KR20160076408A - UV blocking cosmetic composition prepared by being impregnated in NBR(nitrile butadiene rubber) foam - Google Patents
UV blocking cosmetic composition prepared by being impregnated in NBR(nitrile butadiene rubber) foam Download PDFInfo
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- KR20160076408A KR20160076408A KR1020140186583A KR20140186583A KR20160076408A KR 20160076408 A KR20160076408 A KR 20160076408A KR 1020140186583 A KR1020140186583 A KR 1020140186583A KR 20140186583 A KR20140186583 A KR 20140186583A KR 20160076408 A KR20160076408 A KR 20160076408A
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- nitrile butadiene
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0208—Tissues; Wipes; Patches
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/004—Aftersun preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/87—Application Devices; Containers; Packaging
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S424/00—Drug, bio-affecting and body treating compositions
- Y10S424/05—Stick
Abstract
Description
The present invention relates to a cosmetic composition for ultraviolet rays which is prepared by impregnating a foamed NBR (nitrile butadiene rubber) foam. More particularly, the present invention relates to a cosmetic composition containing a low-viscosity ultraviolet ray blocking composition of W / O in a compact type container .
In addition, the present invention relates to a cosmetic composition containing a low-viscosity, water-in-oil type ultraviolet barrier cosmetic composition impregnated with a foamed NBR (nitrile butadiene rubber) foam and packaged in a compact type container, Lt; / RTI >
UV light emitted from sunlight is a major cause of erythema, edema, freckles, and skin cancer in the skin. Recently, many studies on various skin diseases caused by ultraviolet rays are actively conducted.
Generally, ultraviolet rays are classified into UV-C at a wavelength of 240-280 nm, UV-B at a wavelength of 280-320 nm, and UV-A at a wavelength of 320-400 nm according to the wavelength. UV-C passes through the ozone layer and disappears without reaching the surface. UV-B penetrates into the epidermis of the skin, causing erythema, freckles and edema. UV-A penetrates the skin's dermis and is known to promote skin aging and skin irritation by promoting skin cancer, wrinkles and melanin formation.
The general public's interest in the sun protection product market has increased significantly and as a result, there are a variety of sunscreen products with SPF (sun protection factor) on the market. The type of ultraviolet screening product is generally made of cream or lotion and classified into water in oil (W / O) and oil in water (O / W) depending on the composition of internal and external contours of emulsion. .
Until now, ultraviolet screening products have been shown to be mainly used in the summer season. However, recently, there has been an increase in demand for the use of four seasons as well as in summer due to changes in lifestyle due to an increase in the population enjoying leisure activities and awareness of the harmfulness of ultraviolet rays have. As a result, there is an increasing trend of consumers demanding products that have improved usability and convenience.
In general, sunscreen products are made into a water-in-oil type that externally tops the oil to improve water resistance to sweat and water. In the case of an underwater type sunscreen product, the feeling of use when applied to skin is neat as compared to a water-in-oil type product, but the drawback is that it is still easily washed off with sweat or water despite continuing research to improve water resistance And the persistence of the ultraviolet shielding effect, which is a conventional object of the ultraviolet screening product, is remarkably deteriorated.
For example, Korean Patent Registration No. 10-1002866 discloses an ultraviolet screening cosmetic composition in the form of a water-in-oil type emulsion. More specifically, it relates to an ultraviolet screening cosmetic composition containing an aqueous component and an organic gelling agent And is in the form of a solid water-in-oil type emulsion, and is characterized by containing an aqueous phase component, an organic gelling agent, an organic ultraviolet screening agent, an inorganic ultraviolet screening agent, a wax, a surfactant, an oil and a pigment.
The above-mentioned prior art has a high SPF value and a PA value and thus has an excellent ultraviolet ray shielding effect. When the prior art products are used, the skin is not dried because of the excellent sensation of coolness and moistness due to the water component, This has an excellent effect.
However, the above-mentioned prior art has a disadvantage that it is more persistent than an underwater type ultraviolet screening product, but has a feeling of heavy feeling and stickiness. This is not related to the ultraviolet screening product of the water-in-oil type. In the case of a water-in-oil type ultraviolet screening product, the ratio of the internal phase water phase is raised to lightly adjust the feeling of use, so that the product is manufactured at a high viscosity.
In addition, in general, a water-in-oil type product is known to have poor emulsification stability as compared with an underwater type product. In the prior art, the stability of the product deteriorates due to the separation of the water phase from the inner water phase and the traumatic oil phase during long- There is a problem. Therefore, the viscosity is increased to increase the stability, and when the viscosity is increased, the feeling of use is heavy and sticky.
As a study similar to the present invention, UV-screening products of the water-in-oil type have been adjusted to the viscosity and the usability has been improved so that the ultraviolet screening products of the water-in-water type have been packed in the tubes or pump containers. However, Inconvenience occurs.
In addition, particularly in the case of summer, a feeling of cold which reduces the heat of the skin is more preferred. However, when the product of the above formulation is applied to the skin, It is buried in the hands, and it is troublesome to wash the hands again to prevent contamination and stickiness.
In order to solve such a problem, Korean Patent Registration Nos. 10-1257628 and 10-1355051 disclose a proposed technique in which a UV-screening agent of a water-in-oil type is applied to a foamed urethane foam of ether polymer or ester polymer type The present invention relates to a cosmetic product impregnated with a foamed urethane foam.
The foamed urethane foam is a polymer having a urethane bond (-NH-COO-) in a polymer chain, and is produced by bonding an isocyanate having a valence of two or more with an active hydrogen compound such as a polyol. The polyol is selected from a polyether polyol or a polyester polyol.
However, the foamed urethane foam using the polyether polyol or the polyester polyol proceeds together with the exothermic reaction, and polyurethane is foamed while generating heat and high-pressure gas. At this time, in the portion where the foamed thickness is thinly formed, And the pressure is applied, the polyurethane gradually inflates and deforms on the inner surface.
Also, the isocyanate is an aromatic isocyanate such as tolulene diisocyanate (MDI) or methylenediphenyl diisocyanate (MDI), which has a quinone imide structure due to ultraviolet rays, resulting in yellowing of the foamed urethane foam.
When the foamed urethane foam containing the polyester polyol is impregnated with the ultraviolet barrier cosmetic composition, the foam is gradually hardened over time and the surface is cracked and a part of the foam is broken.
In addition, amine is used as a catalyst in the production of foamed urethane foam. The amine is mostly volatilized by heat during the production of the foamed urethane foam, but there is a problem that the amine remains unpleasant to some people with sensitive smell.
Disclosure of Invention Technical Problem [8] Accordingly, the present invention has been made to solve the above problems, and an object of the present invention is to provide a cosmetic composition in which a low viscosity ultraviolet ray blocking composition of W / O is packaged in a compact type container.
In addition, the present invention solves the problem of yellowing and deformation of the inner urethane foam caused by the foamed urethane foam by impregnating the foamed NBR foam with a low-viscosity water-in-oil type UV blocking cosmetic composition instead of impregnating the conventional foamed urethane foam. The purpose is to do.
In addition, the present invention relates to a cosmetic composition containing a low-viscosity, water-in-oil type ultraviolet barrier cosmetic composition impregnated with a foamed NBR (nitrile butadiene rubber) foam and packaged in a compact type container, To provide a barrier cosmetic composition.
It is another object of the present invention to provide an ultraviolet screening product having a good ultraviolet screening effect and being easy to use and carry.
The present invention is characterized in that the ultraviolet light shielding composition is a compact formulation of an ultraviolet light blocking cosmetic composition impregnated with a foamed NBR (nitrile butadiene rubber) foam.
In addition, the foamed NBR (nitrile butadiene rubber) foam of the present invention is characterized by having a hardness of 15 to 35 on the basis of ASKER hardness F type (Type F) before impregnating the contents.
In addition, the foamed NBR (nitrile butadiene rubber) foam of the present invention has a density of 180 to 240 g / L before impregnating the contents.
In addition, the present invention is characterized in that the UV blocking composition has a viscosity of 5000 to 15000 cps.
In addition, the present invention is a cosmetic container containing a foamed NBR (nitrile butadiene rubber) foam impregnated with a cosmetic composition, wherein the composition contains an ultraviolet screening agent.
As described above, the ultraviolet barrier cosmetic composition prepared by impregnating a foamed NBR (nitrile butadiene rubber) foam according to the present invention comprises a cosmetic composition in which a low viscosity ultraviolet ray blocking composition of water-in-oil (W / O) is packaged in a compact type container .
In addition, the present invention improves the problem of yellowing phenomenon and inward deformation occurring in the foamed urethane foam by impregnating foamed NBR foam instead of impregnating the low viscosity, water-in-oil type ultraviolet barrier cosmetic composition into the conventional foamed urethane foam. .
The present invention also relates to a cosmetic composition containing a UV-blocking cosmetic composition having a low viscosity, which is impregnated with a foamed nitrile butadiene rubber (NBR) foam and packaged in a compact type container to improve user portability and convenience of use .
In addition, the present invention has an effect of providing an ultraviolet screening product having a good ultraviolet screening effect and being easy to use and carry.
1 is a perspective view of a foamed NBR (nitrile butadiene rubber) foam according to an embodiment of the present invention.
2 is a perspective view of a foamed NBR (nitrile butadiene rubber) foam according to another embodiment of the present invention.
3 is a cross-sectional view of a foamed NBR (nitrile butadiene rubber) foam according to another embodiment of the present invention.
4 is a perspective view of a foamed NBR (nitrile butadiene rubber) foam according to another embodiment of the present invention.
The ultraviolet barrier cosmetic composition prepared by impregnating the foamed NBR (nitrile butadiene rubber)
FIG. 1 is a perspective view of a foamed NBR (nitrile butadiene rubber) foam according to an embodiment of the present invention, FIG. 2 is a perspective view of a foamed NBR (nitrile butadiene rubber) foam according to another embodiment of the present invention, FIG. 4 is a perspective view of a foamed NBR (nitrile butadiene rubber) foam according to another embodiment of the present invention. FIG. 4 is a perspective view of a foamed NBR (nitrile butadiene rubber) foam according to another embodiment of the present invention.
The present invention relates to a compact type (10), comprising a foamed NBR (nitrile butadiene rubber) foam (10) impregnated with a low viscosity water-in-oil type emulsion ultraviolet screening composition containing an oily component, an emulsifier, an organic or inorganic ultraviolet screening agent, It is a formulation.
The oily components used in the present invention include vegetable oils such as rosehip oil, safflower oil, peach seed oil, methoform seed oil and sunflower seed oil, dicaprylyl carbonate, squalane, neopentylglycol diheptanoate, Acetate, trioctanoin, C12-15 alkyl benzoate, C12-15 alkyl ethyl hexanoate, octyldodecyl myristate, tricaprylyl, octyldodecylstearoyl stearate, bis-hydroxyethoxypropyldimetate Chitosan, chicone, caprylic, capric triglyceride, isotridecylisononanoate, polyglyceryl-2 triisostearate, diisostearyl malate, dipentaerythritol pentaerythritide, cetyl octanoate, And synthetic esters or hydrocarbons such as carboxymethylcellulose, carboxymethylcellulose and carbitol, silicone oils such as phenyltrimethicone, cyclomethicone, dimethicone, decamethylcyclopentasiloxane and the like Up to more than one selected species, it is contained in an amount of 20 to 80% by weight relative to the total weight of the composition. If the oily component is less than 20% by weight, the stability of the composition is poor or the viscosity is too high, and the feeling of use is heavy and tacky, and the usability is poor. When the content is more than 80% by weight, the stability is poor.
As the emulsifier used in the present invention, a non-ionic surfactant having an HLB range of 1 to 6 and a low HLB is suitable for producing a water-in-oil type emulsion, and specifically, cyclopentasiloxane and PEG / PPG-18/18 dimethicone Cyclopentasiloxane and PEG / PPG-18/18 Dimethicone, Glycol Stearate, Sorbitan Sesquioleate, Glyceryl Oleate, Glycol Distearate, Propylene Glycol Propylene glycol monostearate, glyceryl stearate, sorbitan stearate, PEG-30 dipolyhydroxystearate, PEG-10 dimethicone (PEG- -10 Dimethicone), cyclopentasiloxane / PEG.PPG-19.19 dimethicone, sorbitan isostearate, lauryl PEG.PPG-18. (PEG-PPG-18.18 methicone), cetyl PEG.PPG-10.1 dimethicone, lauryl PEG-9 polydimethylsiloxyethyl dimethicone (Lauryl PEG- ), And it is contained in an amount of 0.01 to 10% by weight based on the total weight of the composition. When the amount of the emulsifier is less than 0.01% by weight, the emulsion is not formed or the stability of the composition is poor. When the amount of the emulsifier is more than 10% by weight, stickiness of the emulsifier itself and inherent odor are generated.
The ultraviolet screening agent used in the present invention may be used either individually or in combination with an organic ultraviolet screening agent or an inorganic ultraviolet screening agent. Specific examples of the organic ultraviolet screening agent include octyl methoxycinnamate, octyl salicylate, octocrylene, butyl methoxydibenzoylmethane, oxybenzone, octyltriazone, menthyl anthranilate, 3,4-methyl benzylidene kempfer, Isoamyl-P-methoxy cinnamate, bisethylhexyloxyphenol methoxyphenyltriazine, and methylenebisbenzotriazolyltetramethylbutylphenol. As the inorganic ultraviolet blocking agent, titanium dioxide having an average particle size of 5 to 100 nm , Zinc oxide having an average particle size of 5 to 300 nm, iron oxide having an average particle size of 5 to 300 nm, or the like can be used. At this time, the larger the average particle size of the inorganic sunscreen agent, the more the whitening phenomenon is applied to the skin, thereby decreasing the value of the product. On the other hand, when the particle size is too small, the skin penetrates into the skin to cause irritation. Is suitably 300 nm or less, and 10 to 50 nm is suitable when both skin irritation and cloudiness are considered at the same time.
In addition, the ultraviolet screening agent is contained in an amount of 1 to 35% by weight based on the total weight of the composition. When the ultraviolet screening agent is less than 1% by weight, the ultraviolet screening effect is insignificant to 10 (SPF index) or less. When the ultraviolet screening agent is more than 35% by weight, the whitening phenomenon and shine are worse.
The pigment used in the present invention may be at least one selected from the group consisting of PMMA (polymethylmethacrylate), silica, nylon, nitrile butadiene rubber (NBR), ultramarine, iron oxide, Mica, talc, cerasite and boron nitride can be mixed and used in an amount of 0.1 to 20% by weight based on the total weight of the composition. If the content of the pigment is less than 0.1% by weight, the effects such as adhesion, color, and agglomeration are insignificant. If the content is more than 20% by weight, the viscosity is excessively increased and the feeling of use becomes stiff and the stability of emulsification is deteriorated .
The water component used in the present invention is at least one selected from the group consisting of purified water, propylene glycol, 1,3-butylene glycol and glycerin, and is contained in an amount of 30 to 70% by weight based on the total weight of the composition. When the water phase component is less than 30% by weight, the viscosity is too low to lower the stability of the formulation. When the water phase component is more than 70% by weight, the viscosity becomes too high.
In addition to the above components, at least one selected from preservatives, fragrances and other additives may be further added to the ultraviolet screening composition. Particularly, parabens such as methylparaben, propylparaben, butylparaben, ethylparaben and the like which can be used as a preservative can be mixed into an oil phase, and in case of phenoxyethanol, they can be mixed with an aqueous phase.
In addition, the fragrance is added to the oil phase of the water-in-oil type at the final stage of the process for producing the composition.
The water-in-oil UV blocking cosmetic composition of the present invention has a low viscosity in the range of 5,000 to 15,000 cps. If the viscosity of the water-in-oil type ultraviolet barrier cosmetic composition is less than 5000 cps, separation of oil phase and water phase occurs immediately after preparation of the emulsion, so that it is difficult to impregnate into the NBR (nitrile butadiene rubber)
The UV-blocking cosmetic composition of the present invention is packed in a compact type container using a foamed NBR (nitrile butadiene rubber)
According to another embodiment, as shown in FIG. 2 to FIG. 3, the ultraviolet barrier cosmetic composition is impregnated with a foamed NBR (nitrile butadiene rubber)
As shown in FIG. 4, the foamed NBR (nitrile butadiene rubber)
The foamed NBR (nitrile butadiene rubber)
In addition, the foamed NBR (nitrile butadiene rubber)
If the hardness of the foamed
In addition, the foamed NBR (nitrile butadiene rubber)
If the number of pores in the foamed
Hereinafter, the production examples, examples and test examples of the present invention will be described in detail.
The following Preparation Examples, Examples and Test Examples are illustrative of the present invention, and the present invention is not limited to the following Production Examples, Examples and Test Examples.
[ Manufacturing example ] firing NBR ( nitrile butadiene rubber ) On the form Impregnated UV protection manufactured Cosmetics Method of manufacturing composition
To the vessel of the stirring apparatus, 10.0% by weight of octyl salicylate and 2.0% by weight of titanium dioxide, an ultraviolet ray blocking agent, 0.1% by weight of peach seed oil as an oily component and 0.1% by weight of tecamethylcyclopentasiloxane And then emulsification was carried out. Then, 3% by weight of glycol stearate, 2.0% by weight of sorbitan sesquioleate and 0.1% by weight of methyl paraben, which is a preservative, were added and stirred uniformly while heating at 80 ° C. Respectively.
Then, 4.0 weight% of polymethyl methacrylate and 5.0 weight% of aluminum hydroxide were added and stirred to prepare an oily component.
40.2% by weight of water and 7.0% by weight of glycerin were added to another vessel of the stirring apparatus and uniformly mixed while heating and stirring at 80 DEG C to prepare an aqueous phase component.
0.4 weight% of the above water-based ingredients and fragrance were slowly added to a stirring device containing oil components, emulsified at 80 ° C, and then cooled to room temperature (25 ° C) to prepare a UV-blocking cosmetic having a low viscosity.
[ Test Example One ] Stability experiment of formulation
The stability of the formulation was tested with the water-in-oil UV blocking cosmetic composition of the above Production Example. Example 1 was prepared by impregnating the composition of the present invention into a foamed NBR (nitrile butadiene rubber) foam having a hardness of 25 on the basis of ASKER hardness type F (Type F). In Comparative Example 1, And Comparative Example 2 was obtained by storing the composition of Production Example in a plastic container. The stability was tested in accordance with the conditions shown in Table 1 below, and the results are shown in Table 1 below. Table 1 shows the results obtained when Example 1 and Comparative Examples 1 and 2 were stored at 50 占 폚 for 2 hours.
10 days past
Five days past
2 hours elapsed
As shown in Table 1, Comparative Example 1 in which a low-viscosity water-in-oil UV blocking cosmetic composition according to the present invention was stored in a tube container and Comparative Example 2 in which the cosmetic composition was stored in a plastic container, And the formulation was unstable.
On the other hand, in Example 1, which was impregnated with a foamed NBR (nitrile butadiene rubber) foam, it can be confirmed that the formulation is stable even when the temperature changes and time elapses.
[ Test Example 2 ] firing NBR ( nitrile butadiene rubber ) Preference test according to hardness of foam
The nitrile butadiene rubber foam was impregnated with each of the above preparation examples and then applied to skin using a makeup tool to compare differences in preference according to hardness of NBR (nitrile butadiene rubber) foam.
Example 2 is obtained by impregnating an NBR (nitrile butadiene rubber) foam having a hardness of 5 in Example 2, a NBR (nitrile butadiene rubber) foam having a hardness of 25 in Example 3, The composition of the production example is impregnated with NBR (nitrile butadiene rubber) foam having hardness of 50.
The above Examples 2 to 4 were cremated for 50 days for women in their 20s and 30s for 7 days, and the use results were compared and evaluated. The preference according to the hardness of the foamed foam was evaluated by a questionnaire consisting of sensory evaluation (5 point scaling method), and it was rated as excellent 5 points, good 4 points, average 3 points, poor 2 points and very poor 1 point. The evaluation scores are shown in Table 2 below.
(ASKER hardness F type)
As shown in Table 2, Example 3 in which NBR (nitrile butadiene rubber) foam having a hardness of 25 was impregnated with the composition of the production example showed the highest degree of preference.
[ Test Example 3] firing NBR ( nitrile butadiene rubber ) Of foam Pore Experiment of preference according to number
The above preparation examples were compared with each other in terms of the number of pores of the nitrile butadiene rubber (NBR) foam when they were applied to the skin using a makeup tool after impregnating the foam with NBR (nitrile butadiene rubber).
Example 5 is obtained by impregnating a nitrile butadiene rubber (NBR) foam having a pore number of 5 ppi with the composition of the production example. In Example 6, the composition of the example is impregnated with a nitrile butadiene rubber (NBR) foam having a pore number of 60 ppi, Example 7 is obtained by impregnating a composition of the production example into a nitrile butadiene rubber (NBR) foam having a pore number of 200 ppi.
The above Examples 5 to 7 were cremated for 50 days in the 20s and 30s for 7 days, and the use results were compared and evaluated. The preference according to the hardness of the foamed foam was evaluated by a questionnaire consisting of sensory evaluation (5 point scaling method), and it was rated as excellent 5 points, good 4 points, average 3 points, poor 2 points and very poor 1 point. The evaluation scores are shown in Table 3 below.
Number of pores (ppi)
As shown in Table 3, Example 6 in which the composition of the preparation example was impregnated with NBR (nitrile butadiene rubber) foam having a pore number of 60 ppi showed the highest preference.
As described above, the present invention is not limited to the UV-blocking cosmetic composition prepared by impregnating foamed NBR (nitrile butadiene rubber) foam. The present invention is not limited to the above-described embodiments, It is to be understood that the present invention is not limited to the disclosed embodiments, but, on the contrary, is intended to cover various modifications and equivalent arrangements included within the spirit and scope of the appended claims and their equivalents. Lt; / RTI >
10: Foamed NBR foam 20: impregnated hole
Claims (19)
The foamed NBR (nitrile butadiene rubber) foam 10 is impregnated with a foamed NBR foam having a hardness of 15 to 35 on the basis of an ASKER hardness F type (Type F) before impregnating the contents. Wherein the cosmetic composition is an ultraviolet light.
Wherein the ultraviolet ray blocking cosmetic composition is a water-in-oil type, and the ultraviolet ray blocking cosmetic composition is impregnated in a foamed NBR foam.
Wherein the ultraviolet light blocking cosmetic composition has a viscosity of 5000 to 15000 cps.
Wherein the nitrile butadiene rubber foam (10) has a density of 180 to 240 g / L prior to impregnating the contents with the foamed NBR foam.
Wherein the foamed NBR (nitrile butadiene rubber) foam 10 has a pore number of 10 to 150 ppi (pore per inch).
Wherein the ultraviolet barrier cosmetic composition comprises 20 to 80% by weight of an oily component, 0.01 to 10% by weight of an emulsifier, 1 to 35% by weight of at least one selected from the group consisting of an organic ultraviolet screening agent and an inorganic ultraviolet screening agent, To 20% by weight of the composition and 30 to 70% by weight of the water-based component.
Wherein the oily component is at least one selected from the group consisting of vegetable oils, synthetic esters, hydrocarbons and silicone oils.
Wherein the emulsifier is a nonionic surfactant having an HLB in the range of 1 to 6. 5. The ultraviolet blocking cosmetic composition according to claim 1,
The organic UV blocking agent may be at least one selected from the group consisting of octylmethoxycinnamate, octyl salicylate, octocrylene, butylmethoxydibenzoylmethane, oxybenzone, octyltriazone, menthyl anthranilate, 3,4- -P-methoxycinnamate, bisethylhexyloxyphenol methoxyphenyltriazine, and methylenebisbenzotriazolyltetramethylbutylphenol, which is prepared by impregnating a foamed NBR foam with ultraviolet rays Cosmetic composition.
Wherein the inorganic UV-blocking agent is at least one selected from the group consisting of titanium dioxide, zinc oxide, and iron oxide.
The pigment is at least one selected from the group consisting of PMMA (polymethylmethacrylate), silica, nylon, polyurethane, ultramarine, iron oxide, pearl, synthetic mica, mica, talc, cerasite and boron nitride By weight of the foamed NBR foam.
Wherein the aqueous phase component is at least one selected from the group consisting of purified water, propylene glycol, 1,3-butylene glycol and glycerin.
Characterized in that the foamed NBR (nitrile butadiene rubber) foam (10) is an open cell structure, and the foamed NBR foam is impregnated into a foamed NBR foam.
Characterized in that the foamed NBR (nitrile butadiene rubber) foam (10) is provided with an impregnated hole (20).
Characterized in that the foamed NBR (nitrile butadiene rubber) foam (10) has an impregnated hole (20).
Wherein said composition comprises an ultraviolet screening agent.
The ultraviolet shielding agent may be at least one selected from the group consisting of octylmethoxycinnamate, octyl salicylate, octocrylene, butylmethoxydibenzoylmethane, oxybenzone, octyltriazone, menthyl anthranilate, 3,4-methylbenzylidene kempfer, isoamyl- Wherein the cosmetic container is at least one selected from the group consisting of P-methoxy cinnamate, bishexyloxyphenol methoxyphenyltriazine, and methylene bisbenzotriazolyltetramethylbutylphenol.
Wherein the ultraviolet screening agent is at least one selected from the group consisting of titanium dioxide, zinc oxide, and iron oxide.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
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KR1020140186583A KR20160076408A (en) | 2014-12-22 | 2014-12-22 | UV blocking cosmetic composition prepared by being impregnated in NBR(nitrile butadiene rubber) foam |
PCT/KR2015/014005 WO2016105042A2 (en) | 2014-12-22 | 2015-12-21 | Ultraviolet ray-blocking cosmetic composition prepared by means of impregnation into nbr foam |
Applications Claiming Priority (1)
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KR1020140186583A KR20160076408A (en) | 2014-12-22 | 2014-12-22 | UV blocking cosmetic composition prepared by being impregnated in NBR(nitrile butadiene rubber) foam |
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KR20160076408A true KR20160076408A (en) | 2016-06-30 |
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KR1020140186583A KR20160076408A (en) | 2014-12-22 | 2014-12-22 | UV blocking cosmetic composition prepared by being impregnated in NBR(nitrile butadiene rubber) foam |
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WO (1) | WO2016105042A2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018016931A1 (en) * | 2016-07-22 | 2018-01-25 | 코스맥스 주식회사 | Cosmetic product including cosmetic container using specific rubber |
Family Cites Families (5)
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KR101257628B1 (en) * | 2011-03-24 | 2013-04-29 | (주)아모레퍼시픽 | Cosmetics comprising cosmetic composition impregnated in urethane foam |
KR20130116182A (en) * | 2012-04-12 | 2013-10-23 | (주)아모레퍼시픽 | Foamed material of improvement in use |
US9585456B2 (en) * | 2012-04-13 | 2017-03-07 | Amorepacific Corporation | Cosmetic composition container comprising foam |
US9532934B2 (en) * | 2012-04-13 | 2017-01-03 | Amorepacific Corporation | Cosmetic composition carrier comprising foams |
KR101355051B1 (en) * | 2012-05-09 | 2014-01-27 | (주)아모레퍼시픽 | UV blocking cosmetic composition prepared by being impregnated in urethane foam |
-
2014
- 2014-12-22 KR KR1020140186583A patent/KR20160076408A/en active Search and Examination
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2015
- 2015-12-21 WO PCT/KR2015/014005 patent/WO2016105042A2/en active Application Filing
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018016931A1 (en) * | 2016-07-22 | 2018-01-25 | 코스맥스 주식회사 | Cosmetic product including cosmetic container using specific rubber |
Also Published As
Publication number | Publication date |
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WO2016105042A2 (en) | 2016-06-30 |
WO2016105042A3 (en) | 2016-08-18 |
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