KR20160120358A - Fabrication method for Bi2Te3 thermoelectric materials - Google Patents
Fabrication method for Bi2Te3 thermoelectric materials Download PDFInfo
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Abstract
Description
As technical features of the present invention relates to a type P Bi 2 Te 3 Thermoelectric material manufacturing method, and more particularly, telephone titanium will, including the raw materials of a very small amount on the thermal performance is excellent Bi 2 Te 3 based thermoelectric material production method .
Recently, various new and renewable energy technologies are being researched to replace existing fossil fuels due to global warming and depletion of energy resources. Among them, interest in thermoelectric power generation that generates electricity from various heat sources such as waste heat of an industrial or automobile, solar heat, geothermal heat, body heat, etc. is greatly increased.
Generally, a thermoelectric power generation is caused by a thermoelectric phenomenon, which is a phenomenon in which a power is generated when a temperature difference is given to a material, and in contrast, when a current is supplied to a material, heat is generated due to a Peltier effect It is a phenomenon that direct conversion of electric energy is possible. These thermoelectric generators have various advantages such as simple structure, easy to maintain due to lack of driving parts, non-vibration, semi-permanent, low noise and small size / light weight.
However, the operating efficiency of the thermoelectric power generation system is lower than that of conventional power generation methods (fossil fuel power generation, nuclear power generation) and has a disadvantage that the raw materials and manufacturing methods to be used are very expensive. Therefore, in order to effectively utilize thermoelectric power generation, it is very important to improve the performance of the thermoelectric material itself, which is a basic step of determining its overall efficiency.
Thermoelectric materials are divided into low temperature, middle temperature and high temperature according to the temperature range of use. Among them, Bi 2 Te 3 thermoelectric material shows the best performance index near room temperature and researches on it have been actively conducted. In general, the thermoelectric performance of a thermoelectric material is determined by the whiteness factor, the electric conductivity, and the thermal conductivity, and these properties are most influenced by the carrier concentration and mobility. Carrier characteristics are known to be largely influenced by the properties of the material itself and the amount of raw materials in the material.
As demand for thermoelectric materials increases, there is a growing demand for thermoelectric materials having excellent thermoelectric performance (whiteness coefficient, electrical conductivity, thermal conductivity, carrier concentration and mobility).
The technical object of the present invention is to provide a method for producing a Bi 2 Te 3 thermoelectric material having excellent thermoelectric properties and mechanical properties.
However, these problems are illustrative, and the technical idea of the present invention is not limited thereto.
Production method of the aspect for achieving according to the technical features of the present invention, Bi 2 Te 3 Thermoelectric materials using the step, the thermoelectric material, a raw material for preparing the raw material for Bi 2 Te 3 based thermoelectric material containing Te alloy Thereby forming a Bi 2 Te 3 system thermoelectric powder and sintering the Bi 2 Te 3 system thermoelectric powder to form a Bi 2 Te 3 system sintered body.
In some embodiments of the present invention, the Te alloy may include at least one selected from Se, Sn, Sb and Bi.
In some embodiments of the present invention, the Te alloy may contain 10 ppm to 50 ppm of at least one raw material selected from Se, Sn, Sb, and Bi.
In some embodiments of the present invention, the Te alloy may comprise 6 ppm to 10 ppm Se, 3 ppm to 7 ppm Sb, and 1 ppm to 5 ppm Bi.
In some embodiments of the present invention, the Te alloy may include from 13 ppm to 17 ppm Se, from 6 ppm to 10 ppm Sb, from 1 ppm to 4 ppm Sn, and from 7 ppm to 11 ppm Bi.
In some embodiments of the present invention, the step of forming the thermoelectric powder may be performed by charging the thermoelectric material and the Zr ball together in a high energy milling apparatus and milling the same.
In some embodiments of the present invention, the step of forming the sintered body may be performed using a spark plasma sintering (SPS) method.
In some embodiments of the present invention, the Bi 2 Te 3 based thermoelectric material is Bi 2 Te 3 and / Of Sb 2 Te 3 Alloy.
In some embodiments of the present invention, the Bi 2 Te 3 and / Of Sb 2 Te 3 The alloy composition ratio may be from 20:80 wt% to 30:70 wt%.
Bi 2 Te 3 Thermoelectric material production process according to the technical features of the present invention, the telephone titanium containing raw materials of a very small amount forms a thermal performance (jebaek coefficient, electrical resistivity, and the output factor) is excellent Bi 2 Te 3 Thermoelectric Materials.
The Bi 2 Te 3 thermoelectric material containing a trace amount of the above-mentioned telenium exhibits a Bi 2 Te 3 single phase, has a fine particle size and a uniform grain size to improve the mechanical properties, and thermoelectric Performance can be improved.
The Bi 2 Te 3 thermoelectric material containing a trace amount of the above-mentioned telangium has an output factor value of maximum PF = 3.5 × 10 -3 (W / K 2 m).
The effects of the present invention described above are exemplarily described, and the scope of the present invention is not limited by these effects.
1 is an XRD analysis graph of a Bi 2 Te 3 alloy powder and SPS sintered body according to an amount of raw material contained in telenium according to an embodiment of the present invention.
FIG. 2 is a graph showing the thermoelectric characteristics (whiteness coefficient, electric conductivity, output factor) of the SPS sintered body according to the amount of raw material contained in the telenium according to an embodiment of the present invention.
3 is a graph showing the thermal conductivity of the SPS sintered body according to the amount of raw material contained in the telemium according to an embodiment of the present invention.
4 is a graph showing a thermoelectric performance index (ZT) of SPS sintered body according to an amount of raw material contained in telenium according to an embodiment of the present invention.
5 is a schematic view showing a
Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings. It will be apparent to those skilled in the art that the present invention may be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the concept of the invention to those skilled in the art. The scope of technical thought is not limited to the following examples. Rather, these embodiments are provided so that this disclosure will be more thorough and complete, and will fully convey the scope of the invention to those skilled in the art. As used herein, the term "and / or" includes any and all combinations of one or more of the listed items. The same reference numerals denote the same elements at all times. Further, various elements and regions in the drawings are schematically drawn. Accordingly, the technical spirit of the present invention is not limited by the relative size or spacing depicted in the accompanying drawings.
The method for producing a Bi 2 Te 3 thermoelectric material according to the present invention includes the steps of preparing a raw material for a Bi 2 Te 3 thermoelectric material containing a Te alloy, forming a Bi 2 Te 3 thermoelectric powder using the thermoelectric material step and sintering of the Bi 2 Te 3 based thermoelectric powder by a step of forming a Bi 2 Te 3 based sintered body.
The Te alloy may include at least one selected from the group consisting of Se, Sn, Sb, and Bi. When Te contains at least one material selected from Se, Sn, Sb, and Bi, the change in carrier concentration and mobility So that a high performance index can be obtained.
The Te alloy may contain 10 ppm to 50 ppm of at least one raw material selected from Se, Sn, Sb and Bi. When the Te alloy contains 10 ppm to 50 ppm of raw material, it has excellent thermoelectric properties (whiteness coefficient, electrical conductivity, and output factor).
The Te alloy may include Se, Sb and Bi, or the Te alloy may include Se, Sb, Sn and Bi.
Particularly, the Te alloy includes 6ppm to 10ppm of Se, 3ppm to 7ppm of Sb and 1ppm to 5ppm of Bi, or the Te alloy contains 13ppm to 17ppm of Se, 6ppm to 10ppm of Sb, 1ppm to 4ppm of Sn, and 7ppm To 11 ppm Bi.
In addition, the step of preparing the raw material for thermoelectric material may control the content of the raw material to be contained by using the zone refining process of Te. The zone refining process is a refining method for improving the purity. Alternatively, the content of the raw material can be adjusted by moving a locally generated melting zone to collect a small amount of raw material toward the end of the specimen.
The step of forming the thermoelectric powder may be performed by charging the thermoelectric material and the Zr ball together in a high energy milling apparatus and milling the same. As a milling condition, the milling vessel and the ball can be milled for 70 to 110 minutes at a rotational speed of 900RPM to 1300RPM using Zr. In this case, water cooling can be performed during the entire milling process to minimize the internal heat of the milling vessel caused by the high rotation speed.
The step of forming the sintered body may be performed using a spark plasma sintering (SPS) method. The sintering conditions can be sintered at a temperature raising rate of 30 to 50 ° C per minute at a sintering temperature of 300 ° C to 500 ° C at a pressure of 40 MPa to 60 MPa.
The shaped body made of SPS can increase the density and inhibit the grain growth to produce a sample with fine grain. This can have excellent mechanical properties such as density and hardness, and can also improve thermoelectric performance by decreasing thermal conductivity by phonon scattering.
The Bi 2 Te 3 thermoelectric material may be Bi 2 Te 3 and / Of Sb 2 Te 3 Alloys, especially Bi 2 Te 3 and Of Sb 2 Te 3 The alloy composition ratio may be from 20:80 wt% to 30:70 wt%. The Bi 2 Te 3 system The thermoelectric material has a maximum output factor value of 3.5 x 10 -3 (W / K 2 m) and may have a relative density of 99.8% or more and a hardness of 100 Hv to 140 Hv.
A Bi 2 Te 3 thermoelectric device according to the present invention comprises an upper insulating substrate, a lower insulating substrate positioned opposite to the upper insulating substrate, an upper electrode patterned on the upper insulating substrate, A p-type thermoelectric element disposed in contact with the upper electrode and the lower electrode, and an n-type thermoelectric element positioned in contact with the upper electrode and the lower electrode and alternating with the p-type thermoelectric element, The p-type thermoelectric element, the n-type thermoelectric element, or both may include the thermoelectric material described above.
Hereinafter, an experimental example using the method of manufacturing a thermoelectric material according to an embodiment of the present invention will be described.
1. Design of telemium (Te) containing trace amounts of raw materials
P-type Bi 2 Te 3 In order to confirm the thermoelectric properties of the thermoelectric material according to the content of the raw material contained in the main raw material, telenium, a trace amount of the raw material was included. Table 1 shows the amounts of raw materials and raw materials contained in the prepared telenium.
2. Bi 2 Te 3 Preparation and sintering of thermoelectric material powder
The above-prepared telenium was made into a thermoelectric material powder of 75% Sb 2 Te 3 + 25% Bi 2 Te 3 together with Bi and Sb of the same purity using a planetary mill (P100) . The prepared powders were each prepared in the form of a disk.
3. Bi 2 Te 3 Phase analysis of thermoelectric materials
1 is an XRD analysis graph of a Bi 2 Te 3 alloy powder and SPS sintered body according to an amount of raw material contained in telenium according to an embodiment of the present invention. As a result, both of the alloy powder and the sintered body showed Bi 2 Te 3 single phase, and the peak value was not changed with the change of the content of the raw material. In addition, no generation of other peaks was observed, suggesting that impurities were not mixed by the milling and sintering process.
4. Bi 2 Te 3 Thermoelectric Performance Analysis of Sintered Thermoelectric Materials
Hereinafter, thermoelectric characteristics of the Bi 2 Te 3 thermoelectric material sintered body formed by the method of manufacturing a thermoelectric material according to an embodiment of the present invention are analyzed. The thermoelectric performance of the sample was measured with a thermoelectric property evaluation device (TEP-1000, Zephler) after the sintered body was processed into a sample having a size of 3 mm × 3 mm × 10 mm and the electrical conductivity was measured. In addition, the thermal conductivity was measured by processing the sample in the form of a disk having a diameter of 12.7 Ø and a thickness of 1 mm or less.
FIG. 2 is a graph showing the thermoelectric characteristics (whiteness coefficient, electric conductivity, output factor) of the SPS sintered body according to the amount of raw material contained in the telenium according to an embodiment of the present invention. FIG. 2 (a) is a graph showing the whiteness factor according to the content of raw material contained in the telenium. As the temperature increased, the whitening coefficient tended to decrease. In
Here, the scattering coefficient is most influenced by interfaces such as crystal grain boundaries, and additionally influences such as additives such as nanoparticles and carrier-carrier scattering. Since the samples prepared in this study exhibited the same microstructure and no inclusion of additives or impurities was observed, the difference in the whiteness factor was due to the fact that the change in the carrier concentration caused by the difference in the content of raw materials contained in the telemium affected the whiteness coefficient .
Fig. 2 (b) is a graph showing the electrical conductivity of the sample according to the content of raw material contained in the telenium. Electrical conductivity showed a tendency to decrease under all conditions with increasing temperature, and
The electrical conductivity can be expressed as the product of the unit charge, the carrier concentration, and the mobility.
Similar to the previous whiteness coefficient, the other conditions and characteristics were the same except for the raw material content of telemium in all samples. This difference in electrical conductivity is due to the fact that the raw material content in the telemium, that is, the trace amount of raw material contained in the initial telemium influenced the internal carrier concentration and mobility.
FIG. 2 (c) is a graph showing the power factor calculated using the measured whiteness coefficient and electrical conductivity. The output factor showed the same tendency as the decreasing metal or degenerate semiconductor with increasing the measuring temperature and showed the best value in the
3 is a graph showing the thermal conductivity of the SPS sintered body according to the amount of raw material contained in the telemium according to an embodiment of the present invention. The thermal conductivity increased with increasing temperature in all the samples. The lowest value was obtained in the
In general, the overall thermal conductivity of a sample can be expressed as the sum of the thermal conductivity by carriers and the thermal conductivity by phonons.
No differences were observed except for the carrier characteristics under all conditions. The difference in thermal conductivity is considered to be due to the increase or decrease in carrier concentration and mobility.
FIG. 4 is a graph showing the thermoelectric performance index (ZT) of the SPS sintered body according to the amount of raw material contained in the telenium according to an embodiment of the present invention. to be. The thermoelectric performance showed a higher value in the
This tendency is accompanied by changes in carrier concentration and mobility due to trace amounts of raw materials (Se, Sb, Sn, Bi) contained in the initial telemium as shown in the previous results, Coefficient of conduct, electrical conductivity, and thermal conductivity).
5. Bi 2 Te 3 Application of thermoelectric materials
5 is a schematic view showing a
The upper insulating
The p-type
The
As described above, it is possible to produce a P-type Bi 2 Te 3 thermoelectric material having a thermoelectric performance higher than that of the telemium containing a trace amount of raw material and containing no trace amount of raw material. Further, the Bi 2 Te 3 thermoelectric material including the trace amount of the above-mentioned telenium exhibits a Bi 2 Te 3 single phase, has a fine grain size and a uniform grain size to improve the mechanical properties and reduce the thermal conductivity by phonon scattering The thermoelectric performance can be improved. In addition, the Bi 2 Te 3 thermoelectric material containing a trace amount of the above-mentioned telangium has an output factor value of maximum PF = 3.5 × 10 -3 (W / K 2 m).
It will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the spirit or scope of the invention as defined in the appended claims. Will be apparent to those of ordinary skill in the art.
100: thermoelectric device, 110: upper insulating substrate, 120: lower insulating substrate,
130: upper electrode, 140: lower electrode, 150: p-type thermoelectric element,
160: n-type thermoelectric element, 170: lead electrode
Claims (11)
Forming a Bi 2 Te 3 thermoelectric powder using the thermoelectric material; And
The process for producing a sintering of the Bi 2 Te 3 based thermoelectric powder for forming a Bi 2 Te 3 based sintered body, Bi 2 Te 3 based thermoelectric material.
The Te alloy, method of producing a Bi 2 Te 3 based thermoelectric material containing at least one element selected from Se, Sn, Sb and Bi.
The method of the Se, Sn, Sb, and, Bi 2 Te 3 based thermoelectric material containing 10ppm to 50ppm at least one element selected from Bi.
The Te alloy is the production of Se, Sb and, Bi 2 Te 3 based thermoelectric material containing Bi.
The Te alloy is 6ppm to method of producing a Bi 2 Te 3 based thermoelectric material containing 10ppm of the Se, to 3ppm 7ppm of Sb and Bi of 1ppm to 5ppm.
The Te alloy is the production of Se, Sb, Sn and, Bi 2 Te 3 based thermoelectric material containing Bi.
The Te alloy is 13ppm to 17ppm of the Se, to 6ppm, Bi 2 Te 3 based method for producing a thermoelectric material containing Sb, to 1ppm 4ppm of Sn and Bi of 7ppm to about 11ppm of 10ppm.
A method for manufacturing a Bi 2 Te 3 thermoelectric material, comprising charging a raw material for thermoelectric material and a Zr ball together in a high energy milling device and milling the same.
A method for producing a Bi 2 Te 3 based thermoelectric material, which is carried out using a spark plasma sintering (SPS) method.
The Bi 2 Te 3 -based thermoelectric material includes Bi 2 Te 3 and Of Sb 2 Te 3 , Bi 2 Te 3 based method for producing a thermoelectric material containing an alloy.
The Bi 2 Te 3 and / Of Sb 2 Te 3 Alloy composition ratio is 20:80 wt% to 30:70 wt% is, Bi 2 Te 3 based method for producing a thermoelectric material.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2018080085A1 (en) * | 2016-10-31 | 2018-05-03 | 주식회사 엘지화학 | Chalcogenide compound, production method thereof and thermoelectric element comprising same |
KR20180094533A (en) | 2017-02-15 | 2018-08-24 | 공주대학교 산학협력단 | Manufacturing method of large area sintered alloy for Bi-Sb-Te system and large area sintered alloy for Bi-Sb-Te system using the same |
KR101892394B1 (en) | 2017-07-12 | 2018-08-28 | 공주대학교 산학협력단 | Manufacturing method of Bi-Te system sintered alloy and Bi-Te system sintered alloy using the same |
US11276809B2 (en) | 2016-10-31 | 2022-03-15 | Lg Chem, Ltd. | Chalcogen-containing compound, its preparation method and thermoelectric element comprising the same |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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KR100440268B1 (en) | 2001-04-21 | 2004-07-30 | 김창선 | The method for manufacturing of thermocouple material |
KR101468991B1 (en) | 2013-06-17 | 2014-12-04 | 공주대학교 산학협력단 | Thermoelectric material, method of manufacturing the same, thermoelectric device having the same |
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KR100440268B1 (en) | 2001-04-21 | 2004-07-30 | 김창선 | The method for manufacturing of thermocouple material |
KR101468991B1 (en) | 2013-06-17 | 2014-12-04 | 공주대학교 산학협력단 | Thermoelectric material, method of manufacturing the same, thermoelectric device having the same |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018080085A1 (en) * | 2016-10-31 | 2018-05-03 | 주식회사 엘지화학 | Chalcogenide compound, production method thereof and thermoelectric element comprising same |
US11276809B2 (en) | 2016-10-31 | 2022-03-15 | Lg Chem, Ltd. | Chalcogen-containing compound, its preparation method and thermoelectric element comprising the same |
KR20180094533A (en) | 2017-02-15 | 2018-08-24 | 공주대학교 산학협력단 | Manufacturing method of large area sintered alloy for Bi-Sb-Te system and large area sintered alloy for Bi-Sb-Te system using the same |
KR101892394B1 (en) | 2017-07-12 | 2018-08-28 | 공주대학교 산학협력단 | Manufacturing method of Bi-Te system sintered alloy and Bi-Te system sintered alloy using the same |
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