KR20170112194A - Oil-In-Water Cosmetic Composition with Shape-Memory Ability - Google Patents

Oil-In-Water Cosmetic Composition with Shape-Memory Ability Download PDF

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KR20170112194A
KR20170112194A KR1020160038898A KR20160038898A KR20170112194A KR 20170112194 A KR20170112194 A KR 20170112194A KR 1020160038898 A KR1020160038898 A KR 1020160038898A KR 20160038898 A KR20160038898 A KR 20160038898A KR 20170112194 A KR20170112194 A KR 20170112194A
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South Korea
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suitable amount
sulfonic acid
compound
cosmetic composition
shape memory
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KR1020160038898A
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Korean (ko)
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KR101814379B1 (en
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전영현
박나래
노은영
문성호
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(주)셀트리온
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Priority to KR1020160038898A priority Critical patent/KR101814379B1/en
Priority to PCT/KR2017/000120 priority patent/WO2017119728A1/en
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/87—Polyurethanes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/062—Oil-in-water emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin

Abstract

The present invention relates to an underwater type cosmetic composition having shape memory ability, and more particularly, to a composition for underwater type cosmetic composition which comprises (a) a shape memory polymer; And (b) at least one compound selected from an amine compound and a sulfonic acid compound. The cosmetic composition of the present invention is an underwater type formulation containing a shape memory polymer, and can impart a good pickup force and a natural cohesive force effect while having excellent shape memory ability.

Description

[0001] The present invention relates to an oil-in-water cosmetic composition having shape memory capability,

The present invention relates to a cosmetic composition having shape memory ability. More particularly, the present invention relates to (a) a shape memory polymer; And (b) at least one compound selected from an amine compound and a sulfonic acid compound.

Cosmetics companies have made great efforts to prevent and improve symptoms that interfere with people's pursuit of extrovert beauty, such as dryness, loss of elasticity, wrinkles, spots and freckles. Among the symptoms that interfere with the appearance beauty of the above people, wrinkle formation is typical. The first cause is genetic factors that are influenced by genes inherited from parents. The second cause is the movement of the muscles according to the facial expression. This occurs naturally when humans laugh or frown, and can result in wrinkles being created by constantly applying certain forces over time. The third cause is increased collagen and elastin, which account for the majority of skin dermis, and an increase in matrix metalloproteinase (MMP) that breaks down.

The main reason for the increase in the amount of MMP, which is the main cause of wrinkle formation and skin elasticity reduction, is UV. Ironically, in the global atmosphere, consumers are always exposed to UV radiation. Therefore, consumers' demand for functional cosmetics to improve wrinkles and skin elasticity is increasing, and a large market is formed around the world. However, using existing functional cosmetics, wrinkles and skin elasticity to improve the effect of at least 3 months to use the product is visible only when the effect appears. But consumers are looking for products that can be more effective in the short term. Therefore, there is a growing preference for formulations in which consumers are immediately visually aware of the effect of improving wrinkles and feeling of firmness.

Shape restoration formulations employing shape-memory polymers have been developed as diverse categories of products as formulations that exhibit immediate skin wrinkle improvement and a sense of resilience. When the shape restoring formulation is applied through its unique shape memory ability, the skin defect can be corrected to give immediate skin wrinkle improving effect and elasticity feeling. However, in the case of a cosmetic composition employing a polymer having a shape memory ability, there is a disadvantage in that it is not easy to pick up and it is necessary to use a tool. In addition, there is a limitation in the formulations that disturb aesthetics in consumers due to cracking and tearing .

Therefore, there is a need for formulations that have shape memory ability, which is an advantage of shape restoring formulations, and which have superior pickup performance and give consumers aesthetic through natural gathering power.

Accordingly, the present inventors have found that a cosmetic composition containing a shape memory polymer and containing at least one of an amine compound and a sulfonic acid compound at the same time can produce a cosmetic composition having a shape-restoring force similar to that of a general shape-restoring formulation, The present invention has been completed.

SUMMARY OF THE INVENTION Accordingly, it is an object of the present invention to solve the problems described above. And (b) at least one compound selected from an amine compound and a sulfonic acid compound.

In order to solve the above-mentioned problems, the present invention relates to (a) a shape memory polymer; And (b) at least one compound selected from an amine compound and a sulfonic acid compound.

In addition, the present invention provides a method for improving skin wrinkles or a method for improving skin elasticity immediately by correcting skin imperfections including applying the underwater type cosmetic composition to skin.

Hereinafter, the present invention will be described more specifically.

In one embodiment of the present invention, the shape memory polymer is selected from the group consisting of POLYURETHANE-59, PEG-150 / stearyl alcohol / SMDICOPOLYMER and PEG- / HDD copolymer / bis-decyltetradeceth-20 ether (PEG-240 / HDICOPOLYMER / BIS-DECYLTETRADECETH-20ETHER), and the like.

The term " shape memory ability " used in the present invention is generally defined as a state in which the original stress is removed by thermal, electrical, or environmental changes and then fixed in a temporary or resting state under a certain temperature and external physical force The ability to relax in a state. Specifically, the shape memory ability of the present invention means the ability to restore the original state after a time elapses after the shape is changed to an external stimulus as shown in FIG. 1 (b).

The term " easy to apply " as used in the present invention means the degree to which a consumer feels that the cosmetic composition is thinly spread on the surface of the desired skin area.

The term " easy to take on hand " or " pick-up force " as used in the present invention means the degree to which a cosmetic composition feels easy for a consumer to pick up by a finger, spatula, And preferably a finger is used without a tool such as a spatula.

As used herein, the term " aesthetics of association form " or " natural association force " refers to the extent to which a consumer feels that a cosmetic composition is beautiful when the cosmetic composition is deformed by contact with a finger, a spatula, do.

In an embodiment of the present invention, the amine compound is selected from the group consisting of TRIETHANOLAMINE, TROMETHAMINE, ETHANOLAMINE, STEARAMIDOPROPYL DIMETHYLAMINE, Tetrahydroxypropyl Ethylenediamine ( TETRAHYDROXYPROPYL ETHYLENEDIAMINE, ACETYL GLUCOSAMINE, STEARAMIDOPROPYL DIMETHYLAMINE, and the like, but are not limited thereto.

In one embodiment of the present invention, the sulfonic acid compound is selected from the group consisting of sodium C8-16 isoalkylsuccinyl lactoglobulin sulfonate (SODIUM C8-16 ISOALKYLSUCCINYL LACTOGLOBULIN SULFONATE), sodium xylene sulfonylate (SODIUM XYLENESULFONATE), phenylbenzimidazole sulfone But are not limited to, PHENYLBENZIMIDAZOLE SULFONICACID, DISODIUM PHENYLDIBENZIMIDAZOLE TETRASULFONATE, DISODIUM LAURETH SULFOSUCCINATE, DISODIUM LAURYL SULFOSUCCINATE, But are not limited to, TEA-DODECYL BENZENESULFONATE, SODIUM C14-16OLEFIN SULFONATE, SODIUM HEXANESULFONATE, SODIUM BENZOTRIAZOLYL SODIUM HEXANESULFONATE, BUTYLPHENOL SULFONATE) and polydodecanamediamidium triazadiphenylethenesulfonate (POLYDODANAMIDEAMINIUM TRIAZADIPHENYL ETHENESULFONATE), and the like, but is not limited thereto.

In one embodiment of the present invention, the hardness value of the cosmetic composition may be from 7.0 g to 10.0 g.

The term " hardness " used in the present invention is a numerical representation of the result of testing a material (object) in a defined (rigid) manner and a hardness value. The hardness value (Unit: g)), the higher the physical properties of the material.

In one embodiment of the present invention, at least one of the amine compound and sulfonic acid compound (b) may be a mixture of an amine compound and a sulfonic acid compound.

In one embodiment of the present invention, when at least one of the amine compound and the sulfonic acid compound (b) is a mixture, the mixing ratio of the amine compound: sulfonic acid compound may be 3: 1 to 1: 3.

In one embodiment of the present invention, the cosmetic composition comprises at least one of (a) a shape memory polymer and (b) an amine compound and a sulfonic acid compound in a composition ratio of 1: 0.2 to 1: 200.0, To 1: 30.0, more preferably from 1: 1 to 1: 6.7.

In one embodiment of the present invention, the cosmetic composition comprises (a) 0.1% to 5.0% by weight, preferably 0.5% to 4.0% by weight, more preferably 1.5% 3.0% by weight. When the content is less than 0.1% by weight, the viscosity of the composition is low and the viscosity of the composition is insufficient. On the other hand, when the content is more than 5.0% by weight, the viscosity increases excessively.

In one embodiment of the present invention, the cosmetic composition comprises (b) at least one compound selected from the group consisting of an amine compound and a sulfonic acid compound in an amount of 1.0 wt% to 20.0 wt%, preferably 2.0 wt% to 15.0 wt% More preferably 3.0% by weight to 10.0% by weight. If the content is less than 1.0% by weight, the amine compound or the sulfonic acid compound is insufficient in the content, and if the content is more than 20.0% by weight, the pH is higher or lower than that of a common cosmetic composition, .

In one embodiment of the present invention, the cosmetic composition may be for skin defect correction.

The term " skin defect correction " as used in the present invention means to cover the irregularities, dullness, pores or wrinkles recognized as skin imperfections by the consumer. The irregularities, dullness, pores, or wrinkles of the skin, which is a defect of the skin, are responsible for the bending of the surface of the skin, thereby hindering the appearance of the skin.

In one embodiment of the present invention, the cosmetic composition may further comprise an aqueous phase component and an oil phase component.

Wherein the aqueous phase component contains purified water as a solvent and is selected from the group consisting of propylene glycol, But is not limited thereto.

The oily component may contain, as an oil component, a cyclic silicone oil such as cyclopentasiloxane, cyclohexasiloxane, decamethylcyclopentasiloxane, octamethylcyclopentasiloxane and the like, volatile oils of hydrocarbon of 8-20 carbon atoms and vegetable squalane, Dicaprate, caprylic / capric triglyceride, trihexylhexanone, diisostearyl malate, polyglyceryl-2-triisostearate, dicaprylyl carbonate, Ester oils such as isononyl isonanoate, silicone oils such as phenyltrimethicone, methyltrimethicone, dimethicone, caprylylmethicone, diphenylsiloxyphenyltrimethicone, and ozokerite, ceresin, Carnauba wax, candelilla wax, paraffin wax, behenyl alcohol, lecithin, polyhydroxy stearic acid, isopropyl Such as stearyl stearate, stearate, isostearic acid, stearoyl inulin, dextrin palmitate, glyceryl behenate / eicosadioate, distearammonium hectorite, stearalkonium hectorite, bentonite, silica dimethysilylate And a dispersing agent such as an acrylate / ethylhexyl acrylate / dimethicone methacrylate copolymer, a fatty alcohol, a fatty acid or a higher alcohol may be used, but the present invention is not limited thereto.

In addition, the cosmetic composition of the present invention may contain components commonly used in cosmetic compositions, and examples thereof include surfactants, pH adjusters, pigments, flavors, pigments, preservatives, bactericides, thickeners, antioxidants, stabilizers, The present invention relates to various additives and moisturizing agents such as agents, metal ion sequestering agents, refreshing agents, deodorants, emulsifiers and solubilizing agents, ultraviolet absorbers, ultraviolet scattering agents, vitamins, plant extracts, skin astringents, antiinflammatory agents, cell activators, , An adjuvant such as a skin function-enhancing agent, and a carrier, and the formulations and the additive components are not limited to the above contents. The components can also be introduced in amounts commonly used in the field of dermatology.

The formulations of the cosmetic composition of the present invention are not particularly limited, and may include components of cosmetic compositions commonly used in the art to which the invention belongs according to the formulation to be produced. The cosmetic composition of the present invention can be formulated into, for example, a liquid product, a lotion, an essence, a cream, a sun lotion, a sun cream, a makeup base, a foundation, a baboon cream, a stick- But is not limited thereto. In addition, oil, water, a surfactant, a moisturizer, a lower alcohol, a thickener, a chelating agent, an antiseptic, a fragrance and the like may be selected and added in accordance with the formulation to be prepared. Further, it may contain an ultraviolet screening agent, a light scattering agent, etc., and the formulations and the additive components are not limited to the above contents. The components can also be introduced in amounts commonly used in the field of dermatology.

The cosmetic composition of the present invention may be directly applied to the skin or sprayed depending on its form. The amount of the composition to be used and the number of times of use per day may be appropriately set according to the age, sex, use, severity of symptoms, etc. of the user. For example, an appropriate amount of the composition may be changed from once / day to 5 or 6 times / It can be applied to skin frequently.

The cosmetic composition of the present invention is an underwater type formulation containing a shape memory polymer and can impart good pickup force and natural cohesive force effect while having excellent shape memory ability.

Fig. 1 shows the shapes of Formulation Example 1 and Comparative Formulation Example 1. Fig.

Hereinafter, the present invention will be described in more detail with reference to Examples. It is to be understood, however, that the scope of the present invention is not limited by these examples.

Example  1 to 9 and Comparative Example  Preparation of 1 to 10

Each of the water-in-oil type cosmetic compositions of Examples 1 to 9 and Comparative Examples 1 to 10 was prepared in the form of the compositions shown in Tables 1 and 2 (unit: wt%). Examples 1 to 9 and Comparative Example 1 of the present invention used ADEKANOL GT-700 (ADEKA Co., Japan) as the shape memory polymer and the Pigment-240 / HI Dia Copolymer bis-decyltetradeceth-20 ether.

No. Raw material name Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Example 9 One Awards Purified water To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 2 Disodium iodide 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 3 1,3-butylene glycol 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 4 Gt; < tb > < tb > < tb > < tb > 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 5 Triethanolamine 8.0 - - - - - 3.0 - - 6 Tromethamine - 6.0
- - - - - - 1.5 7 Acetylglucosamine - - 5.0 - - - 3.0 - - 8 Sodium xylene sulfonate - - - 5.0 - - - 3.0 - 9 Sodium hexanesulfonate - - - - 8.0 - - 3.0 - 10 Phenylbenzimidazole sulfonic acid 5.0 3.0 11 Paid Pfizy-26-Butes-26 / Pigi-40 Hydrogenated castor oil 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 12 Spices Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount 13 antiseptic Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount

No. Raw material name Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Comparative Example 6 Comparative Example 7 Comparative Example 8 Comparative Example 9 Comparative Example 10 One Awards Purified water To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 2 Disodium iodide 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 3 1,3-butylene glycol 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 4 Gt; < tb > < tb > < tb > < tb > 2.0 - - - - - - - - - 5 Triethanolamine - 8.0 - - - - - 3.0 - - 6 Tromethamine - - 6.0
- - - - - - 1.5 7 Acetylglucosamine - - - 5.0 - - - 3.0 - - 8 Sodium xylene sulfonate - - - - 5.0 - - - 3.0 - 9 Sodium hexanesulfonate - - - - - 8.0 - - 3.0 - 10 Phenylbenzimidazole sulfonic acid - - - - - - 5.0 - - 3.0 11 Paid Pfizy-26-Butes-26 / Pigi-40 Hydrogenated castor oil 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 12 Spices Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount 13 antiseptic Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount

Examples 1 to 3 in Table 1 show that the amine compounds include 8.0 wt% of triethanolamine, 6.0 wt% of tromethamine and 5.0 wt% of acetylglucosamine, Examples 4 to 6 include sodium xylene 5.0% by weight of sulfonate, 8.0% by weight of sodium hexanesulfonate and 5.0% by weight of phenylbenzimidazole sulfonic acid. Example 7 contained 3.0% by weight of a mixture of triethanolamine and acetylglucosamine, which are two amine-based compounds, and Example 8 is a mixture containing 3.0% by weight of sodium sulfonate and sodium hexane sulfonate, And mixtures thereof. Example 9 contains a mixture of 1.5% by weight of tromethamine as an amine compound and 3.0% by weight of phenylbenzimidazole sulfonic acid as a sulfonic acid compound.

In the above Examples 1 to 9, the content of the shape memory polymer, PIGE-240 / HIDA copolymer, bis-decyltetradeceth-20 ether was 2.0% by weight. The components other than the shape memory polymer and the added amine compound, the mixture of the amine compound, the mixture of the sulfonic acid compound and the mixture of the amine compound and the sulfonic acid compound are the same.

In Table 2, Comparative Example 1 does not add the amine compound and sulfonic acid compound in Example 1, and Comparative Examples 2 to 10 do not add the shape memory polymer in Examples 1 to 9.

Test Example  One: Example  1 to 9 and Comparative Example  1 to 10 sensory evaluation

The sensory evaluation of the shape memory ability, ease of application, ease of picking (pick-up force) and aesthetics of the association shape (natural cohesive force) of Examples 1 to 9 and Comparative Examples 1 to 10 were carried out.

For the sensory evaluation, the results of Examples 1 to 9 and Comparative Examples 1 to 10 were compared with those of 20 women in their 20s and 30s, and a score of 0 to 5 for each item was obtained. Respectively. The average scores for each item are shown in Tables 3 and 4 below.

<Evaluation Criteria for Sensory Evaluation>

0: no effect at all, 1: very bad, 2: bad, 3: normal, 4: good, 5: very good

Test Items Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Example 9 Shape memory ability 4.8 4.5 4.7 4.8 4.5 4.8 4.7 4.5 4.7 Easy to apply 4.3 4.7 4.4 4.5 4.7 4.5 4.3 4.3 4.8 Easy to take (Pickup power) 4.7 4.6 4.7 4.6 4.5 4.6 4.7 4.5 4.6 Aesthetics of association shape (natural cooperative force) 4.5 4.8 4.7 4.6 4.7 4.7 4.5 4.5 4.8

Test Items Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Comparative Example 6 Comparative Example 7 Comparative Example 8 Comparative Example 9 Comparative Example 10 Shape memory ability 4.5 0.8 0.7 0.6 0.7 0.5 0.6 0.7 0.8 0.8 Easy to apply 2.7 4.5 4.7 4.5 4.7 4.6 4.5 4.2 4.4 4.6 Easy to take (Pickup power) 1.8 4.7 4.2 4.5 4.5 4.7 4.8 4.7 4.4 4.5 Aesthetics of association shape (natural cooperative force) 1.9 1.2 1.5 1.4 1.5 1.2 1.3 1.2 1.4 1.6

As shown in Tables 3 and 4, it was confirmed that Examples 1 to 9 prepared according to the present invention show the same or better shape memory ability than the compositions of Comparative Examples 1 to 10. In Examples 1 to 9, it was confirmed that excellent ease of application, pick-up force and natural cohesive force were exhibited as compared with Comparative Example 1. In Comparative Examples 2 to 10 in which the shape memory polymer was not included, Respectively.

Test Example  2: Example  1 to 9 and Comparative example  Hardness measurement

Hardness was evaluated in order to confirm the pickup force and the natural cohesive force of Examples 1 to 9 and Comparative Example 1 showing the shape memory ability in Test Example 1 above.

The hardness was measured using a Sun Rheometer Meter Compac-100 (Sun Scientific, Japan). The diameter of the adapter was 10 mm, the penetration distance was 15 m, and the maximum stress was 2 kg. The cosmetic compositions of Examples 1 to 9 and Comparative Example 1 were measured in a cylindrical container with a diameter of 45 mm and a height of 35 mm. The results are shown in Table 5 below (load weight (unit: g)).

Comparative Example 1 Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Example 9 Hardness (g) 31.0 8.0 10.0 9.0 7.0 8.0 10.0 7.0 9.0 9.0

As shown in Table 5, the compositions of Examples 1 to 9 showed a hardness value of 7.0 g to 10.0 g, while the cosmetic composition of Comparative Example 1 had a high hardness value of 31.0 g. Comparative Example 1 having a high hardness value was very hard and hard to take by hand. Examples 1 to 9, which had a lower hardness value than Comparative Example 1, were not hard and easy to take (excellent pick-up force) It was confirmed that the shape of the remaining cosmetic material in the container was naturally associated. From these results, it was confirmed that Examples 1 to 9 have a pickup force and a natural gathering force as compared with Comparative Example 1. [

Formulation Example  1 and Comparative Formulation Example  1

Formulation Example 1 and Comparative Formulation Example 1, which are makeup formulations, were prepared in the composition of Example 4 and Comparative Example 1, respectively, in the composition shown in Table 6 below (unit: wt%).

No. division Raw material name Formulation Example 1 Comparative Formulation Example 1 One Awards Purified water To 100 To 100 2 1,3-butylene glycol 10.0 10.0 3 glycerin 5.0 5.0 4 Disodium iodide 0.2 0.2 5 Gt; &lt; tb &gt; &lt; tb &gt; &lt; tb &gt; &lt; tb &gt; 2.0 2.0 6 Sodium xylene sulfonate 5.0 - 7 coloring agent Titanium dioxide 8.0 8.0 8 Yellow iron oxide, red iron oxide, black iron oxide 2.0 2.0 9 Paid Dimethicone 4.0 4.0 10 Cyclopentasiloxane 7.0 7.0 11 Emulsifier 2.0 2.0 12 antiseptic Suitable amount Suitable amount 13 Spices Suitable amount Suitable amount

Test Example  3: Formulation Example  1 and Comparative Formulation Example  Comparison of Visual Forms of Makeup Formulations of 1

Using Formulation Example 1 and Comparative Formulation Example 1, the shape memory ability was visually confirmed as follows.

For visual comparison, Formulation Example 1 and Comparative Formulation Example 1 were subjected to a physical impact using a spatula, which is generally used for a cosmetic pick-up, and after 5 minutes, One state is shown in Fig.

As shown in Fig. 1, Comparative Formulation Example 1 (Fig. 1 (a)) shows a very hard and dripping tearing and cracking phenomenon and is difficult to take by hand (pick-up force is poor) (B) of Fig. 3) showed a shape that naturally associates with each other, and confirmed that it is easy to take in the hand (excellent pickup performance). As a result, it was confirmed that Formulation Example 1 has excellent picking power to consumers and can provide cosmetic formulations with aesthetic appeal.

Test Example  4: According to the present invention Cosmetics  Shape memory of composition Polymer  Content range determination test

In order to confirm the effects of the content of the shape memory polymer, the following test was conducted (unit: wt%). The shape memory polymer used was a phage-240 / HIDA copolymer bis-decyltetradeceth-20 ether, the amine compound used was the triethanolamine used in Example 1, and the sulfonic acid compound used was the sodium phthalate Lt; / RTI &gt; was used.

No. Raw material name Example 1 Example 4 Example 10 Example 11 Example 12 Example 13 Example 14 Example 15 Example 16 Example 17 One Awards Purified water To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 2 Disodium iodide 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 3 1,3-butylene glycol 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 4 Gt; &lt; tb &gt; &lt; tb &gt; &lt; tb &gt; &lt; tb &gt; 2.0 2.0 0.5 1.5 3.0 4.0 0.5 1.5 3.0 4.0 5 Triethanolamine 8.0 - 8.0 8.0 8.0 8.0 - - - - 6 Sodium xylene sulfonate - 5.0 - - - - 5.0 5.0 5.0 5.0 7 Paid Pfizy-26-Butes-26 / Pigi-40 Hydrogenated castor oil 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 8 Spices Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount 9 antiseptic Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount

In Table 7, Examples 10 to 13 contain triethanolamine as an amine compound in an amount of 8.0% by weight, Example 10 contains 0.5% by weight of a phage-240 / HCI copolymer bis-decyltetradeceth- , Example 11 is 1.5 wt%, Example 12 is 3.0 wt%, and Example 13 is 4.0 wt%. Examples 14 to 17 contained 5.0% by weight of sodium sulfonate, sodium zeilene sulfonate, Example 14 contained 0.5% by weight of a bis-decyltetradeceth-20 ether having a fat-240 / , Example 15 is 1.5 wt%, Example 16 is 3.0 wt%, and Example 17 is 4.0 wt%.

<Evaluation Criteria for Sensory Evaluation>

0: no effect at all, 1: very bad, 2: bad, 3: normal, 4: good, 5: very good

Test Items Example 1 Example 4 Example 10 Example 11 Example 12 Example 13 Example 14 Example 15 Example 16 Example 17 Shape memory ability 4.8 4.8 2.8 4.5 4.9 4.9 2.4 4.6 4.9 5.0 Easy to apply 4.3 4.5 4.8 4.7 4.0 1.3 4.9 4.5 3.9 1.5 Easy to take (Pickup power) 4.7 4.6 4.7 4.4 4.1 1.8 4.8 4.6 4.0 1.4 Aesthetics of association shape (natural cooperative force) 4.5 4.6 4.1 4.5 4.1 3.5 3.9 4.7 4.0 2.8

Table 8 shows the sensory evaluation of the shape memory ability, easiness of application, ease of picking (pick-up force) and the esthetics (natural articulation force) effect of the association shape of Examples 1 and 4 and Examples 10 to 17, The average score for the item is the result. The sensory evaluation was conducted to compare the effects of the products on 20 consumers in their 20s and 30s, and each item was given a 6 - point scale of 0 ~ 5 points.

As shown in the results of Table 8, the contents of 0.5% by weight and 4.0% by weight of the fat-240 / HCI copolymer bis-decyltetradeceth-20 ether were excellent in shape memory ability, easy to apply, ) And the aesthetics of the association shape (natural cohesive force). Particularly, when the content of the PGE-240 / HCI copolymer bis-decyltetradeceth-20 ether is 1.5 wt% and 3.0 wt%, it is easy to apply and easy to take while maintaining the conventional shape memory ability ) And the aesthetics of the shape of the association (natural cohesive force).

Test Example  5: According to the present invention Cosmetics  Of the composition Amine system  Determination of content range of compound or sulfonic acid compound

In order to confirm the effect of the content of the amine compound or the sulfonic acid compound, the following test was conducted (unit: wt%). As the amine compound and the sulfonic acid compound, triethanolamine and sodium xylene sulfonate used in Test Example 4 were used.

No. Raw material name Example 1 Example 4 Example 18 Example 19 Example 20 Example 21 Example 22 Example 23 Example 24 Example 25 One Awards Purified water To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 2 Disodium iodide 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 3 1,3-butylene glycol 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 4 Gt; &lt; tb &gt; &lt; tb &gt; &lt; tb &gt; &lt; tb &gt; 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 5 Triethanolamine 8.0 - 2.0 3.0 10.0 15.0 - - - - 6 Sodium xylene sulfonate - 5.0 - - - - 2.0 3.0 10.0 15.0 7 Paid Pfizy-26-Butes-26 / Pigi-40 Hydrogenated castor oil 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 8 Spices Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount 9 antiseptic Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount

In Table 9, Examples 18 to 21 contain triethanolamine as the amine compound, Example 18 contains triethanolamine in an amount of 2.0 wt%, Example 19 in 3.0 wt%, Example 20 in 10.0 wt% Example 21 is 15.0 wt%. Examples 22 to 25 include sodium xylene sulfonate as a sulfonic acid compound, Example 22 had a sodium xylene sulfonate content of 2.0 wt%, Example 23 had 3.0 wt%, Example 24 contained 10.0 wt% , And Example 25 is 15.0% by weight.

<Evaluation Criteria for Sensory Evaluation>

0: no effect at all, 1: very bad, 2: bad, 3: normal, 4: good, 5: very good

Test Items Example 1 Example 4 Example 18 Example 19 Example 20 Example 21 Example 22 Example 23 Example 24 Example 25 Shape memory ability 4.8 4.8 4.7 4.5 3.7 3.2 4.8 4.8 3.8 3.2 Easy to apply 4.3 4.5 3.3 3.7 4.5 4.8 3.2 3.4 4.5 4.7 Easy to take (Pickup power) 4.7 4.6 3.5 3.7 4.0 4.5 3.8 3.9 4.5 4.8 Aesthetics of association shape (natural cooperative force) 4.5 4.6 3.3 3.4 3.5 3.2 3.4 3.8 3.7 3.5

Table 10 shows the sensory evaluation of the shape memory ability, easiness of application, ease of picking (pick-up force) and the esthetics (natural articulation force) effect of association forms in Examples 1 and 4 and Examples 18 to 25, The average score for the item is the result. The sensory evaluation was conducted to compare the effects of the products on 20 consumers in their 20s and 30s, and each item was given a 6 - point scale of 0 ~ 5 points.

As shown in Table 10, the content of each of the amine compound and the sulfonic compound was from 2.0 wt% to 15.0 wt% in terms of shape memory ability, ease of application, easiness of picking up (picking force) And a synergistic effect (synergistic effect). In particular, with respect to each of the amine compound and the sulfonic compound, the content of 3.0 wt% to 10.0 wt% is preferable because it is easy to apply while maintaining the existing shape memory ability, easy picking force (picking force) ).

Test Example  6: According to the present invention Cosmetics  Of the composition Amine system  Test for determining the content range of the compound and the sulfonic acid-based compound mixture

In the case of using a mixture of an amine compound and a sulfonic acid compound, the content of the mixture of tromethamine and phenylbenzimidazole sulfonic acid was tested in the following manner to determine the content range of the mixture (unit: wt%). The shape memory polymer used was a polyethylene-bis-decyltetradeceth-20 ether content range of 2.0% by weight.

No. Raw material name Example 26 Example 27 Example 28 Example 29 One Awards Purified water To 100 To 100 To 100 To 100 2 Disodium iodide 0.02 0.02 0.02 0.02 3 Butylene glycol 5.0 5.0 5.0 5.0 4 Gt; &lt; tb &gt; &lt; tb &gt; &lt; tb &gt; &lt; tb &gt; 2.0 2.0 2.0 2.0 5 Tromethamine 1.5 3.0 5.0 10 6 Phenylbenzimidazole sulfonic acid 1.5 3.0 5.0 10 7 Paid Pfizy-26-Butes-26 / Pigi-40 Hydrogenated castor oil 0.2 0.2 0.2 0.2 8 Spices Suitable amount Suitable amount Suitable amount Suitable amount 9 antiseptic Suitable amount Suitable amount Suitable amount Suitable amount

In Table 11, in Example 26, the content of tromethamine, which is an amine compound, and the content of phenylbenzimidazole sulfonic acid, which is a sulfonic acid compound, were 3.0% by weight in Example 27, 5.0% by weight in Example 28, %, And Example 29 is 10.0% by weight.

<Evaluation Criteria for Sensory Evaluation>

0: no effect at all, 1: very bad, 2: bad, 3: normal, 4: good, 5: very good

Test Items Example 26 Example 27 Example 28 Example 29 Shape memory ability 4.5 4.7 4.0 3.4 Easy to apply 3.5 4.5 4.6 4.8 Easy to take (Pickup power) 3.7 4.4 4.7 4.8 Aesthetics of association shape (natural cooperative force) 3.2 4.6 3.5 3.2

Table 12 shows the average scores of the items after performing the sensory evaluation on the shape memory ability, easiness of application, easiness of picking up (pick-up force), and the aesthetics of the association shape (natural cohesive force) of Examples 26 to 29 . The sensory evaluation was conducted to compare the effects of the products on 20 consumers in their 20s and 30s, and each item was given a 6 - point scale of 0 ~ 5 points.

As shown in Table 12, in the case where the content (% by weight) of the mixture of the amine compound and the sulfonate compound is 3.0 wt% to 10.0 wt%, the shape memory ability, easiness of application, Pick-up force) and aesthetics (natural gathering force) of the association shape. However, when the content of the mixture of the amine compound and the sulfonate compound is 20% by weight. The shape memory ability and the aesthetics of the association shape (natural cohesive force) decreased.

Test Example  7: According to the present invention Cosmetics  Of the composition Amine system  Mixing ratio test of compound and sulfonic acid compound mixture

In the case of using a mixture of an amine compound and a sulfonic acid compound, in order to confirm the mixing ratio of the amine compound and the sulfonic acid compound in the mixture, the content of tromethamine and tromethamine in the content of Example 27, which was effective in Test Example 6, Phenyl benzimidazole sulfonic acid was tested as follows (unit: wt%).

No. Raw material name Example 27 Example 30 Example 31 Example 32 Example 33 One Awards Purified water To 100 To 100 To 100 To 100 To 100 2 Disodium iodide 0.02 0.02 0.02 0.02 0.02 3 Butylene glycol 5.0 5.0 5.0 5.0 5.0 4 Gt; &lt; tb &gt; &lt; tb &gt; &lt; tb &gt; &lt; tb &gt; 2.0 2.0 2.0 2.0 2.0 5 Tromethamine 3.0 4.0 4.5 2.0 1.5 6 Phenylbenzimidazole sulfonic acid 3.0 2.0 1.5 4.0 4.5 7 Paid Pfizy-26-Butes-26 / Pigi-40 Hydrogenated castor oil 0.2 0.2 0.2 0.2 0.2 8 Spices Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount 9 antiseptic Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount

In Table 13, Example 27 shows that the mixing ratio of tromethamine, which is an amine compound, and phenylbenzimidazole sulfonic acid, which is a sulfonic acid compound, is 1: 1, Example 30 is 2: 1, Example 31 is 3: 1, Example 32 is 1: 2, and Example 33 is 1: 3.

<Evaluation Criteria for Sensory Evaluation>

0: no effect at all, 1: very bad, 2: bad, 3: normal, 4: good, 5: very good

Test Items Example 27 Example 30 Example 31 Example 32 Example 33 Shape memory ability 4.6 4.3 4.1 4.8 4.6 Easy to apply 4.4 4.6 4.4 4.7 4.4 Easy to take (Pickup power) 4.5 4.5 4.5 4.5 4.5 Aesthetics of association shape (natural cooperative force) 4.4 4.2 3.8 4.8 4.3

Table 14 shows the sensory evaluation of the shape memory ability, ease of application, ease of picking (pick-up force) and the aesthetics of the association shape (natural association force) effects of Examples 27 and 30 to 32, Average result. The sensory evaluation was conducted to compare the effects of the products on 20 consumers in their 20s and 30s, and each item was given a 6 - point scale of 0 ~ 5 points.

As shown in Table 14, it was confirmed that the mixing ratio of the amine compound and the sulfonic compound was 3: 1 to 1: 3, and the shape memory ability, the ease of application, the ease of picking up And it is confirmed that there is an effect of imparting aesthetic (natural gathering force) of association shape.

Claims (10)

(a) a shape memory polymer; And
(b) at least one compound selected from an amine compound and a sulfonic acid compound
&Lt; / RTI &gt;
The method according to claim 1,
The shape memory polymer is selected from the group consisting of POLYURETHANE-59, PEG-150 / STEARYL ALCOHOL / SMDICOPOLYMER and PEG-240 / Decyl tetradeceth-20 ether (PEG-240 / HDICOPOLYMER / BIS-DECYLTETRADECETH-20ETHER).
The method according to claim 1,
The amine compound may be selected from the group consisting of TRIETHANOLAMINE, TROMETHAMINE, ETHANOLAMINE, STEARAMIDOPROPYL DIMETHYLAMINE, TETRAHYDROXYPROPYL ETHYLENEDIAMINE, acetylglucosamine ACETYL GLUCOSAMINE, and STEARAMIDOPROPYL DIMETHYLAMINE. &Lt; RTI ID = 0.0 &gt; 11. &lt; / RTI &gt;
The method according to claim 1,
The sulfonic acid compound is preferably selected from the group consisting of sodium C8-16 isoalkylsuccinyl lactoglobulin sulfonate (SODIUM C8-16 ISOALKYLSUCCINYL LACTOGLOBULIN SULFONATE), SODIUM XYLENESULFONATE, PHENYLBENZIMIDAZOLE SULFONICACID, DISODIUM LAURETH SULFOSUCCINATE, DISODIUM LAURYL SULFOSUCCINATE, THIIAI-DODESILBENZEN SULPOXYLATE, THIOPEI-DODESILBENZEN SULFOSUCCINATE, (SODIUM C14-16OLEFIN SULFONATE), SODIUM HEXANESULFONATE, SODIUM BENZOTRIAZOLYL BUTYLPHENOL SULFONATE, and polydodecane (TEA-DODECYL BENZENESULFONATE), sodium C14-16 olefin sulfonate POLYDODANAMIDEAMINIUM TRIAZADIPHENYL ETHENESULFONATE &lt; RTI ID = 0.0 &gt; In-water type cosmetic composition, characterized in that at least one member selected from the group consisting of.
The method according to claim 1,
Wherein the hardness value of the cosmetic composition is 7.0 g to 10.0 g.
The method according to claim 1,
Wherein at least one of the amine compound and the sulfonic acid compound (b) is a mixture of an amine compound and a sulfonic acid compound.
The method according to claim 6,
Wherein the mixture comprises an amine compound: sulfonic acid compound in a mixing ratio of 3: 1 to 1: 3.
The method according to claim 1,
Wherein the cosmetic composition comprises: (a) 0.1% by weight to 5.0% by weight of the shape memory polymer with respect to the weight of the total composition.
The method according to claim 1,
Wherein the cosmetic composition comprises (b) at least one compound selected from an amine compound and a sulfonic acid compound in an amount of 1.0 wt% to 20.0 wt% based on the weight of the total composition.
10. The method according to any one of claims 1 to 9,
Wherein the cosmetic composition is for skin defect correction.
KR1020160038898A 2016-01-07 2016-03-31 Oil-In-Water Cosmetic Composition with Shape-Memory Ability KR101814379B1 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20210039821A (en) * 2019-10-02 2021-04-12 코스맥스 주식회사 Composition for oil in water emulsion cosmetic with shape memory polymer
WO2022203446A1 (en) * 2021-03-25 2022-09-29 주식회사 엘지생활건강 Cosmetic composition comprising amphiphilic polymer

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100588831B1 (en) * 2005-02-01 2006-06-14 한불화장품주식회사 The manufacturing method and cosmetics composition of shape-memory type hydrogel emulsions by associative polymers
FR3006185B1 (en) * 2013-06-03 2015-08-07 Oreal COSMETIC COMPOSITION COMPRISING NONIONIC ASSOCIATIVE POLYMERS AND SULFONATE ANIONIC SURFACTANTS, AND COSMETIC TREATMENT METHOD

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20210039821A (en) * 2019-10-02 2021-04-12 코스맥스 주식회사 Composition for oil in water emulsion cosmetic with shape memory polymer
WO2022203446A1 (en) * 2021-03-25 2022-09-29 주식회사 엘지생활건강 Cosmetic composition comprising amphiphilic polymer

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