KR20160081554A - Manufacturing method of three-dimensional structure - Google Patents
Manufacturing method of three-dimensional structure Download PDFInfo
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- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
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- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
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- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/20—Apparatus for additive manufacturing; Details thereof or accessories therefor
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- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
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- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
- B33Y70/10—Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
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Abstract
Description
본 발명은 삼차원 구조체 제작 방법에 관한 것이다.
The present invention relates to a method of manufacturing a three-dimensional structure.
일반적으로 프린터는 입력된 사진이나 문서에 따라 잉크를 분사하는 이차원적인 기술이다. 하지만 요즘은, 차세대 생산 기술 중 하나로 삼차원 프린팅 기술이 주목 받고 있다. 디지털화된 삼차원 제품 디자인의 이차원 단면을 연속적으로 재구성하여 소재를 한 층씩 인쇄하면서 적층하는 방식이다. 그래서 재료를 자르거나 깍는 방식의 전통적인 생산방식은 절삭가공(Subtractive manufacturing)이라 하는 반면, 삼차원 프린팅은 새로운 층을 적층하여 쌓는 방식이기 때문에 적층가공(Additive manufacturing)이라 한다.Generally, a printer is a two-dimensional technique that ejects ink according to an input photograph or document. Nowadays, three-dimensional printing technology is attracting attention as one of the next generation production technologies. A two-dimensional cross-section of a digitized three-dimensional product design is continuously reconstructed to laminate the materials one by one. Therefore, the traditional production method of cutting or cutting materials is called "subtractive manufacturing", while the three-dimensional printing is called "additive manufacturing" because it is a method of stacking new layers.
또한, 삼차원 프린팅은 주로 시제품 제작에 이용되어 왔다. 전통적인 시제품 제작 방식은 여러 단계를 거쳐야 하는 반면, 삼차원 프린팅은 출력을 위한 도면이 준비되어 있으면 그 자리에서 시제품을 제작할 수 있기 때문이다. 그리고, 별도의 금형을 제작하거나 여러 종류에 기기를 사용하여 조립하는 일이 적어 초기 투자 규모 역시 줄일 수 있다.In addition, three-dimensional printing has been mainly used for prototype production. Traditional prototyping methods require several steps, whereas three-dimensional printing can produce prototypes in situ if drawings for output are available. In addition, the initial investment can also be reduced because it is not necessary to manufacture a separate mold or assemble using various kinds of devices.
이와 관련하여 삼차원 프린팅 기술로 마련된 종래기술에 대한 선행문헌에는 대한민국 공개특허공보 제10-2004-0102531호의 “마이크로 광 조형 방법 및 장치”(이하, ‘종래기술’이라 함)가 있다.In this regard, a prior art on the prior art provided by the three-dimensional printing technology is disclosed in Korean Patent Laid-Open Publication No. 10-2004-0102531 entitled " Method and apparatus for producing microstructures " (hereinafter referred to as " prior art ").
하지만, 이러한 종래기술들의 경우, 자외선(Ultraviolet : UV) 또는 적외선 레이저에 경화되는 광경화성 수지를 적층하여 삼차원 형태의 구조물을 제작할 수는 있지만 구조물의 주요 소재는 광경화성 수지로 이루어져 소재 선택이 한정적이고, 열에 약한 문제점이 있었다.
However, in such conventional technologies, it is possible to produce a three-dimensional structure by laminating photocurable resins cured by ultraviolet (UV) or infrared laser, but the main material of the structure is made of photo-curable resin, , There was a weak issue in heat.
본 발명은 상기 문제점을 해결하기 위해 창작된 것으로써, 본 발명의 목적은 광경화성 수지를 이용하면서도 열에 강하고, 높은 강도를 가지는 삼차원 구조체의 제작 방법을 제공하는데 있다.
It is an object of the present invention to provide a method of manufacturing a three-dimensional structure having high strength and high strength while using a photo-curable resin.
상기 목적을 달성하기 위하여 본 발명의 삼차원 구조체 제작 방법은, 광경화성 수지에 첨가제가 혼합된 혼합 조성물을 준비하는 조성물 준비단계; 상기 조성물 준비단계에서 준비된 혼합 조성물을 광경화시켜 성형체를 제작하는 성형체 제작단계; 상기 제작된 성형체를 고온 열처리하여 광경화성 수지를 제거하는 열처리단계; 및 상기 열처리단계를 거친 성형체에 도금 및 가공을 수행하여, 삼차원 구조체를 제작하는 구조체 제작단계;를 포함한다.According to an aspect of the present invention, there is provided a method for fabricating a three-dimensional structure, comprising: preparing a composition comprising a photocurable resin and an additive; Preparing a molded article by photocuring the mixed composition prepared in the composition preparing step; A heat treatment step of removing the photocurable resin by high temperature heat treatment of the molded article; And a step of fabricating a three-dimensional structure by performing plating and processing on the molded body through the heat treatment step.
여기서, 상기 첨가제는 세라믹(Ceramic), 알루미나(Alumina), 지르코니아(Zirconia), 그라파이트(Graphite) 및 그라핀(Graphene) 중 적어도 하나 이상을 포함하여 마련되는 것을 특징으로 한다.Here, the additive may include at least one of ceramic, alumina, zirconia, graphite, and graphene.
또한, 상기 성형체 제작단계는, 상기 조성물 준비단계에서 준비된 혼합 조성물을 이용하여 삼차원 프린팅 방식을 수행함으로써, 상기 성형체를 제작하는 단계인 것을 특징으로 한다.The forming step is a step of forming the molded body by performing a three-dimensional printing method using the mixed composition prepared in the composition preparing step.
본 발명에 의해, 제작된 구조체는 삼차원 모델링을 통해 구조체를 디자인하므로, 변형 및 오류수정을 쉽게 할 수 있어서 다양한 소재로 개인 맞춤형 제품을 생산할 수 있고, 여러 단계를 거쳐 제품을 생산하는 방식보다 간편하여 시제품 생산에 있어서 시간과 비용을 절감할 수 있다.According to the present invention, since the manufactured structure can design a structure through three-dimensional modeling, modification and error correction can be easily performed, so that it is possible to produce a personalized product with various materials and to simplify the method Time and cost savings in prototype production.
그리고, 본 발명은 광경화성 수지와 첨가제가 혼합된 혼합 조성물을 이용하여 광경화시킨 성형체에 열처리를 하여 순도 85% 이상의 세라믹, 그라파이트 등의 소재로 삼차원 구조체 제작이 가능하다.The present invention can produce a three-dimensional structure of ceramics, graphite or the like having a purity of 85% or more by subjecting a molded article obtained by photo-curing using a mixed composition obtained by mixing a photo-curable resin and an additive.
또한, 본 발명은 광경화시킬 때 이차원 면단위로 프린팅되는 적층두께를 얇게 제어하여 정밀도를 향상시킬 수 있는 이점을 제공한다.In addition, the present invention provides an advantage that the thickness of a laminate printed on a two-dimensional plane unit can be controlled to be thin to improve precision when photocuring.
아울러, 본 발명은 열처리 단계를 거친 성형체에 최종적으로 구리, 니켈, 크롬, 마그네슘, 은 및 금으로 도금 하고, 가공을 수행함으로써, 표면을 개선하여 구조체의 내식성과 내마모성을 향상시킨 구조체를 완성할 수 있다.
In addition, the present invention can finish a structure having improved corrosion resistance and abrasion resistance of the structure by improving the surface thereof by plating the formed body after the heat treatment step with copper, nickel, chromium, magnesium, silver and gold and finally performing processing have.
도1은 본 발명의 삼차원 구조체 제작 방법을 도시한 흐름도이다.BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a flowchart showing a method for producing a three-dimensional structure of the present invention.
본 발명의 바람직한 실시예에 대하여 첨부된 도면을 참조하여 더 구체적으로 설명하되, 이미 주지된 기술적 부분에 대해서는 설명의 간결함을 위해 생략하거나 압축하기로 한다.
The preferred embodiments of the present invention will be described in more detail with reference to the accompanying drawings, in which the technical parts already known will be omitted or compressed for the sake of brevity.
<삼차원 구조체 제작 방법에 관한 설명>≪ Explanation of the method of producing the three-dimensional structure &
본 발명의 실시예에 따른 삼차원 구조체 제작 방법이 어떠한 과정으로 이루어지는지에 대해 도1을 참조하여 상세하게 설명한다.
A description will now be made in detail of a process for fabricating a three-dimensional structure according to an embodiment of the present invention with reference to FIG.
1.조성물1. Composition 준비단계(S100) Preparation step (S100)
본 단계에서는 광경화성 수지 조성물에 첨가제를 혼합하여 혼합 조성물을 준비한다.In this step, an additive is mixed with the photo-curable resin composition to prepare a mixed composition.
여기서, 첨가제는 세라믹(Ceramic), 알루미나(Alumina), 지르코니아(Zirconia), 그라파이트(Graphite) 및 그라핀(Graphene) 중 적어도 하나 이상을 포함하도록 마련될 수 있지만, 상기 기재된 성분에 제한되지 않고 선택될 수 있다.
Here, the additive may be provided to include at least one of ceramics, alumina, zirconia, graphite, and graphene, but is not limited to the above-described components and may be selected .
2.성형체2. Molded body 제작단계(S200) Production step (S200)
본 단계에서는 상기 조성물 준비단계(S100)에서 준비된 혼합 조성물을 광경화시켜 성형체를 제작하는 단계로, 디지털 광원 처리(Digital Light Processing : DLP)방식으로 프린팅하여 성형체를 제작한다.In this step, a molded body is manufactured by printing with a Digital Light Processing (DLP) method, which is a step of photocuring the mixed composition prepared in the composition preparing step (S100).
여기서, DLP방식은 삼차원 프린팅 방식의 한 종류로, 마스크 투영 이미지 경화 방식 이라고도 한다Here, the DLP method is one kind of three-dimensional printing method and may be referred to as a mask projection image curing method
구체적으로, DLP방식은 액체상태의 광경화성 수지를 투명 플레이트(Plate) 위에 도포하고, 미리 삼차원 모델링을 통해 설계된 성형체 형상을 기반으로 경화장치에서 나온 광을 조사하여 성형체를 소정의 면단위로 경화시켜 프린팅한다. 이후 이와 같이 면단위로 형성되는 성형체의 일부를 연속적으로 적층(Layer by layer)하여 전체적인 성형체를 제작한다.Specifically, in the DLP method, a liquid photocurable resin is applied on a transparent plate, and light emitted from a curing apparatus is irradiated based on a shape of a molded body designed through three-dimensional modeling in advance to cure the molded body in a predetermined plane unit Print. Then, a part of the formed body formed in units of planes is continuously laminated (layer by layer) to produce a whole formed body.
여기서, 경화장치는 자외선(Ultraviolet : UV) 또는 가시광 레이저, 발광다이오드(Light Emitting Diode : LED) 및 메탈조명 중 어느 하나인 것으로 사용된다.Here, the curing apparatus is used as any one of ultraviolet (UV) or visible light laser, light emitting diode (LED) and metal illumination.
그리고, DLP 방식의 특징은 미리 설계한 삼차원 모델링을 통해 제품을 생산하므로, 여러 단계를 거쳐 제품을 생산하는 방식보다 간편하고, 쉽게 오류를 수정할 수 있어서 시제품을 제작할 때 시간과 비용을 절감할 수 있다. 또한 소정의 면단위로 프린팅되는 적층두께를 얇게 제어할 수 있어서 정밀도를 향상시킬 수 있는 특징이 있다.The DLP method features a pre-designed three-dimensional modeling, which makes it easier and easier to correct errors than the method of producing the product through various stages, thus saving time and money when producing prototypes . In addition, it is possible to control the lamination thickness to be printed in a predetermined plane unit to be thin, thereby improving the precision.
또한, 프린팅은 그라비아 또는 슬롯다이 방식으로도 마련될 수 있다.
Printing may also be provided in a gravure or slot die fashion.
3.열처리3. Heat treatment 단계(S300) In step S300,
본 단계에서는 성형체 제작단계(S200)을 통해 광경화 되어 제작된 성형체를 고온 열처리하여 광경화성 수지를 제거하는 단계이다.In this step, the photo-curing resin is removed by high-temperature heat treatment of the molded article which is photo-cured through the molding step (S200).
즉, 조성물 준비단계(S100)에서 준비된 혼합 조성물 중 광경화성 수지는 광을 조사하여 경화시키기 위한 재료로써 이용되고, 첨가제는 성형체의 주요 소재로 마련된다.That is, among the mixed compositions prepared in the composition preparation step (S100), the photo-curing resin is used as a material for curing by irradiating light, and the additive is provided as a main material of the molded article.
구체적으로, 성형체 제작단계에서 제작된 성형체는 섭씨 300°c 이상의 온도에서 열처리하여 상기 광경화성 수지를 제거하며, 이와 같이 열처리 단계(S300)을 거친 성형체는 순도 85% 이상의 세라믹(Ceramic), 알루미나(Alumina), 지르코니아(Zirconia), 그라파이트(Graphite) 및 그라핀(Graphene) 중 적어도 하나 이상을 포함하는 첨가제로 마련된다.
Specifically, the molded product manufactured in the molded product manufacturing step is subjected to heat treatment at a temperature of 300 ° C or more to remove the photo-curable resin. The molded product after the heat treatment step (S300) And an additive comprising at least one of ceramics, alumina, zirconia, graphite and graphene.
4.구조체4. Structure 제작단계(S400) Production step (S400)
본 단계에서는 상기 열처리단계(S300)를 거친 성형체에 도금 및 가공을 수행함으로써, 최종적인 삼차원 구조체를 제작하는 단계이다.In this step, the final three-dimensional structure is fabricated by performing plating and processing on the formed body after the heat treatment step (S300).
구체적으로, 도금은 구리, 니켈, 크롬, 마그네슘, 은 및 금 중에서 어느 하나 또는 이들의 조합을 도금 재료로 이용하여 실시되고, 이후 이와 같이 도금 과정을 거친 성형체는 미세가공 과정을 거침으로써 최종적인 삼차원 구조체로 제작된다.Specifically, the plating is performed by using any one of copper, nickel, chromium, magnesium, silver and gold or a combination thereof as a plating material. After the plating process, the formed body undergoes a microfabrication process, Structure.
이와 같이 제작된 삼차원 구조체는 방열 구조체, 시계 장신구, 인체구조물, 자동차, 자전거, 유모차 등의 다양한 분야의 산업에 걸쳐 활용된다.The three-dimensional structure thus produced is utilized in various fields such as a heat radiating structure, a clock ornament, a human body structure, an automobile, a bicycle, a baby carriage, and the like.
본 발명에 개시된 실시예는 본 발명의 기술 사상을 한정하기 위한 것이 아니라 설명하기 위한 것이고, 이러한 실시예에 의해서 본 발명의 기술 사상의 범위가 한정되는 것은 아니다. 보호범위는 아래 청구범위에 의하여 해석되어야 하며, 그와 동등한 범위 내에 있는 모든 기술 사상은 본 발명의 권리 범위에 포함되는 것으로 해석되어야 할 것이다. The embodiments disclosed in the present invention are not intended to limit the scope of the present invention but to limit the scope of the technical idea of the present invention. The scope of protection is to be construed in accordance with the following claims, and all technical ideas within the scope of equivalents thereof should be construed as being included in the scope of the present invention.
Claims (3)
상기 조성물 준비단계에서 준비된 혼합 조성물을 광경화시켜 성형체를 제작하는 성형체 제작단계;
상기 제작된 성형체를 고온 열처리하여 광경화성 수지를 제거하는 열처리단계; 및
상기 열처리단계를 거친 성형체에 도금 및 가공을 수행하여, 삼차원 구조체를 제작하는 구조체 제작단계;를 포함하는 것을 특징으로 하는
삼차원 구조체 제작 방법.
A composition preparing step of preparing a mixed composition in which an additive is mixed with a photo-curing resin;
Preparing a molded article by photocuring the mixed composition prepared in the composition preparing step;
A heat treatment step of removing the photocurable resin by high temperature heat treatment of the molded article; And
And a step of fabricating a three-dimensional structure by performing plating and processing on the formed body after the heat treatment step
Method of making a three dimensional structure.
상기 첨가제는 세라믹(Ceramic), 알루미나(Alumina), 지르코니아(Zirconia), 그라파이트(Graphite) 및 그라핀(Graphene) 중 적어도 하나 이상을 포함하여 마련되는 것을 특징으로 하는
삼차원 구조체 제작 방법.
The method according to claim 1,
Wherein the additive is at least one of ceramic, alumina, zirconia, graphite, and graphene.
Method of making a three dimensional structure.
상기 성형체 제작단계는,
상기 조성물 준비단계에서 준비된 혼합 조성물을 이용하여 삼차원 프린팅 방식을 수행함으로써, 상기 성형체를 제작하는 단계인 것을 특징으로 하는
삼차원 구조체 제작 방법.
The method according to claim 1,
In the forming step,
And then performing the three-dimensional printing method using the mixed composition prepared in the composition preparing step, thereby forming the molded body
Method of making a three dimensional structure.
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CN109321770A (en) * | 2018-11-21 | 2019-02-12 | 上海交通大学 | A kind of nanometer of enhancing porous material and preparation method thereof |
KR20220056108A (en) * | 2020-10-27 | 2022-05-04 | 한국과학기술원 | Method and system for fabrication of high-resolution structure using size-tunable hydrogels |
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