KR20160148244A - Method of manufacturing fabric used for eco-frendly outdoor dress - Google Patents

Method of manufacturing fabric used for eco-frendly outdoor dress Download PDF

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Publication number
KR20160148244A
KR20160148244A KR1020150084977A KR20150084977A KR20160148244A KR 20160148244 A KR20160148244 A KR 20160148244A KR 1020150084977 A KR1020150084977 A KR 1020150084977A KR 20150084977 A KR20150084977 A KR 20150084977A KR 20160148244 A KR20160148244 A KR 20160148244A
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KR
South Korea
Prior art keywords
nylon
chip
polyester
sheath
thermally conductive
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Application number
KR1020150084977A
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Korean (ko)
Inventor
전상후
문성엽
Original Assignee
원창머티리얼 주식회사
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Priority to KR1020150084977A priority Critical patent/KR20160148244A/en
Publication of KR20160148244A publication Critical patent/KR20160148244A/en

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00Producing multi-layer textile fabrics
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D13/00Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/28Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30Conjugate filaments; Spinnerette packs therefor
    • D01D5/34Core-skin structure; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/09Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/12Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00Woven fabrics designed to make specified articles
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Physical Education & Sports Medicine (AREA)
  • Mechanical Engineering (AREA)
  • Woven Fabrics (AREA)

Abstract

(I) a step of depolymerizing a nylon closed net not subjected to a disassembling operation or a sorting operation, and then mixing thermally conductive inorganic particles with the depolymerized nylon polymer to produce a regenerated nylon chip containing thermally conductive inorganic particles; (Ii) a polyester chip (Chip) containing ceramic particles and the above-mentioned regenerated nylon chip (Chip) containing thermally conductive inorganic particles are co-spun together to form a modified cross section, and the core portion is a polyester contained in the ceramic particles The sheath portion is a step of producing a sheath-core type nylon / polyester conjugate fiber made of nylon containing thermally conductive inorganic particles; (Iii) weaving the regenerated fabric using the sheath-core type nylon / polyester conjugate fiber; And (iv) forming a porous layer on the water-repellent layer after forming a water-repellent layer on the recycled surface.
INDUSTRIAL APPLICABILITY The present invention can save resources and prevent environmental pollution by manufacturing fabrics for outdoor garments.
The fabric for outdoor clothing manufactured by the present invention can be used for a variety of applications because it is excellent in processability, dyeability, and moisture-proof and waterproofing properties like a fabric prepared by using a conventional nylon yarn chip as a raw material instead of a nylon reproducing chip Do.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a method of manufacturing an outdoor eco-

The present invention relates to a method for manufacturing a cloth for an environmentally friendly outdoor garment, and more particularly, to a method for manufacturing an environmentally-friendly outdoor garment fabric having a good physical property by a method of saving resources and protecting the environment.

Due to the growing popularity of wellbeing culture in the world and the increasing demand for outdoor activities and outdoor activities, outdoor textile fabrics are becoming popular among consumers as the latest trend in all sports activities and leisure activities , The demand of the market is dramatically increasing. In addition, functionalities in various requirements suitable for outdoor activities are required. Temperature control, lightness, stretchability, ventilation and protection against external environment, UV shielding, breathability Water resistance, windproofness, breathability, and soft touch are also emphasized.

On the other hand, due to global warming caused by environmental pollution, various natural disasters such as various natural disasters are caused, and efforts and international cooperation are actively carried out to regulate or reduce greenhouse gas emissions have.

Since wastes emit a large amount of harmful gas at incineration and the proportion of greenhouse gas emissions is relatively high, it is studied as an alternative to promote the recycling of waste.

However, these conventional regeneration methods have many problems to be solved yet, and they are not effective alternatives because of the following problems.

First, huge equipment and personnel are invested in collection and sorting. In order to maintain the quality of the original product, many people and equipment are put into the collection and sorting of the recovered waste materials, and the business feasibility is often reconsidered due to the high cost problems due to the large amount of impurities in the recovered waste materials.

Another problem is that the quality of the recycled raw material is poor. As described above, although recycling of wastes takes a great deal of money, the purity of raw materials to be regenerated is insufficient, so that they are mixed with new raw materials or used only for low-grade purposes.

Nylon is also widely used for fibers, but it is also used in various industrial applications such as tire cord, fishing rope and film, and its use as a plastic side is also increasing.

In general, nylon products have not been used to regenerate raw materials such as glass or resin products. This is because, in the case of nylon products, it is difficult to dismantle and sort finished products to a level that can be regenerated because of mixing with various other materials. However, industrial fabrics have many materials made from petroleum such as polyester and nylon, and are required to be recycled in terms of resource saving and recycling.

However, it is a fact that there is virtually no environmentally friendly outdoor textile product that extends from raw materials to finished products in the domestic market as well as the global market, which is a rapidly gaining outdoor market.

Korean Patent No. 10-1225158 discloses a method for producing a double knit fabric by using a synthetic fiber such as nylon, polyester, cotton and polyester blend, and then introducing an antimicrobial coating composition into the double knit fabric, And how to improve functionality.

Korean Patent No. 10-1212677 also discloses a method for producing a biodegradable fabric using a polylactic acid yarn as a typical biodegradable material.

However, in the above conventional methods, there has not been attempted a method of recycling the discarded nylon closed net without selecting or disassembling it, and recycling it as a raw material.

Disclosure of the Invention Problems to be Solved by the Invention It is an object of the present invention to provide a method for manufacturing outdoor fabric for outdoor garments, which can save resources and prevent environmental pollution, To provide a method of manufacturing a fabric for an environmentally friendly outdoor garment.

In order to achieve the above object, in the present invention, there is provided a method for producing a nylon filter, comprising the steps of: (i) depolymerizing a nylon closed net that has not been subjected to a disassembling operation or a screening operation, and then mixing thermally conductive inorganic particles with the depolymerized nylon polymer, (Chip); (Ii) a polyester chip (Chip) containing ceramic particles and the above-mentioned regenerated nylon chip (Chip) containing thermally conductive inorganic particles are co-spun together to form a modified cross section, and the core portion is a polyester contained in the ceramic particles The sheath portion is a step of producing a sheath-core type nylon / polyester conjugate fiber made of nylon containing thermally conductive inorganic particles; (Iii) weaving the regenerated fabric using the sheath-core type nylon / polyester conjugate fiber; And (iv) forming a porous layer on the water-repellent layer after forming a water-repellent layer on the recycled surface.

INDUSTRIAL APPLICABILITY The present invention can save resources and prevent environmental pollution by manufacturing fabrics for outdoor garments.

The fabric for outdoor clothing manufactured by the present invention can be used for a variety of applications because it is excellent in processability, dyeability, and moisture-proof and waterproofing properties like a fabric prepared by using a conventional nylon yarn chip as a raw material instead of a nylon reproducing chip Do.

1 is a cross-sectional view of a cis-core type nylon / polyester composite yarn.

Hereinafter, the present invention will be described in detail.

The method for manufacturing an environmentally friendly outdoor garment according to the present invention comprises the steps of: (i) depolymerizing a nylon closed net that has not been subjected to a disassembling operation or a screening operation, and then thermally conductive inorganic particles are mixed with the depolymerized nylon polymer, A step of producing a nylon chip; (Ii) a polyester chip (Chip) containing ceramic particles and the above-mentioned regenerated nylon chip (Chip) containing thermally conductive inorganic particles are co-spun together to form a modified cross section, and the core portion is a polyester contained in the ceramic particles The sheath portion is a step of producing a sheath-core type nylon / polyester conjugate fiber made of nylon containing thermally conductive inorganic particles; (Iii) weaving the regenerated fabric using the sheath-core type nylon / polyester conjugate fiber; And (iv) forming a porous membrane layer on the water-repellent layer after forming a water-repellent layer on the regenerant layer.

Specifically, in the present invention, a nylon closed net that has not undergone a disassembling operation or a screening operation is first depolymerized, and thermally conductive inorganic particles are mixed with the depolymerized nylon polymer to produce a regenerated nylon chip containing thermally conductive inorganic particles.

Next, the polyester chip (Chip) and the regenerated nylon chip (Chip) are co-spun together to have a modified cross-sectional shape. The core portion is a polyester contained in the ceramic particles and the sheath portion is made of nylon containing thermally conductive inorganic particles Core-type nylon / polyester conjugate fiber.

The cis-core type nylon / polyester conjugate fiber is a regenerated fiber having a good cooling function by rapidly generating heat generated in the human body into the atmosphere. The core portion constituting the regenerated fiber is a polyester yarn containing ceramic particles, The regenerated nylon raw material containing thermally conductive inorganic particles plays a role of rapidly dissipating heat generated in the human body into the atmosphere.

The thermally conductive inorganic particles are metal compounds, carbides, oxides, and nanocomposites having higher thermal conductivity than TiO 2 .

The total fineness of the sheath-core type nylon / polyester conjugate fiber is preferably 10 to 50 denier in the production of a fabric for clothing.

1 is a schematic cross-sectional view of the sheath-core type nylon / polyester conjugate fiber.

Next, the regenerated fabric is woven using the sheath-core type nylon / polyester conjugate fiber.

When the cloth for eco-friendly outdoor clothes is woven using the sheath-core type nylon / polyester conjugate fiber, the regenerated nylon multifilament may be used only for the warp yarn, only for the warp yarn, or for both warp and weft yarns.

Next, a water-repellent layer is formed on the regenerated fabric, and then a porous membrane layer is formed thereon to produce a fabric for an environmentally-friendly outdoor garment of the present invention.

As an example of implementation, a reclaimed fabric is dipped in a non-fluorinated water repellent and dried to form a water repellent layer on the regenerated fabric, then the one-part polyurethane resin composition (including solvent) is coated on the water repellent layer, And dried to form a porous membrane.

Since the nylon closed net of the present invention is reproduced to fabricate the cloth for the environment friendly outdoor clothing, the resources can be saved and the environmental pollution can be minimized.

Further, the present invention simplifies the process because the nylon closed network is demarcated as it is without disassembly operation or selection operation.

In addition, the fabric for environmentally-friendly outdoor garment manufactured by the present invention is excellent in dyeability and physical properties and can be applied to various applications.

Hereinafter, the present invention will be described in more detail with reference to examples and comparative examples.

However, the following examples are only illustrative of preferred embodiments of the present invention and do not limit the scope of protection of the present invention.

Example  One

After the nylon closed net that did not undergo the disassembly and screening operations was depolymerized, the thermally conductive inorganic particles (carbon black) were mixed therewith to prepare a regenerated nylon chip containing thermally conductive inorganic particles.

The relative viscosity of the prepared recycled nylon chip was 2.58.

Next, a regenerated nylon chip (Chip) containing a polyester chip (Chip) containing ceramic particles and thermally conductive inorganic particles (carbon black) is spin-coated to have a flat cross section as shown in Fig. 1, And a sheath portion of a sheath-core type nylon / polyester conjugated fiber of 40 denier / 24 filaments made of nylon containing thermally conductive inorganic particles.

Next, a DTY yarn was produced by drawing-texturing a c-core type nylon / polyester composite fiber.

On the other hand, ITY yarn was produced by processing cyan-core type nylon / polyester conjugate fiber with melange yarn.

Next, a plain weave regenerated fabric was produced using the DTY yarn as a warp and the ITY yarn as a weft.

Next, the regenerated fabric was water repellent with a non-fluorine water repellent agent, and a porous membrane (porous polyurethane coating layer) was formed thereon to prepare an environmentally friendly outdoor fabric having a grain size of 60 inches and a weight of 50 g / yd.

The results of evaluating the physical properties of the manufactured environmentally friendly outdoor fabric were as shown in Table 1.

Comparative Example  One

A virgin nylon chip having a relative viscosity of 2.58, which was not subjected to a regeneration process, was used instead of a regenerated nylon chip having a relative viscosity of 2.58 in Example 1, and a DTY yarn of Example 1 was used in the production of a regenerated fabric. An environmentally friendly outdoor fabric was manufactured in the same manner as in Example 1, except that it was used as warp and weft.

The results of evaluating the physical properties of the manufactured environmentally friendly outdoor fabric were as shown in Table 1.

Comparative Example  2

A virgin nylon chip having a relative viscosity of 2.58, which was not subjected to a regeneration process, was used instead of a regenerated nylon chip having a relative viscosity of 2.58 in Example 1, and the ITY yarn of Example 1 was used in the production of a regenerated fabric. An environmentally friendly outdoor fabric was manufactured in the same manner as in Example 1, except that it was used as warp and weft.

The results of evaluating the physical properties of the manufactured environmentally friendly outdoor fabric were as shown in Table 1.

division Example 1 Comparative Example 1 Comparative Example 2 Water pressure (mmH 2 O) 8,000 7,000 6,000 Water vapor permeability (g / m 2 / day) 8,000 7,000 7,000 Tear strength (N) 8 7 8 Water repellency (point) 90 80 80 Contact cold feeling (Qmax value) 0.20 0.14 0.15

The water pressure in Table 1 was evaluated by the ISO 0811 method, the moisture permeability was evaluated by the ASTM E96 method, the tear strength was evaluated by the ISO 13937-1 method, the water discharge was evaluated by the AATCC 22 method, the contact coldness (Qmax value) Were evaluated using the KES-F7 Thermo Labo II standard.

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B: Shethubu

Claims (4)

(I) depolymerizing a nylon closed net that has not been subjected to a disassembling operation or a screening operation, and then mixing thermally conductive inorganic particles with the depolymerized nylon polymer to produce a regenerated nylon chip containing thermally conductive inorganic particles;
(Ii) a polyester chip (Chip) containing ceramic particles and the above-mentioned regenerated nylon chip (Chip) containing thermally conductive inorganic particles are co-spun together to form a modified cross section, and the core portion is a polyester contained in the ceramic particles The sheath portion is a step of producing a sheath-core type nylon / polyester conjugate fiber made of nylon containing thermally conductive inorganic particles;
(Iii) weaving the regenerated fabric using the sheath-core type nylon / polyester conjugate fiber; And
(Iv) forming a porous membrane layer on the water-repellent layer after forming a water-repellent layer on the regenerant layer.
The method according to claim 1, wherein the total fineness of the sheath-core type nylon / polyester conjugate fiber is 10 to 50 denier. The method according to claim 1, wherein the sheath-core type nylon / polyester composite fiber is used as warp and weft yarns when weaving the fabric. The method according to claim 1, wherein the sheath-core type nylon / polyester conjugate fiber is used as one of warp and weft yarns when weaving the fabric.



KR1020150084977A 2015-06-16 2015-06-16 Method of manufacturing fabric used for eco-frendly outdoor dress KR20160148244A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022173379A1 (en) * 2021-02-10 2022-08-18 Aquafilslo D.O.O. Low global warming potential fiber and its manufacturing process
CN115142181A (en) * 2022-07-01 2022-10-04 福建省谷鸿新材料科技有限公司 Ice-cool and skin-friendly fabric
KR102505310B1 (en) * 2022-12-12 2023-03-06 주식회사 피앤씨텍스타일 Method for manufacturing functional fabric using waste fishing net

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022173379A1 (en) * 2021-02-10 2022-08-18 Aquafilslo D.O.O. Low global warming potential fiber and its manufacturing process
CN115142181A (en) * 2022-07-01 2022-10-04 福建省谷鸿新材料科技有限公司 Ice-cool and skin-friendly fabric
CN115142181B (en) * 2022-07-01 2024-03-29 福建省谷鸿新材料科技有限公司 Ice refreshing skin-friendly fabric
KR102505310B1 (en) * 2022-12-12 2023-03-06 주식회사 피앤씨텍스타일 Method for manufacturing functional fabric using waste fishing net

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