KR20170134806A - The system and process of desalination using lava seawater for high-efficiency and low energy - Google Patents

The system and process of desalination using lava seawater for high-efficiency and low energy Download PDF

Info

Publication number
KR20170134806A
KR20170134806A KR1020160064668A KR20160064668A KR20170134806A KR 20170134806 A KR20170134806 A KR 20170134806A KR 1020160064668 A KR1020160064668 A KR 1020160064668A KR 20160064668 A KR20160064668 A KR 20160064668A KR 20170134806 A KR20170134806 A KR 20170134806A
Authority
KR
South Korea
Prior art keywords
water
reverse osmosis
salinity
lava
seawater
Prior art date
Application number
KR1020160064668A
Other languages
Korean (ko)
Other versions
KR101822188B1 (en
Inventor
김병호
김기주
허철민
양승혁
최일
부완혁
Original Assignee
재단법인 제주테크노파크
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 재단법인 제주테크노파크 filed Critical 재단법인 제주테크노파크
Priority to KR1020160064668A priority Critical patent/KR101822188B1/en
Publication of KR20170134806A publication Critical patent/KR20170134806A/en
Application granted granted Critical
Publication of KR101822188B1 publication Critical patent/KR101822188B1/en

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/025—Reverse osmosis; Hyperfiltration
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K7/00—Steam engine plants characterised by the use of specific types of engine; Plants or engines characterised by their use of special steam systems, cycles or processes; Control means specially adapted for such systems, cycles or processes; Use of withdrawn or exhaust steam for feed-water heating
    • F01K7/16—Steam engine plants characterised by the use of specific types of engine; Plants or engines characterised by their use of special steam systems, cycles or processes; Control means specially adapted for such systems, cycles or processes; Use of withdrawn or exhaust steam for feed-water heating the engines being only of turbine type
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/08—Seawater, e.g. for desalination
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/002—Construction details of the apparatus
    • C02F2201/005—Valves
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/05—Conductivity or salinity
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/10—Energy recovery
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00—Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124—Water desalination
    • Y02A20/131—Reverse-osmosis

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Nanotechnology (AREA)
  • General Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The present invention relates to a lava seawater desalination system and method in which a reverse osmosis process is performed in which the desalination process proceeds differently depending on the salinity, and more particularly, to a lava seawater desalination system and method for recovering lava seawater, A salinity separation unit for separating high salt and low salt lava water into salinity according to salinity, a seawater reverse osmosis unit for separating high salt concentration lava seawater into high concentration concentrated water and primary fresh water, and low salinity lava seawater for low concentration concentrated water and secondary The freshwater discharged from the reverse osmosis unit of the sea water is separated from the reverse osmosis part composed of the low-salt lava seawater to be introduced into the reverse osmosis unit and filtered, and the fresh water discharged from the osmosis reverse osmosis unit is stored A fresh water storage tank, and a drain water treatment unit in which fresh water discharged from the seawater reverse osmosis unit is treated, Since the desalination process is performed according to the water salinity, the unnecessary process is shortened, energy required for desalination is reduced, no pretreatment process is required because there is no foreign matter and harmful components, and lava seawater is collected from two layers having different salinity, The present invention provides a lava seawater desalination system and method capable of supplying aquaculture water having a temperature and a salinity and also capable of generating salinity difference, thereby enabling the energy required for the desalination process to be self-produced, thereby minimizing energy consumption.

Description

[0001] The present invention relates to a high-efficiency low-energy lava seawater desalination system and a desalination method,

The present invention relates to a lava seawater desalination system and a lava seawater desalination method, and more particularly, to a lava seawater desalination system and a desalination method in which a reverse osmosis process in which desalination processes are performed differently according to salinity is provided.

The eastern part of Jeju Island has a structure in which sea water can easily flow inland due to its geological characteristics, and it has clean underground seawater permeated to land for thousands of years. The seawater, which is naturally filtered by a permeable volcanic rock layer, is called "lava seawater", which has penetrated into the land. The seawater is not mixed with the freshwater groundwater and is located below the freshwater layer.

Lava seawater flows inland up to 8 km from the coast. As shown in Fig. 2, it is mainly distributed on the eastern coastal area from Bukchonri in Jocheon-eup in Jeju to Limye-ri in Namwon-eup in Seogwipo city.

The water quality of lava seawater has stable stability (water temperature 16 ~ 18 ℃, pH 7.5) with little seasonal fluctuation and physical property change, and there is no problem of resource depletion due to continuous inflow of seawater and it is sufficient as industrial resource material. Assuming no seawater inflow, it is expected that it will be available for 19,602 years even if 1,000 m3 / day is taken. In addition, harmful components such as E. coli, ammonia nitrogen, phenols, mercury, and cadmium are not detected, and acute toxicity of the animal is not observed, thus securing water quality and cleanliness. Lava seawater contains not only major minerals in seawater but also magnesium (Mg), calcium (Ca), vanadium (V), germanium (Ge), selenium Se) and the like, and thus have various physiological effects.

As shown in [Table 1], lava seawater is similar to general salt groundwater in the items such as salt, calcium, and magnesium, but there is a clear difference in the trace element items such as vanadium, germanium, and selenium, and harmful heavy metals It can be seen that it is almost not included.

Item Average 2011 2012 In 2013 year 2014 Ca (calcium) 434 398 448 470 415 K (potassium) 474 447 450 474 512 Mg (magnesium) 1,414 1,367 1,353 1,490 1,418 Na (sodium) 10,799 10,967 10,357 11,033 10,773 Se (selenium) 0.035 0 0.06 0.02 0.06 V (vanadium) 0.05 0.04 0.08 0.04 0.03 Mo (molybdenum) 0.007 0.004 0.003 0.008 0.01 Zn (zinc) 0.002 0 0.003 0 0.003 B (boron) 4.5 2.9 4.9 4.4 5.7 Br (bromine) 60.5 61.9 58.0 62.8 59.1 Cu (copper) 0.001 0 0.000 0 0.003 Fe (iron) 0.001 0 0.000 0.005 0 Ge (Germanium) 0 0 0 0 0 Mn (manganese) 0.001 0.001 0 0 0.001 Si (SiO2) (silicon-silicate) 7.9 7.5 6.6 9.2 7.8 Sr (strontium) 7.3 7.4 7.0 7.2 7.4 Cl- (chlorine ion) 22,379 21,167 22,900 25,125 20,150 SO42- (sulfate ion) 2,859 2,723 2,913 3,150 2,628 F (fluorine) 1.1 1.1 1.2 1.1 1.1

Therefore, despite the fact that lava seawater does not contain any harmful substances and segregates foreign matter, it is more economical than conventional seawater. However, Has yet to apply the technology for extracting minerals from ordinary seawater, and has not been able to improve the equipment cost and efficiency.

A related art will be described in detail with reference to FIG. 1 (registered trademark) No. 10-1338233 (registered on February 03, 2013) entitled " Method for recovering useful metals in concentrated water by seawater desalination & have.

In the conventional art, when the concentrated water is generated in the reverse osmosis process for seawater desalination, the impurities contained in the concentrated water are removed so that the lithium loss is minimized through the mixed bed ion exchange resin tower, A phosphoric acid or a phosphoric acid compound is added to extract lithium phosphate which is a useful metal having a low solubility.

According to the above-mentioned prior art, it is possible to prevent the marine environmental pollution from occurring without discharging the concentrated water generated in the desalination treatment of seawater to the marine environment, as well as to recycle the waste from recovered useful metals such as lithium phosphate from concentrated water And it is possible to minimize the working time and electric power waste due to the recovery of the useful metal from the concentrated water, thereby making it possible to economically and efficiently recover the useful metal easily.

However, the above-mentioned prior art is effective as general seawater desalination technology, but it does not have a structure capable of taking advantage of lava seawater. In particular, since it is lava seawater, it maximizes production efficiency of fresh water and maximizes useful mineral production I can not show the configuration.

Therefore, the technology that can maximize the fresh water production rate and the useful minerals production rate is requested while greatly reducing the facility cost compared to the general sea water by making full use of the advantage of the lava water.

On the other hand, the concentration of lava seawater differs greatly depending on the mixing depth with the fresh water layer. Therefore, there may be a variation in concentration depending on other factors. Therefore, if lava seawater is uniformly subjected to a desalination process applied to general seawater, waste of energy and process can be serious. However, there is no technology currently available that can be subjected to an appropriate filtration process depending on the salinity when there is a difference in salinity depending on the intake time and the depth of the water intake.

Patent Registration No. 10-1338233 (Registration date: December 03, 2013)

Accordingly, it is an object of the present invention to improve the problems of the prior art and to maximize the advantages of the lava water and to maximize the production rate of the fresh water and the production rate of the useful minerals while greatly reducing the equipment cost compared to the general sea water, The present invention provides a lava seawater desalination system and a lava seawater desalination method capable of remarkably improving the efficiency of a desalination process by selecting an appropriate desalination process.

According to an aspect of the present invention, there is provided a lava seawater desalination system and a lava seawater desalination method including: a water intake device for taking lava seawater to the ground; A salinity separator for separating the lava water taken in by the water intake device into high salt lava water and low salinity lava water according to salinity; The reverse osmosis part is composed of the seawater reverse osmosis part where the high salt lava seawater is separated and separated by the high concentration concentrated water and the first fresh water and the reverse osmosis part where the low salinity lava seawater is separated and filtered by the low concentration concentrated water and the second fresh water. A reverse osmosis part configured to be introduced into the osmotic osmotic pressure part together with the low-salt lava water to be filtered; A fresh water storage tank for storing fresh water discharged from the radar return unit; And a drain water treatment unit for treating the fresh water discharged from the seawater reverse osmosis part.

Wherein the main transfer pipe is branched at a certain point and one of the branched main transfer pipes is connected to the seawater reverse osmosis part and the other is connected to the reverse osmosis part, Wherein the salinity separator comprises a salinity sensor provided in the main transfer pipe and a three-way valve installed at a position where the main transfer pipe is branched. When the salinity of the lava water taken in by the water intake apparatus is not less than a reference value Is transferred to the reverse osmosis part of the sea water, and if it is lower than the reference value, it is transferred to the reverse osmosis part.

Or the water intake system is composed of a high salinity water intake system for taking high salt lava seawater and a low salinity water intake system for taking low salinity lava sea water and a high salinity water intake system is connected to the seawater osmotic pressure by the high salinity lava water transfer pipeline, The salinity separator is connected to the salinity separator by a low salinity lava seawater transfer pipe. Preferably, the salinity separator comprises a first salinity sensor and a first three-way valve installed in the high salinity lava seawater transfer pipe, A second salinity sensor and a second three-way valve installed in the piping, and an omnidirectional branch pipe connecting the first three-way valve and the second three-way valve, and is conveyed along the high salt lava water transfer pipe or the low salt lava water transfer pipe If the salinity of the lava water is above the reference value, it is transferred to the seawater reverse osmosis part. If the salinity of the lava water is below the reference value, It can be.

The reverse osmosis part of the sea water and the reverse osmosis part of the sea water are preferably connected in series to each other, and the concentrated water discharged from one reverse osmosis unit is connected to the next reverse osmosis unit, And the concentrated water, and the fresh water discharged from the plurality of reverse osmosis units constituting the reverse osmosis unit of the sea water is introduced into the first reverse osmosis unit of the plurality of reverse osmosis units forming the nose reverse osmosis unit, and the plurality of reverse osmosis units The concentrated water discharged from the last reverse osmosis is delivered to the drain water treatment section.

In this case, preferably, there is provided a concentrated water re-circulation pipe connecting the first reverse osmosis unit and the last reverse osmosis unit among the plurality of reverse osmosis units constituting the radar reverse osmosis part, and the concentrated water discharged from the last reverse osmosis unit is re- Is introduced into the first reverse osmosis unit along the pipe and separated and discharged into concentrated water and fresh water again.

The effluent treatment section includes a useful mineral recovery tank for storing concentrated water for recovering beneficial minerals from the concentrated concentrated water discharged from the seawater reverse osmosis part, and a beneficial minerals such as a beneficial minerals such as a concentrated concentrated water discharge pipe connecting the seawater reverse osmosis part and the useful mineral recovery tank And a low-concentration concentrated water discharge pipe for discharging low-concentration concentrated water discharged from the water tank, and a low-concentration concentrated water discharge pipe for discharging low-concentration concentrated water discharged from the water- Wherein the high concentration concentrated water chamber and the low concentration concentrated water chamber are separated into an osmotic membrane in the housing and the fresh water is moved from the low concentration concentrated water chamber to the high concentration concentrated water chamber and the high concentration concentrated water discharged from the high concentration concentrated water chamber And a turbine driven by It may consist of saline car development assembly.

In this case, preferably, the low-concentration concentrated water discharge pipe is a pipe branching at a certain point of the concentrated water re-charging pipe and leading to a salt osmotic pressure bath.

The drain water treatment unit preferably includes a farm water tank for storing the low concentration concentrated water discharged from the salt osmosis tank and high concentration concentrated water discharged from the turbine together, a high concentration concentrated water supply pipe for connecting the turbine and the farm water tank, A concentrated three-way valve installed at a branch point of the high concentration concentrated water supply pipe and the high concentration concentrated water recovery pipe, and a third three-way valve installed in the farm water supply tank. A salinity water supply assembly comprising a third salinity sensor.

According to another aspect of the present invention, there is provided a lava seawater desalination method using the lava seawater desalination system having the above configuration, comprising the steps of: taking lava seawater; measuring the salinity of the lava seawater taken in real time; The seawater is transported to the seawater reverse osmosis unit where the salinity is higher than the reference value and the salinity of the low salinity lava which is less than the standard value is transferred to the reverse osmosis unit. A reverse osmosis step of separating the fresh water discharged from the reverse osmosis part of the seawater into fresh water and concentrated water after the entire amount of the fresh water discharged from the reverse osmosis part is transferred to the fresh water storage tank, And the concentrated water discharged from the reverse osmosis step is transferred to a drain water treatment section.

Preferably, lava seawater is taken from the low-salinity lava seawater below the freshwater layer and high-salinity lava seawater below the low salinity lava seawater layer separately from the salinity step. In the salinity separation step, And the low salinity lava water transfer pipeline to which low salinity lava seawater is transported is connected to the high salinity lava seawater transfer line and the low salinity lava seawater transfer pipeline is transported to the radar reverse osmosis part when the salinity of the high salinity lava seawater or the low salinity lava seawater is less than the reference value, , It is transported to the sea water reverse osmosis part.

In this case, preferably, the low concentration concentrated water finally discharged from the radewater desalination part is introduced into the reverse osmosis part and separated into fresh water and concentrated water.

At this time, it is preferable to mix a portion of the low-concentration concentrated water finally discharged from the sea water reverse osmosis part and a part of the concentrated concentrated water finally discharged from the sea water reverse osmosis part to make it as aquaculture water.

In this case, preferably, a portion of the low-concentration concentrated water and the portion of the high-concentration concentrated water are charged into a salt-osmotic pressure bath to further compress the high-concentration concentrated water, so that the turbine can be driven with high concentration concentrated water to produce electric power.

Preferably, when the salinity of the water for aquaculture reaches a predetermined value or more, the concentrated concentrated water for driving the turbine is transferred to the useful mineral recovery tank.

According to the lava seawater desalination system and the lava seawater desalination method according to the present invention, an appropriate desalination process is performed according to the salinity of the lava seawater to be taken, so that unnecessary process operation is not required and the energy required for desalination is reduced. There is no foreign matter and harmful components No pretreatment is required and the lava seawater is collected from two layers with different salinity, so it is possible to generate saline differential power by each concentrated water produced, so that the energy required for the desalination process can be produced by itself, minimizing energy consumption, In the absence of demand for aquaculture water, freshwater to be added to the osmotic osmotic process is produced as high-quality freshwater, thereby improving the freshwater production efficiency and freshwater quality. It is effective.

1 is a drawing showing a prior art,
FIG. 2 is a cross-sectional view showing a region where lava seawater exists,
3 is a configuration diagram of a basic embodiment of a lava seawater desalination system according to the present invention,
4 is a configuration diagram of an alternative embodiment of the lava seawater desalination system according to the present invention,
Fig. 5 is a detailed configuration diagram further illustrating Fig. 4,
6 is a block diagram showing a lava seawater desalination method according to the present invention,
FIG. 7 is a block diagram further illustrating the concentrated water treatment step in FIG. 6;

The specific structure or functional description presented in the embodiment of the present invention is merely illustrative for the purpose of illustrating an embodiment according to the concept of the present invention, and embodiments according to the concept of the present invention can be implemented in various forms. And should not be construed as limited to the embodiments described herein, but should be understood to include all modifications, equivalents, and alternatives falling within the spirit and scope of the invention.

Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.

First, a basic embodiment of the present invention will be described, and then, modified embodiments of the present invention will be described.

As shown in FIG. 3, the present invention according to a basic embodiment comprises a water intake apparatus 1, a salinity separator 3, reverse osmosis units 4 and 5, a fresh water storage tank 7, and a drain water treatment unit.

The water intake device (1) is a device for lifting the lava water existing in the ground to the ground. As shown in FIG. 2, lava seawater exists below the fresh water layer.

The salinity separator 3 separates the lava water from the seawater desalination unit 5 when the salinity is low enough that the lava seawater pulled up by the water intake unit does not have to pass both the seawater reverse osmosis part 4 and the water- It is possible to produce high quality fresh water even after a minimum number of steps according to salinity without going through an unnecessary process.

3, the salinity separator 3 includes a salinity sensor 31 and a seawater reverse osmosis (SWRO) or a radar reverse osmosis unit 5 depending on salinity, (BWRO) and brackish water reverse osmosis (BWRO).

2, the salinity separator 3 is provided with a main transfer pipe for connecting the water intake apparatus 1 and the reverse osmosis unit 4 and 5, One of the two main branch pipes branched to the branch is connected to the reverse osmosis part of the seawater and the other is connected to the reverse osmosis part of the sea water, and the salinity separator 3 is connected to the salinity sensor 31 And a salinity separating three-way valve 32 installed at a point where the main transfer pipe is branched. When the salinity of the lava water taken in by the water intake apparatus 1 is equal to or greater than a reference value, it is transferred to the seawater reverse tamping unit 4, And may be configured to be transported to the backward tilting unit 5 if the value is equal to or less than the reference value.

Sea water reverse osmosis (SWRO) 4 is a device for separating and discharging high-salt lava water through reverse osmosis process with fresh water and concentrated water. At this time, the fresh water produced in the sea water reverse osmosis (SWRO) 4 is introduced into the brackish water reverse osmosis (BWRO) 5 and then subjected to the reverse osmosis process, And low concentration concentrated water.

The high concentration concentrated water discharged from the sea water reverse osmosis part (4) is transferred to the drain water treatment section. The effluent treatment section may be a useful mineral recovery tank 6 as shown in FIG. 3, or may be discharged in its entirety, or may be used for salinity-generating power generation together with a low concentration concentrated water discharged from the radewater- It may also be used as a water supply to the farm for appropriate water temperature in the farm. This will be described later.

Since the basic embodiment of the present invention has been briefly described, the specific configuration and application examples of the present invention will be described below.

The salinity separator 3 may be configured as shown in FIG. 4, unlike FIG. In Fig. 4, the water intake apparatus is composed of a high salt removal unit 11 for taking high-salt lava water and a low-salt removal unit 12 for taking low-salt lava seawater. As shown in FIG. 2, since the lava water exists below the fresh water layer corresponding to the general ground water, the salinity is low due to mixing with the fresh water at a portion close to the fresh water layer and the salinity is low. It is close enough to sea water.

In this case, according to the present invention, the low-salinity lava seawater and the freshwater layer near the fresh water layer are separately taken from the high-salinity lava seawater, respectively, It is possible to produce high quality fresh water only with minimal power consumption and simple process according to the salinity of the lava water by allowing the low-salt lava seawater to pass only the reverse osmosis without having to go through the double reverse osmosis process. .

The high salinity water withdrawal device 11 is connected to the seawater reverse osmosis part 4 through a highly salted lava water transfer pipe and the low salinity water purifier 12 is connected to the reverse osmosis part 5 through a low salinity lava water transfer pipe.

Accordingly, the salinity separator 3 is provided with the first salinity sensor 31a and the first three-way valve 32a installed in the highly salted lava water transfer pipe and the second salinity sensor 31b installed in the low salinity lava water transfer pipe Direction branch pipe 33 connecting the first three-way valve 32a and the second three-way valve 32b and the first three-way valve 32a and the second three-way valve 32b.

In this case, if the salinity of the lava water transferred along the high salt lava water transfer pipe or the low salt lava water transfer pipe is above the reference value, it is transferred to the seawater reverse osmosis part (4). If the salinity of the lava water is below the reference value, (5). In the case of the lava water which is located at a distance or more below the freshwater layer, and the lava water is taken to the high salt removal unit (11), there may be a case where a large amount of the fresh water is mixed due to various factors. So that it is possible to produce high quality fresh water even if only the nose reverse osmosis part 5 is used. In this case, it is not necessary to pass the unnecessary seawater reverse osmosis part 4. Also, in case of the low-salinity water collector 12, lava seawater having a high salinity can be taken due to drought or other reasons. In such a case, the double-side branch pipe 33 may be provided so as to be able to be transferred to the seawater reverse- Is installed.

The seawater reverse osmosis part (4) and the sea water reverse osmosis part (5) are respectively connected in series with a plurality of reverse osmosis units, and the concentrated water discharged from one reverse osmosis unit is connected to the next reverse osmosis unit, And concentrated water.

At this time, the fresh water discharged from the plurality of reverse osmosis troughs constituting the sea water reverse osmosis part (4) is introduced into the first reverse osmosis membrane (54) among the plurality of reverse osmosis membranes forming the radix reverse osmosis part (5) The concentrated water discharged from the last reverse osmosis (46) of the plurality of reverse osmosis units is delivered to the drain water treatment unit.

5, three reverse osmosis units are arranged in series in the reverse osmosis unit 4 and the reverse osmosis unit 5, respectively. At this time, the reverse osmosis of the sea water reverse osmosis part 4 is referred to as a first sea water reverse osmosis 44, a second sea water reverse osmosis 45 and a third sea water reverse osmosis 46, The first and second odd-numbered osmosis units 54, 55 and 56 are referred to as the first odd-numbered osmosis unit 54, the second odd-numbered osmosis unit 55, and the third odd-numbered osmosis unit 56.

The concentrated water discharged from the third radix reverse osmosis tank 56 is supplied to the concentrated water supply pipe 56 through the concentrated water supply pipe 58 connected to the first radix reverse osmosis tank 54 and the third radix reverse osmosis tank 56, Is introduced into the first radix reverse osmosis (54) along the inlet pipe (58) and separated and discharged again into the concentrated water and the fresh water. When it is not necessary to discharge low concentration concentrated water for the saline power generation or the farm water to be described later, the low concentration concentrated water produced in the pseudo-reverse osmosis part (5) is re-introduced into the pseudo-reverse osmosis part (5) So that the fresh water recovery rate in the nose reverse osmosis part 5 is substantially close to 100%. In this case, although the salinity of the concentrated water produced by repeating the radial reverse osmosis (5) several times is slightly increased, it is much lower than that of the concentrated water discharged from the reverse osmosis part of the sea water (4) Since only a small amount of concentrated water with a high concentration is left close to the water, the concentrated water that is close to the concentrated water of high concentration, which is produced repeatedly many times, can be discharged intermittently for a short period of time. Of the fresh water recovery rate is close to 100%.

On the other hand, the effluent treatment section may comprise a useful minerals recovery assembly, a saline drainage power generation assembly 8 and a farm water supply assembly 9, as shown in FIGS.

The useful minerals recovery assembly includes a useful mineral recovery tank 6 and a seawater reverse osmosis unit 4 and a useful mineral recovery tank 6 for storing concentrated water for recovering useful minerals from high concentration concentrated water discharged from the reverse osmosis And a high concentration concentrated water discharge pipe 85 for connecting the high concentration concentrated water discharge pipe 85 and the high concentration concentrated water discharge pipe 85. Since lava seawater is filtered through a wide range of basalt layers, lava seawater is filtered by all harmful impurities and foreign substances, while useful minerals are contained more than ordinary seawater. Thus, high concentration water discharged through the seawater reverse osmosis (4) This is an excellent material for recovering valuable minerals.

The saline solution power generation assembly 8 includes a high concentration concentrated water pipe 84 branching at a certain point of the high concentration concentrated water discharge pipe 85 and a low concentration concentrated water discharge pipe 84 for discharging the low concentration concentrated water discharged from the water The concentrated concentrated water chamber and the low concentration concentrated water chamber are separated into osmosis membranes in the housing so that the fresh water is concentrated from the low concentration concentrated water chamber to the high concentration concentrated water chamber 86, And a turbine 82 driven by a high concentration concentrated water discharged from the high concentration concentrated water chamber.

As described above, in the present invention, unlike salinity generation, which can be seen in the general desalination process, by taking the high salt lava seawater and the low salinity lava seawater separately, it is possible to solve the problem of pressure loss Can be solved, and the amount of electric power produced by the saline power generation is further increased, so that a remarkably efficient process operation is possible.

As shown in FIG. 5, the low-concentration concentrated water used for the saline differential power generation can branch and transfer the low-concentration concentrated water discharge pipe 86 at a predetermined point of the concentrated water re-supply pipe 58 described above.

As shown in FIG. 5, the farm water supply assembly 9 includes a water tank 91 for a farm where the low concentration concentrated water discharged from the saline solution osmotic pressure tank 81 and the high concentration concentrated water discharged from the turbine 82 are mixed and stored together A high concentration concentrated water supply pipe 96 connecting the turbine 82 and the farm water tank 91 and a high concentration concentrated water supply pipe 96 branched from a certain point and connected to a useful mineral recovery tank A third three-way valve 93 provided at a branch point between the high concentration concentrated water supply pipe 96 and the high concentration concentrated water recovery pipe 94 and the third salinity sensor 93 provided at the farm water tank 91 92).

In this case, the concentrated concentrated water discharged from the turbine 82 through the salinity differential power generation by the third salinity sensor 92 is sent to the aquarium 91 for aquaculture when the salinity in the aquarium water tank 91 exceeds the reference value The salinity of the water to be sent to the farm can be automatically adjusted by sending it back to the useful mineral recovery tank 6 through the third valve 93.

In aquaculture farms, such as crabs, caterpillars, etc., salinity and temperature are needed for the cultivars. In the case of the crabs, the optimum temperature is 21 to 24 degrees Celsius. If the water temperature is less than 10 degrees Celsius or more than 27 degrees Celsius,

However, since lava seawater exists below the underground freshwater layer, the water temperature can be kept constant irrespective of the season, and thus it can be utilized as an optimal water for maintaining the water temperature in the pond. In other words, lava seawater can maintain the same salinity as seawater while maintaining a constant temperature.

For comparison, the concentrations and temperatures of general seawater, lava seawater and concentrated water are shown in the table below.

Salinity Concentration (‰) Temperature (℃) Jeju General Seawater 34 to 35 16-18 High concentration lava seawater 32 to 33 15 ~ 18 Low concentration lava seawater 0.8 to 7 15 ~ 18 High concentration lava sea water concentration water 80 16-20 Concentration of low concentration lava sea water 20 or less 16-20

Hereinafter, a lava seawater desalination method according to the present invention will be described. The main features of the lava seawater desalination method will be briefly explained because it is almost overlapped with the lava seawater desalination system described above.

The lava water desalination method according to the present invention is characterized in that the lava water desalination method according to the present invention includes a water intake step for taking lava water as shown in the block diagram of FIG. 6, a high salt lava water having a salinity of at least a standard value, The seawater is transferred to the reverse osmosis part of the seawater, and the low-salinity lava seawater having a salinity less than the reference value is transferred to the reverse osmosis part of the seawater; and seawater is separated and discharged into fresh water and concentrated water by the reverse osmosis part The fresh water discharged from the reverse osmosis unit is transferred to the reverse osmosis unit and then separated into fresh water and concentrated water. The fresh water discharged from the reverse osmosis unit is transferred to the fresh water storage tank, and the concentrated water discharged from the reverse osmosis And a post-treatment step of transferring the water to the drain water treatment unit.

At this time, lava seawater is taken from the low-salinity lava seawater below the freshwater layer and high-salinity lava seawater below the low salinity lava seawater separately from the salinity step, and the salinity of the high salinity lava If the salinity of lavasic lava or low salinity lava seawater is lower than the standard value by transferring the lava seawater transfer pipe and the low salinity lava seawater transfer pipeline where low salinity lava seawater is transported, And is transferred to the reverse osmosis part.

Preferably, the low concentration concentrated water finally discharged from the radewater desalination part is introduced into the reverse osmosis part again and separated into fresh water and concentrated water.

In addition, a part of the low concentration concentrated water finally discharged from the sea water reverse osmosis part and a part of the concentrated concentrated water finally discharged from the sea water reverse osmosis part can be mixed and made into water for aquaculture. In this case, preferably, a portion of the low-concentration concentrated water and the high-concentration concentrated water are mixed before being mixed into the salt-osmotic tank to further compress the concentrated concentrated water, thereby producing electric power by driving the turbine with the concentrated concentrated water. At this time, when the salinity of the aquaculture water exceeds a certain value, the salinity of the aquaculture water can be automatically controlled by transferring the concentrated concentrated water that drives the turbine to the useful mineral recovery tank.

It will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the spirit or scope of the inventions. It will be apparent to those of ordinary skill in the art.

1: Water intake device 2: Feed pump
2a: first feed pump 2b: second feed pump
3: salinity separator 4: seawater reverse osmosis
5: Radix reverse osmosis 6: Useful mineral recovery tank
7: fresh water storage tank 8: saline solution power generation assembly
9: Aquaculture water supply assembly 11: High salt removal machine
12: low salinity water extractor 31: salinity sensor
31a: first salinity sensor 31b: second salinity sensor
32: Salinity separation three-way valve 32a: First three-way valve
32b: second three-way valve 33: bi-directional branch pipe
41-1: first high-pressure pump 41-2: second high-pressure pump
41-3: Third High Pressure Pump 44: First Seawater Reverse Osmosis
45: 2nd seawater reverse osmosis 46: Third seawater reverse osmosis
48: Secondary reverse osmosis input pipe 51-1: First low pressure pump
51-2: second low pressure pump 51-3: third low pressure pump
54: First Radix Reverse Osmosis 55: Second Radix Reverse Osmosis
56: Third radix reverse osmosis 57: Low concentration concentrated water branch valve
58: Condensate water input tube 81: salt osmotic pressure tank
82: Turbine 83: Power input valve
84: High concentration concentrated water column 85: High concentration concentrated water discharge pipe
86: Low concentration concentrated water discharge pipe 91: Aquaculture tank
92: third salinity sensor 93: third three-way valve
94: High concentration concentrated water recovery pipe 95: Low concentration concentrated water supply pipe
96: High concentration concentrated water supply pipe

Claims (14)

A water intake device for taking lava seawater to the ground;
A salinity separator for separating the lava water taken in by the water intake device into high salt lava water and low salinity lava water according to salinity;
The reverse osmosis part is a seawater reverse osmosis part where the high salt lava seawater is separated and separated by high concentration concentrated water and primary fresh water and a reverse osmosis part which separates low-concentration lava seawater into low concentration concentrated water and second fresh water. The reverse osmosis part being configured to be introduced into the reverse osmosis part together with the low-salt lava water to be filtered;
A fresh water storage tank for storing fresh water discharged from the radar return unit; And
And a drain water treatment unit for treating fresh water discharged from the seawater reverse osmosis part. The method according to claim 1,
A main transfer pipe for connecting the water intake device and the reverse osmosis part is provided, and the main transfer pipe is branched into two branches at a certain point, one of the main transfer pipes branched into two branches is connected to the seawater reverse osmosis part, One is connected to the radar reverse osmosis,
The salinity separator comprises a salinity sensor installed in the main transfer pipe and a saline-separated three-way valve installed at the branch point of the main transfer pipe. When the salinity of the lava water received by the water intake apparatus is equal to or greater than a reference value, And is transferred to the radewater desalination unit if it is below the reference value. The method according to claim 1,
The water intake system is composed of a high salinity water intake system for taking high salt lava water and a low salinity water intake system for taking low salinity lava water,
The high salinity water intake system is connected to the seawater osmotic pressure by a high salinity lava water transfer pipeline, and the low salinity water intake system is connected to the radewater desalination side by a low salinity lava seawater pipeline,
The salinity separator comprises a first salinity sensor and a first three-way valve installed in the highly salted lava water transfer pipe, a second salinity sensor and a second three-way valve installed in the low salinity lava water transfer pipe, Directional branch pipe connecting the two-way valve so that if the salinity of the lava water transported along the high salt lava water transfer pipe or the low salt lava water transfer pipe is equal to or greater than the reference value, it is transferred to the sea water reverse osmosis part, And if the salinity is less than the reference value, it is transferred to the odd-numbered reverse osmosis part. The method according to claim 1,
The reverse osmosis part of the seawater and the reverse osmosis part of the seawater are connected in series to a plurality of reverse osmosis units, and the concentrated water discharged from one reverse osmosis unit is connected to the next reverse osmosis unit to be separated into fresh water and concentrated water And the fresh water discharged from a plurality of reverse osmosis tanks that constitute the reverse osmosis part of the sea water is introduced into the first reverse osmosis part of a plurality of reverse osmosis parts forming the reverse osmosis part of the sea water, And the discharged concentrated water is transferred to the drain water treatment section. 5. The method of claim 4,
Wherein the concentrated water discharged from the last reverse osmosis is supplied to the first reverse osmosis unit connected to the first reverse osmosis unit and the last reverse osmosis unit connected to the first reverse osmosis unit, And the lava seawater desalination system according to the present invention is characterized in that the lava seawater desalination system comprises: The method according to claim 1,
The drain water treatment section
A useful mineral recovery assembly comprising a useful mineral recovery tank for storing concentrated water for recovering useful minerals from high concentration concentrated water discharged from the seawater reverse osmosis part, and a high concentration concentrated water discharge pipe for connecting the seawater reverse osmosis part and the useful mineral recovery tank,
A high concentration concentrated water pipe branching at a certain point of the high concentration concentrated water discharge pipe and a low concentration concentrated water discharge pipe for discharging the low concentration concentrated water discharged from the water reverse osmosis part and the high concentration concentrated water pipe and the low concentration concentrated water discharge pipe are connected together Concentration osmotic tank in which a high concentration concentrated water chamber and a low concentration concentrated water chamber are separated into an osmotic membrane in the housing so that fresh water is moved from a low concentration concentrated water chamber to a high concentration concentrated water chamber, and a turbine driven by high concentration concentrated water discharged from a high concentration concentrated water chamber And a salinity differential generator assembly comprising the saline differential generator assembly. The method according to claim 5 or 6,
Wherein the low concentration concentrated water discharge pipe is a pipe branching at a certain point of the concentrated water input pipe and leading to a salt seawater desalination tank. The method according to claim 6,
The drain water treatment section
Concentrated water from the salt concentration osmotic tank is mixed with high concentration water from the turbine. A high concentration water supply pipe connects the turbine with the water tank for cultivation. And a third three-way valve installed at a branch point of the high concentration concentrated water supply pipe and the high concentration concentrated water recovery pipe, and a third salinity sensor provided in the farm water reservoir, ≪ / RTI > further comprising a supply assembly. A lava seawater desalination method using the lava seawater desalination system according to any one of claims 1 to 6,
A water intake step for taking lava seawater;
The salinity of the collected lava water is measured in real time and the highly salted lava water having a salinity of at least the reference value is transferred to the seawater reverse osmosis part and the low salinity lava water having a salinity less than the reference value is transferred to the reverse osmosis part ;
Seawater reverse osmosis and seawater reverse osmosis, seawater is separated into fresh water and concentrated water, and the fresh water discharged from the seawater reverse osmosis is separated into fresh water and concentrated water.
And a post-treatment step of transferring the fresh water discharged from the reverse osmosis step to the fresh water storage tank, and transferring the concentrated water discharged from the reverse osmosis step to the drain water treatment unit. 10. The method of claim 9,
Lava seawater is taken from the low-salinity lava seawater below the freshwater layer and from the low-salinity lava seawater below the low-salinity lava seawater layer,
In the salinity separation step, the high salinity lava seawater transfer line is transferred to the low salinity lava seawater transfer pipeline where the low salinity lava seawater is transferred, and the salinity of the high salinity lava seawater or the low salinity lava seawater Is transferred to the odd-numbered reverse osmosis part when the value is less than the reference value, and is transferred to the reverse osmosis part when the reference value is not less than the reference value. 10. The method of claim 9,
Wherein the low concentration concentrated water finally discharged from the pseudo-reverse osmosis part is introduced into the reverse osmosis part and separated into fresh water and concentrated water. 12. The method of claim 11,
Wherein a part of the low concentration concentrated water finally discharged from the reverse osmosis part of the sea water and a part of the concentrated concentrated water finally discharged from the sea water reverse osmosis part are mixed and made into water for aquaculture. 13. The method of claim 12,
Wherein the high concentration concentrated water is further compressed into a salinity differential osmotic tank before mixing a portion of the low concentration concentrated water and a portion of the high concentration concentrated water to drive the turbine with the concentrated high concentration water to produce electric power. 13. The method of claim 12,
Wherein when the salinity of the drinking water for aquaculture reaches a predetermined value or more, high concentration concentrated water that drives the turbine is transferred to a useful mineral recovery tank.
KR1020160064668A 2016-05-26 2016-05-26 The system and process of desalination using lava seawater for high-efficiency and low energy KR101822188B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020160064668A KR101822188B1 (en) 2016-05-26 2016-05-26 The system and process of desalination using lava seawater for high-efficiency and low energy

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020160064668A KR101822188B1 (en) 2016-05-26 2016-05-26 The system and process of desalination using lava seawater for high-efficiency and low energy

Publications (2)

Publication Number Publication Date
KR20170134806A true KR20170134806A (en) 2017-12-07
KR101822188B1 KR101822188B1 (en) 2018-03-09

Family

ID=60920406

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020160064668A KR101822188B1 (en) 2016-05-26 2016-05-26 The system and process of desalination using lava seawater for high-efficiency and low energy

Country Status (1)

Country Link
KR (1) KR101822188B1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20210037243A (en) * 2019-09-27 2021-04-06 주식회사 엘지화학 Method for concentrating high salinity water
US11502322B1 (en) 2022-05-09 2022-11-15 Rahul S Nana Reverse electrodialysis cell with heat pump
US11502323B1 (en) 2022-05-09 2022-11-15 Rahul S Nana Reverse electrodialysis cell and methods of use thereof
US11855324B1 (en) 2022-11-15 2023-12-26 Rahul S. Nana Reverse electrodialysis or pressure-retarded osmosis cell with heat pump

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5549591B2 (en) * 2009-09-08 2014-07-16 東レ株式会社 Fresh water production method and fresh water production apparatus
KR100944538B1 (en) * 2009-12-30 2010-03-03 (주) 오씨아드 Method for producing high hardness mineral water containing mineral using sea water
KR101239440B1 (en) * 2011-10-26 2013-03-06 홍익대학교부설과학기술연구소 Power generation system using salinity gradient of salt water and fresh water
JP5565536B1 (en) * 2014-03-31 2014-08-06 株式会社フクハラ Brackish water desalination treatment equipment

Also Published As

Publication number Publication date
KR101822188B1 (en) 2018-03-09

Similar Documents

Publication Publication Date Title
Burn et al. Desalination techniques—A review of the opportunities for desalination in agriculture
Quist-Jensen et al. Membrane technology for water production in agriculture: Desalination and wastewater reuse
Morillo et al. Comparative study of brine management technologies for desalination plants
Sahu A comprehensive review of saline effluent disposal and treatment: conventional practices, emerging technologies, and future potential
Cipolletta et al. Brine treatment technologies towards minimum/zero liquid discharge and resource recovery: State of the art and techno-economic assessment
Greenlee et al. Reverse osmosis desalination: water sources, technology, and today's challenges
Xu et al. Critical review of desalination concentrate management, treatment and beneficial use
Moossa et al. Desalination in the GCC countries-a review
KR101822188B1 (en) The system and process of desalination using lava seawater for high-efficiency and low energy
CN203269703U (en) System for producing fresh water and salt production raw material by desalinating seawater in novel membrane method
US20110177550A1 (en) Process for the treatment of water and production of biomass and associated systems
US8206589B2 (en) Desalination system and method for integrated treatment of brackish concentrate and seawater
Khan et al. Inland desalination: Techniques, brine management, and environmental concerns
US20130186822A1 (en) Low energy forward osmosis membrane water processing system
CA2883101A1 (en) Hybrid desalination system
CN203269704U (en) Raw material coupling system for preparing fresh water and salt by using seawater through membrane method
Tan et al. A review of desalination technologies and its impact in the Philippines
CN110697958B (en) High-efficiency salt separating membrane concentration process
NO20101192A1 (en) Water treatment installation, method and application for removal, underwater, of at least ± one undesirable component from water
Moreira et al. Enhancing industries exploitation: Integrated and hybrid membrane separation processes applied to industrial effluents beyond the treatment for disposal
Zarzo Beneficial uses and valorization of reverse osmosis brines
KR102018617B1 (en) Reverse Osmosis Seawater Desalination device
Kabir et al. Electrodialysis desalination, resource and energy recovery from water industries for a circular economy
Que et al. Design and performance of small-scale reverse osmosis desalination for brackish water powered by photovoltaic units: a review
KR101831864B1 (en) System and method of desalination of lava seawater and extraction valuable mineral from lava seawater

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant