KR20200055589A - UV protection cosmetic composition comprising waterborne polyurethane - Google Patents

Abstract

The present invention relates to a UV protection cosmetic composition comprising: water-dispersible polyurethane; a hydrophilic thickener; and an organic sunscreen, and having water resistance. The cosmetic composition can stably maintain oily and aqueous components without containing an emulsifier, and has water resistance.

Description

UV protection cosmetic composition comprising waterborne polyurethane containing water-dispersible polyurethane

It relates to a cosmetic composition for sunscreen having water resistance.

The sunscreen market has been growing rapidly in recent years. Among ultraviolet rays, UVA is a light beam having a long wavelength of about 320 to 400 nm, and is known to reach the dermis layer with low energy but high transmittance. Therefore, in the sunscreen, the PA index, which is an index showing the blocking effect of UVA, is a factor to be considerably considered from both the developer and the consumer. In addition, the UVA blocking index was the largest PA +++ in the past, but it has been written from January 2013 in Japan to PA ++++ in December 2016 in Korea and China. Some organic sunscreens and inorganic sunscreens can be used as raw materials to prevent UVA. However, in the case of an organic sunscreen that can block the UVA region, there is a problem that an excessive amount cannot be applied to the formulation due to a precipitation problem in a silicone heavy water formulation, which makes it difficult to use in PA ++++ products.

For example, Republic of Korea Patent Publication No. 2014-0062695 discloses a water-drop type water-in-silicone (W / S) macro emulsion cosmetic composition. The cosmetic composition is based on a non-emulsifiable silicone elastomer, and contains about 13% of an oil phase (including silicon oil). The above method is difficult to apply to prepare SPF 50+ and PA ++++ formulations, and is difficult to apply to oil-in-water formulations because of the use of salt, and has a disadvantage in that water resistance is good due to a silicone oil, but heavy in use.

On the other hand, polyurethane (Polyurethane, PU) refers to a compound having a urethane or urea bond in a repeating unit by reacting isocyanate with polyol, diol or diamine. Polyurethane has been applied to various fields such as coating, adhesive, elastic body, fabric, synthetic leather, foam, elastic body, fiber, synthetic leather, waterproofing agent, paint, adhesive due to various physical properties. However, polyurethane as a cosmetic component is only partially used for nails, mascara, and the like.

The present inventors developed a cosmetic composition having excellent water resistance and high UV protection index by forming a polyurethane film in an oil-in-water (O / W) formulation with a light feeling of use.

Provided is a cosmetic composition for sunscreen having water resistance, comprising a water-dispersible polyurethane, a hydrophilic thickener, and an organic sunscreen.

One aspect is a water-dispersible polyurethane; Hydrophilic thickeners; And it provides a cosmetic composition for sunscreen having water resistance, including an organic sunscreen.

The water-dispersible polyurethane may be included in 0.2 to 5.0% by weight, or 0.5 to 2.0% by weight based on the total weight of the composition. The water-dispersible polyurethane may have a heavy feeling of use and thick film formation when it exceeds 2.0% by weight, and the emulsion stability may be low when it is less than 0.5% by weight. The water-dispersible polyurethane is, for example, polyurethane-1, polyurethane-2, polyurethane-6, polyurethane-7, polyurethane-10, polyurethane-11, polyurethane-12, polyurethane-13 Polyurethane-14, Polyurethane-15, Polyurethane-16, Polyurethane-17, Polyurethane-18, Polyurethane-19, Polyurethane-21, Polyurethane-35, V / dimethiconylacrylate / poly Carbamill / polyglycol ester, VP / dimethylaminoethyl methacrylate / polycarbamill polyglycol ester, VP / dimethiconyl acrylate / polycarbamill / polyglycol ester, VP / polycarba It may be one or more selected from the group consisting of wheat polyglycol ester, styrene / acrylate copolymer / polyurethane, and combinations thereof. The water-dispersible polyurethane has a self-emulsifying property, and thus has an excellent feeling of use without the use of an emulsifier, and can provide water resistance to a cosmetic composition by forming a polyurethane film on the skin surface.

The hydrophilic thickener may be included in 0.05 to 5.0% by weight, or 0.3 to 1.5% by weight based on the total weight of the composition. The hydrophilic thickener may have a heavy feeling when used in excess of 1.5% by weight, and may have poor formulation stability due to low viscosity when less than 0.3% by weight. The hydrophilic thickener is, for example, carbomer, sodium polyacrylate, acrylate / C10-30 alkyl acrylate cross polymer, acrylamide / sodium acrylate copolymer / trideceth-6 / mineral salt, ammonium acrylic Loyl dimethyl taurate, acrylate, ammonium acrylate copolymer, VP copolymer, acrylate copolymer, glyceryl acrylate, acrylic acid copolymer, lithium magnesium sodium silicate, hydroxyethyl cellulose, polyacrylamide, montmorillonite , Cetyl hydroxyethyl cellulose, agar, octyl acrylamide copolymer, cellulose, polyacrylate-13, corn starch, PEG-240 / H diacopolymer bis-decyl tetradeceth-20 ether, octyl acrylamide co Polymer, met, gellan gum, aluminum star octenyl succinate, xanthan gum, carob bean gum, sodium acryloyl dimethyl taurate copolymer. It may be one or more selected from the group consisting of sodium polyacrylate starch, sodium stearoxy sebum-hydroxyethyl cellulose sulfonate, or a combination thereof.

The organic sunscreen may be included in 5 to 40% by weight, or 10 to 30% by weight based on the total weight of the composition. The organic sunscreen is, for example, bis-ethylhexyloxyphenolmethoxyphenyltriazine, butylmethoxydibenzoylmethane, diethylaminohydroxybenzoylhexylbenzoate, disodiumphenyldibenzimidazoletetrasulfonate, dromet Resoltrisiloxane, menthyl anthranylate, methylenebis-benzotriazolyltetramethylbutylphenol, terephthalidene dicamper sulfonic acid, terephthalidene dicamper sulfonic acid, benzophenone-3, benzophenone-4, polysilicon- 15, ethylhexylmethoxycinnamate, ethylhexyl salicylate, ethylhexyltrizone, homosalate, isoamyl p-methoxycinnamate, octocrylene, phenylbenzimidazole sulfonic acid, trisbisphenyltriazine , Or a combination of these. In addition to the organic sunscreen, the cosmetic composition may further include an inorganic sunscreen such as titanium dioxide or zinc oxide.

The cosmetic composition may further include a polyol. The polyol may be included in 1 to 15% by weight, or 5 to 10% by weight based on the total weight of the composition. The polyol is, for example, glycerin, glycereth-26, PEG-32, dipropylene glycol, methylglucose-20, PEG-8, PEG-75, propylene glycol, butylene glycol , Raffinose, inositol, sorbitol, maltitol, methylgluceth-10, or combinations thereof.

The cosmetic composition may not contain an emulsifier. This is interpreted as meaning not only that the emulsifier is not included at all, but also that it is contained in an amount effective to the extent generally recognized in the art, that is, it is not included as an active ingredient and does not significantly affect the physical properties of the composition. Should be. Specifically, when the cosmetic composition contains less than 0.5%, 0.1%, 0.05%, 0.01% or 0.001% of the total weight of the emulsifier, it may be considered that the emulsifier is not included. Ingredients that can be used as emulsifiers in the art include polysorbate 20, polysorbate 60, polysorbate 80, glyceryl stearate, PEG-100 stearate, sorbitan stearate, sorbitan sesquioleate, PEG -7 glyceryl cocoate, cetrimonium chloride, lauryl phosphate, PEG-40 stearate, PEG-5 glyceryl stearate, PEG-23 stearate, sucrose stearate, butyl alcohol, olive oil PEG-7 ester, PEG-150 stearate, polyglyceryl-3 methylglucose distearate, glycerylolibate, sorbitan oleate, ceteareth-30, steareth-20, PEG-12diisoste Are ?, PEG-8 diisostearate, PEG-10 isostearate, ceteayl alcohol, phyji-4cetes-20, hydrogenated lecithin, hydrogenated olive oil laminator, poly Sorbate 85, Sorbes-30 tetraolibate, hydrogenated polyisobutene, myristylylstate, steareth-2, steareth 21, paulylpiage, fiji-18, 18dibecicone, fiage -7 dimethicone, PEG-10 dimethicone, cetyl PEG phyji-10 1 dimethylcone, PEG-3 dimethicone, pyji-19 dimethicone, lauryl PEG-9 polydimethylsiloxyethyl Dimethicone, polyglyceryl-4isostearate, PEG-8dimethicone, PEG-7dimethicone, polyglyceryl-3polydimethylsiloxyethyldimethicone, lauryl-3polydimethylsiloxy Echil dimethicone, page-20 hydrogenerated castor oil, page-40 hydrogenated castor oil, page 40-40 hydrogenerated castor oil, C12-14 Palace-12, polyglyceryl-19 laurate , Polyglyceryl-10 myristate, choles-14, choles-20, choles 24, page-20glyceryl triisostearate, octyldodes-16, polyglyceryl-10oleate, poly Glyceryl-4 caprate, and cetes-10, and the like. The cosmetic composition may provide an O / W formulation composition having stable oil-phase and water-phase components and water resistance without containing an emulsifier.

In addition, the cosmetic composition may include an oil phase portion further comprising at least one oil selected from the group consisting of silicone oil, ester oil, vegetable oil, animal oil, mineral oil, or a combination thereof. The silicone oil is cyclomethicone, cyclopentasiloxane, cyclohexasiloxane, phenyltrimethicone, dimethicone, dimethicolol, cetyldimethicone, caprylylmethicone, amodimethicone, methyltrimethicone, PCD-dimethicone At least one selected from the group consisting of chicon, trisiloxane, and ester oils are caprylic / caprylic glyceride, cetearyl ethyl hexanoate, isopropyl myristate, isocetyl stearate, octyldodecanol , Methylperfluoroisobutyl ether, C12-15 alkenylbenzoate, triethylhexanoin, cetylethylhexanoin, cholesterylhydroxystearate, diisostearyl malate, isotridecyl isononanoate , Isononyl sononanoate, neopentyl glycol dicaprate, di-C12-13 alkyl maleate, butylene glycol dicaprylate / dicaprate, butyl octyl salicylate, hydrogenated poly (C6-14 olefin) ), Hydrogenated polydecene, cetyl ethyl hexanoate, tribehenin, tricapryline, diethoxyethoxy succinate, tricapryline, and one or more selected from the group consisting of vegetable oil, olive oil , Jojoba seed oil, avocado oil, macadamia seed oil, rosehip fruit oil, meadow form seed oil, tea tree leaf oil, squalane, grape seed oil, rice bran oil, sweet almond oil, American hazel oil, mountain tree oil, camellia oil, One or more selected from the group consisting of almond oil, gimmal palm oil, sunflower oil, and bazaar oil, and the animal oil is at least one selected from the group consisting of hospat, mink oil, egg yolk oil, and squalane, and the mineral oil is mineral oil , Isododecane, polybutene, petrolatum.

The cosmetic composition is a lotion (skin lotion), skin softener, skin toner, astringent, lotion, milk lotion, moisture lotion, nutrition lotion, massage cream, nutrition cream, moisture cream, hand cream, foundation, essence, nutrition essence, pack, Soaps, cleansing foams, cleansing lotions, cleansing creams, body lotions, body cleansers, suspensions, gels, powders, pastes, pacts, mask packs, or may be prepared as a formulation comprising a sheet or aerosol composition. Compositions of these formulations can be prepared according to methods conventional in the art.

The cosmetic composition is a preservative, stabilizer, surfactant, thickener, solubilizer, moisturizer, emollient, ultraviolet absorber, preservative, disinfectant, emulsifier, antioxidant, pH adjuster, organic and inorganic pigments, fragrances, coolants or limiting agents, etc. Additives commonly used in the art may be further included. The compounding amount of the additional ingredients such as the preservative can be easily selected by those skilled in the art within a range that does not impair the objects and effects of the present invention, and the compounding amount may be 0.001 to 40% by weight based on the total weight of the composition.

The sunscreen cosmetic composition comprising a water-dispersible polyurethane, a hydrophilic thickener, and an organic sunscreen, can stably maintain oily and aqueous components without containing an emulsifier, and may have water resistance.

1 is a photomicrograph of emulsifying particles using a polyurethane film without an emulsifier according to an aspect of the present invention.
Figure 2 is a photograph after applying the skin-forming film-forming cosmetic formulation according to an aspect of the present invention (top) and after peeling (bottom).
3 is a photomicrograph of the cosmetic composition particles to which a general polyacrylate film is applied as a comparative example.
4 is a photomicrograph of the cosmetic composition particles to which a general polysorbate 60 is applied as an example.

Hereinafter, the present invention will be described in more detail through examples. However, these examples are for illustrative purposes only, and the scope of the present invention is not limited to these examples.

Manufacturing example. Oil-in-water cosmetic production

The cosmetic compositions of Examples 1 and 2 and Comparative Examples 1 and 2 were prepared under the conditions shown in Table 1 below.

Prize Raw material name Example  One
(weight % ) Comparative example  One
(weight % ) Example  2
(weight % ) Comparative example  2
(weight % ) end
Purified water Balance Balance Balance Balance glycerin 5.0 5.0 5.0 5.0 Butylene Glycol 2.0 2.0 2.0 2.0 Xanthan gum 0.4 0.4 0.4 0.4 Water soluble polyurethane 40% + Purified water  60% 3.0 5.0 receptivity Polyacrylate  40% Purified water  60% 3.0 I Avobenzone 3.0 3.0 3.0 3.0 Bis - Ethylhexyloxyphenol methoxyphenyltriazine 5.0 5.0 5.0 5.0 Ethylhexylmethoxycinnamate 7.5 7.5 7.5 7.5 Ethylhexyl salicylate 5.0 5.0 5.0 5.0 Benzophenone 3 5.0 5.0 5.0 5.0 All Polysorbate  60 2.0 Cyclomethicone 5.0 5.0 5.0 5.0 la Phenoxy ethanol Proper Proper Proper Proper Hydroxyacetophenone Proper Proper Proper Proper

A: Award

B: Award of sunscreen

C: Paid

D: Preservative Award

The specific manufacturing method is as follows.

The composition of Table 1 was weighed, and the aqueous phase was dispersed at 5,000 rpm for 5 minutes using a homomixer (HOMOGENIZING MXER Model 2.5 PRIX, Japan) (step 1). Thereafter, the oil phase was slowly added at 5,000 rpm over 5 minutes (steps 2 to 3), followed by primary emulsification and secondary dispersion (steps 3 to 4).

1. For the base production, the virtual scale is precisely weighed and weighed in a container, and then dispersed in the water phase using an azimuth mixer.

2. Accurately measure the multiphase of the spiral phase, warm it to 75 ℃ and mix it.

3. Maintain 50 ℃, and mix the multi-mixed phases with virtually and emulsify them uniformly using a homomixer.

4. After the emulsification is completed, add the Ra phase.

5. Cool the contents to 30 ℃.

Experimental Example 1. Observation of specificity of emulsified particles and formulation

The compositions of Examples 1 and 2 and Comparative Examples 1 and 2 were observed for particle size, emulsification state or after skin application.

Figure 1 shows that the cosmetic composition of Example 1 was observed with an optical microscope (OLYMPUS BX53PH). It was observed that stable particles were formed as shown in FIG. 1. Figure 2 shows what was observed after applying the cosmetic composition of Example 2 to the skin. When the cosmetic composition of Example 2 was applied to the skin, it was observed to peel off from the skin in a film form after drying compared to Example 1 (top) (bottom).

3 shows that the cosmetic composition of Comparative Example 1 was observed with an optical microscope. In the case of Comparative Example 1 to which a general polyacrylate film was applied, the emulsified particles were unstable as shown in FIG. 3, and after drying, there was a phenomenon in which a feeling of foreign body was felt due to the formation of a film without elasticity.

Figure 4 shows what was observed with an optical microscope (OLYMPUS BX53PH) of Comparative Example 2 to which an emulsifier (polysorbate 60) was applied. As shown in FIG. 4, a gel-type formulation having a general feeling of use while forming stabilized particles was implemented.

Experimental Example 2. Formulation stability test

For Examples 1 and 2 and Comparative Examples 1 and 2, viscosity change and pH change after storage on the same day, 1 day, 1 week, 30 days at 25 ° C. (room temperature), 4 ° C. (low temperature), or 50 ° C. (high temperature), respectively. It was measured and the results are shown in Table 2 (analysis condition: Brookfiled Viscometer DV3TLV 64Spindle 12RPM 1.0min).

division Example 1 Comparative Example 1 Example 2 Comparative Example 2 exam Measurement day Temperature (℃) Viscosity day 25 28,500 50,000 44,500 25,550 1 day 25 28,700 45,000 44,860 26,100 1 week 25 27,690 32,000 43,950 26,690 4 28,450 33,000 44,700 26,550 50 27,650 28,500 44,750 25,650 30 days 25 27,450 Separation 43,860 24,450 4 28,550 Separation 44,650 25,650 50 27,720 Separation 44,800 25,650 pH day 25 6.99 7.01 6.98 6.98 1 day 25 6.97 70.5 7.00 6.99 1 week 25 6.98 6.99 6.99 6.97 4 6.99 6.99 6.98 6.96 50 6.88 6.98 6.99 6.70 30 days 25 6.99 6.97 6.97 6.99 4 6.95 6.98 6.98 6.97 50 6.94 6.96 6.97 6.99

As can be seen from Table 2, in the case of Examples 1, 2 and Comparative Example 2, it was confirmed that a stable formulation was maintained for 30 days in harsh conditions of low temperature or high temperature. That is, it was confirmed that the compositions of Examples 1 and 2 secured stability similar to Comparative Example 2 in which an emulsifier was applied without adding an additional emulsifier. On the other hand, in Comparative Example 1 to which water-soluble polyacrylate was applied, a phenomenon in which the viscosity gradually lowered over time and was separated after 30 days was observed. That is, although water-soluble polyurethane has little or no emulsifying power, the water-based thickener can help with particle formation and stability, so formulation stability can be maintained.

Experimental Example 3. Light stability test

Discoloration test after light irradiation was carried out for Examples 1 and 2 and Comparative Examples 1 and 2. Specifically, discoloration was observed with the naked eye after irradiation with ultraviolet rays (280-400 nm) for 24 hours.

As a result of the ultraviolet irradiation, there was no change in color of Examples 1 and 2 and Comparative Examples 1 and 2, and it was confirmed that it had light stability equivalent to that of a general emulsification system, and it was confirmed that there was no influence of light stability by the urethane film.

Light irradiation conditions: Solar simulator: 250 ~ 765 W / m ² Xenon lamp by Atlas

Experimental Example 4. Confirmation of UV protection effect

Samples of Examples 1 and 2 and Comparative Examples 1 and 2 were tested and tested for UV blocking ability 10 times each using SPF ANALAZER.

As can be seen from Table 3 below, it was confirmed that Examples 1 and 2 and Comparative Examples 1 and 2 did not show a significant difference in UV protection. This shows that Examples 1 and 2 using polyurethane have the same UV blocking effect as Comparative Example 2 of the general emulsifying type (analysis condition: Labsphere UV-2000S, In-vitro test).

division Example 1 Comparative Example 1 Example 2 Comparative Example 2 SPF (before After 85.7 MED ) 50.8 51.0 51.3 52.0 UVA / UVB  Ratio 0.97 0.95 1.02 0.94 Average UVA PF 17.4 17.0 17.6 17.1

Experimental Example 5. Water resistance test

Using the cosmetic compositions of Examples 1 and 2 and Comparative Examples 1 and 2, water resistance tests were performed under the conditions shown in Table 4 below.

Sample application area Application amount Water temperature Acquisition time / drying time 70.0 X 70.0 mm ² 2.0 mg / cm ² 23 ~ 28 ℃ 20 minutes / 20 minutes * 2 times

70.0 × 70.0 area using a PMMA plate in mm ² 2.0 mg / cm ² After coating as much as possible, it was obtained for about 20 minutes in water at 23 to 28 ° C. and dried twice for 20 minutes, and then 10 times per each sample.

The result value for water resistance, that is, the water resistance ratio, was calculated through Equation 1 below, and the results are shown in Table 5 below. When the water resistance ratio was 50% or more, it was designated as water resistance.

<Calculation formula 1>

Water resistance ratio = (SPFi-1) / (SPFi-1) * 100

* Within SPFi: Water resistant UV protection index of each sample

* SPFi: UV blocking index of each sample

division Example 1 Comparative Example 1 Example 2 Comparative Example 2 SPF of the sample 52.8 51.0 51.6 55.0 Sample water resistance SPF 35.2 30.9 37.6 24.0 Water resistance ratio 66.67 60.59 72.86 46.24

As shown in Table 5 above, it was confirmed that the water resistance of the samples of Examples 1, 2 and Comparative Example 2 was. From this, it can be seen that an oil-in-water type sunscreen cosmetic using a water-soluble polyurethane film is an oil-in-water formulation and has excellent water resistance. On the other hand, Comparative Example 2, which is a general emulsifying type, uses the same sunscreen as Examples 1 and 2 as a main component, but was confirmed to have no water resistance.

Experimental Example  6. Sensory evaluation

30 female panelists aged 25-45 were divided into two groups, and Example 1, 2 and Comparative Examples 1 and 2 were appropriately adjusted in each group to be used for both parts of the face. Table 4 below shows the results of evaluating the feeling of use such as spreading feeling, residual feeling, freshness, and overall satisfaction.

Among the above criteria, spreadability refers to the feeling of being rolled and absorbed by the skin when first applied to the skin, and a light application feeling is a cosmetic suitable for suncare cosmetics. The residual feeling is a feeling of use by oil and wax remaining on the skin due to the characteristic properties of the sunscreen after being applied to the skin, and the less the residual feeling, the more suitable for the sunscreen cosmetic. The freshness is the overall feeling of use after absorption. The lower the viscosity and the lighter the formulation, the better the sunscreen cosmetic. Such standards increase the value of use as a cosmetic and may be an important feature of a UV-blocking functional cosmetic.

<Evaluation criteria>

24 or more women judged to be excellent: ◎

18-23 women judged to be excellent: ○

10-17 women judged to be excellent: △

10 or fewer women judged to be excellent: X

division Example 1 Comparative Example 1 Example 2 Comparative Example 2 Spreadability ◎ X ○ X Residual feeling ◎ X ○ ○ Neatness ○ △ △ △ Overall satisfaction ◎ X ○ △

As shown in Table 6, Example 1 had good overall satisfaction, and Example 2 also had relatively excellent effects such as spreadability, residual feeling, and freshness. Comparative Examples 1 and 2 showed a tendency to be less satisfied with the usability compared to products manufactured by the method of the present invention.

Claims (8)

Water-dispersible polyurethane;
Hydrophilic thickeners; And
Cosmetic composition for sunscreen having water resistance comprising an organic sunscreen. The method according to claim 1, Based on the total weight of the composition, the sunscreen cosmetic composition containing less than 0.1% of an emulsifier. The method according to claim 1, The water-dispersible polyurethane is a cosmetic composition that is included in 0.2 to 5.0% by weight based on the total weight of the composition. The method according to claim 1, wherein the water-dispersible polyurethane is polyurethane-1, polyurethane-2, polyurethane-6, polyurethane-7, polyurethane-10, polyurethane-11, polyurethane-12, polyurethane- 13 Polyurethane-14, Polyurethane-15, Polyurethane-16, Polyurethane-17, Polyurethane-18, Polyurethane-19, Polyurethane-21, Polyurethane-35, VP / Dimethiconylacrylate / Polycarbyl / polyglycol ester, VP / dimethylaminoethyl methacrylate / polycarbyl polyglycolester, VP / dimethiconyl acrylate / polycarbyl / polyglycolester, VP / poly At least one cosmetic composition selected from the group consisting of carbamyl polyglycolester, styrene / acrylate copolymer / polyurethane, and combinations thereof. The method according to claim 1, The hydrophilic thickener is a cosmetic composition that is included in 0.05 to 5.0% by weight based on the total weight of the composition. The method according to claim 1, wherein the hydrophilic thickener is carbomer, sodium polyacrylate, acrylate / C10-30 alkyl acrylate cross polymer, acrylamide / sodium acrylate copolymer / trideceth-6 / mineral salt, ammonium Acryloyl dimethyl taurate, acrylate, ammonium acrylate copolymer, VP copolymer, acrylate copolymer, glyceryl acrylate, acrylic acid copolymer, lithium magnesium sodium silicate, hydroxyethyl cellulose, polyacrylamide, Montmorillonite, cetyl hydroxyethyl cellulose, agar, octyl acrylamide copolymer, cellulose, polyacrylate-13, corn starch, PEG-240 / H diacopolymer bis-decyl tetradeceth-20 ether, octyl acrylamide Copolymer, mannan, gellan gum, aluminum star octenyl succinate, xanthan gum, carob bean gum, sodium acryloyl dimethyl taurate copolymer. One or more cosmetic compositions selected from the group consisting of sodium polyacrylate starch, sodium stearoxy sebum-hydroxyethyl cellulose sulfonate, or combinations thereof. The method according to claim 1, The organic sunscreen is bis-ethylhexyloxyphenolmethoxyphenyltriazine, butylmethoxydibenzoylmethane, diethylaminohydroxybenzoylhexylbenzoate, disodiumphenyldibenzimidazole tetrasulfonate, draw Metrizoltrisiloxane, menthyl anthranylate, methylenebis-benzotriazolyltetramethylbutylphenol, terephthalylidene dicamper sulfonic acid, terephthalidene dicamper sulfonic acid, benzophenone-3, benzophenone-4, polysilicon -15, ethylhexyl methoxycinnamate, ethylhexyl salicylate, ethylhexyl trizone, homosalate, isoamyl p-methoxycinnamate, octocrylene, phenylbenzimidazole sulfonic acid, trisbisphenyltri At least one cosmetic composition selected from the group consisting of azine or a combination thereof. The cosmetic composition according to claim 1, further comprising an inorganic sunscreen, a polyol, or both.

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