KR20140120288A - Flim manufacturing method added moram component - Google Patents

Flim manufacturing method added moram component Download PDF

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KR20140120288A
KR20140120288A KR1020140110616A KR20140110616A KR20140120288A KR 20140120288 A KR20140120288 A KR 20140120288A KR 1020140110616 A KR1020140110616 A KR 1020140110616A KR 20140110616 A KR20140110616 A KR 20140110616A KR 20140120288 A KR20140120288 A KR 20140120288A
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polyethylene resin
film
heater
powder
resin
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KR1020140110616A
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Korean (ko)
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유한춘
윤병선
위안진
오찬진
박병건
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전라남도
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D7/00Producing flat articles, e.g. films or sheets
    • B29D7/01Films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/346Clay
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2397/00Characterised by the use of lignin-containing materials
    • C08J2397/02Lignocellulosic material, e.g. wood, straw or bagasse
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04Homopolymers or copolymers of ethene
    • C08J2423/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0806Silver
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/066LDPE (radical process)

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Thermal Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)

Abstract

The present invention relates to a method for manufacturing a film having antibacterial and oxygen permeation preventing functions by adding a ficus nipponica component. The present invention manufactures a film by melting ficus nipponica powder with a heater, adding an additive agent having odor preventing and volatile functions to polyethylene resin, and then heating it with the heater. Accordingly, the film has an antibacterial function because of the antibacterial function of ficus nipponica as a natural ingredient. In case of using the film as a packing material for fresh food, the present invention can obtain an antibacteria effect and the prevention of oxygen permeability to prevent microorganisms generated from fresh food in long-term storage, can increase the storability of the fresh food by maintaining the high freshness of the fresh food, and can fundamentally prevent odor occurred from the fresh food.

Description

모람성분이 첨가되어 항균 및 산소투과억제 기능을 갖는 필름제조방법{Flim manufacturing method added moram component}[0001] The present invention relates to a method for producing a film having an antimicrobial and oxygen permeation inhibiting function,

본 발명은 모람성분이 첨가되어 항균 및 산소투과억제 기능을 갖는 필름제조방법에 관한 것으로서, 더욱 상세하게는, 분말화된 모람을 가열기로 용융되고 구취억제 및 휘산작용을 갖는 첨가제가 첨가된 폴리에틸렌수지에 첨가하여 가열기로 가열하여 필름을 제조하여 필름에 천연성분의 모람이 갖는 항균작용으로 인해 필름에 항균작용 및 산소투과도 억제를 갖도록하여 상기 필름을 신선식품을 포장재로 사용시 신선식품에서 장기간 보관시 발생되는 미생물을 억제시키도록 항균성을 확보하여 신선식품의 신선도를 높게 유지하여 신선식품의 저장성을 높이고, 신선식품에서 구취가 발생하는 것을 원천적으로 예방하도록 한 모람성분이 첨가되어 항균 및 산소투과억제 기능을 갖는 필름제조방법에 관한 것이다.The present invention relates to a method for producing a film having an antimicrobial and oxygen permeation inhibiting function by the addition of a morom component, and more particularly, And the film is made to be heated by a heater to have antimicrobial action and oxygen permeation inhibition on the film due to the antimicrobial action of the natural ingredient, and thus the film is used when the fresh food is used as a packaging material, This is because it has antibacterial and oxygen permeation suppression function by adding antimicrobial ingredient to prevent the generation of bad breath in fresh food. The present invention relates to a film production method.

주지하는 바와 같이, 소비자들에게 전달되기까지 몇 단계의 저장 및 유동과정을 거치는 식품들의 상품가치는 신선도에 따라 크게 좌우되는데, 이들의 신선도유지에 가장중요한 역할을 하는 것은 무엇보다도 포장자재(필름)의 기능이라고 볼수 있다.As well known, the commercial value of foods that undergo several stages of storage and flow until they are delivered to consumers is largely dependent on the freshness. The most important factor in maintaining these freshnesses is the packaging material (film) It is a function of.

포장자재(필름)는 내용물을 물리적 충격으로부터 보호해주는 역할을 할뿐만 아니라 수분, 산소, 미생물 등과 같이 신선도에 나쁜영향을 주는 요소들을 제거하거나 이들이 외부로부터 침투하는 것을 막아준다.Packing material (film) not only protects the contents from physical impact, but also removes elements that adversely affect freshness such as moisture, oxygen and microorganisms, or prevents them from penetrating from the outside.

포장된 식품은 비포장 식품과는 다른 분위기에 놓이게 된다. 대기중에는 노출된 식품은 공기와 미생물들과 항상 접촉하고 있는 반면, 포장된 식품은 포장내부의 특수한 기체조성과 깨끗한 환경에 놓이게 되어, 비록 온도가 좀높아서 상온부근에 이르더라도 쉽게 변질되지 않고 교정된 분위기MA(Modified Atmosphere)에 있게 된다. MA포장에 쓰이는 포장필름은 미생물의 발현과 숙성이 멈추도록 하는 기능을 갖추어야 화학적 변질이 방지된다.Packaged foods are placed in a different atmosphere from unpackaged foods. The exposed food is always in contact with air and microorganisms in the atmosphere, while the packaged food is placed in a special atmosphere and clean environment inside the package, so that even if the temperature is high, MA (Modified Atmosphere). Packaging films used for MA packaging must have the function of stopping the development and aging of microorganisms to prevent chemical alteration.

최근들어 선도유지를 위해 다양한 기능성 재료를 조합하여 흡수, 가스조절, 습도조절, 항균효과 등의 기능을 가진 포장자재가 개발되어 사용되고 있다.In recent years, packaging materials having functions such as absorption, gas control, humidity control, and antimicrobial effect have been developed and used by combining various functional materials in order to maintain the lead.

이러한 포장자재의 소재로서는 유리, 종이, 나무, 금속, 합성수지재 등이 있는데 이중에서 합성수지재가 가격이 비교적 저렴하면서도 여러가지 형태의 포장자재로 가공하기 용이할 뿐만 아니라 투명하고 가벼운 장점이 있다.Among these materials, glass, paper, wood, metal, and synthetic resin are used as materials of the packaging material. Among them, the synthetic resin material is advantageous in transparency and lightness as well as being relatively easy to process with various types of packaging material.

그러나 합성수지재로 제조된 포장자재는 포장되는 신선품을 포장만하여 신선품의 외형유지와 신선식품을 포장재로 포장하여 디스플레이할때 보기 좋게만 사용할 수 있을뿐, 장기간 포장자재에 신선식품을 보관시 보장자재에는 미생물의 활동을 억제하는 기능이 포함되어 있지 않아서, 상기 신선식품에 미생물이 활성화되어 신선식품이 부폐하여 장기간 보관시키지 못하는 문제점이 있었다.However, the packaging material made of synthetic resin material can be used only when it is packed and fresh, and it is only used when it is packaged and displayed. The material does not contain the function of inhibiting the activity of the microorganism, so that the microorganism is activated in the fresh food, and the fresh food is deteriorated, so that it can not be stored for a long time.

상기와 같은 문제점을 해결하기 위해서, 본 발명은 분말화된 모람을 가열기로 용융되고 구취억제 및 휘산작용을 갖는 첨가제가 첨가된 폴리에틸렌수지에 첨가하여 가열기로 가열하여 필름을 제조하여 필름에 천연성분의 모람이 갖는 항균작용으로 인해 필름에 항균작용을 갖도록하여 상기 필름을 신선식품을 포장재로 사용시 신선식품에서 장기간 보관시 발생되는 미생물을 억제시키도록 항균성 및 산소투과도 억제를 확보하여 신선식품의 신선도를 높게 유지하여 신선식품의 저장성을 높이고, 신선식품에서 구취가 발생하는 것을 원천적으로 예방하도록 한 새로운 모람성분이 첨가되어 항균 및 산소투과억제 기능을 갖는 필름제조방법을 제공하는데 그 목적이 있다.In order to solve the above-mentioned problems, the present invention relates to a method for producing a film, which comprises melting powdered morom by a heater, adding it to a polyethylene resin to which an additive having an anti- The antimicrobial action of the honey has the antibacterial effect on the film, so that when the fresh food is used as a packaging material, the antimicrobial activity and the oxygen permeability are suppressed so as to suppress the microorganisms generated in the fresh food for a long time, The present invention also provides a method for producing a film having antimicrobial and oxygen permeation inhibiting function by adding a novel moromic ingredient to prevent the occurrence of bad breath in fresh food.

이와 같은 목적을 달성하기 위해서, 본 발명의 필름제조방법은 모람의 잎과, 줄기와, 열매를 채취하여 세척하여 상온에서 건조시키고, 건조된 상기 모람의 잎, 줄기, 열매를 분쇄기로 분쇄하여 모람을 분말화하는 모람을 건조 및 분말화하는 단계(S100)와; 폴리에틸렌(Polyethylene)수지를 가열기로 용용하는 단계(S200)와; 용융된 상기 폴리에틸렌(Polyethylene)수지 용액에 구취억제 및 휘산작용을 위해 멘톨 또는 페파민트인 첨가제를 첨가하여 가열기로 가열하되, 상기 가열기로 가열하는 온도를 145 내지 155℃를 유지하여 가열시키는 폴리에틸렌(Polyethylene)수지 용액에 첨가제를 첨가하고 가열기로 용융하는 단계(S300)와; 상기 첨가제가 첨가되어 용융된 폴리에틸렌(Polyethylene)수지 21 내지 29kg에 분말화된 모람 90 내지 110g을 투입하여 혼합하고, 가열기로 가열하되, 상기 가열기로 가열하는 온도를 145 내지 155℃를 유지하여 가열시키면서 폴리에틸렌(Polyethylene)수지와 모람분말을 가열기로 용융혼합하는 단계(S400)를 포함하여 필름을 제조하는 것을 특징으로 한다.In order to achieve the above object, the film production method of the present invention is characterized in that leaf, stem, and fruit of mamam are picked, washed, dried at room temperature, and the dried leaf, stem and fruit of the mamam are crushed by a crusher, (S100) drying and pulverizing the moras that are pulverized; A step (S200) of melting a polyethylene resin with a heater; A polyethylene resin is added to the melted polyethylene resin solution to add menthol or peppermint additive for halophilic inhibition and volatilization to the melted polyethylene resin and heated at a temperature of 145 to 155 DEG C by heating with a heater, Adding the additive to the resin solution and melting the mixture with a heater (S300); 90 to 110 g of powdered mosques were added to 21 to 29 kg of the melted polyethylene resin with the additive added thereto and mixed. The mixture was heated by a heater, heated at 145 to 155 ° C by heating with the heater And a step (S400) of melt-mixing the polyethylene resin and the moth powder with a heating machine (S400).

또한, 상기 모람분말이외에 첨가제가 첨가되어 용융된 폴리에틸렌(Polyethylene)수지에 나노화된 백토분말 또는 나노화된 황토분말을 더 첨가하는 것을 특징으로 한다.In addition to the above-mentioned moth powder, an additive is added to the molten polyethylene resin to further add nano-clay or nano-clay loess powder.

또한, 상기 모람분말, 나노화된 백토분말 , 나노화된 황토분말이외에 은나노를 더 첨가하는 것을 특징으로 한다.Further, the present invention is characterized by further adding nano silver in addition to the above-mentioned moth powder, nanotized white clay powder, and nanotized yellow loess powder.

또한, 상기 폴리에틸렌(Polyethylene)수지는 저밀도 폴리에틸렌(Lower Density Polyethylene:LDEP)수지인 것을 특징으로 한다.In addition, the polyethylene resin is a low density polyethylene (LDEP) resin.

본 발명은 분말화된 모람을 가열기로 용융되고 구취억제 및 휘산작용을 갖는 첨가제가 첨가된 폴리에틸렌수지에 첨가하여 가열기로 가열하여 필름을 제조하여 필름에 천연성분의 모람이 갖는 항균작용으로 인해 필름에 항균작용 및 산소투과도 억제를 갖도록하여 상기 필름을 신선식품을 포장재로 사용시 신선식품에서 장기간 보관시 발생되는 미생물을 억제시키도록 항균성을 확보하여 신선식품의 신선도를 높게 유지하여 신선식품의 저장성을 높이고, 신선식품에서 구취가 발생하는 것을 원천적으로 예방하는 효과가 있다.The present invention relates to a method for producing a film by adding powdered morom to a polyethylene resin which is melted by a heater and added to a polyethylene resin to which an additive having odor suppression and vaporizing action is added and heated by a heater to produce a film, Antimicrobial activity and inhibition of oxygen permeability. Thus, when the film is used as a packaging material for fresh foods, antimicrobial properties are secured so as to inhibit microorganisms generated during storage for a long time in fresh foods, thereby maintaining freshness of fresh foods, It is effective to prevent the occurrence of bad breath in fresh foods.

또한, 본 발명의 모람성분이외 나노화된 백토분말, 나노화된 황토분말, 은나노등을 더 첨가하여 필름제조하여 상기 필름에 항균작용을 더 높이는 효과가 있다.In addition, there is an effect of further enhancing the antimicrobial activity of the film by further adding a nanotubular clay powder, nanoized loess powder, silver nano, etc., in addition to the motam component of the present invention.

도 1은 본 발명에 따른 제조방법의 개략도.
도 2는 본 발명에 따른 시험성적서.
BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a schematic view of a manufacturing method according to the present invention;
2 is a test report according to the present invention.

본 발명을 충분히 이해하기 위해서 본 발명의 바람직한 실시예를 첨부 도면을 참조하여 설명한다.For a better understanding of the present invention, a preferred embodiment of the present invention will be described with reference to the accompanying drawings.

본 발명의 실시예는 여러가지 형태로 변형될 수 있으며, 본 발명의 범위가 아래에서 상세히 설명하는 실시예로 한정되는 것으로 해석되어서는 안된다. 본 실시예는 당업계에서 평균적인 지식을 가진 자에게 본 발명을 보다 안전하게 설명하기 위하여 제공되는 것이다.The embodiments of the present invention may be modified in various forms, and the scope of the present invention should not be construed as being limited to the embodiments described in detail below. The present embodiments are provided to explain the present invention more safely to those having ordinary skill in the art.

따라서 도면에서의 요소의 형상 등은 보다 명확한 설명을 강조하기 위해서 과장되어 표현될 수 있다. 각 도면에서 동일한 부재는 동일한 참조부호로 도시한 경우가 있음을 유의하여야 한다.Therefore, the shapes and the like of the elements in the drawings can be exaggeratedly expressed to emphasize a clearer description. It should be noted that in the drawings, the same members are denoted by the same reference numerals.

또한, 본 발명의 요지를 불필요하게 흐릴 수 있다고 판단되는 공지 기능 및 구성에 대한 상세한 기술은 생략된다.Further, detailed descriptions of well-known functions and configurations that may be unnecessarily obscured by the gist of the present invention are omitted.

도 1은 본 발명에 따른 제조방법의 개략도이고, 도 2는 본 발명에 따른 시험성적서이다.Fig. 1 is a schematic view of a manufacturing method according to the present invention, and Fig. 2 is a test report according to the present invention.

발명에 따른 모람성분이 첨가되어 항균 및 산소투과억제기능을 갖는 필름제조방법은 도 1 및 도 2에 도시된 것을 참조하여 실시예를 들어 설명하면 다음과 같다.A method for producing a film having antibacterial and oxygen permeation inhibiting function by adding a honeycomb component according to the present invention will be described with reference to examples shown in FIGS. 1 and 2 as follows.

모람{Ficus nipponica}은 한국자생식물로서, 뽕나무과의 식물로 잎은 두껍고 타원형이며 광택이 나는 표면과 흰빛이 도는 뒷면을 가지고 있다.Monarch {Ficus nipponica} is a native Korean plant, a plant of the mulberry family, whose leaves are thick, elliptical, shiny and has a white back.

이러한 모람의 열매는 약 1cm의 직경을 가지며 초록색으로 완숙시 보랏빛을 띠게 된다.The fruit of this mosque has a diameter of about 1cm and becomes green when it ripens to purple.

민간에 알려진 바로는 잎,열매,수피 및 근피를 해독, 하열, 야뇨, 당뇨병, 편도선, 간장에 좋은 효능을 가지면 살충제로서 사용하기도 한다.Known to the public as leaves, berries, bark, and peaches, it can also be used as an insecticide if it has good potency in detoxification, low fever, nocturia, diabetes, tonsils, and liver.

또한, 모람에는 황산화작용 및 항균성을 갖는 황산화물질 및 항균물질이 포함되어 있다.In addition, the motam contains sulfated and antimicrobial substances having sulfation and antibacterial properties.

[실시예] [Example]

[모람을 건조 및 분말화하는 단계: S100][Step of drying and pulverizing phosphorus: S100]

모람의 잎과, 줄기와, 열매를 채취하여 준다.Leaves of leaves, stem, and fruit are picked.

상기 모람의 잎과 줄기는 봄에 채취하고, 상기 열매는 늦여름에서 초가을까지 채취하여 주는 것이 바람직하다.The leaves and stems of the moth are collected in spring, and the fruits are preferably collected from late summer to early autumn.

이와 같이 채된 상기 모람의 잎과, 줄기와, 열매를 세척하여 준다.The leaf, stem, and fruit of the above-mentioned motam are washed.

이러하게 세척된 상기 모람의 잎과, 줄기와, 열매를 상온에서 건조시켜준다.The leaves, stems, and fruits of the above-mentioned mamma washed are dried at room temperature.

잘 건조된 상기 모람의 잎, 줄기, 열매를 분쇄기로 분쇄하여 준다. The leaves, stems, and fruits of the well-dried moth are pulverized with a pulverizer.

상기 모람의 잎, 줄기, 열매의 분말은 고운분말로 구성되는 것이 바람직하다.It is preferable that the leaves, stems, and fruits of the moths are composed of fine powder.

[폴리에틸렌(Polyethylene)수지를 용용하는 단계: S200][Solubility of polyethylene resin: S200]

폴리에틸렌(Polyethylene)수지를 가열기로 용용하여준다.Polyethylene resin is melted with a heater.

상기 폴리에틸렌(Polyethylene)수지는 저밀도 폴리에틸렌(Lower Density Polyethylene:LDEP)수지로 구성되는 것이 바람직하다.The polyethylene resin is preferably composed of a low density polyethylene (LDEP) resin.

[폴리에틸렌(Polyethylene)수지용액에 첨가제를 첨가하고 가열기로 용융하는 단계: S300][Step of adding an additive to a polyethylene resin solution and melting with a heater: S300]

용융된 상기 폴리에틸렌(Polyethylene)수지 용액에 구취억제 및 휘산작용을 위해 멘톨 또는 페파민트인 첨가제를 첨가하여 준다.Menthol or a peppermint additive is added to the melted polyethylene resin solution for halitosis inhibition and volatilization.

그리고 첨가제가 첨된 상기 폴리에틸렌(Polyethylene)수지 용액을 가열기로 가열하되, 상기 가열기로 가열하는 온도를 145 내지 155℃를 유지하여 가열시켜준다.Then, the polyethylene resin solution to which the additive has been added is heated by a heater, and the temperature of heating by the heater is maintained at 145 to 155 占 폚.

상기 첨가제인 멘톨 또는 페파민트를 첨가하여 모람분말과 함께 필름제조되어 상기 필름으로 신선제품을 보관시, 상기 신선제품에서 냄새가 나는 것을 원천봉쇄하여 항상 신선한 냄새인 멘톨 및 페파민트향을 발생시켜, 신선식품을 보다 더 신선감을 느끼도록 하기 위함이다.When menthol or peppermint, which is an additive, is added to produce a film together with moras powder, when the fresh product is stored in the film, the smell from the fresh product is blocked by source, thereby always generating fresh smell of menthol and peppermint flavor, So that a more fresh feeling can be felt.

[폴리에틸렌(Polyethylene)수지와 모람분말을 가열기로 용융혼합단계: S400][Melt mixing step of polyethylene resin and moth powder with a heater: S400]

용융된 폴리에틸렌(Polyethylene)수지에 분말화된 모람을 투입하여준다.Powdered moras are added to molten polyethylene resin.

또한, 용융된 상기 폴리에틸렌(Polyethylene)수지 21 내지 29kg에 상기 모람 분말 90 내지 110g을 계량기로 계량하여 투입혼합하는 것이 바람직하다.It is also preferable to weigh 90 to 110 g of the above-mentioned morom powder with 21 to 29 kg of the molten polyethylene resin by metering using a mortar.

그리고 폴리에틸렌(Polyethylene)수지에 분말화된 모람을 혼합기로 혼합하여준다.Then, powdered morom mixed with polyethylene resin is mixed with a mixer.

이러하기 혼합되는 폴리에틸렌(Polyethylene)수지에 분말화된 모람에 가열기로 가열시켜 혼합하여 주는 것이 바람직하다.It is preferable to mix the powdered phosphorus with the polyethylene resin to be mixed by heating with a heater.

또한, 용융된 상기 폴리에틸렌(Polyethylene)수지에 상기 모람분말을 혼합하여 가열기로 가열하는 온도는 145 내지 155℃로 유지하는 것이 바람직하다.In addition, it is preferable that the temperature for mixing the molten powder with the melted polyethylene resin and heating it with a heater is maintained at 145 to 155 ° C.

이러한 상기 폴리에틸렌(Polyethylene)수지는 저밀도 폴리에틸렌(Lower Density Polyethylene:LDEP)수지인것이 바람직하다.The polyethylene resin is preferably a low density polyethylene (LDEP) resin.

[실험예][Experimental Example]

상기와 같이 제조되는 모람이 첨가된 필름은 용융된 상기 저밀도 폴리에틸렌수지 25kg에 모람분말 100g을 가열혼합하면서 150℃에서 두께 40㎛, 폭 45cm의 필름상으로 압출하여 제조하였다.The film to which the moras were added was prepared by extruding 100 g of moras powder into 25 kg of the molten low density polyethylene resin while heating and mixing at 150 캜 into a film having a thickness of 40 탆 and a width of 45 cm.

상기 필름과 대조하기 위해, 대조군 필름을 저밀도 폴리에틸렌수지를 두께 40㎛, 폭 45cm의 필름상으로 압출하여 제조하였다.In order to check with the film, a control film was prepared by extruding a low-density polyethylene resin into a film having a thickness of 40 m and a width of 45 cm.

상기와 같은 본 발명의 필름과 대조군 필름에 대해 산소투과도와 항균성을 아래와 같이 실험하였다.The oxygen permeability and antimicrobial activity of the film of the present invention and the control film were tested as follows.

[산소투과도의 실험예][Experimental Example of Oxygen Permeability]

도 2의 시험성적서에 나타난 바와 같이, 본 발명의 필름과 대조군 필름에 대한 산소투과도는 산소투과측정기(Gas Transmission Rate Model BT-3, Toyoseki Co,. Japan)로 3회 반복하였으며 상대습도 0%로 유지시킨후, 23℃에서 시험하였다.As shown in the test report of FIG. 2, the oxygen permeability of the film of the present invention and the control film was repeated three times with an oxygen permeation meter (Gas Transmission Rate Model BT-3, Toyoseki Co, Japan) Held at 23 < 0 > C.

상압부 계기압력은 138 kPa으로 고정하였고, 산소의 유입속도는 20 cc/min를 유지하였다, 투과된 산소의 운반기체로서는 질소를 사용하였다.The pressure of the atmospheric pressure gauge was fixed at 138 kPa, and the flow rate of oxygen was maintained at 20 cc / min. As the carrier gas of the permeated oxygen, nitrogen was used.

아래 표1의 시험성적서에 나타난 바와 같이, 대조군 필름에 대한 산소투과는 약 4,200 cc/day˚㎡로 나타났다. As shown in the test report of Table 1 below, the oxygen permeability for the control film was about 4,200 cc / day 占 퐉 2.

본 발명의 필름에 대한 산소투과도는 약 4,000 cc/day˚㎡로 나타났다.The oxygen permeability of the film of the present invention was found to be about 4,000 cc / day 占 m2.

이와 같이 모람을 첨가된 본 발명의 필름은 약 5%정도 산소투과 억제효과를 볼수가 있다.As described above, the film of the present invention to which morom is added has an oxygen permeation inhibiting effect of about 5%.

모람의 경우에 첨가량을 늘려 필름을 제조시 보다 높은 산소투과 억제효과를 기대할 수 있다.In the case of morem, the addition amount can be increased, and a higher oxygen permeation inhibiting effect can be expected in producing the film.

따라서, 이러한 본 발명의 필름을 포장재로 사용시 상기 포장재에 포장되는 신선식품의 산소투과를 포장재의 외부로 배출을 억제하여 신선식품의 신선도를 유지하는 것이다.Therefore, when the film of the present invention is used as a packaging material, oxygen permeation of fresh food packaged in the packaging material is suppressed to the outside of the packaging material to maintain the freshness of the fresh food.

[항균성의 실험예][Experimental Example of Antimicrobial Activity]

모람이 첨가된 필름에 사용되는 균주는 E.coil,Ps.aeruginosa, B.cereus이다. 고체 배지에 접종된 균들은 항균물질이 존재하는 경우 성장이 이루어지지 않는다The strains used for moramine-added films are E.coil, P. Aeruginosa, and B. cereus. Bacteria inoculated into the solid medium do not grow in the presence of antimicrobial agents

따라서 균을 접종한 고체배지상에 항균물질을 함유한 micro disc를 배치시켜 disc 주위로 균의 성장을 관찰하였다.Therefore, microdisks containing antimicrobial substances were placed on the solid medium inoculated with the bacteria to observe the growth of bacteria around the discs.

항균효과를 지닌 화합물이 존재하면 균의 성장이 억제된 클리어존을 관찰하였다.When a compound having an antimicrobial effect was present, a clear zone in which the growth of the bacteria was inhibited was observed.

항균화합물의 농도가 높거나 그 효과가 강할수록 클리어존의 직경은 증가하게 된다.The higher the concentration of the antimicrobial compound or the stronger the effect, the greater the diameter of the clear zone.

이와 같은 원리를 이용하여 본 실험에서는 모람의 잎, 줄기, 열매추출액을 micro disc 에 적신 후 고체 배지에 배치하여 클리어존의 직경을 관찰하였다.Using this principle, we observed the diameter of the clear zone by immersing leaf, stem, and fruit extract of moth, in a micro disc, and placing it in a solid medium.

이 결과, 모람의 잎, 줄기, 열매추출액이 첨가된 micro disc가 균주 E.coil,Ps.aeruginosa, B.cereus이다. 고체 배지에서 클리어존의 직경이 늘어나지 않는 것을 관찰하였다.As a result, the micro discs with the leaf, stem and fruit extract of Moresum were E. coli, Ps.aeruginosa, and B. cereus. It was observed that the diameter of the clear zone did not increase in the solid medium.

따라서, 본 발명의 모람이 첨가된 필름에는 미생물활성작용을 억제하는 항균성이 포함되어 있어서, 모람이 첨가된 필름을 포장재로 사용시 상기 포장재에 포장되는 신선식품에 대해 미생물의 활성을 억제시켜 신선식품을 상기 포장장재에 보관시 신석식품을 보다 장기간 부폐없이 보관할 수 있는 것이다.Therefore, the film to which the motam of the present invention is added contains antimicrobial activity which suppresses the microbial activity, so that when the film containing the motam is used as a packaging material, the activity of the microorganism is inhibited against the fresh food packed in the packaging material, The nephrin food can be stored for a longer period of time in the packaging material.

한편, 본 발명의 필름제조방법중 폴리에틸렌(Polyethylene)수지와 모람분말을 가열기로 용융혼합단계(S400)에 상기 모람분말이외에 첨가제가 첨가되어 용융된 폴리에틸렌(Polyethylene)수지에 나노화된 백토분말 또는 나노화된 황토분말, 은나노를 더 첨가하여 첨가제가 첨가되어 용융된 폴리에틸렌수지에 모람분말, 나노화된 백토 및 황토분말, 은나노가 더 첨가되어 용융되어 필름으로 제조되어 모람성분이외 나노화된 백토 또는 황토, 은나노로서 필름에 항균성을 더 갖도록 하여 Meanwhile, in the method for producing a film of the present invention, the polyethylene resin and the mora powder are added to the melted polyethylene resin in addition to the moram powder in the melt mixing step (S400) using a heater to form a nano- Loam powder, and silver nano were added to the melted polyethylene resin to add molybdenum powder, nanotized white clay, loess powder and silver nano to the melted polyethylene resin. To have more antibacterial properties

모람이 갖는 생물활성작용을 억제하는 항균성에 나노화된 백토 또는 황토, 은나노의 항균성을 더 추가하여 모람, 나노화된 백토 및 황토, 은나노가 첨가된 필름을 포장재로 사용시 상기 포장재에 포장되는 신선식품에 대해 미생물의 활성을 억제시켜 신선식품을 상기 포장장재에 보관시 신석식품을 보다 장기간 부폐없이 보관할 수 있게 하기 위함이다.In addition to antimicrobial properties of white clay, loess, and silver nano, which are antimicrobial in antimicrobial activity to inhibit the biological activity of motam, when freshly packed films containing morom, nanoized clay, loess and silver nano are used as packaging materials, The present invention is intended to inhibit the activity of microorganisms and store the fresh food in the packaging material so that the fresh food can be stored for a longer period without any deterioration.

이상에서 설명된 본 발명에 따른 실시예는 예시적인 것에 불과하며, 본 발명 속하는 기술분야의 통상의 지식을 가진 자라면 이로부터 다양한 변형 및 균등한 타 실시예가 가능하다는 점을 잘 알 수 있을 것이다. 그러므로 본 발명은 상세한 설명에서 언급되는 형태로만 한정되는 것은 아님을 잘 이해할 수 있을 것이다.While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, is intended to cover various modifications and equivalent arrangements included within the spirit and scope of the invention. It is therefore to be understood that the invention is not limited to the form set forth in the detailed description.

따라서 본 발명의 진정한 기술적 보호범위는 첨부된 특허등록청구범위의 기술적 사상에 의해 정해져야 할 것이다. 또한, 본 발명은 첨부된 청구범위에 의해 정의되는 본 발명의 정신과 그 범위내에 있는 모든 변형물과 균등물 및 대체물을 포함하는 것으로 이해되어야 한다.Accordingly, the true scope of the present invention should be determined by the technical idea of the appended claims. It is also to be understood that the invention includes all modifications, equivalents, and alternatives falling within the spirit and scope of the invention as defined by the appended claims.

S100: 모람을 건조 및 분말화하는 단계
S200: 폴리에틸렌수지를 가열기로 용융하는 단계
S300: 폴리에틸렌수지에 첨가제를 첨가하고 가열기로 용융하는 단계
S400: 폴리에틸렌수지와 모람분말을 가열기로 용융혼합하는 단계
S100: Step of drying and pulverizing honey
S200: melting the polyethylene resin with a heater
S300: adding an additive to the polyethylene resin and melting with a heater
S400: Step of melt-mixing polyethylene resin and moth powder with a heater

Claims (4)

모람의 잎과, 줄기와, 열매를 채취하여 세척하여 상온에서 건조시키고, 건조된 상기 모람의 잎, 줄기, 열매를 분쇄기로 분쇄하여 모람을 분말화하는 모람을 건조 및 분말화하는 단계(S100)와;
폴리에틸렌(Polyethylene)수지를 가열기로 용용하는 단계(S200)와;
용융된 상기 폴리에틸렌(Polyethylene)수지 용액에 구취억제 및 휘산작용을 위해 멘톨 또는 페파민트인 첨가제를 첨가하여 가열기로 가열하되, 상기 가열기로 가열하는 온도를 145 내지 155℃를 유지하여 가열시키는 폴리에틸렌(Polyethylene)수지 용액에 첨가제를 첨가하고 가열기로 용융하는 단계(S300)와;
상기 첨가제가 첨가되어 용융된 폴리에틸렌(Polyethylene)수지 21 내지 29kg에 분말화된 모람 90 내지 110g을 투입하여 혼합하고, 가열기로 가열하되, 상기 가열기로 가열하는 온도를 145 내지 155℃를 유지하여 가열시키면서 폴리에틸렌(Polyethylene)수지와 모람분말을 가열기로 용융혼합하는 단계(S400)를 포함하여 필름을 제조하는 것을 특징으로 하는 모람성분이 첨가되어 항균 및 산소투과억제 기능을 갖는 필름제조방법.
The step (S100) of drying and pulverizing the leaves of the seedlings, the stem, and the fruit, washing the seedlings, drying the seedlings at room temperature, pulverizing the leaves, stem and fruit of the dried seedlings with a grinder to pulverize the seedlings, Wow;
A step (S200) of melting a polyethylene resin with a heater;
A polyethylene resin is added to the melted polyethylene resin solution to add menthol or peppermint additive for halophilic inhibition and volatilization to the melted polyethylene resin and heated at a temperature of 145 to 155 DEG C by heating with a heater, Adding the additive to the resin solution and melting the mixture with a heater (S300);
90 to 110 g of powdered mosques were added to 21 to 29 kg of the melted polyethylene resin with the additive added thereto and mixed. The mixture was heated by a heater, heated at 145 to 155 ° C by heating with the heater A method for producing a film having a function of inhibiting antimicrobial activity and oxygen permeation by adding a moram component, which comprises melt-mixing a polyethylene resin and a morom powder with a heater (S400).
제 1항에 있어서,
상기 모람분말이외에 첨가제가 첨가되어 용융된 폴리에틸렌(Polyethylene)수지에 나노화된 백토분말 또는 나노화된 황토분말을 더 첨가하는 것을 특징으로 하는 모람성분이 첨가되어 항균 및 산소투과억제 기능을 갖는 필름제조방법.
The method according to claim 1,
The method for producing a film having antibacterial and oxygen permeation inhibiting function by adding a morom component to a molten polyethylene resin to which nano-sized white clay powder or nanosized loess powder is further added in addition to the moras powder.
제 2항에 있어서,
상기 모람분말, 나노화된 백토분말 , 나노화된 황토분말이외에 은나노를 더 첨가하는 것을 특징으로 하는 모람성분이 첨가되어 항균 및 산소투과억제 기능을 갖는 필름제조방법.
3. The method of claim 2,
A method for producing a film having antibacterial and oxygen permeation inhibiting function by adding a moss component, which is characterized by further adding nano-particles in addition to the above-mentioned moth powder, nanotized white clay powder, and nano-sized yellow loess powder.
제 1항에 있어서,
상기 폴리에틸렌(Polyethylene)수지는 저밀도 폴리에틸렌(Lower Density Polyethylene:LDEP)수지인 것을 특징으로 하는 모람성분이 첨가되어 항균 및 산소투과억제 기능을 갖는 필름제조방법.
The method according to claim 1,
Wherein the polyethylene resin is a low density polyethylene (LDEP) resin. The method of claim 1, wherein the polyamine resin is a low density polyethylene (LDEP) resin.
KR1020140110616A 2014-08-25 2014-08-25 Flim manufacturing method added moram component KR20140120288A (en)

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