KR20160112368A - Colored photosensitive resin composition for green pixel - Google Patents

Abstract

The present invention relates to a colored photosensitive resin composition for green pixel having excellent solvent resistance, a color filter produced by using the same, and a liquid crystal display device comprising the same. The colored photosensitive resin composition comprises: a coloring agent (A); an alkali water-soluble resin (B); a photopolymerizable compound (C); a photopolymerization initiator (D); and a solvent (E).

Description

Technical Field [0001] The present invention relates to a colored photosensitive resin composition for a green-

The present invention relates to a colored photosensitive resin composition for a green color, a color filter manufactured using the same, and a liquid crystal display including the same.

BACKGROUND ART Color filters are widely used in imaging elements, liquid crystal display elements, and the like, and their application range is rapidly expanding. A color filter used for a color liquid crystal display element, an image pickup element, and the like is generally formed by spin coating a colored photosensitive resin composition for a green color containing a colorant corresponding to each color of red, green and blue on a substrate on which a black matrix is pattern- The coating film formed by uniformly applying and then drying by heating (hereinafter also referred to as pre-baking) is exposed and developed, and if necessary, further heat curing (hereinafter also referred to as post-baking) And then repeatedly forming pixels of each color. In recent years, a color filter for a liquid crystal display (LCD) is required to reproduce a high color, and a color coordinate is required to be changed by changing the backlight. For this purpose, there is a demand for a colored photosensitive resin composition for a green color that has good color reproducibility and can easily change the color coordinates when the backlight is changed.

In a color liquid crystal display, a color reproduction range is a range expressed by a triangle connecting the chromatic coordinates of red, green, and blue in the XYZ color system, and is expressed as an area ratio to the National Television System Committee (NTSC) standard. The color reproduction range of the CRT is about 70% of the NTSC standard. The chromaticity coordinates (x, y) in the XYZ color system of red, green, blue, and each of the chromaticity coordinates (x, y) are in the range of 0.670, 0.330 ), Rust (0.210, 0.710), and blue (0.140, 0.080). In the case of a conventional liquid crystal display device of NTSC 72% (EBU standard) or less, the green pixel of the color filter contains C.I. Pigment Green 36 or C.I. Pigment Green 58 was used, and C.I. Pigment Yellow 150 or C.I. Pigment Yellow 138 and the like were combined to form a green pixel. In Digital Cinema Initiatives (DCI), which is required by ITU-R BT.2020 broadcasting standards (chromaticity coordinates (x, y) are 0.708, 0.292, 0.170, 0.797, The chromaticity coordinates (x, y) in Adobe are 0.640 and 0.330, respectively. The chromaticity coordinates (x, y) in Adobe are 0.680, 0.320, 0.265, 0.690 and 0.150, respectively. , Rust (0.210, 0.710), and blue (0.150, 0.060).

Thus, Korean Patent Laid-Open No. 10-2010-0121551 discloses that CI having a high transmittance and contrast ratio as a color material of a green pixel. Pigment Green 58 is used, but the coloring property of CI Pigment Green 58 is low and it is difficult to realize a pixel in a high color reproduction region.

In addition, when a conventional color material is used to form a green pixel of a color filter having a wide color reproducibility in a liquid crystal display device, there is a method of increasing the concentration of the pigment or forming a thick film thickness of the pattern. However, such a method has a problem in that the development speed is slowed and the degree of curing is insufficient, resulting in deterioration of sensitivity and reliability.

Korea Patent Publication No. 2004-0026095

It is an object of the present invention to provide a colored photosensitive resin composition capable of forming a thin film, realizing a wide color reproducibility, and excellent in pattern adhesion and resolution.

It is an object of the present invention to provide a color filter made of the above-mentioned colored photosensitive resin composition for a green color. It is still another object of the present invention to provide a liquid crystal display device having the color filter of the present invention.

The present invention includes a colorant (A), an alkali-soluble resin (B), a photopolymerizable compound (C), a photopolymerization initiator (D) and a solvent (E) Wherein the photopolymerization initiator (D) comprises at least one photopolymerization initiator for generating a phenyl radical.

 [Chemical Formula 1]

Wherein R 1 to R 13 are each independently a hydrogen atom, a halogen atom, an alkyl group which may have a substituent, an alkoxyl group which may have a substituent, an aryl group which may have a substituent, -SO ₃ H, -COOH, -SO ₃ M, -COOM, a phthalimidomethyl group which may have a substituent, or a sulfamoyl group which may have a substituent, M is a monovalent to trivalent metal or alkylammonium, and the adjacent groups of R 1 to R 4 are integral May form an aromatic ring which may have a substituent, and R10 to R13 may form an aromatic ring which may have a substituent, because adjacent groups are integral with each other.

 The present invention provides a color filter comprising a colored layer formed by forming the colored photosensitive resin composition for a green color in a predetermined pattern, followed by exposure and development. Further, an image pickup device and a liquid crystal display device including the color filter of the present invention are provided.

The colored photosensitive resin composition for a green color of the present invention can be patterned with a thin film thickness. Also, it has excellent pattern adhesion and high resolution, which enables fine pattern development.

In addition, by having excellent solvent resistance, it has an advantage suitable for manufacturing a high-quality color filter.

Hereinafter, the present invention will be described in more detail.

In the conventional liquid crystal display device, the method of forming a green pixel of a color filter having a wide color reproducibility has a problem in that the developing speed is slowed and the degree of curing is insufficient, resulting in lower sensitivity and reliability.

In order to solve this problem, the present inventors have found that the above problems can be solved by including a specific compound and a specific photopolymerization initiator in a colored photosensitive composition, and have completed the present invention.

That is, the present invention comprises a colorant (A), an alkali-soluble resin (B), a photopolymerizable compound (C), a photopolymerization initiator (D), and a solvent (E) Wherein the photopolymerization initiator (D) comprises at least one photopolymerization initiator for generating a phenyl radical.

 [Chemical Formula 1]

Wherein R 1 to R 13 are each independently a hydrogen atom, a halogen atom, an alkyl group which may have a substituent, an alkoxyl group which may have a substituent, an aryl group which may have a substituent, -SO ₃ H, -COOH, -SO ₃ M, -COOM, a phthalimidomethyl group which may have a substituent, or a sulfamoyl group which may have a substituent,

M represents a monovalent to trivalent metal or alkylammonium, adjacent groups of R 1 to R 4 may integrate to form an aromatic ring which may have a substituent, and R 10 to R 13 may have an adjacent group and may have a substituent An aromatic ring can be formed.

Hereinafter, the colored photosensitive resin composition for a green color of the present invention will be described in detail by the constituent components.

The colorant (A)

Pigment ( a1 )

Among the colorants of the present invention, the pigment (a1) includes a compound represented by the following formula (1) as an essential component.

First, the compound represented by the following formula (1) will be described.

The compound represented by the following formula (1) is an essential component in the pigment.

[Chemical Formula 1]

Wherein R 1 to R 13 are each independently a hydrogen atom, a halogen atom, an alkyl group which may have a substituent, an alkoxyl group which may have a substituent, an aryl group which may have a substituent, -SO ₃ H, -COOH, -SO ₃ M, -COOM, a phthalimidomethyl group which may have a substituent, or a sulfamoyl group which may have a substituent,

M represents a monovalent to trivalent metal or alkylammonium, adjacent groups of R 1 to R 4 may integrate to form an aromatic ring which may have a substituent, and R 10 to R 13 may have an adjacent group and may have a substituent An aromatic ring can be formed.

Herein, the aromatic rings include hydrocarbon aromatic rings and heteroaromatic rings. The hydrocarbon aromatic ring may include a benzene ring, a naphthalene ring, an anthracene ring, and / or a phenanthrene ring. Examples of the aromatic ring include a pyridine ring, a pyrazine ring, a pyrrole ring, a quinoline ring, a quinoxaline ring, a furan ring, a benzofuran ring, a thiophen ring, a benzothiophene ring, an oxazole ring, a thiazole ring, , Pyrazole rings, indole rings and / or carbazole rings, and the like.

Specifically, the compound represented by the above formula (1) is also referred to as a kinophthalone pigment. Examples of the halogen atom include fluorine, chlorine, bromine and iodine for R1 to R13 in the above formula (1). The alkyl group which may have a substituent includes a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a tert-butyl group, a neopentyl group, Or straight-chain (straight chain) or branched (branched) alkyl group such as 2-ethylhexyl group; In addition to the above, there may be mentioned trichloromethyl, trifluoromethyl, 2,2,2-trifluoroethyl, 2,2-dibromoethyl, 2,2,3,3-tetrafluoropropyl, 2-ethoxyethyl Benzyl group, 4-methylbenzyl group, 4-tert-butylbenzyl group, 4-methoxybenzyl group, 4-nitrobenzyl group and / or 2,4-dichloro And an alkyl group having a substituent such as a benzyl group. Examples of the alkoxyl group which may have a substituent include a methoxy group, an ethoxy group, a propoxy group, an isopropoxy group, a n-butoxy group, an isobutyloxy group, a tert- Straight-chain or branched alkoxyl groups such as dimethyl-3-pentoxy, n-hexyloxy, n-octyloxy, stearyloxy and / or 2-ethylhexyloxy; A trichloromethoxy group, a trifluoromethoxy group, a 2,2,2-trifluoroethoxy group, a 2,2,3,3-tetrafluoropropyloxy group, a 2,2-ditrifluoromethyl group, An alkoxyl group having a substituent such as a propoxy group, a 2-ethoxyethoxy group, a 2-butoxyethoxy group, a 2-nitropropoxy group and / or a benzyloxy group. The aryl group which may have a substituent includes an aryl group such as a phenyl group, a naphthyl group and / or an anthranyl group; In addition to the above, there may be mentioned, in addition to the above-mentioned groups, a p-methylphenyl group, p-bromophenyl group, p-nitrophenyl group, p-methoxyphenyl group, 2,4- Having a substituent such as a 4-hydroxy-1-naphthyl group, a 6-methyl-2-naphthyl group, a 4,5,8-trichloro-2-naphthyl group, an anthraquinonyl group, An aryl group; Examples of the acidic group include -SO3H and -COOH. Examples of the monovalent to trivalent metal salt of the acid group include a sodium salt, a potassium salt, a magnesium salt, a calcium salt, an iron salt and / or an aluminum salt. Examples of the alkylammonium salt of the acidic group include ammonium salts of long chain monoalkylamines such as octylamine, laurylamine and / or stearylamine; Quaternary alkylammonium salts such as palmityltrimethylammonium, dilauryldimethylammonium, distearyldimethylammonium salts and the like. As the substituent in the phthalimido methyl group (C ₆ H ₄ (CO) ₂ N-CH ₂ -) which may have a substituent and the sulfamoyl group (H ₂ NSO ₂ -) which may have such a substituent, , An alkyl group which may have a substituent, an alkoxyl group which may have a substituent and / or an aryl group which may have a substituent.

The compound represented by Formula 1 is contained in an amount of 5 to 70% by weight, preferably 10 to 70% by weight, and more preferably 20 to 60% by weight based on the total weight of the solid content in the colorant (A) have. When the compound represented by the general formula (1) in the colorant (A) is in the above range, the content of the colorant is lowered, thereby preventing the problem of lowering the reliability of the colorant being eluted by the organic solvent.

And may further comprise pigments commonly used in the art.

The pigment may be an organic pigment or an inorganic pigment. As the pigment, various pigments used in printing ink, ink-jet ink and the like can be used. Specifically, the organic pigment is selected from the group consisting of the water-soluble azo pigment, the insoluble azo pigment, the phthalocyanine pigment, the quinacridone pigment, the isoindolinone pigment, the isoindoline pigment, the perylene pigment, the perinone pigment, the dioxazine pigment, An anthanthrone pigment, an indanthrone pigment, a pravanthrone pigment, a pyranthrone pigment and / or a diketopyrrolopyrrole pigment, and the like. Examples of the inorganic pigments include metal compounds such as metal oxides and metal complex salts. Specific examples of the inorganic pigments include metals such as iron, cobalt, aluminum, cadmium, lead, copper, titanium, magnesium, chromium, zinc, antimony and / Oxides or composite metal oxides. These may be used alone or in combination of two or more.

The pigment may include various pigments used in printing ink, ink-jet ink, and the like. Particularly, organic pigments and inorganic pigments are specifically classified as pigments in the Society of Dyers and Colourists, and more specifically, pigments of the following color index (CI) number But the present invention is not limited thereto.

According to one preferred embodiment of the present invention, the coloring agent is selected from the group consisting of C.I. Pigment Yellow 129, C.I. Pigment Yellow 138, Pigment Yellow 139, Pigment Yellow 150, C.I. Pigment Yellow 185 may be further included.

The content of the pigment (a1) is in the range of 10 to 80% by weight, preferably 20 to 50% by weight based on the total weight of the solid content in the colorant (A).

It is preferable to use a pigment dispersion in which the particle diameter of the pigment is uniformly dispersed. An example of a method for uniformly dispersing the particle diameter of the pigment includes a method of dispersing the pigment dispersion (a3) by containing the pigment dispersant (a3). According to this method, a pigment dispersion in which the pigment is uniformly dispersed in a solution can be obtained have.

Specific examples of the pigment dispersant include cationic surfactants, anionic surfactants, nonionic surfactants, amphoteric surfactants, polyester surfactants, and polyamine surfactants. These surfactants may be used singly or in combination of two or more thereof .

Pigment dispersant ( a3 )

The pigment dispersant (a3) is added for maintenance of deagglomeration and stability of the pigment, and any of those generally used in the art can be used without limitation. (Hereinafter referred to as an acrylic dispersant) containing BMA (butyl methacrylate) or DMAEMA (N, N-dimethylaminoethyl methacrylate). At this time, it is preferable to apply the acrylic dispersant prepared by a living control method as disclosed in Korean Patent Publication No. 2004-0014311. DISCLOSURE OF INVENTION It is an object of the present invention to provide an acrylic dispersant, 2000, DISPER BYK-2001, DISPER BYK-2070, and DISPER BYK-2150.

The acrylic dispersants exemplified above may be used alone or in combination of two or more.

As the dispersant (a3), other resin type pigment dispersants other than the acrylic dispersant may be used. The other resin type pigment dispersing agent may be a known resin type pigment dispersing agent, especially a polycarboxylic acid ester such as polyurethane, polyacrylate, unsaturated polyamide, polycarboxylic acid, polycarboxylic acid (partial) Amine salts of polycarboxylic acids, alkylamine salts of polycarboxylic acids, polysiloxanes, long chain polyaminoamide phosphate salts, esters of hydroxyl group-containing polycarboxylic acids and their modified products, or free ) Oil-based dispersants such as amides formed by reaction of a polyester having a carboxyl group with poly (lower alkyleneimine) or salts thereof; Soluble resin or water-soluble polymer compound such as (meth) acrylic acid-styrene copolymer, (meth) acrylic acid- (meth) acrylate ester copolymer, styrene-maleic acid copolymer, polyvinyl alcohol or polyvinylpyrrolidone; Polyester; Modified polyacrylates; Adducts of ethylene oxide / propylene oxide, and phosphate esters. DISPER BYK-161, DISPER BYK-162, DISPER BYK-163, DISPER BYK-160, BYK (trade name) 164, DISPER BYK-166, DISPER BYK-171, DISPER BYK-182, DISPER BYK-184; EFKA-4060, EFKA-4060, EFKA-4055, EFKA-4055, EFKA-4055, EFKA-4020, EFKA-4015, EFKA-4060, EFKA- 4330, EFKA-4400, EFKA-4406, EFKA-4510, EFKA-4800; SOLSPERS-24000, SOLSPERS-32550, NBZ-4204/10 from Lubirzol; Hinoact T-6000, Hinoact T-7000, Hinoact T-8000; available from Kawaken Fine Chemicals; AJISPUR PB-821, Ajisper PB-822, Ajisper PB-823 manufactured by Ajinomoto; FLORENE DOPA-17HF, fluorene DOPA-15BHF, fluorene DOPA-33, and fluorene DOPA-44 are trade names of Kyoeisha Chemical Co., In addition to the acrylic dispersant, other resin type pigment dispersants may be used alone or in combination of two or more, or may be used in combination with acrylic dispersion.

The amount of the dispersant (a3) to be used is in the range of 5 to 60 parts by weight, more preferably 15 to 50 parts by weight, based on 100 parts by weight of the solid content of the pigment (a1). If the content of the dispersant (a3) exceeds 60 parts by weight, the viscosity may be increased. If the content of the dispersant (a3) is less than 5 parts by weight, it may be difficult to atomize the pigment or cause gelation after dispersion.

dyes( a2 )

The present invention may further include the dye (a2) generally used in the art.

The dye can be used without limitation as long as it is soluble or dispersible in an organic solvent. It is preferable to use a dye having solubility in an organic solvent and securing reliability such as solubility, heat resistance and solvent resistance in an alkali developer, and in the case of a dye having no solubility in an organic solvent, have. Examples of the dye include acid dyes having an acidic group such as a sulfonic acid and a carboxylic acid, salts of an acidic dye and a nitrogen-containing compound, sulfonamides of an acidic dye and derivatives thereof, and azo, xanthate, phthalocyanine Based acid dyes and derivatives thereof.

Preferably, the dye is a compound classified as a dye in a color index (published by The Society of Dyers and Colourists), or a known dye described in a dyeing note (coloring yarn). These dyes may be used alone or in combination of two or more.

The content of the colorant (A) is preferably 5 to 60% by weight, more preferably 10 to 50% by weight based on the total weight of the solid content of the colored photosensitive resin composition.

When the colorant (A) is contained in an amount of 5 to 60% by weight based on the above standard, the color density of the pixel is sufficient even when a thin film is formed, and the residue of the non- Do.

In the present invention, the total solid content in the colored photosensitive resin composition means the total content of the remaining components excluding the solvent from the colored photosensitive resin composition.

The alkali-soluble resin (B)

The alkali-soluble resin is a component which imparts solubility to the alkali developing solution used in the developing process and can be used without limitation as long as it is soluble in an alkali developing solution.

In order to dissolve in an alkaline developing solution, a carboxyl group is introduced into the resin to give an acid value. do. By copolymerizing an ethylenically unsaturated monomer (b1) having a carboxyl group or by reacting an acid anhydride with the resin (b2) having a hydroxyl group to give an acid value. At this time, the acid value of the alkali-soluble resin (B) is preferably 30 to 200 mgKOH / g. When the acid value of the alkali-soluble resin (B) is less than 30 mgKOH / g, it is difficult to secure a sufficient developing rate of the colored photosensitive resin composition. When the acid value exceeds 200 mgKOH / g, the adhesion with the substrate is decreased, The coloring material in the colored photosensitive resin composition precipitates or the storage stability of the colored photosensitive resin composition is lowered, and the viscosity tends to rise.

Specific examples of the ethylenically unsaturated monomer (b1) having a carboxyl group include monocarboxylic acids such as acrylic acid, methacrylic acid and crotonic acid; Dicarboxylic acids such as fumaric acid, mesaconic acid and itaconic acid; And anhydrides of these dicarboxylic acids; (meth) acrylates of a polymer having a carboxyl group and a hydroxyl group at both terminals such as? -carboxypolycaprolactone mono (meth) acrylate, and acrylic acid and methacrylic acid are preferable.

A method of reacting an acid anhydride with the resin copolymer (b2) having a hydroxyl group to give an acid value is a method in which an acid anhydride is additionally reacted with a hydroxyacrylate copolymer to give an acid value, but the method is not limited thereto .

The hydroxyacrylates are typically as follows.

(Meth) acrylate, 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, 4-hydroxybutyl Hydroxyethyl (meth) acrylates such as hydroxyethyl acrylamide;

The copolymerizable unsaturated monomers (b3) in the preparation of the alkali-soluble resin (B) are exemplified below, but are not limited thereto.

Specific examples of the copolymerizable unsaturated monomer (b3) include styrene, vinyltoluene,? -Methylstyrene, p-chlorostyrene, o-methoxystyrene, m-methoxystyrene, p- Aromatic vinyl compounds such as benzyl methyl ether, m-vinyl benzyl methyl ether, p-vinyl benzyl methyl ether, o-vinyl benzyl glycidyl ether, m-vinyl benzyl glycidyl ether and p-vinyl benzyl glycidyl ether;

N-cyclohexylmaleimide, N-benzylmaleimide, N-phenylmaleimide, No-hydroxyphenylmaleimide, Nm-hydroxyphenylmaleimide, Np-hydroxyphenylmaleimide, No-methylphenylmaleimide, Nm N-substituted maleimide-based compounds such as methylphenyl maleimide, Np-methylphenyl maleimide, No-methoxyphenyl maleimide, Nm-methoxyphenyl maleimide and Np-methoxyphenyl maleimide;

Propyl (meth) acrylate, n-butyl (meth) acrylate, i-butyl (meth) acrylate, alkyl (meth) acrylates such as sec-butyl (meth) acrylate and t-butyl (meth) acrylate; (Meth) acrylate, cyclopentyl (meth) acrylate, cyclohexyl (meth) acrylate, 2-methylcyclohexyl (meth) acrylate, tricyclo [5.2.1.0 2,6] decan- Alicyclic (meth) acrylates such as dicyclopentanyloxyethyl (meth) acrylate and isobornyl (meth) acrylate;

Aryl (meth) acrylates such as phenyl (meth) acrylate and benzyl (meth) acrylate;

3- (methacryloyloxymethyl) -2-trifluoromethyl oxetane, 3- (methacryloyloxymethyl) oxetane, 3- (methacryloyloxymethyl) 2- (methacryloyloxymethyl) oxetane, 2- (methacryloyloxymethyl) -4-trifluoromethyloxetane, and the like Unsaturated oxetane compounds.

The monomers exemplified as the copolymerizable unsaturated monomers (b3) may be used alone or in combination of two or more.

The content of the alkali-soluble resin (B) is in the range of 10 to 80% by weight, preferably 10 to 70% by weight based on the solid content in the photosensitive resin composition. When the content of the alkali-soluble resin (B) is 10 to 80% by weight based on the above-mentioned criteria, the solubility in a developing solution is sufficient and pattern formation is easy. In the development, film reduction of the pixel portion of the exposed portion is prevented, It is preferable that the dropout property is improved.

Photopolymerization  The compound (C)

The photopolymerizable compound (C) is a compound capable of polymerizing under the action of the photopolymerization initiator (D) described below, and a monofunctional monomer, a bifunctional monomer or a polyfunctional monomer can be used, and preferably a bifunctional or more polyfunctional monomer Can be used.

Specific examples of the monofunctional monomer include nonylphenylcarbitol acrylate, 2-hydroxy-3-phenoxypropyl acrylate, 2-ethylhexylcarbitol acrylate, 2-hydroxyethyl acrylate or N- But are not limited thereto.

Specific examples of the bifunctional monomer include 1,6-hexanediol di (meth) acrylate, ethylene glycol di (meth) acrylate, neopentyl glycol di (meth) acrylate, triethylene glycol di (meth) , Bis (acryloyloxyethyl) ether of bisphenol A or 3-methylpentanediol di (meth) acrylate, but are not limited thereto.

Specific examples of the polyfunctional monomer include trimethylolpropane tri (meth) acrylate, ethoxylated trimethylolpropane tri (meth) acrylate, propoxylated trimethylolpropane tri (meth) acrylate, pentaerythritol tri (Meth) acrylate, pentaerythritol tetra (meth) acrylate, dipentaerythritol penta (meth) acrylate, ethoxylated dipentaerythritol hexa (meth) acrylate, propoxylated dipentaerythritol hexa ) Acrylate or dipentaerythritol hexa (meth) acrylate, but are not limited thereto.

The photopolymerizable compound (C) is preferably contained in an amount of 5 to 45% by weight, more preferably 7 to 45% by weight based on the solid content in the colored photosensitive resin composition. When the photopolymerizable compound (C) is contained in an amount of 5 to 45% by weight based on the above-mentioned criteria, the strength and smoothness of the pixel portion are preferably improved.

Light curing Initiator (D)

The photopolymerization initiator (D) in the present invention generates radicals capable of initiating polymerization of the photopolymerizable compound (C) by exposure to radiation such as visible light, ultraviolet light, far ultraviolet light, electron beam and / .

In the present invention, the photopolymerization initiator comprises at least one photopolymerization initiator in which a phenyl radical is generated as an essential component. In the case of the photopolymerization initiator in which the phenyl radical is generated, the photocuring can be efficiently performed even in a small amount, and the pattern adhesion is excellent. Thus, there is no short circuit in the development process, A photosensitive resin composition can be provided.

The photopolymerization initiator in which the phenyl radical is generated may be selected from PBG-305 of Tronisan and OXE-01 of BASF.

On the other hand, conventionally, by including only a photopolymerization initiator generally used, the adhesion of the pattern is lowered, and formation of a fine pattern is not easy.

However, in the present invention, by including the photopolymerization initiator as described above, not only the pattern adhesion of the pattern is improved but also the formation of the fine pattern is easy. In addition, the color filter manufactured using the colored photosensitive composition of the present invention exhibits excellent resolution.

According to a preferred embodiment of the present invention, at least one photopolymerization initiator for generating the phenyl radical may include 10 to 100% by weight, preferably 30 to 80% by weight, based on the total weight of the photopolymerization initiator %. ≪ / RTI > If the amount is less than 10% by weight, the adhesion may deteriorate due to the reduction of the resist.

According to a preferred embodiment of the present invention, the photopolymerization initiator is at least one selected from the group consisting of an acetophenone compound, a benzophenone compound, a nonimidazole compound, a triazine compound, an oxime ester compound and a thioxanone compound May further include at least one selected from the group consisting of oxime ester compounds.

Specific examples of the acetophenone-based compound include diethoxyacetophenone, 2-hydroxy-2-methyl-1-phenylpropan-1-one, benzyldimethylketal, 2-hydroxy- 1- [4- 2-methyl-1- (4-methylthiophenyl) -2-morpholinopropane-1-one, 2-methylcyclohexyl phenyl ketone, 2-methyl-1- [4- (1-methylvinyl) phenyl] propane-1-one 2- (4-methylbenzyl) -2- (dimethylamino) -1- (4-morpholinophenyl) butan-1-one.

Examples of the benzophenone compound include benzophenone, methyl 0-benzoylbenzoate, 4-phenylbenzophenone, 4-benzoyl-4'-methyldiphenylsulfide, 3,3 ', 4,4'-tetra tert-butylperoxycarbonyl) benzophenone, 2,4,6-trimethylbenzophenone, and the like.

Specific examples of the imidazole compound include 2,2'-bis (2-chlorophenyl) -4,4 ', 5,5'-tetraphenylbimidazole, 2,2'-bis (2,3- Phenyl) -4,4 ', 5,5'-tetraphenylbiimidazole, 2,2'-bis (2-chlorophenyl) -4,4', 5,5'-tetra (alkoxyphenyl) , 2,2'-bis (2,6-dichlorophenyl) -4,4 ', 5,5'-tetra (trialkoxyphenyl) Imidazole compounds in which 4'5,5'-tetraphenyl-1,2'-biimidazole or phenyl groups at 4,4 ', 5,5' positions are substituted by carboalkoxy groups. Among them, 2,2'-bis (2-chlorophenyl) -4,4 ', 5,5'-tetraphenylbiimidazole, 2,2'-bis (2,3- , 2,2-bis (2,6-dichlorophenyl) -4,4'5,5'-tetraphenyl-1,2'-biimidazole is preferably used do.

Specific examples of the triazine compound include 2,4-bis (trichloromethyl) -6- (4-methoxyphenyl) -1,3,5-triazine, 2,4-bis (trichloromethyl) -6 - (4-methoxynaphthyl) -1,3,5-triazine, 2,4-bis (trichloromethyl) -6-piperonyl-1,3,5-triazine, (Trichloromethyl) -6- [2- (5-methylfuran-2- (4-methoxystyryl) -1,3,5-triazine, Yl) ethenyl] -1,3,5-triazine, 2,4-bis (trichloromethyl) -6- [2- (furan- , 2,4-bis (trichloromethyl) -6- [2- (4-diethylamino-2-methylphenyl) ethenyl] -1,3,5-triazine, 2,4- ) -6- [2- (3,4-dimethoxyphenyl) ethenyl] -1,3,5-triazine.

Examples of the thioxanthone compound include 2-isopropylthioxanthone, 2,4-diethylthioxanthone, 2,4-dichlorothioxanthone, 1-chloro-4- .

The photopolymerization initiator (D) may further include a photopolymerization initiator (d1) to improve the sensitivity of the colored photosensitive resin composition of the present invention. The colored photosensitive resin composition according to the present invention contains a photopolymerization initiation auxiliary (d1), so that the sensitivity is further increased and the productivity can be improved.

As the photopolymerization initiation assistant (d1), for example, at least one compound selected from the group consisting of an amine compound, a carboxylic acid compound, and an organic sulfur compound having a thiol group can be preferably used.

As the amine compound, an aromatic amine compound is preferably used. Specific examples of the amine compound include aliphatic amine compounds such as triethanolamine, methyldiethanolamine and triisopropanolamine, methyl 4-dimethylaminobenzoate, ethyl 4-dimethylaminobenzoate, 4- Dimethylaminobenzoic acid, 2-ethylhexyl 4-dimethylaminobenzoate, 2-dimethylaminoethyl benzoate, N, N-dimethylparatoluidine, 4,4'-bis (dimethylamino) benzophenone ), 4,4'-bis (diethylamino) benzophenone, and the like.

The carboxylic acid compound is preferably an aromatic heteroacetic acid, and more specifically, it is preferably an aromatic heteroaromatic acid such as phenylthioacetic acid, methylphenylthioacetic acid, ethylphenylthioacetic acid, methylethylphenylthioacetic acid, dimethylphenylthioacetic acid, methoxyphenylthioacetic acid, dimethoxyphenylthio Acetic acid, chlorophenylthioacetic acid, dichlorophenylthioacetic acid, N-phenylglycine, phenoxyacetic acid, naphthylthioacetic acid, N-naphthylglycine, naphthoxyacetic acid and the like.

Specific examples of the organic sulfur compound having a thiol group include 2-mercaptobenzothiazole, 1,4-bis (3-mercaptobutyryloxy) butane, 1,3,5-tris (3-mercaptobutyloxyethyl) 1,3,5-triazine-2,4,6 (1H, 3H, 5H) -thione, trimethylolpropane tris (3-mercaptopropionate), pentaerythritol tetrakis (3-mercaptopropionate), dipentaerythritol hexacis (3-mercaptopropionate), and tetraethylene glycol bis (3-mercaptopropionate) .

The photopolymerization initiator (D) is used in an amount of 0.1 to 40% by weight based on the total weight of solids of the colored photosensitive resin composition of the present invention, relative to the content of the alkali-soluble resin (B) and the photopolymerizable compound (C) By weight to 1% by weight to 30% by weight. When the photopolymerization initiator (D) is in the range of 0.1 to 40 wt%, the colored photosensitive resin composition is highly sensitized and the exposure time is shortened, which is preferable because productivity can be improved and high resolution can be maintained. Further, the strength of the pixel portion formed using the composition of the above-described conditions and the smoothness of the surface of the pixel portion can be improved.

In the case of the photopolymerization initiator (d1), the photopolymerization initiator should contain 10 to 100% by weight, preferably 20 to 100% by weight of the total photopolymerization initiator. When the proportion of (d1) in the total photopolymerization initiator is less than 10% by weight, the sensitivity deterioration due to the dye can not be overcome and the pattern is likely to be short-circuited during the development process.

When the photopolymerization initiator (d1) is further used, the photopolymerization initiator (d1) is added to the alkali-soluble resin (B) and the photopolymerizable compound C to 0.1 to 40% by weight, preferably 1 to 30% by weight, based on the total weight of the composition. When the amount of the photopolymerization initiator (d1) used is within the range of 0.1 to 40% by weight, the sensitivity of the colored photosensitive resin composition becomes higher and the productivity of the color filter formed using the composition is improved.

Solvent (E)

As long as the solvent (E) is effective for dissolving other components contained in the colored photosensitive resin composition, a solvent used in a conventional colored photosensitive resin composition can be used without particular limitation, and in particular, an ether, an aromatic hydrocarbon, Alcohols, esters, amides and the like are preferable.

The solvent (E) specifically includes ethylene glycol monoalkyl ethers such as ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, and ethylene glycol monobutyl ether,

Diethylene glycol dialkyl ethers such as diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol dipropyl ether and diethylene glycol dibutyl ether,

Ethylene glycol alkyl ether acetates such as methyl cellosolve acetate and ethyl cellosolve acetate,

Alkylene glycol alkyl ether acetates such as propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate, methoxybutyl acetate and methoxypentyl acetate,

Aromatic hydrocarbons such as benzene, toluene, xylene, and mesitylene,

Ketones such as methyl ethyl ketone, acetone, methyl amyl ketone, methyl isobutyl ketone and cyclohexanone,

Alcohols such as ethanol, propanol, butanol, hexanol, cyclohexanol, ethylene glycol and glycerin,

Esters such as ethyl 3-ethoxypropionate and methyl 3-methoxypropionate, and cyclic esters such as? -Butyrolactone.

The solvent (E) is preferably an organic solvent having a boiling point of 100 ° C to 200 ° C on the application and drying surface, more preferably propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, cyclohexanone, ethyl lactate , Butalactate, ethyl 3-ethoxypropionate, methyl 3-methoxypropionate, and the like.

These solvents (E) may be used alone or in combination of two or more. And 60 to 90% by weight, preferably 70 to 85% by weight, based on the total weight of the colored photosensitive resin composition of the present invention. When the solvent (F) is in the range of 60 to 90% by weight as described above, when the solvent (F) is applied by a coating apparatus such as a roll coater, a spin coater, a slit and spin coater, a slit coater Thereby providing an effect of improving the property.

Additive (F)

The photosensitive resin composition for a green color of the present invention may contain additives (F) such as fillers, other polymer compounds, curing agents, adhesion promoters, ultraviolet absorbers, and anti-aggregation agents according to the needs of those skilled in the art, Can be used in combination.

The filler may be glass, silica, alumina, or the like, but is not limited thereto.

Specific examples of the other polymer compound include a curable resin such as an epoxy resin and a maleimide resin, a thermoplastic resin such as polyvinyl alcohol, polyacrylic acid, polyethylene glycol monoalkyl ether, polyfluoroalkyl acrylate, polyester, polyurethane and the like But is not limited thereto.

The curing agent is used for increasing the curing depth and mechanical strength. Specifically, an epoxy compound, a polyfunctional isocyanate compound, a melamine compound, and an oxetane compound may be used, but the present invention is not limited thereto. Specific examples of the epoxy compound include epoxy resins such as bisphenol A epoxy resin, hydrogenated bisphenol A epoxy resin, bisphenol F epoxy resin, hydrogenated bisphenol F epoxy resin, novolak epoxy resin, other aromatic epoxy resin, alicyclic epoxy resin, Alicyclic or aromatic epoxy compounds, butadiene (co) polymeric epoxides, isoprene (co) polymers other than the brominated derivatives, epoxy resins and brominated derivatives of such epoxy resins, A polymeric epoxide, a glycidyl (meth) acrylate (co) polymer, and triglycidylisocyanurate, but are not limited thereto. Specific examples of the oxetane compound include, but are not limited to, carbonate bisoxetane, xylene bisoxetane, adipate bisoxetane, terephthalate bisoxetane, and cyclohexanedicarboxylic acid bisoxetane. It is not.

The curing agent may be used together with a curing agent in combination with a curing auxiliary compound capable of ring-opening polymerization of the epoxy group of the epoxy compound and the oxetane skeleton of the oxetane compound. Specific examples of the curing auxiliary compound include polyvalent carboxylic acids, polyvalent carboxylic anhydrides, and acid generators. The carboxylic acid anhydrides may be those commercially available as an epoxy resin curing agent. Examples of commercially available epoxy resin curing agents include trade name (ADEKA HARDONA EH-700) (ADEKA INDUSTRIAL CO., LTD.), Trade name (RICACIDO HH) (Manufactured by Shin-Etsu Chemical Co., Ltd.).

The curing agent and the curing auxiliary compound exemplified above may be used alone or in combination of two or more.

Specific examples of the adhesion promoter include vinyltrimethoxysilane, vinyltriethoxysilane, vinyltris (2-methoxyethoxy) silane, N- (2-aminoethyl) -3-aminopropylmethyldimethoxysilane, N Aminopropyltrimethoxysilane, 3-aminopropyltriethoxysilane, 3-glycidoxypropyltrimethoxysilane, 3-glycidoxypropylmethyldimethoxysilane, 2- (2-aminoethyl) (3,4-epoxycyclohexyl) ethyltrimethoxysilane, 3-chloropropylmethyldimethoxysilane, 3-chloropropyltrimethoxysilane, 3-methacryloxypropyltrimethoxysilane, 3- Methoxysilane, 3-isocyanatepropyltrimethoxysilane, and 3-isocyanatepropyltriethoxysilane, or a mixture thereof.

The adhesion promoter may be included in an amount of 0.01 to 10 parts by weight, preferably 0.05 to 2 parts by weight, based on 100 parts by weight of the solid content of the composition.

Specific examples of the ultraviolet absorber include, but are not limited to, 2- (3-tert-butyl-2-hydroxy-5-methylphenyl) -5-chlorobenzothiazole and alkoxybenzophenone.

The anti-aggregation agent may be, for example, sodium polyacrylate, but is not limited thereto.

The process for producing the colored photosensitive resin composition of the present invention will be described as follows.

First, the pigment (a1) in the colorant (A) is mixed with the solvent (F) and dispersed using a bead mill or the like until the average particle diameter of the pigment becomes about 0.2 μm or less. At this time, if necessary, the pigment dispersant (a3), part or all of the alkali-soluble resin (B), or (a2) the dye may be dissolved or dispersed by mixing with the (E) solvent.

The dye (a2), the remainder of the alkali-soluble resin (B), the photopolymerizable compound (C), the photopolymerization initiator (D) and, if necessary, the solvent (E) To prepare a colored photosensitive resin composition.

The present invention provides a color filter comprising a color layer formed by forming the colored photosensitive resin composition of the present invention in a predetermined pattern, followed by exposure and development. Further, an image pickup device and a liquid crystal display device including the color filter of the present invention are provided.

The color filter, the image pickup device, and the liquid crystal display device of the present invention may be manufactured by a known method.

Another aspect of the present invention is a method for manufacturing a color filter, comprising: applying a colored photosensitive resin composition of the present invention; Selectively exposing a part of the colored photosensitive resin composition; And removing the exposed region or the non-exposed region of the colored photosensitive resin composition. The present invention also provides a method for forming a pattern of a colored photosensitive resin composition.

Hereinafter, the present invention will be described in more detail with reference to examples. However, the embodiments of the present invention described below are illustrative only and the scope of the present invention is not limited to these embodiments. The scope of the present invention is indicated in the claims, and moreover, includes all changes within the meaning and range of equivalency of the claims. In the following Examples and Comparative Examples, "%" and "part" representing the content are based on weight unless otherwise specified.

Preparation of pigment dispersion composition

<Pigment dispersion composition M1>

C.I. , Pigment Green 7 (12.0 parts by weight) as a pigment dispersant, 4.0 parts by weight of DISPERBYK-2001 (manufactured by BYK) and 84 parts by weight of propylene glycol methyl ether acetate as a solvent were mixed / dispersed for 12 hours by a bead mill to prepare a pigment dispersion M1 .

<Pigment dispersion composition M2>

, 12.0 parts by weight of a pigment represented by the following formula (2), 4.0 parts by weight of DISPERBYK-2001 (BYK) as a pigment dispersant, and 84 parts by weight of propylene glycol methyl ether acetate as a solvent were mixed / dispersed for 12 hours by a bead mill, Dispersion M2 was prepared.

(2)

<Pigment-dispersed composition M3>

As ryangbu, pigment dispersant of CI Pigment Yellow 138 12.0 as a pigment DISPERBYK-2001 (BYK Co., Ltd.) 4.0 parts by weight, and propylene glycol methyl ether acetate 84 parts by weight of a mixed / dispersed for 12 hours by a bead mill as a solvent, the pigment dispersion M3 .

<Pigment-dispersed composition M4>

12.0 parts by weight of CI Pigment Yellow 150 as a pigment, 4.0 parts by weight of DISPERBYK-2001 (manufactured by BYK) as a pigment dispersant, and 84 parts by weight of propylene glycol methyl ether acetate as a solvent were mixed / dispersed for 12 hours by a bead mill to prepare a pigment dispersion M4 .

Synthesis of alkali-soluble resin

&Lt; Synthesis Example 1 &

A flask equipped with a stirrer, a thermometer reflux condenser, a dropping funnel and a nitrogen inlet tube was charged with 120 parts of propylene glycol monomethyl ether acetate, 80 parts of propylene glycol monomethyl ether, 2 parts of AIBN, 13.0 parts of acrylic acid, 10 parts of benzyl methacrylate, 57.0 parts of styrene, 20 parts of methyl methacrylate and 3 parts of n-dodecylmercapto were charged and replaced with nitrogen. Thereafter, the temperature of the reaction solution was elevated to 110 DEG C with stirring, and the reaction was carried out for 6 hours. The alkali-soluble resin thus synthesized had a solid dispersion value of 100.2 mgKOH / g and a weight average molecular weight Mw of about 15110 as measured by GPC.

Preparation of colored photosensitive resin composition

&Lt; Example 1 >

19.72 parts of the pigment dispersion composition M1, 19.42 parts of the pigment dispersion composition M2, 12.37 parts of the resin of Synthesis Example 1, 4.12 parts of KAYARAD DPHA (manufactured by Nippon Kayaku), 0.82 part of PBG-305 , And 45.56 parts of propylene glycol monomethyl ether acetate were mixed to prepare a colored photosensitive resin composition.

&Lt; Example 2 >

<Pigment dispersion composition M1> 17.65 parts, <Pigment dispersion composition M2> 15.79 parts, <Pigment dispersion composition M3> 8.36 parts, 11.35 parts of resin of <Synthesis example 1>, 3.78 parts of KAYARAD DPHA (manufactured by Nippon Kayaku Co.) -305 (manufactured by Tronis Inc.), and 42.31 parts of propylene glycol monomethyl ether acetate were mixed to prepare a colored photosensitive resin composition.

&Lt; Example 3 >

19.72 parts of the pigment dispersion composition M1, 19.42 parts of the pigment dispersion composition M2, 12.37 parts of the resin of Synthesis Example 1, 4.12 parts of KAYARAD DPHA (manufactured by Nippon Kayaku Co., Ltd.), 0.82 parts of OXE-01 , And 45.56 parts of propylene glycol monomethyl ether acetate were mixed to prepare a colored photosensitive resin composition.

<Example 4>

<Pigment dispersion composition M1>, <Pigment dispersion composition M2> 15.79 parts, <Pigment dispersion composition M3> 8.36 parts, <Synthetic example 1> 11.35 parts, KAYARAD DPHA (manufactured by Nippon Kayaku Co., Ltd.) 3.78 parts, OXE -01 (manufactured by BASF), 0.76 part,

&Lt; Comparative Example 1 &

19.42 parts of the pigment dispersion composition M1, 19.42 parts of the pigment dispersion composition M2, 12.37 parts of the resin of Synthesis Example 1, 4.12 parts of KAYARAD DPHA (manufactured by Nippon Kayaku), 0.82 parts of IRGACURE (R) 369 And 45.56 parts of propylene glycol monomethyl ether acetate were mixed to prepare a colored photosensitive resin composition.

&Lt; Comparative Example 2 &

23.28 parts of the pigment dispersion composition M1, 23.28 parts of the pigment dispersion composition M4, 11.11 parts of the resin of Synthesis Example 1, 3.7 parts of KAYARAD DPHA (manufactured by Nippon Kayaku Co., Ltd.), 0.74 parts of PBG-305 , And 41.58 parts of propylene glycol monomethyl ether acetate were mixed to prepare a colored photosensitive resin composition

&Lt; Comparative Example 3 &

23.28 parts of the pigment dispersion composition M1, 23.28 parts of the pigment dispersion composition M4, 11.11 parts of the resin of Synthesis Example 1, 3.7 parts of KAYARAD DPHA (manufactured by Nippon Kayaku Co., Ltd.), 0.75 parts of IRGACURE (R) 369 And 41.58 parts of propylene glycol monomethyl ether acetate were mixed to prepare a colored photosensitive resin composition

Experimental Manufacturing Example  1: Manufacture of color filters

Using the colored photosensitive resin compositions prepared in Examples 1 to 4 and Comparative Examples 1 to 3, a color filter was prepared so that the chromaticity was x = 0.250 and y = 0.640 in the C light source.

Specifically, each of the above colored photosensitive resin compositions was applied on a 2-inch-square glass substrate ("EAGLE XG", manufactured by Corning Inc.) by spin coating, then placed on a heating plate and held at a temperature of 100 ° C. for 3 minutes to form a thin film . Then, a test photomask having a pattern and a line / space pattern of 1 μm to 100 μm was placed on the thin film and irradiated with ultraviolet rays at a distance of 300 μm from the test photomask. At this time, the ultraviolet light source was irradiated with a high pressure mercury lamp of 1 KW containing g, h and i lines at an illuminance of 80 mJ / cm 2, and no special optical filter was used. The thin film irradiated with ultraviolet rays was immersed in a KOH aqueous solution of pH 10.5 for 80 seconds to develop. The glass plate coated with the thin film was washed with distilled water, dried by blowing nitrogen gas, and heated in a heating oven at 230 ° C for 25 minutes to prepare a color filter.

Experimental Example  One

(1) Measurement of transmittance

The transmittance of a 100 탆 pattern of the substrate prepared in Experimental Preparation Example 1 was measured with a colorimeter (OSP-200 manufactured by Olympus Corporation) and the results are shown in Table 1.

 (2) Measurement of pattern adhesion and resolution

When the pattern produced in Experimental Production Example 2 was evaluated through an optical microscope, the following pattern was evaluated as a degree of peeling, and the results are shown in Table 1 below.

<Evaluation Criteria>

○: No pattern over 30 μm

?: 1 to 3 pattern peelings over 30 占 퐉

X: Pattern peeling over 30 ㎛ 4 or more

(3) Evaluation of resolution

The pattern produced in Experimental Production Example 2 was measured through an optical microscope and the resolution was determined according to the following criteria, and it is shown in Table 1 below.

<Evaluation Criteria>

?: Formation of independent patterns of 10 占 퐉 or less

Δ: When the line width of the pattern of 10 μm or less is excessively enlarged and connected to the neighboring pattern

X: Less than 10 μm pattern loss

 (4) Evaluation of solvent resistance

The chromaticity coordinates of the substrate on which the chromaticity and transmittance of the substrate prepared in Experimental Preparation Example 2 were measured were measured with a colorimeter (OSP-200 manufactured by Olympus Corporation) and the substrate on which the color coordinate measurement was completed was immersed in N-methylpyrrolidone for 30 minutes Respectively. The substrate was taken out, washed with distilled water to measure the chromaticity, and the color difference before and after the immersion in N-methylpyrrolidone was calculated by the following equation (1) (ΔE * ab).

[Equation 1]

^* A ^* b ^* coordinate system chimhu L in the chromaticity coordinate _{^{(L 2 *, a 2 *}} , b 2 *), before immersing the color coordinates _{^{(L 1 * a 1 *,}} b 1 *),

<Evaluation Criteria>

?:? E * ab 3.0 or less

DELTA: DELTA E * ab &gt; 3.0 to 5.0 or less

X: ΔE * ab exceeding 5.0

Pattern adhesion resolution Transmittance Solvent resistance Example 1 ○ ○ 47.3 ○ Example 2 ○ ○ 47.2 ○ Example 3 ○ ○ 47.1 ○ Example 4 ○ ○ 47.4 ○ Comparative Example 1 △ X 47.0 X Comparative Example 2 △ ○ 41.2 △ Comparative Example 3 △ △ 41.1 X

The proportions and contents of the pigment dispersions M1 to M5 were adjusted so that the colored photosensitive resin compositions of the Examples and Comparative Examples had the same color coordinates. The content of the alkali-soluble resin, the photopolymerization initiator and the photopolymerizable compound in Synthesis Example 1 was also adjusted to prepare a colored photosensitive resin composition having the same film thickness.

As can be seen from Table 1, the pattern adhesion of the color filter manufactured using the embodiment is superior to that of the color filter manufactured using the comparative example. In addition, the color filter of the embodiment is superior to the comparative example in resolution, transmittance and / or solvent resistance.

Claims (7)

(A), an alkali-soluble resin (B), a photopolymerizable compound (C), a photopolymerization initiator (D), and a solvent (E)
The colorant (A) comprises a compound represented by the following formula (1)
Wherein the photopolymerization initiator (D) comprises at least one photopolymerization initiator for generating phenyl radicals;
[Chemical Formula 1]

Wherein R 1 to R 13 are each independently a hydrogen atom, a halogen atom, an alkyl group which may have a substituent, an alkoxyl group which may have a substituent, an aryl group which may have a substituent, -SO ₃ H, -COOH, -SO ₃ M, -COOM, a phthalimidomethyl group which may have a substituent, or a sulfamoyl group which may have a substituent,
M represents a monovalent to trivalent metal or alkylammonium, adjacent groups of R 1 to R 4 may integrate to form an aromatic ring which may have a substituent, and R 10 to R 13 may have an adjacent group and may have a substituent An aromatic ring can be formed. The method according to claim 1,
Wherein the colorant (A) further comprises at least one member selected from the group consisting of CI Pigment Yellow 129, 138, 139, 150 and 185. The method according to claim 1,
Wherein the colorant (A) is contained in an amount of 5 to 60% by weight based on the total weight of the solid components in the colored photosensitive resin composition for a green color. The method according to claim 1,
The photopolymerization initiator (D) further comprises at least one member selected from the group consisting of an acetophenone compound, a benzophenone compound, a nonimidazole compound, a triazine compound, and a thioxanone compound A colored photosensitive resin composition for a green color. A color filter comprising a colored layer formed by forming the colored photosensitive resin composition for a green color of claim 1 in a predetermined pattern, followed by exposure and development. An image pickup device comprising the color filter of claim 5. A liquid crystal display element comprising the color filter of claim 5.