KR20170058578A - Natural interior materials with natural mineral substances and their Compositions and manufacturing methods - Google Patents

Natural interior materials with natural mineral substances and their Compositions and manufacturing methods Download PDF

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KR20170058578A
KR20170058578A KR1020150162330A KR20150162330A KR20170058578A KR 20170058578 A KR20170058578 A KR 20170058578A KR 1020150162330 A KR1020150162330 A KR 1020150162330A KR 20150162330 A KR20150162330 A KR 20150162330A KR 20170058578 A KR20170058578 A KR 20170058578A
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natural
oil
mixture
flame retardant
pulp
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KR101743159B1 (en
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진태원
김덕수
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진태원
김덕수
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/10Clay
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/008Producing shaped prefabricated articles from the material made from two or more materials having different characteristics or properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/24Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B3/00Producing shaped articles from the material by using presses; Presses specially adapted therefor
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/10Clay
    • C04B14/106Kaolin
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/20Mica; Vermiculite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/20Mica; Vermiculite
    • C04B14/202Vermiculite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B16/00Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B16/04Macromolecular compounds
    • C04B16/06Macromolecular compounds fibrous
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/08Fats; Fatty oils; Ester type waxes; Higher fatty acids, i.e. having at least seven carbon atoms in an unbroken chain bound to a carboxyl group; Oxidised oils or fats
    • B28B2001/08

Abstract

The present invention provides a composition of natural interior decoration material containing a natural mineral substance, made by the following steps: mixing fine powder made by pulverizing one or several among illite, kaolinite, red clay, mica, pozzolan, raw ore, clay and vermiculite based mineral substance, which are natural substances, with 100-1000 mesh, natural pulp or natural fiber and water at the weight ratio of 1-3 : 1-3 : 3-15; and additively mixing 1-5 g of a binder, 1-5 g of an expansion admixture, 5-30 g of a flame retarding material, 0.1-5 g of a softening material, and 1.0-10.0 g of calcium complex or zinc complex of one or more oils selected from a group of a tee tree oil, a castor oil and a linseed oil based on 100 g of the natural pulp or the natural fiber, wherein the natural mineral materials are contained in the natural pulp or the natural fiber. The present invention can protect a human body from harmful materials, and enhance antibiotic property by emission of far-infrared rays and negative ions.

Description

TECHNICAL FIELD [0001] The present invention relates to a natural interior material containing natural minerals,

The present invention relates to a building interior material, and more particularly, to a building interior material which can be used as a building interior, a vehicle, an aircraft, a ship, an amusement facility, a theme park, a sound device, a speaker, And the inner side walls are made of at least one of natural minerals such as ililite, kaolin, ocher, mica stone, pozzolan, ore ore, clay, and vermiculite, which are environmentally friendly materials, , Anti-virus, blood circulation and metabolism. It activates aged cells to promote excretion of waste products and lipids, thereby eliminating the cause of skin aging and maintaining health and youthfulness. Natural pulp or natural fiber, which is used to increase the sound absorption, flame retardancy, and heat insulation. It relates to a process for producing architectural interior material with water and them.

In general, architectural interiors are substitutes for wood, and they are superior in design diversification and productivity. However, due to the heterogeneity of the materials, their appearance is poor and the thermal expansion coefficient is large, resulting in warping after construction, lack of elasticity, Or most of it is odorous and toxic, the main cause of which is the gradual release of residual formaldehyde and health problems.

Formaldehyde, which occurs in the building interior materials mainly made of synthetic resin, is known as a substance which stimulates nose and eyes with irritating gas and is suspected to cause diseases in humans and animals, and environmental concern is increasing worldwide And the emission is restricted due to the tightening of regulations in each country.

Formaldehyde resins have been widely used as adhesives in the manufacture of wood materials, especially medium density fibrous sheets, and other plate materials. Representative examples of such formaldehyde resins are melamine resins, urea resins, and the like, which are produced by the addition condensation of phenol, melamine, urea and formaldehyde.

Therefore, various methods for reducing formaldehyde remaining in the resin are being studied in various fields in the industry.

On the other hand, in general, with the massive supply of buildings, the claim of residents demanding a pleasant living environment is increasing day by day as the level of living and awareness of living increase. As the disputes with neighboring households become more frequent due to noise, It is gradually becoming shrinking.

In recent years, the noise of floor impact systems such as children's running noise and walking footsteps caused the complaints of the residents because of the speciality of sharing the walls and floors with the neighbors. And the residential environment performance related to the sound insulation performance is important for the comfortable living environment and the privacy of the residents. It is no wonder that a lot of households live in a wall or a floor with one another in the house, so there is a problem of sound insulation. The reasons for such noise problems are the changes in human relationships due to self-centered living, changes in the sound source as the living standard improves, and changes in the performance requirements of the residents. However, the more fundamental problem is the nature of the material used and the problem with the construction method. The concrete used in the apartment house is heavy and is a closed room due to the nature of the material. Therefore, the barrier is good for the noise (air transmission sound) transmitted by air, such as a voice or TV sound, to other materials of the same thickness. However, due to the nature of the material, the impact sound (solid transmission sound) generated by the direct impact on the concrete surface is easily transmitted to the adjacent generation. These characteristics are often experienced by people who live in apartment houses. Typical examples are sounds from upper floors, falling objects, etc. Even if the frequency of occurrence is not high, it is an unpleasant noise source. Therefore, such a noise source causes the complaints of tenants. This noise is an important factor that determines the quality of the residential environment. Among them, the floor impact sound between the generations is a solid sound transmission. When the impact force hits the bottom, impact energy is applied to the floor slab of the mortar, insulation layer (lightweight foam concrete, styrene foam) It is best not to generate the impact source itself in order to reduce the floor impact sound, which is transmitted by vibrating the floor slab so that the emitted sound is decomposed. However, it is impossible to realistically develop a new interlayer noise reducing material as a method to minimize impact energy. Therefore, a sound absorbing material (sound absorbing material) which is used to supply a pleasant apartment and improve the quality by applying a building material having sound insulation, vibration suppression and dustproof effect is a building material used for the purpose of absorbing sound, And plate-like sound-absorbing materials. The porous sound-absorbing material has fine bubbles or fine-tube-shaped holes formed on its surface and inside, and the sound energy is converted into heat energy and absorbed due to the friction caused by the air inside the holes being vibrated by the sound waves . The plate-like sound absorbing material obtains a sound absorbing effect by consuming sound energy while the sound waves vibrate the plate.

In order to secure the sound absorption performance of such a sound-absorbing material, synthetic fibers such as polyester and polyurethane are generally used. Since the sound-absorbing agent is widely used as an interior material, it is important to have flame retardancy. The flame retardant mainly used is a halogen-based flame retardant and a phosphorus-based flame retardant. However, since synthetic fibers such as polyester and polyurethane have high flammability, a large amount of flame retardant should be used. However, if the flame retardant is used in an excessively large amount, the sound absorbing performance of the sound absorbing material deteriorates. And the manufacturing cost of the sound absorbing material is also increased. Above all, such a sound absorbing material has a problem that it is difficult to obtain a flame retardancy exceeding a certain level even if the amount of the flame retardant is increased.

On the other hand, there are many kinds of odorous substances including ammonia in our daily life. Sulfur compounds such as hydrogen sulfide and mercaptan, nitrogen compounds such as ammonia, scatol, and amine, and fatty acids such as formic acid and acetic acid, and the like. In recent years, as the level of living has become more sensitive to odor, the odor that gives an uncomfortable feeling of life is defined as pollution, and regulations under the related laws are strengthened. Various methods have been used to remove such odors. There are four types of deodorization methods currently in use.

The first is a sensory method that uses fragrance, which does not remove a basically stinky substance by making it impossible for a person to smell bad smells by using stronger fragrance than a bad odor in a bathroom or room . Spices added to most of these deodorants are easily diffused indoors and accumulate in the lungs during breathing, which can be harmful to the human body during long-term use.

The second is a physical adsorption method, which is a typical de-aeration method using activated charcoal. Charcoal adsorbs odorous substances with a porous material with a surface area of 1 g of about 300 m 2 . It takes a relatively long time to deodorize, and if the odor particles are adsorbed to the pores of the activated carbon, the adsorbed particles can no longer be adsorbed. Therefore, there is a disadvantage that the used activated carbon must be replaced regularly.

The third is a chemical treatment method. As a typical method, chlorine dioxide is a substance that is mainly used for oxidizing odor molecules.

The fourth method is to enclose the odor particles and confine them in a specific molecule to obtain the deodorizing effect. Materials such as flavonoids, hydroxypropylbetacyclodextrin and zinc chloride are used in this method. Although most of the deodorizers are diluted or dispersed in the form of a short deodorant, a limited deodorant which only deodorizes some of the substances causing the odor, It has a range of limitations. When these products are sprayed using a spray, the deodorizing component is accumulated in the body through the respiratory apparatus, and therefore, there is a problem in that care is required for long-term use.

Korean Patent Application No. 10-2013-13111 Korean Patent Application No. 10-2013-118350

The object of the present invention is to solve the above-mentioned problems, and it is an object of the present invention to prevent the occurrence of respiratory disorders or other allergies caused by toxic substances such as antibacterial and other sick house syndromes due to the emission of far infrared rays and anions by adding natural minerals, Natural pulp or natural fiber which is natural and environmentally friendly as well as flame retardant, lightweight, construction, non-flammable, and natural natural building material containing natural minerals A manufacturing method using the same, and a building interior material.

The composition of the natural building material containing the natural mineral material containing the natural mineral substance in the natural pulp or natural fiber of the present invention, the manufacturing method using the natural building material containing the natural mineral material, and the building interior material include the new de-covering material for solving all the problems of the conventional deodorant . The new deinking ingredients are non-toxic, fragrant, fast deodorizing, powerful deodorizing and long deodorant life.

It is still another object of the present invention to provide a natural pulp or natural fiber containing natural minerals containing natural minerals in order to obtain sufficient flame retardancy while minimizing the use of added materials and to maximize sound absorption performance To provide a composition of the building interior material, a manufacturing method using the same, and a construction interior material.

In order to accomplish the above object, according to a first aspect of the present invention,

"Fine powders obtained by pulverizing one or more of natural minerals such as ilite, kaolin, loess, mica, pozzolan, ore, clay and vermiculite into 100 to 1,000 mesh and natural pulp or natural 1 to 5 g of a binder material per 1 g of natural pulp or natural fiber, 1 to 5 g of an expansion agent, 5 to 30 g of a flame retardant agent, 0.1 to 5 g of a flame retardant agent 0.1 And 5 to 10 g of a calcium complex or zinc complex of at least one oil selected from the group consisting of tea tree oil, castor oil and flaxseed oil, and natural mineral material is contained in the natural fiber A composition of a natural building material containing natural minerals,

A fine powder obtained by pulverizing one or more of natural minerals such as ilite, kaolin, ocher, mica stone, pozzolan, biotite, clay and vermiculite into 100 to 1,000 mesh and a mixture of acetic acid, lactic acid, And the weight ratio of water to one of citric acid, tartaric acid and malic acid is in a range of 1: 0.2 to 1: 4 to 20, and the mixture is stirred at room temperature or 20 to 100 DEG C at 10,000 to 50,000 Hertz (Hertz) An inorganic composite elution step of eluting the mineral composite of mineral component through ultrasonic vibration for 5 hours; The mixture of natural pulp or natural fiber, inorganic composite of residual mineral and eluted mineral component is mixed in a weight ratio of 1: 0.3 to 3, then 1 to 5 g of binder material per 100 g of natural pulp or natural fiber, 1 to 5 g of expander, By weight of the natural mineral substance and 0.5 to 10 g of calcium complex or zinc complex of at least one oil selected from the group consisting of tea tree oil, castor oil and flaxseed oil, and 5 to 30 g of the flame retardant, 0.1 to 5 g of the flexible material, Characterized in that it comprises a mixture of an inorganic complex of an eluted mineral component and a composition of a natural building material containing a natural mineral,

A fine powder obtained by pulverizing one or a plurality of natural minerals such as ilite, kaolin, loess, mica stone, pozzolan, biotite, clay, and vermiculite into 100 to 1,000 mesh and a mixture of acetic acid, lactic acid, The weight ratio of water to one of citric acid, tartaric acid and malic acid is in a range of 1: 0.2 to 1: 4 to 20, and the mixture is stirred at room temperature or 20 to 100 DEG C at a temperature of 10,000 to 50,000 Hertz Eluting the inorganic material through ultrasonic vibration over time, then stagnating for 0.5 to 3 hours to separate into a precipitate layer and a liquid phase layer, and purifying the liquid phase layer with a filter to elute an inorganic complex of mineral component; 1 to 5 g of a binder material, 1 to 5 g of an expanding material, 5 to 30 g of a flame retardant material, 0.1 to 5 g of a flame retardant material, 0.1 to 5 g of a flame retardant material per 100 g of natural pulp or natural fiber, And 5 to 10 g of a calcium complex or a zinc complex of at least one oil selected from the group consisting of tea tree oil, castor oil and flaxseed oil is added to the mineral complex of the mineral component Characterized in that it comprises a composition of a natural building material containing natural minerals,

A fine powder obtained by pulverizing one or more of natural minerals such as ilite, kaolin, loess, mica stone, pozzolan, ore or clay and vermiculite as a raw material into 100 to 1,000 mesh and natural pulp or natural fiber And water in a ratio of 1: 3: 1 to 3: 3: 15; A calcium complex of at least one oil selected from the group consisting of 1 to 5 g of a binder material per 100 g of said first mixture, 1 to 5 g of an expanding agent, 5 to 30 g of a flame retardant, 0.1 to 5 g of a flour material and tea tree oil, castor oil and flaxseed oil Or 1.0 to 10.0 g of a zinc complex are added and mixed; A molding process for molding the second mixture into a building interior material of a predetermined shape; A drying step of drying the molded building material at a temperature of 60 to 100 DEG C in a microwave oven having a wavelength of 15 to 24 mm; And a cutting step of cutting the building interior material dried in the drying step to a predetermined size. The method of manufacturing a natural building material according to claim 1,

A fine powder obtained by pulverizing one or more of natural minerals such as ilite, kaolin, ocher, mica stone, pozzolan, biotite, clay and vermiculite into 100 to 1,000 mesh and a mixture of acetic acid, lactic acid, And the weight ratio of water to one of citric acid, tartaric acid and malic acid is in a range of 1: 0.2 to 1: 4 to 20, and the mixture is stirred at room temperature or 20 to 100 DEG C at 10,000 to 50,000 Hertz (Hertz) An inorganic composite elution step of eluting the mineral composite of mineral component through ultrasonic vibration for 5 hours; The mixture of natural pulp or natural fiber, inorganic composite of residual mineral and eluted mineral component is mixed in a weight ratio of 1: 0.3 to 3, then 1 to 5 g of binder material per 100 g of natural pulp or natural fiber, 1 to 5 g of expander, 5 to 30 g of a flame retardant, 0.1 to 5 g of a fluxing agent and 1.0 to 10.0 g of a calcium complex or zinc complex of at least one oil selected from the group consisting of tea tree oil, castor oil and flaxseed oil; A molding step of molding the mixture produced in the mixing step into a building interior material having a predetermined shape; A drying step of drying the molded building material at a temperature of 60 to 100 DEG C in a microwave oven having a wavelength of 15 to 24 mm; And a cutting step of cutting the building interior material dried in the drying step to a predetermined size. The method of manufacturing a natural building material according to claim 1,

A fine powder obtained by pulverizing one or a plurality of natural minerals such as ilite, kaolin, loess, mica stone, pozzolan, biotite, clay, and vermiculite into 100 to 1,000 mesh and a mixture of acetic acid, lactic acid, The weight ratio of water to one of citric acid, tartaric acid and malic acid is in a range of 1: 0.2 to 1: 4 to 20, and the mixture is stirred at room temperature or 20 to 100 DEG C at a temperature of 10,000 to 50,000 Hertz Eluting the inorganic material through ultrasonic vibration over time, then stagnating for 0.5 to 3 hours to separate into a precipitate layer and a liquid phase layer, and purifying the liquid phase layer with a filter to elute an inorganic complex of mineral component; 1 to 5 g of a binder material, 1 to 5 g of an expanding material, 5 to 30 g of a flame retardant material, 0.1 to 5 g of a flame retardant material, 0.1 to 5 g of a flame retardant material per 100 g of natural pulp or natural fiber, ~ 5 g, and 1.0-10.0 g of a calcium complex or zinc complex of at least one oil selected from the group consisting of tea tree oil, castor oil and flaxseed oil; A molding step of molding the mixture produced in the mixing step into a building interior material having a predetermined shape; A drying step of drying the molded building material at a temperature of 60 to 100 DEG C in a microwave oven having a wavelength of 15 to 24 mm; And a cutting step of cutting the building interior material dried in the drying step to a predetermined size. The method of manufacturing a natural building material according to claim 1,

Wherein the binder material and the expanding material are carboxyl methylcellulose to which 2 to 10 g per 100 g of the natural pulp or the natural fiber is added,

The flame retardant is selected from the group consisting of pentaerythritol, ammonium polyphosphate, boric acid, borax and melamine resin, or a plurality of compounds, and 5-20 parts by weight per 100 parts by weight of the natural pulp or natural fiber A method for manufacturing a natural building material containing natural minerals,

A fine powder obtained by pulverizing one or more of natural minerals such as ilite, kaolin, loess, mica stone, pozzolan, ore or clay and vermiculite as a raw material into 100 to 1,000 mesh and natural pulp or natural fiber 1 to 5 g of a binder material, 1 to 5 g of an expanding material, 5 to 30 g of a flame retardant material, 1.0 to 5 g of a flame retardant material, and 1.0 to 5 g of a flame retardant material per 100 g of the natural pulp or natural fiber, And 1.0 to 10.0 g of a calcium complex or zinc complex of at least one oil selected from the group consisting of tea tree oil, castor oil and flaxseed oil, and an adhesive layer A natural building material containing a natural mineral, characterized in that a plurality of through holes are perforated or a magnesium board or a wood board not perforated is included,

A fine powder obtained by pulverizing one or more of natural minerals such as ilite, kaolin, ocher, mica stone, pozzolan, biotite, clay and vermiculite into 100 to 1,000 mesh and a mixture of acetic acid, lactic acid, And the weight ratio of water to one of citric acid, tartaric acid and malic acid is in a range of 1: 0.2 to 1: 4 to 20, and the mixture is stirred at room temperature or 20 to 100 DEG C at 10,000 to 50,000 Hertz (Hertz) After the mineral composite of the mineral component is eluted through the ultrasonic vibration for 5 hours, the natural pulp or the natural fiber and the inorganic composite mixture of the residual mineral and the eluted mineral component are mixed in a weight ratio of 1: 0.3 to 3, 1 to 5 g of a binder material per 100 g of pulp or natural fiber, 1 to 5 g of an expanding material, 5 to 30 g of a flame retardant material, 0.1 to 5 g of a flexible material, and a calcium complex of at least one oil selected from the group consisting of tea tree oil, castor oil and flaxseed oil Or ah And a magnesium board or a wood board having a plurality of through holes perforated or not through which is bonded to the bottom of the building interior material using an adhesive, Natural building materials with mineral content,

A fine powder obtained by pulverizing one or a plurality of natural minerals such as ilite, kaolin, loess, mica stone, pozzolan, biotite, clay, and vermiculite into 100 to 1,000 mesh and a mixture of acetic acid, lactic acid, The weight ratio of water to one of citric acid, tartaric acid and malic acid is in a range of 1: 0.2 to 1: 4 to 20, and the mixture is stirred at room temperature or 20 to 100 DEG C at a temperature of 10,000 to 50,000 Hertz And then the mixture was filtered through ultrasonic vibration to dissolve the inorganic material and then stagnated for 0.5 to 3 hours to separate into a precipitate layer and a liquid phase layer. The liquid phase layer was purified by a filter to elute the inorganic composite of the mineral component, Inorganic composite is mixed at a weight ratio of 1: 0.3 to 3 and then mixed with 1 to 5 g of a binder material, 1 to 5 g of an expander, 5 to 30 g of a flame retardant, 0.1 to 5 g of a flour material, 100 g of natural wood pulp, Consisting of castor oil and flaxseed oil And 1.0 to 10.0 g of a calcium complex or a zinc complex of at least one oil selected from the group consisting of magnesium and magnesium, and a magnesium alloy, which is bonded to the lower end of the building interior material by using an adhesive, A natural ornamental material containing natural minerals characterized by comprising a board or a wood board,

Characterized in that the binder material and the expanding material are carboxyl methylcellulose in which 2 to 10 g per 100 g of the natural pulp or natural fiber is added,

The flame retardant is selected from the group consisting of pentaerythritol, ammonium polyphosphate, boric acid, borax and melamine resin, or a plurality of compounds, and 5-20 parts by weight per 100 parts by weight of the natural pulp or natural fiber Natural building material containing natural minerals "as its characteristic features,

The calcium complex and the zinc complex of at least one oil selected from the group consisting of tea tree oil, castor oil and flaxseed oil which are harmless to the human body can be obtained by reacting a long carbon chain containing a double bond in the interior of the complex molecule with a calcium or zinc atom Has a semi-circular structure at its center, and can exert an excellent effect in capturing odorous particles by mixing with the binder material, which has been found in the development process of the present invention, and also has an antibacterial function incidentally, You can.

According to the embodiment of the natural building material containing natural minerals according to the present invention, the manufacturing method using the same, and the building interior material, the following effects can be expected.

The most preferred is that the present invention is made by mixing natural pulp with any one of natural pulp or natural fiber, and protects the human body from harmful substances due to the environment-friendly elements due to far-infrared rays and anion emission generated from natural materials Which is capable of exerting the effect of improving the health due to removal of antimicrobial and other bacteria caused by far-infrared rays and anion emission, and further,

Next, an embodiment of the present invention is characterized in that any one of the natural pulp or the natural fiber; Inorganic complex; Tea tree oil, castor oil, and flaxseed oil in a predetermined ratio. In the present invention, since the expandable material is included together with the inorganic composite material, the expandable material inflates the volume of the inorganic composite material, and the density thereof is reduced, and micropores are formed therein.

Therefore, the amount of the added material is reduced compared to the conventional building interior material, thereby making it possible to manufacture the interior material containing natural minerals more simply and inexpensively.

In addition, the present invention has a higher sound absorption coefficient than the prior art. Therefore, according to the embodiment of the present invention, efficient sound absorption can be achieved as the sound absorption performance increases.

Since the deodorizing component included in the building interior material of the present invention can effectively capture and remove odor particles, it not only has a quick deodorizing power and long-lasting power but also has adhesiveness and moldability that can not be found in existing deodorization . Therefore, the present invention has excellent deodorizing power, wide applicability, processability and convenience that can meet various needs of users. The deodorizing component contained in the building interior material of the present invention exhibits an excellent deodorizing effect for removing an odor close to 90% in the initial 30 minutes of the odor generation unlike the conventional deodorization in the initial deodorization ratio.

The flame retardant component included in the construction interior material of the present invention is much superior in flame retardancy to conventional flame retardant materials. Therefore, it can be used in a smaller amount than conventional flame retardants.

Since the flame retardant component included in the building interior material of the present invention has sufficient flame retardancy to absorb sound even in a small amount, the manufacturing cost can be reduced without deteriorating the sound absorption performance of the building interior material. It is an advantage of the present invention that the weight of the building interior material can be reduced.

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, Various changes and modifications may be possible without departing from the scope of the present invention.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a flow chart showing one embodiment of a method for manufacturing a natural building material containing natural minerals according to the present invention;
2 is a flow chart showing another embodiment of a method for manufacturing a natural building material containing natural minerals according to the present invention,
3 is a flow chart showing still another embodiment of a method for manufacturing a natural building material containing natural minerals according to the present invention,
FIG. 4 is a perspective view illustrating a sound absorbing material body and a magnesium board in a natural building material containing natural minerals according to the present invention,
FIG. 5 is a perspective view showing the sound absorbing material body and the magnesium board in a natural building material containing natural minerals according to the present invention,
6 is a cross-sectional view of a sound absorbing material body and a magnesium board in a natural building material containing natural minerals according to the present invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, embodiments of a natural building material containing natural minerals according to the present invention, a manufacturing method using the same, and an architectural interior material will be described in detail with reference to the accompanying drawings.

FIG. 1 is a flow chart showing one embodiment of a method for manufacturing a natural building material containing natural minerals according to the present invention. FIG. 2 shows another embodiment of a method for manufacturing a natural building material containing natural minerals according to the present invention FIG. 3 is a flow chart showing another embodiment of a method for manufacturing a natural building material containing natural mineral according to the present invention. FIG. 4 is a flowchart showing a method for manufacturing a natural building material containing natural minerals according to the present invention. FIG. 5 is a perspective view illustrating a natural building material containing natural minerals according to the present invention, and FIG. 6 is a perspective view showing a sound absorbing material body and a magnesium board in a natural building material containing natural minerals according to the present invention. Sectional view of the main body and the magnesium board.

Before describing the present invention in detail,

Hwangto and Illight activate blood circulation and metabolism by releasing far infrared rays. In particular, Hwangto revitalizes the production of enzymes and activates aged cells to promote waste and fat excretion, thereby eliminating the causes of skin aging. It is also beneficial to the human body, such as keeping it. In the case of ilite, it also has high infrared ray emission at room temperature, anion generation ability, antibacterial ability and antiviral ability.

In addition, the present invention can minimize the environmental pollution and the emission of harmful substances due to the existing building interior materials by activating the blood circulation and the new metabolism due to the emission of far-infrared rays and anions, such as other kaolin, mica stone, It is possible to provide a building interior material for maintaining and enjoying a beneficial and healthy life to the human body.

First, the natural building material composition containing natural mineral in the present invention will be described.

A fine powder obtained by pulverizing one or more of natural minerals such as ilite, kaolin, loess, mica stone, pozzolan, ore or clay and vermiculite as a raw material into 100 to 1,000 mesh and natural pulp or natural fiber 1 to 5 g of a binder material, 1 to 5 g of an expanding material, 5 to 30 g of a flame retardant material, 0.1 to 5 g of a flour material, and 0.1 to 5 g of a flame retardant material per 100 g of natural pulp or natural fiber, And 1.0 to 10.0 g of a calcium complex or a zinc complex of at least one oil selected from the group consisting of tea tree oil, castor oil and flaxseed oil, and adding natural mineral to the natural fiber Construction interior material composition,

Preferably, a fine powder obtained by pulverizing one or more of natural minerals such as ilite, kaolin, loess, mica, pozzolan, ore, clay and vermiculite into 100 to 1,000 mesh is mixed with acetic acid (1: 0.2 to 1: 4 to 20) in the weight ratio of one of lactic acid, sulfuric acid, citric acid, tartaric acid and malic acid to water at a ratio of 1: 0.2 to 1: 4 to 20, and mixing the mixture at room temperature or 20 to 100 DEG C at 10,000 to 50,000 hertz ) For 0.5 to 5 hours to elute an inorganic composite of a mineral component through ultrasonic vibration;

The mixture of natural pulp or natural fiber, inorganic composite of residual mineral and eluted mineral component is mixed in a weight ratio of 1: 0.3 to 3, then 1 to 5 g of binder material per 100 g of natural pulp or natural fiber, 1 to 5 g of expander, By weight of the natural mineral substance and 0.5 to 10 g of calcium complex or zinc complex of at least one oil selected from the group consisting of tea tree oil, castor oil and flaxseed oil, and 5 to 30 g of the flame retardant, 0.1 to 5 g of the flexible material, A mixture of the inorganic complex of the eluted minerals is contained,

More preferably, a fine powder obtained by pulverizing one or a plurality of natural minerals such as ilite, kaolin, loess, mica, pozzolan, clay, and vermiculite into 100 to 1,000 mesh is mixed with acetic acid (1: 0.2 to 1: 4 to 20) in the weight ratio of one of lactic acid, sulfuric acid, citric acid, tartaric acid and malic acid to water at a ratio of 1: 0.2 to 1: 4 to 20, and mixing the mixture at room temperature or 20 to 100 DEG C at 10,000 to 50,000 hertz ) For 0.5 to 5 hours to dissolve the inorganic substance by ultrasonic vibration and then to stagnate for 0.5 to 3 hours to separate into a precipitate layer and a liquid phase layer and to purify the liquid phase layer with a filter to elute the mineral composite of the mineral component Elution process;

1 to 5 g of a binder material, 1 to 5 g of an expanding material, 5 to 30 g of a flame retardant material, 0.1 to 5 g of a flame retardant material, 0.1 to 5 g of a flame retardant material per 100 g of natural pulp or natural fiber, And 5 to 10 g of a calcium complex or a zinc complex of at least one oil selected from the group consisting of tea tree oil, castor oil and flaxseed oil is added to the mineral complex of the mineral component Which is a natural building interior material.

Next, referring to FIG. 1, the building interior material containing natural minerals according to the present embodiment may be any one or a plurality of natural minerals such as ilite, kaolin, loess, mica, pozzolan, clay, A first mixture producing step in which the weight ratio of the fine powder obtained by pulverizing 100 to 1,000 meshes with natural pulp or natural fiber and water is mixed at a ratio of 1: 3: 1 to 3: 3-15;

A calcium complex of at least one oil selected from the group consisting of 1 to 5 g of a binder material per 100 g of said first mixture, 1 to 5 g of an expanding agent, 5 to 30 g of a flame retardant, 0.1 to 5 g of a flour material and tea tree oil, castor oil and flaxseed oil Or 1.0 to 10.0 g of a zinc complex are added and mixed;

A molding process for molding the second mixture into a building interior material of a predetermined shape;

A drying step of drying the molded building material at a temperature of 60 to 100 DEG C in a microwave oven having a wavelength of 15 to 24 mm; And

And a cutting step of cutting the building interior material dried in the drying step to a predetermined size,

Preferably, as shown in FIG. 2, any one or a plurality of natural minerals such as ilite, kaolin, loess, mica, pozzolan, biotite, clay, and vermiculite may be mixed with 100 to 1,000 mesh Mixing the powdered fine powder with any one of acetic acid, lactic acid, sulfuric acid, citric acid, tartaric acid and malic acid in a weight ratio of 1: 0.2 to 1: 4 to 20, An inorganic composite elution step of eluting an inorganic composite of a mineral component through ultrasonic vibration at 10,000 to 50,000 Hertz (Hertz) for 0.5 to 5 hours;

The mixture of natural pulp or natural fiber, inorganic composite of residual mineral and eluted mineral component is mixed in a weight ratio of 1: 0.3 to 3, then 1 to 5 g of binder material per 100 g of natural pulp or natural fiber, 1 to 5 g of expander, 5 to 30 g of a flame retardant, 0.1 to 5 g of a fluxing agent and 1.0 to 10.0 g of a calcium complex or zinc complex of at least one oil selected from the group consisting of tea tree oil, castor oil and flaxseed oil;

A molding step of molding the mixture produced in the mixing step into a building interior material having a predetermined shape;

A drying step of drying the molded building material at a temperature of 60 to 100 DEG C in a microwave oven having a wavelength of 15 to 24 mm; And

And a cutting step of cutting the building interior material dried in the drying step to a predetermined size,

More preferably, as shown in FIG. 3, one or a plurality of natural minerals such as ilite, kaolin, loess, mica, pozzolan, biotite, clay, Mixing the powdered fine powder with any one of acetic acid, lactic acid, sulfuric acid, citric acid, tartaric acid and malic acid in a weight ratio of 1: 0.2 to 1: 4 to 20, (Hertz) for 0.5 to 5 hours. The liquid phase is separated into a precipitate layer and a liquid phase layer by stagnating for 0.5 to 3 hours. The liquid phase layer is purified by a filter to obtain a mineral component An inorganic composite elution step of eluting the inorganic composite;

1 to 5 g of a binder material, 1 to 5 g of an expanding material, 5 to 30 g of a flame retardant material, 0.1 to 5 g of a flame retardant material, 0.1 to 5 g of a flame retardant material per 100 g of natural pulp or natural fiber, ~ 5 g, and 1.0-10.0 g of a calcium complex or zinc complex of at least one oil selected from the group consisting of tea tree oil, castor oil and flaxseed oil;

A molding step of molding the mixture produced in the mixing step into a building interior material having a predetermined shape;

A drying step of drying the molded building material at a temperature of 60 to 100 DEG C in a microwave oven having a wavelength of 15 to 24 mm; And

And a cutting step of cutting the building interior material dried in the drying step to a predetermined size.

On the other hand, in the present embodiment, the binder material, the expansion material, the flame retardant material, the flexible material, and the calcium complex or zinc complex of the oil are added in the ratio shown in Table 1 below.

Mixed component Weight (g / 100 g of pulp fibers) Binder material 1-5 Expander 1-5 Flame retardant 5 to 30 Abundant material 0.1 to 5 Calcium complex of oil or zinc complex 1.0 to 10.0

The binder material serves as an adhesive for bonding one of the natural pulp and the natural fiber to various additives. The expandable material, which can be called a blowing agent, functions to form a plurality of micro pores for securing sound absorption performance of the sound absorbing material.

The flame retardant serves to improve the internal combustion performance, and the flake material increases the flexibility of any one of the natural pulp or the natural fiber and the additive material in order to secure fluidity.

In one embodiment of the present invention, carboxylmethylcellulose may be used as the binder and the expanding agent. The carboxymethylcellulose may be added in an amount of 2 to 10 g per 100 g of the natural pulp or the natural fiber. Preferably, 6.50 g of the carboxylmethylcellulose per 100 g of the natural pulp or natural fiber may be added.

In one embodiment of the present invention, the flame retardant may be selected from the group consisting of pentaerythritol (PT), ammonium polyphosphate (APP), boric acid, borax, and melamine resin. In particular, the compound is added in an amount of 5 to 20 parts by weight per 100 parts by weight of the natural pulp or the natural fiber, but the ammonium polyphosphate is added in a relatively small amount as compared with the pentaerythritol.

In one embodiment of the present invention, an epoxy resin or a urethane resin may be added as other additives. The epoxy resin or urethane resin may serve as a curing agent or an expanding agent or a binder. The preferable amount of the epoxy resin or urethane resin to be added may be 1 to 15 g per 100 g of the natural pulp or the natural fiber. As the added amount increases, the curing rate, the expansion ratio, and the performance of the binder material tend to be improved.

The metal complex of the vegetable oil used in this example is prepared by mixing the above vegetable oil (15%) and calcium oxide or zinc oxide (10%) in water-soluble ethanol of distilled water (25%) and ethanol (50% And stirred at a reaction temperature of 85-90 ° C. After 5 hours, the precipitate formed under the reactor is filtered, washed with water and ethanol, and dried.

On the other hand, in the step of eluting the inorganic complex, any one of acetic acid, lactic acid, sulfuric acid, citric acid, tartaric acid, and malic acid is added in the ultrasound sonication so as to elute the inorganic complex substance at a high rate.

The construction interior material of the present invention is completed by combining a magnesium board 200 having a plurality of through holes 210 formed therein with an adhesive material at the lower end of the building interior body 100 manufactured as described above.

Hereinafter, the process for manufacturing the natural building material containing natural minerals according to the present invention will be described in more detail.

First, a first mixture production step (S1) is performed for manufacturing the building interior material main body 100.

The first mixture-producing step (S1) may be carried out by mixing at least one of natural minerals such as ilite, kaolin, loess, mica, pozzolan, biotite, clay and vermiculite with 100-1,000 mesh A weight ratio of one fine powder to natural pulp or natural fiber and water is 1 to 3: 1 to 3: 3 to 15 to produce a mixture.

Next, at least one kind of oil selected from the group consisting of 1 to 5 g of a binder material per the first mixture 100, 1 to 5 g of an expanding agent, 5 to 30 g of a flame retardant, 0.1 to 5 g of a flour and 0.1 to 5 g of tea tree oil, castor oil and flaxseed oil A second mixture is produced through a second mixture producing step (S2) in which 1.0 to 10.0 g of calcium complex or zinc complex is added and mixed.

Next, a molding step (S3) for molding the mixed mixture in the second mixture producing step (S2) into a predetermined shape may be performed. In the molding step (S3), for example, the second mixture may be injection molded into a panel shape or the like by an injection molding machine.

Next, in the drying step S4, the building interior main body 100 formed in the molding step S3 is dried by a dryer, and the dryer is a microwave dryer of 15 to 24 mm, and is dried in the dryer at 60 to 100 DEG C S4 may be performed.

Preferably, the drying step S4 includes a first drying step S4-1 and a second drying step S4-2. The first drying temperature of the first drying step S4-1 corresponds to the second drying temperature of the second drying step S4-1. It is set to a relatively low temperature value as compared with the drying temperature. For example, the first drying temperature may be set to a room temperature, that is, a temperature of 15 to 25 ° C, and the second drying temperature may be set to a temperature of 60 to 100 ° C. The first drying time may be set to a relatively short time as compared with the second drying time. For example, the first drying time may be set to a time within 1 hour, and the second drying time may be set to a time of 10 hours or more.

That is, in the present embodiment, the first drying step (S4-1) is performed for a relatively short time at a relatively low temperature, the second drying step (S4-2) is performed for a relatively long time at a relatively high temperature, . If the sound absorbing material containing a considerable amount of moisture is dried at a relatively high temperature immediately, there may occur a case where the building interior main body is bent or a crack is formed in the building interior main body. Therefore, in the present embodiment, the building interior material is primarily dried at the first room temperature, and then is secondarily dried at a high temperature when a certain amount of moisture is evaporated.

Finally, a cutting step S5 for cutting the dried building interior material to a predetermined size in the drying step S4 may be performed. In the cutting step (S5), the building interior material is cut into a predetermined size, and the building interior material can be cut to a size that can be used in an actual construction site by a cutting machine.

Preferably, as shown in Figure 2

A fine powder obtained by pulverizing one or more of natural minerals such as ilite, kaolin, ocher, mica stone, pozzolan, biotite, clay and vermiculite into 100 to 1,000 mesh and a mixture of acetic acid, lactic acid, And the weight ratio of water to one of citric acid, tartaric acid and malic acid is in a range of 1: 0.2 to 1: 4 to 20, and the mixture is stirred at room temperature or 20 to 100 DEG C at 10,000 to 50,000 Hertz (Hertz) (S10) of eluting an inorganic composite material with a mineral component through ultrasonic vibration over 5 hours;

The mixture of natural pulp or natural fiber, inorganic composite of residual mineral and eluted mineral component is mixed in a weight ratio of 1: 0.3 to 3, then 1 to 5 g of binder material per 100 g of natural pulp or natural fiber, 1 to 5 g of expander, (S20) of adding 1.0 to 10.0 g of a calcium complex or a zinc complex of at least one oil selected from the group consisting of tea tree oil, castor oil and flaxseed oil, by 5 to 30 g of a flame retardant, 0.1 to 5 g of a flexible material And the resulting mixture is subjected to the molding step (3), the drying step (4) and the cutting step (S5) to produce a natural building interior material,

More preferably, as shown in Fig. 3

A fine powder obtained by pulverizing one or a plurality of natural minerals such as ilite, kaolin, loess, mica stone, pozzolan, biotite, clay, and vermiculite into 100 to 1,000 mesh and a mixture of acetic acid, lactic acid, The weight ratio of water to one of citric acid, tartaric acid and malic acid is in a range of 1: 0.2 to 1: 4 to 20, and the mixture is stirred at room temperature or 20 to 100 DEG C at a temperature of 10,000 to 50,000 Hertz (S100) for eluting an inorganic complex through elution of ultrasound waves over a period of time and then stagnating for 0.5 to 3 hours to separate into a precipitate layer and a liquid phase layer and purifying the liquid phase layer with a filter filter to elute an inorganic complex of a mineral component, ;

1 to 5 g of a binder material, 1 to 5 g of an expanding material, 5 to 30 g of a flame retardant material, 0.1 to 5 g of a flame retardant material, 0.1 to 5 g of a flame retardant material per 100 g of natural pulp or natural fiber, (S200) in which 1.0 to 10.0 g of a calcium complex or zinc complex of at least one oil selected from the group consisting of tea tree oil, castor oil and flaxseed oil is added, 3), a drying step (4), and a cutting step (S5).

Compared to the conventional building interior material, the building interior material produced in this way can exhibit the effect of being beneficial to the human body as compared with the existing building interior material due to the emission of far-infrared rays and anions due to the inclusion of natural minerals. The most representative example of the conventional architectural interior materials is a wood-wool board, that is, a wood fiber interior material, which is formed by compressing wood fibers and an inorganic binder at a high temperature and a high pressure. However, either natural pulp or natural fiber absorbs sound absorption better than wood fiber. Therefore, the construction interior material of the present invention, which uses either natural pulp or natural fiber as a main raw material, has better sound absorption performance than conventional building interior materials using wood fiber as a main raw material. Table 2 below compares the sound absorption performance of the building interior material having the sound absorption function according to the prior art and the building interior material according to the present embodiment by the noise frequency.

Frequency (Hz) Conventional technology In this embodiment 100 0.15 0.40 200 0.45 0.60 300 0.54 0.61 400 0.67 0.67 500 0.72 0.72 600 0.74 0.76 800 0.67 0.72 1000 0.64 0.69 1200 0.60 0.65 1600 0.58 0.63 2000 0.56 0.61 2500 0.51 0.53 3000 0.52 0.55 4000 0.54 0.56 5000 0.57 0.58

[Table 2] shows the absorption coefficient for noise of each frequency under the temperature condition of 23.7 ~ 25.4 ℃ and the humidity condition of 53.8 ~ 55.6% R.H. In Table 2, the architectural interior material according to the prior art is made by adding wood fiber as a main material and various additives other than wood fiber. Therefore, as shown in [Table 2], it can be said that the construction interior material according to the present embodiment has superior sound absorption performance as compared with the construction interior material according to the prior art.

The building interior material according to the present embodiment exhibits excellent deodorizing performance as compared with conventional de-covering.

In order to confirm the deodorization performance of the building interior material of the present invention, propylene glycol monomethyl ether acetate (PGMEA), which is widely used as a cleaning agent for formaldehyde, acetone, and electronic circuit, which are main causes of odor, ammonia, trimethylamine, Were subjected to a deodorization test. As a concrete test method, specimen pieces (1 mm thick, 10 cm wide and 10 cm long pieces of specimens) each having a suitable size were cut into a container of 5 L volume, and each odor sample gas was individually forced After the injection, the deodorizing performance of each gas was measured by measuring the residual gas concentration in the container containing the specimen pieces with a test measurement time of 2 hours. [Table 3], [Table 4], [Table 5] and [Table 6] below show the test results for each deodorization test.

Test Items Test result Odor Sample concentration (ppm) Deodorization rate (%) ammonia 0 minutes 500  0.0 30 minutes 27 94 60 minutes 20 96 90 minutes 14 97 120 minutes Less than 1 100

Test Items Test result Odor Sample concentration (ppm) Deodorization rate (%) Trimethylamine 0 minutes 500  0.0 30 minutes  45 91 60 minutes  20 96 90 minutes  15 97 120 minutes  Less than 1 100

Test Items Test result Odor Sample concentration (ppm) Deodorization rate (%) Formaldehyde 0 minutes 50  0 30 minutes 8 84 60 minutes 4 92 90 minutes 3 94 120 minutes 2 96

Test Items Test result Odor Sample concentration (ppm) Deodorization rate (%) Hydrogen sulfide 0 minutes 200  0 30 minutes  14 93 60 minutes   5 97 90 minutes   4 98 120 minutes   2 99

As can be seen from the above experimental results, it can be seen that the concentration of the odor sample decreases significantly with the lapse of time, and thus the excellent deodorizing performance of the architectural interior material of the present invention can be confirmed. Especially, in the initial deodorization rate, unlike conventional deodorization, it can exhibit a high deodorizing effect that removes almost 90% of the odor within 30 minutes of the generation of odor.

Comparative Example 1 Comparative Example 2 Comparative Example 3 Example 1 Example 2 Example 3 Example 4 Total heat released (MJ / m 2 ) 15.5 17.3 16.31 13.5 10.1 12.1 12.8

Comparative Example 1 Boric acid 20 parts by weight

Comparative Example 2 Borax 20 parts by weight

Comparative Example 3: Ammonium polyphosphate 20 parts by weight

Example 1 Melamine resin + pentaerythritol 20 parts by weight

Example 2 Melamine resin + ammonium polyphosphate 20 parts by weight

Example 3 Melamine resin + boric acid 20 parts by weight

Example 4 Melamine resin + borax 20 weight part

As shown in Table 8 below, the building interior material of the present invention shown in Table 7 was excellent in flame retardancy by 51.4%. In one embodiment of the present invention (Example 5), the level of flame retardant grade 2, which corresponds to the semi-combustible material, was achieved by the KS F ISO 5660-1 test method (cone calorimeter method).

Comparative Example 4 Example 5 Total heat released (MJ / m 2 ) 16.1 8.5

Comparative Example 4: boric acid 10 parts by weight + ammonium polyphosphate 10 parts by weight

Example 5: 5 parts by weight of melamine resin + 5 parts by weight of pentaerythritol + 5 parts by weight of boric acid + 5 parts by weight of ammonium polyphosphate

As can be seen from the above experimental results, the flame retardant building interior material of the present invention is much superior to the conventional flame retardant building interior material.

Hereinafter, a natural building material containing natural minerals according to the present invention will be described.

A fine powder obtained by pulverizing one or more of natural minerals such as ilite, kaolin, loess, mica stone, pozzolan, ore or clay and vermiculite as a raw material into 100 to 1,000 mesh and natural pulp or natural fiber 1 to 5 g of a binder material, 1 to 5 g of an expanding material, 5 to 30 g of a flame retardant material, 1.0 to 5 g of a flame retardant material, and 1.0 to 5 g of a flame retardant material per 100 g of the natural pulp or natural fiber, And 1.0 to 10.0 g of a calcium complex or zinc complex of at least one oil selected from the group consisting of tea tree oil, castor oil and flaxseed oil,

A magnesium board or a wood board which is coupled to the lower end of the building interior material using an adhesive material and in which a plurality of holes are perforated or not,

Preferably, a fine powder obtained by pulverizing one or more of natural minerals such as ilite, kaolin, loess, mica, pozzolan, ore, clay and vermiculite into 100 to 1,000 mesh is mixed with acetic acid (1: 0.2 to 1: 4 to 20) in the weight ratio of one of lactic acid, sulfuric acid, citric acid, tartaric acid and malic acid to water at a ratio of 1: 0.2 to 1: 4 to 20, and mixing the mixture at room temperature or 20 to 100 DEG C at 10,000 to 50,000 hertz ) For 0.5 to 5 hours to elute the inorganic composite of the mineral component and then mix the natural pulp or the natural fiber with the inorganic composite mixture of the residual mineral and the eluted mineral component at a weight ratio of 1: 0.3 to 3 A mixture of 1 to 5 g of a binder material per 100 g of natural pulp or natural fiber, 1 to 5 g of an expanding agent, 5 to 30 g of a flame retardant, 0.1 to 5 g of a flour and 0.1 to 5 g of a tea tree oil, castor oil and flaxseed oil Oil knife And the fabricated construction naejangje body is added to complex or zinc complex 1.0 ~ 10.0g,

A magnesium board or a wood board which is coupled to the lower end of the building interior material using an adhesive material and in which a plurality of holes are perforated or not,

More preferably, a fine powder obtained by pulverizing one or a plurality of natural minerals such as ilite, kaolin, loess, mica, pozzolan, clay, and vermiculite into 100 to 1,000 mesh is mixed with acetic acid (1: 0.2 to 1: 4 to 20) in the weight ratio of one of lactic acid, sulfuric acid, citric acid, tartaric acid and malic acid to water at a ratio of 1: 0.2 to 1: 4 to 20, and mixing the mixture at room temperature or 20 to 100 DEG C at 10,000 to 50,000 hertz ) For 0.5 to 5 hours to elute the inorganic material and then stagnate for 0.5 to 3 hours to separate into a precipitate layer and a liquid phase layer. The liquid phase layer was purified with a filter to elute the mineral composite of the mineral component, Or the natural fiber and the inorganic composite are mixed in a weight ratio of 1: 0.3 to 3, then 1 to 5 g of a binder material, 100 to 500 g of a natural pulp or natural fiber, 1 to 5 g of an expanding agent, 5 to 30 g of a flame retardant, And tea tree oil, castor oil, And 1.0 to 10.0 g of a calcium complex or zinc complex of at least one oil selected from the group consisting of xanthan gum,

And a magnesium board or a wood board, which is coupled to the lower end of the building interior material using an adhesive material and in which a plurality of holes are perforated or not drilled.

On the other hand, in the construction interior material of the present invention, the binder material and the expanding material are carboxyl methylcellulose to which 2 to 10 g per 100 g of the natural pulp or natural fiber is added,

The flame-

Pentaerythritol, ammonium polyphosphate, boric acid, borax, and melamine resin, and 5 to 20 parts by weight per 100 parts by weight of the natural pulp or the natural fiber.

Such an architectural interior material of the present invention can exhibit a relatively efficient sound absorbing performance as compared with a conventional architectural interior material. Among the conventional architectural interiors, the most representative example is a wooden board, that is, a wood fiber panel, which is formed by compressing wood fibers and an inorganic binder at high temperature and high pressure. However, pulp fibers absorb sound better than wood fibers. Therefore, the construction interior material of the present invention, which uses either natural pulp or natural fiber as a main raw material, has better sound absorption performance than conventional building interior materials using wood fiber as a main raw material.

Table 9 below compares the sound absorption performance of the building interior material according to the prior art and the building interior material according to the noise frequency according to the noise frequency.

Frequency (Hz) The construction interior material according to the prior art
Absorption coefficient
The construction interior material according to this embodiment
Absorption coefficient
100 0.02 0.03 125 0.02 0.04 160 0.04 0.05 200 0.06 0.08 250 0.07 0.10 315 0.10 0.15 400 0.16 0.21 500 0.21 0.33 630 0.32 0.48 800 0.37 0.59 1000 0.42 0.68 1250 0.46 0.78 1600 0.49 0.82 2000 0.48 0.90 2500 0.45 0.95 3150 0.42 1.00 4000 0.41 1.00 5000 0.41 1.00

[Table 9] shows the sound absorption coefficient for noise of each frequency under a temperature condition of 18.1 ± 0.1 ° C and a humidity condition of 47.6 ± 0.1% RH, a temperature condition of 17.3 ± 0.2 ° C and a humidity of 52.4 ± 0.3% Respectively. The installation area was 2700 mm in width and 3750 mm in length. The building interior material was 750 mm width, 900 mm length, 18 mm width (including 8 mm plywood). The 15 building interior materials were installed in the above installation area. The test method was measured according to KS F 2805: 2004 (Reverberation Method Sound Absorption Measurement Method), and the measurement frequency band was 100 to 5000 HZ at 1/3 octave band center frequency. The sound absorption coefficient is expressed as A T / S (S: area covered by the test piece, A T : equivalent sound absorption area of the test piece). If the value is 0, sound absorption is not performed at all.

In Table 9, the architectural interior material according to the prior art was made by adding wood fiber as a main material and various additives other than wood fiber. As can be seen from Table 9, the construction interior material according to the present embodiment has superior sound absorption performance as compared with the construction interior material according to the prior art. In particular, the construction interior material according to the present invention has a sound absorption coefficient of 0.5 to 1 at a high frequency band of 1000 Hz or more, which is recognized as a noise by a person, such as a 500 to 1000 Hz frequency band, Sound absorbing performance was 1.6 ~ 2.4 times better than building interior material.

It will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the present invention as defined by the appended claims and their equivalents. .

100: Building interior material main body 200: Magnesium board
210: Through hole S1: First mixture producing step
S2: second mixture forming step S3: molding step
S4: drying step S5: cutting step
S4-1: First drying step S4-2: Second drying step
S10: Inorganic complex elution step S20: Mixing step
S100: Inorganic complex elution step S200: Mixing step

Claims (13)

A fine powder obtained by pulverizing one or more of natural minerals such as ilite, kaolin, loess, mica stone, pozzolan, ore or clay and vermiculite as a raw material into 100 to 1,000 mesh and natural pulp or natural fiber 1 to 5 g of a binder material, 1 to 5 g of an expanding material, 5 to 30 g of a flame retardant material, 0.1 to 5 g of a flour material, and 0.1 to 5 g of a flame retardant material per 100 g of natural pulp or natural fiber, 5 g of natural calcium carbonate, and 1.0 to 10.0 g of a calcium complex or zinc complex of at least one oil selected from the group consisting of tea tree oil, castor oil and flaxseed oil. By weight of natural minerals.
A fine powder obtained by pulverizing one or more of natural minerals such as ilite, kaolin, ocher, mica stone, pozzolan, biotite, clay and vermiculite into 100 to 1,000 mesh and a mixture of acetic acid, lactic acid, And the weight ratio of water to one of citric acid, tartaric acid and malic acid is in a range of 1: 0.2 to 1: 4 to 20, and the mixture is stirred at room temperature or 20 to 100 DEG C at 10,000 to 50,000 Hertz (Hertz) An inorganic composite elution step of eluting the mineral composite of mineral component through ultrasonic vibration for 5 hours;
The mixture of natural pulp or natural fiber, inorganic composite of residual mineral and eluted mineral component is mixed in a weight ratio of 1: 0.3 to 3, then 1 to 5 g of binder material per 100 g of natural pulp or natural fiber, 1 to 5 g of expander, By weight of the natural mineral substance and 0.5 to 10 g of calcium complex or zinc complex of at least one oil selected from the group consisting of tea tree oil, castor oil and flaxseed oil, and 5 to 30 g of the flame retardant, 0.1 to 5 g of the flexible material, A composition of a natural building material containing natural minerals, characterized by containing a mixture of an inorganic complex of eluted mineral components.
A fine powder obtained by pulverizing one or a plurality of natural minerals such as ilite, kaolin, loess, mica stone, pozzolan, biotite, clay, and vermiculite into 100 to 1,000 mesh and a mixture of acetic acid, lactic acid, The weight ratio of water to one of citric acid, tartaric acid and malic acid is in a range of 1: 0.2 to 1: 4 to 20, and the mixture is stirred at room temperature or 20 to 100 DEG C at a temperature of 10,000 to 50,000 Hertz Eluting the inorganic material through ultrasonic vibration over time, then stagnating for 0.5 to 3 hours to separate into a precipitate layer and a liquid phase layer, and purifying the liquid phase layer with a filter to elute an inorganic complex of mineral component;
1 to 5 g of a binder material, 1 to 5 g of an expanding material, 5 to 30 g of a flame retardant material, 0.1 to 5 g of a flame retardant material, 0.1 to 5 g of a flame retardant material per 100 g of natural pulp or natural fiber, And 5 to 10 g of a calcium complex or a zinc complex of at least one oil selected from the group consisting of tea tree oil, castor oil and flaxseed oil is added to the mineral complex of the mineral component Wherein the composition is a natural building material containing natural minerals.
A fine powder obtained by pulverizing one or more of natural minerals such as ilite, kaolin, loess, mica stone, pozzolan, ore or clay and vermiculite as a raw material into 100 to 1,000 mesh and natural pulp or natural fiber And water in a ratio of 1: 3: 1 to 3: 3: 15;
A calcium complex of at least one oil selected from the group consisting of 1 to 5 g of a binder material per 100 g of said first mixture, 1 to 5 g of an expanding agent, 5 to 30 g of a flame retardant, 0.1 to 5 g of a flour material and tea tree oil, castor oil and flaxseed oil Or 1.0 to 10.0 g of a zinc complex are added and mixed;
A molding process for molding the second mixture into a building interior material of a predetermined shape;
A drying step of drying the molded building material at a temperature of 60 to 100 DEG C in a microwave oven having a wavelength of 15 to 24 mm; And
And a cutting step of cutting the building interior material dried in the drying step to a predetermined size.
A fine powder obtained by pulverizing one or more of natural minerals such as ilite, kaolin, ocher, mica stone, pozzolan, biotite, clay and vermiculite into 100 to 1,000 mesh and a mixture of acetic acid, lactic acid, And the weight ratio of water to one of citric acid, tartaric acid and malic acid is in a range of 1: 0.2 to 1: 4 to 20, and the mixture is stirred at room temperature or 20 to 100 DEG C at 10,000 to 50,000 Hertz (Hertz) An inorganic composite elution step of eluting the mineral composite of mineral component through ultrasonic vibration for 5 hours;
The mixture of natural pulp or natural fiber, inorganic composite of residual mineral and eluted mineral component is mixed in a weight ratio of 1: 0.3 to 3, then 1 to 5 g of binder material per 100 g of natural pulp or natural fiber, 1 to 5 g of expander, 5 to 30 g of a flame retardant, 0.1 to 5 g of a fluxing agent and 1.0 to 10.0 g of a calcium complex or zinc complex of at least one oil selected from the group consisting of tea tree oil, castor oil and flaxseed oil;
A molding step of molding the mixture produced in the mixing step into a building interior material having a predetermined shape;
A drying step of drying the molded building material at a temperature of 60 to 100 DEG C in a microwave oven having a wavelength of 15 to 24 mm; And
And a cutting step of cutting the building interior material dried in the drying step to a predetermined size.
A fine powder obtained by pulverizing one or a plurality of natural minerals such as ilite, kaolin, loess, mica stone, pozzolan, biotite, clay, and vermiculite into 100 to 1,000 mesh and a mixture of acetic acid, lactic acid, The weight ratio of water to one of citric acid, tartaric acid and malic acid is in the range of 1: 0.2 to 1: 4 to 20 and the mixture is stirred at room temperature or 20 to 100 DEG C at a rate of 10,000 to 50,000 hertz (Hertz) Eluting the inorganic material through ultrasonic vibration over time, then stagnating for 0.5 to 3 hours to separate into a precipitate layer and a liquid phase layer, and purifying the liquid phase layer with a filter to elute an inorganic complex of mineral component;
1 to 5 g of a binder material, 1 to 5 g of an expanding material, 5 to 30 g of a flame retardant material, 0.1 to 5 g of a flame retardant material, 0.1 to 5 g of a flame retardant material per 100 g of natural pulp or natural fiber, ~ 5 g, and 1.0-10.0 g of a calcium complex or zinc complex of at least one oil selected from the group consisting of tea tree oil, castor oil and flaxseed oil;
A molding step of molding the mixture produced in the mixing step into a building interior material having a predetermined shape;
A drying step of drying the molded building material at a temperature of 60 to 100 DEG C in a microwave oven having a wavelength of 15 to 24 mm; And
And a cutting step of cutting the building interior material dried in the drying step to a predetermined size.
The method according to any one of claims 4 to 6,
Wherein the binder material and the expanding material are carboxyl methylcellulose in which 2 to 10 g per 100 g of the natural pulp or natural fiber is added.
The method according to any one of claims 4 to 6,
The flame-
Pentaerythritol, ammonium polyphosphate, boric acid, borax and melamine resin, and 5 to 20 parts by weight per 100 parts by weight of the natural pulp or the natural fiber. A method for manufacturing a natural building interior material containing minerals.

A fine powder obtained by pulverizing one or more of natural minerals such as ilite, kaolin, loess, mica stone, pozzolan, ore or clay and vermiculite as a raw material into 100 to 1,000 mesh and natural pulp or natural fiber 1 to 5 g of a binder material, 1 to 5 g of an expanding material, 5 to 30 g of a flame retardant material, 1.0 to 5 g of a flame retardant material, and 1.0 to 5 g of a flame retardant material per 100 g of the natural pulp or natural fiber, And 1.0 to 10.0 g of a calcium complex or zinc complex of at least one oil selected from the group consisting of tea tree oil, castor oil and flaxseed oil,
And a magnesium board or a wood board, which is bonded to the lower end of the building interior material using an adhesive material and in which a plurality of through holes are perforated or not perforated, is included in a natural building interior material containing natural minerals.
A fine powder obtained by pulverizing one or more of natural minerals such as ilite, kaolin, ocher, mica stone, pozzolan, biotite, clay and vermiculite into 100 to 1,000 mesh and a mixture of acetic acid, lactic acid, And the weight ratio of water to one of citric acid, tartaric acid and malic acid is in a range of 1: 0.2 to 1: 4 to 20, and the mixture is stirred at room temperature or 20 to 100 DEG C at 10,000 to 50,000 Hertz (Hertz) After the mineral composite of the mineral component is eluted through the ultrasonic vibration for 5 hours, the natural pulp or the natural fiber and the inorganic composite mixture of the residual mineral and the eluted mineral component are mixed in a weight ratio of 1: 0.3 to 3, 1 to 5 g of a binder material per 100 g of pulp or natural fiber, 1 to 5 g of an expanding material, 5 to 30 g of a flame retardant material, 0.1 to 5 g of a flexible material, and a calcium complex of at least one oil selected from the group consisting of tea tree oil, castor oil and flaxseed oil Or ah And a production unit are added to the complex construction naejangje 1.0 ~ 10.0g,
And a magnesium board or a wood board, which is bonded to the lower end of the building interior material using an adhesive material and in which a plurality of through holes are perforated or not perforated, is included in a natural building interior material containing natural minerals.
A fine powder obtained by pulverizing one or a plurality of natural minerals such as ilite, kaolin, loess, mica stone, pozzolan, biotite, clay, and vermiculite into 100 to 1,000 mesh and a mixture of acetic acid, lactic acid, The weight ratio of water to one of citric acid, tartaric acid and malic acid is in a range of 1: 0.2 to 1: 4 to 20, and the mixture is stirred at room temperature or 20 to 100 DEG C at a temperature of 10,000 to 50,000 Hertz And then the mixture was filtered through ultrasonic vibration to dissolve the inorganic material and then stagnated for 0.5 to 3 hours to separate into a precipitate layer and a liquid phase layer. The liquid phase layer was purified by a filter to elute the inorganic composite of the mineral component, Inorganic composite is mixed at a weight ratio of 1: 0.3 to 3 and then mixed with 1 to 5 g of a binder material, 1 to 5 g of an expander, 5 to 30 g of a flame retardant, 0.1 to 5 g of a flour material, 100 g of natural wood pulp, Consisting of castor oil and flaxseed oil And 1.0 to 10.0 g of a calcium complex or zinc complex of at least one oil selected from the group consisting of calcium carbonate,
And a magnesium board or a wood board, which is bonded to the lower end of the building interior material using an adhesive material and in which a plurality of through holes are perforated or not perforated, is included in a natural building interior material containing natural minerals.
12. The method according to any one of claims 9 to 11,
Wherein the binder material and the expanding material are carboxyl methylcellulose in which 2 to 10 g per 100 g of the natural pulp or natural fiber is added.
12. The method according to any one of claims 9 to 11,
The flame-
Pentaerythritol, ammonium polyphosphate, boric acid, borax and melamine resin, and 5 to 20 parts by weight per 100 parts by weight of the natural pulp or the natural fiber. Natural building material with mineral content.









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KR20190096111A (en) * 2018-02-08 2019-08-19 주식회사 마노 Pulp board having flame retardancy
KR20200139431A (en) * 2019-06-04 2020-12-14 주식회사 네이처월드 Health-beneficial mold composition and its manufacturing methods for various applications
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US11218938B2 (en) 2017-11-24 2022-01-04 Samsung Electronics Co., Ltd. Electronic device and communication method thereof
KR20190096111A (en) * 2018-02-08 2019-08-19 주식회사 마노 Pulp board having flame retardancy
CN109852250A (en) * 2019-02-26 2019-06-07 深圳我氧你绿色科技有限公司 The preparation method of anion mineral coating
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