KR20150021459A - Hybrid Heat Insulation Sheet, Method for Manufacturing the Same and Heat Insulating Panel - Google Patents

Abstract

The present invention relates to a hybrid insulation sheet, a method to manufacture the same, and an insulation panel. A phase change material (PCM) and a nanofiber web are combined for transferred heat to be blocked in the nanofiber web, thereby reducing primarily a quantity of heat transferred. A structure maximizing the efficiency of a heat cut-off can be realized by absorbing heat from the phase change material embedded in the nanofiber web.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a hybrid heat-insulating sheet,

The present invention relates to a heat insulating sheet, and more particularly, to a hybrid heat insulating sheet, a method of manufacturing the same, and a heat insulating panel.

Recently, energy-efficient eco-friendly industry has emerged and various studies are being conducted to solve energy and environmental problems at the same time in the world.

Especially, from the viewpoint of global warming, the amount of power consumption of the refrigerator can be reduced, and in order to reduce the energy of the building, various technologies are being developed for the insulation material.

The refrigerator consumes a large amount of electricity in household appliances, and the reduction in the power consumption of the refrigerator is indispensable as a measure against global warming. The power consumption of the refrigerator is largely determined by the efficiency of the cooling compressor and the heat insulating performance of the heat insulator relative to the amount of heat leakage.

In recent years, VIP (Vacuum Insulation Panel) and aerogels have been attracting attention. VIM (Vacuum Insulation Material), DIM (Dynamic Insulation), and so on have been attracting attention as insulation materials for energy saving of buildings, traditionally used for insulation materials such as mineral wool and polyurethane. Materials) are being studied with future technologies.

VIPs and aerogels with very low thermal conductivity have the advantage of reducing energy consumption compared to existing insulation materials and thus can greatly expand the residential area. In particular, aerogels can be made of translucent and transparent materials, very big.

Korean Patent Laid-Open Publication No. 10-2011-77859 discloses a core part including a core material; And a jacket covering the core portion, wherein the core portion is formed in a reduced pressure state, wherein the jacket material comprises at least one nonwoven fabric layer. In this case, the core of the vacuum insulation material is made of glass fiber, polyurethane, polyester, polypropylene and polyethylene, but the pore size inside the glass fiber aggregate is not suitable for trapping air, And the glass fiber has a complicated and difficult manufacturing process.

Korean Patent Laid-Open Publication No. 10-2011-15326 discloses a core of a vacuum insulator, which is located inside the shell of a vacuum insulator, wherein the core is formed by thermally fusing synthetic resin fibers and bonding them together. However, The fibers are heated and fused to each other by heating the fiber to a temperature of the melting point so that the synthetic resin fiber has an inorganic ball state having almost no pores,

Therefore, the inventors of the present invention invented by inventing the structural characteristics of the heat insulating sheet capable of maximizing the heat insulating efficiency by continuing the research for improving the heat insulating efficiency, thereby saving energy, being environmentally friendly, more economical, Thus completing the present invention.

Korean Patent Laid-Open No. 10-2011-77859 Korean Patent Publication No. 10-2011-15326

The present invention has been made in view of the problems of the prior art, and it is an object of the present invention to provide a nanofiber web which blocks heat by using laminated nanofibers and fine micropores produced thereby, The present invention provides a hybrid thermal insulation sheet which can be embedded in a nanofiber web to improve heat insulation efficiency, and a manufacturing method thereof.

Another object of the present invention is to provide a hybrid heat-insulating sheet and a method of manufacturing the same which can easily realize a structure that is folded many times by applying a nanofiber web having excellent flexibility.

It is still another object of the present invention to provide a hybrid thermal insulation sheet and a method of manufacturing the same that can maximize heat shielding efficiency by implementing a heat insulating sheet by hybridizing a multi-stage heat shielding structure and a heat absorbing structure.

It is still another object of the present invention to provide an insulating panel which can be improved in heat insulation characteristics by applying a heat insulating sheet capable of sequentially performing heat shielding and heat absorption.

According to an aspect of the present invention, there is provided a nanofibrous web comprising: a first nanofiber web and a second nanofiber web which are hybridized by nanofibers composed of a polymer having a low thermal conductivity and have a fine pore structure; And a phase change material (PCM) interposed between the first and second nanofiber webs.

According to an embodiment of the present invention, there is also provided a method of fabricating a nanostructure, comprising: forming a first nanofiber web having a fine pore structure on a first support; Forming a second nanofiber web having a fine pore structure on a second support; And hybridizing the first and second nanofiber webs with a phase change material interposed between the first and second nanofiber webs.

According to another aspect of the present invention, there is provided a cigarette comprising: a casing member having an inner space; And a hybrid heat-insulating sheet disposed inside the sheath material and supporting the sheath material, wherein the hybrid heat-insulating sheet has a microporous pore structure integrated by a nanofiber made of a polymer having a low thermal conductivity, First and second nanofiber webs; And a phase change material interposed between the first and second nanofiber webs.

As described above, in the present invention, the heat transferred by hybridizing a phase change material (PCM, Phase Change Material) and a nanofiber web is cut off from the nanofiber web to reduce the amount of heat transferred, It is possible to provide a technology for realizing a structure capable of absorbing heat from a phase change material having a high heat capacity and maximizing the heat shielding efficiency.

 The present invention adopts a heat insulating sheet of a nanofiber web in which electrospun nanofibers are arranged in a three-dimensional network structure to improve heat insulation performance by using nano-sized micropores of a nanofiber web having a high heat shielding ability .

The present invention achieves a hybrid insulation sheet of a laminated structure of a nanofiber web / support / nanofiber web / phase change material / nanofiber web / support / nanofiber web, It is possible to provide a technique capable of increasing the heat insulation efficiency.

In the present invention, a vacuum insulation panel (Vacuum Insulation Panel (VIP) having a core of a hybrid insulation sheet in which a phase change material is embedded in a nanofiber web can be provided to provide a vacuum insulation technique capable of maximizing the insulation characteristics.

According to the present invention, it is possible to provide an ultra-thin insulating sheet and a heat insulating panel by applying a nanofiber web, and thus it is possible to provide a technology for expanding the internal space of the refrigerator and the building with excellent heat insulating properties.

1 is a conceptual sectional view for explaining a hybrid thermal insulation sheet according to a first embodiment of the present invention;
2 is a conceptual sectional view for explaining a hybrid thermal insulation sheet according to a second embodiment of the present invention,
3 is a conceptual sectional view for explaining a hybrid thermal insulation sheet according to a third embodiment of the present invention,
4 is a conceptual cross-sectional view illustrating a method of manufacturing a hybrid thermal insulation sheet according to a third embodiment of the present invention,
5 is a conceptual sectional view for explaining a hybrid thermal insulation sheet according to a fourth embodiment of the present invention;
6 is a conceptual cross-sectional view illustrating a method of manufacturing a hybrid thermal insulation sheet according to a fourth embodiment of the present invention,
7 is a conceptual sectional view for explaining a hybrid thermal insulation sheet according to a fifth embodiment of the present invention,
8 is a conceptual cross-sectional view illustrating a method of manufacturing a hybrid thermal insulation sheet according to a fifth embodiment of the present invention,
9 is a conceptual sectional view showing a vacuum insulation panel (VIP) according to an embodiment of the present invention.
10 is a schematic cross-sectional view illustrating an electrospinning apparatus for forming a nanofiber web applied to a hybrid thermal insulation sheet according to an embodiment of the present invention.

The terms and words used in the present specification and claims should not be construed as limited to ordinary or dictionary terms and the inventor may appropriately define the concept of the term in order to best describe its invention It should be construed as meaning and concept consistent with the technical idea of the present invention.

Therefore, the embodiments described in this specification and the configurations shown in the drawings are merely the most preferred embodiments of the present invention and do not represent all the technical ideas of the present invention. Therefore, It is to be understood that equivalents and modifications are possible.

Hereinafter, the present invention will be described in more detail with reference to the drawings.

In the following description, the hybrid heat-insulating sheet and the heat insulating panel according to the present invention hybridize a phase change material (PCM, Phase Change Material) and a nanofiber web to block the heat transferred from the nanofiber web, , And a structure capable of absorbing heat from the phase change material to maximize heat insulation efficiency.

The heat-insulating sheet and the heat-insulating panel of the present invention to be described later can be applied to a refrigerator and a building, but the present invention is not limited thereto and can be similarly applied to a heat-insulating material used in other industrial fields.

FIG. 1 is a conceptual sectional view for explaining a hybrid insulation sheet according to a first embodiment of the present invention, and FIG. 2 is a conceptual sectional view for explaining a hybrid insulation sheet according to a second embodiment of the present invention.

In the present invention, a heat insulating sheet to which a phase change material and a nanofiber web are bonded is used. A hybrid heat insulating sheet is defined as a heat insulating sheet hybridized with a phase change material and a nanofiber web, And a plurality of pores arranged to trap air and suppress air convection to thereby primarily block heat. Therefore, the amount of heat transferred to the phase change material in the nanofiber web is reduced. When the heat passing through the nanofiber web is transferred to the phase change material, the heat is secondarily absorbed in the phase change material. As a result, the heat insulation performance of the hybrid insulation sheet is improved by blocking the heat in two stages. Here, hybridization means a bonding relationship such as adhesion, adhesion, lamination, contact, fixing, and the like.

Nanofibrous webs are randomly stacked of electrospun nanofibers and arranged in a three dimensional network structure. The nanofibers result in the formation of irregularly distributed micropores in the nanofiber web, and the ability to block the nanofibrous webs due to micropores increases, resulting in excellent thermal insulation performance.

1 and 2, the hybrid thermal insulation sheet 100 has a structure in which the phase change material 120 is wrapped around the nanofiber webs 151 and 152 and is hybridized. On the outer surface of the hybrid thermal insulation sheet 100, The fibrous webs 151 and 152 are disposed and the core-phase-change material 120 is disposed in the interior of the hybrid thermal insulation sheet 100.

The heat transmitted to the hybrid thermal insulation sheet 100 is first contacted with and transferred to the nanofiber webs 151 and 152 and blocks heat from the plurality of micropores and nanofibers of the nanofiber webs 151 and 152. The amount of heat transferred to the nanofiber webs 151 and 152 is reduced by the amount of heat intercepted by the nanofiber webs 151 and 152 to be transferred to the phase change material 120 and the heat is absorbed by the phase change material 120, The heat insulating efficiency of the heat insulating sheet 100 is substantially increased.

The phase change material 120 absorbs the transmitted heat and has excellent heat shielding performance. That is, when heat is transferred, the phase change material 120 absorbs heat while changing from a solid phase to a liquid phase by endothermic reaction. And the phase change material 120 changes back to solid when the ambient temperature falls.

1, a phase change material 120 is disposed on a second nanofiber web 152 and a phase change material 120 is disposed on a first nanofiber web 151. In this case, The first nanofibrous web 151 and the second nanofibrous web 152 are formed by a simple manufacturing method in which the first nanofibrous web 151 is fixed to the second nanofibrous web 152 by wrapping the first nanofibrous web 120, The core 120 may be embedded in the core. At this time, if the hybridization process is performed while the second nanofiber web 152 is supported by the support (not shown), the first and second nanofiber webs 151 and 152 can maintain flatness.

2, after the phase change material 120 is interposed between the first and second nanofiber webs 151 and 152, the edges of the first and second nanofiber webs 151 and 152 are joined together to form the hybrid heat- ).

On the other hand, a nanofiber web is produced by preparing a spinning solution by mixing a polymer material having a low thermal conductivity and a solvent at a certain ratio, spinning the spinning solution to form nanofiber, And is formed in the form of a nano web having pores.

As the diameter of the nanofibers is smaller, the specific surface area of the nanofibers is increased and the heat shielding ability of the nanofiber web having a plurality of micropores is increased, thereby improving the heat insulating performance.

The nanofibers have a diameter of, for example, 1 .mu.m or less, and the nanofiber web made of nanofibers has many micropores, so that air can be trapped in the micropores.

The fine pores formed in the nanofiber web are preferably set to 4 nm to 1 μm or less, and the diameter of the nanofibers can be controlled.

Here, the spinning method applied to the present invention is a spinning method using general electrospinning, air-electrospinning (AES), electrospray, electrobrown spinning, centrifugal electrospinning, , And flash-electrospinning may be used.

For the purpose of improving the heat resistance of a nanofiber web of a hybrid thermal insulation sheet, a mixed polymer having a low thermal conductivity and excellent heat resistance, or a mixed polymer of a polymer having a low thermal conductivity and a polymer having a high heat resistance, The nanofiber web obtained by the above method can be applied.

At this time, the polymer which can be used in the present invention is preferably dissolved in an organic solvent to be spinnable and low in thermal conductivity, and more preferably excellent in heat resistance.

Polymers that are capable of radiation and have low thermal conductivity include, for example, polyurethane (PU), polystyrene, polyvinyl chloride, cellulose acetate, polyvinylidene fluoride (PVDF), polyacrylonitrile , Polyvinyl acetate, polyvinyl alcohol, polyimide, and the like.

The polymer having excellent heat resistance is a resin which can be dissolved in an organic solvent for electrospinning and has a melting point of 180 ° C or higher. Examples of the resin include polyacrylonitrile (PAN), polyamide, polyimide, polyamideimide, poly Aromatic polyesters such as polyethylene terephthalate, polyethylene terephthalate, polyethylene terephthalate, and the like, polytetrafluoroethylene, polydiphenoxaphospazene, poly (ethylene terephthalate), poly Polyphosphazenes such as bis [2- (2-methoxyethoxy) phosphazene], polyurethane copolymers including polyurethane and polyether urethane, cellulose acetate, cellulose acetate butyrate, cellulose acetate propionate Etc. may be used.

The thermal conductivity of the polymer is preferably set to less than 0.1 W / mK.

Among the above polymers, polyurethane (PU) has a thermal conductivity of 0.016 to 0.040 W / mK, polystyrene and polyvinyl chloride have a thermal conductivity of 0.033 to 0.040 W / mK, and the nanofiber web obtained by spinning the polystyrene and polyvinyl chloride also has a low thermal conductivity .

The thickness of the nanofiber web can be set between 5 and 50 um, preferably 30 um.

Further, the nanofiber web may be laminated in multiple layers to have various thicknesses. That is, the heat insulating sheet of the nanofiber web applied to the present invention can have a high heat insulating performance while being manufactured in an ultra thin structure.

The solvent is selected from the group consisting of DMA (dimethyl acetamide), N, N-dimethylformamide, N-methyl-2-pyrrolidinone, DMSO, THF, DMAc, ethylene carbonate, DEC, dimethyl carbonate, ethyl methyl carbonate, propylene carbonate, water, acetic acid, and acetone. .

Since the nanofiber web is manufactured by the electrospinning method, the thickness is determined according to the spinning amount of the spinning solution. Therefore, there is an advantage in that it is easy to make the thickness of the nanofiber web to a desired thickness.

As described above, since the nanofibers are formed by the nanofiber web in which the nanofibers are accumulated by the spinning method, they can be formed into a plurality of pores without any additional process, and the size of the pores can be controlled according to the spinning amount of the spinning solution. Therefore, it is possible to finely form a large number of pores, so that the heat shielding performance is excellent and the heat insulating performance can be improved accordingly.

In the present invention, the spinning liquid for forming the nanofiber web may contain inorganic particles, which are heat insulating fillers for blocking heat transfer. In this case, the nanofibers of the nanofiber web may contain inorganic particles. The inorganic particles are located inside the radiated nanofiber, or are partially exposed to the surface of the nanofiber to block heat transfer. Further, the inorganic particles can improve the strength of the nanofiber web with an insulating filler.

Preferably, the inorganic particles are _{SiO 2, SiON, Si 3 N} 4, HfO 2, ZrO 2, Al 2 O 3, TiO 2, Ta 2 O 5, MgO, Y 2 O 3, BaTiO 3, ZrSiO 4, HfO ₂ , or one or more particles selected from the group consisting of glass fibers, graphite, rock wool, and clay are preferable, but not always limited thereto, More than one species may be mixed and included in the spinning solution.

In addition, fumed silica may be included in the spinning solution for forming the nanofiber web.

FIG. 3 is a conceptual sectional view for explaining a hybrid thermal insulation sheet according to a third embodiment of the present invention, FIG. 4 is a conceptual sectional view for explaining a method of manufacturing a hybrid thermal insulation sheet according to a third embodiment of the present invention FIG. 5 is a conceptual sectional view for explaining a hybrid thermal insulation sheet according to a fourth embodiment of the present invention, and FIG. 6 is a conceptual sectional view for explaining a method of manufacturing a hybrid thermal insulation sheet according to a fourth embodiment of the present invention to be.

In the present invention, a hybrid insulation sheet can be realized by composing a nonwoven fabric or a woven fabric into a nano-fiber web, and the non-woven fabric or woven fabric as a support can be a material capable of forming a double structure with a nanofiber web. Ring, hot melt bonding, ultrasonic bonding, laminating, etc., and it is sufficient that the nanofiber web can be combined with existing materials.

Particularly, the nonwoven fabric which can be used is a polyolefin-based porous membrane of a commercialized two- or three-layer structure, for example, a PP or PE membrane or a PP / PE / PP membrane or a monolayer PP or PE membrane, It is also possible to use a PET nonwoven fabric made of polyethylene terephthalate (PET) fiber or a nonwoven fabric made of PP / PE fibers having a double structure coated with PE.

Referring to FIGS. 3 and 4, it is possible to reinforce the strength of the hybrid heat-insulating sheet by combining the support body 170 such as a nonwoven fabric or woven fabric with the second nanofiber web 152. In this case, the second nanofiber web 152 may be formed by spinning the nanofibers on the support 170. In this case, the phase change material 120 may be placed on the second nanofibrous web 152, The fibrous web 151 is secured to the second nanofiber web 152 such that the phase change material 120 is interposed between the first and second nanofiber webs 151 and 152.

5 and 6, a second support body 172 in which a first support body 171 in which a first nanofiber web 151 is combined and a second nanofiber web 152 are prepared is prepared, After the phase change material 120 is interposed between the first and second nanofiber webs 151 and 152 and the first and second nanofiber webs 151 and 152 are fixed, the first and second supports 171 and 172 are joined together . Here, the first and second nanofiber webs 151 and 152 can be formed by directly spinning the nanofibers on the first and second supports 171 and 172, respectively.

FIG. 7 is a conceptual sectional view for explaining a hybrid thermal insulation sheet according to a fifth embodiment of the present invention, and FIG. 8 is a conceptual sectional view for explaining a method of manufacturing a hybrid thermal insulation sheet according to a fifth embodiment of the present invention .

The hybrid heat insulating sheet is obtained by combining the first and third nanofiber webs 151 and 153 on both sides of the first support 171 and composing the second and fourth nanofiber webs 152 and 154 on both sides of the second support 172 The phase change material 120 may be positioned between the first and second nanofiber webs 151 and 152 and the first and second supports 171 and 172 may be joined together.

The fifth hybrid heat-insulating sheet is a laminated structure of a nanofiber web / support / nanofiber web / phase change material / nanofiber web / support / nanofiber web, The heat is cut off from the fibrous web, so that the amount of heat transferred to the phase change material can be further reduced, and the heat insulating performance can be improved.

The nanofiber web used in the hybrid thermal insulation sheet described above may be a plate-like folded structure or a nanofiber web laminated structure laminated in multiple layers.

9 is a conceptual sectional view illustrating a vacuum insulated panel (VIP) according to an embodiment of the present invention.

The above-mentioned hybrid heat-insulating sheet is built in the heat insulation panel and can exhibit heat insulation performance.

9, the vacuum insulation panel 300 according to an embodiment of the present invention includes a cover material 310 having a gas barrier property and preferably forming a predetermined reduced pressure space therein, And a hybrid heat-insulating sheet 100 which is disposed on the outer surface of the cover member 310 and supports the outer cover member 310.

Since the hybrid thermal insulation sheet 100 applied to the vacuum insulation panel 300 includes a porous nanofiber web, it is possible to provide a plurality of micropores capable of trapping air, so that the air trapped in the micropores is self- It is possible to exert excellent heat insulating performance even when the inside of the outer cover 310 is not a vacuum or a reduced pressure space. Therefore, it is advantageous to apply it as a building insulation.

Here, the depressurized space means a depressurized space in which the inner pressure is lower than the atmospheric pressure.

In the vacuum insulation panel 300 according to an embodiment of the present invention, when the inside of the envelope material 310 is a vacuum or a depressurized space, moisture or gas is supplied to the inside of the envelope material 310 or the hybrid heat- And a getter material (not shown) for adsorbing a substance or the like. The getter material includes, for example, a desiccant in the form of a powder and a gas adsorbent, and can be packed with a PP or PE nonwoven fabric.

In addition, the getter material preferably includes at least one selected from the group consisting of silica gel, zeolite, activated carbon, zirconium, barium compound, lithium compound, magnesium compound, calcium compound and quicklime.

The kind of the getter material that can be used in the present invention is not particularly limited, and a material commonly used in the field of vacuum insulation material can be used.

The sheath material 310 covers the hybrid thermal insulation sheet 100 and serves to maintain the interior of the hybrid insulation sheet 100 under a reduced pressure or a vacuum state. The cover material 310 is previously formed in an envelope shape. After inserting the hybrid heat-insulating sheet 100, sealing is performed by thermocompression of the inlet portion in a vacuum atmosphere. Accordingly, the outer cover material 310 is used after being sealed in an envelope shape by first sealing outer edges of three sides of the upper outer cover material 310a and the lower outer cover material 320b.

The type of the cladding material usable in the present invention is not particularly limited, and materials conventionally used in the field of vacuum insulation materials can be used. The cover material 310 used in the present invention includes, for example, a sealing layer surrounding the hybrid thermal insulation sheet 100; A barrier layer surrounding the sealing layer; And a nonwoven layer or protective layer surrounding the barrier layer.

The sealing layer described above covers the embedded hybrid heat-insulating sheet 100 as the sealing (compression) is performed by the thermocompression bonding method and makes it possible to adhere to the core to maintain the shape of the panel. The material of the sealing layer usable in the present invention is not particularly limited and can be bonded by thermocompression. For example, the thermocompression layer may be a linear low density polyethylene (LLDPE), a low density polyethylene (LDPE) Polyolefin-based resins such as polyethylene (VLDPE) and high-density polyethylene (HDPE), thermocompression bonding such as polypropylene (PP), polyacrylonitrile film, polyethylene terephthalate film or ethylene-vinyl alcohol copolymer film, Or a mixture thereof, or a mixture thereof.

The barrier layer surrounds the sealing layer, maintains the degree of vacuum therein, and can block external gases and water vapor. In the present invention, the material of the barrier layer is not particularly limited and a laminate film (vapor deposition film) in which a metal is vapor-deposited on a metal foil or a resin film can be used. As the metal, aluminum, copper, stainless steel or iron can be used, but the present invention is not limited thereto.

The deposition film may be formed by depositing a metal such as aluminum, stainless steel, cobalt or nickel, silica, alumina or carbon by a deposition method or a sputtering method, A general resin film used in the art can be used. In the present invention, it is preferable to use an aluminum deposited film or aluminum foil as the barrier layer.

In addition, the nonwoven fabric layer surrounds the barrier layer and serves as a protective layer for primarily protecting the vacuum insulation from external impacts. In addition, the nonwoven fabric layer can solve the problem that the thermal performance of the heat insulating material is lowered due to the high thermal conductivity of the barrier layer. The material of the nonwoven fabric layer may be PP or PTFE.

In place of the nonwoven fabric layer, a protective layer made of one or two layers for protecting the barrier layer may be used. Such a protective layer may be composed of one or more resins selected from the group consisting of polyamide, polypropylene, polyethylene terephthalate, polyacrylonitrile, polyvinyl alcohol, nylon, PET, K-PET and ethylene vinyl alcohol.

10 is a schematic cross-sectional view illustrating an electrospinning apparatus for forming a nanofiber web applied to a hybrid thermal insulation sheet according to an embodiment of the present invention.

10, the electrospinning device includes a mixer 2 incorporating a stirrer 2 using a pneumatic mixing motor 2a as a driving source so as to prevent phase separation until a polymer material having a low thermal conductivity is mixed with a solvent, A mixing tank 1, and a plurality of spinning nozzles 4 to which a high voltage generator is connected. The polymer solution discharged from the mixing tank 1 to the plurality of spinning nozzles 4 connected to the metering pump not shown through the transfer tube 3 is passed through the spinning nozzle 4 charged by the high voltage generator, 5, and the nanofibers 5 are accumulated on the grounded collector 6 in the form of a conveyor moving at a constant speed to form the porous nanofiber web 7.

Generally, when a multi-hole radiation pack (for example, 245 mm / 61 holes) is applied for mass production, mutual interference occurs between the multi-holes, so that the fibers are blown away and are not collected. As a result, the separation membrane obtained using a multi-hole spinning pack becomes too bulky, making it difficult to form a separation membrane and causing radiation trouble.

In consideration of this, according to the present invention, as shown in FIG. 12, by using an air electrospinning method in which air 4a is jetted for each spinning nozzle 4 by using a multi-hole spinning pack, The web 7 is produced.

That is, according to the present invention, air is injected from the outer circumference of the spinning nozzle when electrospinning is performed by air electrospinning, and thus the fiber composed of a polymer having a high volatility plays a dominant role in collecting and accumulating air, Can produce this high nanofiber web and minimize the radiation problems that may occur as the fibers fly.

In the present invention, when a polymer material having a low thermal conductivity is mixed with a heat-resistant polymer material, the mixture is preferably added to a two-component solvent to prepare a mixed spinning solution.

The obtained porous nanofiber web 7 is then calendered at a temperature lower than the melting point of the polymer in the calendering device 9 to obtain a thin film nanofiber web 10 to be used as a core material.

In the present invention, if necessary, the porous nanofiber web 7 obtained as described above is allowed to remain on the surface of the nanofiber web 7 while passing through a pre-air dry zone by the preheater 8 It is also possible to carry out a calendering process after a process of controlling the amount of solvent and moisture.

The Pre-Air Dry Zone by the preheater 8 is a method in which air of 20 to 40 ° C is applied to the web by using a fan to remove the solvent remaining on the surface of the nanofiber web 7 By regulating the amount of water, the nanofiber web 7 can be controlled to be bulky, thereby increasing the strength of the separator and controlling the porosity.

In this case, when calendering is performed while the solvent is excessively volatilized, the porosity is increased but the strength of the nanofiber web is weakened. On the other hand, when the volatilization of the solvent is low, the nanofiber web is melted.

The method of forming the porous nanofiber web 10 using the electrospinning apparatus of FIG. 10 is such that a polymer material having a low thermal conductivity is first solved, a mixture of a polymer material having a low thermal conductivity and a heat resistant polymer material is dissolved in a solvent, Prepare. In this case, a predetermined amount of inorganic particles may be added to the spinning solution to reinforce the heat resistance, if necessary. In addition, when a nanofiber web is formed using a polymer material having a low thermal conductivity and an excellent heat resistance, for example, polyurethane (PU), the heat insulating property and the heat resistance property are simultaneously obtained.

Thereafter, the spinning solution is directly radiated to the collector 6 using an electrospinning device or is radiated to a porous substrate 11 such as a nonwoven fabric to form a single-layer porous nanofiber web 10 or a porous nanofiber web 10, And a porous substrate (11).

Subsequently, when the obtained nanofiber web sheet has a wide width, it is cut to a desired width, and then it is folded in the form of a plate several times to have a desired thickness or wound in a plate shape by a winding machine, or a plurality of sheets for cores are cut A plurality of layers are stacked. In addition, after laminating in multiple layers, it can be cut into a desired shape.

It is preferable to increase the lamination density by hot or cold pressing a plurality of laminated nanofiber web sheets as necessary.

In the present invention, it is also possible to manufacture a nanofiber web sheet having a large area and then cut it into a predetermined shape according to the application to be used as a thermal insulation material for a building or a refrigerator.

On the other hand, in the present invention, when forming a nanofiber web, a spinning solution is spun onto a transfer sheet composed of a nonwoven fabric or a polyolefin-based film made of a polymer material that is not dissolved by a solvent contained in a spinning solution, After the web is formed, a nanofiber web sheet can be produced by laminating the nanofiber web with a nonwoven fabric while separating the nanofiber web from the transfer sheet, and the resulting sheet can be laminated in multiple layers. As the nanofiber web is produced using the transfer sheet described above, the productivity in the mass production process can be improved.

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is clearly understood that the same is by way of illustration and example only and is not to be construed as limited to the embodiments set forth herein. Various changes and modifications may be made by those skilled in the art.

100: Hybrid insulation sheet 120: Phase change material
151, 152: nanofiber web 170, 171, 172: support
300: vacuum insulation panel 310:

Claims (19)

First and second nanofiber webs that are integrated by a nanofiber composed of a polymer having a low thermal conductivity and have a fine pore structure and are hybridized; And
And a phase change material (PCM) interposed between the first and second nanofiber webs. The method of claim 1, wherein the nanofiber web is disposed on an outer circumferential surface of the phase change material to reduce the amount of heat transferred by blocking heat with the microporous structure and the nanofibers, Absorbing sheet. The hybrid thermal insulation sheet according to claim 1, further comprising a support compounded with at least one of the first nanofiber web and the second nanofiber web. The hybrid thermal insulation sheet according to claim 1, further comprising a support on which the nanofibers are directly radiated to form at least one of the first nanofiber web and the second nanofiber web. [2] The method of claim 1, further comprising: providing a first support having the first nanofiber web on one surface thereof and a third nanofiber web on the other surface thereof; And a second support body having the second nanofiber web formed on one surface thereof and the fourth nanofiber web formed on the other surface thereof, The hybrid thermal insulation sheet according to any one of claims 3 to 5, wherein the support is a nonwoven fabric or a woven fabric. The hybrid heat-insulating sheet according to claim 1, wherein the nanofibers are less than 1 [mu] m in diameter. The hybrid thermal insulation sheet according to claim 1, further comprising inorganic particles on the nanofibers. The method of claim 8, wherein the inorganic particles are _{SiO 2, SiON, Si 3 N} 4, HfO 2, ZrO 2, Al 2 O 3, TiO 2, Ta 2 O 5, MgO, Y 2 O 3, BaTiO 3, ZrSiO ₄ and HfO ₂ , or at least one particle selected from the group consisting of glass fibers, graphite, rock wool, clay, and the like. The hybrid thermal insulation sheet according to claim 8, wherein the inorganic particles are located inside the nanofiber, or are partially exposed on the surface of the nanofiber. Forming a first nanofiber web having a fine pore structure on a first support;
Forming a second nanofiber web having a fine pore structure on a second support; And
And hybridizing the first and second nanofiber webs with a phase change material interposed between the first and second nanofiber webs. ≪ RTI ID = 0.0 > 11. < / RTI > 12. The method of claim 11, wherein the first and second nanofibrous webs are formed by spinning a spinning solution containing a polymer material on each of the first and second supports. 12. The method of claim 11, wherein each of the first and second nanofibrous webs is formed by combining with each of the first and second supports. 12. The method of manufacturing a hybrid thermal insulation sheet according to claim 11, wherein the spinning solution further comprises fumed silica. A cover material having an inner space; And
And a hybrid heat insulating sheet disposed inside the sheath material to support the sheath material,
The hybrid heat-insulating sheet comprises:
First and second nanofiber webs that are integrated by a nanofiber composed of a polymer having a low thermal conductivity and have a fine pore structure and are hybridized; And
And a phase change material interposed between the first and second nanofiber webs. The heat insulating panel according to claim 15, wherein the nanofibers are made of a polymer having a thermal conductivity of less than 0.1 W / mK. The heat insulating panel according to claim 15, further comprising a support on which at least one of the first nanofiber web and the second nanofiber web is compounded or the nanofibers are radiated. 16. The thermal insulation panel according to claim 15, wherein the sheathing material is made of a metal material. 16. The heat insulating panel according to claim 15, wherein the inner space of the shell material is vacuum or reduced in pressure.

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