KR20140048971A - 가솔린의 벤젠 함량을 줄이기 위한 공정 - Google Patents

가솔린의 벤젠 함량을 줄이기 위한 공정 Download PDF

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Publication number
KR20140048971A
KR20140048971A KR1020147003609A KR20147003609A KR20140048971A KR 20140048971 A KR20140048971 A KR 20140048971A KR 1020147003609 A KR1020147003609 A KR 1020147003609A KR 20147003609 A KR20147003609 A KR 20147003609A KR 20140048971 A KR20140048971 A KR 20140048971A
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KR
South Korea
Prior art keywords
alkylation
alkylation reaction
benzene
alkylating agent
mcm
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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KR1020147003609A
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English (en)
Korean (ko)
Inventor
샤이-유안 에이치. 황
로날드 벌크호프
리차드 에프. 구아리노
제이. 에릭 모이
기이타 펄와니
Original Assignee
바져 라이센싱 엘엘씨
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Publication of KR20140048971A publication Critical patent/KR20140048971A/ko
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20Organic compounds not containing metal atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66Catalytic processes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1037Hydrocarbon fractions
    • C10G2300/104Light gasoline having a boiling range of about 20 - 100 °C
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1088Olefins
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1096Aromatics or polyaromatics

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020147003609A 2011-08-19 2011-11-30 가솔린의 벤젠 함량을 줄이기 위한 공정 Withdrawn KR20140048971A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
USPCT/US2011/048463 2011-08-19
USPCT/US2011/048463 2011-08-19
PCT/US2011/062635 WO2013028215A1 (en) 2011-08-19 2011-11-30 Process for reducing the benzene content gasoline

Publications (1)

Publication Number Publication Date
KR20140048971A true KR20140048971A (ko) 2014-04-24

Family

ID=45401161

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020147003609A Withdrawn KR20140048971A (ko) 2011-08-19 2011-11-30 가솔린의 벤젠 함량을 줄이기 위한 공정

Country Status (8)

Country Link
EP (1) EP2744875B1 (https=)
JP (1) JP2014524509A (https=)
KR (1) KR20140048971A (https=)
CN (1) CN103797091B (https=)
AU (1) AU2011375417B8 (https=)
MX (1) MX352408B (https=)
TW (1) TW201309788A (https=)
WO (1) WO2013028215A1 (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9199891B2 (en) 2011-02-07 2015-12-01 Badger Licensing Llc Process for reducing the benzene content of gasoline
KR20140037039A (ko) 2011-02-07 2014-03-26 바져 라이센싱 엘엘씨 파라핀 희석제의 존재 하에 저급 올레핀을 사용하는 알킬화 벤젠에 의해 가솔린의 벤젠 함량을 줄이기 위한 공정
US9200215B2 (en) 2011-02-07 2015-12-01 Badger Licensing Llc Process for reducing the benzene content of gasoline

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3755483A (en) 1972-04-28 1973-08-28 Mobil Oil Vapor phase alkylation in presence of crystalline aluminosilicate catalyst
US3751504A (en) 1972-05-12 1973-08-07 Mobil Oil Corp Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation
US4016218A (en) 1975-05-29 1977-04-05 Mobil Oil Corporation Alkylation in presence of thermally modified crystalline aluminosilicate catalyst
US4393262A (en) 1978-12-14 1983-07-12 Mobil Oil Corporation Production of isopropylbenzene
IT1127296B (it) * 1979-12-19 1986-05-21 Euteco Impianti Spa Procedimento perfezionato per la produzione di cumene
US4547605A (en) 1983-09-28 1985-10-15 Mobil Oil Corporation Catalyst for alkylation of aromatic hydrocarbons
US4582815A (en) 1984-07-06 1986-04-15 Mobil Oil Corporation Extrusion of silica-rich solids
US5149894A (en) 1986-01-29 1992-09-22 Chevron Research And Technology Company Alkylation using zeolite SSZ-25
US4954663A (en) 1988-10-06 1990-09-04 Mobil Oil Corp. Process for preparing long chain alkyl phenols
US4954325A (en) 1986-07-29 1990-09-04 Mobil Oil Corp. Composition of synthetic porous crystalline material, its synthesis and use
US4962256A (en) 1988-10-06 1990-10-09 Mobil Oil Corp. Process for preparing long chain alkyl aromatic compounds
US4908120A (en) 1987-08-20 1990-03-13 Mobil Oil Corporation Catalytic dewaxing process using binder-free zeolite
US4891458A (en) 1987-12-17 1990-01-02 Innes Robert A Liquid phase alkylation or transalkylation process using zeolite beta
US5001295A (en) 1988-10-06 1991-03-19 Mobil Oil Corp. Process for preparing dialkylnaphthalene
US4992606A (en) 1988-10-06 1991-02-12 Mobil Oil Corp. Process for preparing short chain alkyl aromatic compounds
US5043501A (en) 1990-03-15 1991-08-27 Mobil Oil Corp. Process for preparing dimethylnaphthalene
US5250777A (en) 1990-04-02 1993-10-05 Inductotherm Corp. Method and apparatus for variable phase induction heating and stirring
US5334795A (en) 1990-06-28 1994-08-02 Mobil Oil Corp. Production of ethylbenzene
EP0485683B1 (en) * 1990-11-13 2001-01-10 Fina Technology, Inc. Preparation of alkylated aromatics
US5120890A (en) * 1990-12-31 1992-06-09 Uop Process for reducing benzene content in gasoline
US5229341A (en) 1991-01-11 1993-07-20 Mobil Oil Corp. Crystalline oxide material
US5545788A (en) 1991-06-19 1996-08-13 Mobil Oil Corporation Process for the alkylation of benzene-rich reformate using MCM-49
US5236575A (en) 1991-06-19 1993-08-17 Mobil Oil Corp. Synthetic porous crystalline mcm-49, its synthesis and use
US5284643A (en) 1992-12-10 1994-02-08 Mobil Oil Corp. Gallium-containing zeolite MCM-22
US5362697A (en) 1993-04-26 1994-11-08 Mobil Oil Corp. Synthetic layered MCM-56, its synthesis and use
US6008422A (en) * 1997-07-14 1999-12-28 Uop Llc Alkylation process using interbed recycling of cooled reactor effluent
US20060194998A1 (en) * 2005-02-28 2006-08-31 Umansky Benjamin S Process for making high octane gasoline with reduced benzene content
US7476774B2 (en) * 2005-02-28 2009-01-13 Exxonmobil Research And Engineering Company Liquid phase aromatics alkylation process
US8395006B2 (en) * 2009-03-13 2013-03-12 Exxonmobil Research And Engineering Company Process for making high octane gasoline with reduced benzene content by benzene alkylation at high benzene conversion

Also Published As

Publication number Publication date
EP2744875A1 (en) 2014-06-25
CN103797091A (zh) 2014-05-14
EP2744875B1 (en) 2016-08-03
TW201309788A (zh) 2013-03-01
WO2013028215A1 (en) 2013-02-28
JP2014524509A (ja) 2014-09-22
AU2011375417B8 (en) 2017-08-17
AU2011375417A1 (en) 2014-02-20
MX352408B (es) 2017-11-23
MX2014001749A (es) 2014-07-30
AU2011375417A8 (en) 2017-08-17
AU2011375417B2 (en) 2017-04-27
CN103797091B (zh) 2016-07-06

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Legal Events

Date Code Title Description
PA0105 International application

Patent event date: 20140212

Patent event code: PA01051R01D

Comment text: International Patent Application

PG1501 Laying open of application
PC1203 Withdrawal of no request for examination
WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid