KR20170070339A - Electrochemical energy storage device and manufacturing method thereof - Google Patents
Electrochemical energy storage device and manufacturing method thereof Download PDFInfo
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- KR20170070339A KR20170070339A KR1020150177160A KR20150177160A KR20170070339A KR 20170070339 A KR20170070339 A KR 20170070339A KR 1020150177160 A KR1020150177160 A KR 1020150177160A KR 20150177160 A KR20150177160 A KR 20150177160A KR 20170070339 A KR20170070339 A KR 20170070339A
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- electrode
- rubber cap
- case
- electrode element
- electrochemical energy
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Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/08—Housing; Encapsulation
- H01G9/10—Sealing, e.g. of lead-in wires
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/26—Electrodes characterised by their structure, e.g. multi-layered, porosity or surface features
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/78—Cases; Housings; Encapsulations; Mountings
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/004—Details
- H01G9/04—Electrodes or formation of dielectric layers thereon
- H01G9/06—Mounting in containers
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Sealing Battery Cases Or Jackets (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
Abstract
The present invention discloses an electrochemical energy storage device and a method of manufacturing the same. The electrochemical energy storage device of the present invention comprises an electrode element for storing electrochemical energy, a pair of electrode terminals protruding from an upper portion of the electrode element, a case having an open portion formed on the upper portion and an electrode element embedded through the open portion, A pair of through-holes through which the electrode terminals of the pair are passed, a rubber cap spaced apart from the upper portion of the electrode element, and a polymer resin formed on the upper surface of the rubber cap so as to lock the end of the opening portion, do.
Description
The present invention relates to an electrochemical energy storage device, and more particularly, to an electrochemical energy storage device for sealing an opening portion of a case by double sealing to prevent leakage, and a method of manufacturing the same.
In the information age, high-value-added industries that collect and utilize diverse and useful information in real time through various information and communication devices are leading. In order to secure the reliability of such systems, it is recognized that supply of stable energy is an important factor.
As part of securing stable energy, an electrochemical energy storage device, which can convert electrical energy into chemical energy and store it, and convert it into electrical energy when necessary, is used.
Batteries, which are the most common electrochemical energy storage devices, are widely used because they can store a considerable amount of energy in relatively small volumes and weights, and can output moderate power in many applications. However, batteries have a common problem of low storage characteristics and low cycle life regardless of type. This is due to the natural deterioration of the chemical contained in the battery or deterioration due to use. The disadvantage of such a battery is a natural phenomenon, so no alternative is presented.
An electric double-layer capacitor (EDLC) is an energy storage device using an electric double layer formed between an electrode and an electrolyte, unlike a battery using a chemical reaction.
The basic structure of an electric double layer capacitor is composed of an electrode, an electrolyte, a current collector, and a separator. A voltage of several volts is applied to both ends of the unit cell electrode, And a series of electrochemical mechanisms that move along and adsorb onto the surface of the electrode.
In the electric double layer capacitor, the electrolytic solution is mainly used by dissolving a certain amount of metal salt or organic salt in the organic solution. In this case, it is possible to store more energy than conventional capacitors, and it is advantageous that rapid charge / discharge is possible.
In order to safely use such an electric double charge capacitor, an electrode element is embedded in a case and sealed with a rubber cap. At this time, if the electric double charge capacitor is used for a long time, foreign matter is generated on the surface of the rubber cap, and the lifetime of the electric double charge capacitor due to foreign matter is shortened.
SUMMARY OF THE INVENTION An object of the present invention is to provide an electrochemical energy storage device for sealing a rubber cap and a polymer resin in an opening of a case by double sealing to prevent leakage, and a method of manufacturing the same.
In order to achieve the above object, an electrochemical energy storage device according to the present invention comprises: an electrode element for storing electrochemical energy; a pair of electrode terminals protruding from the electrode element; A rubber cap formed on an upper surface of the rubber cap and having a pair of through holes through which the pair of electrode terminals are inserted, And a polymer resin which is formed so that an end of the opening portion is locked to seal the case.
In addition, the case may be formed such that a side of the case in contact with the rubber cap is depressed inwardly, and an end of the opening is formed in a hook shape and spaced apart from the rubber cap.
The polymer resin is an epoxy resin.
The method of manufacturing an electrochemical energy storage device according to the present invention includes the steps of preparing an electrode element for storing electrochemical energy, embedding the electrode element through the opening in a case having an opening portion at an upper end thereof, A step of deforming a side surface of the case in contact with the rubber cap and an end of the opening, and a step of forming a polymer resin so that the end of the opening is locked on the upper portion of the rubber cap .
According to the electrochemical energy storage device and the method of manufacturing the same according to the present invention, leakage of liquid can be prevented by double sealing the rubber cap and the polymer resin in the opening portion of the case.
1 is a cross-sectional view illustrating an electrochemical energy storage device according to an embodiment of the present invention.
2 is an exploded perspective view illustrating an electrode device according to an embodiment of the present invention.
3 is a flowchart illustrating a method of manufacturing an electrochemical energy storage device according to an embodiment of the present invention.
Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings. In the drawings, the same reference numerals as used in the appended drawings denote like elements, unless indicated otherwise. In the following description of the present invention, a detailed description of known functions and configurations incorporated herein will be omitted when it may make the subject matter of the present invention rather obvious or understandable to those skilled in the art.
In the electrochemical energy storage device of the present invention, an electric double charge capacitor using an electric double layer formed between an electrode and an electrolytic solution is used, but the technical idea of the present invention is not limited thereto. That is, the electrochemical energy storage device can be applied to any device capable of storing electrochemical energy, and it can be applied to an electrolytic capacitor having a capacitance of several tens to several hundreds of microns A super capacitor, a lithium ion capacitor, or the like may be used.
FIG. 1 is a cross-sectional view illustrating an electrochemical energy storage device according to an embodiment of the present invention, and FIG. 2 is an exploded perspective view illustrating an electrode device according to an embodiment of the present invention.
1 and 2, an electrochemical
The
The
The positive electrode current collector and the negative electrode current collector accumulate electrons generated by the electrochemical reaction of the active material in the
As the electrode active material, a substance capable of adsorbing or desorbing a cation or anion of a salt in the electrolyte in the positive electrode current collector and the negative electrode current collector may be used. That is, activated carbon may be used as an electrode active material. Porous carbon-based materials having high electrical conductivity, thermal conductivity, low density, suitable corrosion resistance, low coefficient of thermal expansion, and high purity can be used as the electrode active material. For example, an activated carbon powder (ACP), a carbon nano tube (CNT), a graphite, a vapor grown carbon fiber (VGCF), a carbon aerogel, Carbon nano fiber (CNF) produced by carbonizing a polymer such as polyacrylonitrile (PAN) and polyvinylidenefluoride (PVdF) may be used.
The conductive material may be carbon black (CB), acetylene black, ketjen black, graphite, super-p, or the like as a material for imparting conductivity to the electrode .
The binder serves as a bridge for bonding the electrode active material and the conductive material, and for binding the electrode active material, the positive electrode collector, and the negative electrode collector. Materials usable as binders include carboxy methyl cellulose (CMC), polyvinylpyrrolidone (PVP), fluorinated polytetrafluoroethylene (PTFE) powder or emulsion, and rubber-based styrene butadiene rubber ( styrene butadiene rubber (SBR), and the like. These materials may be used in a mixture of at least one of these materials.
The CMC maintains the viscosity of the electrode slurry in a state similar to that of the paste, and enhances the binding strength with the positive electrode collector and the negative electrode collector. CMC increases the binding force but increases the embrittlement of the electrode material layer after casting the electrode slurry. CMC can be used to obtain the binding force between the current collector and the electrode slurry.
Polyvinylpyrrolidone serves as a dispersant and helps disperse the particles constituting the electrode slurry. Polyvinylpyrrolidone can be substituted if there are other substances that are low in addition and can aid dispersion.
Polytetrafluoroethylene is emulsified in the electrode slurry and melts at the melting point or higher, so that the polymer is held by the polymer like a web. Polytetrafluoroethylene can stably increase the bonding force between particles.
Rubber-based styrene-butadiene rubber protects the surface by coating the surface of the particles.
Additionally, the binder may further comprise polyvinylidene fluoride, carboxymethyl cellulose, hydropropyl methylcellulose, polyvinyl alcohol, and the like.
The electrolytic solution can make the charge generated from the positive electrode and the negative electrode move smoothly, and can be composed of a salt of a cation and an anion as a liquid solvent. For example, hydrochloric acid, sulfuric acid, nitric acid, acetic acid may be used alone or in combination with distilled water by selecting two or more electrolytes. It is also possible to use Li 2 SO 4 , Na 2 SO 4 , K 2 SO 4 , (NH 4 ) 2 SO 4 , LiOH, NaOH, KOH and NH 4 OH alone or in combination with distilled water have.
As the electrolyte, a cyclic carbonate, a linear carbonate, a lactone, an ether, an ester, a ketone, and / or water may be used.
Examples of the cyclic carbonates include ethylene carbonate (EC), propylene carbonate (PC), and butylene carbonate (BC). Examples of the linear carbonate include diethyl carbonate (DEC), dimethyl carbonate (DMC), dipropyl carbonate ), Ethyl methyl carbonate (EMC), and methyl propyl carbonate (MPC). Examples of the lactone are gamma butyrolactone (GBL), and examples of the ether include dibutyl ether, tetrahydrofuran, 2-methyltetrahydrofuran, 1,4-dioxane, 1,2-dimethoxyethane and the like . Examples of the esters include methyl acetate, ethyl acetate, methyl propionate, methyl pivalate, and the like. The ketones include, but are not limited to, polymethyl vinyl ketone. These solvents may be used alone or in admixture of two or more.
This, as well as the electrolytic solution as Li +, Na +, K + or a cation including an alkali metal ion composed of a combination thereof, such as, and PF 6 -, BF 4 -, Cl -, Br -, I-, ClO 4 - , Anions such as ASF 6 - , CH 3 CO 2 - , CF 3 SO 3 - , N (CF 3 SO 2 ) 2 - , C (CF 2 SO 2 ) 3 - (DEC), dimethyl carbonate (DMC), dipropyl carbonate (DPC), dimethyl sulfoxide, acetonitrile (AN), dimethoxyethane, diethoxyethane, An organic solvent selected from the group consisting of tetrahydrofuran, N-methyl-2-pyrrolidone (NMP), ethylmethyl carbonate (EMC), gamma butyrolactone or a mixture thereof may be used. TEABF 4 (tetraethylammonium tetrafluoroborate), TEMABF 4 (triethylmethylammonium tetrafluoroborate), LiClO 4 (lithium perchlor orate, lithium hexafluorophosphate (LiPF 6 ), lithium hexafluoroarsenate (LiAsF 6 ) and lithium tetrafluoroborate (LiBF 4 ), or a mixture of two or more salts thereof.
The electrolytic solution may be used to impregnate or coat the
The
The
The
The
At this time, the
The
The
The case 5 may be formed in a cylindrical shape and the maximum diameter? 1 is 18.1 mm 占 0.1, the diameter? 2 of the portion where the fixing
However, the
The rubber cap (60) is coupled inside the upper portion of the opening portion to seal the case (20). That is, the
The
The
That is, since the electrochemical
As described above, the electrochemical
The
The
An epoxy resin is a thermosetting resin produced by polymerization of a dendritic substance and an epoxy group having an epoxy group in a molecule and has excellent mechanical properties such as bending strength and hardness and has no generation of volatile substances and no shrinkage in volume at the time of curing, And has a large adhesive force on the surface.
Particularly, the
3 is a flowchart illustrating a method of manufacturing an electrochemical energy storage device according to an embodiment of the present invention.
Referring to FIGS. 1 to 3, the electrochemical
In step S10, the
Then, in step S11, the
Next, in step S12, a
Then, in step S13, the side surface of the
Next, in step S14, the
While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is clearly understood that the same is by way of illustration and example only and is not to be taken by way of limitation in the embodiment in which said invention is directed. It will be understood by those skilled in the art that various changes in form and detail may be made therein without departing from the scope of the appended claims.
10: electrode element 11: anode
13: cathode 15: separator
20: electrode terminal 30: first terminal
31: first connecting portion 33: first round bar
35: first electrode tab 37: first external connection
40: second terminal 41: second connection part
43: second round bar 45: second electrode tab
47: second external connection part 50: case
51: Fixed portion 53: Case end
60: Rubber cap 61: First through hole
63: second through hole 70: polymer resin
100: Electrochemical energy storage device
Claims (4)
A pair of electrode terminals protruding from the upper portion of the electrode element;
A case in which an opening is formed in an upper portion and the electrode element is embedded through the opening;
A rubber cap formed with a pair of through-holes through which the pair of electrode terminals pass, and spaced apart from the electrode elements; And
A polymer resin which is formed on an upper surface of the rubber cap so as to lock the end of the opening and seals the case;
And an electrochemical energy storage device.
In this case,
Wherein the side surface in contact with the rubber cap is depressed inwardly and the end of the opening is formed in a shape of a hook and spaced apart from the rubber cap.
Wherein the polymer resin is an epoxy resin.
Embedding the electrode element through the opening in a case having an opening at an upper end thereof;
Forming a rubber cap which is an elastic material so as to be spaced apart from an upper portion of the electrode element;
Deforming a side surface of the case, which is in contact with the rubber cap, and an end of the opening; And
Forming a polymeric resin on an upper surface of the rubber cap so that an end of the opening is locked;
≪ / RTI >
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KR1020150177160A KR20170070339A (en) | 2015-12-11 | 2015-12-11 | Electrochemical energy storage device and manufacturing method thereof |
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KR1020150177160A KR20170070339A (en) | 2015-12-11 | 2015-12-11 | Electrochemical energy storage device and manufacturing method thereof |
Publications (1)
Publication Number | Publication Date |
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KR20170070339A true KR20170070339A (en) | 2017-06-22 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20190081277A (en) * | 2017-12-29 | 2019-07-09 | 비나텍주식회사 | Manufacture method of series-connected capacitor module having half case |
KR20190081276A (en) * | 2017-12-29 | 2019-07-09 | 비나텍주식회사 | Series-connected capacitor module having half case |
WO2019190739A1 (en) * | 2018-03-26 | 2019-10-03 | Nesscap Co., Ltd. | Flexible closure for energy storage device and energy storage device including the same |
-
2015
- 2015-12-11 KR KR1020150177160A patent/KR20170070339A/en unknown
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20190081277A (en) * | 2017-12-29 | 2019-07-09 | 비나텍주식회사 | Manufacture method of series-connected capacitor module having half case |
KR20190081276A (en) * | 2017-12-29 | 2019-07-09 | 비나텍주식회사 | Series-connected capacitor module having half case |
WO2019190739A1 (en) * | 2018-03-26 | 2019-10-03 | Nesscap Co., Ltd. | Flexible closure for energy storage device and energy storage device including the same |
US11380952B2 (en) | 2018-03-26 | 2022-07-05 | Maxwell Technologies Korea Co., Ltd. | Flexible closure for energy storage device and energy storage device including the same |
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