KR20160099144A - Hair processing agent and method for perming or dying hair using the same - Google Patents

Abstract

The present invention relates to a hair treatment agent enabling hair to be permed or dyed, and a method for perming the hair using the hair treatment agent, a method for dyeing the hair using the hair treatment agent, or a method for simultaneously perming and dyeing the hair using the hair treatment agent. The hair treatment agent according to the present comprises: 20 to 25 wt% of 2-mercapto-4-butyrolactone; more than 0 to 0.1 wt% or less of disodium EDTA; more than 0 to 0.1 wt% or less of panthenol; more than 0 to 0.1 wt% or less of tocopheryl acetate; 1.0 to 3.0 wt% of PEG-7-glyceryl cocoate; 1.0 to 4.0 wt% of PPG/PEG-17/6 copolymer; 0.1 to 0.5 wt% of sodium citrate; more than 0 to 0.1 wt% or less of hydrolyzed collagen; more than 0 to 0.1 wt% or less of hydrolyzed keratin; more than 0 to 0.1 wt% or less of citric acid; and a remainder consisting of purified water. The hair treatment agent according to the present invention does not give damage to hair, forms the hair in various forms, enables the hair to be dyed in various colors, and enables a user to simultaneously have procedures of a perm and dyeing the hair. Further, the hair treatment agent according to the present invention is capable of remarkably reducing procedure time, and is capable of obtaining an economic effect due to the cost reduction by removing the necessity of using a second preparation when undergoing the procedure of a perm. Further, the hair treatment agent according to the present invention is capable of improving satisfaction of an operator by preventing an unpleasant smell from being generated during the procedures of a perm or dyeing the hair.

Description

TECHNICAL FIELD [0001] The present invention relates to a hair treatment agent and a method of perming hair dyeing using the hair treatment agent,

The present invention relates to a hair treatment agent capable of perming or dyeing hair, a permanent method of hair using the hair treatment agent, a hair dyeing method, or a method of simultaneously performing hair perming and dyeing.

As the quality of life of modern man has increased, people have become increasingly interested in cosmetics, and dyeing procedures that vary the color of hair or permers to form hair in a straight or wave form have been routinely placed on the public .

Thus, in recent years, many people have undergone permanent surgery and dyeing procedures, or they want to receive them continuously in a short period of time, but they have been observed to seriously damage keratin fibers in the hair.

Permanent treatment of hair is generally carried out by applying a first preparation combined with a reducing agent that reduces the cystine bond in the hair to form a desired shape and then oxidizing the cystine bond to maintain the shape of the formed hair And then applying the second material blended to the hair.

At this time, salts and esters of thioglycolic acid are mainly used as the reducing agent included in the first preparation, and cysteine, cysteamine, thiolactic acid and derivatives thereof are also frequently used. Thioglycolic acid is excellent in the action of forming hair, but it causes an unpleasant odor. Since the action against hair is stronger than that of cysteine, the degree of hair damage is great. And a phenomenon such as breakage of the end, breaking of the end, and breakage occurs.

In addition, the oxidizing agent contained in the second preparation is generally composed of bromate as a main component and hydrogen peroxide as a main component. The bromate has less stimulation to the hair than the hydrogen peroxide, but the treatment time is prolonged and the hair is exposed to the drug for a long time And eventually the hair tends to be damaged. On the other hand, hydrogen peroxide has a strong oxidizing action and can shorten the treatment time, but has a disadvantage that the irritation to the hair is strong and the degree of damage is large and the treatment is likely to be uneven.

Conventional perm medicines used for shaping hair as described above show various side effects such as damage of scalp and hair due to various chemical components, hair loss, atopy, respiratory or skin contact allergies due to odor, and the like.

Korean Patent Laid-Open No. 10-2005-0027846 (permanent solution and permer method using the same) provides a permanent solution containing cysteine or thioglycolic acid and containing at least one composition of ocher powder, soybean powder and mung bean powder Korean Patent Laid-Open No. 10-2000-0002954 (a loess powder composition for removal of impurities from a perm solution) provides a composition for removing the odor of a perm medicine used by mixing a loess powder with a common perm solution. In addition, Korean Patent No. 10-0460197 (composition of the first solution of permanent wave lotion) has a long chain of isoalkyl-amide propyl Dimethylammonium Ethosulfate component similar to the lipid component present in hair And hydrolyzed collagen are added to cysteine, thioglycolic acid salts, an alkaline agent, a moisturizer, a perfume, and purified water to provide a composition for preventing hair damage and improving the efficiency of a wave.

However, the above conventional techniques have a limitation in removing the smell of pharmacologically, and only a part of the composition is used as a natural ingredient, so that the scalp and hair are still damaged. When cysteine is used instead of thioglycolic acid as a reducing agent, It takes a long time and has a posterior heating effect, and a resilient wave can not be maintained for a long time.

On the other hand, the dyes used in hair dyeing can be classified into permanent dyes, semi-permanent dyes, temporary dyes and other dyes depending on how long the dyed colors last.

At this time, the permanent dye is generally referred to as an " oxidative dye ", which is a principle that exhibits color by oxidation of a dye using an oxidative dye. The oxidative permanent stabilizer may be one formulation, but is generally a two-dosage formulation consisting of a dye as a first preparation and an oxidizing agent as a second preparation.

The first formulation contains a dye for coloring, an oxidizing dye precursor and a coupler, and an alkaline agent, such as ammonia and monoethanolamine, which causes oxidation of the hair by swelling the hair and promoting the decomposition of hydrogen peroxide. A chelating agent is also used for the purpose of controlling the oxidation reaction of dyes using a reducing agent or an antioxidant and blocking metal ions. In addition, hair conditioning agents and fragrances such as patty alcohols, surfactants or cationic polymers are included.

The hydrogen peroxide contained in the oxidizing agent as the second agent promotes the oxidative decomposition of the melanin granules of the hair by generating oxygen to brighten the background color of the hair and at the same time the oxidation dye contained in the first preparation is polymerized by oxidation with the oxidizing agent in the hair , And the polymerized dyeing is deposited on the skin of the hair to dye the hair.

However, the alkaline agent contained in the dye 1, especially the first agent, increases the pH to swell the hair, thereby reducing the gloss and gloss of the hair, dissolving the hair component to seriously damage the hair, and generating a unique odor during the dyeing process Which causes irritation to some parts of the body such as the eyes, or discomfort throughout the procedure to both the practitioner and the recipient.

It is an object of the present invention to provide a hair treatment agent which can form the shape of hair into various forms without damaging the hair, enable dyeing with various colors, and does not cause an unpleasant odor during the procedure.

It is still another object of the present invention to provide a permanent method capable of forming hair into various shapes without damaging the hair using the hair treatment agent.

It is still another object of the present invention to provide a dyeing method capable of dyeing hair with various colors without damaging the hair using the hair treating agent.

According to one embodiment of the present invention, 20-25% by weight of 2-mercapto-4-butyrolactone;

Dyssodium dithiae more than 0 and not more than 0.1% by weight;

More than 0 to 0.1% by weight of panthenol;

More than 0 to 0.1% by weight of tocopheryl acetate;

1.0 to 3.0% by weight of phage-7 glyceryl cocoate;

1.0 to 4.0% by weight of a PPy / PPY-17/6 copolymer;

0.1 to 0.5% by weight of sodium citrate;

Hydrolyzed collagen in an amount of more than 0 and not more than 0.1% by weight;

Hydrolyzed keratin 0 to 0.1% by weight or less;

Citric acid not less than 0 and not more than 0.1% by weight; And

And the balance purified water.

The hair treatment agent may further comprise at least one wetting agent selected from the group consisting of paper-6 and propylene glycol in an amount of 3 to 5% by weight.

The hair treatment agent further comprises 0.5 to 1% by weight of at least one surfactant selected from the group consisting of polysorbate-80, laureth-23 and isostearate-25 can do.

The hair treatment agent may further comprise 3.0 to 5.0% by weight of at least one moisturizing agent selected from the group consisting of glycerin, isoprene glycol and dipropylene glycol.

Wherein the hair treatment agent comprises at least one hair conditioning agent selected from the group consisting of guar hydroxypropyl trimonium chloride, polyquatermium-39 and amodimethicone, 2% by weight or less.

The hair treatment agent may further include an appropriate amount of a flavoring agent.

The pH of the hair treatment agent may be 5.3 to 5.6.

According to another embodiment of the present invention, there is provided a hair treatment composition comprising: diluting the hair treatment agent with at least one of water and a treatment;

Applying a diluted hair treatment agent to at least a portion of the hair;

Molding the hair to which the hair treatment agent is applied; And

Washing the hair treatment agent applied to the hair and drying the hair.

In the diluting step, the total amount of at least one of the water and the treatment may be 10 times the volume of the hair treatment agent.

The hair may be firstly heated at 70 to 90 ° C for 5 to 10 minutes, and then heated at 100 to 150 ° C for 5 to 10 minutes.

According to another embodiment of the present invention, there is provided a hair treatment composition comprising: diluting a hair treatment agent with at least one of water and a treatment agent and a dye;

Applying a diluted hair treatment agent to at least a portion of the hair; And

And washing the applied hair treatment agent and drying the hair.

In the diluting step, the total amount of the dye and the at least one of the water and the treatment may be 10 times the volume of the hair treatment agent.

The dye may be at least one selected from the group consisting of coffee, orange juice, and coffee milk.

The method may further include heating the hair at 60 to 70 ° C for 5 to 10 minutes and then allowing the hair to stand at 15 to 25 ° C for 5 to 10 minutes.

According to another embodiment of the present invention, there is provided a hair treatment composition comprising: diluting a hair treatment agent with at least one of water and a treatment agent and a dye;

Applying a diluted hair treatment agent to at least a portion of the hair;

Molding the hair treated with the hair treatment agent; And

There is provided a method of perming and dyeing hair, comprising washing the applied hair treatment agent and drying the hair.

In the diluting step, the total amount of at least one of the water and the treatment and the dye may be 10 times the volume of the hair treatment agent.

The hair may be firstly heated at 70 to 90 ° C for 5 to 10 minutes, and then heated at 100 to 150 ° C for 5 to 10 minutes.

According to the present invention, the shape of the hair can be molded into various shapes without damaging the hair, or the hair can be dyed in various colors.

In addition, according to the present invention, it is possible to simultaneously perform perming and dyeing on hair.

Further, according to the present invention, it is not necessary to use the second material at the time of permanent operation, and the procedure time can be remarkably shortened, and the economic effect can be obtained by cost reduction.

Further, according to the present invention, an unpleasant odor is not generated during perming or dyeing, and the satisfaction of the operator can be improved.

Figs. 1 (a) to 1 (c) are photographs of the hair before and after hair treatment in Experimental Example 2 and before and after drying.
2 (a) and 2 (b) are photographs of the hair before and after hair fading and dyeing in Experimental Example 4.

Hereinafter, preferred embodiments of the present invention will be described. However, the embodiments of the present invention can be modified into various other forms, and the scope of the present invention is not limited to the embodiments described below. Further, the embodiments of the present invention are provided to more fully explain the present invention to those skilled in the art.

The present invention relates to a hair treatment agent capable of perming and / or dyeing hair, a permanent method of hair using the hair treatment agent, a hair dyeing method, or a method of simultaneously performing hair perming and dyeing.

Specifically, according to one embodiment of the present invention, 20-25% by weight of 2-mercapto-4-butyrolactone; Dyssodium dithiae more than 0 and not more than 0.1% by weight; More than 0 to 0.1% by weight of panthenol; More than 0 to 0.1% by weight of tocopheryl acetate; 1.0 to 3.0% by weight of phage-7 glyceryl cocoate; 1.0 to 4.0% by weight of a PPy / PPY-17/6 copolymer; 0.1 to 0.5% by weight of sodium citrate; Hydrolyzed collagen in an amount of more than 0 and not more than 0.1% by weight; Hydrolyzed keratin 0 to 0.1% by weight or less; Citric acid not less than 0 and not more than 0.1% by weight; And the remaining purified water.

The hair treatment agent provided by the present invention is a cyclic mercapto compound, which contains 2-mercapto-4-butyrolactone and can block unpleasant odors.

In addition, the hair treatment agent provided by the present invention may further contain an appropriate amount of a perfume as needed, thereby further blocking the unpleasant odor and providing a variety of fragrance.

The hair treating agent provided by the present invention has a pH of about 5.3 to 5.6, which is a weak acidity, and when the hair is permanently or dyed using the hair treating agent, hair damage can be significantly reduced compared to the conventional weak alkaline hair treating agent.

The hair treatment agent provided in the present invention may optionally include at least one member selected from the group consisting of wetting agents, surfactants, moisturizers, and hair conditioning agents.

Specifically, the hair treatment agent of the present invention may further comprise at least one wetting agent selected from the group consisting of phage-6 and propylene glycol, in an amount of 3 to 5% by weight

The hair treatment agent of the present invention may further contain one or more surfactants selected from the group consisting of polysorbate-80, laureth-23 and isostearate-25 in an amount of 0.5 to 1 wt% %. ≪ / RTI >

The hair treatment agent of the present invention may further comprise 3.0 to 5.0% by weight of at least one moisturizing agent selected from the group consisting of glycerin, isoprene glycol and dipropylene glycol.

The hair treatment agent of the present invention may further comprise at least one hair conditioning agent selected from the group consisting of guar hydroxypropyl trimonium chloride, polyquaternium-39 and amodimethicone. And more preferably 0 to 2% by weight.

The hair treatment agent provided by the present invention contains all of the above-mentioned ingredients in a specific amount, thereby preventing an unpleasant odor from being generated and securing the effect of permitting hair to be pared or stained without damaging it.

According to another embodiment of the present invention, there is provided a method of perming hair using the hair treatment agent provided in the present invention, comprising: diluting the hair treatment agent with at least one of water and a treatment; Applying a diluted hair treatment agent to at least a portion of the hair; Molding the hair to which the hair treatment agent is applied; And washing the hair treatment agent applied to the hair and drying the hair.

The hair treatment agent used in the permanent method of the present invention is the same as described above, which is provided in the present invention as described above.

However, in the permanent method of the present invention, the above-mentioned hair treatment agent is not used as it is, but it may be diluted with at least one of water and a treatment, and then applied to at least a part of hair desired for permanent treatment.

At this time, it is most preferable that the total amount of at least one of the water and the treatment is set to be 10 times the volume of the hair treatment agent, because the hair can be allowed to perform with excellent wave efficiency without damaging the hair.

The amount of the water and the treatment to be used for diluting the hair treatment agent is not particularly limited. For example, a mixture of water and a treatment at a volume ratio of 2 to 3: 1 may be used.

The type of the treatment is not particularly limited, and any commercially available treatment can be used without limitation, but an aqueous treatment can be preferably used.

The perming method of the present invention may optionally perform washing of the hair of the subject who is subject to the perming treatment with only shampoo or running water prior to applying the diluted hair treating agent to the hair.

The type and amount of the shampoo which can be used at this time are not particularly limited, and any shampoo commonly used in the art can be used without limitation, and the amount can also be appropriately used depending on the thickness and amount of the hair.

When the washing of the hair is completed as described above, a step of drying the hair for 5 to 10 minutes using a towel or using a dryer may be performed if necessary.

The perming method of the present invention can perform the step of washing and drying the hair as described above, and then applying the diluted hair treating agent to at least a part of the hair. Thereafter, the diluted hair treating agent- May be molded into various shapes.

The shape and method of shaping the hair are not particularly limited. For example, a hair may be formed by winding all or a part of the hair using an ironing machine, or all or a part of the hair may be pressed using a flatiron, However, the present invention is not limited thereto, and may be molded into various forms by a method commonly used in the art according to the requirements of the physician.

After shaping the hair in the permanent method of the present invention, a step of warming all or part of the hair may be performed. For example, it is preferable to carry out the step of firstly heating the mixture at 70 to 90 ° C for 5 to 10 minutes and then heating the mixture at 100 to 150 ° C for 5 to 10 minutes.

The perming method of the present invention can perform the step of washing and drying the hair treatment agent applied to the hair after warming. At this time, it is preferable that the washing is performed using water flowing without using the shampoo so that the shape of the hair can be maintained.

Conventionally, a method of permitting hair is carried out using a first preparation containing a reducing agent (hereinafter also referred to as a permanent waving first preparation) and a second preparation containing an oxidizing agent (hereinafter also referred to as a permanent waving second preparation) In the present invention, by using the hair treatment agent of the present invention diluted to an appropriate concentration as described above, the hair can be allowed to spread in various forms without being damaged without further processing the second agent.

Therefore, the perming method of the present invention can significantly shorten the procedure time compared to the conventional perming method, and economical effect can be obtained due to the cost reduction due to the unused use of the second material.

According to another embodiment of the present invention, there is provided a hair treatment composition comprising the steps of: diluting the hair treatment agent with at least one of water and a treatment agent and a staining agent; Applying a diluted hair treatment agent to at least a portion of the hair; And washing the applied hair treatment agent and drying the hair.

The hair treatment agent used in the dyeing method of the present invention is the same as described above, which is provided in the present invention as described above.

However, in the dyeing method of the present invention, the hair treatment agent is not used as it is, but it may be diluted with at least one of water and a treatment agent, and then applied to at least a part of the hair desired for permanent treatment.

At this time, it is most preferable that the total amount of the water and the treatment and the total amount of the dye is 10 times the volume of the hair treatment agent, because dyeing can be carried out with a desired color without damaging the hair.

In addition, the amount of the dye and the at least one of the water and the treatment used in diluting the hair treatment agent is not particularly limited. For example, water and a dye are mixed in a volume ratio of 2: 3: 1 Can be used.

The type of the treatment is not particularly limited, and any commercially available treatment can be used without limitation, but an aqueous treatment can be preferably used.

In addition, the dyeing method of the present invention can be applied not only to chemical synthetic dyes generally used conventionally (for example, a product sold in the market in Wella, L'Oreal, Hyo, Milbon or Amos) as a dye, but also coffee, orange juice or Coffee milk and the like are used as a staining agent, it is possible to dye the hair with the inherent color of the foodstuffs, thereby further reducing the degree of damage.

In the dyeing method of the present invention, if necessary, the step of washing the hair of the subject who is to be subjected to the dyeing treatment using only the shampoo or running water may be performed prior to applying the diluted hair treatment agent to the hair.

The type and amount of the shampoo which can be used at this time are not particularly limited, and any shampoo commonly used in the art can be used without limitation, and the amount can also be appropriately used depending on the thickness and amount of the hair.

When the washing of the hair is completed as described above, a step of drying the hair for 5 to 10 minutes using a towel or using a dryer may be performed if necessary.

The dyeing method of the present invention can then perform the step of applying the diluted hair treatment agent to at least a portion of the hair to stain all or part of the hair that has been washed and dried in various colors.

In the dyeing method of the present invention, if necessary, the hair treatment agent may be applied to the hair, followed by heating all or a part of the hair. For example, it is preferable to carry out the step of heating at 60 to 70 ° C for 5 to 10 minutes and then leaving at a room temperature of 15 to 25 ° C for 5 to 10 minutes.

Thereafter, the dyeing method of the present invention can perform a step of washing and drying the diluted hair treatment agent applied to the hair. The cleaning may be performed using a shampoo commonly used in the art and, if necessary, a treatment.

According to another embodiment of the present invention, there is provided a hair treatment composition comprising: diluting a hair treatment agent with at least one of water and a treatment agent and a dye; Applying a diluted hair treatment agent to at least a portion of the hair; Molding the hair treated with the hair treatment agent; And a step of washing the applied hair treatment agent and drying the hair.

The hair treatment agent used in the permanent agent and dyeing method of the present invention is the same as that described above as provided in the present invention as described above.

However, in the dyeing method of the present invention, the hair treatment agent is not used as it is, but it may be diluted with at least one of water and a treatment agent, and then applied to at least a part of the hair desired for permanent treatment.

At this time, it is most preferable that the total amount of the water and the treatment and the total amount of the hair dye is 10 times the volume of the hair treatment agent, because the hair and the dye can be simultaneously performed with high efficiency without damaging the hair.

In addition, the amount of the dye and the at least one of the water and the treatment used in diluting the hair treatment agent is not particularly limited. For example, water and a dye are mixed in a volume ratio of 2: 3: 1 Can be used.

The type of the treatment is not particularly limited, and any commercially available treatment can be used without limitation, but an aqueous treatment can be preferably used. In addition, the dyeing method of the present invention can be applied not only to chemically synthesized hair dye agents (for example, those commercially available from Wella, L'Oreal, Hyoe, Milbon or Amos) conventionally used as a dye, but also coffee, orange juice, Coffee milk and the like are used as a staining agent, it is possible to dye the hair with the inherent color of the foodstuffs, thereby further reducing the degree of damage.

The perming and dyeing method of the present invention can optionally perform a step of washing the hair of the subject and the hair of the subject to be subjected to the dyeing operation before applying the diluted hair treating agent to the hair.

The above washing and drying step can be carried out by the same process as described in the permanent method or the dyeing method of the present invention, and thus the description thereof will be omitted.

The perming and dyeing method of the present invention can be carried out by applying the hair treatment agent diluted as described above to at least a part of the washed and dried hair, and then the hair coated with the diluted hair treatment agent is shaped into various forms . ≪ / RTI >

The shape and method of shaping the hair are not particularly limited. For example, it is possible to form a wave or a straight line on all or a part of the hair by a method commonly used in the art, but is not limited thereto.

The permanent and dyeing methods of the present invention can be carried out by heating all or a part of the hair if necessary, if all or a part of the hair of the subject is formed into various forms. For example, it is preferable to carry out the step of firstly heating the mixture at 70 to 90 ° C for 5 to 10 minutes and then heating the mixture at 100 to 150 ° C for 5 to 10 minutes.

In addition, the perming and dyeing method of the present invention can perform the step of washing and drying the hair treatment agent applied to the hair after warming. At this time, it is preferable that the washing is performed using water flowing without using the shampoo so that the shape of the hair can be maintained.

Conventionally, when performing both permanent hair dyeing and dyeing procedures, hair damage is serious when they are performed at the same time, and dyeing is generally performed after the permer is first performed and then it takes about 2 weeks or more.

However, the method of perming and dyeing of the present invention can be carried out by using the hair treatment agent provided in the present invention diluted to an appropriate concentration with at least one of water and treatments and a stain agent, To be performed.

In addition, the method of perming and dyeing the present invention does not involve the treatment of the second preparation containing the oxidizing agent, unlike the conventional common perming method, so that the hair can be put in various forms quickly, economically and without damaging.

Example

Hereinafter, the present invention will be described more specifically by way of specific examples. The following examples are provided to aid understanding of the present invention, and the scope of the present invention is not limited thereto.

[Production Example 1]

The ingredients shown in Table 1 were blended to prepare a hair treatment agent having a pH of 5.5.

ingredient Content (% by weight) Disodium iodide 0.1 Panthenol 0.1 Tocopheryl acetate 0.1 Phage-7 glyceryl cocoate 3.0 PPy / PPY-17/6 copolymer 1.0 PIG-6 5.0 glycerin 3.0 Polysorbate-80 1.0 2-mercapto-4-butyrolactone 20.0 Citric acid 0.1 Sodium citrate 0.5 Hydrolyzed collagen 0.1 Hydrolyzed keratin 0.1 Spices Suitable amount Purified water Remainder

[Production Example 2]

The ingredients shown in Table 2 were blended to prepare a hair treatment agent having a pH of 5.5.

ingredient Content (% by weight) Disodium iodide 0.1 Panthenol 0.1 Tocopheryl acetate 0.1 Phage-7 glyceryl cocoate 1.0 PPy / PPY-17/6 copolymer 2.0 Guar hydroxypropyltrimonium chloride 0.2 Isoprene glycol 2.0 Dipropylene glycol 3.0 Laureates -23 1.0 2-mercapto-4-butyrolactone 23.0 Citric acid 0.1 Sodium citrate 0.5 Hydrolyzed collagen 0.1 Hydrolyzed keratin 0.1 Spices Suitable amount Purified water Remainder

[Production Example 3]

The ingredients shown in Table 3 were blended to prepare a hair treatment agent having a pH of 5.5.

ingredient Content (% by weight) Disodium iodide 0.1 Panthenol 0.1 Tocopheryl acetate 0.1 Phage-7 glyceryl cocoate 1.0 PPy / PPY-17/6 copolymer 4.0 Polyquaternium-39 1.0 Amodimicchicone 1.0 PIG-6 2.0 Propylene glycol 3.0 Isosteareds-25 0.5 2-mercapto-4-butyrolactone 25.0 Citric acid 0.1 Sodium citrate 0.5 Hydrolyzed collagen 0.1 Hydrolyzed keratin 0.1 Spices Suitable amount Purified water Remainder

[Example 1]

5 ml of the composition obtained in Preparation Example 1, 35 ml of water and 15 ml of treatment were blended to prepare a general perming agent.

[Example 2]

5 ml of the composition obtained in Preparation Example 2, 35 ml of water and 15 ml of the treatment were blended to prepare a general perming agent.

[Example 3]

6 ml of the composition obtained in Preparation Example 3, 20 ml of water and 40 ml of a hair dye were blended to prepare a perming and dyeing agent.

[Comparative Example 1]

2 ml of the composition obtained in Preparation Example 1, 35 ml of water and 15 ml of treatment were blended to prepare a general permallant preparation.

[Comparative Example 2]

8 ml of the composition obtained in Preparation Example 1, 35 ml of water and 15 ml of treatment were blended to prepare a general perming agent.

[Comparative Example 3]

In order to see the effect of the hair treatment agent according to the present invention, a gloss having a pH of 9 was prepared as a usual perming agent.

[Experimental Example 1] Wave efficiency and damage evaluation (1)

Korean female hair, about 30 cm in length, was washed with shampoo, and the hair was wound using a rod. Thereafter, the perming agents of Examples 1 to 2 and Comparative Examples 1 to 3 were applied, heated to 60 DEG C for 10 minutes, and left at room temperature for 10 minutes. After that, the rod was removed and the hair was washed with running water and then dried.

However, the perming agent of Comparative Example 3 was allowed to stand at room temperature, and the hair was lightly dried with a towel. Then, the second agent for permer obtained by mixing 5 g of sodium bromate and 95 g of purified water was applied to the hair, After standing, the hair was washed with running water and then dried.

The wave efficiency of the dried hair was calculated using the following formula, and the results are shown in Table 4 below. In addition, the degree of hair damage due to the wave was evaluated by three professional hairdressers to report the state of the hair before and after the wave treatment, and the degree of damage was evaluated as an evaluation standard, and the average value of the results was shown in Table 4.

Wave efficiency (%) = 100- {100 X (B-A)} / (C-A)

A: Distance between the first load and the sixth load

B: 6 wave lengths of curled hair

C: Length when six wavy curls of hair are spread out

(Provided that the units of A, B and C are cm).

Evaluation Criteria for Hair Damage

3: No damage to hair

2: Hair is slightly damaged

1: The hair is very damaged.

division Wave efficiency (%) Degree of damage of hair Example 1 74 3 Example 2 72 2.3 Example 3 70 2.7 Comparative Example 1 58 2.7 Comparative Example 2 65 1.7 Comparative Example 3 61 1.3

As shown in Table 5, when the perming agent belonging to the present invention was used, the wave efficiency was all 70% or more, and the damage evaluation result of the hair was 2.3 or more. Thus, the hair was not damaged, You can see what is possible.

However, in Comparative Example 1 in which the content of the hair treatment agent is less than the range of the present invention, the degree of hair damage is low, but the wave efficiency is remarkably lowered to about 58% In Comparative Example 2, which exceeds the scope of the invention, the wave efficiency is about 65%, but the damage evaluation result of the hair is 1.7, indicating that the degree of damage is severe. Also, in Comparative Example 3, which is a permallant used in the general market, the wave efficiency is only about 61%, and the damage evaluation result is also 1.3, which shows that hair is severely damaged.

[Experimental Example 2] Wave efficiency and damage evaluation (2)

Korean female hair, about 20 cm in length, was washed with shampoo, and the hair was wound using a rod. Thereafter, the perming agent of Example 1 was applied, and the mixture was first heated to 80 deg. C for 10 minutes, then heated at 120 deg. C for 5 minutes, and left at room temperature for 10 minutes. After that, the rod was removed and the hair was washed with running water and then dried.

In order to evaluate the wave efficiency and the degree of damage of the hair through the above-mentioned permanent operation, photographs before and after the operation are shown in FIGS. 1 (a) to (c), respectively.

As shown in FIGS. 1 (a) and 1 (b), it can be seen that after the perming procedure, the wave is well formed on the entire head. Particularly, as shown in FIG. 1 (c) can see.

[Experimental Example 3]

For the sensory evaluation of the materials obtained in Examples 1 to 3 and Comparative Examples 1 to 3, 30 ml of each material was put into a wide bottle and the blended test method was applied to five panels The sensory test was carried out. The sensory test was graded at the 5th grade according to the following criteria, and the average results are shown in Table 5 below.

Evaluation standard

5: Very good

4: Excellent

3: Usually

2: Poor

1: Poor

division Rating Example 1 4.4 Example 2 4 Example 3 4.2 Comparative Example 1 4.2 Comparative Example 2 3.8 Comparative Example 3 2.4

As shown in Table 4, in Examples 1 to 3 using the hair treatment agents falling within the scope of the present invention, the sensory evaluation results showed that the average score of the five panels was extremely high, more than four points, It is seen that the comparative examples 1 and 2 using the hair treatment agent of the present invention also have excellent evaluation results of about 4.2 and 3.8 points, respectively. On the other hand, Comparative Example 2, which is a permallant used in the general market, has a very low evaluation result of 2.4 points.

[Experimental Example 4] Wave, dyeing efficiency and damage evaluation

Korean male hair having a length of about 10 cm was washed using a shampoo, the hair of Example 3 was applied to the entire hair, and the hair was wound using a rod. Thereafter, the mixture was first heated to 80 deg. C for 10 minutes, then heated at 120 deg. C for 5 minutes, and left at room temperature for 10 minutes. After that, it was washed with shampoo and dried.

Photographs of before and after drying are shown in FIG. 2 (a) and FIG. 2 (b), respectively, to evaluate the wave and dyeing efficiency and degree of damage of the hair through the simultaneous treatment of permer and dyeing.

As shown in FIGS. 2 (a) and 2 (b), after the simultaneous application of perming and dyeing, it can be seen that the wave is well formed in the overall hair, and the dyeing is also well done in dark brown. Moreover, despite this simultaneous procedure, there is little damage to the hair.

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the disclosed exemplary embodiments, but, on the contrary, It will be obvious to those of ordinary skill in the art.

Claims (17)

20 to 25% by weight of 2-mercapto-4-butyrolactone;
Dyssodium dithiae more than 0 and not more than 0.1% by weight;
More than 0 to 0.1% by weight of panthenol;
More than 0 to 0.1% by weight of tocopheryl acetate;
1.0 to 3.0% by weight of phage-7 glyceryl cocoate;
1.0 to 4.0% by weight of a PPy / PPY-17/6 copolymer;
0.1 to 0.5% by weight of sodium citrate;
Hydrolyzed collagen in an amount of more than 0 and not more than 0.1% by weight;
Hydrolyzed keratin 0 to 0.1% by weight or less;
Citric acid not less than 0 and not more than 0.1% by weight; And
The rest being purified water. The method according to claim 1,
Further comprising 3 to 5% by weight of at least one wetting agent selected from phage-6 and propylene glycol. The method according to claim 1,
Wherein the surfactant further comprises 0.5 to 1% by weight of at least one surfactant selected from the group consisting of polysorbate-80, laureth-23 and isostearate-25. . The method according to claim 1,
Further comprising 3.0 to 5.0% by weight of at least one moisturizing agent selected from the group consisting of glycerin, isoprene glycol and dipropylene glycol. The method according to claim 1,
At least one hair conditioning agent selected from the group consisting of guar hydroxypropyl trimonium chloride, polyquatermium-39 and amodimethicone in an amount of more than 0 to 2% by weight Wherein the hair treatment agent further comprises a surfactant. The method according to claim 1,
A hair treatment agent further comprising an appropriate amount of a flavoring agent. The method according to claim 1,
Wherein the pH of the hair treatment agent is 5.3 to 5.6. Diluting the hair treatment agent of any one of claims 1 to 7 with at least one of water and a treatment;
Applying a diluted hair treatment agent to at least a portion of the hair;
Molding the hair to which the hair treatment agent is applied; And
Washing the hair treatment agent applied to the hair and drying the hair. 9. The method of claim 8,
Wherein in the diluting step, the total amount of at least one of water and the treatment is 10 times the volume of the hair treatment agent. 9. The method of claim 8,
Subsequently heating the hair at 70 to 90 ° C for 5 to 10 minutes, and then heating the hair for 5 to 10 minutes at 100 to 150 ° C for a second time. Diluting the hair treatment agent according to any one of claims 1 to 7 with at least one of water and a treatment agent and a staining agent;
Applying a diluted hair treatment agent to at least a portion of the hair; And
A method of dyeing hair, comprising washing the applied hair treatment agent and drying the hair. 12. The method of claim 11,
Wherein in the diluting step, the total amount of at least one of the water and the treatment and the dye is 10 times the volume of the hair treatment agent. 12. The method of claim 11,
Wherein the dye is at least one selected from the group consisting of coffee, orange juice, and coffee milk. 12. The method of claim 11,
The hair is heated at 60 to 70 DEG C for 5 to 10 minutes and then allowed to stand at a temperature of 15 to 25 DEG C for 5 to 10 minutes. Diluting the hair treatment agent according to any one of claims 1 to 7 with at least one of water and a treatment agent and a staining agent;
Applying a diluted hair treatment agent to at least a portion of the hair;
Molding the hair treated with the hair treatment agent; And
A method of perming and dyeing hair, comprising washing the applied hair treatment agent and drying the hair. 16. The method of claim 15,
Wherein in the diluting step, the total amount of at least one of water and the treatment and the dye is 10 times the volume of the hair treatment agent. 16. The method of claim 15,
The hair is first heated at 70 to 90 ° C for 5 to 10 minutes, and then heated at 100 to 150 ° C for 5 to 10 minutes, .

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