KR20140140835A - High-voltage substitution of fuel oil with nano device manufacturing method and apparatus for manufacturing - Google Patents

Abstract

Manufacturing alternative energy influences energy price. The alternative energy obtains manufacturing value if manufacturing more economical energy is the objective, and if the alternative energy manufactured in an era that prioritizes the environment is environment-friendly energy of enhanced calorific value. A method for manufacturing alternative fuel using a high-voltage nanodevice of the present invention selects nano technology in order to supplement a phenomenon in which the manufactured alternative energy is oil-water separated, thereby enhancing calorie of energy which will be manufactured, supplementing chromaticity and the oil-water separation phenomenon, and lowering manufacturing costs using waste oil at sea and waste oil. In other words, the present invention is the method for manufacturing complete alternative fuel comprising the steps of directly injecting mixed formulations from each waste oil at sea, a waste oil tank, a food waste water tank, and an inorganic salt composition tank into a steam boiler piping; nano converting by heating at 70-80°C and applying an electric current using an ultra high voltage (15000 V) leakage transformer to make ionic bond between nano converted microparticles, thereby making stable chemical bonds; and high-alpha condensation polymerizing the same in an emulsifier after re-agitation.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a high-voltage nano-

The present invention relates to a new type of alternative fuel production method which can enhance the economic efficiency of energy in a high energy cost era and drastically reduce environmental pollution caused by incomplete combustion with a large amount of energy consumption. When the time of existing product has been improved, the phenomenon of elimination of water separation is eliminated and a complete chemical bonding material is produced. Dilution of food waste wastewater is minimized by minimizing the environmental cost and further reducing the manufacturing cost, thereby improving the economical efficiency. In addition, through the nanoflower with high voltage, the impurities inherent in conventional waste oil, marine waste oil and PCB (transformer OT oil) are precipitated and the color of the product is increased. As all metal particles contained in waste oil and marine waste oil are nanoized, the calorific value is increased by itself. However, as the salt (Nacl) in the food wastewater is ionized to Na + + Cl-, the positive electrode of the high voltage nano- - chemically combined with AgCl to precipitate Cl-, so that the heating element, Na +, generates heat, raising the heat to produce good alternative energy, and the nanoparticles produce alternative energy that is not separated by adsorption and chemical bonding.

{High-voltage substitution of fuel oil with nano device manufacturing method and apparatus for manufacturing}

The present invention is based on the finding that the present invention has been successfully applied to a conventional fuel oil and its production method and its manufacturing apparatus in which the content of low sulfur and waste oil is 70%, the composition thereof is 30%, and the dilution method is competitive with competitive products such as natural gas in the conventional patent 1995-0005963 And the guarantee period of 40 days is defined as the guarantee period of the patent as referred to in claim 2, claim 3, claim 5 and claim 6 of the patent, since the possibility of oil separation is exemplified after that period, It is not necessary to explain how the heating value increases as referring to the heating value of the industrial fuel in the patented method 2003-0008372 "Method of producing alternative fuel oil using waste oil and waste cooking oil", and the composition ratio of BC oil, water and petroleum products This patent clearly differs from the present patent, and as in the case of the patent 1995-0005963, the guarantee period for the suspension and separation mentioned in claim 2, claim 3, claim 6, Since 2003, the technical patents have been needed to illustrate the possibility of oil segregation, and in particular, the above patents 2003-0008372 have shown that many manufacturers tried various methods from 2005 to 2010, Patent No. 10-2006-0116177 entitled " Apparatus for producing alternative fuel oil for industrial boiler and method for producing alternative oil for industrial boiler "is an additive petroleum product and a petroleum chemical product, and includes thinner, toluene, methyl alcohol, propylene, isopropyl alcohol , Petroleum products and petrochemical product tanks are referred to in claim 1, which is referred to as "Petroleum and Petroleum Alternative Fuel Business Act Enforcement Decree (June 15, 2007 revision) Article 5 (petroleum and petroleum products) Type of alternative fuels) 5 Oil-fired fuel oil: Because it was changed to manufacture by mixing petroleum product heavy oil with emulsifier, The patent of the present invention supplements the conventional technical problems and applies the developed nanotechnology to solve the problems of the existing calorific value and the color of the oil separation problem It is an improved patent.

The fact that oil-water separation phenomenon occurs over time in manufacturing an existing alternative fuel is meaningless as a substitute energy and is a matter of value as energy. It is like having a substance lose its original value over time does not have its original value. The present invention overcomes such limitations and solves the problem of an increase in the cost of producing alternative fuels due to an increase in energy prices and the problem of the calorific value of alternative fuels produced by the revision of the Enforcement Decree of the Petroleum and Petroleum Substitute Fuel Business Act (2007. 06. 15 revision) In particular, gives meaning to the environmental elements of the present invention.

The present invention combines with oil (marine waste oil, waste oil, BC oil, etc.) and water (food waste water, livestock wastewater, sea water leachate, etc.) to produce new oil. Water is a representative polar material and oil is a representative nonpolar material. In the natural state, water and oil are bound to each other in the direction of lowering the chemical energy between them, and they are in a safe state. Thus polarity combines polarity between non-polarity and non-polarity. Until now, the emulsified fuel has remained in a state of bonding for a certain period of time with the emulsifier and the like, but after a lapse of time, it has the inherent physical properties and thus has the energy to be restored to its original state. However, when an extra high voltage (15,000 V) is passed through silver (Ag), the particles become finer than 1 nm (1 / billion), and the particles are charged, and the impurities are precipitated, do. In addition, when the particles are nanoized, the smaller the particle size of the material, the higher the ratio of the surface atoms, the more thermodynamically the surface atoms have higher energy than the internal atoms and the lower the activation energy required for diffusion. . Therefore, a completely chemically bonded new material is produced without oil separation. The meaning of alternative fuels is that as energy prices rise, they have the need for alternative fuels. If energy prices are low, the need for alternative energy is less. Therefore, the economic value of manufacturing cost is the value of the alternative energy. The cost of alternative energy production proposed in this patent is 40% for diluted water (food wastewater, livestock wastewater, water, leachate, etc.), 5% for mineral composition, while using ocean waste oil, waste oil, The problem is that the content of sulfur (S) contained in the waste oil or marine waste oil is low, but this patent induces complete combustion when the produced alternative fuel is burned, The sulfur content passes through emission standards. The increase in calorific value is due to the fact that when the high-voltage discharge occurs, silver (Ag), which is a nanomaterial, reacts with salt (Nacl) contained in the food wastewater and binds to the digesting medium Cl- to form silver chloride (AgCl 2) This doubles the heating value. In other words, since Ag + 2NaCl → AgCl₂ ↓ + 2Na, the alternative fuels have a calorific value of 8,300 Kcal, but the alternative fuels produced by this technology form charges by nanoizing the metals and base metals contained in the waste oil, marine waste oil, (2Na) generated by the reaction between silver and salinity will further improve the calorific value, resulting in a calorific value of about 9,000Kcal to 9,500Kcal.

As described above, the present invention solves the problems of oil separation in the production of alternative fuels and solves the problem of calories, which is a disadvantage of alternative fuels. , That is, the mixing of food wastes wastewater has simultaneously pursued economical efficiency and environment due to the reduction of manufacturing cost due to the increase of food wastewater treatment cost. Food wastewater, livestock wastewater, which is problematic in the treatment of B-C oil, waste oil, marine waste oil, PCB (organic oil), etc. and prohibition of marine dumping. Leachate is used as a raw material, which has a large impact on the environment. The exhaust gas test results when burning this alternative fuel (2011, 06, 17) showed 20.8% moisture, 0.45% sulfur, 0.433 ash (sample made from livestock waste wastewater), 0.13 Cr, Pb, Cd ,: Less than 1%, As non-detected, suitable for environmental standards.

Fig. 1 shows an alternative fuel oil production apparatus model using a high-voltage nano-
Figure 2 shows the alternative fuel production sequence

Firstly, it is possible to use BC oil, various kinds of waste oil, marine waste oil, marine accidental waste oil, food wastes extraction plant, vegetable oil, and PCB (organic oil) which can be used as main raw material for the present invention, Considering the fact that marine waste oil and marine accidents are effluent waste oil, it is economical and environmentally friendly. Inputs can range from 70% to 55%, but 55% is the most economical. Second, the inorganic composition (NaCl, Mgcl2, Cacl2, Na2co3) can be mentioned, but the food waste wastewater is salty, so it can be procured without adding it. The composition is 1-50 parts by weight of NaCl, 10-70 parts by weight of MgCl2, 30-90 parts by weight of CaCl2, and 10-70 parts by weight of Na2CO3. Third, the use of food waste wastewater is most economical due to various wastewater, food waste wastewater, livestock waste wastewater, water, etc., and the input amount is 40% economical. Particularly, the reason for ion binding of food wastewater is that the salt in food wastewater and sodium L-glutamate [HOOC (CH2) 2CH (NH2) COONa] react with the inorganic composition (NaCl, MgCl2, Cacl2, Na2CO3) It is because it is crazy. In addition, since the heavy metals and non-metals in the wastewater are influenced by the combustion, the amount of heat can be significantly increased compared with the use of pure water (H2O). If the increase in food processing cost is added to the cost of manufacturing cost, Because. The above three factors are put into the boiler evaporation water of the steam boiler by the solenoid valve that sets the target amount, and when it is heated (70 ℃ ~ 80 ℃) and discharged into the high voltage nano tank with the first high voltage (15,000V) After the impurities contained in the wastewater were precipitated, the color was changed and the metal non-metal particles in the oil were nanoized and introduced into a vertical type stirrer. The mixture was stirred at 500 rpm to 1,000 rpm and passed through an emulsifier, The mixture is then atomized to induce complete chemical bonding to produce alternative fuels. When the high fatty acid ester oil particles and the metal and nonmetal particles are decomposed into nano-particles by ultrafiltration and the added inorganic composition (Na 2 CO 3, MgCl 2, Cacl2) and NaCl in food wastewater are nano-atomized to form primary ionic bonds. Particularly when the particles of the nanoized metal are burned, they are completely burned to increase the heat quantity and minimize the emission of harmful substances. In addition, silver (Ag), which is a nano-structured conductor during high-voltage discharge, binds to Cl-, which is nano-sized with Ag + to reduce heat, and precipitates as Agcl2. Especially, Ag + (silver nano) acts to decompose dioxin when burned. Since the relation of Ag + 2Nacl → Agcl₂ ↓ + 2Na, the calorific value of the alternative fuel produced without the special high voltage discharge system is 8,300Kcal, but the heating value of 2Na when the special high voltage discharge is generated and the metal and non- Because heat is doubled, calories of 9,200 Kcal to 9,500 Kcal are generated. In theory, the calorific value of B-C is 10,500 Kcal, but incomplete combustion occurs at 8,300 Kcal due to the boiler's functional conditions. The treatment apparatus of the present invention is characterized in that the treatment tank is provided with a valve for controlling and supplying the storage tank portion of the main raw material tank, the auxiliary raw material tank, the composition tank, and the raw material in the tank by time, the steam boiler for heating the supplied diluted solution, The standard facility is to install a + and - plate on both wall surfaces, install a leakage transformer to increase the voltage to 15,000V connected to each terminal, and connect it to the controller. The bottom of the high-voltage nano-tanks is installed so that both sides are inclined by 10 ° to 15 °, and the precipitator collectors are installed to be rotated and discharged out of the screw type. The agitator is installed with 5 ~ 7 layer vertical rotating blades with 3 ~ 5 wings per layer, so that they can be agitated from top to bottom. The emulsifying device allows the treatment mixture to flow into the screw-type friction emulsification device and effectively emulsify. In this screw-type friction device, a screw shaft of the emulsification device is rotated by a shaft rotation by a motor, and a gear for adjusting a friction distance, that is, a friction distance adjusting gear is set near the shaft, The mixture of the treatment mixed liquid is more effectively performed and at the same time the emulsification treatment is performed to prevent the water separation. That is, a paper forming portion is formed at the end of the screw shaft. In this paper forming part, the treatment mixed liquid passes through the micro park plate and flows into the alternative fuel oil tank while performing the friction action. If the treatment mixture is not easily emulsified by the naked eye determination, the adjustment gear is adjusted to advance the screw shaft toward the fine park plate to further narrow the gap at the paper forming portion at the end of the screw shaft, To pass through the micro park plate. This fine park plate filters the treated mixed liquor and at the same time relaxes the traveling speed due to friction and flows into the alternative fuel oil tank. This emulsification apparatus is equipped with a minute park plate having a number of micropores at a distance from the paper forming unit at the end of the screw shaft and constitutes an outflow port of an oil-filled alternative fuel oil, And then flows into the alternative fuel oil tank. It is preferable that the emulsifying device is inclined toward the fine pore disk and that a supporting stand is provided below both ends of the screw shaft container. A motor is installed on one side of the support so that the screw shaft is rotated by the shaft.

The fuel type of the alternative fuel obtained by the treatment apparatus according to the present invention is water in oil (W / O). That is, water has a dispersed phase, oil has a continuous phase and small water droplets are dispersed in oil, but the shape of the water dispersion is finer, the continuous phase of the oil is narrower than the shape of the patent 1995-0005963, And the water separation is not performed. The reason why the dispersion phase and the continuous phase are in equilibrium is that the equilibrium of the force between the molecules of the oil and the water is maintained and the equilibrium of the force between the water molecule and the oil molecule is further differentiated by the nano- So that a stable coupling can be achieved. The inorganic salt composition solution (Na2CO3, MgCl2, NaCl, CaCl2) used in the present invention is basic, and high fatty acid esters are present in waste oil, marine waste oil, waste cooking oil and the like, Wastewater) reacts with the high voltage ionized inorganic salt composition to become ionic bonds. In addition, a high-speed rotation (500 rpm - 1000 rpm) is carried out in a vertical stirrer to produce an alkali metal salt, thereby exhibiting its function as an emulsifier. The water and the salt remain in the ion-bonded state and the water separation does not occur. One component Na2CO3 of the inorganic salt composition solution reacts with water to generate NaOH in the aqueous solution state.

Na2CO3 + 2H2O - > 2NaOH + H2CO3

Since the alkaline earth metal chlorides MgCl2 and CaCl2 become basic in the aqueous solution state, the following reaction formula is performed in an aqueous solution state.

2NaOH + MgCl2? Mg (OH) 2 + 2NaCl

2NaOH + CaCl2? Ca (OH) 2 + 2NaCl

In this reaction, in MgCl 2 and CaCl 2,

2Na2CO2 + MgCl2 + CaCl2 = MgCO3 + CaCO3 + 4 NaCl

The waste oil and waste oil and waste cooking oil in the chloride are rotated at a temperature of from 80 to 90 ° C at a speed of 500 to 1000 rpm to hydrolyze the components of the higher fatty acid ester in the waste oil or waste cooking oil to produce a higher fatty acid sodium salt In other words,

(Wherein R, R 'and R' are each an advanced alkyl group).

The higher fatty acid sodium salt produced in the above reaction exerts its function as an emulsifier and nano-forms food waste wastewater, waste oil and waste edible oil with high specific voltage (over 10,000V) while emulsifying, It is 1000 times smaller than 4μ, and it is made into micro-fine particles. In other words, when the particles are nano-sized,

The self-occupying ratio is increased because the atoms constituting the surface are higher in energy than the atoms inside, and have a tendency to keep the emulsified state because the thermal expansion coefficient is large and the activation energy is low. Therefore, the alternative energy that is nanoized becomes a material that forms a complete chemical bond without oil separation.

Alternative fuel for marine waste oil and B-C oil

Marine waste oil is oil mixed with seawater but it is a preferable manufacturing method because it is possible to procure marine waste oil because the cost is low and the manufacturing cost is low. That is, in FIG. 1, 55% of the marine waste oil and BC oil (1), 40% of the food waste water (2) and 5% of the inorganic substance liquid (3) are sent to the boiler evaporation water through the 1a, 2a, Lt; RTI ID = 0.0 > 70 C < / RTI &

After sending it to the special high-voltage nano-tanks (5), the switch was opened in the transformer (6) and energized for 15 minutes at 15,000V for 3 minutes. After the settling time (2 minutes) 8), and the precipitate is discharged using a screw-type discharger (7). The alternative fuel sent to the agitator (8) is sent to the emulsifier (10) through the high-speed agitation process (500 rpm to 1000 rpm) to produce an alternative fuel And is stored in the storage tank 12 through the pipe 11. If alternative fuel made through this process is an alternative fuel

Alternative fuel of vegetable oil extracted from food wastes

When food waste is collected and put into water and heated to 70 ° C ~ 80 ° C, when animal oil and vegetable oil floats on the water, it is collected to prepare alternative fuel

In Fig. 2, the replacement oil produced in Example 1 is placed in the main tank 1, the vegetable oil collected in the tank 2 is added to the inorganic salt composition tank 3, (48%), vegetable oil (48%) and inorganic salt composition (4%) were flowed into the steam boiler pipe, and then the boiler (4) was heated to 70 ° C to 80 ° C to produce a high-voltage nano- 5), and then the transformer 6 is turned on to conduct the nanofabrication. That is, a voltage of 15,000 V is generated for 3 minutes in the leakage transformer 6, so that both of the metal silver (Ag) and the metal base metal inside the substitute fuel are nanoized to increase the heat quantity, so that the impurities are precipitated and removed by the precipitate remover 7 And the ionized alternate fuel is rapidly moved to the vertical agitator 8 to form ionic bonds between the particles. The number of revolutions of the stirring wing of the agitator is maintained at 500 rpm to 1000 rpm, and the agitating process starting from the top is completed when it reaches the bottom. After the agglomeration, the alternative fuel is sent to the emulsifier 10 to undergo a high-alpha condensation process to further enhance the surface of the ionic bond of water in oil (W / O) by secondary chemical ion bonding The water separation does not occur. After completing the high-alpha condensation process in the high-alpha condenser (10), the alternative fuel is stored in the alternative fuel storage tank through the pipe.

Alternative fueling of effluent spilled oil from sea and production of hydrogen using the fuel

Especially, since the oil spilled on the sea due to shipwreck or marine accidents is floated on the sea due to specific gravity as well as marine waste oil, it can be sucked by a high-pressure vacuum inhaler and then used to collect alternative fuels. Since seawater contains a lot of electrolytes (Nacl, Mgcl2, Cacl2, K, etc.), it creates an alternative fuel by ion-binding (chemically bonding) oil and seawater and turns the steam turbine to generate electricity. Electrolysis of seawater produces a large amount of natural hydrogen (H2), which is a valuable environmental business since it produces waste water that will pollute the ocean and produce alternative energy and hydrogen (H2). It is best to produce alternative fuels and hydrogen by removing the oil that has been spilled by the above method because the emulsifier is sprayed on the oil continuously spilled in the harbor, The environmental burden of removing oil from a sea accident is 20 times higher than the price of oil, which is very economical and environmentally friendly. Since the oil spilled on the sea floats on the surface due to the specific gravity of water and oil, the floating oil is collected by a high-pressure vacuum inhaler, and is put into the main material tank 1 of FIG. 2 and the marine waste oil is put into the material tank 2, (MgCl2, CaCL2, Na2CO3) was placed in the composition tank 3 and then the solenoid valve was operated to constitute 70% of marine effluent waste oil, 28% of marine waste oil and 2% (4) It is sent to the evaporation water piping line and heated to 70 ℃ ~ 80 ℃. Then, it flows into the special high voltage nano-tank (5) and then the leakage transformer (6) is discharged and discharged at 15,000V for 3 minutes. The impurities in the marine effluent are precipitated, and the contained metals and nonmetals are ionized into the nano state and chemical bonding takes place. The impurities are discharged to the screw type precipitator discharger 7 and the nanoized alternative fuel is sent to the vertical type agitator 8 and then sent to the emulsifier 10 for secondary alkaline ionization And stored in an alternative fuel storage tank (12). Then, the turbine is rotated by the fuel to produce electric power, and then hydrogen is ion-decomposed by the electric power to obtain hydrogen.

1. Main material storage tank
2. Part storage tank
3. Inorganic salt composition storage tank
1a, 2a, 3a solenoid valve
4. Steam Boiler
5. Special high voltage nano
5a, 5b. Silver plate
6. Leakage transformer
7. Screw-type sediment discharger
10. Emulsifier (High-alpha Synthesizer)
11. Alternative energy storage tank

Claims (6)

In order to improve impurity precipitation and colorimetry such as waste oil and wastewater, and to install a special high-voltage nano-tanks for inducing silver nano-ion bonding, silver (Ag) and other (copper, aluminum, Metal plate), and the terminal is attached with special parts made of silver plate or other plate or syringe. Installation The transformer can be installed in various ways such as 1000V ~ 5000V, 5000V ~ 10000V, 10000V ~ 15000V depending on the products manufactured and the power supply time is 1 minute, 3 minutes, 5 minutes, 10 minutes, 15 minutes, 20 minutes etc. How to use and installation structure In the special high voltage (15000V) nanotube, the silver plate is attached to the + terminal,
(Ag + 2Nacl → Agcl₂ ↓ + 2Na) which binds to the salt (Nacl) contained in food wastewater of substitute fuel and precipitates Agcl to obtain 2Na, 30% to 43% inorganic salt composition (Nacl 1 - 50 parts by weight, MgCl 2 (water)) 55% to 70% of the main ingredients (BC oil, marine waste oil, waste oil, PCB 10 to 70 parts by weight, Cacl 2 30 to 90 parts by weight, Na 2 CO 3 10 to 70 parts by weight), 1% to 10% As in Example 2, food waste is collected and heated to 70 ° C to 80 ° C in the water. When animal oil and vegetable oil are floated on water, they are collected to produce alternative fuel. That is, the alternative fuel oil produced in the main material tank is 48 % Of vegetable oil, 48% of vegetable oil, 4% of inorganic salt composition in inorganic salt composition tank, and the composition As in Example 3, a method of producing alternative energy by constructing 70% of marine effluent waste oil, 28% of marine waste oil, and 2% of non-waste salt composition as a main material, and a method of operating a steam turbine How to produce hydrogen by electrolysis of seawater with electricity  The main material storage tank for storing the oil, the material storage tank for storing the wastewater, and the tank for storing the inorganic salt composition, are directly supplied to the steam pipes of the steam boiler and heated to 70 ° C to 80 ° C This is a method of mixing, which is heated 10 times faster than the existing boiler,

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