KR20160076408A - UV blocking cosmetic composition prepared by being impregnated in NBR(nitrile butadiene rubber) foam - Google Patents

UV blocking cosmetic composition prepared by being impregnated in NBR(nitrile butadiene rubber) foam Download PDF

Info

Publication number
KR20160076408A
KR20160076408A KR1020140186583A KR20140186583A KR20160076408A KR 20160076408 A KR20160076408 A KR 20160076408A KR 1020140186583 A KR1020140186583 A KR 1020140186583A KR 20140186583 A KR20140186583 A KR 20140186583A KR 20160076408 A KR20160076408 A KR 20160076408A
Authority
KR
South Korea
Prior art keywords
foam
butadiene rubber
cosmetic composition
nbr
nitrile butadiene
Prior art date
Application number
KR1020140186583A
Other languages
Korean (ko)
Inventor
조성렬
Original Assignee
(주)에스엔피월드
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by (주)에스엔피월드 filed Critical (주)에스엔피월드
Priority to KR1020140186583A priority Critical patent/KR20160076408A/en
Priority to PCT/KR2015/014005 priority patent/WO2016105042A2/en
Publication of KR20160076408A publication Critical patent/KR20160076408A/en

Links

Images

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0208Tissues; Wipes; Patches
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • A61K8/064Water-in-oil emulsions, e.g. Water-in-silicone emulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31Hydrocarbons
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/004Aftersun preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/87Application Devices; Containers; Packaging
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S424/00Drug, bio-affecting and body treating compositions
    • Y10S424/05Stick

Abstract

The present invention relates to a UV-blocking cosmetic composition produced by being impregnated in foaming nitrile butadiene rubber (NBR) foam. Specifically, a water-in-oil-type (W/O) low viscosity UV-blocking composition is packed in a compact-type container, and a low viscosity W/O UV-blocking cosmetic composition is impregnated in foaming NBR foam and packed in a compact-type container, so user portability and usage convenience are improved and a cooling effect is also ensured. According to the present invention, a compact formulation UV-blocking cosmetic composition is produced by impregnating a UV-blocking composition in foaming NBR foam. The foaming NBR foam has a hardness of 15 to 35 on the basis of ASKER durometer Type F and a density of 180 to 240 g/L before contents are impregnated. A viscosity of the UV-blocking composition is 5000 to 15000 cps. Also, according to the present invention, a cosmetic container in which foaming NBR foam having a cosmetic composition impregnated therein is formed is produced, wherein the cosmetic composition contains a UV-blocking agent.

Description

(UV blocking cosmetic composition prepared by being impregnated in NBR (nitrile butadiene rubber) foam) which is prepared by impregnating a foamed NBR (nitrile butadiene rubber)

The present invention relates to a cosmetic composition for ultraviolet rays which is prepared by impregnating a foamed NBR (nitrile butadiene rubber) foam. More particularly, the present invention relates to a cosmetic composition containing a low-viscosity ultraviolet ray blocking composition of W / O in a compact type container .

In addition, the present invention relates to a cosmetic composition containing a low-viscosity, water-in-oil type ultraviolet barrier cosmetic composition impregnated with a foamed NBR (nitrile butadiene rubber) foam and packaged in a compact type container, Lt; / RTI >

UV light emitted from sunlight is a major cause of erythema, edema, freckles, and skin cancer in the skin. Recently, many studies on various skin diseases caused by ultraviolet rays are actively conducted.

Generally, ultraviolet rays are classified into UV-C at a wavelength of 240-280 nm, UV-B at a wavelength of 280-320 nm, and UV-A at a wavelength of 320-400 nm according to the wavelength. UV-C passes through the ozone layer and disappears without reaching the surface. UV-B penetrates into the epidermis of the skin, causing erythema, freckles and edema. UV-A penetrates the skin's dermis and is known to promote skin aging and skin irritation by promoting skin cancer, wrinkles and melanin formation.

The general public's interest in the sun protection product market has increased significantly and as a result, there are a variety of sunscreen products with SPF (sun protection factor) on the market. The type of ultraviolet screening product is generally made of cream or lotion and classified into water in oil (W / O) and oil in water (O / W) depending on the composition of internal and external contours of emulsion. .

Until now, ultraviolet screening products have been shown to be mainly used in the summer season. However, recently, there has been an increase in demand for the use of four seasons as well as in summer due to changes in lifestyle due to an increase in the population enjoying leisure activities and awareness of the harmfulness of ultraviolet rays have. As a result, there is an increasing trend of consumers demanding products that have improved usability and convenience.

In general, sunscreen products are made into a water-in-oil type that externally tops the oil to improve water resistance to sweat and water. In the case of an underwater type sunscreen product, the feeling of use when applied to skin is neat as compared to a water-in-oil type product, but the drawback is that it is still easily washed off with sweat or water despite continuing research to improve water resistance And the persistence of the ultraviolet shielding effect, which is a conventional object of the ultraviolet screening product, is remarkably deteriorated.

For example, Korean Patent Registration No. 10-1002866 discloses an ultraviolet screening cosmetic composition in the form of a water-in-oil type emulsion. More specifically, it relates to an ultraviolet screening cosmetic composition containing an aqueous component and an organic gelling agent And is in the form of a solid water-in-oil type emulsion, and is characterized by containing an aqueous phase component, an organic gelling agent, an organic ultraviolet screening agent, an inorganic ultraviolet screening agent, a wax, a surfactant, an oil and a pigment.

The above-mentioned prior art has a high SPF value and a PA value and thus has an excellent ultraviolet ray shielding effect. When the prior art products are used, the skin is not dried because of the excellent sensation of coolness and moistness due to the water component, This has an excellent effect.

However, the above-mentioned prior art has a disadvantage that it is more persistent than an underwater type ultraviolet screening product, but has a feeling of heavy feeling and stickiness. This is not related to the ultraviolet screening product of the water-in-oil type. In the case of a water-in-oil type ultraviolet screening product, the ratio of the internal phase water phase is raised to lightly adjust the feeling of use, so that the product is manufactured at a high viscosity.

In addition, in general, a water-in-oil type product is known to have poor emulsification stability as compared with an underwater type product. In the prior art, the stability of the product deteriorates due to the separation of the water phase from the inner water phase and the traumatic oil phase during long- There is a problem. Therefore, the viscosity is increased to increase the stability, and when the viscosity is increased, the feeling of use is heavy and sticky.

As a study similar to the present invention, UV-screening products of the water-in-oil type have been adjusted to the viscosity and the usability has been improved so that the ultraviolet screening products of the water-in-water type have been packed in the tubes or pump containers. However, Inconvenience occurs.

In addition, particularly in the case of summer, a feeling of cold which reduces the heat of the skin is more preferred. However, when the product of the above formulation is applied to the skin, It is buried in the hands, and it is troublesome to wash the hands again to prevent contamination and stickiness.

In order to solve such a problem, Korean Patent Registration Nos. 10-1257628 and 10-1355051 disclose a proposed technique in which a UV-screening agent of a water-in-oil type is applied to a foamed urethane foam of ether polymer or ester polymer type The present invention relates to a cosmetic product impregnated with a foamed urethane foam.

The foamed urethane foam is a polymer having a urethane bond (-NH-COO-) in a polymer chain, and is produced by bonding an isocyanate having a valence of two or more with an active hydrogen compound such as a polyol. The polyol is selected from a polyether polyol or a polyester polyol.

However, the foamed urethane foam using the polyether polyol or the polyester polyol proceeds together with the exothermic reaction, and polyurethane is foamed while generating heat and high-pressure gas. At this time, in the portion where the foamed thickness is thinly formed, And the pressure is applied, the polyurethane gradually inflates and deforms on the inner surface.

Also, the isocyanate is an aromatic isocyanate such as tolulene diisocyanate (MDI) or methylenediphenyl diisocyanate (MDI), which has a quinone imide structure due to ultraviolet rays, resulting in yellowing of the foamed urethane foam.

When the foamed urethane foam containing the polyester polyol is impregnated with the ultraviolet barrier cosmetic composition, the foam is gradually hardened over time and the surface is cracked and a part of the foam is broken.

In addition, amine is used as a catalyst in the production of foamed urethane foam. The amine is mostly volatilized by heat during the production of the foamed urethane foam, but there is a problem that the amine remains unpleasant to some people with sensitive smell.

Disclosure of Invention Technical Problem [8] Accordingly, the present invention has been made to solve the above problems, and an object of the present invention is to provide a cosmetic composition in which a low viscosity ultraviolet ray blocking composition of W / O is packaged in a compact type container.

In addition, the present invention solves the problem of yellowing and deformation of the inner urethane foam caused by the foamed urethane foam by impregnating the foamed NBR foam with a low-viscosity water-in-oil type UV blocking cosmetic composition instead of impregnating the conventional foamed urethane foam. The purpose is to do.

In addition, the present invention relates to a cosmetic composition containing a low-viscosity, water-in-oil type ultraviolet barrier cosmetic composition impregnated with a foamed NBR (nitrile butadiene rubber) foam and packaged in a compact type container, To provide a barrier cosmetic composition.

It is another object of the present invention to provide an ultraviolet screening product having a good ultraviolet screening effect and being easy to use and carry.

The present invention is characterized in that the ultraviolet light shielding composition is a compact formulation of an ultraviolet light blocking cosmetic composition impregnated with a foamed NBR (nitrile butadiene rubber) foam.

In addition, the foamed NBR (nitrile butadiene rubber) foam of the present invention is characterized by having a hardness of 15 to 35 on the basis of ASKER hardness F type (Type F) before impregnating the contents.

In addition, the foamed NBR (nitrile butadiene rubber) foam of the present invention has a density of 180 to 240 g / L before impregnating the contents.

In addition, the present invention is characterized in that the UV blocking composition has a viscosity of 5000 to 15000 cps.

In addition, the present invention is a cosmetic container containing a foamed NBR (nitrile butadiene rubber) foam impregnated with a cosmetic composition, wherein the composition contains an ultraviolet screening agent.

As described above, the ultraviolet barrier cosmetic composition prepared by impregnating a foamed NBR (nitrile butadiene rubber) foam according to the present invention comprises a cosmetic composition in which a low viscosity ultraviolet ray blocking composition of water-in-oil (W / O) is packaged in a compact type container .

In addition, the present invention improves the problem of yellowing phenomenon and inward deformation occurring in the foamed urethane foam by impregnating foamed NBR foam instead of impregnating the low viscosity, water-in-oil type ultraviolet barrier cosmetic composition into the conventional foamed urethane foam. .

The present invention also relates to a cosmetic composition containing a UV-blocking cosmetic composition having a low viscosity, which is impregnated with a foamed nitrile butadiene rubber (NBR) foam and packaged in a compact type container to improve user portability and convenience of use .

In addition, the present invention has an effect of providing an ultraviolet screening product having a good ultraviolet screening effect and being easy to use and carry.

1 is a perspective view of a foamed NBR (nitrile butadiene rubber) foam according to an embodiment of the present invention.
2 is a perspective view of a foamed NBR (nitrile butadiene rubber) foam according to another embodiment of the present invention.
3 is a cross-sectional view of a foamed NBR (nitrile butadiene rubber) foam according to another embodiment of the present invention.
4 is a perspective view of a foamed NBR (nitrile butadiene rubber) foam according to another embodiment of the present invention.

The ultraviolet barrier cosmetic composition prepared by impregnating the foamed NBR (nitrile butadiene rubber) foam 10 of the present invention will now be described.

FIG. 1 is a perspective view of a foamed NBR (nitrile butadiene rubber) foam according to an embodiment of the present invention, FIG. 2 is a perspective view of a foamed NBR (nitrile butadiene rubber) foam according to another embodiment of the present invention, FIG. 4 is a perspective view of a foamed NBR (nitrile butadiene rubber) foam according to another embodiment of the present invention. FIG. 4 is a perspective view of a foamed NBR (nitrile butadiene rubber) foam according to another embodiment of the present invention.

The present invention relates to a compact type (10), comprising a foamed NBR (nitrile butadiene rubber) foam (10) impregnated with a low viscosity water-in-oil type emulsion ultraviolet screening composition containing an oily component, an emulsifier, an organic or inorganic ultraviolet screening agent, It is a formulation.

The oily components used in the present invention include vegetable oils such as rosehip oil, safflower oil, peach seed oil, methoform seed oil and sunflower seed oil, dicaprylyl carbonate, squalane, neopentylglycol diheptanoate, Acetate, trioctanoin, C12-15 alkyl benzoate, C12-15 alkyl ethyl hexanoate, octyldodecyl myristate, tricaprylyl, octyldodecylstearoyl stearate, bis-hydroxyethoxypropyldimetate Chitosan, chicone, caprylic, capric triglyceride, isotridecylisononanoate, polyglyceryl-2 triisostearate, diisostearyl malate, dipentaerythritol pentaerythritide, cetyl octanoate, And synthetic esters or hydrocarbons such as carboxymethylcellulose, carboxymethylcellulose and carbitol, silicone oils such as phenyltrimethicone, cyclomethicone, dimethicone, decamethylcyclopentasiloxane and the like Up to more than one selected species, it is contained in an amount of 20 to 80% by weight relative to the total weight of the composition. If the oily component is less than 20% by weight, the stability of the composition is poor or the viscosity is too high, and the feeling of use is heavy and tacky, and the usability is poor. When the content is more than 80% by weight, the stability is poor.

As the emulsifier used in the present invention, a non-ionic surfactant having an HLB range of 1 to 6 and a low HLB is suitable for producing a water-in-oil type emulsion, and specifically, cyclopentasiloxane and PEG / PPG-18/18 dimethicone Cyclopentasiloxane and PEG / PPG-18/18 Dimethicone, Glycol Stearate, Sorbitan Sesquioleate, Glyceryl Oleate, Glycol Distearate, Propylene Glycol Propylene glycol monostearate, glyceryl stearate, sorbitan stearate, PEG-30 dipolyhydroxystearate, PEG-10 dimethicone (PEG- -10 Dimethicone), cyclopentasiloxane / PEG.PPG-19.19 dimethicone, sorbitan isostearate, lauryl PEG.PPG-18. (PEG-PPG-18.18 methicone), cetyl PEG.PPG-10.1 dimethicone, lauryl PEG-9 polydimethylsiloxyethyl dimethicone (Lauryl PEG- ), And it is contained in an amount of 0.01 to 10% by weight based on the total weight of the composition. When the amount of the emulsifier is less than 0.01% by weight, the emulsion is not formed or the stability of the composition is poor. When the amount of the emulsifier is more than 10% by weight, stickiness of the emulsifier itself and inherent odor are generated.

The ultraviolet screening agent used in the present invention may be used either individually or in combination with an organic ultraviolet screening agent or an inorganic ultraviolet screening agent. Specific examples of the organic ultraviolet screening agent include octyl methoxycinnamate, octyl salicylate, octocrylene, butyl methoxydibenzoylmethane, oxybenzone, octyltriazone, menthyl anthranilate, 3,4-methyl benzylidene kempfer, Isoamyl-P-methoxy cinnamate, bisethylhexyloxyphenol methoxyphenyltriazine, and methylenebisbenzotriazolyltetramethylbutylphenol. As the inorganic ultraviolet blocking agent, titanium dioxide having an average particle size of 5 to 100 nm , Zinc oxide having an average particle size of 5 to 300 nm, iron oxide having an average particle size of 5 to 300 nm, or the like can be used. At this time, the larger the average particle size of the inorganic sunscreen agent, the more the whitening phenomenon is applied to the skin, thereby decreasing the value of the product. On the other hand, when the particle size is too small, the skin penetrates into the skin to cause irritation. Is suitably 300 nm or less, and 10 to 50 nm is suitable when both skin irritation and cloudiness are considered at the same time.

In addition, the ultraviolet screening agent is contained in an amount of 1 to 35% by weight based on the total weight of the composition. When the ultraviolet screening agent is less than 1% by weight, the ultraviolet screening effect is insignificant to 10 (SPF index) or less. When the ultraviolet screening agent is more than 35% by weight, the whitening phenomenon and shine are worse.

The pigment used in the present invention may be at least one selected from the group consisting of PMMA (polymethylmethacrylate), silica, nylon, nitrile butadiene rubber (NBR), ultramarine, iron oxide, Mica, talc, cerasite and boron nitride can be mixed and used in an amount of 0.1 to 20% by weight based on the total weight of the composition. If the content of the pigment is less than 0.1% by weight, the effects such as adhesion, color, and agglomeration are insignificant. If the content is more than 20% by weight, the viscosity is excessively increased and the feeling of use becomes stiff and the stability of emulsification is deteriorated .

The water component used in the present invention is at least one selected from the group consisting of purified water, propylene glycol, 1,3-butylene glycol and glycerin, and is contained in an amount of 30 to 70% by weight based on the total weight of the composition. When the water phase component is less than 30% by weight, the viscosity is too low to lower the stability of the formulation. When the water phase component is more than 70% by weight, the viscosity becomes too high.

In addition to the above components, at least one selected from preservatives, fragrances and other additives may be further added to the ultraviolet screening composition. Particularly, parabens such as methylparaben, propylparaben, butylparaben, ethylparaben and the like which can be used as a preservative can be mixed into an oil phase, and in case of phenoxyethanol, they can be mixed with an aqueous phase.

In addition, the fragrance is added to the oil phase of the water-in-oil type at the final stage of the process for producing the composition.

The water-in-oil UV blocking cosmetic composition of the present invention has a low viscosity in the range of 5,000 to 15,000 cps. If the viscosity of the water-in-oil type ultraviolet barrier cosmetic composition is less than 5000 cps, separation of oil phase and water phase occurs immediately after preparation of the emulsion, so that it is difficult to impregnate into the NBR (nitrile butadiene rubber) foam 10 with a uniform composition. When the viscosity is more than 15000 cps There is a problem that the value as a product is deteriorated due to the sticky and heavy use feeling on the skin.

The UV-blocking cosmetic composition of the present invention is packed in a compact type container using a foamed NBR (nitrile butadiene rubber) foam 10. This is because the compact type container is excellent in portability compared to a tube or pump type container in terms of portability and ease of making, but in the case of a flowable cosmetic, it is likely to overflow or contaminate the container, 1, the ultraviolet barrier cosmetic composition is impregnated into a foamed NBR (Nitride Butadiene Rubber) foam 10 and embedded in a compact type container, as shown in FIG.

According to another embodiment, as shown in FIG. 2 to FIG. 3, the ultraviolet barrier cosmetic composition is impregnated with a foamed NBR (nitrile butadiene rubber) foam 10 having an impregnated hole 20, and is embedded in a compact type container .

As shown in FIG. 4, the foamed NBR (nitrile butadiene rubber) foam 10 may be formed such that the impregnated holes 20 are formed in a non-aligned manner.

The foamed NBR (nitrile butadiene rubber) foam 10 impregnated with the ultraviolet barrier cosmetic composition of the present invention can not impregnate the ultraviolet ray blocking cosmetic composition because the bubble is trapped in NBR (nitrile butadiene rubber) in the case of a closed cell An open cell shape is preferred.

In addition, the foamed NBR (nitrile butadiene rubber) foam 10 used in the present invention should be a proper NBR (nitrile butadiene rubber) foam 10, and it is suitably an open cell type foamed NBR nitrile butadiene rubber foam having a hardness of from 15 to 35 and a density of from 180 to 240 g / L in terms of DUROMETER HARDNESS measuring instrument type F (Type F) on the basis of ASKER NBR (nitrile butadiene rubber) foam 10 may be used.

If the hardness of the foamed foam 10 is less than 15 and the density of the foamed foam 10 is less than 180 g / L, the foamed foam 10 is too soft to impregnate the UV-blocking cosmetic material in a uniform distribution, There is a problem in that the water-in-oil type ultraviolet barrier cosmetic impregnated in a foamed NBR (nitrile butadiene rubber) foam 10 is excessively discharged when a tool or a hand is put on the makeup. When the hardness is more than 35 and the density is more than 240 g / L, There is a problem that the foam is hard and the ultraviolet blocking cosmetic material in the water-in-oil type can not easily be discharged.

In addition, the foamed NBR (nitrile butadiene rubber) foam 10 of the present invention includes at least one foamed foam having a pore number of 10 to 150 ppi (pore per inch). The pore number may be NBR (nitrile butadiene rubber) The number of pores per inch of the form.

If the number of pores in the foamed foam 10 is less than 10 ppi, the number of pores impregnated with the cosmetic composition will be low, resulting in poor penetration. If the foamed pore 10 has a pore number of more than 150 ppi, the pore number may be dense, . And more preferably 50 to 100 ppi.

Hereinafter, the production examples, examples and test examples of the present invention will be described in detail.

The following Preparation Examples, Examples and Test Examples are illustrative of the present invention, and the present invention is not limited to the following Production Examples, Examples and Test Examples.

[ Manufacturing example  ] firing NBR ( nitrile butadiene rubber ) On the form Impregnated  UV protection manufactured Cosmetics  Method of manufacturing composition

To the vessel of the stirring apparatus, 10.0% by weight of octyl salicylate and 2.0% by weight of titanium dioxide, an ultraviolet ray blocking agent, 0.1% by weight of peach seed oil as an oily component and 0.1% by weight of tecamethylcyclopentasiloxane And then emulsification was carried out. Then, 3% by weight of glycol stearate, 2.0% by weight of sorbitan sesquioleate and 0.1% by weight of methyl paraben, which is a preservative, were added and stirred uniformly while heating at 80 ° C. Respectively.

Then, 4.0 weight% of polymethyl methacrylate and 5.0 weight% of aluminum hydroxide were added and stirred to prepare an oily component.

40.2% by weight of water and 7.0% by weight of glycerin were added to another vessel of the stirring apparatus and uniformly mixed while heating and stirring at 80 DEG C to prepare an aqueous phase component.

0.4 weight% of the above water-based ingredients and fragrance were slowly added to a stirring device containing oil components, emulsified at 80 ° C, and then cooled to room temperature (25 ° C) to prepare a UV-blocking cosmetic having a low viscosity.

[ Test Example  One ] Stability experiment of formulation

The stability of the formulation was tested with the water-in-oil UV blocking cosmetic composition of the above Production Example. Example 1 was prepared by impregnating the composition of the present invention into a foamed NBR (nitrile butadiene rubber) foam having a hardness of 25 on the basis of ASKER hardness type F (Type F). In Comparative Example 1, And Comparative Example 2 was obtained by storing the composition of Production Example in a plastic container. The stability was tested in accordance with the conditions shown in Table 1 below, and the results are shown in Table 1 below. Table 1 shows the results obtained when Example 1 and Comparative Examples 1 and 2 were stored at 50 占 폚 for 2 hours.

division 45 ° C
10 days past
Cycle [45 ° C → 30 ° C → freezing (-10 ° C) for each 8 hours]
Five days past
50 ℃
2 hours elapsed
Example 1 stability stability Appearance stability Comparative Example 1 detach detach Appearance bubble generation Comparative Example 2 detach detach Appearance bubble generation

As shown in Table 1, Comparative Example 1 in which a low-viscosity water-in-oil UV blocking cosmetic composition according to the present invention was stored in a tube container and Comparative Example 2 in which the cosmetic composition was stored in a plastic container, And the formulation was unstable.

On the other hand, in Example 1, which was impregnated with a foamed NBR (nitrile butadiene rubber) foam, it can be confirmed that the formulation is stable even when the temperature changes and time elapses.

[ Test Example  2 ] firing NBR ( nitrile butadiene rubber ) Preference test according to hardness of foam

The nitrile butadiene rubber foam was impregnated with each of the above preparation examples and then applied to skin using a makeup tool to compare differences in preference according to hardness of NBR (nitrile butadiene rubber) foam.

Example 2 is obtained by impregnating an NBR (nitrile butadiene rubber) foam having a hardness of 5 in Example 2, a NBR (nitrile butadiene rubber) foam having a hardness of 25 in Example 3, The composition of the production example is impregnated with NBR (nitrile butadiene rubber) foam having hardness of 50.

The above Examples 2 to 4 were cremated for 50 days for women in their 20s and 30s for 7 days, and the use results were compared and evaluated. The preference according to the hardness of the foamed foam was evaluated by a questionnaire consisting of sensory evaluation (5 point scaling method), and it was rated as excellent 5 points, good 4 points, average 3 points, poor 2 points and very poor 1 point. The evaluation scores are shown in Table 2 below.

division Foam NBR (nitrile butadiene rubber) foam hardness used for impregnation
(ASKER hardness F type)
preference
Example 2 5 2.4 Example 3 25 4.8 Example 4 50 3.8

As shown in Table 2, Example 3 in which NBR (nitrile butadiene rubber) foam having a hardness of 25 was impregnated with the composition of the production example showed the highest degree of preference.

[ Test Example  3] firing NBR ( nitrile butadiene rubber ) Of foam Pore  Experiment of preference according to number

The above preparation examples were compared with each other in terms of the number of pores of the nitrile butadiene rubber (NBR) foam when they were applied to the skin using a makeup tool after impregnating the foam with NBR (nitrile butadiene rubber).

Example 5 is obtained by impregnating a nitrile butadiene rubber (NBR) foam having a pore number of 5 ppi with the composition of the production example. In Example 6, the composition of the example is impregnated with a nitrile butadiene rubber (NBR) foam having a pore number of 60 ppi, Example 7 is obtained by impregnating a composition of the production example into a nitrile butadiene rubber (NBR) foam having a pore number of 200 ppi.

The above Examples 5 to 7 were cremated for 50 days in the 20s and 30s for 7 days, and the use results were compared and evaluated. The preference according to the hardness of the foamed foam was evaluated by a questionnaire consisting of sensory evaluation (5 point scaling method), and it was rated as excellent 5 points, good 4 points, average 3 points, poor 2 points and very poor 1 point. The evaluation scores are shown in Table 3 below.

division Foamed NBR (nitrile butadiene rubber) foam used for impregnation
Number of pores (ppi)
preference
Example 5 5 2.6 Example 6 60 4.7 Example 7 200 3.4

As shown in Table 3, Example 6 in which the composition of the preparation example was impregnated with NBR (nitrile butadiene rubber) foam having a pore number of 60 ppi showed the highest preference.

As described above, the present invention is not limited to the UV-blocking cosmetic composition prepared by impregnating foamed NBR (nitrile butadiene rubber) foam. The present invention is not limited to the above-described embodiments, It is to be understood that the present invention is not limited to the disclosed embodiments, but, on the contrary, is intended to cover various modifications and equivalent arrangements included within the spirit and scope of the appended claims and their equivalents. Lt; / RTI >

10: Foamed NBR foam 20: impregnated hole

Claims (19)

An ultraviolet light blocking cosmetic composition is impregnated in a foamed NBR (nitrile butadiene rubber) foam 10,
The foamed NBR (nitrile butadiene rubber) foam 10 is impregnated with a foamed NBR foam having a hardness of 15 to 35 on the basis of an ASKER hardness F type (Type F) before impregnating the contents. Wherein the cosmetic composition is an ultraviolet light.
The method according to claim 1,
Wherein the ultraviolet ray blocking cosmetic composition is a water-in-oil type, and the ultraviolet ray blocking cosmetic composition is impregnated in a foamed NBR foam.
The method according to claim 1,
Wherein the ultraviolet light blocking cosmetic composition has a viscosity of 5000 to 15000 cps.
The method according to claim 1,
Wherein the nitrile butadiene rubber foam (10) has a density of 180 to 240 g / L prior to impregnating the contents with the foamed NBR foam.
The method according to claim 1,
Wherein the foamed NBR (nitrile butadiene rubber) foam 10 has a pore number of 10 to 150 ppi (pore per inch).
The method according to claim 1,
Wherein the ultraviolet barrier cosmetic composition comprises 20 to 80% by weight of an oily component, 0.01 to 10% by weight of an emulsifier, 1 to 35% by weight of at least one selected from the group consisting of an organic ultraviolet screening agent and an inorganic ultraviolet screening agent, To 20% by weight of the composition and 30 to 70% by weight of the water-based component.
The method according to claim 6,
Wherein the oily component is at least one selected from the group consisting of vegetable oils, synthetic esters, hydrocarbons and silicone oils.
The method according to claim 6,
Wherein the emulsifier is a nonionic surfactant having an HLB in the range of 1 to 6. 5. The ultraviolet blocking cosmetic composition according to claim 1,
The method according to claim 6,
The organic UV blocking agent may be at least one selected from the group consisting of octylmethoxycinnamate, octyl salicylate, octocrylene, butylmethoxydibenzoylmethane, oxybenzone, octyltriazone, menthyl anthranilate, 3,4- -P-methoxycinnamate, bisethylhexyloxyphenol methoxyphenyltriazine, and methylenebisbenzotriazolyltetramethylbutylphenol, which is prepared by impregnating a foamed NBR foam with ultraviolet rays Cosmetic composition.
The method according to claim 6,
Wherein the inorganic UV-blocking agent is at least one selected from the group consisting of titanium dioxide, zinc oxide, and iron oxide.
The method according to claim 6,
The pigment is at least one selected from the group consisting of PMMA (polymethylmethacrylate), silica, nylon, polyurethane, ultramarine, iron oxide, pearl, synthetic mica, mica, talc, cerasite and boron nitride By weight of the foamed NBR foam.
The method according to claim 6,
Wherein the aqueous phase component is at least one selected from the group consisting of purified water, propylene glycol, 1,3-butylene glycol and glycerin.
The method according to claim 1,
Characterized in that the foamed NBR (nitrile butadiene rubber) foam (10) is an open cell structure, and the foamed NBR foam is impregnated into a foamed NBR foam.
The method according to claim 1,
Characterized in that the foamed NBR (nitrile butadiene rubber) foam (10) is provided with an impregnated hole (20).
A cosmetic container having a foamed NBR (nitrile butadiene rubber) foam (10) impregnated with a cosmetic composition.
16. The method of claim 15,
Characterized in that the foamed NBR (nitrile butadiene rubber) foam (10) has an impregnated hole (20).
16. The method of claim 15,
Wherein said composition comprises an ultraviolet screening agent.
18. The method of claim 17,
The ultraviolet shielding agent may be at least one selected from the group consisting of octylmethoxycinnamate, octyl salicylate, octocrylene, butylmethoxydibenzoylmethane, oxybenzone, octyltriazone, menthyl anthranilate, 3,4-methylbenzylidene kempfer, isoamyl- Wherein the cosmetic container is at least one selected from the group consisting of P-methoxy cinnamate, bishexyloxyphenol methoxyphenyltriazine, and methylene bisbenzotriazolyltetramethylbutylphenol.
18. The method of claim 17,
Wherein the ultraviolet screening agent is at least one selected from the group consisting of titanium dioxide, zinc oxide, and iron oxide.
KR1020140186583A 2014-12-22 2014-12-22 UV blocking cosmetic composition prepared by being impregnated in NBR(nitrile butadiene rubber) foam KR20160076408A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
KR1020140186583A KR20160076408A (en) 2014-12-22 2014-12-22 UV blocking cosmetic composition prepared by being impregnated in NBR(nitrile butadiene rubber) foam
PCT/KR2015/014005 WO2016105042A2 (en) 2014-12-22 2015-12-21 Ultraviolet ray-blocking cosmetic composition prepared by means of impregnation into nbr foam

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020140186583A KR20160076408A (en) 2014-12-22 2014-12-22 UV blocking cosmetic composition prepared by being impregnated in NBR(nitrile butadiene rubber) foam

Publications (1)

Publication Number Publication Date
KR20160076408A true KR20160076408A (en) 2016-06-30

Family

ID=56151585

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020140186583A KR20160076408A (en) 2014-12-22 2014-12-22 UV blocking cosmetic composition prepared by being impregnated in NBR(nitrile butadiene rubber) foam

Country Status (2)

Country Link
KR (1) KR20160076408A (en)
WO (1) WO2016105042A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018016931A1 (en) * 2016-07-22 2018-01-25 코스맥스 주식회사 Cosmetic product including cosmetic container using specific rubber

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101257628B1 (en) * 2011-03-24 2013-04-29 (주)아모레퍼시픽 Cosmetics comprising cosmetic composition impregnated in urethane foam
KR20130116182A (en) * 2012-04-12 2013-10-23 (주)아모레퍼시픽 Foamed material of improvement in use
US9585456B2 (en) * 2012-04-13 2017-03-07 Amorepacific Corporation Cosmetic composition container comprising foam
US9532934B2 (en) * 2012-04-13 2017-01-03 Amorepacific Corporation Cosmetic composition carrier comprising foams
KR101355051B1 (en) * 2012-05-09 2014-01-27 (주)아모레퍼시픽 UV blocking cosmetic composition prepared by being impregnated in urethane foam

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018016931A1 (en) * 2016-07-22 2018-01-25 코스맥스 주식회사 Cosmetic product including cosmetic container using specific rubber

Also Published As

Publication number Publication date
WO2016105042A2 (en) 2016-06-30
WO2016105042A3 (en) 2016-08-18

Similar Documents

Publication Publication Date Title
KR101355051B1 (en) UV blocking cosmetic composition prepared by being impregnated in urethane foam
KR101159877B1 (en) UV blocking cosmetic composition prepared by being impregnated in urethane foam
KR101945203B1 (en) Airless Type Container Filled with Foamy Urethane Foam for Impregnating Cosmetic Composition
KR101551370B1 (en) Cosmetic composition for uv-protecting prepared being impregnated in a sponge foam
US8784854B2 (en) Cosmetic product comprising UV-blocking cosmetic composition impregnated into expanded urethane foam
US10647809B2 (en) Viscosity modification of organic phase containing compositions
CN103209676A (en) Sunscreen composition
CN111867551A (en) Cosmetic composition for cutting ultraviolet rays, having ultraviolet ray cutting efficiency increased by ultraviolet rays
KR20230047985A (en) Sunscreen composition comprising polyglyceryl surfactants
CN105188652A (en) Cosmetic or dermatological emulsion comprising a merocyanine and an emulsifying system containing an alkali metal salt of a phosphoric acid ester of a fatty alcohol
KR20200055589A (en) UV protection cosmetic composition comprising waterborne polyurethane
US20200297604A1 (en) Sprayable Sunscreen Compositions and Methods
KR102134931B1 (en) Cosmetic composition comprising transparent and visible spherical particles
KR102092297B1 (en) Cosmetics of water insoluble sponge containing cosmetic compositions of sunscreen function
CN105188654A (en) Cosmetic or dermatological water-in-oil emulsion comprising a merocyanine and at least one emulsifying polymer of the polyoxyalkylenated glycol fatty acid ester type
KR20230147588A (en) A cosmetic composition having chromatic emulsion phase for protecting UV
KR20060024612A (en) Sheet type sun block product
KR20160076408A (en) UV blocking cosmetic composition prepared by being impregnated in NBR(nitrile butadiene rubber) foam
KR101944236B1 (en) Cosmetic composition
KR102587340B1 (en) make-up cosmetic composition having improved feeling of use
CN108904301B (en) Cosmetic comprising water-insoluble sponge impregnated with cosmetic composition having ultraviolet shielding function
US20130045258A1 (en) Cosmetic product comprising uv-blocking cosmetic composition impregnated into expanded urethane foam
KR20030046103A (en) Preparation method for Oil-in-Water sun block emulsion composition
JP2022522684A (en) UV blocking cosmetic composition whose UV blocking efficiency is increased by UV rays
KR20160086728A (en) Cosmetics of water insoluble sponge containing cosmetic compositions of sunscreen function

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
AMND Amendment
E601 Decision to refuse application
AMND Amendment
J201 Request for trial against refusal decision
J301 Trial decision

Free format text: TRIAL NUMBER: 2017101001548; TRIAL DECISION FOR APPEAL AGAINST DECISION TO DECLINE REFUSAL REQUESTED 20170330

Effective date: 20180717