KR20150145954A - Wastewater purifying device and wastewater purifying system - Google Patents
Wastewater purifying device and wastewater purifying system Download PDFInfo
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- KR20150145954A KR20150145954A KR1020140075541A KR20140075541A KR20150145954A KR 20150145954 A KR20150145954 A KR 20150145954A KR 1020140075541 A KR1020140075541 A KR 1020140075541A KR 20140075541 A KR20140075541 A KR 20140075541A KR 20150145954 A KR20150145954 A KR 20150145954A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/08—Alkali metal chlorides; Alkaline earth metal chlorides
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
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- Water Supply & Treatment (AREA)
- Environmental & Geological Engineering (AREA)
- Hydrology & Water Resources (AREA)
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Abstract
Description
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a polluted water purification apparatus and system, and more particularly, to a polluted water purification apparatus and system which are modularized and easy to install and maintain in order to purify polluted water by condensing and precipitating organic matters in polluted water. will be.
In general, contaminated water containing organic matter such as green tide or red tide will block the sunlight in water and reduce the amount of dissolved oxygen, thereby destroying the water body system by reducing the survival rate of aquatic organisms.
More specifically, green tide refers to a phenomenon in which green algae, which are phytoplankton, are greatly increased in a eutrophicated lake or a stream having a slow flow rate, and the water is changed to green. When a green tide is covered on the surface of the lake, sunlight is blocked in water and dissolved oxygen is added The amount of dissolved oxygen in the water is reduced. This causes fish and aquatic creatures to die, smell bad, and destroy the ecosystem of the water, resulting in a number of social, economic and environmental problems. Once the nutrients entering the water are not removed, they remain in the aquatic ecosystem so that the algal blooms are recycled.
On the other hand, red tide is a phenomenon in which plankton suddenly reproduces in an enormous number and changes color of sea, river, canal, lake, etc. In general, red tide is often called red tide, The color depends on the color of the plankton causing. Phytoplankton such as diatom and dinoflagellate are the most common plankton causing red tides. In addition, there are many kinds of plankton that cause red tide by cyanobacteria, prototrophs (noctiluca), and ciliates (mesodinium) . The greatest cause of red tides is the eutrophication of water, as in South Korea, where there are too many organic nutrients in the water.
Here, various technologies related thereto are provided.
Korean Patent Laid-Open No. 10-2011-0030838 discloses a method for removing green algae or red tide through the application of yellow clay, more specifically, applying loess to a green or red tide occurrence area to cause aggregation of green or red tide organisms and loess, The present invention relates to a method for improving the quality of water by precipitating in water and, incidentally, destroying cells of algae and red tide organisms by the aluminum component in the loess.
Here, the prior art has only a temporary effect. The problem is that the sedimented green tide or red tide creature floats up again, the turbidity of the water body becomes high due to a large amount of yellow clay spraying, the fish is killed, As the soils become acidified, marine organisms can cause various secondary environmental pollution such as causing physiological disorder or death.
On the other hand, a technique for improving the quality of water by adding metal oxides in addition to the yellowing method and coagulating the organic matters contained in the polluted water is generally used.
Here, when a metal oxide (such as aluminum sulfate) is used, the flocculation reaction can be effectively performed, but a serious problem that causes various diseases (for example, Alzheimer's) as a harmful component to the human body may occur.
That is, a technology for effectively cleaning various polluted water including organic matter such as red tide or green tide and at the same time, harmless to the human body is desperately needed.
Korean Registered Utility Model No. 0343482 (Registered on Feb. 19, 2004) relates to a contaminated water purification system, which forms a water hole into which polluted water can flow in and out, and contains lumps, briquettes, mud, silica sand, A plurality of water tanks are arranged in series so that the contaminated water can be gradually purified.
Korean Patent Registration No. 0912071 (registered on Aug. 8, 2009) relates to a wastewater incineration purification apparatus, which can rapidly and effectively purify wastewater by burning organic matter and harmful bacteria contained in wastewater by microwaves generated from an incineration wave generator It is possible to obtain a purifying device capable of varying the size, and it is also possible to connect a plurality of the devices to one another, so that the device can be widely used for industrial or home use.
However, the Korean Registered Utility Model No. 0343482 has a disadvantage in that it requires a large-scale treatment facility, and is inconvenient in that the process of sedimentation and filtration, that is, the treatment takes a long time, is disclosed in Korean Patent No. 0912071 There is a problem that a large power consumption is required to process a large amount of polluted water.
SUMMARY OF THE INVENTION Accordingly, the present invention has been made keeping in mind the above problems occurring in the prior art, and it is an object of the present invention to provide a polluted water purification apparatus capable of performing polluted water treatment harmless to the human body through a desalination liquid condensate.
An object of the present invention is to provide a polluted water purification apparatus that can utilize wastes that cause serious environmental pollution as valuable industrial industrial resources and can perform a polluted water purification process economically.
An object of the present invention is to provide a polluted water purification apparatus capable of effectively raising the polluted water purification rate.
Disclosed is a contaminated water purification system capable of variably cleaning polluted water according to pollution degree and capacity of polluted water.
Among the embodiments, the pollution water purification apparatus includes a polluted water storage tank; A water quality measuring unit for measuring a water quality in the polluted water storage tank; And an injector for injecting first and second additives for flocculating and precipitating organic substances in the polluted water into the polluted water storage tank based on the measured water quality.
Here, the injection unit may include a first injection unit for injecting a first additive made of an aqueous solution of a metal oxide having a hydroxyl group (-OH) into the contaminated water in order to primarily coagulate the organic substances contained in the contaminated water; And a second ejection unit for ejecting a second additive including desulfurized condensed water extracted from the food waste desorbing liquid to the contaminated water for secondary aggregation and precipitation of the primary aggregate after the primary aggregation type.
In one embodiment, the polluted water purification apparatus may further include a mixing section for mixing the contaminated water before the operation of the jetting section.
In one embodiment, the polluted water purification apparatus may further include a purified water discharge unit for discharging the purified water from which the organic matter in the polluted water has been removed through the flocculation and sedimentation to the outside.
Here, the purified water discharging part may include an ultraviolet ray filter for sterilizing ultraviolet ray, which is discharged to the outside.
In one embodiment, the contaminated water purification apparatus may further include a sludge discharge unit for discharging the sludge generated through the flocculation and sedimentation.
In one embodiment, the polluted water purification apparatus may further include a control unit for controlling the injection unit by determining an injection time and an injection amount of at least one of the first and second additives based on the measured water quality.
Among the embodiments, the polluted water purification system includes a plurality of polluted water purification devices capable of being connected in series or in parallel according to at least one operating mode, and the purified water discharge line of the first polluted water purification device located at the front- Connectable with polluted water inflow line of water purifier; And a supply device for supplying first and second additives for flocculating and precipitating the organic matter in the contaminated water to each of the plurality of pollution water purification apparatuses, wherein each of the plurality of pollution water purification apparatuses comprises: A polluted water storage tank connected to a purified water discharge line; A water quality measuring unit for measuring a water quality in the polluted water storage tank; And a jetting unit for jetting the first and second additives into the contaminated water storage tank based on the measured water quality.
In one embodiment, the polluted water purification system may further comprise at least one pollution water purification apparatus based on the water quality measured in the plurality of pollution control apparatuses, and a control unit for controlling the operation of each of the supply apparatuses.
In one embodiment, the control unit may discharge the purified water discharge line of the first pollution water purification apparatus to the second polluted water purification apparatus, based on the measured water quality after spraying the first and second additives in the first pollution water purification apparatus, To the contaminated water inlet line of the device.
In one embodiment, the control unit may selectively apply one of the plurality of pollution control devices in serial connection, parallel connection, or combination connection in which serial connection and parallel connection are combined according to the at least one operating mode .
The disclosed technique may have the following effects. It is to be understood, however, that the scope of the disclosed technology is not to be construed as limited thereby, as it is not meant to imply that a particular embodiment should include all of the following effects or only the following effects.
The polluted water purification apparatus and system according to an embodiment of the present invention can perform polluted water treatment harmless to the human body through the desalination liquid condensate which is a natural substance.
The polluted water purification system and system according to an embodiment of the present invention can effectively increase the polluted water purification rate by controlling the input amount and the injection time of the additive based on the water quality measurement result of polluted water.
The polluted water purification system according to an embodiment of the present invention can provide a variable polluted water purification capability by controlling connection between a plurality of polluted water purification apparatuses in accordance with pollution degree and capacity of polluted water.
1 is a perspective view illustrating a polluted water purification system according to an embodiment of the present invention.
Fig. 2 is a view showing the polluted water purification apparatus shown in Fig. 1; Fig.
The description of the present invention is merely an example for structural or functional explanation, and thus the scope of the right of the disclosed technology should not be construed as being limited by the embodiments described in the text. That is, the embodiments are to be construed as being variously embodied and having various forms, so that the scope of the disclosed technology should be understood to include equivalents capable of realizing technical ideas.
1 is a perspective view illustrating a polluted water purification system according to an embodiment of the present invention.
Referring to FIG. 1, a contaminated water purification system 100 includes an
The polluted water purification system 100 performs steps of coagulating and precipitating organic matters in the polluted water by injecting first and second additives into the polluted water that has flowed in. Before describing the polluted water purification system 100, the first and second additives will be described in detail.
The first additive
The first additive corresponds to an aqueous solution of a metal hydroxide having a hydroxyl group (-OH), and can be uniformly sprayed on the water body in the form of an aqueous solution. In addition, the first additive can change the chemical state in the waterbody within a short time, and can primarily aggregate the green alga or red tide organism.
In one embodiment, the first additive may comprise at least one of sodium hydroxide (NaOH) and potassium hydroxide (KOH). Here, sodium hydroxide and potassium hydroxide have high solubility at room temperature, so they can be prepared in aqueous solution having high concentration [solubility of sodium hydroxide in water: 111 g / 100 ml (20 캜), potassium hydroxide in water Solubility: 110 g / 100 ml (25 캜)].
The concentration of sodium hydroxide (NaOH) or potassium hydroxide (KOH) in the first additive is not limited, but it is preferable that the concentration is high considering the coagulation speed and economical efficiency. For example, the first additive may consist of a saturated aqueous solution, in particular a saturated aqueous solution of sodium hydroxide (NaOH).
The second additive includes desulfurized condensate extracted from the food waste remover. Herein, food waste is collectively referred to as food wastes or food wastes which are abandoned by households and restaurants, food waste left over from the distribution process, food waste after the distribution period, etc., Lt; / RTI >
In one embodiment, the food waste rejection liquid is leachate generated during food garbage disposal, and may be a liquid contaminated water which can not be used in everyday life or industrially.
The desalination liquid condensate can be produced by heating and cooling the food waste removal liquid and can contain acetic acid (CH3COOH).
In general, the organic additive is a composition in which substances effective for flocculation or sedimentation are uniformly mixed. In contrast, the second additive used in the present invention is constituted separately from the first additive, After tea aggregation is terminated, it may be added to the polluted water to induce secondary aggregation and sedimentation of aggregates.
More specifically, the second additive is in the form of an aqueous liquid, like the first additive, and can be uniformly sprayed on the water body. On the other hand, since the polluted water occupies a predominant volume of water, the main phase is a liquid phase, and the second additive sprayed is also a liquid phase, so that the sprayed second additive changes the chemical state in the water body in a short time, Lt; RTI ID = 0.0 > coagulation < / RTI >
The aqueous solution of the desalin solution of the second additive reacts with the phosphorus component in the contaminated water to form a water-insoluble and heavier phosphate, and the formed phosphoric acid precipitates, so that the phosphorus component can be effectively removed, Can lead to the precipitation of the primary aggregate undergoing the reaction.
In one embodiment, the second additive may further comprise a metal oxide. Here, the metal oxide is selected from the group consisting of aluminum sulfate (Al 2 (SO 4) 3), aluminum chloride (AlCl 3), ferrous sulfate (FeSO 4), ferric sulfate (Fe 2 (SO 4) 3) And ferric chloride (FeCl3). The metal oxide may be harmful to the human body, but it may be contained in a small amount in the second additive for rapid aggregation reaction.
Here, the metal oxide can induce secondary agglomeration and precipitation in the primary agglomerate in the same manner as the aqueous solution of the desorbing liquid. More specifically, the water-soluble and non-water-soluble aluminum hydroxide [Al (OH) 3], iron hydroxide [Fe (OH) 2, or Fe OH) 3] and the like act synergistically so that rapid precipitation can be achieved.
Further, the aluminum ion or the iron ion of the second additive reacts with the phosphorus component in the water body to form a water-insoluble and heavier phosphate, and the phosphate formed is precipitated, so that the phosphorus component can be effectively removed. In addition, the phosphate formed can lead to precipitation of the primary aggregate that is floating during the precipitation process.
In one embodiment, aluminum sulfate (Al2 (SO4) 3), aluminum chloride (AlCl3), ferrous sulfate (FeSO4), ferric sulfate [Fe2 (SO4) 3], ferrous chloride Since ferric chloride (FeCl3) has high solubility at room temperature, it can be prepared in an aqueous solution having a high concentration [solubility of aluminum sulfate in water: 36.4 g / 100 ml (20 ° C) Solubility in water of ferrous sulfate: 25.6 g / 100 ml, solubility of ferrous chloride in water: 68.5 g / 100 ml (20 캜), chloride Solubility of ferric iron in water: 92 g / 100 ml (20 캜)].
In one embodiment, the first additive may be added until the pH of the contaminated water is adjusted to a range of 9 to 11, and the second additive may be added until the pH of the contaminated water is adjusted to a range of 6.5 to 8.5 .
More specifically, the polluted water generated in the green tide or the red tide generally becomes acidified due to the formation of nitrogen oxides or phosphorus oxides and the decrease of dissolved oxygen, and generally has a pH of 6-7. In the contaminated water purification process according to the present invention, it is preferable that the pH of the polluted water containing organic substances is adjusted to 9 to 11 by the addition of the first additive. The primary agglomeration and the rate of the agglomeration and the rate of the agglomeration are maximized in the pH range, and the aggregation strengthening effect or sedimentation effect of the second additive is maximized. It is preferable that the pH of the contaminated water after primary agglomeration is in the range of 6.5 to 8.5 on the basis of the primary water after the secondary agglomeration and precipitation. Therefore, in the polluted water purification process according to the present invention, each of the first and second additives can be put into the respective pH ranges until they are adjusted.
Referring again to FIG. 1, the
The
In one embodiment, the
The polluted water purification apparatus receives polluted water, flocculates and deposits organic matters in polluted water by using the first and second additives, and discharges polluted water (hereinafter referred to as " purified water " Or supply). Hereinafter, the pollution control device will be described in detail with reference to FIG.
Fig. 2 is a view showing the polluted water purification apparatus shown in Fig. 1; Fig.
2, the pollution
The polluted
Meanwhile, the polluted water inflow line and the purified water discharge line may be connected to the upper surface, side surface, and the like of the polluted
The water
Hereinafter, the water quality corresponds to the pH concentration is explained as an example.
The water
The
In one embodiment, the
In one embodiment, the
In one embodiment, as described above, the jetting
Alternatively, when the plurality of polluted
The mixing
For example, the
The purified
In the case where a plurality of polluted water purification apparatuses are serially connected to purify the polluted water stepwise, the purified
In one embodiment, the purified
The ultraviolet filter may comprise a conventional fluorescent lamp and an ultraviolet ray transmission filter (or glass).
In one embodiment, the purified
The carbon filter can remove the taste of the purified water and odor inducing substances through carbon and also remove the coloring substance, residual chlorine, surfactant, trihalomethane, trihalomethane precursor, pesticide and other organic substances .
1, the carbon filter may be provided in a purified water discharging portion of each of the pollution control devices in a pollution water purification system including a plurality of pollution water purification devices, and in particular, (Between the first and second pollution water purifying apparatuses on the right side) of the third pollution water purification apparatus in consideration of the water treatment cost, the efficiency of the carbon filter, etc. The purified water discharge unit includes an ultraviolet filter, It is possible to provide not only a carbon filter but also a filter used for ordinary water treatment. Particularly, when a plurality of polluted water purification apparatuses are connected, the presence or absence of each filter, It will be apparent to those skilled in the art that various changes may be made.
The
In one embodiment, the polluted
The control unit receives the measured water quality information from the water
As described above, when the measured pH concentration is 8 or less, the control unit can determine the amount of the first or second additive to be added in proportion to the difference in the pH concentration measured based on the pH 8. Further, the control unit may control the
The control unit can determine the operation mode of the polluted water purification system based on the pH concentration of the supplied polluted water or the supplied amount of the polluted water. Here, the operating mode includes a serial mode in which the pollution control apparatuses are connected in series, a parallel mode in which the pollution control apparatuses are connected in parallel, and a combination mode in which the series connection and the parallel connection are combined (combined) as described above.
The control unit can control the connection configuration between the plurality of polluted
The control unit includes a communication module for receiving the measured water quality information and transmitting various control signals, a processing module for determining the operation of each component based on the measured water quality information and pre-stored water quality management policy, a first additive for each water quality information, An input module for receiving a water quality management policy or a specific parameter from an administrator of the pollution water purification system, and a display for displaying the state of the pollution water purification system to the manager, Modules, and the like. For example, the control unit may be implemented as a conventional computer or a server.
The polluted
It will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the spirit or scope of the present invention as defined by the following claims It can be understood that
100: Pollution water purification system
110: Additive storage device
111: First additive storage device
112: Second additive storage device
120: Feeder
121: First additive supply device
122: second additive supply device
130: Contaminated water storage tank
140: Water quality measuring device
150:
160:
170: purified water discharging portion
180: sludge discharge portion
200: Pollution water purification device
210: Contaminated water storage tank
220: Water quality measurement unit
230:
231: First injection unit
232: Second injection unit
240: mixing part
250: purified water discharging portion
260: sludge discharge portion
Claims (11)
A water quality measuring unit for measuring a water quality in the polluted water storage tank; And
And a jetting unit for jetting the first and second additives for coagulating and precipitating organic matters in the polluted water into the polluted water storage tank based on the measured water quality.
A first injection unit for injecting a first additive made of an aqueous solution of a metal oxide having a hydroxyl group (-OH) into the contaminated water in order to primarily flocculate the organic matter contained in the contaminated water; And
And a second injection unit for spraying a second additive containing desulfurization liquid condensate extracted from the food waste removal liquid to the contaminated water to coagulate and precipitate the primary aggregate secondarily after the primary aggregation type.
And a mixing unit for mixing the contaminated water before the operation of the jetting unit.
And a purified water discharging unit for discharging the purified water from which organic matter has been removed in the contaminated water to the outside through the flocculation and sedimentation.
And an ultraviolet ray filter for sterilizing ultraviolet rays from the purified water discharged to the outside.
And a sludge discharge unit for discharging the sludge generated through the flocculation and sedimentation.
And a control unit for controlling the injection unit by determining an injection time and an injection amount of at least one of the first and second additives based on the measured water quality.
And a supply device for supplying first and second additives for flocculating and precipitating the organic matter in the contaminated water to each of the plurality of polluted water purification apparatuses,
Each of the plurality of pollution control devices
A contaminated water storage tank connected to a polluted water inflow line and a purified water discharge line;
A water quality measuring unit for measuring a water quality in the polluted water storage tank; And
And a jetting unit for jetting the first and second additives into the contaminated water storage tank based on the measured water quality.
Further comprising: a control unit for controlling operations of each of the at least one pollution water purification apparatus and the supply apparatus based on the measured water quality in the plurality of pollution water purification apparatuses.
The purified water discharge line of the first pollution water purification apparatus is connected to the polluted water inflow line of the second pollution water purification apparatus based on the measured water quality after spraying the first and second additives in the first pollution water purification apparatus Or shutting off the polluted water.
Wherein the at least one pollution control device selectively applies one of a serial connection, a parallel connection, or a combined connection in which a serial connection and a parallel connection are combined according to the at least one operation mode.
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KR950012552A (en) | 1993-10-22 | 1995-05-16 | 프레데릭 얀 스미트 | Color display tube with magnetic shield |
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