KR20140093489A - A fuel additives using nanomaterials for diesel - Google Patents

Abstract

The present invention relates to a new fuel additive composition that is developed to utilize a nanomaterial as a fuel to add fuel to existing fossil fuel to achieve a fuel saving effect. The present invention enables stable mixing of nanomaterials with a fossil fuel by mixing a stabilizer with nanomaterials so that when the fossil fuel is burned, the nanodevices also diffuse in the fossil fuel and function to help burn well together .
The fuel additive composition according to the present invention diffuses well to fossil fuel and burns together with fossil fuel, thereby generating a large amount of energy. As a result, fossil fuel is saved, and at the same time, There is a main purpose.
The present invention relates to a new technique for reducing fuel by promoting complete combustion when added in a small amount to diesel, which is a kind of fossil fuel, as a fuel additive material composed of a mixture of a nanomaterial and a stabilizer.
The "fuel composition for diesel fuel using the nano device" according to the present invention has the advantage of being easy to manufacture and being inexpensive because of its low price, and being able to popularize it and to increase the fuel saving effect by adjusting its addition amount as necessary. It also has the advantage of promoting complete combustion, reducing the amount of smoke generated when fossil fuels are burned and contributing to environmental protection.
[Index]
Nano, fossil fuel, complete combustion

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a fuel composition for a diesel fuel using nanodevices,

The present invention relates to a fuel saving composition for diesel prepared by mixing a stabilizer with a nanomaterial, and more particularly, to a fuel saving composition for a diesel fuel produced by mixing a nanomaterial with a stabilizer, Is a new technology for fuel saving compositions.

Nano Technology (NT) is a technology that synthesizes, assembles, controls, or measures and identifies materials at small size units such as atoms or molecules. In general, nanotechnology classifies materials or objects with sizes ranging from 1 to 100 nanometers. The nano comes from the Greek nano, which means dwarf. One nanosecond (ns) stands for one billionth of a second. One nanometer (nm) is 1 / billionth of a meter, which corresponds to about one-tenth of the thickness of a human hair, about three to four atoms in size. The specific characteristics are as follows.

end. Optical

In the nano area, the color changes with size. For example, gold (Au) is generally golden, but when it is below 20 nm, it turns red, and the color changes even if the size changes slightly.

I. Chemical

As all materials are cleaved from a large chunk into a small chunk, the surface area of the entire material increases sharply, which causes the nanomaterials to have unique characteristics. For example, titanium dioxide (TiO2) is widely used because it has sterilizing power, self-cleaning ability and anti-fogging effect when it receives weak ultraviolet ray generated from fluorescent lamp or incandescent lamp when TiO2 particle size is less than 20 nm.

All. Mechanical

The particles of the polycrystalline material have the same basic arrangement but tend to have strong mechanical properties as the grain size per unit area existing between the particles and the particle is larger. However, in the case of nanomaterials, unlike the general tendency, there is a tendency that the intensity increases rapidly in a specific grain size region. However, when mixed with other composites, the mechanical strength of the nanoparticles is considered to be superior in terms of mechanical properties.

la. Electronic

Semiconductors, magnetic metals, and nanoparticles, which have electronic properties, are generally known to have the largest magnetic properties at about 10 to 100 nm. It is also known that magnetic properties can be maximized and spherical magnetic metal nanoparticles of very small size and uniform size can be synthesized and these particles can be used as one bit each through regular arrangement. The size is several nanometers, mainly composed of cobalt, cobalt and platinum alloy.

Nanotechnology Scanning Probe Technology is a core technology that is the foundation of nanotechnology. It is a technology that measures and analyzes nanometer-level properties, structures and components. The nano measurement technology can be divided into X-ray technology electron / ion beam technology infrared ray, ultraviolet ray, and visible ray technology depending on the type of the source, mainly SPM technology. Since the scope of the technology of nanometer measurement technology is very large, it is difficult to realize the total classification and analysis. Therefore, in this analysis, the SPM technology, which is the representative technology of the nano measurement technology, can be considered in this analysis. In relation to the semiconductor industry, where Korea is stronger than other countries, the surface shape, structure, , Which is currently used or is expected to increase in the future, is limited to some nano measurement technologies. As nanotechnology evolves, it will be used in many fields such as chemistry, physics, biology, geography and so on.

The various applications of nanotechnology are as follows.

end. Electronic field

Communications Nano-structured microprocessor devices with performance over 1 million times the cost of low power consumption, communications systems with more than 10 times the bandwidth and high transfer rate, large capacity information storage devices, Intelligent nanosensor systems that collect, process, store information, memory semiconductors, pocket-sized super robots, faster, smaller, thinner and lighter smart interfaces

I. Materials / Manufacturing Machinery

Nanostructured metals and ceramics that do not have the exact shape, high strength materials designed on the atomic layer, high performance catalysts, printing with nanoparticles with excellent color, new standards for nanoscale measurements, cutting tools, electrical and chemical , Nano coatings for structural applications

All. Medical field

Rapid and effective sequencing to enable the revolution of diagnostics and therapeutics, effective and affordable health care using telemedicine and biomedical devices, new drug delivery systems through nanostructures Durability and biocompatible artificial organs, diagnosis, Nano sensing system that can prevent

All. Biotechnology field

Synthesis of hybrid systems Skin, genetic analysis / manipulation, biochemically degradable chemicals made by molecular engineering, genetic improvement of plants and animals, gene and drug supply to animals, DNA analysis using nanotechnology-based analysis technology

la. Environment, energy field

New batteries, photosynthesis of clean fuel, proton photovoltaic cells, nanometer-sized porous catalysts, porous materials that can remove very fine contaminants, nanoparticle-reinforced polymers that replace metals in the automotive industry, nanoparticles of inorganic materials, polymers Abrasion-resistant, environment-friendly tire

hemp. Defense Sector

Weapon system change (miniaturization, high speed, improvement of long-distance movement ability), unmanned remote weapon (unmanned submarine, unmanned fighter, remote sensor system), stealth weapon

bar. Aerospace

Low power, high performance computer with anti-radiation, nanotechnology for micro spacecraft, nanoscale sensor, avionics using nanotechnology, heat resistant, abrasion resistant nano coating

As we have seen, nanotechnology has many applications. When nanotechnology is applied to fuel, it can achieve higher energy efficiency than simply using fossil fuels. When the fuel additive composition that can be used in addition to the fossil fuel is developed by utilizing the advantages of the nanotechnology, it is possible to apply the new technology in which the fuel efficiency is reduced due to the improvement of the energy efficiency and the complete combustion is achieved.

The present invention enables stable mixing of nanomaterials with a fossil fuel by mixing a stabilizer with nanomaterials so that when the fossil fuel is burned, the nanodevices also diffuse in the fossil fuel and function to help burn well together .

The fuel additive composition according to the present invention diffuses well to fossil fuel and burns together with fossil fuel, thereby generating a large amount of energy, thereby saving fossil fuel and promoting complete combustion, thereby contributing to environmental protection. There is a main purpose.

The fuel additive composition according to the present invention is largely divided into a nanodevice and a stabilizer. The nano device is used as an energy source that promotes complete combustion and generates high energy. The stabilizer helps the chemical stability of the nanodevice and also helps nanomaterials to mix well with fossil fuel diesel. In other words, stabilizers function to help nanomaterials burn well together when the fossil fuel burns by allowing the nanomaterials to spread evenly over the diesel in a short period of time.

The fuel additive composition according to the present invention can experience a high fuel saving effect by generating a large amount of energy when a nanomaterial is injected into a fossil fuel such as diesel and burned together. In addition, since complete combustion is promoted, the amount of soot generated is significantly reduced, which can contribute greatly to environmental protection. If the amount of nanomaterials is adjusted appropriately depending on the application, a high fuel saving effect can be obtained. It is also a new technology that can contribute massively to mass production at low cost.

The 'fuel saving composition for diesel fuel using nano device' according to the present invention is largely divided into nanomaterial and stabilizer. Nanomaterials are used as an energy source for generating high energy and at the same time promoting complete combustion. Stabilizers also help to stabilize the nanomaterials while helping nanomaterials to mix well with fossil fuel diesel. . In other words, stabilizers function to help nanomaterials burn well together when fossil fuels are burned by allowing the nanomaterials to diffuse and spread evenly over a short period of time.

The nanomaterials developed for the purpose of reducing fuel by adding to the diesel according to the present invention are "calcium chloride, zinc chloride and magnesium chloride", and their composition ratios are described in Table 1 below.

The stabilizer that helps diffusion of nanomaterials when mixed with the nanomaterial according to the present invention and mixed with the diesel is "oleic acid, diethylene glycol ", and its composition ratio is described in Table 1 below.

The constituent material of the 'fuel saving composition for diesel fuel using nano device' according to the present invention will be described in detail as follows.

The formula for calcium chloride is CaCl ₂ . The molecular weight is 110.99. It is highly hygroscopic due to cubic or granular crystals and is well soluble in water. Therefore, it is frequently used as a dehydrating agent. Because calcium is one of the most important biological components, it is administered when symptoms of hypocalcemia such as fever (milk fever) appear (such as hypersensitivity). Rickets, osteomalacia, and other bone diseases. Intravenous injection is useful as an antidiabetic agent for the rapid supply of calcium and magnesium, and may also be used as an acidosis diuretic. It is not used by subcutaneous or intramuscular injection because it exhibits strong local irritation.

Zinc chloride is a compound of zinc and chlorine. Its formula is ZnCl2. It is a colorless crystalline powder which is deliquescent. It dissolves well in water (432 g in 100 g of water at 25 ° C) and crystallizes in aqueous solution, resulting in various kinds of hydrates. It is industrially produced by dissolving zinc oxide or zinc debris in hydrochloric acid to remove impurities such as iron and aluminum and then concentrating. In organic synthesis, it is used as a catalyst for various condensation reactions and is used as a dehydrating agent, a bactericide, a wood preservative, an activated carbon production, a battery material, and a medicine. ZnCl2. Colorless crystalline powder with melting point of 313 캜, boiling point of 732 캜, specific gravity of 2.91 (25 캜). It is easily soluble in water and dissolves in water (432 g in 100 g of water at 25 ° C). When crystallized in aqueous solution, various kinds of hydrates are formed. The aqueous solution shows weak acidity. Industrially, debris of zinc oxide or zinc is dissolved in hydrochloric acid to remove impurities such as iron and aluminum and then concentrated. To make pure in the laboratory, pure zinc and hydrogen chloride are reacted in anhydrous ether. Commercially available products often contain some basic salts. In organic synthesis, it is used as a catalyst for various condensation reactions and the like. It is also used as a dehydrating agent, bactericide, wood preservative, activated carbon production, battery material, medicine and so on. It is also used as a soldering paste material.

Magnesium chloride is a compound of chlorine and magnesium. The formula is MgCl2. In addition to anhydrides, there are 2,4,6,8,10,12 hydrates and usually exist as hexahydrate MgCl2 · 6H2O. In Strasbourg, Germany, MgCl2 · 6H2O is produced in bischafite. It is also contained in seawater, which is a byproduct when salt is made and contains about 2% in the water. The anhydrous substance is a colorless crystalline powder having a melting point of 712 캜, a boiling point of 1,412 캜, and a specific gravity of 2.325 (25 캜). It is highly hygroscopic, and it dissolves well in water and alcohol. To make an anhydride industrially, magnesium is added to MgO (Magnesia) to react with chlorine gas. In the laboratory, magnesium chloride ammonium MgCl2 · NH4Cl · 6H2O is pyrolyzed. Even if the normal hydrate is heated, it is hydrolyzed to produce magnesium oxide, so that pure magnesium chloride can not be obtained. The hexahydrate is a colorless crystal with a specific gravity of 1.56. It is easily soluble in water (52.8 g for 100 g of water at 0 ° C) and is also soluble in alcohol. The hexavalent MgCl2-KCl6H2O is dissolved in water and fractionally crystallized or separated from the water in order to industrially obtain the hexavalent cargo. The anhydride is important as a raw material for producing magnesium metal, and magnesium oxide is mixed to make magnesia cement. Hydrates are used in the manufacture of tofu, wood preservatives, wool refining, and sulfuric acid paper.

The oleic acid has the formula C17H3COOH. Also called heritage. It is mainly contained in animal and plant oil, and is the main component of oils such as camellia oil and olive oil. It is colorless, odorless, oily liquid with specific gravity of 0.898 and melting point of 14 ℃. It does not dissolve in water but dissolves in organic solvent. If left in the air, it becomes oxidized to yellow or brown, and smells bad. Lubricants, raw materials for soap, and waterproofing agents for fabrics.

Diethylene glycol is a compound produced when ethylene glycol used as an antifreeze and as a raw material for polyester is synthesized from ethylene oxide. The structural formula of diethylene glycol is HOCH2CH2OCH2CH2H. It is hygroscopic, has no odor, is sticky and has a slightly sweet taste. It is used as a raw material for polyester resins, and as a moisturizer. If you mix it with poor quality wines, it tastes good, but when you eat it is harmful to your kidneys and liver.

[Table 1] shows the composition ratio of 'fuel composition for diesel using nano device' composed of the above-mentioned materials.

The above composition ratio is a result of finding the most suitable golden ratio through repeated experiment. The nanomaterials according to the composition ratio are burned together with the diesel to generate energy and promote the complete combustion. The stabilizer composed of the above composition ratio is a function that allows the nanomaterial to diffuse well in the diesel To help the nanomaterials burn well.

10 ml (added at a ratio of 1,000: 1) of the fuel additive composition according to the present invention was added to diesel of 10 liters (L) at a mixing ratio of [Table 1], and the results were as shown in Table 2.

The experiment was carried out by the experiment of the fuel consumption of the vehicle and the experiment was carried out under the same conditions. And the fuel consumption is 60km / h on the highway, which is the same vehicle type for 10 minutes.

Claims (1)

"Nanomaterial " and" oleic acid 29 ", both of which are 2.5-3.5 wt% of calcium chloride in the size of 40-80 nm, 2.5-3.5 wt% of zinc chloride in the size of 40-80 nm, 1.8-2.2 wt% of magnesium chloride in the size of 40-80 nm, -35 wt.%, Butyl carbitol 55-65 wt.%, And then added to the diesel to obtain a fuel saving effect. The "fuel composition for diesel fuel using nano device"