KR20170140533A - Complex Warm Polyester Faber - Google Patents

Complex Warm Polyester Faber Download PDF

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KR20170140533A
KR20170140533A KR1020160072939A KR20160072939A KR20170140533A KR 20170140533 A KR20170140533 A KR 20170140533A KR 1020160072939 A KR1020160072939 A KR 1020160072939A KR 20160072939 A KR20160072939 A KR 20160072939A KR 20170140533 A KR20170140533 A KR 20170140533A
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South Korea
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polyester fiber
present
aluminum oxide
tungsten carbide
warmth
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KR1020160072939A
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Korean (ko)
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KR101849216B1 (en
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신동수
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신동수
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/106Radiation shielding agents, e.g. absorbing, reflecting agents
    • A41D31/0033
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00Materials specially adapted for outerwear
    • A41D31/04Materials specially adapted for outerwear characterised by special function or use
    • A41D31/06Thermally protective, e.g. insulating
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D1/00Treatment of filament-forming or like material
    • D01D1/02Preparation of spinning solutions
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/28Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30Conjugate filaments; Spinnerette packs therefor
    • D01D5/34Core-skin structure; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/52Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads thermal insulating, e.g. heating or cooling
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D2400/00Functions or special features of garments
    • A41D2400/10Heat retention or warming
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Multicomponent Fibers (AREA)

Abstract

The present invention relates to a composite warmth-retaining polyester fiber, in which tungsten carbide (WC) in a polyester fiber and aluminum oxide (Al_2O_3) are contained, wherein the WC and Al_2O_3 are contained, respectively, in 0.1 to 2 wt% of the weight of the polyester fiber. The composite warmth-retaining polyester fiber according to the present invention has an effect of enhancing warmth-retaining properties by performing combined warmth-retaining functions through an inorganic material which emits far-infrared rays inside the fiber and an inorganic material which reflects body heat back to the human body.

Description

복합보온성 폴리에스테르 섬유{Complex Warm Polyester Faber}Composite warm polyester fiber {Complex Warm Polyester Faber}

본 발명은 복합보온성 폴리에스테르 섬유에 관한 것으로 섬유자체적으로 원적외선이 방사되고, 신체에서 발산되는 체열를 반사하여 보온성이 우수한 복합보온성 폴리에스테르 섬유에 관한 것이다.The present invention relates to a composite heat-resistant polyester fiber, and more particularly, to a composite heat-resistant polyester fiber having excellent heat retention by reflecting far-infrared rays of the fibers themselves and radiating body heat emitted from the body.

섬유제품의 보온성에 관한 관심과 기술개발을 위한 연구는 섬유산업의 초기부터 이루어져왔다.Interest in the warmth of textile products and research for technology development have been made since the early days of the textile industry.

섬유제품의 보온의 개념은 인체에서 방출되는 열을 외부로 손실되지 않게 하는 단열에 의한 소극적 보온효과에서 적외선 반사소재를 사용하는 방법, 인체 방사 에너지를 흡수하는 소재를 사용하는 방법 등 축열, 발열 등의 적극적 보온효과로 점차 연구영역이 넓어지고 있다.The concept of thermal insulation of a textile product is a method of using infrared reflective material in a passive warming effect by heat insulation which does not lose the heat radiated from the human body to the outside, a method of using a material absorbing human radiant energy, The research area is gradually widening due to the active warming effect.

소극적 보호효과는 공기층에 의한 단열보온방식은 피복을 구성하는 직물의 두께를 증가시키는 이유가 되어 활동성이 낮아지는 원인이 되며, 기타 소재를 이용하는 방식은 피복의 세탁성이나 내구성을 저하시키는 요소가 되어 범용적으로 사용하기 어려운 단점이 있다. The passive protection effect is caused by the increase of the thickness of the fabric constituting the covering layer due to the air layer, which causes the activity to be lowered, and the method using other materials is a factor that deteriorates the washing property and durability of the covering There is a disadvantage that it is difficult to use it universally.

대한민국 실용신안공고 제200227811호에서는 방적사 또는 멀티필라멘트사인 경사와위사가 서로 교차하여 제직된 원단에 있어서, 폴리아미드 섬유 상에 은이 도금되어 있는 은 도금사가 경사방향 또는 위사 양방향에 일정간격으로 배열되어 있는 것을 특징으로 하는 다기성 원단이 제안되었다. 상기 원단은 은 도금사가 경사 또는 위사방향을 일정하게 배열되어 있어 제전효과 및 단열이나 보온효과가 우수한 특성이 있다고 하지만 직물에 일정 간격으로 배치된 은 도금사의 존재로 보온효과를 기대하기는 상기 은도금사와 함께 직조되는 더 많은 올 수의 열전도도에 차이가 없는 일반사로 인해 단열성이나 보온성을 발현하기가 어렵다. 더욱이 은 도금사가 배치된 부분 외에 대부분이 열전도도가 낮은 섬유로 구성된다는 점은 동일층의 직물에서 일부분의 열전도도 차이로 인해 단열성을 구현되지 않아 효과가 미미한 문제점이 있었다.Korean Utility Model Provisional Publication No. 200227811 discloses a fabric obtained by weaving yarn yarns and multifilament yarns intersecting weft yarns and weft yarns in such a manner that silver plated yarns plated on polyamide fibers are arranged at regular intervals in both oblique and weft directions And the like. Although the silver plated yarn has the characteristics of excellent antistatic effect and thermal insulation or thermal insulation effect because the silver plating yarns are arranged in the warp or weft direction constantly, in order to expect a warming effect in the presence of the silver plated yarn arranged at regular intervals in the fabric, It is difficult to exhibit heat insulation and warmth due to the general yarn having no difference in the thermal conductivity of more wool which is woven together. In addition, the fact that most of the fabric is made of fibers having low thermal conductivity in addition to the portion where the silver plating yarns are disposed has a problem in that the effect is insufficient because the heat insulating property is not realized due to a difference in thermal conductivity of a part of the fabric of the same layer.

적극적 보온효과는 축열 소재의 활용한 보온, 세라믹 등이 소재를 통한 원적외선 방출을 통한 보온, 열을 직접적으로 발생시키는 소재나 구성을 통한 보온 등이 있으며, 국제공개공보 WO2002/34988에서는 전원으로부터 열을 발생시키기 위한 전도성 사로 제조된 직물로서 일 이상의 비전도성사와 일 이상의 양의 온도계수(PTC)가열사를 포함하고 상기 비전도성사 및 PTC 가열사가 조합되어 가열 직물을 형성하는 구조가 제안되었다. 상기 발명은 별도의 전원을 발생시키는 구조가 필요하며 피복적합성이 저하되는 등 문제가 있다.The active warming effect can be achieved by the heat insulation using the heat accumulating material, the warming through the far-infrared ray emission through the material such as the ceramic, and the warming through the material or the structure directly generating heat. In WO2002 / 34988, There has been proposed a structure in which one or more nonconductive sheets and one or more positive temperature coefficient (PTC) heating yarns are combined as a fabric made from conductive yarn to form a heating fabric, and the nonconductive sheet and the PTC heating yarn are combined to form a heating fabric. The above-described invention requires a structure for generating a separate power source, and there is a problem that the suitability for covering is lowered.

본 발명은 상기와 같은 종래의 기술의 문제점을 해결하기 위해 발명된 것으로 원적외선을 방출하는 무기물 및 인체에서 발산되는 체열을 다시 인체로 반사하는 무기물로 복합적인 보온기능을 수행하여 보온성을 향상시킬 수 있는 복합보온성 폴리에스테르 섬유에 관한 것이다.The present invention has been made to solve the problems of the conventional art as described above, and it is an object of the present invention to provide an apparatus and a method for improving the warmth by performing a combined warming function by an inorganic material emitting far infrared rays and an inorganic material reflecting body heat, The present invention relates to a composite heat-resistant polyester fiber.

또한, 폴리에스테르 섬유를 시스-코어형으로 형성하여 원적외선 방출기능과 체열을 반사하는 기능의 효율을 높여 보온성을 향상시킬 수 있는 복합보온성 폴리에스테르 섬유에 관한 것이다.Further, the present invention relates to a composite heat-resistant polyester fiber capable of improving the warmth by increasing the efficiency of the function of reflecting the far-infrared ray emitting function and the body heat by forming the polyester fiber into a sheath-core type.

본 발명은 폴리에스테르 섬유에 텅스텐 카바이드(WC), 산화알루미늄(Al2O3)이 함유되되, 상기 텅스텐 카바이드(WC), 산화알루미늄(Al2O3)은 각각 폴리에스테르 섬유 중량의 0.1~2중량%가 함유되는 것을 특징으로 하는 복합보온성 폴리에스테르 섬유를 제공한다.The present invention relates to a polyester fiber comprising tungsten carbide (WC) and aluminum oxide (Al 2 O 3 ), wherein the tungsten carbide (WC) and aluminum oxide (Al 2 O 3 ) By weight based on the total weight of the thermosetting polyester fiber.

또한, 상기 폴리에스테르 섬유는 시스부와 코어부를 갖는 시스-코어형 복합섬유로 상기 코어부에는 텅스텐 카바이드가 함유되고, 상기 시스부에는 산화알루미늄이 함유되는 것을 특징으로 하는 복합보온성 폴리에스테르 섬유를 제공한다.The present invention also provides a composite heat-resistant polyester fiber characterized in that the polyester fiber is a sheath-core type composite fiber having a sheath portion and a core portion, tungsten carbide is contained in the core portion, and aluminum oxide is contained in the sheath portion do.

또한, 상기 텅스텐 카바이드 및 산화알루미늄의 크기는 0.05~1㎛인 것을 특징으로 하는 복합보온성 폴리에스테르 섬유를 제공한다.Also, the composite heat-resistant polyester fiber is characterized in that the size of the tungsten carbide and the aluminum oxide is 0.05 to 1 탆.

또한, 상기의 복합보온성 폴리에스테르 섬유를 포함하는 것을 특징으로 하는 원단을 제공한다.Further, the present invention provides a fabric comprising the composite heat-resistant polyester fiber.

상기와 같이 본 발명에 따른 복합보온성 폴리에스테르 섬유는 섬유 내부에 원적외선을 방출하는 무기물과 체열을 다시 인체로 반사하는 무기물을 통해 보온기능을 복합적으로 수행하여 보온성을 향상시킬 수 있는 효과가 있다.As described above, the composite heat-resistant polyester fiber according to the present invention has an effect of enhancing the warmth by performing a combined function of an inorganic material emitting far-infrared rays and an inorganic material reflecting body heat again to the human body.

또한, 폴리에스테르 섬유를 시스-코어형으로 형성하고 시스부에 체열을 반사하는 무기물을 함유시켜 체열 반사기능을 향상시킬 수 있는 효과가 있다.Further, the polyester fiber is formed into a sheath-core type, and the sheath portion contains an inorganic material that reflects body heat, thereby improving the heat reflection function.

도 1은 본 발명에 따른 복합보온성 폴리에스테르 섬유의 일실시예의 단면을 나타낸 도면이다.
도 2는 본 발명에 따른 복합보온성 폴리에스테르 섬유의 또다른 실시예의 단면을 나타낸 도면이다.
1 is a cross-sectional view of an embodiment of a composite heat-resistant polyester fiber according to the present invention.
2 is a cross-sectional view of another embodiment of the composite heat-resistant polyester fiber according to the present invention.

이하 본 발명의 바람직한 일실시예를 상세히 설명하기로 한다. 우선, 본 발명을 설명함에 있어, 관련된 공지기능 혹은 구성에 대한 구체적인 설명은 본 발명의 요지를 모호하지 않게 하기 위하여 생략한다.Hereinafter, a preferred embodiment of the present invention will be described in detail. In the following description of the present invention, a detailed description of known functions and configurations incorporated herein will be omitted so as to avoid obscuring the subject matter of the present invention.

본 명세서에서 사용되는 정도의 용어 '약', '실질적으로' 등은 언급된 의미에 고유한 제조 및 물질 허용오차가 제시될 때 그 수치에서 또는 그 수치에 근접한 의미로 사용되고, 본 발명의 이해를 돕기 위해 정확하거나 절대적인 수치가 언급된 개시 내용을 비양심적인 침해자가 부당하게 이용하는 것을 방지하기 위해 사용된다.As used herein, the terms " about, " " substantially, " " etc. ", when used to refer to a manufacturing or material tolerance inherent in the stated sense, Accurate or absolute numbers are used to help prevent unauthorized exploitation by unauthorized intruders of the referenced disclosure.

본 발명에서 '원단'은 사로 제직기로 직조되는 직물, 편직기 편조되는 편물 또는 장섬유 또는 단섬유로 직조, 편조되지 않고 기계적, 화학적 방법으로 형성되는 부직포를 모두 포함하는 의미로 사용된다.In the present invention, the term "fabric" is used to mean a fabric woven with a weaving machine, a knitting machine, a nonwoven fabric knitted or knitted with a long fiber or a short fiber, and a nonwoven fabric formed by a mechanical or chemical method without being woven or braided.

도 1은 본 발명에 따른 복합보온성 폴리에스테르 섬유의 일실시예의 단면을 나타낸 도면이고, 도 2는 본 발명에 따른 복합보온성 폴리에스테르 섬유의 또다른 실시예의 단면을 나타낸 도면이다.Fig. 1 is a cross-sectional view of one embodiment of the composite heat-resistant polyester fiber according to the present invention, and Fig. 2 is a cross-sectional view of another embodiment of the composite heat-resistant polyester fiber according to the present invention.

본 발명은 원적외선을 방출하는 텅스텐 카바이드(WC) 및 체열을 반사할 수 있는 산화알루미늄((Al2O3)을 폴리에스테르 섬유에 함유시켜 보온성을 효과적으로 향상시킬 수 있는 복합보온성 폴리에스테르 섬유에 관한 것이다.The present invention relates to a composite thermal insulation polyester by incorporating the aluminum oxide to reflect the tungsten carbide (WC) and body temperature, which emits far-infrared ((Al 2 O 3) to a polyester fiber which can effectively improve the thermal insulation fibers .

상기 텅스텐 카바이드, 산화알루미늄은 원적외선을 방출하여 체온을 상승을 통한 보온성을 높이는 작용을 하며, 상기 산화알루미늄은 신체에서 발생되는 체열을 반사시켜 다시 신체로 돌려보내는 작용으로 복합적인 기능으로 폴리에스테르 섬유의 보온성을 높이게 된다.The tungsten carbide and aluminum oxide emit far-infrared rays to increase the warmth by raising the body temperature. The aluminum oxide reflects the body heat generated from the body and returns it to the body. As a result, The warmth is enhanced.

상기 텅스텐 카바이드(WC), 산화알루미늄의 함량이 너무 적으며 보온성의 상승효과가 크지 않으며, 상기 텅스텐 카바이드(WC), 산화알루미늄의 함량이 너무 많으면 섬유 제조시 사절현상 등이 발생하여 공정성이 저하될 수 있으므로 함유되되, 상기 텅스텐 카바이드(WC), 산화알루미늄는 각각 폴리에스테르 섬유 중량의 0.1~2중량%가 함유되는 것을 특징으로 하는 복합보온성 폴리에스테르 섬유를 제공한다.The content of the tungsten carbide (WC) and the aluminum oxide is too small and the synergistic effect of warming property is not significant. If the content of tungsten carbide (WC) and aluminum oxide is too large, , Wherein the tungsten carbide (WC) and the aluminum oxide each contain 0.1 to 2% by weight of the polyester fiber.

또한, 상기 텅스텐 카바이드와 산화알루미늄의 크기가 너무 크면 방사공정에서 기계장치의 마모율을 높일 수 있으므로, 상기 텅스텐 카바이드와 산화알루미늄의 크기는 0.05~1㎛인 것이 바람직할 것이다.If the sizes of the tungsten carbide and aluminum oxide are too large, the wear rate of the mechanical device in the spinning process can be increased. Therefore, the size of the tungsten carbide and the aluminum oxide is preferably 0.05 to 1 μm.

상기와 같이 텅스텐 카바이드와 산화알루미늄을 함유하는 본 발명의 폴리에스테르 섬유는 도 1에서와 같이 텅스텐 카바이드(100)와 산화알루미늄(200)이 섬유 내부에 단순히 함유된 상태에서도 보온 효과가 우수하지만, 본 발명의 복합보온성 폴리에스테르 섬유의 보온효과를 더욱 높이기 위해 도 2에서와 같이 본 발명의 폴리에스테르 섬유를 시스부와 코어부를 갖는 시스-코어형 복합섬유로 형성하는 것이 바람직할 것이다.As described above, the polyester fiber of the present invention containing tungsten carbide and aluminum oxide as described above is excellent in thermal insulation effect even when tungsten carbide (100) and aluminum oxide (200) are simply contained in the fiber, In order to further enhance the warming effect of the composite heat-resistant polyester fiber of the present invention, it is preferable to form the polyester fiber of the present invention with the sheath-core type composite fiber having the sheath portion and the core portion as shown in Fig.

상기 시스-코어형 복합섬유로 형성될 경우에는 코어부에는 텅스텐 카바이드(100)를 함유시키고, 시스부에는 산화알루미늄(200)을 함유시켜 본 발명의 복합보온성 폴리에스테르 섬유를 형성할 수 있을 것이다.In the case of the sheath-core type composite fiber, the core portion may contain tungsten carbide (100) and the sheath portion may contain aluminum oxide (200) to form the composite heat-resistant polyester fiber of the present invention.

상기 시스부에 함유되는 산화알루미늄은 도 1의 폴리에스테르 섬유에 비해 섬유외곽에 산화알루미늄의 함량이 높아지게 되어 체열을 반사하는 기능이 더 상승하게 되어 보온성을 더욱 향상시킬 수 있다.The aluminum oxide contained in the sheath portion has a higher content of aluminum oxide on the outer side of the fiber than in the polyester fiber of Fig. 1, so that the function of reflecting body heat further increases, thereby further improving warmth.

상기 본 발명의 복합보온성 폴리에스테르 섬유는 사용용도 및 목적에 따라 다양한 이형단면 형태 및 또다른 기능성 물질을 함유시킬 수 있을 것이다.The composite heat-resistant polyester fiber of the present invention may contain various modified cross-sectional shapes and other functional materials depending on the intended use and purpose.

상기와 같이 본 발명에 따른 복합보온성 폴리에스테르 섬유를 함유하는 원단은 복합보온성 폴리에스테르 섬유의 원적외선 방사기능, 체열을 반사하는 기능을 통해 보온성을 높일 수 있어 의류용에 적합할 것이다.As described above, the fabric containing the composite heat-resistant polyester fiber according to the present invention can improve the warmth through the function of reflecting the far-infrared radiation function and the body heat of the composite heat-resistant polyester fiber, and thus it is suitable for clothing.

이하 본 발명에 따른 복합보온성 폴리에스테르 섬유를 제조하기 위한 방법의 실시예를 나타내지만, 본 발명이 실시예로 한정되는 것은 아니다.Hereinafter, examples of the method for producing the composite heat-resistant polyester fiber according to the present invention are shown, but the present invention is not limited to the examples.

실시예Example 1 One

폴리에스테르 수지에 입자크기 0.5㎛의 텅스텐 카바이드 1중량%, 입자크기 0.5㎛의 산화알루미늄 1.0중량%를 함유시켜 방사조성물을 제조 후, 일반적인 멀티필라멘트의 방사공정과 동일한 방법으로 방사공정을 진행하여 본 발명의 복합보온성 폴리에스테르 섬유를 제조하였다.1% by weight of tungsten carbide having a particle size of 0.5 占 퐉 and 1.0% by weight of aluminum oxide having a particle size of 0.5 占 퐉 were contained in a polyester resin to prepare a spinning composition and then the spinning process was carried out in the same manner as the spinning process of general multifilament, The composite heat-resistant polyester fiber of the present invention was produced.

실시예 2Example 2

시스-코어형 복합섬유로 제조하였으며, 시스부를 형성하는 폴리에스테르 수지에 입자크기 0.5㎛의 산화알루미늄 1.0중량%를 함유시켰으며, 코어부를 형성하는 폴리에스테르 수지에 입자크기 0.5㎛의 텅스텐 카바이드 1중량%를 함유시켰다.Core-type composite fiber, 1.0 wt% of aluminum oxide having a particle size of 0.5 mu m was contained in the polyester resin forming the sheath portion, 1 wt.% Of tungsten carbide having a particle size of 0.5 mu m %.

시스부와 코어부의 부피비는 50:50으로 일반적인 시스-코어형 복합섬유의 방사공정과 동일한 방법으로 방사공정을 진행하여 본 발명의 복합보온성 폴리에스테르 섬유를 제조하였다.The volume ratio of the sheath portion and the core portion was 50:50, and the spinning process was performed in the same manner as the spinning process of the general sheath-core type conjugate fiber to prepare the composite heat-resistant polyester fiber of the present invention.

◎ 보온성 평가◎ Evaluation of warmth

상기에서 제조된 실시예 1,2를 원단으로 제조한 후에 보온성을 평가하여 표 1에 나타내었다. 비교예로 아무런 물질도 함유시키지 않은 폴리에스테르 섬유를 제조하고 원단으로 제조한 후, 평가하였다. After the fabricated examples 1 and 2 were fabricated, the warmth was evaluated and shown in Table 1. As a comparative example, polyester fibers not containing any substance were prepared and fabricated and evaluated.

1) 평가방법1) Evaluation method

- 광원이 설치된 외부온도 25℃, 습도 40%로 고정 열 차단 평가 장치를 이용하여 실험하였다.- Experiments were conducted using a fixed heat interrupter with an external temperature of 25 ° C and a humidity of 40%.

- 광원에 전원공급 후 원단의 표면 온도와 광원과 원단 내부 공간의 온도를 합하여 평균값을 산출하였으며, 초기온도와 일정시간 후의 상승된 온도의 차이를 측정하여 표 1에 나타내었다.(ΔT: 상승 온도차)- After supplying power to the light source, the average value was calculated by adding the surface temperature of the fabric and the temperature of the light source and the inner space of the fabric. The difference between the initial temperature and the rising temperature after a certain time was measured and is shown in Table 1 (ΔT: )

구분division ΔT (상승 온도차)ΔT (rising temperature difference) 0 min0 min 10 min10 min 20 min20 min 30 min30 min 40 min40 min 50 min50 min 60 min60 min Blank Blank 00 88 88 99 99 99 99 비교예Comparative Example 00 88 99 1010 1111 1111 1111 실시예 1Example 1 00 1111 1212 1313 1414 1515 1515 실시예 2Example 2 00 1111 1212 1313 1515 1515 1616

표 1에서와 같이 본 발명에 복합보온성 폴리에스테르 섬유로 제조된 원단은 아무런 물질이 함유되지 않은 비교예 보다 시간에 따른 온도가 상승되는 차이가 커지는 것으로 본 발명의 복합보온성 폴리에스테르 섬유는 보온성이 매우 우수한 것을 알 수 있다.As shown in Table 1, the fabric made of the composite heat-resistant polyester fiber according to the present invention has a larger difference in temperature rise over time than the comparative example in which no material is contained. The composite heat- It can be seen that it is excellent.

100: 텅스텐 카바이드 200: 산화알루미늄100: tungsten carbide 200: aluminum oxide

Claims (4)

폴리에스테르 섬유에 텅스텐 카바이드(WC), 산화알루미늄(Al2O3)이 함유되되,
상기 텅스텐 카바이드(WC), 산화알루미늄(Al2O3)은 각각 폴리에스테르 섬유 중량의 0.1~2중량%가 함유되는 것을 특징으로 하는 복합보온성 폴리에스테르 섬유.
The polyester fiber contains tungsten carbide (WC) and aluminum oxide (Al 2 O 3 )
Wherein the tungsten carbide (WC) and the aluminum oxide (Al 2 O 3 ) each contain 0.1 to 2% by weight of the polyester fiber.
제1항에 있어서,
상기 폴리에스테르 섬유는 시스부와 코어부를 갖는 시스-코어형 복합섬유로 상기 코어부에는 텅스텐 카바이드가 함유되고, 상기 시스부에는 산화알루미늄이 함유되는 것을 특징으로 하는 복합보온성 폴리에스테르 섬유.
The method according to claim 1,
Wherein the polyester fiber is a sheath-core type conjugate fiber having a sheath portion and a core portion, tungsten carbide is contained in the core portion, and aluminum oxide is contained in the sheath portion.
제1항에 있어서,
상기 텅스텐 카바이드 및 산화알루미늄의 크기는 0.05~1㎛인 것을 특징으로 하는 복합보온성 폴리에스테르 섬유.
The method according to claim 1,
Wherein the size of the tungsten carbide and the aluminum oxide is 0.05 to 1 占 퐉.
제1항 내지 제3항 중 어느 한 항의 복합보온성 폴리에스테르 섬유를 포함하는 것을 특징으로 하는 원단.A fabric comprising the composite heat-resistant polyester fiber according to any one of claims 1 to 3.
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