additional quantum carbon additive may be added. The quantum carbon liquid has a pH of 1.8 to 2.2, an electromotive force ORP of 280 mv to 380 mv, an electrical conductivity of 1.2 ms / cm to 5.0 ms / cm, The solid content is 0.1% - 0.8%.

In the present method, the excitation device natural frequency used here satisfies the following formula.

Where f is the natural frequency of the excitation device, h is the thickness of the excitation device mm, L is the length of the excitation device, E is the elastic modulus of the excitation device, and P is the density of the excitation device. Among them, the excitation frequency is adjustable between 10-3000 Hz.

2. Manufacturing System

SUMMARY OF THE INVENTION The present invention provides a system for manufacturing a high-boiling-point fuel gas. A detailed explanation is as follows.

1. Overall structure

2-6, the overall structure of the system includes a direct current power generation device 1, a water ion electrolysis device 2, a fuel gas compression device 3, and a fuel gas reforming device 5.

2 is a control system of the present system. The control system is used for data collection and automation management such as point of view, pressure, temperature, material supply, compressed fuel gas parameters, combustion parameters, and so on.

2. Compressor

As shown in FIGS. 3-4, the molecular end produced by the electrolysis of the present system can be compressed and stored by a compression device. A pressure gauge system 3-1, a storage tank 3-2 and a gas compression chamber connected to the gas outlet 2-11 of the water ion electrolysis device 2. [ The compressed fuel gas system is a general installation with a pressure range of 20.7 to 24.8 MPa and the storage tank (3-2) is a standard gas tank.

3. Modification device

As shown in Figs. 5-6, it is necessary to carry out the modification to the molecular end in the combustion process. After passing the gas through the reformer tank 5-1, the gas enters the combustion apparatus 6 which is a general facility and is burnt.

The reforming can be performed by using a plurality of reforming apparatuses 5. In the reforming device tank 5-1, a reforming liquid 5-2 and a gas-liquid exchange layer 5-3 are provided. The reformate (5-2) is a hydrocarbon compound. The gas-liquid exchanging layer 5-3 may be a fibrous body such as felt, glass fiber, or heterogeneous plastic particles, and the iron wool may be used as the gas-liquid exchanging layer 5-3. The gas flowing into the reforming apparatus is drawn out after passing through the gas-liquid exchange layer. The gas inlet of the fuel gas reforming apparatus tank 5-1 passes through the gas pipe to the lower side of the gas-liquid exchange layer 5-3, and the gas outlet is located above the liquid level of the reformate 5-2 do.

More vaginal fluid (5-2) is one vaginal fluid containing hydrocarbons C _x H _{2x + 2} and / or carbon hydrogen oxygen compound C _x H _{2x + 2} O. Additional 0.1% to 1.0% quantum carbon additive may be added. The fundamental parameters of the quantum carbon liquid are pH 1.8 to 2.2, electromotive force ORP of 280 mv to 380 mv, electrical conductivity of 1.2 ms / cm to 5.0 ms / cm , And a solid content of 0.1% - 0.8%.

The calorific fuel gas produced in a technical solving means used in the present invention does not contain a sulfur (S) and nitrogen (N) component heating value can reach 11000 ~ 51000 kcal Kcal / m ^3.

4. Electrolysis device

As shown in Figs. 7-8, in the electrolysis, in this embodiment, two electrolytic electrolyzers can be used, and as shown in Fig. 7, one DC generator ( 1). As shown in Fig. 8, both of them can be selected depending on the situation.

9-12, the water ion electrolytic apparatus 2 includes a drive shaft 2-1, an insulating disk 2-2, a housing 2-3, a rotary electrode plate 2-4, A gas-liquid separation control tank 2-6, a low-pressure limiting pressure gauge 2-7, a high-pressure limiting pressure gauge 2- (2-4), at least one group of the heat- 8, a safety valve 2-9, a material addition port 2-10, a gas discharge port 2-11, an electrolytic solution 2-12, a system pipeline 2-13, 2-14, a system circulation pump 2-15, an anode electrode plate and a cathode electrode plate 2-17.

Two insulating disks 2-2 are provided on opposite sides of the inner wall of the electrolytic device housing 2-3, respectively, and the positive electrode plate and the negative electrode plate 2-17 are connected to two insulating disks 2- 2). The rotary electrode plate 2-4 is provided between the two positive electrode plates and the negative electrode plates 2-17 through the drive shaft 2-1.

The upper part of the electrolytic device housing 2-3 is connected to the gas-liquid separation control tank 2-6 through the heat dissipation pipe 2-5 and is connected to the liquid recovery port 2-6 of the gas- The outlet is connected to the interior of the electrolytic device housing 2-3 through the system pipeline 2-13. The gas outlet 2-11 of the gas-liquid separation control tank 2-6 is connected to the fuel gas compression device 3 and the fuel gas reforming device 5. [

A low pressure limit pressure gauge 2-7, a high pressure limit gauge 2-8, a safety valve 2-9 and a material addition port 2-10 are installed in the gas-liquid separation control tank 2-6. The heat-radiating pipe 2-5 is preferably a corrugated pipe, and the air-cooled blade fan 2-14 for radiating heat is provided beside it.

Here, the number of the rotating electrode plates 2-4 may be at least one, or a plurality of electrode groups, and the interval between the rotating electrode plates is 1 to 10 mm. Each of the rotary electrode plates 2-4 has a plurality of exciting devices 2-4-1. The exciting devices 2-4-1 are connected to the rotary electrodes 2-4-2 through the fixing bolts 2-4-2. And can be fixed to the plate 2-4.

The rotating electrode plate 2-4 is rotated at a predetermined angle in the electrolytic solution 2-12 and electrolyzed in the action of the electrode power supplies DC + and DC- of the anode and the cathode electrode plates 2-17 Hydrogen and oxygen gas.

The rotating electrode plate 2-4 drives the excitation device 2-4-1 during rotation to generate excitation, and the natural frequency of the excitation device satisfies the following formula.

Wherein, f is the natural frequency, h is the thickness of mm, of this device L is density g / cm ^3, where a frequency of the elastic modulus GPa, P is here the devices in the device length mm, E is excitation of the excitation arrangement of this apparatus Adjustable between 10 and 3000 Hz. The excitation device (2-4-1) in the present invention is here. Hydrogen and oxygen gas generated by the electrolysis generated in the anode and the cathode of the excitation electrode are recombined into a new molecular end by the hydrogen molecule and the hydrogen molecule under the action of excitation frequency.

The new molecular stage and the electrolytic solution reach the gas-liquid separation control tank 2-6 through the heat pipe 2-5 to perform the gas-liquid separation, and the separated gas passes through the discharge port 2-11 The low pressure limit pressure gauge 2-7 and the high pressure limit pressure gauge 2-8 maintain a pressure between 0.01 and 1.0 Mpa and the material addition port 2-10 is responsible for the addition of the filler liquid and additive , The safety valves 2-9 are controlled at 1.5 - 2.0 Mpa, the pipelines 2-13 are system automatic circulation pipelines and the circulation pumps 2-15 are opened according to the condition conditions such as temperature control .

5. Generator

As shown in Figs. 13-15, the dc generator includes a housing 1-1, a rotor magnet 1-2, a stator metal disk 1-3, a fixing member 1-4, 1-5 and a motor 4. [ The metal disk top guide line is connected to DC- and the metal disk center axis guide is connected to DC +. The rotor magnet disk 1-2 is a conductive metal disk, and the metal may be copper and a copper alloy or a conductive metal, and is composed of at least one or more; The rotor magnet 1-2 is a high magnetic flux magnet with a magnetic flux of between 0.5 and 1.2 T and at least one stator metal disk 1-3 sandwiched between the two.

The frequency modulation motor 4 provides kinetic energy of a constant rotation speed and is converted from the direct current power generation device 1 to a rated direct current electrolysis power source and supplied to the water ion electrolysis device 2. [

6. Implementation Effect

The high calorific value fuel gas produced by the technical solution used in the present invention belongs to the width-wise combustion, the width-wise combustion in the closed space is safer than explosion combustion and its safety and stability are superior to other gas characteristics . The new molecular stage is liquefied to a liquid fuel at the same temperature point, and the combustion temperature is above 3500 degrees Celsius. In addition, it can withstand pressures of 200 kg / cm ³ or more and does not cause any characteristic change even in long-term storage.

The comparison between the high calorific value fuel gas produced by the technical solution used in the present invention and other general fuels is as follows:

The beneficial effects of the present invention can be demonstrated in the following several examples.

Example 1

H₃O⁺+HO^-로부터 이온화된 H₃O⁺+HO^- 양성자 수화물과 수산기 이온의 혼합물질을 탄화수소와 결합하여 개질을 진행한다.Ionization of water: H ₂ O + H ₂ O

Ionized H ₃ O ⁺ + HO ^- from H ₃ O ⁺ + HO ^- Reacts with a mixture of hydrocarbons and proton hydrates to reform.

The electrolytic solution (2-12) is selected from KOH at a concentration of 5% to 30% and selects 15%. The reformate (2-21) is selected from a mixture comprising a C1-C5 alcohol alkane.

The detection and analysis of the molecular gas component of the hydrocarbon structure produced by the method of Embodiment 1 are as shown in FIG. 16, and the chromatographic analysis record is as shown in FIG. According to the results of the detection and analysis, the gas is composed of various carbon structures and the calorific value is> 12000 Kcal / m ³ .

Example 2

H₃O⁺+HO^-로부터 이온화된 H₃O⁺+HO^- 양성자 수화물과 수산기 이온의 혼합물질을 탄화수소와 결합하여 개질을 진행한다.Ionization of water: H ₂ O + H ₂ O

Ionized H ₃ O ⁺ + HO ^- from H ₃ O ⁺ + HO ^- Reacts with a mixture of hydrocarbons and proton hydrates to reform.

The electrolytic solution (2-12) is selected from KOH at a concentration of 5% to 30% and selects 20%. The reformate (2-21) is a hydrocarbon compound and is selected from a C3-C8 alkane mixture.

The molecular gas components of the hydrocarbon structure before and after the reforming are shown in the following table. As shown in the table, the calorific value of the multi-component hydrocarbon structure is> 30000 Kcal / m ³ .

Example 3

H₃O⁺+HO^-로부터 이온화된 H₃O⁺+HO^- 양성자 수화물과 수산기 이온의 혼합물질을 탄화수소와 결합하여 개질을 진행한다.Ionization of water: H ₂ O + H ₂ O

Ionized H ₃ O ⁺ + HO ^- from H ₃ O ⁺ + HO ^- Reacts with a mixture of hydrocarbons and proton hydrates to reform.

The electrolytic solution (2-12) is selected from KOH at a concentration of 5% to 30% and is selected at 30%. The reformate (2-21) is a hydrocarbon compound and is selected from a C5-C12 alcohol alkane mixture. The calorific value of the multi-component hydrocarbon structure obtained after the reforming is> 50000 Kcal / m ³ .

The examples show that the safe, high-calorific fuel gas of the present invention is eco-friendly energy and has a remarkable energy saving and emission reduction effect as compared with conventional ordinary fuels. As can be seen from the combustion results, it is possible to maintain the energy saving and economical efficiency of 50% or more of the general fuel. In addition, it is possible to effectively control the emission of harmful gases such as NO _x , SO _x , and CO ₂ , and to reduce the combustion discharge amount by more than 60%. The present invention is not limited to the above embodiments and can be applied to all applications in the combustion field. For example, general commercial combustion, high-pressure fuel storage tanks, liquefied storage and transportation, and the like.

It will be apparent to those skilled in the art that various modifications and variations can be made in the technical solutions of the present invention without departing from the spirit of the invention. And will fall within the scope of protection defined by the claims of the present invention.

The specific embodiments described herein merely illustrate the spirit of the invention. It will be apparent to those skilled in the art that various changes and modifications may be made or equivalents may be substituted for the specific embodiments described above without departing from the spirit of the invention or beyond the scope of the appended claims.

1, housing: 1-1, rotor magnet: 1-2, stator metal disk: 1-3, fixing member: 1-4, insulating bracket: 1-5, water ion electrolytic device: 2, Drive shaft: 2-1, insulation disk: 2-2, electrolytic device housing: 2-3, rotating electrode plate: 2-4, excitation device: 2-4-1, fixing bolt: 2-4-2, : 2-5, gas-liquid separation control tank: 2-6, low pressure limit pressure gauge: 2-7, high pressure limit gauge: 2-8, safety valve: 2-9, material addition port: 2-10, 2-11, electrolytic solution 2-12, system pipeline 2-13, air cooled blade fan 2-14, system circulation pump 2-15, insulated electric plate 2-16, anode plate and cathode electrode The fuel gas reforming apparatus 5: 1, the fuel gas reforming apparatus 5: 1, the fuel gas reforming apparatus 5: 1, the fuel gas reforming apparatus 5: : 5-2, gas-liquid exchange layer: 5-3, combustion device: 6.

Claims (10)

A method for producing a safe, high calorie fuel gas,
Hydrogen, oxygen and water produced by electrolysis are molecularly bonded by hydrogen bond resonance in water molecule to form a molecular end, and the molecular end is represented by the general formula (H ₃ O ⁺ -O ₂ -OH ^- -H ₂ ) _n , where 1? n? 36;
And reforming the molecular stage using the reforming liquid to obtain a mixed-type highly heat-generating fuel gas containing H ₂ and O ₂ . The method according to claim 1,
Wherein the reforming is a mixed reforming process in which a contact reaction with the gas phase liquid phase interface is carried out and a compounding reaction proceeds. The method according to claim 1,
Wherein the reformate is a reformate comprising a hydrocarbon compound C _x H _{2x + 2} and / or a carbon-hydrogen-oxygen compound C _x H _{2x + 2} O. The method of claim 3,
Wherein the reformate further comprises a quantum carbon additive wherein the quantum carbon is a graphene liquid of 0.3 nm to 1.0 nm and wherein the quantum carbon liquid has a pH of 1.8 to 2.2, an electromotive force ORP of 280 mv to 380 mv, Wherein the electrical conductivity is 1.2 ms / cm - 5.0 ms / cm, and the solid content is 0.1% - 0.8%. The method according to claim 1,
The natural frequency of the excitation device used here satisfies the following formula,

Wherein f is the natural frequency of the excitation device, h is the thickness of the excitation device, L is the length of the excitation device, E is the elastic modulus of the excitation device, and P is the density of the excitation device. Gt; The method according to claim 1,
Wherein the mixed pyrex fuel gas comprises C _n H _{2n + 2} gas, wherein 15>n> 0. The method according to claim 6,
The high calorific value fuel gas,
H ₂ : 20% to 60%;
O ₂ : 10% to 30%;
C _n H _{2n + 2} (5 > _n &gt; = 1): 15% to 30%;
C _n H _{2n + 2} (n ≥ 6): 5% to 25%. In a safe, high calorific fuel gas production system,
A water ion electrolytic apparatus having a rotating electrode plate,
And a fuel gas reforming device connected to the water ion electrolysis device and comprising a hydrocarbon compound reformate,
Wherein the rotating electrode plate is provided with an excitation device. 9. The method of claim 8,
The natural frequency of the excitation device satisfies the following formula,

Wherein f is the natural frequency of the excitation device, h is the thickness mm of the excitation device, L is the length of the excitation device, E is the elastic modulus of the excitation device, and P is the density of the excitation device. Fuel gas production system. 9. The method of claim 8,
The gas-liquid exchange layer is provided in the fuel gas reforming apparatus, the gas-liquid exchange layer is installed in the reformate, and the gas flowing into the fuel gas reforming apparatus is drawn out after passing through the gas- Characterized in that the fuel gas production system is a safety high calorie fuel gas production system.

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