KR20170076250A - Magnesium alloy and method for manufacturing the same - Google Patents

Magnesium alloy and method for manufacturing the same Download PDF

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Publication number
KR20170076250A
KR20170076250A KR1020150186288A KR20150186288A KR20170076250A KR 20170076250 A KR20170076250 A KR 20170076250A KR 1020150186288 A KR1020150186288 A KR 1020150186288A KR 20150186288 A KR20150186288 A KR 20150186288A KR 20170076250 A KR20170076250 A KR 20170076250A
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South Korea
Prior art keywords
magnesium alloy
rolled material
magnesium
molten metal
produce
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KR1020150186288A
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Korean (ko)
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KR101787550B1 (en
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박우진
엄형섭
김상진
최대환
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주식회사 포스코
재단법인 포항산업과학연구원
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Priority to KR1020150186288A priority Critical patent/KR101787550B1/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C23/00Alloys based on magnesium
    • C22C23/02Alloys based on magnesium with aluminium as the next major constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/46Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting
    • B21B1/463Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting in a continuous process, i.e. the cast not being cut before rolling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B3/00Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B37/00Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
    • B21B37/74Temperature control, e.g. by cooling or heating the rolls or the product
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/001Continuous casting of metals, i.e. casting in indefinite lengths of specific alloys
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D15/00Casting using a mould or core of which a part significant to the process is of high thermal conductivity, e.g. chill casting; Moulds or accessories specially adapted therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D21/00Casting non-ferrous metals or metallic compounds so far as their metallurgical properties are of importance for the casting procedure; Selection of compositions therefor
    • B22D21/02Casting exceedingly oxidisable non-ferrous metals, e.g. in inert atmosphere
    • B22D21/04Casting aluminium or magnesium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/06Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of magnesium or alloys based thereon

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Continuous Casting (AREA)

Abstract

The present invention relates to a magnesium alloy and a method of manufacturing the same.
In one embodiment of the present invention, 1.0 to 5.0% by weight of aluminum (Al), 0.3 to 3.0% by weight of zinc (Zn), 0.01 to 3.0% by weight of antimony (Sb) (Sr): 0.01 to 1.0 wt.%, The balance being magnesium (Mg) and other unavoidable impurities.

Description

[0001] MAGNESIUM ALLOY AND METHOD FOR MANUFACTURING THE SAME [0002]

One embodiment of the present invention relates to a magnesium alloy and a method of making the same.

The addition of aluminum (Al) to the magnesium alloy can improve the casting of the magnesium alloy. For this reason, alloys for casting such as AZ91 containing about 9 wt% of aluminum (Al) are widely used in automobile parts and the like. On the other hand, when a small amount of aluminum (Al) is added, the warm formability of the magnesium alloy can be improved. Therefore, an aluminum alloy such as AZ31 containing about 3 wt% of aluminum (Al) has been developed.

However, AZ31 alloys developed for all new materials are not yet universally applied. One of the reasons for this is that the mechanical properties such as tensile strength and elongation are lower than that of the aluminum-based alloy. Therefore, it is necessary to improve the tensile strength and elongation to apply a magnesium alloy such as AZ31 to a plate or an outer plate of an automobile.

Magnesium alloy and a method of manufacturing the same.

The magnesium alloy, which is one embodiment of the present invention, comprises 1.0 to 5.0 wt% of aluminum (Al), 0.3 to 3.0 wt% of zinc (Zn), 0.01 to 3.0 wt% of antimony (Sb) %, Strontium (Sr): 0.01 to 1.0 wt%, magnesium (Mg), and other unavoidable impurities.

The average crystal grain size of the magnesium alloy may be 4 to 10 탆.

The yield strength of the magnesium alloy may be 160 to 260 MPa.

The tensile strength of the magnesium alloy may be 230 to 350 MPa.

The elongation percentage of the magnesium alloy may be 10 to 30%.

According to another aspect of the present invention, there is provided a method of manufacturing a magnesium alloy, comprising: preparing a molten metal; Casting the molten metal to produce a magnesium alloy; Rolling the magnesium alloy to produce a rolled material; And heat treating the rolled material, wherein the step of heat-treating the rolled material comprises: heat treating the rolled material; Cooling the solution-applied rolled material; And aging the cooled rolled material.

Solubilizing the rolled material; May be performed at a temperature range of 350 to 450 DEG C for 10 to 20 hours.

The step of cooling the solution-treated rolled material may be water-cooled to a range of 1 to 100 ° C / h.

Aging the cooled rolled material may be carried out at a temperature of 150 to 250 DEG C for 15 to 25 hours.

Wherein the molten metal comprises 1.0 to 5.0% by weight of aluminum (Al), 0.3 to 3.0% by weight of zinc (Zn), 0.01 to 3.0% by weight of antimony (Sb) %, Strontium (Sr): 0.01 to 1.0 wt%, magnesium (Mg), and other unavoidable impurities.

The step of casting the molten metal to produce the magnesium alloy may be a direct shot casting method, a continuous casting method, a metal casting method, or a combination thereof, but is not limited thereto.

The step of rolling the magnesium alloy to produce the rolled material may be rolled 5 to 8 times at a temperature range of 200 to 250 캜.

The average crystal grain size of the magnesium alloy may be 4 to 10 탆.

The yield strength of the magnesium alloy may be 160 to 260 MPa.

The tensile strength of the magnesium alloy may be 230 to 350 MPa.

The elongation percentage of the magnesium alloy may be 10 to 30%.

According to one embodiment of the present invention, antimony (Sb) and strontium (Sr) are added to an AZ-based magnesium alloy, and after the casting, a yield strength and a tensile strength Can be produced. As a result, a high strength magnesium alloy can be provided.

1 shows a rolled material according to an embodiment of the present invention.
2 shows a tensile test specimen of a rolled material according to an embodiment of the present invention.

BRIEF DESCRIPTION OF THE DRAWINGS The advantages and features of the present invention and the manner of achieving them will become apparent with reference to the embodiments described in detail below with reference to the accompanying drawings. However, it is to be understood that the present invention is not limited to the disclosed embodiments, but may be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. It is intended that the disclosure of the present invention be limited only by the terms of the appended claims. Like reference numerals refer to like elements throughout the specification.

Thus, in some embodiments, well-known techniques are not specifically described to avoid an undesirable interpretation of the present invention. Unless defined otherwise, all terms (including technical and scientific terms) used herein may be used in a sense commonly understood by one of ordinary skill in the art to which this invention belongs. Whenever a component is referred to as "including" an element throughout the specification, it is to be understood that the element may include other elements, not the exclusion of any other element, unless the context clearly dictates otherwise. Also, singular forms include plural forms unless the context clearly dictates otherwise.

The magnesium alloy, which is one embodiment of the present invention, comprises 1.0 to 5.0 wt% of aluminum (Al), 0.3 to 3.0 wt% of zinc (Zn), 0.01 to 3.0 wt% of antimony (Sb) 0.01 to 1.0% by weight of strontium (Sr), the balance magnesium (Mg) and other unavoidable impurities.

First, the reason for limiting the above components will be described.

Aluminum (Al) not only contributes to improving the fluidity of the magnesium alloy, but also enhances the strength by forming precipitates for strengthening magnesium (Mg) and Mg-Al. It may also form additional antimony (Sb) and Al-Sb precipitate phases.

Therefore, it is possible to add 1% by weight or more of the magnesium or aluminum element in order to form each precipitation phase and to expect the strength improvement as described above. However, when it is added in an amount exceeding 5% by weight, the moldability can be reduced due to reduction of ductility.

Adding a small amount of zinc (Zn) to the magnesium alloy can be expected to enhance the solvency. However, if the addition amount is excessively large, mechanical properties such as ductility may be reduced due to segregation.

Therefore, 0.3 wt% or more can be added in order to expect solid solution strengthening effect, but when it exceeds 3 wt%, coarse precipitation phase is formed and strength can be reduced

Antimony (Sb) can form a Mg-Sb precipitate phase with magnesium (Mg), which is a base metal. In addition, aluminum (Al) and Al-Sb precipitation phases to be added together can be formed, thereby contributing to improvement of tensile strength.

More specifically, even when a trace amount of about 0.01% by weight is added, the tensile strength can be improved. However, when it is added in an amount exceeding 3% by weight, a coarse precipitation phase is formed and the strength and ductility can be reduced.

Strontium (Sr) can form Mg-Sr precipitation phases with magnesium (Mg), which is a base metal. In addition, aluminum (Al) and Al-Sb precipitation phases to be added together can be formed, thereby contributing to improvement of tensile strength. In addition, it also contributes to an improvement in the tensile strength or an improvement in elongation due to grain refinement.

More specifically, even when a trace amount of about 0.01% by weight is added, tensile strength and elongation can be improved due to grain refinement or precipitation. However, when it is added in an amount exceeding 1% by weight, a coarse precipitation phase may be formed and the strength and ductility may be lowered.

Therefore, by utilizing the property of antimony (Mg-Sb) to form a fine dispersion phase with magnesium, the role of strontium (Al-Sr) to form a fine dispersion state of aluminum and the grain refining function of strontium (Sr) Magnesium alloy of the desired strength and ductility can be obtained.

More specifically, the average crystal grain size of the magnesium alloy satisfying the above-described components and composition ranges may be 4 to 10 탆. The yield strength of the magnesium alloy may be 160 to 260 MPa. The tensile strength of the magnesium alloy may be 230 to 350 MPa, and the elongation of the magnesium alloy may be 10 to 30%.

According to another aspect of the present invention, there is provided a method of manufacturing a magnesium alloy, comprising: preparing a molten metal; Casting the molten metal to produce a magnesium alloy; Rolling the magnesium alloy to produce a rolled material; And heat treating the rolled material.

In addition, in the magnesium alloy manufacturing method according to an embodiment of the present invention, the magnesium alloy can be manufactured and heat-treated by an extrusion process as well as a rolling process.

More specifically, the step of heat-treating the rolled material may include: a step of solubilizing the rolled material; Cooling the solution-applied rolled material; And aging the cooled rolled material.

The heat treatment of the rolled material may be performed at a temperature ranging from 350 to 450 ° C for 10 to 20 hours.

Thereafter, the step of cooling the solution-treated rolled material can be water-cooled to a range of 1 to 100 ° C / h.

Aging the cooled rolled material may be carried out at a temperature of 150 to 250 DEG C for 15 to 25 hours.

More specifically, when the rolled material is subjected to the subsequent heat treatment in the temperature and time range, a magnesium alloy having improved yield strength and tensile strength without decreasing the elongation rate can be provided.

The molten metal may be used in an amount of 1.0 to 5.0 wt% of aluminum (Al), 0.3 to 3.0 wt% of zinc (Zn), 0.01 to 3.0 wt% of antimony (Sb) By weight, strontium (Sr): 0.01 to 1.0% by weight, magnesium (Mg), and other unavoidable impurities. At this time, the components and the composition ranges of the molten metal are the same as those of the magnesium alloy described above, and thus a detailed description thereof will be omitted.

The step of casting the molten metal to produce the magnesium alloy may be a direct chill casting method, a continuous casting method, a metal casting method, or a combination thereof. However, the present invention is not limited thereto. It is possible.

In addition, since the above method is a general process, a detailed description will be omitted.

The step of rolling the magnesium alloy to produce a rolled material may be performed at a temperature ranging from 200 to 250 ° C. In addition, the magnesium alloy may be rolled 5 to 8 times.

The average crystal grain size of the magnesium alloy produced by the above method may be 4 to 10 탆. The yield strength of the magnesium alloy may be 160 to 260 MPa. The tensile strength of the magnesium alloy may be 230 to 350 MPa, and the elongation of the magnesium alloy may be 10 to 30%.

Example

Various kinds of magnesium alloys having the chemical compositions shown in Table 1 were melted and then cast into a cylindrical shape billet having a diameter of 50 mm through gravity casting.

Thereafter, it was machined into a rectangular shape with a thickness of 20 mm, a width of 40 mm, and a length of 300 mm through machining. More specifically, the machined slabs were made of a rolled material having a thickness of 0.8 mm at a temperature of 200 to 250 ° C in only 5 to 8 passes.

The rolled material was heat-treated for strength improvement, and the curing heat treatment was water-cooled at a rate of 10 ° C / h after solution treatment at 415 ° C for 12 hours. Thereafter, the resultant was aged at 200 DEG C for 20 hours.

The tensile test piece of the rolled material completed the heat treatment was prepared to a thickness of 0.7 mm according to ASTM B557M standard, and the tensile test was conducted by a universal testing machine.

division Chemical composition (% by weight) Tensile Properties Al Zn Sb Sr Mg Yield strength
(MPa)
Maximum Seal
Strength (MPa)
Elongation (%)
Comparative Example 1 One 0.3 - - Remainder 158 223 22.3 Comparative Example 2 3 One - - Remainder 196 275 15.8 Comparative Example 3 5 3 - - Remainder 219 292 10.2 Example 1 One 0.3 0.1 0.01 Remainder 167 238 27.5 Example 2 3 0.3 0.4 0.1 Remainder 210 292 21.2 Example 3 5 0.3 3.0 1.0 Remainder 224 314 18.3 Example 4 One One 0.1 0.01 Remainder 177 245 26.2 Example 5 3 One 0.4 0.1 Remainder 218 308 20.7 Example 6 5 One 3.0 1.0 Remainder 234 324 13.1 Example 7 One 3 0.1 0.01 Remainder 194 275 23.1 Example 8 3 3 0.4 0.1 Remainder 232 327 18.9 Example 9 5 3 3.0 1.0 Remainder 252 334 12.3

As a result, as shown in Table 1, it can be seen that the yield strength, the tensile strength and the elongation ratio of the Examples are all superior to those of the Comparative Examples.

More specifically, FIG. 1 illustrates a rolled material according to an embodiment of the present invention. 2 shows a tensile test specimen of a rolled material according to an embodiment of the present invention.

Therefore, as shown in FIGS. 1 and 2, it can be seen that the rolled material and the tensile test piece according to one embodiment of the present invention have excellent elongation and moldability.

More specifically, in Comparative Example 2 and Example 5 of Table 1, although the composition ranges of aluminum and zinc are the same, in Comparative Example 2, which does not contain antimony and strontium components, It can be seen that the strength, tensile strength, and elongation are all for heat.

This can be attributed to the effect of the precipitation phase and grain refinement due to the addition of antimony and strontium and the effect of the subsequent heat treatment process after the magnesium alloy processing.

Therefore, the present invention is superior in strength and ductility to the comparative example from the above characteristics.

While the present invention has been described in connection with what is presently considered to be practical exemplary embodiments, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, You will understand.

It is therefore to be understood that the above-described embodiments are illustrative in all aspects and not restrictive. The scope of the present invention is defined by the appended claims rather than the detailed description, and all changes or modifications derived from the meaning and scope of the claims and their equivalents should be interpreted as being included in the scope of the present invention .

Claims (19)

(Al): 1.0 to 5.0 wt%, zinc (Zn): 0.3 to 3.0 wt%, antimony (Sb): 0.01 to 3.0 wt%, strontium (Sr): 0.01 to 1.0 wt% based on 100 wt% % By weight, balance magnesium (Mg), and other unavoidable impurities.
The method according to claim 1,
Wherein the magnesium alloy has an average crystal grain size of 4 to 10 占 퐉.
3. The method of claim 2,
Wherein the magnesium alloy has a yield strength of 160 to 260 MPa.
The method of claim 3,
Wherein the magnesium alloy has a tensile strength of 230 to 350 MPa.
The method according to claim 1,
Wherein the magnesium alloy has an elongation of 10 to 30%.
Preparing a molten metal;
Casting the molten metal to produce a magnesium alloy;
Rolling the magnesium alloy to produce a rolled material; And
And heat treating the rolled material,
Heat treating the rolled material;
Solubilizing the rolled material;
Cooling the solution-applied rolled material; And
And aging the cooled rolled material. ≪ Desc / Clms Page number 19 >
The method according to claim 6,
Solubilizing the rolled material; The
Is carried out at a temperature range of 350 to 450 < 0 > C.
8. The method of claim 7,
Solubilizing the rolled material; Quot;
Wherein the magnesium alloy is carried out for 10 to 20 hours.
The method according to claim 6,
Cooling the solution-applied rolled material;
And water-cooled in a range of 1 to 100 DEG C / h.
The method according to claim 6,
Aging the cooled rolled material,
Is carried out in a temperature range of 150 to 250 < 0 > C.
11. The method of claim 10,
Aging the cooled rolled material,
Wherein the magnesium alloy is carried out for 15 to 25 hours.
The method according to claim 6,
Preparing the molten metal,
Wherein the molten metal comprises 1.0 to 5.0 wt% of aluminum (Al), 0.3 to 3.0 wt% of zinc (Zn), 0.01 to 3.0 wt% of antimony (Sb), 0.01 to 3.0 wt% of strontium (Sr) 1.0% by weight, balance magnesium (Mg) and other unavoidable impurities.
The method according to claim 6,
Casting the molten metal to produce a magnesium alloy,
A direct chill casting method, a continuous casting method, a metal casting method, or a combination thereof.
The method according to claim 6,
Rolling the magnesium alloy to produce a rolled material,
Is carried out in the temperature range of 200 to 250 < 0 > C.
15. The method of claim 14,
And rolling the magnesium alloy to produce a rolled material,
Wherein the magnesium alloy is rolled 5 to 8 times.
16. The method according to any one of claims 6 to 15,
Wherein the magnesium alloy has an average crystal grain size of 4 to 10 占 퐉.
16. The method according to any one of claims 6 to 15,
Wherein the magnesium alloy has a yield strength of 160 to 260 MPa.
16. The method according to any one of claims 6 to 15,
Wherein the magnesium alloy has a tensile strength of 230 to 350 MPa.
16. The method according to any one of claims 6 to 15,
Wherein the magnesium alloy has an elongation of 10 to 30%.
KR1020150186288A 2015-12-24 2015-12-24 Magnesium alloy and method for manufacturing the same KR101787550B1 (en)

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JP2008106337A (en) * 2006-10-27 2008-05-08 Shingijutsu Kenkyusho:Kk Rolled material of magnesium alloy, and method for producing the same
JP2008163361A (en) * 2006-12-27 2008-07-17 Mitsubishi Alum Co Ltd Method for producing magnesium alloy thin sheet having uniformly fine crystal grain

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