KR20140081125A - W/O type make up cosmetic composition having temperature sensitive to clensing - Google Patents

Abstract

The present invention relates to a water-in-oil emulsion type make-up cosmetic composition. More specifically, the present invention, with regard to a water-in-oil emulsion type make-up cosmetic composition comprising a water phase portion and an oil phase portion, relates to a water-in-oil emulsion type make-up cosmetic composition comprising the water phase portion which includes a polyglyceryl fatty acid ester-based surfactant. The water-in-oil emulsion type make-up cosmetic composition does not easily wash out in water due to waterproofing property in cold water or at room temperature, and can be easily removed in warm water. Therefore, the water-in-oil emulsion type make-up cosmetic composition greatly reduces the excessive use of a cleansing product in a cleansing step or a cleansing process through several steps and can reduce skin irritation caused by the excessive rolling action on skin, thereby providing a user with convenience in a cleansing step to enhance product competitiveness.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a makeup cosmetic composition having a water-

The present invention relates to a makeup cosmetic composition with a water-in-oil emulsion type which can be easily removed from hot water and can greatly reduce the use of excessive cleansing products in a cleansing step or work over various stages and reduce skin irritation caused by excessive skin rolling will be.

Make-up cosmetics are manufactured to have high water resistance such as water-proof function so that they are not easily removed by sebum or sweat.

To clear make-up cosmetics, many kinds of cleansing products and several cleansing steps are required.

Cleansing products include cleansing water, cleansing lotion, cleansing cream, cleansing gel, cleansing oil, foam cleansing, and deep scrub. Cleansing products are selected for each purpose and skin.

In general, cleansing is firstly washed using a oil type remover such as cleansing oil and finished with lukewarm water after a second cleansing using an aqueous type remover such as foam cleansing. Such a complex cleansing step over three stages has a possibility to cause unnecessary skin irritation through excessive skin rolling as well as time consuming, and it is necessary to simplify and simplify the cleansing steps of these various steps.

Thus, a cleansing product that achieves the same effect with only one cleansing without using various cleansing products has been proposed and put on the market.

Korean Patent Registration No. 10-1081144 discloses a stick-type cleansing agent which can be washed off with water, including polyethylene / microcrystalline mixed wax, mineral wax, oil thickener, inorganic thickener, nonionic surfactant, antibacterial moisturizing powder, In presenting the cosmetic composition, the composition shows that the effect of cleansing is maximized, there is no skin irritation, and no secondary cleansing process is required.

Korean Patent Registration No. 10-0465973 discloses a cleansing composition of an O / W emulsion, and it is mentioned that even a small amount of oil can sufficiently remove makeup ingredients. In the case of cleansing oil, the face is wiped with a tissue or a cotton pad after application to the skin. In this case, there is skin irritation. WO 2006/003941 and Korean Patent Registration No. 10-0579345 disclose an oil type cleansing cosmetic composition which can be rinsed with water I am suggesting.

Various cleansing products have been proposed to make cleansing easier.

Korean Patent Registration No. 10-1081144 Korean Patent Registration No. 10-0465973 WO 2006/003941 Korean Patent Registration No. 10-0579345

Therefore, the inventors of the present invention have conducted various studies to maximize the cleansing effect by changing the composition of the makeup product instead of improving the function of the cleansing product. As a result, when a specific surfactant is used as an additional composition, The present invention is accomplished by confirming that the function of the product can be maintained while maintaining the water resistance of the product in low temperature water or hot water, and easily removed in lukewarm water or hot water.

Accordingly, an object of the present invention is to provide a make-up cosmetic composition in a water-in-oil type which is easy to clean with only lukewarm water or hot water.

In order to accomplish the above object, the present invention provides a makeup cosmetic composition for emulsifying oil in water, comprising an aqueous phase and an oil phase,

Wherein the water-soluble part comprises a polyglyceryl fatty acid ester-based surfactant so as to be easily removed from hot water.

The polyglyceryl fatty acid ester surfactant is used in an amount of 3 to 10% by weight in the total composition.

The water-in-oil type makeup cosmetic composition according to the present invention can be easily removed from hot water because it is not easily washed in water due to its water resistance at cold or room temperature, and thus greatly reduces the use of excessive cleansing products during a cleansing step or work at various stages , Skin irritation due to excessive skin rolling can be reduced.

The oil-in-water type make-up cosmetic composition can be manufactured into various cosmetic cosmetic formulations such as bib cream and foundation, thereby improving the competitiveness of the product by giving convenience to the user in the cleansing step.

Fig. 1 is a photograph showing the cleaning power according to the temperature after application of the composition of Example 1
Fig. 2 is a photograph showing the cleaning power of the composition of Comparative Example 1,
3 is a photograph showing the cleaning power of the composition of Comparative Example 2,

Hereinafter, the present invention will be described in more detail.

In the present invention, a polyglyceryl fatty acid ester surfactant is further used as a surfactant in the design of a water-in-oil type makeup cosmetic composition so that it can be easily removed from hot water due to its water resistance at cold or normal temperatures.

The polyglyceryl fatty acid ester surfactant is a typical water-in-oil (W / O type) emulsifying surfactant and has a Hydrophilic-Lipophilic Balance (HLB) value of 10 or more. Such a polyglyceryl fatty acid ester surfactant is added to an oil-in-water type makeup cosmetic composition as an additional composition so as to maintain the water resistance of the makeup product at room temperature or low temperature and drastically reduce the water resistance so as to be easily cleaned in lukewarm water or hot water. At this time, the hot water or hot water is water having a temperature higher than the body temperature, and usually means water at 38 ° C or higher.

The polyglyceryl fatty acid ester surfactant is used in an amount of 3 to 10% by weight, preferably 4 to 8% by weight, in the whole composition so as to ensure the above-mentioned effect and not to affect the function of the conventional makeup product. If the content is less than the above range, a change in detergency according to the temperature to be obtained in the present invention can not be expected. On the contrary, if the content exceeds the above range, Use it properly.

According to Experimental Example 1 of the present invention, the polyglyceryl fatty acid ester surfactant was tested. As a result, it was confirmed that the polyglyceryl fatty acid ester surfactant remained water-resistant at 30 ° C., but was easily removed with water only at 40 ° C. hot water. 6% by weight, respectively.

As already mentioned, the polyglyceryl fatty acid ester surfactant is a typical nonionic surfactant. Even if a similar nonionic surfactant is used, a change in cleaning force according to the temperature can not be expected.

 In addition to the surfactant of the present invention, nonionic surfactants include glycerin fatty acid esters, sorbitan fatty acid esters, POE (polyoxyethylene) sorbitan fatty acid esters, POE alcohol ethers, and lecithin. At this time, it is necessary to select different surfactants depending on whether the formulation to be manufactured is an underwater type (O / W type) or a water-in-oil type (W / O type) and select an emulsifier corresponding to the HLB The most stable emulsion composition can be prepared.

As a result of using the other nonionic surfactants through Comparative Examples 2 to 4 of the present invention, there was almost no change in detergency according to the expected temperature when the polyglyceryl fatty acid ester surfactant was used.

Preferable polyglyceryl fatty acid ester surfactants can be prepared by reacting polyglycerol with a fatty acid either directly or by purchasing commercially available surfactants. Representative examples include polyglyceryl-4 caprylate / caprate, polyglyceryl-5 caprylate / caprate, polyglyceryl-6 caprylate / caprate, polyglyceryl-7 caprylate / caprate , Polyglyceryl-8 caprylate / caprate, polyglyceryl-9 caprylate / caprate, polyglyceryl-10 caprylate / caprate, polyglyceryl-4 caprate, polyglyceryl- Polyglyceryl-5 caprate, polyglyceryl-8 caprate, polyglyceryl-9 caprate, polyglyceryl-10 caprate, polyglyceryl-4-laurate , Polyglyceryl-5 laurate, polyglyceryl-6 laurate, polyglyceryl-7 laurate, polyglyceryl-8 laurate, polyglyceryl-9 laurate, polyglyceryl- Glyceryl-6-cocoate, 8 cocoate, polyglyceryl-9 cocoate, polyglyceryl-10 cocoate, polyglyceryl-11 cocoate, polyglyceryl-12 cocoate, polyglyceryl- 6 myristate, polyglyceryl-7 myristate, polyglyceryl-8 myristate, polyglyceryl-9 myristate, polyglyceryl-10 myristate, polyglyceryl-11 myristate, polyglyceryl- Polyglyceryl-12 stearate, polyglyceryl-11 stearate, polyglyceryl-12 stearate, polyglyceryl-12 stearate, polyglyceryl- Polyglyceryl-6 behenate, and combinations thereof.

Preferred are polyglyceryl-2 caprate, polyglyceryl-3 caprate, polyglyceryl-4 caprate, polyglyceryl-5 caprate, polyglyceryl-6 caprate, polyglyceryl- Polyglyceryl-6 caprate, polyglyceryl-6 behenate, and combinations thereof, and most preferably polyglyceryl-2 caprate is used.

The composition of the water-in-oil type makeup cosmetic composition containing the polyglyceryl fatty acid ester type surfactant is composed of an upper part and an upper part, and the compositions of the upper part and the upper part are not limited to the present invention, It can be different.

For example, any form of make-up cosmetics conventionally manufactured in the art can be used. Examples of such makeup cosmetics include sunscreen, makeup base, foundation, babe cream, concealer, lipstick, lip gloss, lip liner, powder, It can be used for makeup cosmetics of various formulations such as fact, powder, eye shadow, blusher, eyeliner, eye mascara, hair gel, hair mascara.

In addition, the formulations of the respective formulations may contain various kinds of bases and additives necessary for formulation of the formulations, and ordinary additives may be used as long as the effects are not impaired.

Preferably, the water-in-oil type makeup cosmetic composition according to the present invention comprises an oil phase part comprising 5.0 to 50.0% by weight of an oil and 0.1 to 10% by weight of a stabilizer and 1 to 20% by weight of a polyol, 3 to 10% by weight of a polyglyceryl fatty acid ester surfactant, and water as a remainder.

The method for preparing the water-in-oil type makeup cosmetic composition is not particularly limited in the present invention, and it follows the known method for preparing the composition.

For example, it is possible to prepare the mixture by adding each composition to the mixer and uniformly mixing them. The mixing can be performed by applying heat as required, and a mixer such as a homogenizer is used for uniform mixing.

At this time, the water phase is heated to 50 to 80 DEG C, preferably 65 to 75 DEG C, and if necessary, stirring is performed using a homomixer at a speed of 2000 to 4000 rpm, preferably 3000 rpm for 3 to 10 minutes.

Examples of the oil used herein include mango butter oil, shea butter oil, cocoa bean seed oil, macadamia nut oil, olive oil, midoform seed oil, refined grape seed oil, rosehip oil, sapphire oil, peach seed oil, Vegetable oils such as oils; Dicaprylyl carbonate, squalane, neopentyl glycol deptanoate, tocopheryl acetate, trioctanoin, C12-15 alkyl ethyl hexanoate, octyldodecyl myristate, tricaprylyl, octyldodecylstearoyl Stearate, bis-hydroxyethoxypropyl dimethicone, caprylic, capric triglyceride, isotridecylisononanoate, polyglyceryl-2 triisostearate, diisostearyl malate, dipentaerythritol, But are not limited to, synthetic esters such as isopropyl myristate, isopropyl myristate, cetyl ethyl hexanoate, cetyl octanoate, ozokerite, glyceryl trioctanoate, octyldodecyl myristate, isopropyl palmitate, isopropyl myristate, oil; Silicone oils such as phenyl trimethicone, cyclomethicone, dimethicone, and decamethyl cyclopentasiloxane; Hydrogenated oils, including hydrogenated, hydrogenated PVC-60 castor oil, hydrogenated polyisobutene, hydrogenated polydecene; Or a combination of these may be further used.

The oil comprises 5 to 50.0% by weight of the total composition. If the content is less than or more than the above range, the stability of the water-in-oil emulsified composition deteriorates and it is difficult to make various makeup products.

Stabilizers include hydrocarbons; And a fatty acid, a silicone polymer stabilizer selected from the group consisting of lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, linoleic acid, and mixtures thereof. Examples of the silicone polymer include biphase 15 / methylethyldimethylsilane, dimethicone / dimethicone phage-10/15, dimethicone / polyglycerin-3, dimethicone / dimethicone, dimethicone / dimethicone vinyl dimethicone , Cyclomethicone / dimethicone, cyclomethicone / dimethicone, cyclomethicone / trimethylsiloxysilicate, cyclopentasilonic acid / dimethicone, cyclopentasilonic acid / phage-12 dimethicone, cyclopentasilonic acid / At least one selected from the group consisting of cetearyl dimethicone / vinyl dimethicone, cyclopentasilonic acid / dimethicone / vinyl dimethicone, dimethicone / vinyl dimethicone cross polymer.

The stabilizer comprises from 0.1 to 10.0% by weight of the total composition. If the content is less than or more than the above range, the stability of the water-in-oil emulsified composition deteriorates and it is difficult to make various makeup products.

Water is distilled water, preferably deionized distilled water.

Usable moisturizers include polyhydric alcohols such as glycerin, erythritol, xylitol, maltitol glycerin, propylene glycol, 1,3-butylene glycol, sorbitol, polyglycerin, polyethylene glycol, 1,2-pentanediol and isoprene glycol; Amino acid, sodium lactate, and sodium pyrrolidonecarboxylate, and other ingredients such as xyloglucan, corn seed, carrageenan, pectin, mannan, cardan, galactan, deltansulfuric acid, glycocon, keratan sulfate, chondroitin, But are not limited to, tin sulfate, kerato sulfate, chondroitin, mucoitin sulfate, kerato sulfate, locust bean gum, succinoglucan, calonym acid, hyaluronic acid, heparan sulfate, sodium hyaluronate, collagen, mucopolysaccharide, chondroitin A water-soluble polymeric substance which is sulfuric acid; Dimethyl polysiloxane, methylphenyl siloxane; Culture supernatant of lactic acid bacteria or bifidus bacteria; And a combination of these.

At this time, other ingredients besides the composition can be arbitrarily selected and formulated according to the formulations of the other cosmetics, the purpose of use, and the like.

Examples of the wrinkle improving agent include ascorbyl glucoside, kinetin, auxin, a peptide, an alpha-hydroxy (hydroxypropyl) phosphate, and the like. Acid, etc. may be used. As the whitening agent, arbutin, ascorbic acid, magnesium ascorbyl phosphate, ascorbyl acid-2-glucoside and the like may be used. The effective active ingredient is used in an amount of not more than 5% by weight in the aqueous phase.

In the oily phase, useful licorice, ethyl ascorbyl ether, alpha-bisabolol and the like having a whitening effect as an effective active ingredient can be used. As the active ingredient having a wrinkle-reducing effect, an oil soluble active ingredient such as retinol and derivatives thereof (e.g., retinyl palmitate), adenosine and the like can be used. These active ingredients are used in the total composition in the range of 0 to 10.0% by weight, preferably 0.001 to 10.0% by weight.

In addition, if necessary, auxiliary surfactants, pigment powders, pigments, sunscreen agents, neutralizing agents, pH adjusting agents, preservatives, bactericides, oxidative stabilizers, organic solvents, thickeners, softening agents, antioxidants, free radical destruction A preservative, an antipruritic agent, a substance P antagonist, a filler, a polymer, a propellant, a basicizing or acidifying agent, or a preservative, an antioxidant, a stabilizer, an emollient, a silicone, an alpha hydroxy acid, a defoamer, a vitamin, Colorants, and the like. The selection of the additive can be made by a person having ordinary skill in the art, and the content thereof is also used within a usual range. Preferably, the content of such additives should not exceed 15% by weight in the total cosmetic composition.

Typically, the pigment powder includes extender pigments, white pigments, colored pigments, pearlescent pigments, metal powders, organic powders and the like. Examples of extender pigments include talc, mica, kaolin, calcium carbonate, mica, talc, kaolin, alumina, barium silicate, zeolite, muscovite, magnesium carbonate and barium sulfate. White pigments such as titanium oxide and zinc oxide Examples of the coloring pigment include benzalkonium, iron oxide yellow, iron oxide black, iron oxide black, iron oxide black, iron oxide black, iron oxide black, iron oxide black, iron oxide black, , Tin oxide, and ferric ferrocyanide. Examples of metal powders include gold, silver, copper, palladium, and platinum. Examples of organic powders include polymethyl methacrylate, nylon, cellulose, and starch Do.

The pigment is not particularly limited in the present invention, and natural substances, inorganic substances and organic substances generally known in cosmetics can be used.

Natural pigments include, but are not limited to, gardenia yellow, gardenia blue, gardenia green, gardenia red, red national color, red spot yellow pigment, safflower yellow spot, anato pigment, cochineal pigment, Anthocyanins, anthocyanins, picosapentaenoic acid, anthocyanins, anthocyanins, anthocyanins, blue pigments, blueberry pigments, fluorescent pigments, caramel pigments, red radish pigments, persimmon pigments, current pigments, riboflavin, beta carotene, cacao pigments, turmeric pigments, Cyan, phycocyanin, chlorophyll pigments, and combinations thereof.

Examples of the inorganic pigments include metal oxides such as iron oxide (red, black, yellow and brown), titanium dioxide, zinc oxide, chromium oxide, bismuth oxychloride, aluminum oxide, zirconium oxide, cobalt oxide, One kind selected from the group consisting of calcium hydroxide, iron hydroxide, aluminum hydroxide, chromium hydroxide, magnesium hydroxide, ferric ammonium ferrocyanide, prussian blue, iron sulfide, manganese violet, carbon black, mica, kaolin and combinations thereof is possible.

Examples of the organic pigments include indigo lake, carmin lake, rake originating from well known FD & C and D & C dye series such as D & C Red 21 aluminum lake, D & C Red 7 calcium lake, aromatic azo, indigoid, triphenylmethane, ≪ / RTI > and gentian < RTI ID = 0.0 >

When the formulation is a solution or an emulsion, a solvent, a dissolving agent or an emulsifying agent is used as a carrier component, and examples thereof include water, ethanol, isopropanol, ethyl carbonate, ethyl acetate, benzyl alcohol, benzyl benzoate, 3-butyl glycol oil, glycerol aliphatic ester, polyethylene glycol or fatty acid esters of sorbitan.

In addition, in the case of preservatives, methylparaben, propylparaben, butylparaben, ethylparaben, phenoxyethanol and the like are used, and the coloring matter is PMMA (polymethylmethacrylate), silica, nylon, polyurethane, ultramarine Iron oxide, pearl, synthetic mica, mica, talc, cerasite and boron nitride may be mixed and used.

In addition, as an ultraviolet screening agent, both an organic ultraviolet screening agent and an inorganic ultraviolet screening agent can be used.

Examples of the organic sunscreen agents include octylmethoxycinnamate, octyl salicylate, octocrylene, butylmethoxydibenzoylmethane, oxybenzone, octyltriazone, menthyl anthranilate, 3,4-methyl benzylidene kempfer, isoamyl -P-methoxy cinnamate, bisethylhexyloxyphenol methoxyphenyltriazine, methylenebisbenzotriazolyltetramethylbutylphenol and the like can be used. As the inorganic ultraviolet blocking agent, titanium dioxide having an average particle size of 5 to 100 nm, Zinc oxide having an average particle size of 5 to 300 nm, iron oxide having an average particle size of 5 to 300 nm, or the like can be used.

The thickening agent is a cosmetic composition for imparting an appropriate viscosity when used to enhance the feeling of use, and it is a kind selected from the group consisting of carbomer, carbol, gelatin, xanthan gum, natural cellulose, high cell, methyl cellulose, Lt; / RTI >

[Example]

Hereinafter, preferred embodiments of the present invention will be described in order to facilitate understanding of the present invention. However, the following examples are provided to further understand the present invention, and the present invention is not limited by the examples.

EXAMPLES AND COMPARATIVE EXAMPLES Preparation of water-in-oil (W / O) or oil-in-water (O / W)

Cosmetic compositions were prepared according to the following methods with the compositions shown in Tables 1 and 2 below. First, the composition of the oil phase 1 and 2 was metered in the mixer, and then the oil phase was prepared by uniformly mixing at 75 ° C. To this was added uniformly mixed water phase at 75 DEG C, and the mixture was homogeneously mixed and then cooled to prepare a water-in-oil (W / O) type emulsified composition. At this time, Comparative Example 2 and Comparative Example 3 were prepared by adding an oily portion to an aqueous phase as an oil-in-water (O / W) emulsified composition.

In the following Tables 1 and 2, titanium dioxide, CI 77491, CI 77492, CI 77499, triethoxycaprylyl silane, mica and ultramarine were mixed and used as a mixed powder.

Content (% by weight) Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Top part 1 Cetyl PEG / PPG-10/1 Dimethicone 2.5 2.5 2.5 2.5 2.5 2.5 Phenyl trimecicone 2.0 2.0 2.0 2.0 2.0 2.0 Cyclopentasiloxane, cyclohexasiloxane 7.1 7.1 7.1 7.1 7.1 7.1 Dimethicone 10.0 10.0 10.0 10.0 10.0 10.0 Talc 2.0 2.0 2.0 2.0 2.0 2.0 Silica dimethyl silylate 0.5 0.5 0.5 0.5 0.5 0.5 Microcrystalline wax 1.0 1.0 1.0 1.0 1.0 1.0 Top part 2 Mixed powder 4.6 4.6 4.6 4.6 4.6 4.6 Silica dimethysilylate 0.2 0.2 0.2 0.2 0.2 0.2 Cetyl ethyl hexanoate 5.0 5.0 5.0 5.0 5.0 5.0 Water top glycerin 15.0 15.0 15.0 15.0 15.0 15.0 Polyglyceryl-4-caprate 6.0 4.0 10.0 - - - Polyglyceryl-2 caprate - - - 6.0 - - Polyglyceryl-3-caprylate - - - - 6.0 - Polyglyceryl-6 behenate - - - - - 6.0 Polysorbate 20 - - - - - - lecithin - - - - - - Propylene glycol
Monostearate - - - - - - Sodium chloride 1.0 1.0 1.0 1.0 1.0 1.0 Purified water 42.60 44.60 38.60 42.60 42.60 42.60 additive Chlorphenazine 0.2 0.2 0.2 0.2 0.2 0.2 Phenoxyethanol 0.3 0.3 0.3 0.3 0.3 0.3

Content (% by weight) Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Comparative Example 6 Top part 1 Cetyl PEG / PPG-10/1 Dimethicone 2.5 2.5 2.5 2.5 2.5 2.5 Phenyl trimecicone 2.0 2.0 2.0 2.0 2.0 2.0 Cyclopentasiloxane, cyclohexasiloxane 7.1 7.1 7.1 7.1 7.1 7.1 Dimethicone 10.0 10.0 10.0 10.0 10.0 10.0 Talc 2.0 2.0 2.0 2.0 2.0 2.0 Silica dimethyl silylate 0.5 0.5 0.5 0.5 0.5 0.5 Microcrystalline wax 1.0 1.0 1.0 1.0 1.0 1.0 Top part 2 Mixed powder 4.6 4.6 4.6 4.6 4.6 4.6 Silica dimethysilylate 0.2 0.2 0.2 0.2 0.2 0.2 Cetyl ethyl hexanoate 5.0 5.0 5.0 5.0 5.0 5.0 Water top glycerin 15.0 15.0 15.0 15.0 15.0 15.0 Polyglyceryl-4-caprate - - 6.0 - - 2.0 Polyglyceryl-2 caprate - - - - - - Polyglyceryl-3-caprylate - - - - - - Polyglyceryl-6 behenate - - - - - - Polysorbate 20 - 6.0 - - - - lecithin - - - 6.0 - - Propylene glycol
Monostearate - - - - 6.0 - Sodium chloride 1.0 1.0 1.0 1.0 1.0 1.0 Purified water 48.60 42.60 42.60 42.60 42.60 42.60 additive Chlorphenazine 0.2 0.2 0.2 0.2 0.2 0.2 Phenoxyethanol 0.3 0.3 0.3 0.3 0.3 0.3

(Experimental Example 1) Cleaning power test

In order to confirm the detergency of the compositions of Examples 1 to 6 and Comparative Examples 1 to 5 according to the temperature, each of the compositions was applied to the hands and washed in water at 25 ° C and 40 ° C. The results of the presence or absence of water are shown in Table 3 below. At this time, if the remnant of the make-up remains almost "○", if it remains a little, it is marked "Δ", and when it is almost not, it is marked "×".

division 25 ℃ 45 ° C Example 1 ○ × Example 2 ○ × Example 3 ○ × Example 4 ○ × Example 5 ○ × Example 6 ○ × Comparative Example 1 ○ ○ Comparative Example 2 × × Comparative Example 3 - - Comparative Example 4 ○ ○ Comparative Example 5 ○ ○ Comparative Example 6 ○ ○

As shown in Table 3, when the surfactant according to the present invention was used in a specific amount, water resistance was maintained at room temperature, and it was clearly removed in hot water.

In contrast, when the type of surfactant is different (Comparative Examples 2, 4 and 5), and the unused or less used (Comparative Examples 1 and 6), the makeup applied to the back of the hand remains in the hot water and further cleansing is required . In the case of Comparative Example 3, an O / W emulsion composition was prepared.

Specifically, FIG. 1 is a photograph showing the cleaning power according to temperature after application of the composition of Example 1, FIG. 2 shows the composition of Comparative Example 1, and FIG. 3 shows the composition of Comparative Example 2.

1, the composition of Example 1 according to the present invention maintains the makeup state at room temperature of 25 ° C, but it can be seen that even if it is washed with water at 40 ° C, it is cleanly washed away with the naked eye.

In contrast, in the case of Comparative Example 1 in which the surfactant is not present in the present invention, the makeup state remained unchanged. In addition, in the case of the composition of Comparative Example 2, which is O / W instead of W / O of the present invention, it was confirmed that the make-up was almost erased at 40 ° C, but it was easily erased even at 25 ° C, which is required to maintain water resistance.

(Experimental Example 2) Dispersion stability test

The stability of the compositions prepared in the above Examples and Comparative Examples was measured. Each composition was visually observed for 4 weeks at 25 ° C., 5 ° C., cycle, and 45 ° C. oven, respectively, to confirm whether layer separation and precipitation occurred. In this case, 'cycle' means a condition that circulates at 0 ° C, 25 ° C, 35 ° C and 45 ° C for 6 hours, respectively. The results are shown in Table 4. (?: Stable,?: Slightly separated or precipitated, X: separated or precipitated)

Immediately after manufacture Stability (4 weeks) 25 ℃ 5 ℃ cycle Example 1 ○ ○ ○ ○ Example 2 ○ ○ ○ ○ Example 3 ○ ○ ○ ○ Example 4 ○ ○ ○ ○ Example 5 ○ ○ ○ ○ Example 6 ○ ○ ○ ○ Comparative Example 1 ○ △ △ △ Comparative Example 2 ○ ○ △ X Comparative Example 5 ○ △ △ △ Comparative Example 6 ○ ○ ○ ○

As shown in Table 4, the composition prepared according to the present invention was stable even when the temperature was changed.

In comparison, the compositions of Comparative Examples 1, 2 and 5 exhibited poor dispersion stability, resulting in layer separation. In the case of Comparative Example 6, although the stability was excellent, there was no effect on the change of cleaning force depending on the temperature as shown in Table 3, and the effect to be obtained in the present invention can not be sufficiently secured.

The composition according to the present invention can be made into various makeup cosmetic products to satisfy consumers.

Claims (5)

1. A makeup cosmetic composition for oil-in-water type emulsion comprising an aqueous phase and an oil phase,
Wherein the water-soluble part comprises a polyglyceryl fatty acid ester-based surfactant so as to be easily removed from hot water. The water-in-oil type makeup cosmetic composition according to claim 1, wherein the polyglyceryl ester nonionic surfactant comprises 3 to 10% by weight in the total composition. The polyglyceryl ester nonionic surfactant according to claim 1, wherein the polyglyceryl ester nonionic surfactant is polyglyceryl-4 caprylate / caprate, polyglyceryl-5 caprylate / caprate, polyglyceryl-6 caprylate / Polyglyceryl-9 caprylate / caprate, polyglyceryl-8 caprylate / caprate, polyglyceryl-9 caprylate / caprate, polyglyceryl-10 caprylate / caprate Polyglyceryl-5 caprate, polyglyceryl-6 caprate, polyglyceryl-7 caprate, polyglyceryl-8 caprate, polyglyceryl-9 caprate, poly Polyglyceryl-5 laurate, polyglyceryl-6 laurate, polyglyceryl-7 laurate, polyglyceryl-8 laurate, polyglyceryl -9 laurate, polyglyle Polyglyceryl-10 cocoate, polyglyceryl-8 cocoate, polyglyceryl-10 cocoate, polyglyceryl-10 cocoate, polyglyceryl-8 cocoate, Polyglyceryl-8 myristate, polyglyceryl-9 myristate, polyglyceryl-10 myristate, polyglyceryl-6 myristate, polyglyceryl- State, polyglyceryl-11 myristate, polyglyceryl-12 myristate, polyglyceryl-10 oleate, polyglyceryl-11 oleate, polyglyceryl-12 oleate, polyglyceryl-10 stearate, Polyglyceryl-6 stearate, polyglyceryl-11 stearate, polyglyceryl-12 stearate, polyglyceryl-6 behenate, and combinations thereof. A topical cosmetic composition. The makeup cosmetic composition according to claim 1, wherein the water-in-oil type makeup cosmetic composition comprises an oil phase part comprising 5.0 to 50.0% by weight of an oil and 0.1 to 10% by weight of a stabilizer, 1 to 20% 3 to 10% by weight of a polyglyceryl fatty acid ester surfactant, and a water phase containing water as a remainder. The cosmetic composition according to claim 1, wherein the water-in-oil type makeup cosmetic composition is at least one selected from the group consisting of sunscreen, makeup base, foundation, babe cream, concealer, lipstick, lipgloss, lip liner, powder, two-way cake, primer, An eye liner, an eye mascara, a hair gel, or a hair mascara.

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