KR20170015624A - In mold decoration film and method for fabricating the same - Google Patents

In mold decoration film and method for fabricating the same Download PDF

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Publication number
KR20170015624A
KR20170015624A KR1020150107399A KR20150107399A KR20170015624A KR 20170015624 A KR20170015624 A KR 20170015624A KR 1020150107399 A KR1020150107399 A KR 1020150107399A KR 20150107399 A KR20150107399 A KR 20150107399A KR 20170015624 A KR20170015624 A KR 20170015624A
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South Korea
Prior art keywords
release film
layer
coating layer
semi
finished product
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KR1020150107399A
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Korean (ko)
Inventor
윤홍승
진봉재
김윤하
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주식회사 나노기술
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Priority to KR1020150107399A priority Critical patent/KR20170015624A/en
Publication of KR20170015624A publication Critical patent/KR20170015624A/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/14688Coating articles provided with a decoration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/06Interconnection of layers permitting easy separation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/14688Coating articles provided with a decoration
    • B29C2045/14696Coating articles provided with a decoration transparent decorated inserts

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

Disclosed is an IMD film used in an IMD (in-mold decoration) operation in which a product is formed by injection molding and a pattern formed by printing is formed on the surface of a product, and a method of manufacturing an IMD film. The disclosed IMD film is an inorganic material coating layer which is laminated on a base release film and a base release film and cured by sol or gel state or ultraviolet irradiation, And a primer layer which is laminated on the inorganic material coating layer and has a pattern formed by printing and a component which increases the adhesion strength by being laminated on the printing layer. The material of the inorganic coating layer may be at least one resin selected from the group consisting of a silane-based resin and a siloxane-based resin, and a resin contained in the inorganic coating layer by absorbing ultraviolet light A photopolymerization initiator. The base release film is separated and removed from the inorganic material coating layer after the IMD operation.

Description

[0001] IMD film and manufacturing method thereof [0002]

The present invention relates to an IMD film for use in in-mold decoration (IMD) and a method of manufacturing the IMD film.

IMD (in mold decoration) is a method of embedding a film laminated with a printing pattern in a mold when injection molding a plastic product or a ceramic product, etc., and injection molding and printing on the surface of a plastic product or a ceramic product Refers to a technique of transferring a pattern, and an IMD film refers to a film used in IMD. IMD film is widely used for the surface decoration and surface protection of cases of smart phones, notebook PCs, digital cameras, and other cases of household appliances, cosmetic containers, and automobile parts. The IMD film generally comprises a release film, a hard coat layer laminated on the release film, a print layer laminated on the hard coat layer, and a primer layer for enhancing the adhesion between the print layer and the resin injected into the mold do.

Conventional IMD films require a semi-hardening process by heat or light irradiation in order to keep the hard coating layer in a formless state during its production and prevent the machine from being contaminated due to the excessive adhesion property of the hard coat layer .

The heat curing method is a method in which an isocyanate-based thermosetting initiator is added to the hard coat layer material and cured by applying heat, and the surface hardness of the hard coat layer is lowered compared with the semi-curing method by light irradiation, The surface protection of the applied injection molding product may be insufficient. On the other hand, it is difficult to control the degree of light irradiation appropriately by the light irradiation semi-curing method, so that the hard coating layer can be excessively cured before injection molding, and thus, when the IMD film is wound in a roll form, The yield of the IMD film good product may be reduced or a crack may be generated on the surface of the injection molded product to which the IMD is applied.

On the other hand, the conventional IMD film further includes a primer layer for enhancing the adhesion between the hard coat layer and the print layer, which is semi-cured by heat or light irradiation. Therefore, the step of laminating the primer layer on the hard coat layer is required, so that the productivity is lowered and the cost is increased.

Korean Patent Registration No. 10-0559677

The present invention provides an IMD film which does not require a process of semi-curing the IMD film prior to application to the IMD work, and has improved followability and hardness to the product shape, and a method of manufacturing the IMD film.

The present invention also provides an IMD film which does not require a primer layer for enhancing adhesion between a coating layer for protecting a printing layer and a printing layer, and a method of manufacturing the IMD film.

The present invention relates to an IMD film used in an IMD (in mold decoration) operation in which a product is formed by injection molding and a pattern formed by printing is formed on the surface of the product, wherein a base release film An inorganic material coating layer which is laminated on the base release film and is cured by sol or gel state or ultraviolet light irradiation; and an inorganic material coating layer laminated on the inorganic material coating layer, A printing layer formed by the printing, and a primer layer laminated on the printing layer and containing a component for increasing the adhesion, wherein the material of the inorganic coating layer is a silane-based resin resin and a siloxane-based resin, and at least one resin selected from the group consisting of a resin contained in the inorganic material coating layer by absorbing ultraviolet rays, Comprises a photopolymerization initiator, wherein the base release film provides a film IMD (in mold decoration film) is separated off from the inorganic material coating layer after the IMD operation.

The material of the inorganic material coating layer may not contain an organic material.

The IMD film of the present invention may further include a cover release film which is laminated on the primer layer and is separated and removed from the primer layer before the IMD operation.

The inorganic material coating layer and the print layer may be directly adhered to each other without interposing another layer for increasing the adhesive force between the two.

The present invention also relates to a first release film and an inorganic material coating layer laminated on the base release film and cured by sol or gel state or ultraviolet ray irradiation, And a second release film laminated on the inorganic material coating layer, a third release film, a third release film laminated on the third release film, and a component for increasing the adhesive strength A second semi-finished product having a primer layer which is laminated on the primer layer and a printed layer in which a pattern is formed by printing, a second semi-finished product manufactured from the first semi-finished product, A second release film separating the first release film and the second release film so as to separate the second release film from the first release film and the second release film so that the side of the inorganic material coating layer exposed when the second release film is separated is adhered to the exposed side surface of the print layer, And a first semi-finished product and a second semi-finished product laminated step for laminating the separated first semi-finished product and the second semi-finished product, wherein the material of the inorganic material coating layer is a silane- At least one resin selected from the group consisting of siloxane-based resins, and a photopolymerization initiator that absorbs ultraviolet light to polymerize the resin contained in the inorganic material coating layer.

The material of the inorganic material coating layer may not contain an organic material.

The method for producing an IMD film of the present invention may further comprise a third release film separating step of separating the third release film after the first semi-finished product and the second semi-finished product lapping step.

The first semi-finished product manufacturing step may include: applying a coating agent for applying a liquid coating agent to one side of the first release film; drying the coating agent applied to the first release film to evaporate the solvent; A drying step of forming the inorganic material coating layer, and a second release film attaching step of attaching the second release film to the exposed side of the inorganic material coating layer.

The step of applying the coating may include applying the liquid coating material using one of a slot die, a comma roller, and a micro gravure roller.

The second semi-finished product manufacturing step may include a primer layer forming step of forming the primer layer on the third release film, and a printing step of forming the print layer by gravure printing on the exposed side of the primer layer And a layer forming step.

The IMD film of the present invention does not require a process of semi-curing the inorganic material coating layer of the IMD film before inserting it into a mold for application to IMD (in-mold decoration) operation. Therefore, the flexibility of the inorganic material coating layer is high, so that even in the case of a product having a complicated three-dimensional shape, the followability to the product shape is excellent and the IMD work productivity is improved.

In the present invention, due to the characteristics of the material forming the inorganic material coating layer, the inorganic material coating layer is sufficiently cured even by irradiating ultraviolet rays after the IMD work, and the surface hardness of the product is greatly improved. In addition, when applying a liquid coating agent to form an inorganic coating layer, the thickness of the inorganic coating layer can be easily controlled by controlling the flow rate of the coating agent, whereby the hardness of the product surface can be easily adjusted.

Since the IMD film of the present invention can be produced by a roll-to-roll process, the productivity is high, and the thickness uniformity and flatness of the IMD film are excellent. Further, on the material properties of the inorganic coating layer, a separate primer layer is not further applied to increase the adhesive force between the inorganic coating layer and the printing layer. Therefore, the manufacturing method is simple, the productivity is improved, and the cost is reduced.

The IMD film of the present invention is excellent in abrasion resistance, chemical resistance, water repellency and antifouling properties, and can be added with various surface characteristics by adding a functional material to a coating agent for forming an inorganic material coating layer .

In the IMD process using the IMD film of the present invention, when an inorganic material coating layer is cured by irradiating ultraviolet rays after injection molding of the product, a product coated with an IMD film on only a specific part of the product is formed by a method such as masking It is possible.

1 is a cross-sectional view of an IMD film according to an embodiment of the present invention.
FIGS. 2 to 7 sequentially illustrate the method for manufacturing the IMD film of FIG. 1. FIG.

Hereinafter, an IMD film according to an embodiment of the present invention and a method of manufacturing the same will be described in detail with reference to the accompanying drawings. The terminology used herein is a term used to properly express the preferred embodiment of the present invention, which may vary depending on the intention of the user or operator or the custom in the field to which the present invention belongs. Therefore, the definitions of these terms should be based on the contents throughout this specification.

1 is a cross-sectional view of an IMD film according to an embodiment of the present invention. Referring to FIG. 1, the IMD film 1 according to an embodiment of the present invention is formed by injection molding a product (not shown) And is used for in mold decoration (IMD) operation in which a pattern (not shown) formed by printing on the surface is displayed. The IMD film 1 includes a base release film 3, an inorganic material coating layer 4 which is laminated on the base release film 3, a printing layer 4 which is laminated on the inorganic material coating layer 4, (9), and a primer layer (8) laminated on the printing layer (9).

The printing layer (9) is a layer formed by printing on the surface of the injection-molded product. The primer layer 8 includes a component that increases the adhesive strength. When the IMD film 1 is inserted and placed in the injection mold in the process of IMD and the molten injection material such as resin or ceramic is injected into the injection mold, Thereby enhancing the adhesion between the injection material and the print layer 9.

The inorganic material coating layer 4 is a layer in a sol or gel state and has a property of being hardened hardly when irradiated with ultraviolet rays. The material of the inorganic material coating layer 4 includes an oligomer as a base resin, a monomer serving as a reactive diluent, a photopolymerization initiator, and a small amount of an additive. The oligomer and the monomer are preferably selected so that the surface of the injection molded product (not shown) is hardened to impact and the moisture resistance, water repellency and corrosion resistance of the surface of the product are improved At least one resin selected from the group consisting of a silane-based resin and a siloxane-based resin is included. Examples of the silane-based resin include isobutyltrimethoxysilane and isooctyltrimethoxysilane. Siloxane-based resins include polyacrylsiloxane, polyacryl-uratansiloxane, polyepoxysiloxane, (polyepoxysilxone). The organic material is not included as the material of the inorganic material coating layer 4. [ The photopolymerization initiator absorbs ultraviolet rays to generate radicals or cations and initiates polymerization of the resin contained in the inorganic material coating layer 4. [

When a silane-based resin or a siloxane-based resin is applied as the material of the inorganic material coating layer 4, there is a tendency that the inorganic material coating layer 4 is relaxed without being shrunk when the inorganic material coating layer 4 is cured by ultraviolet irradiation, It is possible to prevent the deformation of the product. Since the inorganic material coating layer 4 does not contain any organic material but contains an inorganic material, the hardness becomes large when the inorganic material coating layer 4 is cured, and the effect of suppressing the surface damage of the injection molded product is improved.

The base release film 3 is, for example, a flexible film made of a resin such as PET (Polyethylene phthalate). Specifically, the IMD film 1 is inserted into an injection molding die, the injection molding material is injected to form a product, and the surface of the base release film 3 is irradiated with ultraviolet rays to form an inorganic material coating layer 4) are cured and then separated and removed from the inorganic material coating layer 4. [ A releasing agent is applied to the side surface of the base release film 3 facing the inorganic material coating layer 4 so that the base release film 3 is easily peeled off from the inorganic material coating layer 4. [ The releasing agent may be, for example, a silicone-based resin, an acrylic-based resin, or a fluorine-based resin.

7) may further include a cover release film 7 (see FIG. 7) that is laminated to the primer layer 8 have. The cover release film 7 protects the primer layer 8 and prevents contamination, and can be a film of the same material as the base release film 3. [ The cover release film 7 is separated and removed from the primer layer 8 before the IMD operation, specifically, before the IMD film 1B is inserted into the injection mold.

FIGS. 2 to 7 sequentially illustrate the method for manufacturing the IMD film of FIG. 1. FIG. 2 to 7, the IMD film according to the embodiment of the present invention can be continuously produced in a roll-to-roll type. The IMD film manufacturing method includes a first semi-finished product manufacturing step, a second semi-finished product manufacturing step, a second release film separating step, a first semi-finished product and a second semi-finished product lumbering step, and a third release film separating step. The first semi-finished product manufacturing step includes a first release film 3, an inorganic material coating layer 4 laminated on the first release film 3, and a second release film 5 laminated on the inorganic material coating layer 4 (2), which are sequentially shown in Figs. 2 to 4. Fig.

The second semi-finished product manufacturing step comprises a second release film 7, a second release film 7 having a primer layer 8 laminated to the third release film 7 and a print layer 9 laminated to the primer layer 8, The step of manufacturing the semi-finished product 6 is shown sequentially in Fig. 5 and Fig.

The second release film separating step, the first semi-finished product and second semi-finished product lipping step, and the third release film separating step are shown in FIG. The second release film separating step is a step of separating the second release film 5 from the first semi-finished product 2, and the first semi-finished product and the second semi-finished product laminate step are separated from the second release film 5 The first semi-finished product in which the second release film 5 is separated and the second semi-finished product 6 are joined together so that the side of the exposed inorganic material coating layer 4 is adhered to the exposed side of the printed layer 9, And separating the third release film (7) after the first semi-finished product and the second semi-finished product lapping step.

The first semi-finished product manufacturing step includes a coating agent applying step, a drying step, and a second release film attaching step. Referring to FIG. 2, the coating agent applying step is a step of applying a coating agent to one side of the first release film 3 supplied from the first release film feeding roller 12. The first release film 3 is, for example, a flexible film made of a resin such as PET (Polyethylene phthalate). A releasing agent is applied to the surface of the first release film 3 so that the first release film 3 is easily peeled off from the inorganic material coating layer 4. [ The releasing agent may be, for example, a silicone-based resin, an acrylic-based resin, or a fluorine-based resin. The coating agent is a liquid state or a colloid state in which an oligomer, a monomer, a photopolymerization initiator, and a small amount of an additive which are materials of the inorganic material coating layer 4 are mixed and melted in a solvent.

The coating agent 4 is applied to one side of the first release film 3 through the slot die 15 when the first release film 3 is supported by the support roller 13 and proceeds. The thickness of the coating agent 4 can be adjusted by adjusting the flow rate of the coating agent 4 flowing out of the slot die 15 and the speed of the first release film 3, Surface properties such as surface hardness of the product can be adjusted.

The coating agent 4 may be applied to one side of the first release film 3 by using a comma roller or a micro gravure roller, as shown in FIG. The method of applying the coating using a slot die 15, a comma roller, or a microgravure roller may be performed by spray coating, dip coating, or flow coating There is an advantage that the thickness of the coating layer is made thinner and it is easy to control uniformly.

Referring to FIG. 3, the drying step may be performed by drying the coating agent 4 applied to the first release film 3 by using heat, wind or the like to evaporate the solvent, Thereby forming an inorganic material coating layer 4 in a gel state. In addition, when the first release film 3 coated with the coating agent 4 passes through the dryer, the first release film 3 is supported by the guide rollers 17 and 18 in the dryer and proceeds in one direction , The solvent is evaporated by radiant heat (H) and hot air in the dryer. The inorganic coating layer 4 having the solvent evaporated to become a sol or gel state has adhesiveness and elasticity, and the first release film 3 and the inorganic coating layer 4 are weakly adhered.

4, the step of attaching the second release film is a step of attaching the second release film 5 to the exposed side of the inorganic coating layer 4 formed on the first release film 3. The second release film 5 may be a film of the same material as the first release film 3. The release film attaching unit 22 has a pair of closely-spaced rollers 23 and 24. The first release film 3 on which the inorganic material coating layer 4 is laminated through the drier and the second release film 5 which is unwound and fed from the second release film feed roller 20 are sandwiched between the inorganic material coating layer 4 The second release film 5 is adhered to the inorganic coating layer 4 by allowing the second release film 5 to face and passing between the pair of the contact rollers 23 and 24. The second release film 5 is weakly adhered to the inorganic material coating layer 4. The first semi-finished product 2 formed through the release film attaching unit 22 is wound around the first semi-finished product roller 27 and recovered.

The second semi-finished product manufacturing step includes a primer layer forming step and a print layer forming step. Referring to FIG. 5, the primer layer forming step is a step of forming a laminate of the primer layer 8 on the third release film 7. Specifically, when the third release film 7 is unwound from the third release film feeding roller 32 and is supported and supported by the support roller 33, a slot die 35 (not shown) is formed on one side of the third release film 7, ) Can be applied in a liquid or colloidal state. The primer applied through the slot die 35 is naturally dried or dried through a dryer (not shown) to form a primer layer 8. The thickness of the primer layer 8 can be controlled by adjusting the flow rate of the primer flowing out of the slot die 35 and the speed of the third release film 7. The primer may be applied to one side of the third release film 7 by using a comma roller or a micro gravure roller, as shown in Fig. On the other hand, the third release film 7 may be a film of the same material as the first release film 3 and the second release film 5.

Referring to FIG. 6, the print layer forming step includes forming a print layer 9 by gravure printing on the exposed side of the primer layer 8 laminated on the third release film 7, to be. Concretely, the gravure printing roller 37 supplied with ink rotates while contacting with the third release film 7, so that a pattern on the outer circumferential surface of the gravure printing roller 37 is printed and laminated on the primer layer 8, The pattern is naturally dried or dried through a dryer (not shown) to form the printing layer 9. The pressure roller 39 presses the third release film 7 toward the gravure printing roller 37 so that the third release film 7 is in close contact with the outer circumferential surface of the gravure printing roller 37.

Referring to FIG. 7, the second release film separating step is performed by a second release film separating roller 42. The second release film 5 is separated from the first semi-finished product 2 while the first semi-finished product 2 fed and fed by the first semi-finished product roller 27 passes through the second release film separation roller 42 , And the second release film 5 is wound and recovered on the second release film rollers 44.

The first semi-finished and second semi-finished laminate steps are performed by a laminate unit 45 having a pair of closely spaced rollers 46, 47. The first release film 3 and the inorganic material coating layer 4 are left, the third release film 7, the primer layer 8, And the second semi-finished product 6 having the printing layer 9 are arranged so that the inorganic material coating layer 4 and the printing layer 9 face each other and pass between the pair of closely contacted rollers 46 and 47 The first semi-finished product 2 and the second semi-finished product 6 in which the second release film 5 is separated are combined to form an IMD film 1B. The inorganic coating layer 4 and the printing layer 9 are separated from each other by a pair of tightly adhered rollers 4 in a state in which a separate primer layer for enhancing the adhesive force between the two is not interposed due to strong adhesive property of the inorganic coating layer 4. [ (46, 47). The first semi-finished product 2 from which the second release film 5 has been separated passes through the direction changing roller 43 and is changed in the proceeding direction so that the inorganic material coating layer 4 faces downwardly to face the primer layer 8 do.

In the IMD film 1B, the first release film 3 becomes the base release film described above, and the third release film 7 becomes the cover release film described above. Although the IMD film 1B may be wound and recovered on the IMD film roller 50, a third release film separating step may be further performed by the third release film separating roller 48. The third release film 48 is separated from the IMD film 1B while the IMD film 1B formed through the laminating unit 45 passes through the third release film separating roller 48, 3 release film 48 is wound and recovered on the third release film roller 49. [ The IMD film 1 formed by removing the third release film 48 from the IMD film 1B is an IMD film according to another embodiment of the present invention described with reference to FIG. Wound and recovered. The first release film 3 of the IMD film 1 becomes the base release film described above with reference to FIG.

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it will be understood by those skilled in the art that various changes and modifications may be made without departing from the scope of the present invention. Therefore, the true scope of protection of the present invention should be defined only by the appended claims.

1: IMD film 2: first semi-finished product
3, 5, 7: Release film 4: Inorganic material coating layer
6: Second semi-finished product 8: Primer layer
9: print layer 15, 35: slot die

Claims (10)

An IMD film used in an IMD (in mold decoration) operation for forming a product by injection molding and for causing a pattern formed by printing to appear on the surface of the product,
A base release film; An inorganic material coating layer which is laminated on the base release film and cured by sol or gel state or ultraviolet irradiation; A printing layer laminated on the inorganic material coating layer, the pattern being formed by printing; And a primer layer laminated on the print layer, the primer layer including a component for increasing the adhesive strength,
Wherein the material of the inorganic material coating layer is at least one resin selected from the group consisting of a silane-based resin and a siloxane-based resin, and a resin contained in the inorganic material coating layer And a photopolymerization initiator,
Wherein the base release film is separated and removed from the inorganic material coating layer after the IMD operation.
The method according to claim 1,
Wherein the material of the inorganic material coating layer does not contain an organic substance.
The method according to claim 1,
And a cover release film laminated on the primer layer and separated and removed from the primer layer before the IMD operation.
The method according to claim 1,
Wherein the inorganic coating layer and the printing layer are directly adhered to each other without interposing another layer for enhancing adhesion between the inorganic coating layer and the printing layer.
A first release film and an inorganic material coating layer laminated on the base release film and cured by sol or gel state or ultraviolet irradiation, A first semi-finished product manufacturing step of manufacturing a first semi-finished product having a second release film laminated on a coating layer; A third release film, a third release film laminated on the first release film, a primer layer including a component for increasing the adhesive strength, and a print layer laminated on the primer layer, A second semi-finished product manufacturing step of manufacturing a second semi-finished product having the second semi-finished product; A second release film separating step of separating the second release film from the first semi-finished product; And separating the second semi-finished product and the second semi-finished product from the second release film so that the side of the exposed inorganic coating layer is adhered to the exposed side of the printed layer by separating the second release film A first semi-finished product and a second semi-finished product,
Wherein the material of the inorganic material coating layer is at least one resin selected from the group consisting of a silane-based resin and a siloxane-based resin, and a resin contained in the inorganic material coating layer Wherein the photopolymerization initiator is a photopolymerization initiator.
6. The method of claim 5,
Wherein the material of the inorganic coating layer does not contain any organic material.
6. The method of claim 5,
And a third release film separating step of separating the third release film after the first semi-finished product and the second semi-finished product lapping step.
6. The method of claim 5,
The first semi-finished product manufacturing step may include: applying a coating agent to a side surface of the first release film to apply a liquid coating agent; A drying step of drying the coating agent applied to the first release film to evaporate a solvent to form the inorganic material coating layer; And a second release film attaching step of attaching the second release film to the exposed side surface of the inorganic material coating layer.
9. The method of claim 8,
Wherein the step of applying the coating comprises applying the liquid phase coating using one of a slot die, a comma roller, and a micro gravure roller. ≪ / RTI >
6. The method of claim 5,
The second semi-finished product manufacturing step may include: a primer layer forming step of forming the primer layer on the third release film; And forming a printing layer on the exposed side of the primer layer by gravure printing.
KR1020150107399A 2015-07-29 2015-07-29 In mold decoration film and method for fabricating the same KR20170015624A (en)

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KR102335406B1 (en) * 2020-07-30 2021-12-09 주식회사 서연이화 Method for manufacturing plastic glazing
KR102368001B1 (en) * 2021-06-17 2022-02-25 넥스타테크놀로지 주식회사 Apparatus for preparing semiconductor molding film
CN115256541A (en) * 2022-07-18 2022-11-01 恒玮电子材料(昆山)有限公司 Die cutting process for controlling dimension of Mylar area of easy-to-draw glue

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102335406B1 (en) * 2020-07-30 2021-12-09 주식회사 서연이화 Method for manufacturing plastic glazing
KR102368001B1 (en) * 2021-06-17 2022-02-25 넥스타테크놀로지 주식회사 Apparatus for preparing semiconductor molding film
CN115256541A (en) * 2022-07-18 2022-11-01 恒玮电子材料(昆山)有限公司 Die cutting process for controlling dimension of Mylar area of easy-to-draw glue

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