KR20150060011A - Deodorant composition - Google Patents

Abstract

The present invention can provide a composition to effectively remove various medicine odor components of a menstrual blood odor. According to the present invention, provided is a composition for menstrual blood odor deodorization containing a compound represented as chemical formula 1. In the chemical formula 1, X respectively and independently represents O, S, or NH, A_1 and A_2 respectively and independently represent H, OR, SR, or NHR, R respectively and independently represents H, and n represents an integer of 5 to 10.

Description

[Technical Field] The present invention relates to a composition for deodorant,

The present invention relates to a composition for acupuncture and deodorant comprising cucurbituril.

Incense or odor is a very good feeling or unpleasant feeling in a very small amount, so controlling incense and smell is very important for a healthier and more convenient life. To this end, various methods have been studied to remove odors and control the fragrance.

In women, although it depends on the individual, the incidence of acupuncture points during menstruation is very difficult to solve for women, and it is found that it is the second place among troubles that occur when using sanitary napkins. Conventionally, the deodorization method is used to remove the menstrual discharge.

As a representative method of deodorization, there are a masking method that makes odor impracticable by using incense, a physical method of adsorbing odor molecules by a very large number of fine pores such as activated carbon, a chemical method which uses an acid base neutralization or a redox reaction, And biological methods for eliminating odors from the process. The physical method has a high deodorizing power, but it requires a large surface area, and its use is limited because it is effective only in the powder state rather than in the liquid phase. In the chemical method, the chemical deodorant component is catechin, copper sulfate, copper acetate, copper chloride, copper gluconate, zinc sulfate, zinc chloride zinc chloride, zinc gluconate, zinc ricinoleate, green tea extract and persimmon extract were used. When the deodorant component is a metal salt, deodorization is carried out by forming a coordination bond with malodor molecules, and flavonoids containing a large number of hydroxyl groups (hydroxoy groups) are deodorized by oxidation-reduction action. Such a method using a chemical deodorant is very effective for collecting with some fatty acids, but it has a disadvantage that it is difficult to apply to various living odors. In addition, the masking method uses natural oriental herbal ingredients and fragrance, but it has been found that it is not preferable for women to produce such fragrance during the menstrual period.

In recent years, odor elimination technology using molecular trapping technology has been used to capture odor molecules at the molecular level and to eliminate odors. Such molecular trapping technology can impart excellent functionality such as protection, transmission and stability improvement of a drug which is difficult to achieve by the prior art, and in particular, a technique of removing odor by using cyclodextrin has been used (see Patent Document 1 Reference).

However, the deodorization technique described above removes only the perceived odor of some kinds of odor, or does not sufficiently remove it quantitatively, in order to remove perceived acupuncture from the secretions occurring during the menstrual period of women, there was. In addition, although the effect is good like activated carbon, it is difficult to apply to a product for eliminating acupuncture points, or most of the substances have high toxicity such as skin irritation although the effect is good.

1: International Patent PCT / US2001 / 15164

In order to solve the problems caused by the menstrual discharge, the present invention can provide a composition for effectively removing various fractions of menstrual blood.

The present invention provides a composition for menstrual bleeding, comprising a compound represented by the following formula (1).

≪ Formula 1 >

In Formula 1, X independently represents O, S or NH; A ₁ and A ₂ each independently represent H, OR, SR, or NHR; each R is independently H, a substituted or unsubstituted C ₁ -C ₃₀ alkyl, substituted or unsubstituted C ₂ -C ₃₀ alkenyl, substituted or unsubstituted C ₂ -C ₃₀ alkynyl, substituted or unsubstituted C ₂ -C ₃₀ alkyl carbonyl, substituted or unsubstituted Substituted or unsubstituted C ₁ -C ₃₀ alkylthiol, substituted or unsubstituted C ₁ -C ₃₀ thioalkyl, substituted or unsubstituted C ₁ -C ₃₀ alkylthiol, substituted or unsubstituted C ₁ -C ₃₀ alkoxy, substituted or unsubstituted C ₁ -C ₃₀ hydroxyalkyl, substituted Or unsubstituted C ₁ -C ₃₀ alkylsilyl, substituted or unsubstituted C ₁ -C ₃₀ aminoalkyl, substituted or unsubstituted C ₁ -C ₃₀ aminoalkylthioalkyl, substituted or unsubstituted C ₅ -C ₃₀ cycloalkyl, substituted or unsubstituted C ₅ -C ₃₀ heterocycloalkyl, substituted or unsubstituted C ₆ -C ₃₀ aryl, substituted or unsubstituted C ₆ -C ₂₀ arylalkyl, substituted Or unsubstituted C ₄ -C ₃₀ heteroaryl, or substituted or unsubstituted C ₄ -C ₂₀ heteroarylalkyl, and n represents an integer of 5 to 10.

According to the present invention, there is also provided a method for deodorizing a menstrual discharge, comprising the step of releasing the fragrance of the menstrual discharge and collecting the menstrual discharge when the fragrance-bearing compound of the formula (1) is contacted with the menstrual blood.

In addition, the present invention provides a sanitary napkin comprising the aforementioned composition for menstrual discharge.

The present invention relates to a composition for acupuncture and moxibustion and deodorization, and can use cucurbituril for excellent deodorization of menstrual discharge.

In addition, cucurbituril is very toxic to human body, so it can be safely used in sanitary napkins and the like.

1 is a diagram showing the structure of cyclodextrin.
2 is a graph comparing the structure and physical properties of cyclodextrin and cucurbituril.
FIG. 3 is a diagram showing the structure of the spherical carbobutyrate. FIG.
FIG. 4 is a graph showing acetone by Headspace-GC / Mass method. FIG.
FIGS. 5 and 6 are graphs respectively showing a mixture of acetone and beta-cyclodextrin and a mixture of acetonin and cucurbituril by Headspace-GC / Mass method.
7 is a graph of dimethylsulfide analyzed by the Headspace-GC / Mass method.
8 and 9 are graphs respectively showing a mixture of dimethyl sulfide and beta-cyclodextrin and a mixture of dimethyl sulfide and cucurbituril by Headspace-GC / Mass method.

The present invention relates to a composition for menstrual-cycle deodorization comprising a compound represented by the following general formula (1).

≪ Formula 1 >

Wherein each X independently represents O, S or NH; A ₁ and A ₂ each independently represent H, OR, SR or NHR; each R is independently H, a substituted or unsubstituted C ₁ Substituted or unsubstituted C ₂ -C ₃₀ alkyl, substituted or unsubstituted C ₂ -C ₃₀ alkenyl, substituted or unsubstituted C ₂ -C ₃₀ alkynyl, substituted or unsubstituted C ₂ -C ₃₀ carbonylalkyl, Substituted or unsubstituted C ₁ -C ₃₀ alkylthiol, substituted or unsubstituted C ₁ -C ₃₀ alkylthiol, substituted or unsubstituted C ₁ -C ₃₀ alkoxy, substituted or unsubstituted C ₁ -C ₃₀ hydroxyalkyl, hwandoen C ₁ -C ₃₀ alkyl silyl group, a substituted or unsubstituted C ₁ -C ₃₀ aminoalkyl, substituted or unsubstituted C ₁ -C ₃₀ alkylthio-alkyl amino, substituted or unsubstituted C ₅ -C ₃₀ cycloalkyl Alkyl, substituted or unsubstituted C ₅ -C ₃₀ heterocycloalkyl, substituted or unsubstituted C ₆ -C ₃₀ aryl, substituted or unsubstituted C ₆ -C ₂₀ arylalkyl, Unsubstituted C ₄ -C ₃₀ heteroaryl, or substituted or unsubstituted C ₄ -C ₂₀ heteroarylalkyl, and n represents an integer of 5 to 10.

Hereinafter, the composition according to the present invention will be described in more detail.

The menstrual discharge refers to the odor generated by the menstrual blood absorbed in the sanitary napkin when the sanitary napkin is used. Such acupuncture can occur in the component itself of fluid excretions such as sweat, physiological fluid and menstrual blood, or may occur when the components of fluid excretion deteriorate. Compounds related to the acupuncture point may be widely present, and specific examples thereof include diacetyl, trimethylamine, 3-methylbutanal, 3-methylbutanol, acetone, methylmercaptan, propylmercaptan, dimethylsulfide, Disulfide, and the like. Among these components, sulfur compounds such as dimethyl sulfide and dimethyl disulfide are included in the acupuncture point with a very small amount, but since they are highly correlated with the offensive odor, it is important to effectively remove the above components.

The composition for acupuncture and moxibustion according to the present invention may comprise a compound represented by the following formula (1) (hereinafter referred to as a compound of the formula (1)).

≪ Formula 1 >

In Formula 1, each X may independently be O, S, or NH, and may be specifically O. A ₁ and A ₂ each independently may be H, OR, SR or NHR, wherein each R is independently H, substituted or unsubstituted C ₁ -C ₃₀ alkyl, substituted or unsubstituted C ₂ -C ₃₀ alkenyl, substituted or unsubstituted C ₂ -C ₃₀ alkynyl, substituted or unsubstituted C ₂ -C ₃₀ alkyl carbonyl, substituted or unsubstituted C ₁ -C ₃₀ thioalkyl, substituted or unsubstituted C ₁ -C ₃₀ alkylthiol, a substituted or unsubstituted C ₁ -C ₃₀ alkoxy, substituted or unsubstituted C ₁ -C ₃₀ hydroxyalkyl, substituted or unsubstituted C ₁ -C ₃₀ alkyl silyl group, a substituted or unsubstituted Substituted or unsubstituted C ₁ -C ₃₀ aminoalkyl, substituted or unsubstituted C ₁ -C ₃₀ aminoalkylthioalkyl, substituted or unsubstituted C ₅ -C ₃₀ cycloalkyl, substituted or unsubstituted C ₅ -C ₃₀ heterocycloalkyl , Substituted or unsubstituted C ₆ -C ₃₀ aryl, substituted or unsubstituted C ₆ -C ₂₀ arylalkyl, substituted or unsubstituted C ₄ -C ₃₀ heteroaryl, or substituted or unsubstituted C ₄ -C ₂₀ heteroarylalkyl. Specifically, A ₁ and A ₂ each independently may be H, OH, or O-CH ₂ -CH═CH ₂ . In addition, n may be an integer of 5 to 10.

In the present invention, the compound of formula (1) may specifically be cucurbituril. Cucurbituril was first synthesized by Behrend et al. In 1905, cucurbit [6] uril (CB [6]), and its structure was identified in 1981. CB [6] is disadvantageous in that practicality is deteriorated because the inner cavity of the molecule is small in size and thus can capture only a very small and low molecular weight substance. However, since synthesis methods and purification methods of CB [5], CB [7], CB [8] and CB [10] have been developed, they have been used in various fields. In the present invention, Can be easily used.

The compound of formula (I) may have an excellent deodorizing effect compared to the cyclodextrin used as the deodorant of the present invention. The cyclodextrin has the structure shown in Fig. Specifically, cyclodextrin has a structure in which a glucose unit is linked. Depending on the number of glucose units, 5-cyclodextrin may be called? -Cyclodextrin, 6-cyclodextrin, and 7? -Cyclodextrin depending on the number of glucose units .

Since the cyclodextrin contains a hydroxyl functional group in the glucose unit, the cyclodextrin is more hydrophilic than the compound of the formula (1). In addition, since the molecular inlet of the compound of Chemical Formula 1 is a polar substance such as oxygen and the inside is composed of a hydrophobic bond, the compound of Chemical Formula 1 may have stronger binding force to the hydrophobic substance than the cyclodextrin.

In the present invention, FIG. 2 shows the structure, internal diameter and volume of the compound of Formula 1 (for example, cucurbituril) and cyclodextrin, and the compound of Formula 1 has a larger diameter and volume than the cyclodextrin.

First, in terms of the structure, the compound of formula (I) has a structure in the shape of a jar, and the cyclodextrin has a cone-cut structure (see FIG. 1). Due to the structure of these compounds, in the case of the compound of formula (I), the molecules (acetic acid component) entering the ring of the compound are difficult to escape to the outside again, and since the acicular component is hydrophobic, . However, in the case of cyclodextrin, the binding force with the acupuncture agent is weak and it is not easy to take out the acupuncture point because the molecule can enter and exit the larger diameter side. Also, looking at the inner diameter, the compound of formula (1) has a wider inner diameter than cyclodextrin. As a result, the compound of formula (I) can capture large molecules that can not be captured by cyclodextrin, and can collect a small number of substances having small molecular weights.

In the present invention, the n-value of the compound of Formula 1, that is, the cucurbituril may be an integer of 5 to 10, specifically, an integer of 5 to 8, more specifically, an integer of 6 to 8, as described above. 3 shows the structure of the compound according to the number of n. As shown in FIG. 3, when n is 5, the compound of Chemical Formula 1 is cucurbit [5] uril and n is 6 , Cucurbit [6] uril), and when n is 7, cucurbit [7] uril. Also, when n is 8, it may be cucurbit [8] uril.

Since the acupuncture point in the present invention is a mixture of odorous molecules having various molecular sizes, it is preferable that the compound of the formula (1) is varied in size of n, rather than having a single size, The deodorization efficiency of the stool can be increased. At this time, the mixing ratio of the compound of the formula (1) in which the size of n is different is not particularly limited and can be appropriately adjusted.

The content of the compound of formula (I) in the composition according to the present invention is not particularly limited and may be 0.01 to 10% by weight, 0.1 to 5% by weight, and 0.5 to 0.3% by weight based on 100% by weight of the composition. The deodorizing effect of the menstrual discharge is excellent in the above content range.

The composition for acupuncture and moxibustion according to the present invention may further include conventional deodorizing components conventionally used in addition to the compound of formula (1).

The types of these components may be selected from the group consisting of catechin, copper sulfate, copper acetate, copper chloride, copper gluconate, zinc sulfate, zinc chloride, zinc gluconate, zinc ricinilite, zinc lactate, green tea extract, have. By further including the general deodorizing component, the deodorizing effect can be further maximized.

The present invention also relates to a method for deodorizing menstrual blood using a composition comprising the compound of formula (1).

In the present invention, the deodorization of the menstrual discharge can be performed by directly spraying the composition containing the compound of the formula (I) onto the human body or spraying it onto the sanitary napkin. There is also a composition in the sanitary napkin that includes the compound of formula (I) to deodorize the menstrual discharge.

Since the compound of formula (1) has a ring structure, odor can be removed by collecting a molecule that induces an acupuncture component, that is, a malodorous substance in the ring.

Particularly, in the present invention, the compound of the formula (1) bearing the fragrance in the ring may be used. That is, the fragrance is preliminarily impregnated in the compound of formula (1), and then it can be used for deodorizing the menstrual discharge.

At this time, the fragrance is a molecule that can give a good feeling or comfort to a person. In the present invention, a fragrance composed of a cyclic compound or an alkyl group having a low molecular affinity with the compound of the formula (1) Citronellol, 2-Ethylbutyl acetate, Ethyl cinnamate, Geranial, Pinanol, Safrole, trans-geranyl, At least one fragrance selected from the group consisting of L-galaniol, Eucalyptol, Linalool, L-Menthone and D-Limonen can be used.

Since the fragrance has a weak binding force with the compound of the formula (1), when the fragrance is contacted with the compound after the fragrance is carried in the ring of the compound of the formula (1), the compound of the formula , The compound of formula (1) releases the fragrance inside the ring and collects the menstrual blood component that comes in contact with the ring. The fragrance may be released to give the effect of masking the odor.

The present invention also relates to a sanitary napkin comprising the compound of formula (1). The sanitary napkin comprising the composition according to the present invention can effectively suppress menstrual discharge, and the compound of formula (1) is human-friendly, so that the sanitary napkin to be manufactured is also harmless to the human body.

Hereinafter, embodiments of the present invention will be described in detail to facilitate understanding of the present invention. However, the embodiments according to the present invention can be modified into various other forms, and the scope of the present invention should not be construed as being limited to the following embodiments. Embodiments of the invention are provided to more fully describe the present invention to those skilled in the art.

≪ Example 1 > Comparison of effect of deodorization of acupoints (sensory evaluation)

Production Example 1

The mixture ratio of cucurbit [6] uril (POSTECH Advanced Materials Science Division, Korea) and cucurbit [7] uril (POSTECH Advanced Materials Science Division, Korea) as deodorant was 5: 5 was dissolved in water at a concentration of 0.50% to prepare a cucurbituril (CBs) solution.

≪ Comparative Example 1 &

Hydroxypropyl-cyclodextrin (β-CD) (Sigma-Aldrich, USA) as a deodorant was dissolved in water at a concentration of 0.5% to prepare a solution.

≪ Comparative Examples 2 to 4 >

(Taiyo Green Power, China) as a deodorant of Comparative Example 2, Zinc gluconate (Zn-Glu) (JOST Chemical, USA) as a deodorant of Comparative Example 3 and FG- 50 (Rilis < / RTI > Chem., Japan) was used.

The solution prepared according to the preparation example and the comparative example was applied to 10 female 20- to 40-year-old female susceptible to menstrual discharges by spraying 2 to 3 times immediately before using the sanitary napkin during menstruation period, A 5-point scale was used for the evaluation with a sniff test. The results of the sniff test are shown in Table 2 below.

- Evaluation standard -

1 point: Very low deodorizing power

2 points: weak deodorizing power

3 points: Normal

4 points: strong deodorant power

5 points: Very strong deodorizing power

Manufacturing example Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Deodorizing effect 4.2 2.1 3.0 2.1 3.5

As shown in Table 1, it can be confirmed that the preparation example using the cucurbituril (CBs) solution is superior in deodorizing power against the menstrual discharge, as compared with the comparative example using the conventionally used deodorant.

≪ Example 2 > Comparison of Deodorizing Effect on Acupuncture Points 1

Deodorizing powers of the components of the menstrual discharge (acetonin, trimethylamine, 3-methylbutanol, dimethyl disulfide and propyl mercaptan) were evaluated using deodorizers of Production Examples and Comparative Examples.

At this time, the concentration of each of the acupoints was 1000 ppm, and 1 g of deodorant (deodorant of Preparation Example and Comparative Example) was mixed per 10 g of the acupoint. The results of the deodorizing force evaluation are shown in Table 3 below.

- Evaluation standard -

1 point: Very low deodorizing power

2 points: weak deodorizing power

3 points: Normal

4 points: strong deodorant power

5 points: Very strong deodorizing power

Acupressure Manufacturing example Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Acetone 5 2 4 2 3 Trimethyl amine 3 2 4 5 5 3-methyl butanol 5 4 3 One 2 dimethyl disulfide 5 3 4 4 2 propyl mercaptan 4 2 3 One 5

As shown in Table 2 above, it can be seen that the solution of the preparation example using cucurbituril is effective for the deodorization of the acupuncture agent.

≪ Example 3 > Comparison of Deodorizing Effects on Acupuncture Points 2

The solution prepared according to the example and the comparative example 1 was used to evaluate the deodorizing power against the components of the menstrual discharge.

First, acetone (acetoin) and dimethyl disulfide, which are known as acupoints, were prepared in 0.1% aqueous solution, respectively. Thereafter, the solution was mixed with the solution prepared in Production Example or the solution prepared in Comparative Example 1 at a ratio of 10: 1 to prepare various solutions. The composition of the solution is shown in Table 3 below.

Constituent Solution 1 0.1% acetonin solution Solution 2 0.1% acetonin solution + 0.5% beta -CD solution (solution of Comparative Example 1) Solution 3 0.1% acetonin solution + 0.5% cucurbituril solution (solution of preparation example) Solution 4 0.1% dimethyl disulfide solution Solution 5 0.1% dimethyl disulfide solution + 0.5% beta -CD solution (solution of Comparative Example 1) Solution 6 0.1% dimethyl disulfide solution + 0.5% cucurbituril solution (solution of preparation example)

The amounts of the respective components of the solutions 1 to 6 were analyzed by the Headspace-GC / Mass method and shown in FIGS. 4 to 9.

FIG. 4 is a graph of acetonine analyzed by the Headspace-GC / Mass method, and peaks appear at about 2.80 and 3.50 (x axis). However, it can be seen that the peaks in FIG. 5, which is an analysis graph of solution 2 in which beta-cyclodextrin is added to acetonin and FIG. 6, which is an analysis graph of solution 3 in which cucurbituril is added, It was confirmed that the better effect was obtained, that is, the deodorizing effect of acetone was excellent.

7 is a graph of dimethyl disulfide analyzed by the Headspace-GC / Mass method, and a peak is confirmed near about 6.50 (x axis). In the case of Fig. 8, which is an analysis graph of solution 5 in which beta-cyclodextrin is added to dimethyl disulfide, the effect of decreasing the peak is not large, indicating that the deodorizing effect of dimethyl disulfide is not excellent. However, in FIG. 9, which is an analysis graph of solution 6 in which cucurbituril was added to dimethyl disulfide, it can be seen that the peak was reduced, indicating that the deodorizing effect of dimethyl disulfide on cucurbituril is excellent.

Example 4: Comparison of deodorizing effect on dimethyl disulfide

Using a mixed solution of a solution of Preparation Example 1 (cucurbituril), a solution of Comparative Example 3 (zinc gluconate) and a solution of Preparation Example 1 and Comparative Example 3 in a ratio of 1: 1, The deodorizing ability of dimethyl disulfide, which is a component of menstrual discharge, was evaluated by a sniff test on a 5-point scale. The results of the sniff test are shown in Table 4 below.

- Evaluation standard -

1 point: Very low deodorizing power

2 points: weak deodorizing power

3 points: Normal

4 points: strong deodorant power

5 points: Very strong deodorizing power

Comparative Example 3 Production Example 1 Comparative Example 3+ Preparation Example 1 Zn-Glu CBs CBs + Zn-Glu Deodorizing effect 1.8 3.7 4.2

As shown in Table 4, when the cucurbituril is mixed with the conventional deodorizing material, it can be confirmed that the deodorizing power is further increased.

Claims (6)

Claims 1. A composition for menstrual-cycle deodorization comprising a compound represented by the following formula
≪ Formula 1 >

Wherein each X independently represents O, S or NH; A ₁ and A ₂ each independently represent H, OR, SR or NHR; each R is independently H, a substituted or unsubstituted C ₁ Substituted or unsubstituted C ₂ -C ₃₀ alkyl, substituted or unsubstituted C ₂ -C ₃₀ alkenyl, substituted or unsubstituted C ₂ -C ₃₀ alkynyl, substituted or unsubstituted C ₂ -C ₃₀ carbonylalkyl, Substituted or unsubstituted C ₁ -C ₃₀ alkylthiol, substituted or unsubstituted C ₁ -C ₃₀ alkylthiol, substituted or unsubstituted C ₁ -C ₃₀ alkoxy, substituted or unsubstituted C ₁ -C ₃₀ hydroxyalkyl, hwandoen C ₁ -C ₃₀ alkyl silyl group, a substituted or unsubstituted C ₁ -C ₃₀ aminoalkyl, substituted or unsubstituted C ₁ -C ₃₀ alkylthio-alkyl amino, substituted or unsubstituted C ₅ -C ₃₀ cycloalkyl Alkyl, substituted or unsubstituted C ₅ -C ₃₀ heterocycloalkyl, substituted or unsubstituted C ₆ -C ₃₀ aryl, substituted or unsubstituted C ₆ -C ₂₀ arylalkyl, Unsubstituted C ₄ -C ₃₀ heteroaryl, or substituted or unsubstituted C ₄ -C ₂₀ heteroarylalkyl, and n represents an integer of 5 to 10.
The method according to claim 1,
Acupuncture points include acupuncture points comprising at least one selected from the group consisting of diacetyl, trimethylamine, 3-methylbutanal, 3-methylbutanol, acetone, methylmercaptan, propylmercaptan, dimethylsulfide, propanethiol and dimethyldisulfide (2).
The method according to claim 1,
Which further comprises at least one selected from the group consisting of catechins, copper sulfate, copper acetate, copper chloride, copper gluconate, zinc sulfate, zinc chloride, zinc gluconate, zinc ricinilite, zinc lactate, green tea extract, (2).
A method for deodorizing a menstrual discharge, comprising the step of releasing the fragrance inside the ring and collecting the menstrual discharge when the compound represented by the following formula (1)
≪ Formula 1 >

Wherein each X independently represents O, S or NH; A ₁ and A ₂ each independently represent H, OR, SR or NHR; each R is independently H, a substituted or unsubstituted C ₁ Substituted or unsubstituted C ₂ -C ₃₀ alkyl, substituted or unsubstituted C ₂ -C ₃₀ alkenyl, substituted or unsubstituted C ₂ -C ₃₀ alkynyl, substituted or unsubstituted C ₂ -C ₃₀ carbonylalkyl, Substituted or unsubstituted C ₁ -C ₃₀ alkylthiol, substituted or unsubstituted C ₁ -C ₃₀ alkylthiol, substituted or unsubstituted C ₁ -C ₃₀ alkoxy, substituted or unsubstituted C ₁ -C ₃₀ hydroxyalkyl, hwandoen C ₁ -C ₃₀ alkyl silyl group, a substituted or unsubstituted C ₁ -C ₃₀ aminoalkyl, substituted or unsubstituted C ₁ -C ₃₀ alkylthio-alkyl amino, substituted or unsubstituted C ₅ -C ₃₀ cycloalkyl Alkyl, substituted or unsubstituted C ₅ -C ₃₀ heterocycloalkyl, substituted or unsubstituted C ₆ -C ₃₀ aryl, substituted or unsubstituted C ₆ -C ₂₀ arylalkyl, Unsubstituted C ₄ -C ₃₀ heteroaryl, or substituted or unsubstituted C ₄ -C ₂₀ heteroarylalkyl, and n represents an integer of 5 to 10.
5. The method of claim 4,
The fragrance carried on the inside of the ring is selected from the group consisting of citronellol, 2-ethylbutyl acetate, ethyl cinnamate, geranil, pinanol, saffrol, trans-geraniol, eucalyptol, - limonene. ≪ RTI ID = 0.0 > 11. < / RTI >
A sanitary napkin comprising a compound represented by the following formula (1):
≪ Formula 1 >

Wherein each X independently represents O, S or NH; A ₁ and A ₂ each independently represent H, OR, SR or NHR; each R is independently H, a substituted or unsubstituted C ₁ Substituted or unsubstituted C ₂ -C ₃₀ alkyl, substituted or unsubstituted C ₂ -C ₃₀ alkenyl, substituted or unsubstituted C ₂ -C ₃₀ alkynyl, substituted or unsubstituted C ₂ -C ₃₀ carbonylalkyl, Substituted or unsubstituted C ₁ -C ₃₀ alkylthiol, substituted or unsubstituted C ₁ -C ₃₀ alkylthiol, substituted or unsubstituted C ₁ -C ₃₀ alkoxy, substituted or unsubstituted C ₁ -C ₃₀ hydroxyalkyl, hwandoen C ₁ -C ₃₀ alkyl silyl group, a substituted or unsubstituted C ₁ -C ₃₀ aminoalkyl, substituted or unsubstituted C ₁ -C ₃₀ alkylthio-alkyl amino, substituted or unsubstituted C ₅ -C ₃₀ cycloalkyl Alkyl, substituted or unsubstituted C ₅ -C ₃₀ heterocycloalkyl, substituted or unsubstituted C ₆ -C ₃₀ aryl, substituted or unsubstituted C ₆ -C ₂₀ arylalkyl, Unsubstituted C ₄ -C ₃₀ heteroaryl, or substituted or unsubstituted C ₄ -C ₂₀ heteroarylalkyl, and n represents an integer of 5 to 10.

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