KR20160061774A

KR20160061774A - Polypropylene resin composition for non-woven fabric having excellent rupture strength and soft property and manufactured by using the same

Info

Publication number: KR20160061774A
Application number: KR1020140164611A
Authority: KR
Inventors: 김상현; 김성학; 소지수; 한성욱
Original assignee: 롯데케미칼 주식회사
Priority date: 2014-11-24
Filing date: 2014-11-24
Publication date: 2016-06-01

Abstract

Conventionally, soft nonwoven fabric materials have been produced through the use of a composite spinning process or through characteristic modification of a nonwoven fabric material. However, since the strength of the nonwoven fabric is reduced or the process cost is increased, A polypropylene resin composition and a molded article using the polypropylene resin composition. (A) 80 to 99% by weight of a homopolypropylene resin; (b) 1 to 20% by weight of random polypropylene copolymer or random polypropylene terpolymer; And (c) 0.01 to 2 parts by weight of a β crystal nucleating agent per 100 parts by weight of the total of the components (a) and (b); and a molded article using the polypropylene resin composition.

Description

TECHNICAL FIELD [0001] The present invention relates to a polypropylene resin composition for a nonwoven fabric having excellent breaking strength and softness, and a molded article using the same. [0002] Polypropylene resin compositions for nonwoven fabrics,

More particularly, the present invention relates to a polypropylene resin composition for nonwoven fabric having excellent breaking strength and softness, and a molded article produced using the same.

In recent disposable sanitary nonwoven fabrics market including infant diapers and sanitary napkins, there has been a growing interest in nonwoven fabrics having a soft feel capable of satisfying consumers' emotions. Accordingly, A nonwoven fabric manufacturing technology and material technology that can be implemented are required.

Korean Patent Registration No. 1302804 discloses a method of producing a soft nonwoven fabric by using a soft tactile feeling of polyethylene by co-spinning polypropylene and a high density polyethylene to a core portion and an extrusion process for melting a polypropylene and a polyethylene And composite spinning dies and nozzles are indispensable, which necessitates an expensive complex spinning process. In addition, the nonwoven fabric strength may be lowered due to polyethylene, and the interface between polypropylene and polyethylene conjugated spinning fibers is easily separated.

Korean Patent Laid-Open Publication No. 2011-0027973 discloses a method of improving the nonwoven fabric material by blending an expensive elastomeric random copolymer and an amide type slip agent in homopolypropylene, but the cost increase due to the elastomeric random copolymer There is a problem that not only the problem but also the radioactivity may be lowered and the strength of the nonwoven fabric is lowered.

Conventionally, soft nonwoven fabric materials have been produced through the use of a composite spinning process or through characteristic modification of a nonwoven fabric material. However, since the strength of the nonwoven fabric is reduced or the process cost is increased, And to provide a polypropylene resin composition and a molded article using the polypropylene resin composition, wherein the polypropylene resin composition has good breaking strength and soft characteristics at the same time.

In order to solve the above problems, the present invention provides a thermoplastic resin composition comprising: (a) 80 to 99% by weight of a homopolypropylene resin; (b) 1 to 20% by weight of random polypropylene copolymer or random polypropylene terpolymer; And (c) 0.01 to 2 parts by weight of a? -Crystalline nucleating agent based on 100 parts by weight of the total of the components (a) and (b).

The homopolypropylene resin has a melt index (230 DEG C, 2.16 kg load) of 1 to 100 g / 10 min and a molecular weight distribution (Mw / Mn) of 2 to 6. The polypropylene resin composition for a non-

The random polypropylene copolymer is an ethylene-propylene copolymer containing 0.5 to 5 mol% of ethylene or a propylene-butene-1 copolymer containing 1 to 10 mol% of butene-1. To provide a resin composition.

The random polypropylene terpolymer is an ethylene-propylene-butene-1 terpolymer containing 0.5 to 5 mol% of ethylene and 1 to 10 mol% of butene-1 .

Wherein the random polypropylene copolymer or random polypropylene terpolymer has a melt index (230 DEG C, 2.16 kg load) of 1 to 100 g / 10 min and a molecular weight distribution (Mw / Mn) of 2 to 6. [ Propylene resin composition.

The β crystal nucleating agent may be an amide compound, an alkali metal salt or alkaline earth metal salt of a carboxylic acid, an aromatic sulfonic acid compound, a diester or triester of a dibasic or tribasic carboxylic acid, a tetraoxaspiro compound, an imidocarboxylic acid derivative , A phthalocyanine pigment, a quinacridone pigment, and an alkaline earth metal salt of an acid imide compound. The present invention also provides a polypropylene resin composition for a nonwoven fabric.

The present invention also provides a polypropylene resin composition for a nonwoven fabric, which further comprises 0.01 to 0.5 parts by weight of a slip agent per 100 parts by weight of the total of the components (a) and (b).

The slip agent is at least one selected from the group consisting of erucamide, oleamide, stearamide, bainamide, ethylene bis-stearamide and ethylene bis-amide. do.

In order to solve the above-mentioned problems, the present invention provides a molded article produced using the resin composition.

According to the present invention, it is possible to provide a polypropylene composition which is obtained by mixing a homopolypropylene with a random polypropylene copolymer or a random polypropylene terpolymer and inducing a? Crystal structure so as to have excellent breaking strength and soft characteristics at the same time.

In addition, since the polypropylene resin composition according to the present invention has a low thermal bonding temperature compared to the homopolypropylene, it is possible to minimize the damage of the surface of the nonwoven fabric due to heat in the nonwoven fabric heat bonding process. When the slip agent is further included, However, it is possible to provide a polypropylene composition having improved workability and improved fracture strength of the nonwoven fabric by improving physical properties of elongation and breaking point stress.

Hereinafter, the present invention will be described in detail with reference to preferred embodiments. Prior to this, terms and words used in the present specification and claims should not be construed as limited to ordinary or dictionary terms, and the inventor should appropriately interpret the concepts of the terms appropriately The present invention should be construed in accordance with the meaning and concept consistent with the technical idea of the present invention. Accordingly, it is to be understood that the constituent features of the embodiments described herein are merely the most preferred embodiments of the present invention, and are not intended to represent all of the inventive concepts of the present invention, so that various equivalents, And the like.

(A) 80 to 99% by weight of a homopolypropylene resin; (b) 1 to 20% by weight of random polypropylene copolymer or random polypropylene terpolymer; And (c) 0.01 to 2 parts by weight of a? -Crystalline nucleating agent based on 100 parts by weight of the total of the components (a) and (b). Hereinafter, each component constituting the present invention will be described in detail.

In the present invention, the homopolypropylene resin is a base resin of the polypropylene resin composition for a nonwoven fabric of the present invention. Although it is not particularly limited in its physical properties, the homopolypropylene resin has a melt index (230 DEG C , A 2.16 kg load) of 1 to 100 g / 10 min and a molecular weight distribution (Mw / Mn) of 2 to 6, preferably a melt index of 5 to 30 g / 10 min and a molecular weight distribution of 3 to 5 have. The weight average molecular weight of the homopolypropylene resin is preferably 120,000 to 520,000 g / mol.

The homopolypropylene resin may include 80 to 99% by weight, preferably 85 to 95% by weight, of the entire polypropylene resin component.

In the present invention, the random polypropylene copolymer or the random polypropylene terpolymer is mixed to improve the softness by lowering the flexural modulus while increasing the breaking strength as compared with the homopolypropylene resin alone, Is contained in an amount of 1 to 20 wt%, preferably 5 to 15 wt%, of the total polypropylene resin component including the resin.

If the content of the random polypropylene copolymer or the random polypropylene terpolymer is less than 1% by weight, improvement of the breaking strength and bending elasticity property may be insufficient. If the content of the random polypropylene copolymer or the random polypropylene terpolymer exceeds 20% by weight, It can be difficult.

As the random polypropylene copolymer or the random polypropylene terpolymer, an ethylene-propylene copolymer containing 0.5 to 5 mol% of ethylene or a propylene containing 1 to 10 mol% of butene-1 in the case of the random polypropylene copolymer -Butene-1 copolymer, and the random polypropylene terpolymer is preferably an ethylene-propylene-butene-1 terpolymer containing 0.5 to 5 mol% of ethylene and 1 to 10 mol% of butene-1 .

In the present invention, the 棺 crystal nucleating agent is used to induce the 棺 crystal structure of the polypropylene resin and is not particularly limited as long as it can induce β crystallization of the polypropylene resin. Examples thereof include amide-based compounds, Metal salts or alkaline earth metal salts, aromatic sulfonic acid compounds, diesters or triesters of dibasic or tribasic carboxylic acids, tetraoxaspiro compounds, imidocarboxylic acid derivatives, phthalocyanine pigments, quinacridone pigments, Alkaline earth metal salts and the like can be used.

Specifically, examples of the amide compound include N, N'-diphenylhexanediamide, N, N'-dicyclohexylterephthalamide, N, N'-dicyclohexyl-2,6-naphthalenedicarboxamide, N, N'-dibenzoyl-1,4-diaminocyclohexane, N, N'-dicyclohexanecarbonyl-p-phenylenediamine, N, N-phenyl-5- (benzoylamino) pentane, N, N'-dicyclohexanecarbonyl-1,4-diaminocyclohexane, N-cyclohexyl- Amide and the like can be used. As the alkali metal salt or alkaline earth metal salt of the carboxylic acid, sodium benzoate, magnesium benzoate, potassium 1,2-hydroxystearate, magnesium succinate, magnesium phthalate and the like can be used, As the compound, sodium benzenesulfonate, sodium naphthalenesulfonate and the like can be used. As the phthalocyanine-based pigment, phthalo Cyanine blue and the like can be used. As the quinacridone pigment, quinacridone and the like can be used. As the alkaline earth metal salt of the acid imide compound, calcium salt of phthaloylglycine, hexahydrophthaloylglycine calcium Salt, naphthoylglycine calcium salt, N-phthaloylalanine calcium salt, N-4-methyl phthaloylglycine calcium salt and the like can be used.

The β-crystal nucleating agent is contained in an amount of 0.01 to 2 parts by weight, preferably 0.05 to 1 part by weight, based on 100 parts by weight of the total of the homopolypropylene resin (a) and the random polypropylene copolymer or random polypropylene terpolymer component (b) May be included as the weight part content. When the amount of the β crystal nucleating agent is less than 0.01 part by weight, sufficient β crystal may not be generated sufficiently, and if it exceeds 2 parts by weight, the amount of β crystal nucleating agent may be unsatisfactory from the viewpoint of improvement in physical properties.

In the present invention, the slip agent is preferably an amide slip agent for improving the soft feel of the surface of the nonwoven fabric without deteriorating the breaking strength when the polypropylene resin composition is applied to the nonwoven fabric application. The amide slip agent can be preferably used as a compound having a high melting point of amide series synthesized from a fatty acid and having a hydroxyl group substituted with an amino structure to have a neutral structure.

The slip agent may be, for example, erucamide, oleamide, stearamide, telluamide, ethylene bis-stearamide, ethylene bis-amide, etc. The beads may have an average particle diameter of 1 to 2 mm, 1.5 mm, and the average particle diameter of the powder is 0.1 to 0.9 mm, preferably 0.2 to 0.6 mm.

The slip agent may be included in an amount of 0.01 to 0.5 parts by weight based on 100 parts by weight of the homopolypropylene resin (a) and the random polypropylene copolymer (b) or the random polypropylene terpolymer component, 0.2 part by weight. If the content of the slip agent is less than 0.01 parts by weight, the degree of softness improvement of the nonwoven fabric may not be satisfactory. If the amount of the slip agent is more than 0.5 parts by weight, the breaking strength may be lowered.

It is needless to say that the polypropylene resin composition for a nonwoven fabric of the present invention may further contain various functional additives in addition to the above components, depending on the intention of the operator, the end use of the final product, and the like. Examples of the functional additives include antioxidants, neutralizers, organic peroxides, flame retardants, colorants, lubricants, release agents, pigments and the like, and they may be used alone or in combination of two or more in an amount of 0.01 to 1 part by weight per 100 parts by weight of the resin composition of the present invention Lt; / RTI >

The preparation of the resin composition using the above components in the present invention can be carried out according to a conventional method known in the art. For example, the above components are put into a Henschel mixer in the required amount, and the Henschel mixer is mixed at 300 to 700 rpm for 0.5 to 3 minutes, 1,200 to 1,800 rpm for 0.1 to 2 minutes, and further mixed at 300 to 700 rpm. And then the mixture is thoroughly mixed for 2 to 8 minutes in total, and then the mixture is extruded through a single-screw extruder, multi-screw extruder, kneader or Benbury mixer having an L / D of 25 or more at a processing temperature of 160 to 230 ° C, preferably 180 to 220 ° C To prepare pellets.

The nonwoven fabric using the polypropylene resin composition for a nonwoven fabric according to the present invention can be produced through a conventional staple fiber process and a spunbond process. For example, the polypropylene resin composition is melt-spun and stretched to obtain filament fibers of a predetermined thickness And then laminating the laminated filament webs by heat bonding or needle punching.

Hereinafter, the present invention will be described in detail with reference to examples.

Example One

(a) 90 parts by weight of a homopolypropylene resin (melt index (230 占 폚, 2.16 kg load) 16 g / 10 min, molecular weight distribution (Mw / Mn) 4, Lotte Chemical), (b) ethylene-propylene- 10 parts by weight of a 棺 -crystalline nucleating agent (MAYZO, MPM (trade name, manufactured by Mitsubishi Chemical Corporation)) of 10 parts by weight (ethylene 3 mol%, butene-1 4.5 mol% 2000) was put into a Henschel mixer, and the Henschel mixer was mixed at 500 rpm for 1 minute, 1,500 rpm for 0.5 minutes, and then mixed at 500 rpm for a period of 3 to 5 minutes After mixing, a polypropylene resin composition in the form of a pellet was prepared using a 40 mm single screw extruder having an L / D of 35 to a processing temperature of 180 to 220 ° C. Thereafter, the pellet-shaped resin composition thus prepared was molded at 190-240 ° C using an injection molding machine to prepare a physical property specimen.

Example 2

A physical property specimen was prepared in the same manner as in Example 1, except that (c) the β-crystal nucleating agent was adjusted to 0.05 part by weight in Example 1.

Example 3

A physical property specimen was prepared in the same manner as in Example 1, except that (c) β-crystal nucleating agent was adjusted to 0.1 part by weight in Example 1.

Example 4

A physical property specimen was prepared in the same manner as in Example 1, except that (c) β-crystal nucleating agent was adjusted to 1 part by weight in Example 1.

Example 5

(3 mol% of ethylene, 12 g / 10 min of a melt index (230 DEG C, load of 2.16 kg), a molecular weight of 3,000 mol%) as the component (b) (Mw / Mn) 4) was used as a dispersing agent.

Example 6

In Example 1, (c) a β-crystal nucleating agent was adjusted to 0.05 part by weight, and 0.1 part by weight of slurry zero erucamide (product of AKZO NOBEL, ARMOSLIP-E) was further added, A physical property specimen was prepared.

Comparative Example One

A physical property specimen was prepared in the same manner as in Example 1, except that the components (b) and (c) were not added and 100 parts by weight of the homopolypropylene resin (a) was used.

Comparative Example 2

The same procedure as in Example 1 was carried out except that the component (c) was not added in Example 1 and 95 parts by weight of the homopolypropylene resin (a) and 5 parts by weight of the ethylene-propylene-butene- To prepare a physical property specimen.

Comparative Example 3

A physical property specimen was prepared in the same manner as in Example 1, except that the component (c) was not added.

Comparative Example 4

Except that (a) 85 parts by weight of homopolypropylene resin and (b) 15 parts by weight of ethylene-propylene-butene-1 terpolymer were used in Example 1 in the same manner as in Example 1 To prepare a physical property specimen.

The composition (unit: parts by weight) of the resin composition prepared according to the above Examples and Comparative Examples is summarized in Table 1 below.

Test Example

The melt index of the resin compositions prepared according to the above Examples and Comparative Examples and the physical properties of the specimens were measured according to the following methods, and the results are shown in Table 1 below.

[Assessment Methods]

(1) Melt index: Measured by ASTM D1238 at 230 캜 and 2.16 kgf.

(2) Yield point stress: Measured according to ASTM D638.

(3) Breaking point stress: Measured according to ASTM D638.

(4) Elongation: measured according to ASTM D638.

(5) Flexural modulus: measured according to ASTM D790.

(6) Heat-bonding temperature: A 30 탆 film was molded in a CPP molding machine using a pellet-shaped composition, and two sheets of the MD direction were thermally bonded, left at room temperature for 2 hours or longer, and subjected to a tensile tester at a test speed of 200 mm / The temperature was measured to be 1,000 g or more. The heat bonding pressure was 2 kg / cm 2 and the heat bonding time was 2 seconds.

(7) Coefficient of friction: Measured by a film according to ASTM D1894.

Referring to Table 2, it can be seen that when the random polypropylene copolymer or the random polypropylene terpolymer and the β crystal nucleating agent are mixed with the homopolypropylene in the optimum amount (Examples 1 to 5), the yield point stress, It has been confirmed that it has excellent elongation, low flexural modulus and low heat bonding temperature, excellent breaking strength, minimizes damage to the surface of the nonwoven fabric by heat, and has soft properties at the same time.

In this case, when a random polypropylene terpolymer is used rather than a random polypropylene terpolymer, it is more preferable in terms of soft characteristics (see Examples 2 and 5), and the elongation and breaking point stress are increased as the content of the β nucleating agent increases , The flexural modulus and the thermal bonding temperature tended to decrease. However, when the amount of the β crystal nuclei was slightly exceeded, the content-to-weight ratio did not increase. In addition, when the slip agent is further included at an optimum content, the friction coefficient decreases without deteriorating other physical properties.

On the other hand, when the random polypropylene copolymer or the random polypropylene terpolymer is not included (Comparative Example 1), the breaking point stress and elongation are decreased, and the flexural modulus and the heat bonding temperature are increased. In addition, when no β crystal nucleating agent was included (Comparative Examples 2 to 4), the breaking point stress and elongation were somewhat increased, and the flexural modulus was somewhat reduced, but it was less than the comparative example .

While the preferred embodiments of the present invention have been disclosed for illustrative purposes, those skilled in the art will appreciate that various modifications, additions and substitutions are possible, without departing from the scope and spirit of the invention as disclosed in the accompanying claims. Such modifications and changes are to be considered as falling within the scope of the following claims.

Claims

(a) 80 to 99% by weight homopolypropylene resin;
(b) 1 to 20% by weight of random polypropylene copolymer or random polypropylene terpolymer; And
(c) 0.01 to 2 parts by weight of? crystal nucleating agent per 100 parts by weight of the total of components (a) and (b);
And the polypropylene resin composition for a nonwoven fabric.

The method according to claim 1,
Wherein the homopolypropylene resin has a melt index (230 占 폚, 2.16 kg load) of 1 to 100 g / 10 min and a molecular weight distribution (Mw / Mn) of 2 to 6.

The method according to claim 1,
Wherein the random polypropylene copolymer is an ethylene-propylene copolymer containing 0.5 to 5 mol% of ethylene or a propylene-butene-1 copolymer containing 1 to 10 mol% of butene-1. Composition.

The method according to claim 1,
Wherein the random polypropylene terpolymer is an ethylene-propylene-butene-1 terpolymer containing 0.5 to 5 mol% of ethylene and 1 to 10 mol% of butene-1.

The method according to claim 1,
Wherein the random polypropylene copolymer or the random polypropylene terpolymer has a melt index (230 DEG C, 2.16 kg load) of 1 to 100 g / 10 min and a molecular weight distribution (Mw / Mn) of 2 to 6. [ Resin composition.

The method according to claim 1,
The β-crystal nucleating agent may be selected from amide-based compounds, alkali metal salts or alkaline earth metal salts of carboxylic acids, aromatic sulfonic acid compounds, diesters or triesters of dibasic or tribasic carboxylic acids, tetraoxaspiro compounds, imidocarboxylic acid derivatives, Wherein the polypropylene resin composition is at least one selected from the group consisting of phthalocyanine pigments, quinacridone pigments, and alkaline earth metal salts of an acid imide compound.

The method according to claim 1,
Wherein the slip agent is further contained in an amount of 0.01 to 0.5 parts by weight based on 100 parts by weight of the total of the components (a) and (b).

8. The method of claim 7,
Wherein the slip agent is at least one member selected from the group consisting of erucamide, oleamide, stearamide, butenamide, ethylene bis-stearamide and ethylene bis-amide.

A molded article produced by using the resin composition of any one of claims 1 to 8.