CN106118769A - A kind of gas reformation device and gas preparation method - Google Patents
A kind of gas reformation device and gas preparation method Download PDFInfo
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- CN106118769A CN106118769A CN201610639890.XA CN201610639890A CN106118769A CN 106118769 A CN106118769 A CN 106118769A CN 201610639890 A CN201610639890 A CN 201610639890A CN 106118769 A CN106118769 A CN 106118769A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
- C25B11/034—Rotary electrodes
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/30—Cells comprising movable electrodes, e.g. rotary electrodes; Assemblies of constructional parts thereof
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Abstract
The present invention relates to a kind of reformer and method, belong to new energy field, be specifically related to a kind of gas reformation device and gas preparation method.Hydrogen, oxygen and the water that electrolysis produces is formed micel by molecular linkage by hydrogen bond resonance in hydrone by the present invention；Utilize bag reformation liquid that described micel is carried out reformation and obtain high heating value combustion gas.High heating value gas safe prepared by the present invention is good, it is easy to storage, and calorific value is high, free from environmental pollution.
Description
Technical field
The present invention relates to a kind of reformer and method, belong to new energy field, be specifically related to a kind of gas reformation device
And gas preparation method.
Background technology
The world today is still in the fossil energy economy era taking the energy with oil, natural gas and coal as the leading factor.This is changed
The stone economy of energy epoch will terminate, and a unprecedented new forms of energy revolution has begun to.Replace the new forms of energy of fossil energy economy
Economy, in other words the new forms of energy economy of rare-view set-up, will be " hydrogen economy ", " low-carbon economy " and nuclear energy, solar energy, wind
The modernization of the diversification energy such as energy, water energy, biomass energy, underground heat utilizes complementary new forms of energy economy.
Hydrogen elemental form is typically the hydrogen that is made up of diatomic molecule, and hydrogen is the lightest gas, zero degree and one
Under atmospheric pressure, every liter of hydrogen only has 0.09 grammes per square metre.Be equivalent to the 1/14.5 of same volume air weight；Hydrogen easily burns, and is institute
There is (flash-point ＜-253 DEG C, it is believed that without flash-point) that flash-point in material is minimum；Hydrogen Ignition minimum energy, only 0.021mJ
(MJ)=0.005mcal (calorie in the least), is the 1/14 of gasoline ignition energy 0.30mJ；Hydrogen flammable range in atmosphere is
Greatly, volume content is 4%～75% (gasoline is 1.3%～7.6%)；Hydrogen burning velocity in atmosphere is the fastest, for 250cm/s
(gasoline is 45cm/s)；The boiling point of hydrogen-252.9 DEG C, fusing point-259.1 DEG C, close to thermodynamic temperature-273 DEG C.Hydrogen and oxygen
The quality calorific value (low heat value) of gasification synthetic water steam is the highest in all combustibles, reaches 120MJ/kg, is that gasoline is low
2.76 times of combustion value 43.5MJ/kg.Hydrogen and oxygen have much special character, are optimal cleanings as energy fuel
The energy.
But there is a lot of intractable problems, particularly store transport and secure context, there is also many technology
Obstacle.
First, the cost of water electrolysis hydrogen production is higher.Produce 1kg hydrogen and the theoretical capacity of 0.5kg oxygen at standard conditions
It is 2390 (Ah), theoretical power consumption W=I*E=2390/1000*1.23=2.95KWh (1.23V is water decomposition voltage), electricity
Solve groove actual power consumption amount and actual decomposition voltage will be bigger than theoretical value.Practical operation voltage, according to structure and the behaviour of electrolysis bath
Make situation, generally 1.5-2 times of theoretical decomposition voltage.Water-electrolytic hydrogen making equipment produces 1 mark cubic meter hydrogen and 0.5 mark is vertical now
The actual power consumption of side's rice oxygen is 5KWh, more than theoretical value.The visible cost utilizing water electrolysis hydrogen production is higher, from economic angle
Degree considers do not have cost advantage compared with other fuel.
Secondly, the safety of hydrogen is poor.Due to hydrogen be a kind of highly volatile, the material that burns, explode, dangerous
Factor is also the subject matter limiting its application, and experiment shows: the combustion limits of (1) hydrogen in atmosphere are the widest, by volume
Hydrogen content reaches 4%～70% with regard to incendivity, wants wide many compared with the combustion limits 1.3%～7.6% of gasoline；(2) point
Combustion hydrogen least energy has only to 0.005mcal, and flame during combustion of hydrogen does not has color to be difficult to find；(3) High Pressure Hydrogen
Gas and low temperature liquid hydrogen are easy to reveal, higher to storage request.
As can be seen here, Hydrogen Energy there is also problems at present at technical elements such as low-cost production, safe storage transports, but
Hydrogen Energy has prominent advantage: one is clean environment firendly；Two is that raw materials for production are extensive, can break away from the dependence for fossil energy,
So, prepare the most safely and efficiently, accumulating and application Hydrogen Energy have become the anxious difficult problem to be tackled key problems in the world today.
Summary of the invention
The technical problem to be solved is the cost existed for tradition water-electrolyzing oxy
Height, the problem that safety is low, its object is to provide a kind of gas-liquid exchange uniformly, gas is discharged easily, and energy consumption reduces, safety
Gas reformation device and gas preparation method reliably.Use the high heating value gas safe prepared by this device and method good,
Being prone to storage, calorific value is high, free from environmental pollution.
In order to solve the problems referred to above, according to an aspect of the invention, it is provided a kind of gas reformation device, including: combustion
Gas reformer tank body；Described gas reformation device tank body fills reformation liquid, described reformation liquid is provided with gas-liquid switching layer；
Wherein, the gas leading to gas reformation device tank interior immerses reformation body and is exported combustion gas weight after gas-liquid switching layer again
Engagement positions tank body.
Optimizing, above-mentioned a kind of gas reformation device, the air inlet of described gas reformation device tank body is led to by trachea
Below gas-liquid switching layer, its gas outlet is positioned at the ullage of reformation liquid.
Optimizing, above-mentioned a kind of gas reformation device, described gas-liquid switching layer is corpus fibrosum and/or steel wire lump.
Optimizing, above-mentioned a kind of gas reformation device, described corpus fibrosum is felt, glass fibre, Special plastic granule
In one or more.
Optimizing, above-mentioned a kind of gas reformation device, described reformation liquid includes: Hydrocarbon CxH2x+2And/or it is hydrocarbon
Oxygen compound CxH2x+1O。
Optimizing, above-mentioned a kind of gas reformation device, described reformation liquid includes that quantum carbon element, described quantum carbon element are
The Graphene liquid of 0.3nm-1.0nm, the basic parameter of described quantum carbon element liquid is: pH is 1.8-2.2；Electromotive force ORP is
280mv-380mv；Electrical conductivity is 1.2ms/cm-5.0ms/cm；Solid content is 0.1%-0.8%.
Optimize, above-mentioned a kind of gas reformation device, the air inlet of described gas reformation device tank body and water ion electricity
Solution device is connected；Inside described water ion electrolysis unit, electric rotating pole plate is set；Exciting dress it is provided with on described electric rotating pole plate
Put.
Optimizing, above-mentioned a kind of gas reformation device, the natural frequency of described exciting device follows formula:
In formula: f is exciting device natural frequency；H is exciting device thickness mm；L is exciting device length mm；E is exciting
Device elastic modelling quantity；P is exciting device density.
In order to solve the problems referred to above, according to another aspect of the present invention, it is provided that a kind of gas preparation method, including:
The hydrogen and the oxygen that electrolysis are produced by hydrogen bond resonance in hydrone form micel with water by molecular linkage,
The formula of described micel is (H3O+-O2-OH--H2)n, wherein: 1≤n≤36；
Utilize and include the reformation liquid of Hydrocarbon CxH2x+2 and/or hydrocarbon oxygen compound CxH2x+2O to described point
Son group reforms, and obtains including H2、O2Mixed type high heating value combustion gas.
Optimizing, above-mentioned a kind of gas preparation method, described reformation liquid includes that quantum carbon element, described quantum carbon element are
The Graphene liquid of 0.3nm-1.0nm, the basic parameter of described quantum carbon element liquid is: pH is 1.8-2.2；Electromotive force ORP is
280mv-380mv；Electrical conductivity is 1.2ms/cm-5.0ms/cm；Solid content is 0.1%-0.8%.
Therefore, compared with prior art, the invention have the advantages that
(1) safety is good: be reassembled into new by excitation principle through hydrogen bond by unimolecule hydrogen or oxygen gas and hydrone
Micel, then micel is carried out reformation obtain high heating value combustion gas, its ignition temperature is more than 3500 Celsius temperatures, and belongs to
Quick-fried contracting burning, in the space closed, explosion type combustion completion is stable relatively；
(2) it is prone to storage: between-90 DEG C～-190 DEG C temperature spot of new molecule is liquefied as liquid combustion simultaneously
Material；200kg/cm can be born3There is not any qualitative change in pressure above long term storage；
(3) more environmentally-friendly: not sulfur-bearing S and nitrogen N composition, calorific value is up to 11000～51000 kilocalorie (Kcal/m3), the most often
For rule fuel, energy-conservation and economy all can save more than 50%, has clean environment firendly, calorific value feature high, multiduty.
Accompanying drawing explanation
Fig. 1 is high heating value combustion gas composition principle figure；
Fig. 2 is that control system is prepared in high heating value combustion gas；
Fig. 3 is the high heating value combustion gas preparation system schematic diagram with gas pressure compression apparatus；
Fig. 4 is water ion electrolysis unit and compressed gas device connection diagram；
Fig. 5 is the high heating value combustion gas preparation system schematic diagram with gas reformation device；
Fig. 6 is water ion electrolysis unit and gas reformation device and the connection diagram of burner；
Fig. 7 is to use two direct-current generating devices and the schematic diagram of the monolateral combination of water ion electrolysis unit；
Fig. 8 is to use single direct-current generating device and the schematic diagram of the monolateral combination of water ion electrolysis unit；
Fig. 9 is water ion electrolysis unit schematic diagram；
Figure 10 is water ion electrolysis unit partial schematic diagram；
Figure 11-1 is the electric rotating pole plate schematic front view of water ion electrolysis unit；
Figure 11-2 is the electric rotating pole plate schematic side view of water ion electrolysis unit；
Figure 11-3 is the exciting device connection diagram of the electric rotating pole plate of water ion electrolysis unit；
Figure 12-1 is the positive-negative electrode plate schematic front view of water ion electrolysis unit；
Figure 12-2 is the positive-negative electrode plate schematic side view of water ion electrolysis unit；
Figure 13 is direct-current generating device schematic diagram；
Figure 14-1 is the rotor magnet schematic front view of direct-current generating device；
Figure 14-2 is the rotor magnet schematic side view of direct-current generating device；
Figure 15-1 is the stator metal dish schematic front view of direct-current generating device；
Figure 15-2 is the stator metal dish schematic side view of direct-current generating device；
Figure 16 is the chromatography result schematic diagram of embodiment 1；
Figure 17 is the chromatography record of embodiment 1.
In figure:
Direct-current generating device 1, housing 1-1, rotor magnet 1-2, stator metal dish 1-3, fixture 1-4, insulating support 1-
5；Water ion electrolysis unit 2, moving axis 2-1, insulating disc 2-2, electrolysis unit housing 2-3, electric rotating pole plate 2-4, exciting device 2-
4-1, fixing bolt 2-4-2, radiating tube 2-5, gas-liquid separation control tank 2-6, low pressure pressure limiting table 2-7, high pressure pressure limiting table 2-8, peace
Full valve 2-9, material add mouth 2-10, gas outlet 2-11, electrolyte 2-12, system pipeline 2-13, air-cooled paddle fan 2-14, are
System circulating pump 2-15, insulation electroplax 2-16, positive-negative electrode plate 2-17, gas pressure compression apparatus 3, manometer system 3-1, holding vessel
3-2；Motor 4；Gas reformation device 5, gas reformation device tank body 5-1, reformation liquid 5-2, gas-liquid switching layer 5-3；Burner
6。
Detailed description of the invention
Below by embodiment, and combine accompanying drawing, technical scheme is described in further detail.
One, preparation method
As it is shown in figure 1, be the preparation method schematic diagram of the present invention.Existing water-electrolyzing oxy is produced
Raw hydrogen or oxygen gas is the mixed gas of elementary gas, and hydrogen-oxygen elementary gas is mixed certain potential safety hazard.
The method of the present invention in electrolysis water ionization to producing during hydrogen or oxygen gas, by water, hydrogen, oxygen three
Unimolecule forms a new micel by molecular linkage, is strapped in micel by hydrogen molecule higher for activity.Therefore, newly
Micel in hydrogen-oxygen molecular ratios sufficiently stable, be reduced into water during burning, belong to quick-fried contracting burning, close space in, quick-fried
Contracting burning relative explosion type burning is foolproof.
The ignition temperature of new micel is more than 3500 Celsius temperatures, and can be liquefied as liquid fuel, Ke Yicheng
By 200kg/cm3Pressure above, there is not any qualitative change in long term storage.
When implementing this method, electrolyte can be selected for KOH, and concentration is 5%-30%, the formula of the micel that bonding produces
For (H3O+-O2-OH--H2)n, wherein: 1≤n≤36.
Reformation liquid is to include Hydrocarbon CxH2x+2And/or hydrocarbon oxygen mixes compound CxH2x+2The reformation liquid of O.Also may be used
To add quantum carbon element additive.Wherein, quantum carbon element is the Graphene liquid of 0.3nm-1.0nm, the basic ginseng of quantum carbon element liquid
Number is: pH is 1.8-2.2；Electromotive force ORP is 280mv-380mv；Electrical conductivity is 1.2ms/cm-5.0ms/cm；Solid content is
0.1%-0.8%.
In this method, the exciting device natural frequency for exciting follows formula:
In formula: f is exciting device (intrinsic) frequency；H is exciting device thickness mm；L is exciting device length mm；E is sharp
Vibrating device elastic modelling quantity；P is exciting device density；Wherein, excited frequency is to adjust between 10-3000Hz.
Two, preparation system
The invention provides safe high fever value combustion gas preparation system.It is described in detail below.
1, overall structure
As shown in figures 2-6, the overall structure of system includes: direct-current generating device 1, water ion electrolysis unit 2, combustion gas compression
Device 3, gas reformation device 5.
Fig. 2 is the control system of native system.This control system is for time point, pressure, temperature, material supply, compression
Combustion gas parameter, combustion parameter etc. carry out data acquisition and carry out automated management.
2, compressor
As shown in Figure 3-4, the micel that during native system electrolysis, exciting produces can be by compressor compression storage.Bag
Include: manometer system 3-1, holding vessel 3-2 and the gas compression being connected with the gas outlet 2-11 of water ion electrolysis unit 2
Chamber.Compressed gas system is conventional equipment, pressure limit 20.7-24.8Mpa, and holding vessel 3-2 is calibrating gas tank.
3, reformer
As seen in figs. 5-6, when burning, need micel is reformed.By gas after reformer tank body 5-1
Entering burner 6 to burn, this burner 6 is conventional equipment.
Multiple reformer 5 can be used to reform.Reformation liquid 5-2 and gas-liquid it is provided with in reformer tank body 5-1
Switching layer 5-3.Reformation liquid 5-2 is Hydrocarbon.Gas-liquid switching layer 5-3 is corpus fibrosum, such as felt, glass fibre, abnormity
Plastic grain；Steel wire lump can also be used as gas-liquid switching layer 5-3.Lead to the gas within reformer to exchange through gas-liquid
It is exported again after Ceng.
Reformation liquid 5-2 is to include Hydrocarbon CxH2x+2And/or hydrocarbon oxygen mixes compound CxH2x+2The reformation liquid of O.Also
The quantum carbon element additive of 0.1%-1.0% can be added.Wherein, quantum carbon element is the Graphene liquid of 0.3nm-1.0nm, quantum
The basic parameter of carbon element liquid is: pH is 1.8-2.2；Electromotive force ORP is 280mv-380mv；Electrical conductivity is 1.2ms/cm-5.0ms/
cm；Solid content is 0.1%-0.8%.
Gas after reformation includes CxH2x+2Gas, wherein, 15 > x > 0.Specifically include following volume constituents:
H2: 20%～60%；O2: 10%～30%；CnH2n+2(5 > n 1): 15%～30%；CnH2n+2(n 6): 5%
～25%.
High heating value combustion gas prepared by the technical solution adopted in the present invention not sulfur-bearing S and nitrogen N composition, calorific value is up to 11000
～51000 kilocalorie Kcal/m3。
4, electrolysis unit
As Figure 7-8, when electrolysis, the present embodiment can use two direct-current generating devices 1 to be electrolysed, such as Fig. 7
Shown in；Single direct-current generating device 1 can also be used to be electrolysed, as shown in Figure 8.Both select according to operating mode.
Water ion electrolysis unit is as shown in figs9-12.Water ion electrolysis unit 2 includes moving axis 2-1, insulating disc 2-2, housing
2-3, electric rotating pole plate 2-4, exciting device 2-4-1, radiating tube 2-5 least one set or many groups, gas-liquid separation control tank 2-6, low
Pressure pressure limiting table 2-7, high pressure pressure limiting table 2-8, relief valve 2-9, material add mouth 2-10, gas outlet 2-11, electrolyte 2-12, are
Road 2-13 under the overall leadership, air-cooled paddle fan 2-14, system circulating pump 2-15, positive-negative electrode plate 2-17.
Wherein, insulating disc 2-2 is arranged at the internal both sides of housing 2-3；Positive-negative electrode plate 2-it is respectively provided with inside insulating disc 2-2
17.Electric rotating pole plate 2-4 is arranged between two pieces of positive-negative electrode plate 2-17 by moving axis 2-1.
Wherein, electric rotating pole plate 2-4 is the most a piece of, it is also possible to formed electrode group, every interval 1-10mm by multi-disc.Often
Sheet electric rotating pole plate 2-4 device has several exciting devices 2-4-1, this exciting device 2-4-1 can be by fixing bolt 2-4-2
It is fixed on electric rotating pole plate 2-4.
Electric rotating pole plate 2-4 rotates with a fixed angular speed in electrolyte 2-12, and at the electrode of positive-negative electrode plate 2-17
Under the effect of power supply DC+ and DC-, produce hydro-electrolytic hydroxide gas.
Electric rotating pole plate 2-4 drives exciting device 2-4-1 to produce exciting in rotation, and exciting device natural frequency follows public affairs
Formula:
In formula: f is exciting device natural frequency；H is exciting device thickness mm；L is exciting device length mm；E is exciting
Device elastic modulus G Pa；P exciting device density g/cm3；Excited frequency is to adjust between 10-3000Hz.On exciting device just
Produced by negative pole, hydrogen and oxygen electrolyzing gas is under the effect of excited frequency, the unimolecule hydrogen or oxygen gas of generation and hydrone, passes through
Hydrogen bond is reassembled into new micel.Exciting device 2-4-1 in the present invention can select exciting sheet.
New micel and electrolyte arrive gas-liquid separation control tank 2-6 through radiating tube 2-5 and carry out gas-liquid separation, separate
After gas by outlet 2-11 export, low pressure pressure limiting table 2-7 and high pressure pressure limiting table 2-8 be responsible for keep pressure at 0.01-
Running between 1.0Mpa, material adds mouth 2-10 and is responsible for adding replenisher and additive, and relief valve 2-9 controls at 1.5-
2.0Mpa, pipeline 2-13 are system Automatic Cycle pipeline, can ON cycle pump 2-15 according to working conditions such as temperature controls.
5, TRT
Direct-current generating device as illustrated in figs. 13-15, comprising: housing 1-1, rotor magnet 1-2, stator metal dish 1-3, solid
Locking member 1-4, insulator support 1-5, motor 4.Metal dish top guide line couples and couples for DC-, metal dish central shaft guided bone
Form for DC+.Rotor magnet disk 1-2 is conducting metal disk, and metal can be copper and copper alloy or conducting metal, extremely
One or more pieces compositions few；Rotor magnet 1-2 is high magnetic flux Magnet, and magnetic flux is between 0.5-1.2T tesla, two panels it
Between at least accompany one or more pieces stators metal dish 1-3 composition.
Frequency modulation motor 4 provides the kinetic energy of certain rotating speed, direct-current generating device 1 be converted to specified DC electrolysis power supply and supply
Feedwater ion electrolysis unit 2.
6, implementation result
High heating value combustion gas prepared by the technical solution adopted in the present invention belongs to quick-fried contracting burning, quick-fried contracting in the space closed
The relative explosion type that burns burning is fool proof, and the character of the safety and stability having is better than other exchangeability；New micel exists
One temperature spot is liquefied as liquid fuel simultaneously；Ignition temperature is more than 3500 Celsius temperatures；200kg/cm can be born3Above
There is not any qualitative change in pressure long term storage.
High heating value combustion gas prepared by the technical solution adopted in the present invention and other conventional fuel are compared as follows:
Table 1-reformed gas compares with calorific value and the CO2 emissions of different fuel
| Fuel type | Quantity KG | Calorific value Kcal | CO2CER % |
| LPG | 1 | 11000 | 20 |
| Heavy oil | 1 | 10000 | 75 |
| Diesel oil | 1 | 9600 | 60 |
| Coal | 1 | 5000 | 90 |
| Electric energy | 1KW | 860 | Conversion |
| Natural gas | 1 | 8000 | 20 |
| The present invention reforms gas | 1 | 11000-51000 | Less than 5% |
Several embodiment can be crossed below beneficial effects of the present invention is verified.
Embodiment 1
The electron ion of water:The H ionized out3O++HO-Proton hydrate and hydroxide ion
Compounding substances be combined reformation with hydrocarbon alkane.
Electrolyte 2-12 selects KOH concentration to be 5%-30%, selects 15%.Reformation liquid 2-21 selects and includes C1-C5 alcohol alkane
Mixture.
The hydrocarbon structure molecular gas composition prepared by method in the present embodiment 1 is detected and analyzed, and its chromatograph is divided
Analysis result is as shown in figure 16；Chromatography record is as shown in figure 17.Detection and analysis result show, gas is by multiple hydrocarbon structure
Composition, calorific value ＞ 12000Kcal/m3。
Embodiment 2
The electron ion of water:The H ionized out3O++HO-Proton hydrate and hydroxide ion
Compounding substances be combined reformation with hydrocarbon alkane.
Electrolyte 2-12 selects KOH concentration to be 5%-30%, selects 20%.Reformation liquid 2-21 is Hydrocarbon, selects
C3-C8 paraffins mixture.
Before and after reformation, hydrocarbon structure molecular gas composition is as shown in the table.Same as can be seen from the table, many components
Hydrocarbon structure calorific value ＞ 30000Kcal/m3.
Hydrocarbon structure molecular gas component analysis table before and after table 2-reformation
Embodiment 3
The H ionized out3O++HO-The compounding substances of proton hydrate and hydroxide ion with
Hydrocarbon alkane combines to be reformed.Electrolyte 2-12 selects KOH concentration to be 5%-30%, selects 30%.Reformation liquid 2-21 is Hydrocarbon,
Select C5-C12 alcohol alkylating mixture.The hydrocarbon structure calorific value ＞ 50000Kcal/m of many components3。
Example shows, the safe high fever value combustion gas of the present invention is clean energy resource, and existing any conventional fuel compares all
There is the most outstanding effects of energy saving and emission reduction.Knowable to burning actual achievement, for relatively conventional fuel, energy-conservation and economy all can be saved
More than 50%；Effectively controlling the discharge of the harmful gass such as NOX, SOX, CO2, burning and exhausting all can reduce discharging more than 60%.The present invention
It is not limited to the example above, is applicable to all application of combustion field.As, conventional commercial burning；Fuel under high pressure storage tank；Liquefaction accumulating
Etc..
Above embodiment is only to be described the preferred embodiment of the present invention, not enters the scope of the present invention
Row limits, and on the premise of designing spirit without departing from the present invention, technical scheme is done by those of ordinary skill in the art
The various deformation gone out and improvement, all should fall in the protection domain that claims of the present invention determines.
Specific embodiment described herein is only to present invention spirit explanation for example.Technology neck belonging to the present invention
Described specific embodiment can be made various amendment or supplements or use similar mode to replace by the technical staff in territory
Generation, but without departing from the spirit of the present invention or surmount scope defined in appended claims.
Claims (10)
1. a gas reformation device, including: gas reformation device tank body (5-1)；It is characterized in that, described gas reformation device
Tank body (5-1) fills reformation liquid (5-2), described reformation liquid (5-2) is provided with gas-liquid switching layer (5-3)；Wherein, combustion is led to
The gas of gas reformer tank body (5-1) inside immerses reformation body (5-2) and is exported combustion again after gas-liquid switching layer (5-3)
Gas reformer tank body (5-1).
A kind of gas reformation device the most according to claim 1, it is characterised in that described gas reformation device tank body (5-
1) air inlet leads to gas-liquid switching layer (5-3) lower section by trachea, and its gas outlet is positioned at the ullage of reformation liquid (5-2).
A kind of gas reformation device the most according to claim 1, it is characterised in that described gas-liquid switching layer (5-3) is fine
Dimension body and/or steel wire lump.
A kind of gas reformation device the most according to claim 3, it is characterised in that described corpus fibrosum is felt, glass fibers
One or more in dimension, Special plastic granule.
A kind of gas reformation device the most according to claim 1, it is characterised in that described reformation liquid (5-2) including: hydrocarbon
Compound CxH2x+2And/or hydrocarbon oxygen compound CxH2x+1O。
A kind of gas reformation device the most according to claim 5, it is characterised in that described reformation liquid (5-2) includes quantum
Carbon element, described quantum carbon element is the Graphene liquid of 0.3nm-1.0nm, and the basic parameter of described quantum carbon element liquid is: pH is 1.8-
2.2；Electromotive force ORP is 280mv-380mv；Electrical conductivity is 1.2ms/cm-5.0ms/cm；Solid content is 0.1%-0.8%.
A kind of gas reformation device the most according to claim 1, it is characterised in that described gas reformation device tank body (5-
1) air inlet is connected with water ion electrolysis unit (2)；Described water ion electrolysis unit (2) is internal arranges electric rotating pole plate (2-
4)；It is provided with exciting device (2-4-1) on described electric rotating pole plate (2-4).
A kind of gas reformation device the most according to claim 7, it is characterised in that described exciting device (2-4-1) consolidates
Frequency is had to follow formula:
In formula: f is exciting device natural frequency；H is exciting device thickness mm；L is exciting device length mm；E is exciting device
Elastic modelling quantity；P is exciting device density.
9. a gas preparation method, it is characterised in that
The hydrogen and the oxygen that electrolysis are produced by hydrogen bond resonance in hydrone form micel with water by molecular linkage, described
The formula of micel is (H3O+-O2-OH--H2)n, wherein: 1≤n≤36；
Utilize and include the reformation liquid of Hydrocarbon CxH2x+2 and/or hydrocarbon oxygen compound CxH2x+2O to described micel
Reform, obtain including H2、O2Mixed type high heating value combustion gas.
A kind of gas preparation method the most according to claim 9, it is characterised in that described reformation liquid includes quantum carbon element,
Described quantum carbon element is the Graphene liquid of 0.3nm-1.0nm, and the parameter of described quantum carbon element liquid is: pH is 1.8-2.2；Electromotive force
ORP is 280mv-380mv；Electrical conductivity is 1.2ms/cm-5.0ms/cm；Solid content is 0.1%-0.8%.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610639890.XA CN106118769A (en) | 2016-08-07 | 2016-08-07 | A kind of gas reformation device and gas preparation method |
| EP16912020.1A EP3495457A4 (en) | 2016-08-07 | 2016-08-09 | Method and system for preparing safe high heating value fuel gas |
| US16/323,729 US20190177628A1 (en) | 2016-08-07 | 2016-08-09 | Method and system for preparing fuel gas with high heat value and safety |
| KR1020197002387A KR20190021414A (en) | 2016-08-07 | 2016-08-09 | Method and system for producing safe, high calorific fuel gas |
| PCT/CN2016/094187 WO2018027565A1 (en) | 2016-08-07 | 2016-08-09 | Method and system for preparing safe high heating value fuel gas |
| JP2019526352A JP2019528365A (en) | 2016-08-07 | 2016-08-09 | Safe high calorific fuel gas production method and system |
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| CN201610639890.XA CN106118769A (en) | 2016-08-07 | 2016-08-07 | A kind of gas reformation device and gas preparation method |
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