KR20160023365A - Method for Producing Articles Using Injection Molding of Alloy - Google Patents
Method for Producing Articles Using Injection Molding of Alloy Download PDFInfo
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- KR20160023365A KR20160023365A KR1020140109669A KR20140109669A KR20160023365A KR 20160023365 A KR20160023365 A KR 20160023365A KR 1020140109669 A KR1020140109669 A KR 1020140109669A KR 20140109669 A KR20140109669 A KR 20140109669A KR 20160023365 A KR20160023365 A KR 20160023365A
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- alloy
- mold
- injection
- injection molding
- molding method
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D17/00—Pressure die casting or injection die casting, i.e. casting in which the metal is forced into a mould under high pressure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D17/00—Pressure die casting or injection die casting, i.e. casting in which the metal is forced into a mould under high pressure
- B22D17/20—Accessories: Details
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D21/00—Casting non-ferrous metals or metallic compounds so far as their metallurgical properties are of importance for the casting procedure; Selection of compositions therefor
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/147—Alloys characterised by their composition
- H01F1/153—Amorphous metallic alloys, e.g. glassy metals
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F41/00—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties
- H01F41/02—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Dispersion Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
Abstract
Description
TECHNICAL FIELD The present invention relates to an injection molding method of an alloy, and more particularly, to a method of injection molding a metal or an alloy containing an amorphous or amorphous component.
Injecting molding refers to the molding method of plastic or metal powder. In the plastic injection, the molding material supplied from the hopper is mixed in a heating cylinder, injected into a closed mold, melted, and injected at a high pressure by an injection cylinder. In addition, the injection of the metal powder can be accomplished by heating the mixture of the powder of the metal and the resin binder and injecting the mixture into the mold to form a certain shape, and then cooling the mixture to remove the binder. The plastic injection has the advantage that it can be mass-produced and the metal powder injection has the advantage that a product having a complicated shape can be produced. However, in the case of metal powder injection, the metal powder and the resin binder must be used together during the injection process. Therefore, the resin binder must be removed separately after molding, and large shrinkage occurs during the cooling process.
Patent Registration No. 10-0768700 discloses that the sum of at least one component selected from the group consisting of Fe, Fe and Co is 40 to 75 wt% and at least one component selected from the group of W, Mo, Cr, Nb, Is 20 wt% or more, and the sum of at least one component selected from the group consisting of B, C, Cu, and Si is 2 to 15 wt%, and other unavoidable impurities; ; Molding the mixture into a shape of a part by injection molding; Removing the binder from the extrudate; Wherein the alloy powder comprises 20 to 35 wt% of Cr, 1 to 2.5 wt% of Si, 0.5 wt% or less of C, Wherein the alloy is 0.1 to 3% by weight of Cu, 2 to 5% by weight of B, 0.1 to 8% by weight of Mo, 14 to 22% by weight of Ni and 4 to 15% by weight of Co.
Japanese Patent Application Laid-Open No. 10-2014-0003069 discloses a honeycomb structure comprising a plurality of shape portions formed in a predetermined shape in a state of being spaced apart from each other by a predetermined distance and a connecting portion connecting adjacent ones of the plurality of shape portions, Internal structure forming mold; A top plate core having an upper plate forming portion corresponding to an upper plate shape of a metal member to be formed; And a lower core corresponding to the upper core and having a lower plate forming portion corresponding to a lower plate shape of a metal member to be formed, and wherein at least one of the upper core and the lower core includes a lower plate formed between the upper plate forming portion and the lower plate forming portion And an auxiliary forming die formed to correspond to the lower plate shape of the metal member to be formed and inserted into the lower plate forming portion.
Patent Publication No. 10-2014-0068246 relates to an injection molding system comprising: a melting zone configured to melt a molten material contained therein; And a plunger rod configured to discharge molten material from the melting zone into the mold, wherein the plunger rod and the molten zone are provided on a horizontal axis in a row, the plunger rod extending horizontally through the molten zone And moving the molten material into the mold in the horizontal direction to form a molded article comprising the bulk amorphous alloy.
For injection molding of a metal or alloy that is not in powder form, the metal or alloy must be melted at a temperature of, for example, 500 to 1200, and the shrinkage level should be low during the cooling process after molding in the mold. A suitable mold should be prepared. The prior art does not disclose such a series of techniques.
The present invention has been made to solve the problems of the prior art and has the following purpose.
An object of the present invention is to provide an injection molding method of an alloy capable of forming an arbitrary shape of an amorphous metal or a metal or alloy containing an amorphous component made to be capable of low-temperature melting.
According to a preferred embodiment of the present invention, an injection method of an alloy includes melting an alloy of a metal or a non-metal at a temperature of 600 to 1200 to produce an alloy containing an amorphous alloy or an amorphous component; Preparing a mold in which the alloy is melted and injected; Making the alloy into a spherical or pseudo spherical shape having an average diameter of 1 to 15 and melting it at a high frequency applying coil at a temperature of 600 to 1200; Injecting the molten alloy into the mold; And a step of performing injection molding in a predetermined shape in the mold, wherein the mold has a pair of sub-molds having opposing contact surfaces and forming a closed space by the contact of the contact surfaces.
According to another preferred embodiment of the present invention, the molten alloy is injected at the side of the pair of sub-molds, and the pair of sub-molds are relatively moved in the horizontal direction.
According to another preferred embodiment of the present invention, the alloy is made of zirconium, titanium, beryllium, copper, nickel, aluminum and silicon or consists of aluminum, titanium, copper, nickel and beryllium.
According to another preferred embodiment of the present invention, the alloy has a shrinkage ratio of 0.002 to 0.8% during cooling from a temperature of 600 to 1200 to room temperature.
According to another preferred embodiment of the present invention, the pair of molds is made of stainless steel to which carbon, silicon, manganese, chromium, molybdenum and vanadium are added.
The injection molding method according to the present invention can be applied to the manufacture of various industrial parts having complex shapes and strength and elasticity, including automobile parts, computer parts, frames of mobile devices, sporting goods and aircraft parts. Further, the method according to the present invention is not limited to the shape of the parts, but allows mass production of precision parts such as plastic injection molded parts.
BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1A shows an embodiment of an injection molding method of an alloy according to the present invention.
Figure 1B shows an embodiment of an x-ray diffraction analysis test for an alloy applied to the method according to the present invention.
FIGS. 2A and 2B show an embodiment of a mold that can be applied to the injection molding method according to the present invention.
3A and 3B illustrate an embodiment of an injection apparatus applicable to the injection molding method according to the present invention.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, the present invention will be described in detail with reference to the embodiments shown in the accompanying drawings, but the present invention is not limited thereto. In the following description, components having the same reference numerals in different drawings have similar functions, so that they will not be described repeatedly unless necessary for an understanding of the invention, and the known components will be briefly described or omitted. However, It should not be understood as being excluded from the embodiment of Fig.
BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1A shows an embodiment of an injection molding method of an alloy according to the present invention.
Referring to FIG. 1A, an injection molding method of an alloy according to the present invention comprises the steps of: (P11) preparing an alloy containing an amorphous alloy or an amorphous component by melting a metal or a non-metallic material at a temperature of 600 to 1200; A step (P12) of preparing a mold to be injected by melting the alloy; (P13) of making the alloy into a spherical or pseudo spherical shape having an average diameter of 1 to 15 and melting at a high frequency applying coil at a temperature of 600 to 1200; Injecting the molten alloy into the mold (P14); And a step (P15) of injection-molding the mold in a predetermined shape, wherein the mold has a pair of sub-molds having opposing contact surfaces and a sealed space formed by the contact of the contact surfaces.
The injection molding method according to the present invention can be applied to an injection molding method of an amorphous alloy containing an amorphous metal or a metal in a crystalline form. In addition, the injection molding method according to the present invention melts an alloy made into a lump shape rather than a powder, and injects the alloy into a mold, thereby molding the product by a process similar to plastic injection. Therefore, no resin binder is used separately. The amorphous metal may include amorphous alloys such as Fe-Based, Fe-Ni-Based, Ni-Based or Co-based. But is not limited thereto. And amorphous metal containing crystalline metal means an amorphous alloy containing amorphous metal as a whole but containing a metal in a partially crystalline state. Crystalline metal-containing amorphous metals have similar properties to amorphous alloys when they are melted.
An alloy serving as a material for injection molding according to the present invention may be prepared (P11). The alloy may be, for example, zirconium (Zr), titanium (Ti), copper (Cu), nickel (Ni), beryllium (Be), aluminum (Al), tin (Sn), silicon (Si), niobium Can be made from a metal selected from the group consisting of gold (Au), silver (Ag), lead (Pb), platinum (Pt) and cobalt (Co). For example, the alloy may include 40 to 50 wt% zirconium; 12 to 16 wt% titanium; 2 to 4 wt% beryllium; 20 to 30 wt% copper; 13 to 18 wt% of nickel; 0.5 to 2 wt% aluminum; And from 0.1 to 1.0 wt% silicon. Or the alloy comprises 34 to 43 wt% zirconium; 32 to 45 wt% titanium; 2 to 4 wt% beryllium; 5-12 wt% copper; 6-12 wt% nickel; 1.0 to 4 wt% aluminum; And 0.2 to 1.0 wt% silicon. The alloy further comprises 3 to 65 wt% aluminum; 10 to 15 wt% titanium; 12 to 18 wt% copper; 10 to 15 wt% of nickel; And 2.0 to 3.0 wt% beryllium. Alternatively, the alloy may include 42 to 55 wt% aluminum; 5 to 12 wt% titanium; 15-25 wt% copper; 15 to 25 wt% of nickel; And 1 to 5 wt% beryllium. Such an alloy may include, for example, dissolving copper, nickel, some zirconium and beryllium at a temperature of 800-1000 to form a melt; Charging a remaining amount of zirconium into the melt to melt the molten zirconium; And charging titanium and aluminum after the remaining zirconium is completely melted. The alloy thus formed may be an amorphous alloy or an amorphous alloy containing a crystal metal. In the case of the alloy made according to the present embodiment, XRD analysis results of the type shown in FIG. 1B can be shown. In Fig. 1 (b), the peak appears as a crystal component.
The alloy made by the method described above can be made, for example, in the form of a spherical or pseudo spherical mass having a diameter of from 1 to 15, and can then be a material for injection molding. However, the alloy can be made in various shapes or sizes and can be made into a suitable shape or size that can be melted, for example, in the high frequency application coil described below.
When the alloy is made (P11), a mold for injection molding can be prepared (P12). The mold may have a structure suitable for the shape of the product to be manufactured. For example, the mold can be made of a pair of mold blocks or sub-molds, and each mold block or sub-mold can have a surface to be in contact with each other, and the contact surfaces are in contact with each other, Can be formed. A molding space can be formed in the closed space and a mold in which the molding space corresponds to the shape of the product can be fixed. The molten metal injected into the closed space can be injected into the mold and molded.
When the mold is ready (P12), the prepared alloy must be melted and injected into the mold. Melting, injection, injection, molding, cooling and discharge of the product of the alloy can be done in the injection apparatus.
The alloy according to the present invention can be, for example, high frequency melting. High-frequency melting refers to, for example, melting an alloy made in the form of a lump by applying high frequency while passing through an induction coil. The frequency to be applied to the induction coil may be, for example, 100 Hz to 500 kHz, the temperature may be 600 to 1200 depending on the type of alloy, and the frequency may be appropriately selected in consideration of the skin effect. The induction coil may be, but is not limited to, a circular coil shape, a square coil shape, an elliptical coil shape, a pancake coil shape, or a helical coil shape.
When the alloy becomes high-frequency melting (P14), it can be injected into the mold (P14). A method of applying pressure to the hydraulic cylinder to inject the molten alloy into the mold may be applied. Specifically, the pair of mold blocks or sub-molds may be composed of a movable mold block and a stationary mold block, and the movable mold block and the stationary mold block may be arranged to face each other in a horizontal direction. An injection hole may be formed on one side of the stationary mold block and a nozzle of the cylinder may be connected to the injection hole. Then, the molten alloy can be injected through the injection hole into the closed space of the mold block described above.
When the molten metal is injected into the mold block and pressure is applied by the moving mold block, the product can be molded inside the closed space (P15). Then, the mold may be cooled to cool the molded product, and then the movable mold block may be moved to discharge the molded product (P16). Thereafter, the product can be completed through a surface finishing process.
The degree of shrinkage during the cooling process is a major factor affecting product performance. Therefore, the level of contraction needs to be adjusted appropriately. On the other hand, the shrinkage level is based on the inherent properties of the alloy itself.
The shrinkage level of the alloy applied to the process according to the present invention can be from 0.002 to 0.8% from the temperature of 600 to 1200 at 10 -4 Torr to 2 atm until cooled to room temperature. Viscosity, flowability, shrinkage and flow rate were measured for alloys to which the method according to the invention was applied.
For the test, the change in fluidity with pressure was measured for tubes of different diameters. The change in viscosity was measured based on the change in shear force and the change in flow rate was measured while varying the diameter of the tube from 10 cm to 10 cm in length. The viscosity was measured while changing the temperature from 600 to 1200, and the shrinkage was measured as the volume change. The measurement temperature range was from 25 to 1200 and the pressure change was measured while varying the pressure applied to the 10 cm diameter tube from 10 -4 Torr to 1620 Torr.
The results of each measurement are shown in the table below.
* The temperature was measured in 10 units and the pressure in 10 Torr increments.
* Each value represents the relative deviation in%. For example, viscosity 5 ~ 10 is the lowest temperature change from 600, which corresponds to the lowest temperature, 1200 is the maximum temperature change, and maximum viscosity change is 10% .
The product manufactured by the alloy according to the present invention has a hardness of 280 to 1200 HV, an elastic modulus of 150 to 400 Gpa, a tensile strength of 600 to 3000 MPa and a specific gravity of 3.2 to 5.2. (Thermal Capacity: J / mk) of 2.40 to 3.5 and a thermal capacity (J / cm) of 150 to 200, and a thermal capacity / mol-K) is in the range of 10 to 50.
As you can see from the above results. It can be seen that the injection molding method according to the present invention can be made to have various physical properties depending on the field of application of the product, and precision injection like plastic can be performed regardless of the shape of the product.
Hereinafter, an embodiment of a mold that can be applied to the injection method according to the present invention will be described.
FIGS. 2A and 2B show an embodiment of a mold that can be applied to the injection molding method according to the present invention.
2A and 2B, a mold 100 applied to a method according to the present invention includes a
The
An
The product can be molded in a mold fixed inside the molding space. When the
The
At least one
It is necessary to prevent relative movement in a state where the
A mold 100 having various structures can be applied to the method according to the present invention.
The mold can be placed in the injection apparatus.
3A and 3B illustrate an embodiment of an injection apparatus applicable to the injection molding method according to the present invention.
Referring to FIGS. 3A and 3B, an
The
A
The
The
When the material is injected into the
The fixing
When molding is completed in the
The
The
The internal pressure of the
The method according to the present invention can be applied to an injection apparatus having various structures.
The injection molding method according to the present invention can be applied to the manufacture of various industrial materials having complex shapes and strength and elasticity, including automobile parts, computer parts, frames of mobile devices, sporting goods and aircraft parts. Further, the method according to the present invention is not limited to the shape of the parts, but allows mass production of precision parts such as plastic injection molded parts.
While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it will be understood by those of ordinary skill in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention . The invention is not limited by these variations and modifications, but is limited only by the claims appended hereto.
100:
11, 21:
13: forming groove 14: injection hole
15: Guide hole 16: Position fixing unit
17: Restriction extension groove 22: Coupling groove
23: pressure groove 25: guide member
26: fastening and fixing unit 27: sealing projection
30: Injection device 31: Mold module
32: fixed module 33: chamber module
34: input module 311: injection chamber
312a, 312b: mold 332: high frequency unit
333: cooling unit 334: injection cylinder
341: Input tube
Claims (5)
Preparing a mold in which the alloy is melted and injected;
Making the alloy into a spherical or pseudo spherical shape having an average diameter of 1 to 15 and melting it at a high frequency applying coil at a temperature of 600 to 1200;
Injecting the molten alloy into the mold; And
And injection-molding the mold in a predetermined shape,
Wherein the mold comprises a pair of sub-molds having opposing contact surfaces and a sealed space formed by the contact of the contact surfaces.
Priority Applications (1)
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KR1020140109669A KR20160023365A (en) | 2014-08-22 | 2014-08-22 | Method for Producing Articles Using Injection Molding of Alloy |
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KR1020140109669A KR20160023365A (en) | 2014-08-22 | 2014-08-22 | Method for Producing Articles Using Injection Molding of Alloy |
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KR1020160053276A Division KR20160053893A (en) | 2016-04-29 | 2016-04-29 | Method for Producing Articles Using Injection Molding of Alloy |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2023236719A1 (en) * | 2022-06-11 | 2023-12-14 | 安徽昊方机电股份有限公司 | Needle for warp knitting machine and method for manufacturing needle by means of amorphous alloy injection molding process |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100768700B1 (en) | 2006-06-28 | 2007-10-19 | 학교법인 포항공과대학교 | Fabrication method of alloy parts by metal injection molding and the alloy parts |
KR20140003069A (en) | 2012-06-29 | 2014-01-09 | 한국생산기술연구원 | Metal member having inner structure, inner structure molding frame, injection molding method of metal member using the same and metal member manufactured by the same |
KR20140068246A (en) | 2011-09-30 | 2014-06-05 | 크루서블 인텔렉츄얼 프라퍼티 엘엘씨. | Injection molding of amorphous alloy using an injection molding system |
-
2014
- 2014-08-22 KR KR1020140109669A patent/KR20160023365A/en not_active Application Discontinuation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100768700B1 (en) | 2006-06-28 | 2007-10-19 | 학교법인 포항공과대학교 | Fabrication method of alloy parts by metal injection molding and the alloy parts |
KR20140068246A (en) | 2011-09-30 | 2014-06-05 | 크루서블 인텔렉츄얼 프라퍼티 엘엘씨. | Injection molding of amorphous alloy using an injection molding system |
KR20140003069A (en) | 2012-06-29 | 2014-01-09 | 한국생산기술연구원 | Metal member having inner structure, inner structure molding frame, injection molding method of metal member using the same and metal member manufactured by the same |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2023236719A1 (en) * | 2022-06-11 | 2023-12-14 | 安徽昊方机电股份有限公司 | Needle for warp knitting machine and method for manufacturing needle by means of amorphous alloy injection molding process |
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