KR20140074980A

KR20140074980A - Coated steel material with excellent laser cuttability, primary rust prevention performance, and legibility

Info

Publication number: KR20140074980A
Application number: KR1020147011943A
Authority: KR
Inventors: 츠토무 고모리; 이사무 가게; 카즈히코 시오타니
Original assignee: 제이에프이 스틸 가부시키가이샤
Priority date: 2011-10-31
Filing date: 2012-06-01
Publication date: 2014-06-18
Also published as: IN2014KN00765A; CN104023972A; WO2013065349A1; KR101568775B1; CN104023972B

Abstract

Provided is a coated steel which combines excellent laser cutting property and primary rustproofing property and is excellent in visibility, in particular, visibility of characters written in white paint. More specifically, it is preferable that the surface of the steel contains, as a dry coating film, a colored pigment comprising titania powder, zinc powder, aluminum powder, black iron oxide pigment and black colored pigment, wherein the content of the titania powder is Wherein the content of the zinc powder is 5 g / m 2 or more and 30 g / m 2 or less, the content of the aluminum powder is 0.1 g / m 2 or more and 10 g / m 2 or less, and the content of the titania powder is Ag / The value of Y represented by the following formula (1) is 0.010 or more when the content of the zinc powder is Bg / m2, the content of the aluminum powder is Cg / m2, and the content of the colored pigment is Xg / 0.200 or less and the brightness of distant cell values on the surface of the dried coating film is 7.0 or less.
group
Y = X / (A + B + C) ... (One)

Description

TECHNICAL FIELD [0001] The present invention relates to a coated steel material excellent in laser cutting property, primary rust prevention property and visibility,

The present invention relates to a painted steel which has excellent laser cutting performance and primary rust prevention performance and is also excellent in visibility of characters written in legibility, will be.

Fabricators such as ships, bridges and construction machines have high dimensional precision (± 0.5 mm) and an influence of heat on the members. The use of laser cutting as a cutting method of a thick steel sheet is increasing because of the advantages such as a relatively low cost and a relatively easy automation of a no human interface. However, the laser cutting has a problem that the cutting speed is slower than the plasma cutting, and the cuttable plate thickness is limited compared to the gas cutting.

Further, there is a problem that the upper limit of the laser cutting speed and the cuttable plate thickness is lowered by the primer as the primary rust prevention treatment performed in the fabricator. This mechanism is not clear, and it is in fact the fact that each fabricator deals with it based on empirical methods. One of them is a pretreatment referred to as preliminary baking in the fabricator and a prior irradiation of a low output laser to the painted film of the cuts is performed have. This preprocessing improves the laser cutting property. However, since laser irradiation is required twice along the actual cutting line, the loss is great both in terms of process energy and input energy. Therefore, the economic loss is also large. Therefore, there is a high demand for pretreatment for improving laser cuttability without performing two laser irradiation like the preceding baking, and many proposals have been made so far.

For example, Patent Document 1 discloses a technique for improving the laser cuttability by restricting the amount of Zn in the coating film added as a rust preventive agent, considering that Zn contained in the coating film (primer layer) adversely affects the laser cutting property Has been proposed. However, since Zn is an effective element for rust prevention, the rust inhibition of the coating film is deteriorated by restricting the amount of Zn. However, Patent Document 1 does not disclose a method for compensating for the deterioration of rust resistance by restricting the amount of Zn in the coating film.

On the other hand, with respect to a technique for improving the rust prevention property of a coating film, Patent Document 2 discloses a technique for coating a high corrosion resistant paint using mixed powder of Zn: 65 to 85 wt% and Al: 3 to 15 wt% A technique of improving corrosion resistance (heat resistance) and heat resistance of a coating film has been proposed. However, in the technique proposed in Patent Document 2, no consideration is given to laser cutting property. And, as shown in the embodiment, in the technique proposed in Patent Document 2, the film thickness at the time of coating is set to be as thick as 75 占 퐉 in order to ensure high corrosion resistance. Therefore, since the amount of (Zn + Al) contained in the coating film increases in association with the increase in the film thickness, the laser cutting property can be considered to be low.

Patent Document 3 proposes a technique for improving the corrosion resistance of a coated metal plate by using a high corrosion-resistant paint made of Zn-Al-Mg alloy powder. However, in the technique proposed in Patent Document 3, since Zn, Al and Mg are alloyed and powdered, the cost of coating materials is lower than that in the case of using a single Zn powder or Al powder Rise. Also, in the technique proposed in Patent Document 3, no consideration is given to the laser cutting property. And, as shown in the embodiment, in the technique proposed in Patent Document 3, the film thickness at the time of coating is set to be as thick as 60 占 퐉 in order to ensure high corrosion resistance. Therefore, as in the case of the technique proposed in Patent Document 2, since the amount of (Zn + Al) contained in the coating film increases, the laser cutting property can be considered to be low.

With respect to these techniques, Patent Document 4 proposes a technique of adding titania powder to a primer in addition to zinc powder and aluminum powder. According to the technique proposed in Patent Document 4, the content of titania powder, zinc powder and aluminum powder contained in the primer is optimized so that the laser cuttability and primary rust prevention property of the coated steel are improved. However, in the technique proposed in Patent Document 4, it is difficult to discriminate the characters of the manufacturing symbol using the white paint generally used to clarify the history of the steel by the whitening of the primer surface by including white titania powder .

Japanese Patent Application Laid-Open No. 10-226846 Japanese Patent Application Laid-Open No. 59-221361 Japanese Patent Application Laid-Open No. 2001-164194 Japanese Patent Publication No. 4449938 (Japanese Unexamined Patent Application Publication No. 2007-290129)

As described above, in the technique proposed in Patent Document 1, there is no countermeasure against the deterioration of the rustproofing performance accompanied by the decrease in the amount of Zn in the coating film, and there is a possibility that the rustproofing property is significantly lowered by limiting the amount of Zn. In addition, in the technologies proposed in Patent Documents 2 and 3, the laser cutting property is not considered, and the amount of (Zn + Al) contained in the coating film which can be estimated from the thickness of the coating film is large and the laser cutting property is inferior I can think.

In the technique proposed in Patent Document 4, a coated steel material excellent in laser cutting property and primary rust prevention property can be obtained, but in the actual manufacturing process, the surface of the developed steel is whitened, and the history of the steel material is clarified There is a problem in that it is difficult to discriminate characters such as a manufacturing symbol by a commonly used white paint. In Patent Document 4, although there is a description (description) that a coloring pigment may be added, there is no description of the characteristics of the coloring pigment to be added and the addition amount thereof. Therefore, there has been a problem that the laser cutting property is lowered depending on the kind of the selected coloring pigment.

In fact, in the field of manufacturing or processing steel, in order to discriminate the kind and history of the steel, letters and symbols are generally printed on the surface of the steel with a white paint, and the visibility of the letters and symbols is important Function.

SUMMARY OF THE INVENTION The present invention has been made in view of the above circumstances and provides a coated steel material having a coating film having high laser cutting property and excellent rustproofing property when cut by a laser and having excellent visibility, .

In order to solve the above problems, the inventors of the present invention have found that, in the technique proposed in Patent Document 4, various factors that affect the visibility, in particular, the visibility of characters indicating the production numbers of steel materials to be printed on the surface of painted steel, Review. As a result, it has been considered to adopt a brightness of a Munsell value as an index necessary for increasing the visibility of the coating film surface formed on the surface of the steel material. Further, by including a color pigment having a lightness value of a distant cell value of 7.0 or less on the surface of the coating film in addition to the technique proposed in Patent Document 4, that is, the coating film containing titania powder, zinc powder and aluminum powder, I have come to realize that this is dramatically improved.

In order to reduce the distant cell value, it is necessary to add a black pigment to the coating film. However, in a system (graphite) added with graphite, which is generally known as a black pigment for a paint, there was. Further, as a result of studying various black pigments, it was found that only a certain kind of pigment can prevent the laser cuttability from being disturbed and make the distant cell value on the surface of the dried coating film be 7.0 or less. This is not a problem at all in ordinary paints and coatings (or primers), and is a problem inherent to a coating film (primer) used to improve the laser cutting property (as proposed in Patent Document 4) to be. Further, it has been found that it is possible to improve the visibility (visibility of characters written in white paint) with a white pigment without damaging the laser cutting property and the primary rustproofing property of the steel by optimizing the content of the color pigment in the coating film. Further, it is found that an appropriate range of the content of the coloring pigment can be obtained by satisfying the desired formula for specifying the amount of the coloring component (coloring pigment) relative to the amount of the added component (titania powder, zinc powder, aluminum powder) in the coating film component .

The present invention has been completed on the basis of the above-described recognition, and its gist is as follows. [1] A process for producing a coloring pigment comprising, on a surface of a steel material, a titania powder, a zinc powder, an aluminum powder, and a color pigment comprising one or more of iron oxide black pigment and calcined black pigment M 2 or more and 26 g / m 2 or less, the content of the zinc powder is 5 g / m 2 or more and 30 g / m 2 or less, the content of the aluminum powder is 0.1 g / m 2 or more and 10 g / , The content of the titania powder is Ag / m2, the content of the zinc powder is Bg / m2, the content of the aluminum powder is Cg / m2, and the content of the colored pigment is Xg / m2. 1) of not less than 0.010 and not more than 0.200 and a brightness value of a distant cell value on the surface of the dried coating film is not more than 7.0, characterized by having a coating film excellent in laser cutting property, primary rust prevention property and visibility ashes.

group

Y = X / (A + B + C) ... (One)

[2] The honeycomb structure according to item [1], wherein the content of the titania powder is 8.0 g / m 2 or more and 18 g / m 2 or less, the content of the zinc powder is 13 g / Or more and 1.5 g / m 2 or less, the content of the colored pigment is 1.0 g / m 2 or more and 5.0 g / m 2 or less, and the value of Y represented by the formula (1) is 0.030 or more and 0.200 or less. And a coated steel excellent in visibility.

[3] The coating film according to any one of [1] to [2], wherein the dry film further contains one or more elements selected from the group consisting of Mo, W, Ni, Cu, Mg, V, Co, , W, Ni, Cu, P, Mg, V, Co, Sn, and Sb, and the total content of the elements of the elements and / M 2 or more and 5 g / m 2 or less, and is excellent in laser cutting property, primary rust prevention property and visibility.

According to the present invention, it is possible to provide a colored pigment (black iron oxide pigment, one kind of black color pigment) containing a titania powder, a zinc powder and an aluminum powder each having a high laser absorptivity, Or a colored pigment composed of two or more kinds), it is possible to obtain a coated steel having good laser cutting property and rustproofing property and excellent visibility, in particular, visibility of characters written in white paint.

1A is a photograph showing a character on a painted steel plate in a case where an evaluation of visibility in a painted steel sheet of the present invention (coated steel No. 2) is as follows:
Fig. 1B is a photograph showing the characters on the coated steel sheet in the case where characters can not be discriminated and read unless the evaluation of visibility in the coated steel sheet of the comparative example (coated steel No. 22) is approached to x: 2 m away.

(Mode for carrying out the invention)

Hereinafter, the present invention will be described in detail.

The coated steel material of the present invention is characterized in that the surface of the steel material contains a titania powder, a zinc powder, an aluminum powder, and a colored pigment composed of at least one of a black iron oxide pigment and a black calcined pigment, M 2 or more and 26 g / m 2 or less, the content of the zinc powder is 5 g / m 2 or more and 30 g / m 2 or less, the content of the aluminum powder is 0.1 g / m 2 or more and 10 g / (1), when the content of the zinc powder is Bg / m 2, the content of the aluminum powder is Cg / m 2, and the content of the colored pigment is X g / Of not less than 0.010 and not more than 0.200 and a brightness value of a distant cell value on the surface of the dry film is 7.0 or less.

group

Y = X / (A + B + C) ... (One)

Here, the " brightness of distant cell value " is an index indicating the degree of brightness of color in the color display method specified in JIS Z 8721 (1993). Black to gray to white, ideal black to zero and ideal white to 10, with the difference between the lightness and the lightness being approximately equal.

Generally, a steel material coated with a zinc (Zn) rich primer or a zinc primer as a primary rust prevention treatment is applied to a surface of a shot blasted steel It is known that when the laser is cut, the cutting speed is lowered. The mechanism of the reduction of the laser cutting speed at this time is not necessarily clarified. However, by the formation of the coating film (primer painting) performed as the primary rustproofing treatment, the coating film (primary rust (2) the decomposition or evaporation of binder resin or zinc powder in the coating film (primary rust inhibitor) by heating during laser cutting; and (2) (3) scattering and absorption of laser light by vaporization, and (3) reduction of the partial pressure of assist gas (oxygen) caused by the generated gas. .

Therefore, in the present invention, the problem of the above (1) is solved by increasing the absorption rate of laser by adding titania (TiO ₂ ) powder having a high laser absorptivity into the coated film of the coated steel to improve the laser cutting property.

At the beginning of the laser cutting process, the laser light is condensed on the cut portion, the light energy is absorbed, and the temperature of the cut portion is locally increased and melted. At this time, when the cut portion is covered with the coating film containing the titania powder having a high laser absorbing property, the light energy is efficiently absorbed by the coating film, so that the laser cutting efficiency can be increased.

The titania powder has a very high laser absorptivity and an effect of efficiently discharging the molten slag from the cut groove. Therefore, by the addition of the titania powder, the viscosity of the molten slag generated at the time of laser cutting is lowered, and the molten slag is efficiently discharged from the inside of the cut groove, thereby improving the cut surface smoothness and improving the dross dross may be inhibited.

Further, since the titania powder is easily available and relatively inexpensive, the present invention using the titania powder is advantageous in terms of stable production and cost.

To effectively exhibit such effects, in the present invention, the content of the titania powder contained in the coating film (dry coating film) of the coated steel is set in the range of 4.5 g / m 2 to 26 g / m 2. When the content of the titania powder is less than 4.5 g / m 2, the effect of improving the laser cutting property is small. On the other hand, if the content of the titania powder exceeds 26 g / m 2, the formation of a uniform coating film is inhibited, which may hinder the improvement of rust-preventive properties. Therefore, the content of the titania powder should be not less than 4.5 g / m 2 and not more than 26 g / m 2. Preferably, it is 8.0 g / m 2 or more and 18 g / m 2 or less.

In addition, the zinc (Zn) powder is a component that is extremely effective in improving the primary rust prevention property, and is a component that causes the above-mentioned problems (2) and (3). Here, for the purpose of eliminating the above-mentioned problems (2) and (3), if the amount of the zinc powder contained in the coating film is decreased, the primary rustproofing property is deteriorated and a new problem arises. Therefore, in the present invention, aluminum (Al) powder having an effect of suppressing the zinc powder content in the coating film and improving the primary rustproofing property is added.

Even when the aluminum powder is contained in the coating film, they are decomposed and evaporated at the time of laser cutting so that the laser cutting property is not adversely affected. Therefore, by adding aluminum powder together with the zinc powder to the coating film, primary rustproofing is ensured without causing the problems of (2) and (3).

From the viewpoint of securing laser cutting property and rust prevention property, it is preferable that the content of the zinc powder contained in the coating film (dry coating film) is 5 g / m 2 or more and 30 g / m 2 or less. When the content of the zinc powder is less than 5 g / m 2, even if aluminum powder is added, the corrosion resistance of the coated steel may be insufficient. On the other hand, when the content of the zinc powder exceeds 30 g / m 2, there is a possibility that the laser cutting property becomes insufficient even when the titania powder is added. Therefore, the content of the zinc powder is 5 g / m 2 or more and 30 g / m 2 or less. And preferably not less than 13 g / m 2 and not more than 27 g / m 2.

The aluminum powder is added for the purpose of suppressing the deterioration of the rust-preventive property due to the reduction of the added amount of the zinc powder. When the content of the aluminum powder contained in the coating film (dry film) is less than 0.1 g / m 2, There is a fear that it is not expressed. On the other hand, when the content of the aluminum powder is more than 10 g / m 2, the formation of a uniform coating film is inhibited and the rust prevention property may be lowered. Therefore, the content of the aluminum powder should be 0.1 g / m 2 or more and 10 g / m 2 or less. And preferably not less than 0.5 g / m 2 and not more than 1.5 g / m 2.

As described above, in the present invention, a coated steel having high laser cutting property and excellent rustproofing property can be obtained. However, in this state, since the surface of the coating film (dry film surface) is whitened due to the addition of the titania powder, it is difficult to discriminate the characters of the manufacturing symbols using the white paint generally used for clarifying the history of the steel . As a result of measuring the brightness of the surface of the coated steel material having the whitened coating film obtained as described above, it was confirmed that the brightness of the distant cell value was about 7.5.

Therefore, the inventors of the present invention have studied the distant cell value of the surface of the steel material so that the characters used as a white paint can be easily discriminated by the naked eye, and as a result, it has been found that the value should be 7.0 or less. For the above reasons, in the present invention, the coating film formed on the steel material is made to be a coating film containing a colored pigment which makes the brightness of distant cells of the surface of the coating film 7.0 or less, in addition to titania powder, zinc powder and aluminum powder.

When the brightness of the distant cell value is set to 7.0 or less as described above, the coating film surface (coated steel surface) having a tone of gray system equivalent to that of the coating film formed of a commonly used zinc (Zn) rich primer or zinc primer, Furthermore, even when a character of the manufacturing symbol is affixed to the surface of the coated steel material using a white paint, the character can be easily distinguished. From the viewpoint of visibility, the brightness of the distant cell value is preferably 6.3 or less, and more preferably 5.8 or less. However, when the distant cell value is less than 5.0, it is inevitable to reduce the content of white titania powder among components constituting the coating film, and the laser cuttability is deteriorated as the content of the titania powder is reduced I am concerned. Therefore, it is preferable that the distant cell value has a brightness of not less than 5.0 and not more than 7.0. Further, it is more preferably 5.5 or more and 6.5 or less.

In the present invention, the black colored pigment used for setting the brightness of distant cells on the surface of the dried coating film to 7.0 or less is limited to a specific kind as described above. According to the recognition of the present inventors, when a colored pigment containing carbon as a main component such as carbon black, black lead, or black organic pigment added as a black pigment in a paint is used , The laser cutting property of the coated steel material tends to be lowered. This is because, when a color pigment contained in carbon as a main component is contained in a coating film, a CO gas / CO ₂ gas is generated in an oxidation reaction during laser cutting and the oxygen partial pressure of the cut portion is lowered It is presumed that the cutting ability is lowered. Therefore, carbon black, graphite, black organic pigments and the like are not suitable for the colored pigments used in the present invention, and it is necessary to use black iron oxide pigments or black calcined pigments in the present invention. The black iron oxide pigments and the black calcined pigments are sometimes referred to as composite oxide pigments. Examples thereof include Fe ₃ O ₄ , Fe-Cr, Fe-Cr-Ni-Mn, Co-Fe- -Mn system, and the like. However, the present invention is not limited to these, and any inorganic main constituent substantially free from carbon and organic matter can be used.

As described above, in the present invention, the coating film formed on the steel material is made to be a coating film containing a coloring pigment which, in addition to the titania powder, the zinc powder and the aluminum powder, makes the brightness of distant- It is possible to obtain a coated steel excellent in laser cutting property and rustproofing property and also having visibility, particularly visibility of characters written in white paint.

The addition amount of the coloring pigment is such that when the titania powder contained in the coating film (dry film) is Ag / m 2, the zinc powder is Bg / m 2, the aluminum powder is Cg / m 2 and the coloring pigment is X g / 1) The value of Y represented by the formula Y = X / (A + B + C) is 0.010 or more and 0.200 or less. When the ratio of the total content of titania powder, zinc powder and alumina powder, which is a white-based substance contained in the coating film (dry film), to the content of the coloring pigment is 0.010 or more, the brightness of the distant cell value becomes 7.0 or less , Visibility is improved. Preferably 0.030 or more.

On the other hand, when the value of Y is more than 0.200, there is a case where the laser cutting property is deteriorated or the occurrence of red rust due to black iron oxide being a color pigment in the corrosion resistance evaluation is visually observed. Although the cause of these is not clear, it is presumed that the ratio of the presence of titania having a high laser absorbing property on the surface of the coated steel is lowered. Further, when the value of Y is more than 0.200, the corrosion resistance (rust prevention property) may deteriorate. Therefore, the value of Y is set to 0.200 or less. And preferably 0.100 or less.

If the coloring pigment is added in an amount of 1.0 g / m 2 or more, the visibility of the steel sheet when a character or the like is described with a white paint is further improved. On the other hand, if the addition exceeds 5.0 g / m 2, adverse effects on corrosion resistance and laser cutting property , It is preferable that the content of the coloring pigment contained in the coating film (dry film) is 1.0 g / m 2 or more and 5.0 g / m 2 or less, and the value of Y represented by the formula (1) is 0.030 or more and 0.200 or less .

In the present invention, it is preferable that the dried coating film contains a predetermined amount of at least one element selected from the group consisting of Mo, W, Ni, Cu, P, Mg, V, Co, Sn and Sb. The corrosion resistance is further improved by adding elements such as Mo, W, Ni, Cu, P, Mg, V, Co, Sn and Sb alone or in combination to the coating film. The reason why the corrosion resistance is further improved as described above is not clear. However, when these elements are added to the coating film, a dense corrosion product or a stable complex oxide is formed, or when the element is dispersed in the rust It is presumed that an inhibitory effect of erosion progression is obtained due to the reason such as inhibiting the intrusion of Cl ion which becomes oxoacid ion to cause corrosion and the like.

One or more elements of Mo, W, Ni, Cu, Mg, V, Co, Sn, and Sb can be contained in the coating film as a single substance or as a compound. The P element can be contained as a compound. In addition, as a result of the experiment, when the total content of these elements is less than 0.01 g / m 2 in terms of the element, the above-mentioned effect may not be sufficiently exhibited. On the other hand, when the total content exceeds 5 g / And cracking properties may be deteriorated in some cases. Therefore, it is preferable that at least one element of Mo, W, Ni, Cu, P, Mg, V, Co, Sn and Sb is 0.01 g / m 2 or more and 5 g / m 2 or less in terms of the element. Further, it is more preferable to be not less than 0.1 g / m 2 and not more than 4 g / m 2.

As a particularly suitable example, the coating film is made of an alkylsilicate-based binder resin.

In this manner, the effect of suppressing lowering of the laser cuttability is very high, and the primary rustproofing property can be kept very good, and also the visibility of characters written with a white paint can be improved.

As described above, the coating film of the present invention including the titania powder having a high laser absorbing property is superior in the coating film of the zinc powder and the conventional coating film in which aluminum powder is added to the zinc powder. In the process of laser cutting, Is an essentially different coating in that it has the added function of efficiently absorbing energy and facilitating the discharge of melted slag. In the present invention, since the coating film contains the titania powder having a high laser absorbing property, even if the coating film contains zinc powder adversely affecting the laser cutting property, if the content thereof is reduced to a predetermined amount, It is possible to efficiently absorb the light energy of the laser light and to obtain the coated steel having excellent laser cutting property.

Further, the aluminum powder, Mo, W, Ni, Cu, P, Mg, V, Co, Sn and Sb have an effect of enhancing the corrosion resistance without adversely affecting the laser cutting property in particular. Therefore, by adding at least one element selected from the group consisting of Mo, W, Ni, Cu, P, Mg, V, Co, Sn and Sb to the titania powder and the zinc powder, The deterioration of the corrosion resistance accompanying the reduction of the zinc powder content is suppressed and the property of excellent laser cutting property is maintained.

In view of the above, in the present invention, it is preferable that the surface of the steel material body is made of titania powder, zinc powder and aluminum powder or one or more of Mo, W, Ni, Cu, P, Mg, V, Co, (Primer) containing two or more kinds of elements as a single substance or as a compound.

In addition, any kind of colored pigment may be used in the addition of a color pigment, and in order to ensure visibility with a white pigment, a black pigment such as a black iron oxide pigment not containing carbon as a main component, And is a coloring pigment comprising a calcined pigment, which is a coating film which is different from the conventional art and which can not be deduced from the conventional art.

As the titania powder, the zinc powder and the aluminum powder, those processed by an atomization technique or a mechanical crushing technique can be used, and it is preferable that the average particle diameter is controlled to 15 탆 or less. If necessary, these powders may be surface-treated with Al, Zr, polyol or the like to improve the dispersibility in the paint. Examples of the paint additive other than the powder and the binder resin include a dispersing agent, a moistening agent, a defoaming agent, an anti-sedimentation agent, a thickener, etc., Maybe.

Each metal powder of Mo, W, Ni, Cu, Mg, V, Co, Sn and Sb can be used. As the compound of Mo, W, Ni, Cu, P, Mg, V, Co, Sn and Sb, a compound which is an ion of each element or an oxygen acid ion of each element in an aqueous solution is suitable. molybdate such as molybdic acid and sodium molybdate salt such as molybdic acid and phosphomolybdic acid and sodium phosphomolybdate and tungstophosphoric acid such as tungstic acid tungstates such as tungstic acid and tungstate, phosphotungstic acid and sodium phosphotungstate, tungstates such as sodium phosphotungstate, nickel sulfate, Nickel salts such as nickel phosphate and the like, copper salts such as copper sulfate and the like, phosphates such as phosphoric acid and calcium phosphate, magnesium nitrate ), Magnesium sulfate A cobalt salt such as a salt of vanadic acid, cobalt nitrate or cobalt sulfate such as magnesium salt or sodium vanadate, Stannum salts such as stannous oxide, stannic oxide, stannous chloride, stannous sulfate and the like, antimony trioxide, Antimony pentoxide, antimony chloride, and the like can be used.

Further, the steel material of the base of the coated steel of the present invention is not particularly limited, but is generally used for steel sheets up to about 25 mm in thickness.

An example of a method of combining the coating materials used in the coated steel material as described above and a coating method of the coating material into the steel material will be described below.

First, titania powder, zinc powder and aluminum powder are put into a paint liquid defined in JIS K 5552, and further, a predetermined color pigment is added thereto, and the mixture is sufficiently mixed and stirred by a shaker machine or the like (blended and agitated) to combine the paints. When one or more elements of Mo, W, Ni, Cu, P, Mg, V, Co, Sn and Sb are contained as a single substance or as a compound, the titania powder, the zinc powder, The element or compound of these elements is put into a powder state and put into the coating liquid. Next, the combined paint is applied to the steel sheet by an air spray painting apparatus, for example, in such a manner that the content of each of the titania powder, zinc powder, aluminum powder and colored pigment in the dried coating film Or the total amount of at least one of Mo, W, Ni, Cu, P, Mg, V, Co, Sn, and Sb to be a desired content in terms of the element. spray spraying rate and spray velocity are adjusted and sprayed to obtain a coated steel material.

It is also conceivable to adjust the viscosity of the coating material by a thinner according to an actual coating environment, for example, a room temperature at the time of coating with a steel sheet. W, Ni, Cu, P, or the like, so that the content of each of the titania powder, the zinc powder, the aluminum powder, and the coloring pigment in the coated film after drying is adjusted to a desired content, , Mg, V, Co, Sn, and Sb in such a manner that the total content of the at least one of them becomes a desired content in terms of the element, the desired coating film can be formed.

[Example]

A commercially available zinc-rich primer (consisting of an alkylsilicate-based binder resin and a coating liquid comprising a thinner and a Zn powder) corresponding to the JIS K 5552 (2002) zinc rich primer was used, and an alkylsilicate-based binder resin and a thinner Titania powder, zinc powder and aluminum powder were added to the coating liquid and mixed, and further, a color pigment was added and dispersed to prepare a coating film for coating, and the surface of the steel material was spray-coated. The coating film coating composition was prepared so that the content of titania powder, the content of zinc powder, the content of aluminum powder and the content of coloring pigment in the dried coating film after the formation of the coating film were the values shown in Table 1.

As the steel material of the foundation, SM490A grade, which is a rolled steel for welding structure, having dimensions of 200 mm x 100 mm x thickness 12 mm and subjected to a shot blast treatment was used.

Further, titania powder, zinc powder and aluminum powder were added to the coating liquid comprising an alkylsilicate-based binder resin and a thinner using the same commercially available zinc rich primer as described above, and a mixture of Mo, W, Ni, Cu, P , Mg, V, Co, Sn, and Sb are added and mixed in a powder state. Further, a coloring pigment is added and dispersed to prepare a coating film coating composition. Spray painting. As the Mo compound, sodium molybdate, sodium tungstate as the W compound, nickel sulfate as the Ni compound, copper sulfate as the Cu compound, calcium phosphate as the P compound, magnesium sulfate as the Mg compound, sodium vanadate as the V compound, cobalt sulfate , Stannous chloride was used as the Sn compound, and antimony trioxide was used as the Sb compound.

When the coating film coating material is combined, the titania powder content, the zinc powder content, the aluminum powder content, the total content (in terms of element) of the above-mentioned compounds and the above-mentioned coloring pigment content in the dried coating film are shown in Table 2 .

As the steel material of the lower part, SM490A grade rolled steel for welded structure, having dimensions of 200 mm x 100 mm x thickness 12 mm and subjected to shot blast treatment was used.

The coated steel thus obtained was evaluated for laser cutting property, rust prevention property and visibility in accordance with the following method.

The obtained various kinds of coated steel materials were subjected to a cutting property test by laser cutting. The laser cutting was carried out by using a carbon dioxide gas laser apparatus manufactured by Mitsubishi Electric Corporation manufactured by Mitsubishi Denki K.K., spraying oxygen at 0.1 MPa as an assist gas at an output of 2.1 kW, The property of the laser cut face when cut at a cutting speed of 1000 mm / min was visually observed. The evaluation criteria are as follows.

◎: A state in which the generation of a dross is almost nonexistent or extremely small and the cut surface is arranged at the best cut surface.

∘: A state in which a dross occurred in a part with a good cutting plane, but the cut plane was arranged.

DELTA: Dross occurred at 50% or more of the total extension of the cutting line, but it was completely cut.

X: A state in which a dross is formed on almost the entire surface of the cut line, and a part of the cut line is not cutable.

In addition, "drooss" refers to an adhered material in which a molten metal containing gas generated along a cutting line on the surface opposite to the laser irradiation surface at the time of cutting is cold and solidified.

The rust-preventive properties were evaluated by a salt spray test in accordance with JIS K 5552 (2002) zinc rich primer. The number of days until red rust occurred was measured by a salt spray test according to JIS K 5552 (2002) for various kinds of coated steel materials obtained. The evaluation criteria are as follows.

◎ ◎: The number of days until reding occurs is over 50 days (very good).

◎: The number of days until reding occurs is 30 days or more (excellent).

○: The number of days until the reding occurs is 18 days or more and less than 30 days (good).

X: The number of days until reding occurs is less than 18 days (bad).

The letters "B", "8", and "9" were written as white paint in the size of 8 cm × 10 cm on each of the obtained coated steel materials so that the illuminance of the surface was 300 lux, (1.2 vision) from a place 10m away, 6m away and 2m away from the place where the human readability of the text was evaluated. The evaluation criteria are as follows.

◎: When characters can be distinguished from the place 10m away.

A: It is difficult to distinguish characters from a place 10 m apart, but it is possible to distinguish characters from a place 6 m apart.

×: When characters are not distinguishable and can not be read unless approaching to the place of 2m away.

The evaluation of the three characteristics of the laser cuttability evaluation, the rustproofing evaluation and the visibility evaluation as "⊚" or "⊚" is referred to as an overall evaluation "⊚", and the three characteristic evaluations are "⊚" or " &Quot; is " o ", and that one of the above three characteristic evaluations is " x "

The evaluation results are shown in Table 1 and Table 2.

Fig. 1 to 4, 9 to 14, 17, 18, and 23 to 38 show the coating film formed on the surface of the steel sheet according to the present invention, but they are excellent in visibility of characters written in white paint, , Saline spray redness days were more than 20 days. Fig. 1A is a schematic view showing an example of the present invention. Fig. A: Evaluation of visibility in a painted steel sheet of 2 ⊚: A photograph showing characters on a painted steel plate in a case where characters can be distinguished from a place 10 m away.

On the other hand, in the case of the coated steel material No. 1 of Comparative Example, 5 to 8, 15, 16 and 19 to 22 are deviated from the scope of the present invention, and either the visibility, the laser cutting property or the corrosion resistance is insufficient. Fig. 1B is a graph showing the results of comparison between the coated steel material No. 1 and the coated steel material. Evaluation of visibility in a painted steel sheet of 22: x: Photograph showing characters on a painted steel plate in a case where characters can not be distinguished and read until a place apart by 2 m is approached. It is well known that the visibility of characters is poor as compared with the example of the present invention shown in Fig. 1A.

The coated steel excellent in laser cutting ability and primary rust prevention property of the present invention and excellent in the visibility of characters written in white paint can be widely applied to steel sheets used for shipbuilding, bridges, architecture and the like.

Claims

A method for producing a coating material, which comprises, on a surface of a steel material, a titania powder, a zinc powder, an aluminum powder, and a colored pigment composed of at least one of a black iron oxide pigment and a black iron oxide pigment as a dry coating film and the content of the titania powder is 4.5 g / Or more and 26 g / m 2 or less, the content of the zinc powder is 5 g / m 2 or more and 30 g / m 2 or less, the content of the aluminum powder is 0.1 to 10 g / m 2, the content of the titania powder is Ag / The value of Y represented by the following formula (1) is 0.010 or more and 0.200 or less when the content of the powder is Bg / m 2, the content of the aluminum powder is Cg / m 2 and the content of the colored pigment is X g / Also, a coated steel sheet having a brightness value of a distant cell value (Munsell value) of the dry film surface is 7.0 or less.
group
Y = X / (A + B + C) ... (One)

The content of the zinc powder is not less than 13 g / m 2 and not more than 27 g / m 2, the content of the aluminum powder is not less than 0.5 g / m 2 and not more than 1.5 g / m 2, the content of the titania powder is not less than 18 g / Wherein the content of the pigment is 1.0 g / m 2 or more and 5.0 g / m 2 or less, and the value of Y represented by the formula (1) is 0.030 or more and 0.200 or less.

3. The method according to claim 1 or 2,
The dry film may further contain one or more elements selected from the group consisting of Mo, W, Ni, Cu, Pb, Co, Sn and Sb, At least one element selected from the group consisting of Mg, V, Co, Sn, and Sb, wherein the total amount of the element and / or the compound of the element is 0.01 g / Painted steel.