KR20180026262A - Manufacturing Method Of The Automotive Diaphragm Fabric Using Aramid Fabric - Google Patents
Manufacturing Method Of The Automotive Diaphragm Fabric Using Aramid Fabric Download PDFInfo
- Publication number
- KR20180026262A KR20180026262A KR1020160113408A KR20160113408A KR20180026262A KR 20180026262 A KR20180026262 A KR 20180026262A KR 1020160113408 A KR1020160113408 A KR 1020160113408A KR 20160113408 A KR20160113408 A KR 20160113408A KR 20180026262 A KR20180026262 A KR 20180026262A
- Authority
- KR
- South Korea
- Prior art keywords
- fabric
- diaphragm
- aramid
- yarn
- manufacturing
- Prior art date
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 50
- 239000004760 aramid Substances 0.000 title claims description 28
- 229920003235 aromatic polyamide Polymers 0.000 title claims description 28
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 229910000077 silane Inorganic materials 0.000 claims description 14
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- 238000007670 refining Methods 0.000 claims description 8
- -1 silane compound Chemical class 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 229920002472 Starch Polymers 0.000 claims description 3
- 235000019698 starch Nutrition 0.000 claims description 3
- 239000008107 starch Substances 0.000 claims description 3
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 claims description 2
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 claims description 2
- 239000000853 adhesive Substances 0.000 claims 1
- 239000012530 fluid Substances 0.000 abstract description 14
- 238000006073 displacement reaction Methods 0.000 abstract description 3
- 229920006231 aramid fiber Polymers 0.000 description 9
- 239000007822 coupling agent Substances 0.000 description 8
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 7
- 229920001971 elastomer Polymers 0.000 description 7
- 239000000835 fiber Substances 0.000 description 7
- 230000003014 reinforcing effect Effects 0.000 description 6
- 239000012783 reinforcing fiber Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 4
- 229920001084 poly(chloroprene) Polymers 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 229920002379 silicone rubber Polymers 0.000 description 3
- 239000004945 silicone rubber Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229920000784 Nomex Polymers 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 238000009530 blood pressure measurement Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 229940125782 compound 2 Drugs 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- 239000004763 nomex Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
- D01F6/605—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides from aromatic polyamides
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
- D02G3/047—Blended or other yarns or threads containing components made from different materials including aramid fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B15/00—Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C3/00—Stretching, tentering or spreading textile fabrics; Producing elasticity in textile fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C7/00—Heating or cooling textile fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/01—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with hydrogen, water or heavy water; with hydrides of metals or complexes thereof; with boranes, diboranes, silanes, disilanes, phosphines, diphosphines, stibines, distibines, arsines, or diarsines or complexes thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/11—Starch or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
- D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/06—Load-responsive characteristics
- D10B2401/063—Load-responsive characteristics high strength
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2505/00—Industrial
- D10B2505/12—Vehicles
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
본 발명은 자동차용 펌프등과 같이 반복하여 만곡시켜 유체에 압력을 가하거나 만곡 변위를 이용해서 압력의 측정과 유체의 개폐 실행할 때 사용되는 부품인 다이어프램에 사용되는 직물에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fabric used in a diaphragm which is a part used for repeatedly bending a fluid, such as an automobile pump, to apply pressure to a fluid or to perform pressure measurement and fluid opening and closing using a curved displacement.
일반적으로 얇은 막을 의미하는 다이아프램은 펌프등과 같은 부품에서 반복하여 만곡시켜 유체에 압력을 가하거나 만곡 변위를 이용해서 압력의 측정과 유체의 개폐 실행할 때 사용되는 부품으로서 자동차에 다양하게 사용되고 있는데, 그 구조를 살펴보면 탄성체와 탄성체의 운동을 안정적으로 보강하는 직물로 구성된다.The diaphragm, which generally means a thin membrane, is used in a variety of applications in automobiles, such as a pump or the like, which is repeatedly bent to repeatedly bend the fluid to apply pressure to the fluid or to measure the pressure and to open and close the fluid. Looking at the structure, it consists of a fabric that stably reinforces the movement of the elastic body and the elastic body.
이러한 보강직물은 탄성체에 혼입 또는 복합함으로써 재료가 변형될 수 있는 한도, 강도 등을 개선한 것을 말한다. 사용되는 섬유로는 탄소섬유, 유기 기능섬유(아라미드 섬유), 유리섬유, 세라믹 섬유 등이 있다.Such a reinforcing fabric means that the reinforcing fabric is improved in strength, etc. so long as the material can be deformed by incorporation or compounding in the elastic body. The fibers to be used include carbon fibers, organic functional fibers (aramid fibers), glass fibers, and ceramic fibers.
최근에는 자동차의 성능향상으로 인해 고온에서 열적안정성을 가지는 아라미드원단의 사용이 많아지고 있다. 이러한 아라미드 섬유는 높은 내열성을 보이는 대표적인 슈퍼섬유로 고강도 특성을 가져 슬링바 방탄복 등에 주로 사용되는 파라계 아라미드와 내열성 열적 안정성 및 전기절연성으로 방화복 자동차 내열보강 섬유 절연지 등으로 사용되는 메타계 아라미드 섬유로 크게 분류된다.In recent years, the use of aramid fabrics having thermal stability at high temperatures has been increasing due to improved performance of automobiles. Such aramid fiber is a typical super fiber having high heat resistance and has a high strength property and is a meta-based aramid fiber used as a para-aramid used mainly in a sling bar body armor and the like and a thermostable thermally stable and electrically insulated fireproofing automobile heat- .
최근에는 탄성체가 고무재질로 이루어지고, 보강원단이 아라미드 섬유로 구성된 다이어프램이 고온 고압의 가혹한 환경이나 연속적인 진동 충격에 강하고, 탄성이 우수한 장점이 있어서 많이 사용되고 있다. 이와 같이 고무에 아라미드 섬유를 보강섬유로 결합한 예로서 대한민국공개특허제10-2010-0098470호(공개일자 2010년09월 07일)에는 고탄성의 클로로프렌 고무(Polychloroprene)를 매트릭스 수지로 하고, 고강도의 아라미드 섬유를 보강섬유로 하는 섬유보강 고무 복합재료의 제조방법이 소개되어 있다. 상기 제조방법은 a) 아라미드 섬유직물을 플라즈마 처리하는 단계와 b) 클로로프렌 고무를 가열하거나, 클로로프렌 고무와 가교제를 유기용매에 용해한 고무조성물을 제조하는 단계와 c)상기 a) 단계의 아라미드 섬유직물에 b)단계의 고무조성물을 도포한 후, 압착하여 프리프레그를 제조하는 단계와 d) 상기 프리프레그를 적층한 후 경화하는 단계로 이루어진다. In recent years, a diaphragm made of a rubber material and a reinforced fabric made of aramid fiber has been widely used because it is resistant to harsh environments such as high-temperature and high-pressure, continuous vibration, and elasticity. As disclosed in Korean Patent Laid-Open No. 10-2010-0098470 (published on September 07, 2010), for example, an aramid fiber is bonded to rubber by a reinforcing fiber, a high-elasticity chloroprene rubber (Polychloroprene) is used as a matrix resin, A method of manufacturing a fiber reinforced rubber composite material using fibers as reinforcing fibers has been introduced. The process comprises the steps of: a) plasma treating the aramid fiber fabric, b) heating the chloroprene rubber, or preparing a rubber composition in which the chloroprene rubber and the crosslinking agent are dissolved in an organic solvent, and c) contacting the aramid fiber fabric of step a) b) applying the rubber composition of the step b), followed by pressing to produce a prepreg; and d) laminating the prepreg and curing.
그러나 이러한 방법에서는 상기 프리프레그를 제조하기 위하여 먼저 보강섬유를 플라즈마 처리해야 하기때문에 대규모 시설이 필요하고, 따라서 제조비용이 높은 문제가 있다. However, in this method, since the reinforcing fibers must be subjected to the plasma treatment in order to prepare the prepreg, a large-scale facility is required, and thus the manufacturing cost is high.
또한, 고온 고압용 복합소재로서 실리콘 고무를 매트릭스 수지로 사용하고, 동시에 보강섬유와의 접착강도를 개선하기 위한 연구도 소개되어 있다. 즉, 매트릭스 수지와의 결합력을 향상시키기 위하여 보강섬유에다 아미노프로필 트리에톡시실란이나 비닐트리 에톡시실란을 주성분으로 하는 실란계 커플링제를 도포하는 것이다. 그러나, 이 경우에는 상기 커플링제를 톨루엔이나 자일렌, 에탄올, 메탄올 등의 유기 용제에 희석하여 사용해야 하기 때문에 작업공정에서 작업자가 인체에 유해한 휘발성유기물질에 노출되는 등 작업환경이 열악하고, 화재 위험이 상존할 뿐 아니라, 박리강도가 다소 취약하여 이에 대한 개선의 필요성이 요구되어 왔다.Further, studies have been made to use silicone rubber as a matrix resin as a high-temperature and high-pressure composite material and at the same time to improve the bonding strength with reinforcing fibers. That is, a silane-based coupling agent containing aminopropyltriethoxysilane or vinyltriethoxysilane as a main component is applied to the reinforcing fiber in order to improve the bonding strength with the matrix resin. However, in this case, since the coupling agent must be diluted with an organic solvent such as toluene, xylene, ethanol or methanol, the work environment is poor, And the peel strength is somewhat weak, so that there is a need for improvement of the peel strength.
그러므로 본 발명은 자동차용 펌프등과 같이 반복하여 만곡시켜 유체에 압력을 가하거나 만곡 변위를 이용해서 압력의 측정과 유체의 개폐 실행할 때 사용되는 부품인 다이어프램에 사용되는 직물로서 고온에서 열적 내구성을 가지고 유체의 이송 시 내압성능이 우수한 자동차용 다이어프램용 원단을 제공하는 것을 목적으로 한다Therefore, the present invention is a fabric used for a diaphragm, which is used for pressure measurement and fluid opening / closing operation by repeatedly bending a fluid such as an automobile pump or applying a pressure to a fluid or using a curved displacement, and has thermal durability at a high temperature And an object of the present invention is to provide a fabric for a diaphragm for an automobile which is excellent in pressure resistance performance during fluid transportation
그러므로 본 발명에 의하면, 원사로서 아라미드 방적사를 2합하여 경사 및 위사로 사용하고, 경사로 사용하기전에 호제로 사이징하고 제직한 후, 90~98℃, 35~45min간 지거에서 전처리한 후 NaOH(농도 50%) 80~90 g/ℓ, 정련제 15~25 g/ℓ를 함유하는 정련욕에서 90~100℃에서 정련을 통하여 호발한 후 건조한 후, 수성 실란계 커플링제를 함침하고 180~200℃에서 큐어링하고, 200~230℃, 35~50m/min의 조건으로 열처리하는 것을 특징으로 하는 아라미드직물을 사용한 자동차용 다이어프램용 원단의 제조방법이 제공된다.Therefore, according to the present invention, two aramid yarns as yarn are used as warp yarns and weft yarns before sizing, and then pretreated at 90 to 98 DEG C for 35 to 45 minutes, %) 80 to 90 g / l, and a refining agent 15 to 25 g / l, and dried at 90 to 100 ° C., dried, impregnated with an aqueous silane coupling agent and cured at 180 to 200 ° C. Ring and subjected to a heat treatment at a temperature of 200 to 230 ° C and a temperature of 35 to 50 m / min. A method for manufacturing a fabric for an automobile diaphragm using the aramid fabric is provided.
이하 본 발명을 보다 상세히 설명하기로 한다. Hereinafter, the present invention will be described in more detail.
본 발명의 자동차용 다이어프램용 원단의 제조방법은 아라미드 방적사를 사용하여 보강직물을 제조하고, 상기 보강직물을 정련을 하여 호발한 후 실란계 수성 커플링제를 함침한 후 큐어링(curing)하는 것이다. 상기에서 아라미드 섬유는 메타계 아라미드 섬유를 사용한다.The manufacturing method of the diaphragm for automobile diaphragm according to the present invention is to manufacture a reinforcing fabric by using an aramid yarn, refining the reinforcing fabric, impregnating the fabric with a silane based coupling agent, and then curing the reinforcing fabric. In the above, the aramid fiber uses a meta-based aramid fiber.
본 발명에서는 원사로서 아라미드 방적사를 2합하여 경사 및 위사로 사용하고, 경사로 사용하기전에 호제로 사이징하고 제직한다. In the present invention, two yarns of aramid yarn as yarn are used as warp and weft yarns, and are weighed and weighed before warp yarns are used.
내열성과 내구성을 확보하기 위하여 본 발명의 다이아프램의 보강재로는 아라미드 소재를 적용하고자 한다. 다이아프램의 특성인 유연성 확보를 위해 보강 직물의 증량을 최소화 할 수 있는 원사의 굵기를 선정한다. 아라미드 20수('S), 30수로는 직물을 사용하기에는 두께가 두꺼워 40수('S) 방적사를 사용하고, 조직은 고무와의 접촉면적과 작업성을 고려하여 평직을 적용한다. In order to secure heat resistance and durability, an aramid material is used as a reinforcing material of the diaphragm of the present invention. In order to ensure the flexibility of the diaphragm, the thickness of the yarn that minimizes the increase of the reinforcing fabric is selected. Aramid 20 ('S), 30 The water is thicker to use the fabric, and it uses 40 yarns (' S) yarn, and the tissue applies plain weave considering the contact area with rubber and workability.
원사별 평직에 대한 중량은 다음과 같다. 원사는 방적사를 사용하는 대신 직물의 강도를 고려해 2합사를 적용하였다.The weight for plain weave by yarn is as follows. Instead of using a spun yarn, the yarn was subjected to 2 yarns in consideration of the strength of the fabric.
본 발명에서는 상기 아라미드 방적사를 2합하여 위사 및 경사로 사용하는데, 경사로 사용할 경우 사이징을 통하여 사를 구성하는 단섬유를 집합 결속시켜 꼬임을 방지함과 동시에 사의 표면을 보호하여, 평활성을 증대시켜서 제직성을 향상 시킬 수 있다. 본 발명에서는 경사로 아라미드 방적사를 적용하였으므로 전분 25~30%, PVA 60~70%, 왁스 4.8~7%, 오일 0.2~3%를 혼합하여 호제로 사용하는 것이 직기에서 개구성을 양호하게 하며 낙호발생을 적게 할 수 있어 바람직하다.In the present invention, two aramid yarns are used as weft yarns and warp yarns. When yarns are used as the warp yarns, the short fibers constituting yarns are gathered and bound together by sizing to prevent twisting, while protecting the yarn surface, Can be improved. In the present invention, since the ramp aramid yarn is applied, it is preferable to use 25 to 30% of starch, 60 to 70% of PVA, 4.8 to 7% of wax and 0.2 to 3% of oil, Can be reduced.
본 발명의 경우 후가공으로 염색 등의 공정을 거치지는 않지만 프라이머인 수성 실란계 커플링제 처리를 통한 실리콘계 고무와의 접착력을 강화하기 위해서 프라이머인 수성 실란계 커플링제가 직물에 고르게 흡수 및 침투를 하기위해 호제를 완전히 제거하는 것이 중요하므로 정련을 통하여 호발을 실시한다. 제직 후 90℃, 35~45min 지거에서 전처리한 후 NaOH(농도 50%) 80~90 g/ℓ, 정련제 15~25 g/ℓ를 함유하는 정련욕에서 90~100℃에서 정련을 통하여 호발한 후 건조하게 된다.In the case of the present invention, in order to enhance the adhesion with the silicone rubber through the treatment of the aqueous silane coupling agent as a primer, the aqueous silane coupling agent, which is a primer, It is important to completely remove the gypsum so that the gypsum is diluted through refining. After pre-treatment at 90 ° C for 35 to 45 min after weaving, the product was developed by refining at 90 to 100 ° C in a refining bath containing 80 to 90 g / l NaOH (concentration 50%) and 15-25 g / l refining agent And dried.
이후 수성 실란계 커플링제를 함침하고 180~200℃에서 큐어링하고, 200~230℃, 35~50m/min의 조건으로 열처리하여 본 발명의 아라미드직물을 사용한 자동차용 다이어프램을 제조하게 된다.Thereafter, an aqueous silane coupling agent is impregnated and cured at 180 to 200 ° C. and heat-treated at 200 to 230 ° C. and 35 to 50 m / min to produce an automotive diaphragm using the aramid fabric of the present invention.
상기 수성 실란계 커플링제는 n-2-아미노에틸-3-아미노프로필 트리메톡시 실란, 3-글리시독시 프로필트리메톡시 실란, 3-메타크릴 옥시프로필 트리 메톡시 실란, 3-머캅토 프로필트리 메톡시 실란 중 어느 하나이상인 수성 실란계 화합물과 아세트산, 물을 중량비 2:0.6:16~2:1:18로 혼합한 수성 실란계 커플링제인 것이 바람직하다.The aqueous silane coupling agent may be selected from the group consisting of n-2-aminoethyl-3-aminopropyltrimethoxysilane, 3-glycidoxypropyltrimethoxysilane, 3-methacryloxypropyltrimethoxysilane, 3- Trimethoxysilane, and an aqueous silane coupling agent in which acetic acid and water are mixed at a weight ratio of 2: 0.6: 16 to 2: 1: 18.
상기 실란 화합물들은 모두 수용성으로서 물에 비교적 잘 용해되는 특성이 있으나, 상기 아세트산이 실란 화합물의 수용성을 향상시켜 주는 기능을 한다. 따라서, 상기 아세트산의 함량이 중량비로 실란 화합물 2에 대하여 0.6 미만이면 실란 화합물이 물에 완전히 용해되지 않는 문제가 있고, 반대로 1초과면 상기실란계 수성 커플링제의 pH가 과도하게 높아지는 문제가 있다.The silane compounds are all water-soluble and have a property of dissolving in water relatively well, but the acetic acid functions to improve the water-solubility of the silane compound. Therefore, if the content of acetic acid is less than 0.6 based on the weight of the silane compound 2, there is a problem that the silane compound is not completely dissolved in the water. On the other hand, when the content is more than 1, the pH of the silane-based aqueous coupling agent becomes excessively high.
또한 상기 물은 실란 화합물을 직물에 고르게 도포하는 매질 기능을 하며, 그 함량이 중량비로 실란 화합물 2에 대하여 16 미만이면 실란화합물의 농도가 너무 높아져 비용의 손실이 따르고, 반대로 함량이 중량비로 실란 화합물 2에 대하여 18을 초과하면 실란 화합물 처리의 효과가 충분하지 못한 문제가 있다.Further, the water functions as a medium for uniformly applying the silane compound to the fabric. If the content of the silane compound is less than 16 per weight of the silane compound 2 in terms of the weight ratio, the concentration of the silane compound becomes too high resulting in cost loss. On the contrary, 2, the effect of treating the silane compound is insufficient.
이와 같이 구성된 실란계 수성 커플링제에 상기 아라미드 직물을 침지하여 함침한 후, 3.5~4.5kg/㎠ 압력의 망글 롤러(mangle roller)를 이용하여 아라미드 직물에 함침된 실란계 수성 커플링제의 양을 일정하게 분산시켜 주는데, 이때 압력이 3.5 kg/㎠ 미만이면 상기 아라미드 직물의 표면에 커플링제가 불균일하게 분포하는 문제가 있고, 반대로 4.5kg/㎠ 초과하면 아라미드 직물이 커플링제에 충분히 함침되지 못하는 문제가 있다. After the aramid fabric is impregnated and impregnated with the silane-based aqueous coupling agent thus formed, the amount of the silane-based aqueous coupling agent impregnated into the aramid fabric is measured by a mangle roller at a pressure of 3.5 to 4.5 kg / If the pressure is less than 3.5 kg / cm < 2 >, there is a problem that the coupling agent is unevenly distributed on the surface of the aramid fabric. On the other hand, if the pressure is more than 4.5 kg / cm < 2 >, the problem that the aramid fabric is not sufficiently impregnated with the coupling agent have.
그리고, 상기와 같이 망글롤러로 압착한 후에는 180~200℃에서 큐어링하고, 200~230℃, 35~50m/min의 조건(텐터 10챔버기준)으로 열처리하여 아라미드 직물 자체의 인장강도 및 인장탄성률이 현저히 증가되도록 한다. 이때 큐어링 온도가 180℃ 미만이면 인장강도 및 인장탄성률에서 주목할 만한 변화가 없고, 반대로 200℃ 초과이면 상기 아라미드 직물이 수축 손상되는 문제가 있다.Then, after being compressed by the mesh rollers as described above, curing is performed at 180 to 200 ° C. and heat treatment is performed under the conditions of 200 to 230 ° C. and 35 to 50 m / min (based on the tenter 10 chamber) to determine the tensile strength of the aramid fabric itself, So that the modulus of elasticity is significantly increased. If the curing temperature is lower than 180 ° C, there is no noticeable change in tensile strength and tensile elastic modulus. On the contrary, if the curing temperature is higher than 200 ° C, the aramid fabric is shrunk and damaged.
이와 같이 제조된 다이아프램용 원단은 별도공정에서 고무와 결합하여 다이아프램으로 제조되는데, 그 예로는 상기한 바와 같이 큐어링한 아라미드 직물의 일면 또는 양면에 아라미드 직물의 양면 각각 면적 1㎡ 당 무게가 460~500g인 실리콘 고무판을 적층하고, 200~220℃의 온도 하에서 3~3.5kg/㎠ 의 압력으로 양면을 압착하여 다이아프램을 제조하게 된다.The diaphragm fabric thus manufactured is made of a diaphragm in combination with rubber in a separate process. For example, the aramid fabric having a cured aramid fabric has a weight per square meter of area of both sides of the aramid fabric A silicone rubber sheet having a thickness of 460 to 500 g is laminated and a diaphragm is produced by squeezing both surfaces at a pressure of 3 to 3.5 kg / cm 2 at a temperature of 200 to 220 ° C.
그러므로 본 발명에 의해 유체의 이송 시 내압성능을 향상하고 고온에서 열적 내구성이 우수한 다이어프램을 제공할 수 있으며, 편물과 대비하여 보다 강인하여 내파열압등과 내구성이 향상된 다이어프램을 제공할 수 있다.Therefore, according to the present invention, it is possible to provide a diaphragm capable of providing a diaphragm having improved resistance to internal pressure at the time of transfer of a fluid and having excellent thermal durability at high temperature, and being stronger than a knitted fabric, thereby improving diaphragm rupture pressure and durability.
도 1은 본 발명의 아라미드직물을 사용한 자동차용 다이어프램용 원단의 표면사진이며,
도 2는 본 발명의 아라미드직물을 사용한 자동차용 다이어프램용 원단을 사용한 다이어프램의 한예의 사진이며,
도 3은 본 발명의 아라미드직물을 사용한 자동차용 다이어프램용 원단을 사용한 다이어프램의 적용례의 사진이다.1 is a photograph of a surface of a fabric for an automobile diaphragm using an aramid fabric according to the present invention,
2 is a photograph of an example of a diaphragm using a fabric for an automobile diaphragm using the aramid fabric of the present invention,
3 is a photograph of an application example of a diaphragm using a fabric for an automobile diaphragm using the aramid fabric of the present invention.
다음의 실시예에서는 본 발명의 아라미드직물을 사용한 자동차용 다이어프램용 원단을 제조하는 비한정적인 예시를 하고 있다.The following examples illustrate non-limiting examples of making fabrics for automotive diaphragms using the aramid fabrics of the present invention.
[실시예 1][Example 1]
원사로서 아라미드 방적사를 2합하여 표 1과 같이 경사 및 위사로 사용하고, 경사로 사용하기전에 전분 30%, PVA 60%, 왁스 7%, 오일 3%를 혼합하여 호제로 사용하여 사이징하고 제직한 후, 90℃, 45min 지거에서 전처리한 후 NaOH (농도50%)80 g/L, 정련제 25 g/L를 함유하는 정련욕에서 90℃에서 정련을 통하여 호발한 후 건조한 후, 수성 실란계 커플링제를 함침하고 200℃에서 큐어링하고, 230℃ㅧ35m/min의 조건(텐터 10챔버기준)으로 열처리하여 자동차용 다이어프램용 원단을 제조하였다. 제조된 원단의 물성은 표 1에 나타내었다.The aramid spun yarn as a yarn was used as warp and weft as shown in Table 1. The yarn was sieved and weighed using a mixture of starch 30%, PVA 60%, wax 7% and oil 3% After pre-treatment at 90 DEG C for 45 minutes, the mixture was subjected to refining at 90 DEG C in a refining bath containing 80 g / L of NaOH (concentration 50%) and 25 g / L of a scouring agent, followed by drying, followed by impregnation with an aqueous silane coupling agent , Curing at 200 ° C, and heat treated at 230 ° C and 35 m / min (tenter 10 chamber basis) to fabricate automotive diaphragm fabrics. The physical properties of the prepared fabric are shown in Table 1.
Claims (3)
상기 호제는 전분 25~30중량%, PVA 60~70중량%, 왁스 4.8~7중량%, 오일 0.2~3중량%를 혼합한 것을 특징으로 하는 아라미드직물을 사용한 자동차용 다이어프램용 원단의 제조방법. The method according to claim 1,
The method of manufacturing an automotive diaphragm fabric according to claim 1, wherein the adhesive agent comprises 25-30 wt% of starch, 60-70 wt% of PVA, 4.8-7 wt% of wax, and 0.2-3 wt% of oil.
상기 수성 실란계 커플링제는 n-(2-아미노에틸)-3-아미노프로필 트리메톡시 실란, 3-글리시독시 프로필트리메톡시 실란, 3-메타크릴 옥시프로필 트리 메톡시 실란, 3-머캅토 프로필트리 메톡시 실란 중 어느 하나이상인 수성 실란계 화합물과 아세트산, 물을 중량비 2:0.6:16~2:1:18로 혼합한 수성 실란계 커플링제인 것을 특징으로 하는 아라미드직물을 사용한 자동차용 다이어프램용 원단의 제조방법.The method according to claim 1,
The aqueous silane coupling agent is selected from the group consisting of n- (2-aminoethyl) -3-aminopropyltrimethoxysilane, 3-glycidoxypropyltrimethoxysilane, 3-methacryloxypropyltrimethoxysilane, 3- Wherein the aqueous silane coupling agent is a water-based silane coupling agent in which acetic acid and water at a weight ratio of 2: 0.6: 16 to 2: 1: 18 are mixed with an aqueous silane compound, A method for manufacturing a diaphragm fabric.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020160113408A KR101872450B1 (en) | 2016-09-02 | 2016-09-02 | Manufacturing Method Of The Automotive Diaphragm Fabric Using Aramid Fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020160113408A KR101872450B1 (en) | 2016-09-02 | 2016-09-02 | Manufacturing Method Of The Automotive Diaphragm Fabric Using Aramid Fabric |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20180026262A true KR20180026262A (en) | 2018-03-12 |
| KR101872450B1 KR101872450B1 (en) | 2018-06-28 |
Family
ID=61728750
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020160113408A KR101872450B1 (en) | 2016-09-02 | 2016-09-02 | Manufacturing Method Of The Automotive Diaphragm Fabric Using Aramid Fabric |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR101872450B1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101983080B1 (en) * | 2018-07-06 | 2019-05-30 | 주식회사 백일 | High Fidelity Speaker Damper Using Aramid Warp Knitted Fabric |
| KR101995665B1 (en) * | 2018-03-21 | 2019-07-02 | 김점석 | Diaphragm-based fabrics woven into aramid w cover rings and aramid w cover rings for the slag weaving of the diaphragm |
| CN113564923A (en) * | 2021-06-08 | 2021-10-29 | 上海工程技术大学 | Surface sizing agent for aramid fiber composite material and preparation and application thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102153251B1 (en) * | 2020-01-16 | 2020-09-07 | 정일범 | Method for manufacturing diaphragm |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0813331A (en) * | 1994-06-23 | 1996-01-16 | Kuraray Co Ltd | Method for sizing yarn |
| KR20100098470A (en) | 2009-02-28 | 2010-09-07 | 충남대학교산학협력단 | Aramid fiber reinforced chloroprene rubber composite and manufacturing method thereof |
| KR20120035141A (en) * | 2009-03-16 | 2012-04-13 | 보르벡크 머터리얼스 코포레이션 | Reinforced polymeric articles |
| KR101325606B1 (en) * | 2012-06-26 | 2013-11-20 | 영풍화성(주) | Method of manufacturing coated sailcloth comprising ultra high milecular weight polyethylene fiber and high strength polyester fiber |
| KR20140129675A (en) * | 2013-04-30 | 2014-11-07 | 안켐 주식회사 | manufacturing method of the automotive diaphragm fabric |
-
2016
- 2016-09-02 KR KR1020160113408A patent/KR101872450B1/en active IP Right Grant
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0813331A (en) * | 1994-06-23 | 1996-01-16 | Kuraray Co Ltd | Method for sizing yarn |
| KR20100098470A (en) | 2009-02-28 | 2010-09-07 | 충남대학교산학협력단 | Aramid fiber reinforced chloroprene rubber composite and manufacturing method thereof |
| KR20120035141A (en) * | 2009-03-16 | 2012-04-13 | 보르벡크 머터리얼스 코포레이션 | Reinforced polymeric articles |
| KR101325606B1 (en) * | 2012-06-26 | 2013-11-20 | 영풍화성(주) | Method of manufacturing coated sailcloth comprising ultra high milecular weight polyethylene fiber and high strength polyester fiber |
| KR20140129675A (en) * | 2013-04-30 | 2014-11-07 | 안켐 주식회사 | manufacturing method of the automotive diaphragm fabric |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101995665B1 (en) * | 2018-03-21 | 2019-07-02 | 김점석 | Diaphragm-based fabrics woven into aramid w cover rings and aramid w cover rings for the slag weaving of the diaphragm |
| KR101983080B1 (en) * | 2018-07-06 | 2019-05-30 | 주식회사 백일 | High Fidelity Speaker Damper Using Aramid Warp Knitted Fabric |
| CN113564923A (en) * | 2021-06-08 | 2021-10-29 | 上海工程技术大学 | Surface sizing agent for aramid fiber composite material and preparation and application thereof |
| CN113564923B (en) * | 2021-06-08 | 2023-06-06 | 上海工程技术大学 | Surface sizing agent for aramid fiber composite material and preparation and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| KR101872450B1 (en) | 2018-06-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101872450B1 (en) | Manufacturing Method Of The Automotive Diaphragm Fabric Using Aramid Fabric | |
| KR101094665B1 (en) | A process for preparing aramid prepreg for fiber-reinforced composite | |
| RU2550098C2 (en) | Toothed belt | |
| JP5114736B2 (en) | Manufacturing method of SMC sheet material | |
| EP3643832B1 (en) | Cord for rubber reinforcement and rubber product obtained using same | |
| WO2006001385A1 (en) | Cord for reinforcing rubber, method of manufacturing the cord, and rubber product using the cord | |
| KR20160074296A (en) | Method for manufacturing hybrid ceramic fiber reinforced composite material and hybrid ceramic fiber reinforced composite material manufactured thereby | |
| CN106113813A (en) | A kind of shuffling cloth using superhigh molecular weight polyethylene fibers and aramid fiber | |
| US20170087806A1 (en) | Fiber-reinforced composite laminate and articles made therefrom | |
| KR20150081233A (en) | Complex materials having excellent thermal and excellent moldability and Preparing method thereof | |
| US9764529B2 (en) | Composite articles and methods of producing same | |
| KR20140129675A (en) | manufacturing method of the automotive diaphragm fabric | |
| WO2014015801A1 (en) | Composite plastic sheet, application of same, and application method therefor | |
| RU2793691C1 (en) | Method for obtaining a composite high-modulus material based on butadiene elastomer with a flexible reinforcing element | |
| CN115160608B (en) | Basalt fiber reinforced polyether-ether-ketone based composite material, and preparation method and application thereof | |
| KR900002177B1 (en) | The process for the preparing fiber reinforced complex material | |
| KR101716674B1 (en) | Process Of Producing Aramid Short Staple Dipcord For Extrusiontype High Temperature And High Pressure rubber hose | |
| JP2015218398A (en) | Carbon fiber sizing agent and carbon fiber cord for rubber reinforcement | |
| KR101171424B1 (en) | Aramid complex product and method for manufacturing the same | |
| JP6237347B2 (en) | FIBER-REINFORCED THERMOPLASTIC RESIN COMPOSITE HAVING TWO-LAYER COATING CONFIGURATION | |
| JP2011226004A (en) | Method for producing carbon fiber | |
| Fiore et al. | Ef-fect of Glass Fiber Hybridization on the Durability in Salt-Fog Environ-ment of Pinned Flax Composites. Polymers 2021, 13, 4201 | |
| JP2024141138A (en) | Rubber reinforcing fiber cord | |
| JP2002321228A (en) | Jacket for vulcanizing belt sleeve | |
| CN118029141A (en) | Preparation method and application of ultra-high molecular weight polyethylene impregnating solution |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| E902 | Notification of reason for refusal | ||
| E701 | Decision to grant or registration of patent right |