KR20160048042A - antimicrobial functional food film with mineral matter development method - Google Patents

antimicrobial functional food film with mineral matter development method Download PDF

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KR20160048042A
KR20160048042A KR1020160008836A KR20160008836A KR20160048042A KR 20160048042 A KR20160048042 A KR 20160048042A KR 1020160008836 A KR1020160008836 A KR 1020160008836A KR 20160008836 A KR20160008836 A KR 20160008836A KR 20160048042 A KR20160048042 A KR 20160048042A
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KR101623060B1 (en
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정해동
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정해동
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38Packaging materials of special type or form
    • B65D65/42Applications of coated or impregnated materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C19/00Other disintegrating devices or methods
    • B02C19/16Mills provided with vibrators
    • B29C47/0021
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D7/00Producing flat articles, e.g. films or sheets
    • B29D7/01Films or sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/24Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/50Containers, packaging elements or packages, specially adapted for particular articles or materials for living organisms, articles or materials sensitive to changes of environment or atmospheric conditions, e.g. land animals, birds, fish, water plants, non-aquatic plants, flower bulbs, cut flowers or foliage
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/22Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04Polymers of ethylene
    • B29K2023/06PE, i.e. polyethylene

Abstract

The present invention relates to a method for manufacturing a packaging material of antimicrobial and functional food. More specifically, the present invention relates to a food packaging material manufactured by mixing fine powder of pegmatite while using a synthetic resin as a main ingredient. More specifically, the pegmatite contains necessary ingredients for a human body such as magnesium, sodium, silicon, and calcium and minor minerals such as beryllium, uranium, niobium, tantalum, and cerium. More specifically, beneficial physiologically critical minerals assisting a regenerative ability of the human body are contained in the most ideal conditioning. More specifically, the present invention has a harmful component suction force, an antimicrobial function, and an antifungal function to significantly store food and maintains freshness for a long period of time.

Description

항균력을 가진 기능성 식품 포장재 제조 방법{antimicrobial functional food film with mineral matter development method}TECHNICAL FIELD [0001] The present invention relates to an antimicrobial functional food film,

본 발명은 항균력을 가진 기능성 식품 포장재 제조 방법에 관한 것으로, 구체적으로는 합성수지를 주원료로 하고 미세 분말의 거정석(페그마타이트)을 혼합하여 제조하는 식품용 포장재에 관한 것이다.The present invention relates to a method for producing a functional food packaging material having antibacterial activity, and more particularly, to a food packaging material prepared by mixing synthetic resin as a main raw material and fine granules (pegmatite).

거정석은 심성암을 함유하는 암맥에서 주로 발견되는 조립질 화성암으로서 심성암이 되고 남은 마그마 잔액에 염소, 불소, 물 등의 휘발성 물질들이 농집하여 서서히 냉각되어 생기는 광물로 베릴륨, 우라늄, 니오브, 탄탈, 세륨 등의 희소 광물이 많이 침전되어 있고, 특히 인체의 재생 능력을 도우는 유익한 생리 필수 미네랄 들이 가장 이상적인 조화를 이루면서 함유되어 있다.Gyeongseok is a granitic rock which is found mainly in the dyke containing plutonite. It is formed as plutonite and volatile materials such as chlorine, fluorine and water are concentrated in the residual magma residue and slowly cooled. It is composed of beryllium, uranium, niobium, tantalum, And many other rare minerals are precipitated. Especially beneficial physiological minerals that help the human body's regenerating ability are contained in the most ideal harmony.

또한 거정석은 마그네슘, 나트륨, 규소, 칼슘 등의 인체에 필요한 성분들이 풍부하게 함유되어 있는 기석으로 다량의 음이온을 방출하며, 유해 성분을 흡착하고 항균 및 항곰팡이의 기능이 있어 이를 이용하여 만든 포장재는 식품으로서의 저장성이 탁월하고 신선도가 장시간 유지되는 효과가 있다.In addition, Gyeongseok is rich in magnesium, sodium, silicon, calcium, and other necessary components for human body. It emits a large amount of negative ions, absorbs harmful components, and has antibacterial and antifungal functions. Is excellent in storage stability as a food and has an effect of maintaining freshness for a long time.

식품 포장재에 관한 사업 중에 가장 핵심적인 분야는 신선도 유지 및 저장성에 있다. 특히 야채, 과일 등은 산소, 미생물 및 수분에 의해 보존 기간이 정해지는데 현재까지는 뚜렷한 대안이 없이 인공 첨가물인 방부제 등을 사용해 왔다. 허나 이런 방부제는 인체에 유해하여 건강에 악영향을 끼칠 뿐 아니라 식품의 고유한 맛과 향에도 영향을 끼치므로 새로운 형태의 식품 포장재가 개발되고 있는 실정이다.이러 한식품 포장재에는 황토, 맥반석, 은나노 등의 항균성을 가진 물질을 합성 수지에 혼합하여 개발되긴 했지만 그 효능이 미비하여 충분히 시장에 적용되지 못했다. 그래서 거정석(페그마타이트)을 이용한 합성수지를 개발하려 하는 것이다.One of the key areas of business for food packaging materials is maintaining freshness and storage. Especially, vegetable and fruit are preserved by oxygen, microorganism and moisture. Presently, preservatives such as artificial additives have been used without a clear alternative. However, since these preservatives are detrimental to human health and adversely affect health, they also affect the unique taste and flavor of food, and thus new types of food packaging materials have been developed. Such packaging materials include yellow loess, elvan, silver nano But it has not been applied to the market sufficiently. So, we are trying to develop synthetic resin using pegmatite.

본 발명은 상기의 문제점을 해결하기 위해 개발된 것으로 거정석이 갖고 있는 각종 기능을 살려 원적외선 및 음이온의 방출, 항균 및 살균력을 갖고 있는 인체에 유익한 식품 포장재를 제조하려 한다.The present invention has been developed in order to solve the above problems, and aims to manufacture a food packaging material useful for a human body which has far-infrared rays and anion emission, antibacterial and sterilizing power by utilizing various functions of gyeongseok.

상기 목적은 규소, 산화알미늄, 산화칼슘 뿐만 아니라 티타늄, 홀뮴, 셀레늄, 니오브 및 탄탈 등의 희소 광물질을 함유하고 있는 거정석을 2,000메쉬 정도로 분쇄 흡착하여 합성수지와 혼합하여 항균용 식품포장재를 제조하려는 것이다.The object of the present invention is to produce a food packaging material for antimicrobial use by pulverizing and adsorbing rare earths containing rare metals such as titanium, holmium, selenium, niobium and tantalum as well as silicon, aluminum oxide and calcium oxide to about 2,000 mesh .

본 발명에 따른 식품 포장재는 원적외선 및 음이온을 방출하며, 중금속 및 유해성분이나 에틸렌 가스의 흡착력을 향상시켜, 항균활성과 항산화 활성이 증진되어 식품의 저장성이 월등히 증대되는 효과가 있다.The food packaging material according to the present invention emits far-infrared rays and anions, enhances the adsorption power of heavy metals, harmful components and ethylene gas, and has an antimicrobial activity and an antioxidative activity.

도 1은 본 발명의 식품포장재 제조 방법을 나타낸 플로우차트.
도 2는 거정석의 원적외선 방출량을 나타낸 시험성적서.
도 3은 거정석이 음이온의 방출량을 나타낸 시험성적서.
도 4는 거정석의 탈취 시험 결과를 나타낸 시험성적서.
도 5는 대장균 및 녹농균의 24시간 후의 감소율을 나타낸 시험성적서.
도 6은 석면 검출 현황을 나타낸 시험성적서.
도 7은 시간에 따른 포름알데히드 검출량을 나타낸 시험성적서.
도 8은 유해 물질 검출 테스트를 한 사진.
도 9는 포도 테스트 사진.
도 10은 고추 테스트 사진.
도 11은 브로코리 테스트 사진.
도 12는 단감 테스트 사진.
도 13은 콩나물 테스트 사진.
도 14는 피망 테스트 사진.
도 15는 깻잎 테스트 사진.
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a flow chart showing a method of manufacturing a food packaging material of the present invention. FIG.
FIG. 2 is a test report showing the far-infrared emission of gravelite. FIG.
FIG. 3 is a test report showing the amount of anions emitted by gravelite.
Fig. 4 is a test report showing the result of deodorization test of gravel.
5 is a test report showing the reduction rate of Escherichia coli and P. aeruginosa after 24 hours.
6 is a test report showing the state of asbestos detection.
Figure 7 is a test report showing the amount of formaldehyde detection over time.
8 is a photograph showing a test for detecting a noxious substance.
9 is a photograph of a grape test.
FIG. 10 is a picture of pepper test.
Fig. 11 is a photograph of a broccoli test. Fig.
12 is a photograph of a persimmon test.
13 is a photograph of a bean sprout test.
14 is a photograph of a pimento test.
15 is a photograph of a sesame leaf test.

본 발명은 항균력을 가진 기능성 식품 포장재 제조 방법에 관한 것으로, 저밀도 폴리에틸렌과 거정석을 혼합한 식품포장재로서, 거정석 분말입자는 2,000 ~ 5,000메쉬의 크기이며, 저밀도 폴리에틸렌 100중량부에 대하여 거정석 분말입자 5~15중량부로 포함되어,The present invention relates to a method for producing a functional food packaging material having antibacterial activity, which is a food packaging material obtained by mixing low density polyethylene and ground stone, wherein the ground stone powder particles have a size of 2,000 to 5,000 mesh and 100 parts by weight of low- 5 to 15 parts by weight of particles,

(1) 규소, 마그네슘, 칼슘을 포함하는 거정석을 350메쉬로 분쇄하는 단계;(1) pulverizing gravelalloys containing silicon, magnesium and calcium into 350 mesh;

(2) 상기 350메쉬의 거정석 분말을 공기 고속 와류 또는 고주파 압력변동에 따른 진동을 이용하여 2,000 ~ 5,000메쉬로 자기 파쇄하는 단계;(2) self-crushing the 350 mesh ground stone powder at a speed of 2,000 ~ 5,000 mesh using a high-speed air eddy current or vibration due to high frequency pressure fluctuation;

(3) 저밀도 폴리에틸렌 100중량부에 대하여 거정석분말 5 ~ 15 중량부로 혼합하여 마스터배치를 만드는 단계;(3) mixing 5 to 15 parts by weight of goethite powder with respect to 100 parts by weight of low-density polyethylene to prepare a master batch;

(4) 실링층에서 테르폴리머 100중량부에 대하여 마스터배치를 5 ~ 15 중량부를 혼합하여 실린더를 통해 3층의 필름을 생산하는 단계;를 포함하는 것이다.(4) mixing 5 to 15 parts by weight of the master batch with 100 parts by weight of the terpolymer in the sealing layer to produce a three-layer film through the cylinder.

본 발명의 실시예를 참조하여 본 발명을 상세히 설명한다. 다만 이들 실시예는 발명을 구체적으로 설명하기 위해 제시한 것일 뿐, 본 발명의 범위가 이들 실시예에 의해 제한되지 않는다는 것은 이 분야에 통상의 지식을 가진 자에게는 자명한 것이므로 그 설명은 생략하기로 한다.BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in detail with reference to examples of the present invention. It will be apparent to those skilled in the art that these embodiments have been presented for the purpose of illustrating the invention and that the scope of the invention is not limited by these embodiments. do.

실시예Example 1. 식품포장재 제조 1. Food packaging materials manufacturing

본 실시예에서는 거정석을 이용하여 식품포장재를 제조하였다. (도 1 참고)In this embodiment, a food packaging material was prepared using gingolite. (See FIG. 1)

먼저 식품포장재에 첨가되는 천연광물질인 거정석의 덩어리(직경 1센티미터 이하) 5킬로그램과 저밀도 폴리에틸린 수지를 준비하였다. 그런 다음 상기 거정석 덩어리를 350메쉬의 분말로 1차 분쇄하였다.First, 5 kilograms of lump of natural minerals (less than 1 centimeter in diameter) and low density polyethylenes resin, which are added to food packaging materials, were prepared. Then, the above-mentioned gypsum lumps were firstly pulverized with a powder of 350 mesh.

상기 분쇄된 거정석 분말을 공기의 고속와류 또는 고주파 압력변동에 따른 진동을 이용한 자기파쇄 방식의 고성능 분쇄설비로 약 2,500메쉬로 2차 가공하였다. 2,500메쉬로 가공한 것은 완제품 인쇄시 발생할 수 있는 기계의 마모 및 완제품의 투명도를 고려하였다.The above ground gypsum powder was subjected to secondary processing at about 2,500 mesh with a high-performance pulverizing apparatus using magnetic pulverization using vibration of high-speed eddy-current or high-frequency fluctuation of air. The 2,500 mesh processing was taken into account the wear of the machine and the transparency of the finished product when printing the finished product.

준비된 2,500메쉬의 거정석 분말과 저밀도 폴리에틸렌 원료를 1: 10의 비율로 계량한 후 (거정석 분말 5킬로그램, 저밀도 폴리에틸렌 원료 50킬로그램),혼합기에 넣고 약 10분간 교반시켰다. 이때 교반 속도는 약 100rpm으로 하였다.The prepared 2,500 mesh gypsum powder and the low density polyethylene raw material were weighed at a ratio of 1:10 (5 kg of gypsum powder, 50 kg of low density polyethylene raw material), stirred in a mixer for about 10 minutes. The stirring speed was about 100 rpm.

획득된 원료로 만든 마스터배치를 실링층에서 테르폴리머 95중량%에 대하여 마스터배치 5중량% 수준으로 첨가하여 고온의 진공성형관을 거치면서 고체구조로 변화되었다.The master batch made from the obtained raw materials was added to the master batch at a level of 5% by weight with respect to 95% by weight of the terpolymer in the sealing layer, and converted into a solid structure through a high-temperature vacuum tube.

실시예 : 거정석을 포함하는 포장재와 포함하지 않은 포장재 제조 후 저장성 평가 Example: After going production that does not contain the packaging material containing the packaging crystallization Storage Evaluation

포장재 제조시 거정석을 전혀 첨가하지 않은 상태에서 폴리에틸렌 50킬로그램만을 이용하여 포장재를 제조하고, 거정석을 첨가한 것도 같은 양으로 포장재를 제조하였다. 각각의 포장재에 7가지의 야채와 채소를 넣고 실험하였다. (도 9), (도 10), (도 11), (도 12), (도 13), (도 14), (도 15) 참조.Packing materials were prepared using only 50 kilograms of polyethylene in the absence of gingelite, and gingelite was added in the same amount. Seven kinds of vegetables and vegetables were put into each packing material. (Fig. 9), Fig. 10, Fig. 11, Fig. 12, Fig. 13, Fig. 14, and Fig.

그 저장성에 대한 결과는 현저하게 차이가 나는 것으로 나타났다.The results on the storage stability were found to be significantly different.

Claims (1)

저밀도 폴리에틸렌과 거정석을 혼합한 식품포장재로서, 거정석 분말입자는 2,000 ~ 5,000메쉬의 크기이며, 저밀도 폴리에틸렌 100중량부에 대하여 거정석 분말입자 5~15중량부로 포함되어,
규소, 마그네슘, 칼슘을 포함하는 거정석을 분쇄하는 단계;
상기 분쇄된 거정석 분말을 공기 고속 와류 또는 고주파 압력변동에 따른 진동을 이용하여 2,000 ~ 5,000메쉬로 자기 파쇄하는 단계;
저밀도 폴리에틸렌 100중량부에 대하여 거정석분말 5 ~ 15 중량부로 혼합하여 마스터배치를 만드는 단계;
실링층에서 테르폴리머 100중량부에 대하여 마스터배치를 5 ~ 15 중량부를 혼합하여 실린더를 통해 필름을 생산하는 단계;를 포함하는 항균력을 가진 기능성 식품 포장재 제조 방법.
A food packaging material obtained by mixing low density polyethylene and gingelite, wherein the gingelite powder particles have a size of 2,000 to 5,000 mesh and are contained in an amount of 5 to 15 parts by weight of ground stone powder per 100 parts by weight of low density polyethylene,
Pulverizing ganggyeol containing silicon, magnesium and calcium;
Self-pulverizing the pulverized gangrene powder at 2,000 ~ 5,000 mesh using high-speed air eddy current or vibration due to high-frequency pressure fluctuation;
Mixing 5 to 15 parts by weight of goethite powder with respect to 100 parts by weight of low density polyethylene to prepare a master batch;
And 5 to 15 parts by weight of a master batch is mixed with 100 parts by weight of the terpolymer in the sealing layer to produce a film through a cylinder.
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