KR20140073270A - Dishwash detergent composition having abrasives - Google Patents
Dishwash detergent composition having abrasives Download PDFInfo
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- KR20140073270A KR20140073270A KR1020120141314A KR20120141314A KR20140073270A KR 20140073270 A KR20140073270 A KR 20140073270A KR 1020120141314 A KR1020120141314 A KR 1020120141314A KR 20120141314 A KR20120141314 A KR 20120141314A KR 20140073270 A KR20140073270 A KR 20140073270A
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- abrasive
- composition
- detergent composition
- silica
- wax
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- 239000000203 mixture Substances 0.000 title claims abstract description 35
- 239000003599 detergent Substances 0.000 title claims abstract description 23
- 239000003082 abrasive agent Substances 0.000 title description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 32
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 16
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 15
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 11
- 239000000194 fatty acid Substances 0.000 claims description 11
- 229930195729 fatty acid Natural products 0.000 claims description 11
- 150000004665 fatty acids Chemical class 0.000 claims description 11
- 235000011187 glycerol Nutrition 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- 238000004140 cleaning Methods 0.000 abstract description 10
- 239000004094 surface-active agent Substances 0.000 abstract description 9
- 238000005498 polishing Methods 0.000 abstract description 7
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 238000004851 dishwashing Methods 0.000 abstract description 3
- 239000004615 ingredient Substances 0.000 abstract description 3
- 239000000344 soap Substances 0.000 abstract description 3
- 235000010216 calcium carbonate Nutrition 0.000 description 13
- 239000007788 liquid Substances 0.000 description 10
- 239000002245 particle Substances 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000011109 contamination Methods 0.000 description 4
- 239000006072 paste Substances 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 241001133760 Acoelorraphe Species 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000013618 particulate matter Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 208000002193 Pain Diseases 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- UWLPCYBIJSLGQO-UHFFFAOYSA-N dodecanoic acid;propane-1,2,3-triol Chemical compound OCC(O)CO.CCCCCCCCCCCC(O)=O UWLPCYBIJSLGQO-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 235000012041 food component Nutrition 0.000 description 1
- 239000005417 food ingredient Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- HSNNVKUBZQTSQA-UHFFFAOYSA-N hexadecanoic acid;tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCC(O)=O HSNNVKUBZQTSQA-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 235000012045 salad Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- -1 sesquicarbonates Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000606 toothpaste Substances 0.000 description 1
- 229940034610 toothpaste Drugs 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/12—Carbonates bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/14—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
본 발명은 연마제를 이용한 주방세제 조성물에 관한 것으로, 보다 상세하게는 탄산칼슘과 실리카의 효과적인 배합으로 제품의 기능성을 향상시킴과 동시에 합성계면활성제를 사용하지 않고 비누성분과 1종에 해당하는 원료 만을 사용 함으로써 인체에 안전성을 확보하는데 있다.The present invention relates to a kitchen detergent composition using an abrasive, and more particularly, to a composition for improving the functionality of a product by effectively mixing calcium carbonate and silica, and at the same time, it is possible to use only a soap component and one kind of raw material Thereby ensuring safety to the human body.
본 발명은 탄산 칼슘 및 실리카를 주 성분으로 하고, 합성계면활성제를 사용하지 않으며, 천연비누 성분이 포함되어 있는 왁스타입의 주방용 세척제 조성물에 관한 것이다. 본 발명의 주방 세척제 조성물은 스테인레스로 만들어진 조리기구나 싱크대, 범랑, 놋그릇 등의 탄 얼룩이나 찌든 때를 제거하는 것을 목적으로 한다.The present invention relates to a wax-type dishwashing detergent composition containing calcium carbonate and silica as main components and not containing a synthetic surfactant and containing a natural soap component. The kitchen detergent composition of the present invention is intended to remove stains and stains of cooking utensils made of stainless steel, sinks, floats, brassware, and the like.
스테인레스 냄비나 범랑, 가스렌지등의 제품을 오래 사용하다 보면, 오래된 기름때나, 탄 자국이 생기게 되는데 이런 오염은 기존의 일반적인 주방세제나 액상 주방세제로는 제거하기 힘들다. 이런 오염을 제거하기 위해서는 연마제가 포함되어 있는 조성물이 필요한데 ,연마제 함유 조성도 액상형태의 조성으로는 세정 효과가 떨어지기 때문에, 고형이거나 왁스상태의 조성물이 필요하며, 왁스상태의 조성이라 해도, 여러가지 유해한 공업용 성분을 사용한 다목적세정제 조성물로 제공되는 경우가 많기 때문에 대부분의 경우에는 인체에 대한 안전성이 떨어지는 단점이 있다. 본 발명은 인체에 보다 안전하면서도 세정력이 뛰어난 찌든때 제거용 주방 세척제 조성물을 개발하는데 그 목적이 있다.If you use stainless steel pots, gas stoves, or other products for a long time, you will get old grease and burn marks. Such contamination is difficult to remove with conventional general kitchen detergent or liquid kitchen detergent. In order to remove such contamination, a composition containing an abrasive is required. Since the cleaning effect is deteriorated by the composition of the abrasive in liquid form, a composition of solid or wax is required. Even in the composition of wax, Since it is often provided as a multi-purpose detergent composition using harmful industrial components, there is a disadvantage that the safety against the human body is poor in most cases. It is an object of the present invention to develop a kitchen detergent composition which is more safe for human body and has excellent detergency and is capable of removing stains.
연마제의 선택은 연마 작용의 정도, 긁힘 방지, 제품의 제형에 중요한 역할을 하게 된다. 연마 작용 정도는 연마제의 양, 연마제를 구성하는 입자의 평균 입도 및 입도 분포, 그리고 사용되는 연마제의 모오스 경도에 의해 결정된다. 적당한 입자 싸이즈와 모오스 경도를 가진 물질을 선택하는 것이 찌든때는 손 쉽게 세정하면서 주방기기들의 긁힘을 방지하는데 큰 역할을 하게 된다. 또한 연마제의 양에 따라 제품의 경도에 영향을 주므로 제품 사용시 편리함을 위해서 적합한 연마제의 양이 필요하다.The selection of the abrasive agent plays an important role in the degree of polishing action, scratch prevention, and formulation of the product. The degree of polishing action is determined by the amount of the abrasive, the average particle size and particle size distribution of the particles constituting the abrasive, and the Mohs hardness of the abrasive used. Choosing materials with moderate particle size and Mohs hardness will play a big role in preventing scratching of kitchen appliances while cleaning them easily. Also, since the amount of abrasive influences the hardness of the product, the amount of abrasive suitable for the convenience of use of the product is required.
연마제를 포함한 세정제는 그 제형의 형태에 따라 연마제의 함유량도 다르고, 세정력도 차이가 난다. 미합중국 특허(US-A) WP 4179414호(모빌 오일 코포레이션)는 중탄산나트륨 50~60중량%와 물 50~35중량%, 염화나트륨 및 디에탄올아미드를 함유하고 있는 페이스트 타입을 개시하고 있다. 미합중국 특허(US-A) 제426466호(프록터 앤드 갬블 캄파니)는 액체상과 분산된 고체상으로된 액체 반죽(mull)을 개시하고 있는데, 이것은 비이온계 액체 계면활성제 30~95%, 상기 액체상에 불용성인 분산된 입자상 물질 1~6중량%, 사슬구조의 형태의 점토 및 임의의 최대 물 10중량%로 구성된다. 다수의 실시예 중에서 입자상 물질은 중탄산나트륨과 같이 빌더로서 작용할 수 있다. 미합중국 특허(US-A) 제3981826호(프록터 앤드 갬블 캄파니)는 액체 다가알콜 과 저급 일가 알코올의 수분산성 혼합물 및 염화물, 세스퀴탄산염, 황산염, 인산염, 탄산염 및 붕산염 중에서 선택되는 고체 입자상 연마제 무기염 5~60 중량%를 함유하고 수용성 무기염을 현탁시키기 위한 특정의 현탁액을 함유하는 수성 액체 연마 세정제를 제공하기 위한 것이다.The cleaning agent including the abrasive agent has a different abrasive content depending on the form of the formulation, and also has different cleaning power. United States Patent (US-A) WP 4179414 (Mobil Oil Corporation) discloses a paste type containing 50 to 60% by weight of sodium bicarbonate and 50 to 35% by weight of water, sodium chloride and diethanolamide. US-A-426466 (Procter & Gamble Campany) discloses a liquid mull with a liquid phase and a dispersed solid phase comprising 30 to 95% of a nonionic liquid surfactant, 1 to 6% by weight of dispersed particulate matter which is insoluble, 10% by weight of clay in the form of a chain structure and any maximum water. Among many embodiments, particulate matter can act as a builder, such as sodium bicarbonate. US-A-3981826 (Procter & Gamble Campany) discloses a water-dispersible mixture of a liquid polyhydric alcohol and a lower monovalent alcohol and a solid particulate abrasive weapon selected from chlorides, sesquicarbonates, sulfates, phosphates, carbonates and borates. To provide an aqueous liquid polishing detergent containing 5 to 60% by weight of a salt and containing a specific suspension for suspending a water-soluble inorganic salt.
본 발명의 목적은 연마제를 함유하는 왁스 상태의 주방용 세척제 조성물로서, 찌든때에 대한 세정력이 뛰어나면서도, 인체에 안전함을 제공하기 위하여, 합성계면활성제를 사용하지 않고, 위생용품기준 1종세적제 성분으로만 이루어진 조성물을 제공하는 것이다.It is an object of the present invention to provide a detergent composition for kitchen use in a wax state containing an abrasive, which is excellent in detergency against stinging, and which does not use a synthetic surfactant in order to provide safety to a human body, ≪ / RTI >
본 발명은 상기와 같은 종래 기술의 문제점을 해결하기 위하여 발명한 것으로, 연마제가 포함된 주방 세척제로써 주방기구의 찌든때에 효과적인 세정력을 제공하며, 위생용품 규격 1종 세척제에 해당되는 성분으로만 이루어지고, 합성계면활성제를 사용하지 않아 인체에 안전한 조성물을 제공하기 위한 것이다.The present invention has been made to solve the problems of the prior art as described above, and it is an object of the present invention to provide a kitchen cleaner containing an abrasive agent, which provides an effective cleaning force when stuck in a kitchen utensil, And a composition which is safe for human body without using a synthetic surfactant.
본 발명은 주방세척제로써 탄산칼슘과 실리카의 효과적인 입자 싸이즈의 배합과 왁스화 시키므로서 주방기구들의 찌든때에 대한 세정력을 높여주었고, 합성계면활성제를 사용하지 않고 천연지방산을 이용하므로서 인체에 안전한 조성물을 제공하였다.The present invention improves the detergency against stains of kitchen utensils by mixing and waxing the effective particle size of calcium carbonate and silica as a kitchen cleaner and it is possible to improve the cleaning ability by using natural fatty acid without using synthetic surfactant, Respectively.
본 발명으로 인체에 안전한 세척제 1종에 해당되는 원료를 이용하여, 찌든때에 대하여 다목적 세정제 수준의 세정력을 갖는 왁스상태의 주방 세척제 조성물을 가능하게 하였다.The present invention makes it possible to use a wax-like detergent composition having a detergency at the level of multi-purpose detergent at the time of grinding by using raw materials corresponding to one type of human-safe detergent.
본 발명은 탄산 칼슘 및 실리카를 주 성분으로 하는 왁스타입의 주방용 세척제의 조성물에 관한 것이다.The present invention relates to a composition of a wax-type kitchen detergent comprising calcium carbonate and silica as main components.
주방기구 찌든때를 위한 세척제는 그 형태가 액체, 페이스트, 왁스타입으로 나눌 수 있는데, 형태에 따라서 세정력도 달라지게 된다. 왁스타입의 경우 가장 많은 연마제를 포함할 수 있고, 다른 제형 대비 마찰력이 가장 높으므로 그 형태만으로 놓고 볼 때는 가장 뛰어난 세정력을 갖는다.Cleaning agents for kitchen utensils can be divided into liquid, paste, and wax types, depending on the type of detergent. The wax type may contain the most abrasive and has the highest frictional force compared to other formulations and therefore has the best detergency when viewed in its form alone.
왁스 타입의 주방용 세척제의 제형을 위해서는 기존 액체형태의 계면활성제에 많은 연마제를 포함하던지, 세제 베이스를 비누로 하는 두가지 방법이 있다. 액체형태의 계면활성제에 연마제를 적용하는 경우 왁스상태로 만들기 위해서는 고점도로 생산 및 포장이 힘들므로 본 발명에서는 C8~C18 까지의 지방산을 가지고 각각의 실험을 하였으며, 보다 안전한 세제조성물을 제공하기 위하여 합성계면활성제를 사용하지 않는 조성물을 달성하였다. 최종 제품의 경도가 높을 경우 제품 사용이 불편하고, 경도가 낮을 경우 왁스형태가 되질 않으며 사용량이 헤퍼진다. 이에 따라 사용하기 편리한 경도를 소비자 조사에 따라서 5~50수준으로 정하였고, 이에 가능 한 지방산과 그 함량을 선택하였다. There are two ways to formulate a wax-type kitchen detergent, either by including a large amount of abrasive in a conventional liquid surfactant, or by soaping a detergent base. When a polishing agent is applied to a surfactant in a liquid form, it is difficult to produce and pack in a high viscosity in order to make it into a wax state. Therefore, in the present invention, each experiment was conducted with C8 to C18 fatty acids. In order to provide a safer detergent composition, A composition without surfactant was achieved. When the hardness of the final product is high, the use of the product is inconvenient, and when the hardness is low, the wax is not formed and the usage amount is worsened. As a result, the hardness for easy use was set at 5 ~ 50 according to the consumer survey, and the possible fatty acids and their contents were selected.
본 발명의 조성물은 연마제,지방산 그리고 충진제로서 글리세린을 함유하는 것을 특징으로The composition of the present invention is characterized by containing glycerin as an abrasive, a fatty acid and a filler
하는 왁스 형태의 주방용 세척제 조성물이다.
In the form of a wax.
연마제는 두종류로 이루어진 것을 특징으로 한다. 그중의 한가지인 탄산칼슘은 국내 광산에서 쉽게 생산할 수 있고, 경도도 그리 강하지 않기 때문에 연마작용 시 경질 표면의 손상을 최소화 할 수 있어 세제 조성물 중 연마제로 가장 많이 사용되고 있다. 탄산칼슘의 입자 크기가 너무 작거나 크면 연마력이 떨어지거나 경질 표면의 손상이 발생될 수 있다. 따라서 적당한 입자 싸이즈의 배합비에 따라 사용하면 경질표면의 손상을 최소화 하면서 경질의 찌든때를 제거할 수 있다. 또한 연마제의 함량에 따라 조성물의 점도 및 물성에 영향을 주므로 적당한 연마제 함량이 설정 되어야 한다. The abrasive is characterized by being composed of two kinds. One of them, calcium carbonate, can easily be produced in domestic mines, and since hardness is not so strong, it is possible to minimize the damage of the hard surface in the polishing operation, and it is most widely used as a polishing agent in the detergent composition. If the particle size of the calcium carbonate is too small or too large, abrasive force may drop or damage to the hard surface may occur. Therefore, depending on the blend ratio of the appropriate particle size, the hard stain can be removed while minimizing damage to the hard surface. The content of the abrasive also influences the viscosity and physical properties of the composition, so that a proper abrasive content should be set.
본 발명에 사용된 탄산칼슘의 입자크기 및 분포는 200mesh 이하의 작은 크기를 갖는 입자의 비율이 30%~80%이며, 중량%로서 10%~65% 함유하는 것을 특징으로 하며, 더욱 바람직하게는 20~55% 함유하는 것을 특징으로 한다.The particle size and distribution of the calcium carbonate used in the present invention is characterized by containing 30% to 80% of particles having a small size of 200mesh or less and 10% to 65% by weight, more preferably, 20 to 55%.
실리카는 인체에 안전을 확보하기 위해서 치약용 실리카를 주로 사용하며 3%~50% 함유하는 것을 특징으로 하며, 바람직하게는 10%~40% 함유하는 것을 특징으로 한다.
Silica is mainly used as a toothpaste silica in order to secure safety to a human body and is characterized by containing 3% to 50%, preferably 10% to 40%.
그리고 연마제로서 상기 두성분 탄산칼슘 및 실리카는 40~65% 함유하는 것을 특징으로 하며, 탄산칼슘/실리카의 상대적인 배합비율은 20/1~1/10 , 바람직하게는 8/2~4/6인 것을 특징으로 하는 조성물이다.The two component calcium carbonate and silica are contained as an abrasive in an amount of 40 to 65%, and the relative ratio of calcium carbonate / silica is 20/1 to 1/10, preferably 8/2 to 4/6 ≪ / RTI >
지방산은 탄소수 C8~18중에서 선택되어지며, 바람직하게는 C12~16중에서 선택되어지는 The fatty acid is selected from C8-18 carbon atoms, preferably C12-16
포화탄화수소계의 천연계 지방산으로서 팜 나무,야자나무 또는 광물성으로부터 뽑아 내어진것을1~10% 함유하는 것을 특징으로 한다.It is a saturated hydrocarbon-based natural fatty acid containing 1 to 10% extracted from palm trees, palm trees or mineral.
글리세린은 식품성분으로 많이 사용되고 있는 성분으로서 10%~40% 함유하는 것을 특징으로 한다. 인체에 안전한 느낌을 주는 조성물이 아니라면 다른 폴리올성분 예를들면Glycerin is a commonly used ingredient as a food ingredient and is characterized by containing 10% to 40%. Other polyol components such as, for example, < RTI ID = 0.0 >
프로필렌글리콜,에틸렌글리콜,부틸렌글리콜등의 성분을 사용하여도 조성물의 형태를Propylene glycol, ethylene glycol, butylene glycol, and the like are used,
만들수는 있으나, 본 발명의 조성물은 인체에 안전한 성분을 사용하는 것이 또한 하나의 목적이므로, 글리세린을 사용하는 것을 특징으로 한다.However, the composition of the present invention is characterized by using glycerin because it is also an object to use a human-safe ingredient.
이하 본발명을 실시예를 통하여 자세히 설명한다.Hereinafter, the present invention will be described in detail by way of examples.
(( 실시예Example ))
< 혼합물 제조 > <Preparation of mixture>
표1에서와 같이 왁스타입, 페이스트, 액체 타입을 각각 제조 하였다.Wax type, paste and liquid type were prepared as shown in Table 1, respectively.
실시예1에서와 같이 왁스타입의 조성이 상대적으로 뛰어난 세정력을 발휘하였다The wax type composition exhibited a relatively excellent cleaning power as in Example 1
(왁스타입)(Wax type)
(페이스트)(Paste)
(액상)(Liquid phase)
SilicaSilica
glycerineglycerine
xanthangumxanthangum
지방산fatty acid
AXAX
기타Etc
물water
3030
2020
--
33
--
55
ToTo
100 100
2020
1010
0.50.5
--
55
55
ToTo
100 100
1010
1010
0.30.3
--
55
55
ToTo
100 100
실험방법 : Experimental Method:
<세정력평가>≪ Evaluation of cleaning power &
<오염제작><Pollution Production>
1) 샐러드기름 100 + 카본블랙(미쯔비시 #3750) 1.5g을 균일 분산1) Salad oil 100 + carbon black (Mitsubishi &num; 3750)
2) stainless판에 1)오염을 2mg/1cm2 도포하고 ,송풍항온조에서 170℃,2hr 가열
2) Apply 1) stain 2mg / 1cm2 to the stainless steel plate and heat it at 170 ℃ for 2hr in the air-
<평가방법><Evaluation method>
1) 스테인레스에 제작된 오염위에 샘플 1g을 넣는다.1) Place 1 g of sample on the stainless steel contamination.
2) 샘플위에 4cm*4cm 수세미(2중)로 50회 문질러준다.2) Scrub 50 times with 4cm * 4cm scrubber (double) on the sample.
3) 제거된 오염을 육안으로 판정한다.
3) The contamination removed is judged visually.
표3와Table 3 and 같이 지방산의 종류에 따라 Depending on the type of fatty acids 각각을Each 제조 하였다Gt; ..
SilicaSilica
glycerineglycerine
LauricLauric
acidacid
MyristicMyristic
acidacid
PalmiticPalmitic
acidacid
NaOHNaOH
기타Etc
물water
3030
2020
33
--
--
0.60.6
55
ToTo
100 100
3030
2020
--
33
--
0.50.5
55
ToTo
100 100
3030
2020
--
--
33
0.450.45
55
ToTo
100 100
경도는 고무경도계(The hardness is measured by a rubber hardness meter DUROMETERDUROMETER )를 이용하여 10회 측정하여 평균값을 비교하였다.), And the average value was compared.
탄산칼슘과 실리카의 비율에 따라 각각의 Depending on the ratio of calcium carbonate and silica,
실시예를Examples
제조하여, 세척력을 평가하였다. And the cleaning power was evaluated.
SilicaSilica
glycerineglycerine
지방산fatty acid
수산화나트륨Sodium hydroxide
향incense
기타Etc
물water
33
2020
33
0.60.6
0.20.2
33
ToTo
100 100
55
2020
33
0.60.6
0.20.2
33
ToTo
100 100
1010
2020
33
0.60.6
0.20.2
33
ToTo
100 100
1515
2020
33
0.60.6
0.20.2
33
ToTo
100 100
2020
2020
33
0.60.6
0.20.2
33
ToTo
100 100
2525
2020
33
0.60.6
0.20.2
33
ToTo
100 100
정tablet
력Power
Claims (4)
The composition according to claim 1, wherein the composition has a durometer hardness of 5 to 50
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