KR20160001953A - Manufaturing method of multi functional composition containing detoxicated sulfur - Google Patents

Abstract

The present invention relates to a method for manufacturing a multifunctional composition containing detoxified sulfur. More specifically, the manufacturing method comprises: a detoxified sulfur pulverizing step of pulverizing detoxified sulfur; a mixture preparing step of mixing the detoxified sulfur, which is pulverized by the detoxified sulfur pulverizing step, with a multifunctional mixture consisting of purified water, hypochlorous acid water, salicylic acid, beta-glucans, ionized silicate, selenium, ascorbic acid, chitosan, and minerals; a liposome forming step of forming a film on the mixture prepared by the mixture preparing step; a drying step of drying the mixture on which the film is formed by the liposome forming step; a liquefying step of liquefying the mixture dried by the drying step; and a dispersing and stirring step of mixing a stabilizer with the mixture liquefied by the liquefying step, and stirring the same. The multifunctional composition containing the detoxified sulfur manufactured by the above steps is applicable in various fields such as beauty products or feed, agricultural pesticides, fertilizers, antibiotics, antiviral agents, antifungal drugs, agricultural materials, etc. since the detoxified sulfur and minerals contained in the multifunctional composition have a high penetration rate and a high adsorption rate.

Description

TECHNICAL FIELD [0001] The present invention relates to a multifunctional composition containing a sulfur-

More particularly, the present invention relates to a method for producing a multifunctional composition containing legal sulfur, and more particularly, to a method for producing a multifunctional composition containing sulfur, And a method for producing a multifunctional composition containing sulfur, which can be applied to various fields such as agricultural materials.

Sulfur (sulfur) is a kind of element which belongs to group 6B of the periodic table. It maintains a yellow solid state at room temperature but reacts with almost all metals except gold and platinum to form sulfide , the natural mainly pyrite jayeonhwang combined with heavy metals or glass state (FeS _2), galena (PbS), sphalerite (ZnS), chalcopyrite (CuFeS ₂₎ or sulfides such as barite (BaSO _4), anhydrite (硬石膏, in the form of CaSO _4), gypsum (CaSO ₄ · 2H2 _O) of hydrogen sulfide (H ₂ S) of volcanic gas, baths, spa, etc., including the sulfates, such as, sulfur dioxide (SO _2), sulfuric acid (H ₂ SO ₄₎ do.

However, since sulfur is highly toxic, it must be used after the method of removing toxic components in order to apply it as pesticide or fertilizer. Normally, sulfur is put into a porcelain bowl and sealed, then heated for about 48 hours, Is often used.

However, since the sulfur produced by the conventional method as described above is not completely removed from toxic components, if the mixing amount of sulfur can not be precisely controlled, the phenomenon that the agricultural or livestock is extinct when applied as pesticides or fertilizers There is a problem that can occur.

In order to solve the problem of toxic components of sulfur as described above, Korean Patent Registration Nos. 10-0454574 and 10-0509656 disclose a sulfur process method for removing toxic components from sulfur. However, And the manufacturing process is complicated, which is not applicable to mass production.

In addition, conventionally, since sulfur in the form of law is low in the rate of absorption into the body of livestock, most of the sulfur is excreted in the excrement so that the efficacy of sulfur can not be exhibited properly.

An object of the present invention is to provide a pesticidal composition which can be utilized as various pesticides and fertilizers because of its high penetration and absorption rate of sulfur and minerals and can be added to pesticides and fertilizers to improve performance and is harmless to the human body In addition, since it is biodegraded in the soil and acts as a nutrient, it improves the quality of the soil and adds useful ingredients for the growth of agricultural products. It can be used for disinfection, sterilization, antibacterial, antiviral, It is another object of the present invention to provide a method for producing a multifunctional composition containing sulfur, which is effective also for releasing anions, adsorbing waste and heavy metals, purifying soil, proliferating lactic acid bacteria, inhibiting harmful bacteria, inhibiting excess nitrogen absorption, and enhancing immunity.

Another object of the present invention is to provide a multifunctional composition containing sulfur, which is effective for skin care and effective for anti-inflammation, antifungal and the like, containing effective ingredients for skin regeneration and whitening such as salicylic acid, ascorbic acid, ionic silicate and chitosan Method.

The object of the present invention is to provide a process for the preparation of a process for the preparation of a process for the preparation of a process for the preparation of a process for the preparation of a process for the preparation of a process for the preparation of Functional mixture, a liposomizing step of forming a coating on the mixture prepared through the step of preparing the mixture, a drying step of drying the coated mixture through the liposomizing step, a drying step of drying through the drying step And a dispersing and stirring step of mixing and stirring the stabilized agent in the liquefied mixture through the liquefaction step. The present invention also provides a process for producing a multifunctional composition containing sulfur, .

According to a more preferred feature of the present invention, the legal sulfur pulverization step is carried out by pulverizing the legal sulfur into a particle size of 0.01 to 0.1 micrometer.

According to a more preferred feature of the present invention, the preparation of the mixture comprises 1 to 30% by weight of the legal sulfurized pulverized by the above-described sulfurizing step, and the purified water, hypochlorous acid water, salicylic acid, beta- glucan, ionic silicate, selenium, ascorbic acid, 70 to 99% by weight of a multifunctional mixture of chitosan and mineral is mixed.

According to a further preferred feature of the present invention, the mineral is at least one selected from the group consisting of bentonite, zeolite, ilite, tourmaline and molybdenum.

According to an even more preferred feature of the present invention, the liposomizing step comprises mixing 1 to 5% by weight of the mixture prepared through the mixture preparation step to 95 to 99% by weight of a phospholipid mixture, mixing the mixture at a rate of 5 to 10 Minute, stirring the primary stirred mixture at a rate of 10 to 50 rpm for 10 to 20 minutes, and then heating the mixture at a temperature of 65 to 75 ° C for 30 to 60 minutes is repeated three to six times Is repeated.

According to a further preferred feature of the present invention, the phospholipid mixture comprises 85 to 98% by weight of purified water, 1 to 10% by weight of phospholipid and 1 to 5% by weight of water-soluble beta-glucan.

According to a further preferred feature of the present invention, the phospholipid is one selected from the group consisting of lecithin, cephalin, sphingomyelin, cardiolipin, phosphoinositide and acetic acid.

According to an even more preferred feature of the present invention, the drying step comprises centrifuging the coated mixture through the liposomizing step to remove the liquid component, and then drying the dried product at a temperature of 100 to 150 at a temperature of 35 to 45 DEG C for 10 to 15 minutes And dried.

According to a further preferred feature of the present invention, the liquefaction step comprises mixing 20 to 25% by weight of the dried mixture through the drying step with 5 to 10% by weight of a surfactant and 65 to 75% by weight of water.

According to an even more preferred feature of the invention, the dispersion agitation step comprises mixing from 99 to 99.5% by weight of the liquefied mixture through the liquefaction step with 0.5 to 1% by weight of the stabilizer, For 10 to 15 minutes, and homogenizing the emulsified mixture for 5 to 10 times at a pressure of 100 to 300 atm using a high-pressure homogenizer.

The process for preparing a multifunctional composition containing sulfur according to the present invention can be utilized as various pesticides and fertilizers because of the high penetration and absorption rate of sulfur and minerals. Since it is composed of natural ingredients and not only harmless to human body but also biodegraded in the soil and acts as a nutrient, it improves the quality of the soil and adds useful ingredients for the growth of agricultural products, , Pesticide prevention, acidification prevention, as well as a multifunctional composition containing sulfur, which is effective for releasing far infrared rays and anions, adsorbing waste and heavy metals, and purifying soil, proliferating lactic acid bacteria, inhibiting harmful bacteria, suppressing nitrogen absorption and enhancing immunity .

In addition, it has an excellent effect of providing a multifunctional composition containing legal sulfur which is effective for skin care and effective for skin regeneration and whitening, such as salicylic acid, ascorbic acid, ionic silicate and chitosan, .

FIG. 1 is a flow chart showing a method for producing a multifunctional composition containing sulfur according to the present invention.

Hereinafter, preferred embodiments of the present invention and physical properties of the respective components will be described in detail with reference to the accompanying drawings. However, the present invention is not limited thereto, And this does not mean that the technical idea and scope of the present invention are limited.

The process for producing a multifunctional composition containing a legal sulfur according to the present invention comprises: a step of subjecting a process sulfur to pulverization (S101); and a step of subjecting the process sulfurized through the process step (S101) to purified water, hypochlorous acid water, (S103) for mixing with a multifunctional mixture composed of salicylic acid, beta-glucan, ionic silicate, selenium, ascorbic acid, chitosan and minerals, a liposomal preparation for forming a coating on the mixture prepared through the mixture preparation step (S103) A liquefaction step (S109) for liquefying the dried mixture through the drying step (S107), and a liquefaction step (S109) for drying the mixture formed through the drying step (S107) (S109) in which the stabilizing agent is mixed and stirred in the liquefied mixture through the slurry mixing step (S109).

The legal sulfur pulverization step (S101) is performed by pulverizing the process sulfur with a particle size of 0.01 to 1 micrometer. The above-mentioned process sulfur pulverized with the particle size improves the mixing property with the above-mentioned multifunctional mixture, Formation of the coating film is easy in the liposomizing step (S105).

The preparation of the mixture (S103) may be carried out in the same manner as the preparation of the multifunctional mixture comprising purified water, hypochlorous acid water, salicylic acid, betaglucan, ionic silicate, selenium, ascorbic acid, chitosan and minerals 1 to 30% by weight of the legal sulfurized pulverized by the above-described sulfurizing step (S101) is mixed with purified water, hypochlorous acid water, salicylic acid, beta glucan, ionic silicate, selenium, ascorbic acid, chitosan and mineral And 70 to 99% by weight of the multifunctional mixture.

Wherein the multifunctional mixture comprises 0.1 to 5 wt% of hypochlorous acid, 0.1 to 5 wt% of salicylic acid, 1 to 5 wt% of beta glucan, 0.5 to 2 wt% of ionic silicate, 0.5 to 2 wt% of selenium, 5 wt.%, Chitosan 1 to 5 wt.%, Mineral 8.5 to 44 wt.%, And purified water balance.

The above-mentioned sulfur has sterilization, heavy metal detoxification and purification. The hypochlorous acid water serves as a sterilizing disinfectant when it shows a concentration of 20 to 30 ppm. When the concentration of 80 to 120 ppm shows it, It serves to control the pH of the multifunctional mixture.

The salicylic acid exhibits an effect of increasing antioxidant, exfoliation, antibacterial effect, skin whitening effect, feed efficiency improvement, mortality reduction and livestock egg production rate. The beta glucan is a kind of microorganism called Aureobasidium, The same functional polysaccharide-producing polysaccharide such as sugar alcohols and pullulan exhibits the form of beta-glucan (1-3) which is polymerized with glucose as a center of β-1,3 chemical bond. Antitumor, antitumor, immunity , Lowering cholesterol, inhibiting body fat formation, liver protection, improving animal diarrhea, and improving pheosis.

In addition, the ionic silicate exhibits cell growth, cleavage, promotion of regeneration, improvement of immunity, improvement of self-sterilizing power, improvement of circulation action, prevention of aging and improvement of wrinkles, and the selenium has an anionization, anticancer, antioxidant activity, glutathione activation, , Improved immunity and skin whitening effect.

In addition, the chitosan serves to improve the adsorption, persistence, moisturizing, film formation and thickening of the multifunctional mixture, and the ascorbic acid promotes skin whitening, antioxidation, anti-aging, wrinkle and collagen synthesis .

In addition, it is preferable that the mineral is at least one selected from the group consisting of bentonite, zeolite, ilite, tourmaline and molybdenum. The bentonite is excellent in the removal of odor, excellent adsorption of waste, antimicrobial activity, promotion of metabolism, The tourmaline exhibits the effect of promoting the absorption of the multifunctional mixture, preventing deterioration, releasing anions, and removing odors, and the molybdenum has an effect of releasing anions, promoting growth, decomposing harmful substances and containing nitrate reductase The zeolite exhibits effects of deodorization, hygroscopicity, antimicrobial activity, elimination of waste products, excess nitrogen inhibition, acid soil improvement, skin cell activation and anion release effect. The yilite is useful for proliferation of beneficial bacteria, reduction of harmful bacteria, Radiation and immunity.

Also, the multifunctional mixture is preferably mixed in a pulverized state before being mixed with the pulverized legal sulfur mixture. The multifunctional mixture of the above-mentioned ingredients is added to a milling device filled with a ball mill having a diameter of 4 to 6 millimeters After the primary milling at a speed of 500 to 1000 rpm for 15 to 30 minutes, the primary milled mixture is fed into a milling machine filled with a ball mill having a diameter of 0.5 to 0.7 mm and fed at a speed of 1500 to 3000 rpm at a speed of 60 to 180 Min. ≪ / RTI >

The mixture obtained through the first pulverization process during the pulverization process has a particle size of 2 to 5 micrometers and the particle size of the mixture subjected to the second pulverization process has a size of 0.1 to 0.2 micrometer.

The liposomalization step (S105) is a step of forming a coating on the mixture prepared through the mixture preparation step (S103), and 1 to 5% by weight of the mixture prepared through the mixture preparation step (S103) 99% by weight, and the mixture is stirred for 5 to 10 minutes at a speed of 1,500 to 2,000 rpm, and the primary agitated mixture is subjected to secondary stirring for 10 to 20 minutes at a speed of 10 to 50 rpm, At a temperature of 30 to 60 minutes, is repeated three to six times.

In the case where a phospholipid mixture is used in the liposomizing step (S105) as described above, the phospholipid mixture contains 85 to 98% by weight of purified water, 1 to 10% by weight of phospholipid and 1 to 5% by weight of water- And the phospholipid is preferably one selected from the group consisting of lecithin, sepharin, sphingomyelin, cardiolipin, phosphoinositide and acetic acid.

As described above, when the liposomalization step (S105) is performed, the niacin mixture particles produced through the mixture preparation step (S103) are contained in the coating of the phospholipid mixture, and a vesicle in which a single or multiple emulsified capsules are formed in capsule form The beta-glucan contained in the phospholipid mixture is easily dissolved in water as a glucose polymer, and is classified into cellulose, laminaran and lichenan depending on the structure of glucose. That is, since the non-aqueous sulfur is not saturated with water, a phospholipid mixture containing water-soluble betaglucan is surrounded by particles of the mixture prepared through the preparation of the mixture to saturate it in a capsule form.

In addition, the liposomizing step (S105) may be carried out using cholesterol or vegetable oil in addition to phospholipids. When cholesterol is used, cholesteryl acetate, cholesteryl isostearate, and cholesteryl methadamate It is preferable to use a mixture of nantle extract, clove tree extract, nut oil and glyceryl when using vegetable oil.

The nymph tree extract and clove tree extract are registered as a product that can be used as a material for the management of pests of environmentally friendly and organic agricultural products in a comprehensive disease pest control management system. 100% vegetable ingredient acts on the hormone series of pests, And suppresses growth and feeding, thereby remarkably controlling the number of insect pests in the same area in the long term. Moreover, it has excellent anti-inflammatory action against harmful bacteria causing inflammation. Therefore, it is very effective for skin diseases acne arthritis asthma diabetes. It is absorbed quickly to the scalp layer to heal damaged damaged scalp and hair and helps to prevent collagen and aging. Incense is like garlic or sulfur, Contains essential amino acids. It contains a substance called tocopherol or azadiractin. It has a very strong antifungal effect on fungus and bacteria. It has a good harmony between saturated and unsaturated fatty acids. So it is easy to saponify, it is very effective for treating acne, High and excellent preservation.

The drying step (S107) is a step of drying the coated mixture through the liposomizing step (S105). The coated mixture is centrifuged through the liposomizing step (S105) to remove the liquid component. At a temperature of 35 to 45 캜 for 10 to 15 minutes.

After the drying step (S107), moisture contained in the coating-formed mixture is removed through the liposomizing step (S105).

The liquefaction step (S109) is a step of liquefying the dried mixture through the drying step (S107). In the drying step (S107), 20 to 25% by weight of the dried mixture is mixed with 5 to 10% 65 to 75% by weight.

As the surfactant, an anionic surfactant or a nonionic surfactant can be used. As the anionic surfactant, alkyl acyl glutamate, alkyl phosphate, alkyl lactylate, diacyl phosphate, alkyl lactate and trialkophosphate And the like. As nonionic surfactants, alkoxylated alkyl ethers, alkoxylated alkyl esters, alkylpolyglycosides, polyglyceryl esters and sugar esters can be used.

The dispersing and stirring step S111 is a step of mixing and agitating the stabilizing agent to the liquefied mixture through the liquefaction step S109. The stabilizing agent is added to 99 to 99.5% by weight of the liquefied mixture through the liquefaction step S109 To 1% by weight, and emulsifying at a temperature of 65 to 75 DEG C for 10 to 15 minutes using a homogenizer, and homogenizing the emulsified mixture for 5 to 10 times at a pressure of 100 to 300 atm using a high-pressure homogenizer Followed by cooling to a temperature of 30 to 40 占 폚.

At this time, acrylate, acrylate crosspolymer and carboxymethyl cellulose having 10 to 30 carbon atoms are preferably used as the dispersing agent, and xanthan gum, gellan gum and the like may be used.

The multifunctional composition containing the sulfur-containing sulfur according to the present invention is completed when the dispersion stirring step (S111) is completed. The multifunctional composition containing the sulfur-containing sulfur prepared by the above method can be used for the infiltration of sulfur and minerals, It can be applied to various fields such as beauty products, feed, pesticide, fertilizer, antimicrobial agent, antiviral agent, antifungal agent and agricultural material.

S101; Legal sulfur crushing step
S103; Mixture preparation step
S105; Liposomation step
S107; Drying step
S109; Liquefaction phase
S111; Dispersion stirring step

Claims (10)

A process for crushing legal sulfur; a sulfur crushing step;
A step of preparing a mixture of the legal sulfurized pulverized by the legal sulfur pulverization step with a multifunctional mixture of purified water, hypochlorous acid water, salicylic acid, beta glucan, ionic silicate, selenium, ascorbic acid, chitosan and minerals;
A liposomatization step of forming a coating on the mixture prepared through the preparation of the mixture;
Drying the coated mixture through the liposomizing step;
Liquefying the dried mixture through the drying step; And
And a dispersion and stirring step of mixing and stirring the stabilized agent in the liquefied mixture through the liquefaction step.
The method according to claim 1,
Wherein the legal sulfur pulverization step is a step of pulverizing the process sulfur into a particle size of 0.01 to 0.1 micrometer.
The method according to claim 1,
The preparation of the mixture is carried out using a multifunctional mixture 70 consisting of 1 to 30% by weight of the legal sulfurized pulverized by the legal sulfur crushing step and purified water, hypochlorous acid water, salicylic acid, betaglucan, ionic silicate, selenium, ascorbic acid, chitosan and minerals By weight to 99% by weight based on the total weight of the multifunctional composition.
The method according to claim 1 or 3,
Wherein the mineral is at least one selected from the group consisting of bentonite, zeolite, ilite, tourmaline and molybdenum.
The method according to claim 1,
Wherein the liposomizing step comprises mixing 1 to 5% by weight of the mixture prepared through the preparation of the mixture into 95 to 99% by weight of a phospholipid mixture, primary stirring at a speed of 1500 to 2000 rpm for 5 to 10 minutes, And the mixture is stirred for 10 to 20 minutes at a rate of 10 to 50 rpm and then heated for 30 to 60 minutes at a temperature of 65 to 75 DEG C for 3 to 6 times. ≪ / RTI >
The method of claim 5,
Wherein the phospholipid mixture comprises 85 to 98% by weight of purified water, 1 to 10% by weight of phospholipid and 1 to 5% by weight of water-soluble beta-glucan.
The method of claim 6,
Wherein the phospholipid is selected from the group consisting of lecithin, cephalin, sphingomyelin, cardiolipin, phosphoinositide, and acetic anhydride.
The method according to claim 1,
Wherein the drying step comprises centrifuging the mixture having the coating formed through the liposomizing step to remove the liquid component and then drying the mixture at a temperature of from 100 to 150 at a temperature of 35 to 45 ° C for 10 to 15 minutes, Wherein the multifunctional composition is a polyfunctional compound.
The method according to claim 1,
Wherein the liquefaction step comprises mixing 20 to 25% by weight of the dried mixture through the drying step with 5 to 10% by weight of a surfactant and 65 to 75% by weight of water. Way.
The method according to claim 1,
The dispersing and stirring step is performed by mixing 0.5 to 1% by weight of the stabilizer with 99 to 99.5% by weight of the mixture liquefied through the liquefaction step, emulsifying the mixture at 65 to 75 ° C for 10 to 15 minutes using a homogenizer And homogenizing the emulsified mixture for 5 to 10 times at 100 to 300 atm using a high-pressure homogenizer.

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