KR20130120627A - Heating glass using graphene and manufacturing method for the same - Google Patents
Heating glass using graphene and manufacturing method for the same Download PDFInfo
- Publication number
- KR20130120627A KR20130120627A KR1020120043668A KR20120043668A KR20130120627A KR 20130120627 A KR20130120627 A KR 20130120627A KR 1020120043668 A KR1020120043668 A KR 1020120043668A KR 20120043668 A KR20120043668 A KR 20120043668A KR 20130120627 A KR20130120627 A KR 20130120627A
- Authority
- KR
- South Korea
- Prior art keywords
- graphene
- glass
- film
- transparent
- heat generating
- Prior art date
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 138
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 131
- 239000011521 glass Substances 0.000 title claims abstract description 106
- 238000010438 heat treatment Methods 0.000 title claims abstract description 69
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- 239000000758 substrate Substances 0.000 claims abstract description 69
- 239000010408 film Substances 0.000 claims description 70
- 239000002356 single layer Substances 0.000 claims description 25
- 239000010409 thin film Substances 0.000 claims description 19
- 239000002019 doping agent Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 18
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 15
- 229910052802 copper Inorganic materials 0.000 claims description 15
- 239000010949 copper Substances 0.000 claims description 15
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 13
- 239000010410 layer Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000005260 corrosion Methods 0.000 claims description 5
- 230000007797 corrosion Effects 0.000 claims description 5
- 229910003771 Gold(I) chloride Inorganic materials 0.000 claims description 4
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 4
- FDWREHZXQUYJFJ-UHFFFAOYSA-M gold monochloride Chemical compound [Cl-].[Au+] FDWREHZXQUYJFJ-UHFFFAOYSA-M 0.000 claims description 4
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical group Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 239000002041 carbon nanotube Substances 0.000 description 9
- 229910021393 carbon nanotube Inorganic materials 0.000 description 9
- 230000008569 process Effects 0.000 description 9
- 239000002070 nanowire Substances 0.000 description 6
- 238000002834 transmittance Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- 238000005452 bending Methods 0.000 description 3
- 239000002071 nanotube Substances 0.000 description 3
- 238000005411 Van der Waals force Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- XOJVVFBFDXDTEG-UHFFFAOYSA-N Norphytane Natural products CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229960003280 cupric chloride Drugs 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- -1 polyethylene terephthalate Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/84—Heating arrangements specially adapted for transparent or reflecting areas, e.g. for demisting or de-icing windows, mirrors or vehicle windshields
- H05B3/86—Heating arrangements specially adapted for transparent or reflecting areas, e.g. for demisting or de-icing windows, mirrors or vehicle windshields the heating conductors being embedded in the transparent or reflecting material
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/182—Graphene
- C01B32/194—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/02—Details
- H05B3/04—Waterproof or air-tight seals for heaters
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/02—Details
- H05B3/06—Heater elements structurally combined with coupling elements or holders
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
- H05B3/12—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
- H05B3/14—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
- H05B3/145—Carbon only, e.g. carbon black, graphite
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/84—Heating arrangements specially adapted for transparent or reflecting areas, e.g. for demisting or de-icing windows, mirrors or vehicle windshields
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2204/00—Structure or properties of graphene
- C01B2204/02—Single layer graphene
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2204/00—Structure or properties of graphene
- C01B2204/04—Specific amount of layers or specific thickness
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Surface Heating Bodies (AREA)
- Nanotechnology (AREA)
- Inorganic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Resistance Heating (AREA)
Abstract
Description
The present invention relates to a heating glass using graphene and a method for manufacturing the same, and more particularly, to a heating glass using graphene and a method for manufacturing the same by converting electrical energy into thermal energy.
Hot wires are installed on the rear glass of automobiles for the purpose of preventing sexual love. Currently, the heating wires commonly used on the rear glass of automobiles have excellent electrical conductivity, but are not opaque and thus cannot be applied to the front and side surfaces.
Indium Tin Oxide (ITO) is a representative transparent heating element used to replace the hot wire. However, In used in ITO requires new substitute materials due to limited reserves and continuous price increase in the international market.In addition, ITO has excellent transparency and electrical conductivity, but when it is bent, the electrical conductivity is rapidly increased due to cracking. There is a problem falling.
In order to solve the problems of the ITO, a study on the surface heating element using carbon nanotubes having excellent electrical conductivity is being conducted, and a study on the surface heating element using metal oxide nanowires is being made.
Carbon nanotubes are excellent in thermal conductivity, can be easily bent, and have the advantage of maintaining excellent electrical conductivity even at a high radius of curvature.
However, the surface heating element according to the related art, which manufactures metal oxide nanowires and carbon nanotubes using a spray method, has an electrical conductivity of individual nanowires or nanotubes constituting the heating element. Although excellent, there is a problem in that many contacts (tube-tube junctions) are present when nanowires or nanotubes are applied to a large area to form a heating element.
In addition, in the case of carbon nanotubes, since a conductor and a semiconductor tube are mixed, a schottky barrier is formed at the contact point of the conductor and the semiconductor tube, thereby increasing the contact resistance. Therefore, the carbon nanotube must be formed thick to maintain high electrical conductivity. In this case, the light transmittance is reduced by the stacked nanotubes, and the adhesion to the substrate is weak, so that it may easily fall off due to an external impact.
The present invention has been devised to solve the above problems, and provides a heating glass using graphene having a transparent surface heating element made of graphene having excellent transparency, flexibility, electrical conductivity, and thermal conductivity, and a method of manufacturing the same. The purpose is.
In order to achieve the above object, the present invention, a pair of transparent glass substrate bonded in a laminated structure; A transparent heat generating film laminated on a first glass substrate among the glass substrates and generating heat on the entire surface when power is applied; A pair of electrodes for applying external power to the transparent heat generating film; And a transparent bonding film for bonding between the glass substrates. The transparent heat generating film provides a heat generating glass using graphene, which is made of graphene.
Preferably, the transparent heat generating film may be composed of single layer graphene or multilayer graphene, or may be composed of multilayer graphene including an organic dopant between layers.
Here, as the organic dopant, ferric chloride (AuCl 3 ) may be used, and the transparent bonding film may be made of PVB (Polyvinyl Butyral).
In another aspect, the present invention, the step of transferring the graphene on the first glass substrate to form a transparent heat generating film; Forming a pair of electrodes for applying power to both ends of the transparent heat generating film; Laminating a second glass substrate on the transparent heat generating film, and bonding the first and second glass substrate using a transparent bonding film; provides a method for producing a heating glass using a graphene comprising a. .
Forming the transparent heat generating film, the step of coating the graphene grown on a copper-based thin film substrate with a polymer; Immersing the thin film substrate having the graphene in a corrosion solution in the container; Repeatedly removing the thin film substrate by immersing the graphene in the container into a new container containing clean water; Immersing a first glass substrate in water in the container, stacking graphene on the surface, and drying the first glass substrate to transfer the graphene onto the first glass substrate; Repeated one or more times to form a transparent heating film made of single layer graphene or multilayer graphene.
Preferably, in the forming of the transparent heat generating film, the electrical conductivity may be improved by doping the organic dopant between the single layer graphene or the multilayer graphene or between the single layer graphene and the multilayer graphene transferred on the first glass substrate. have.
Therefore, the heat generating glass according to the present invention can ensure a stable structure even in a large area and ensure excellent heat conductivity based on excellent electrical and thermal conductivity by using graphene excellent in sheet resistance and thermal conductivity.
Such heat generating glass of the present invention is excellent in transparency and light transmittance can be applied as the front, rear, and side glass of the vehicle.
1 is a schematic exploded perspective view showing a heating glass using graphene according to an embodiment of the present invention
Figure 2 is a perspective view showing the heating glass of Figure 1
Figure 3 is a graph showing the sheet resistance measurement results of the transparent heating film (graphene surface heating element) produced in Examples 1 to 3 of the present invention
4 is a graph showing the sheet resistance values of the transparent heating film for exothermic glass produced in Examples 4 and 5 of the present invention before and after doping and before and after bonding process using PVB film.
5 is a graph showing the heating performance of the heating glass produced in Example 5 of the present invention
EMBODIMENT OF THE INVENTION Hereinafter, the heat generating glass of this invention and its manufacturing method are demonstrated in detail.
As is known, graphene has high electrical and thermal conductivity, such as carbon nanotubes, and can be grown in large areas using chemical vapor deposition using a copper thin film as a catalyst. Thus grown graphene has an advantage that can be easily transferred to the desired substrate.
Since the graphene of large area is composed of one carbon atom layer, there is no junction in carbon nanotubes or metal oxide nanowires. It is possible to implement a uniform heating element because of the excellent thermal conductivity.
In addition, unlike carbon nanotubes or metal oxide nanowires, graphene shows uniform absorption characteristics in all visible light irrespective of wavelength, and thus shows uniform transmittance in visible light.
In addition, graphene has excellent adhesion due to strong van der Waals force with the substrate, does not easily fall off from external impact, and various materials such as PET (polyethylene terephthalate), silicon (Si), and glass It can be transferred to the substrate, and stable adhesion can be maintained even when it is bent.
In addition, graphene can maintain a stable structure due to the interaction of the strong van der Waals forces between graphene and graphene even when stacking a plurality of sheets.
Therefore, even in the case of multilayer graphene in which graphene is stacked in sheets, it is possible to control electric conductivity and light transmittance.
In the case of the multilayered graphene, an organic dopant may be inserted and added between the graphene and the graphene when the graphene is stacked in order to improve the electrical properties, and the graphene having the improved electrical conductivity may be used. The transparent heating glass of the invention can be produced.
Hereinafter, the manufacturing method of the heating glass according to the present invention will be described.
First, single layer graphene is grown on a copper thin film or a copper thin film substrate which is a metal catalyst using chemical vapor deposition.
Before separating the grown monolayer graphene from the copper thin film, the graphene surface is first coated with a polymer such as PMMA to prevent cracking of the graphene when the single layer graphene is separated from the copper thin film.
Next, the copper thin film is immersed in an etchant in the container to remove the copper thin film from the single layer graphene.
In order to completely remove the corrosion solution remaining on the graphene after the removal of the copper thin film as described above, take out the graphene in the container and then immersed in another container containing clean water to be immersed and washed with clean new water. Repeat 5 ~ 6 times to completely remove the corrosion solution remaining on the graphene.
After the single layer graphene from which the copper thin film is removed through this process, the transparent glass substrate to be transferred to the graphene is immersed in water in a container, the graphene is laminated on the surface, and the water is dried on the glass substrate. Transfer single layer graphene onto the glass substrate.
By repeating the transfer process on the same glass substrate, a plurality of single layer graphene may be laminated on the glass substrate to form a multilayer graphene.
Here, the electrical conductivity and the light transmittance of the graphene plane heating element, that is, the transparent heat generating
In addition, in order to improve the electrical conductivity of the transparent heat generating
During doping, a dopant may be inserted in each layer between the single layer graphenes, or a plurality of single layer graphenes may be transferred and stacked on the
That is, in the doping process of the transparent heat generating
When the dopant is doped on the single layer or multilayer graphene, the single layer or multilayer graphene is transferred onto the
Next, a pair of
In brief, the
The transparent heating glass manufactured as described above may be applied to the front and rear glass of the vehicle, the window glass, and the like.
On the other hand, the
1 and 2, the
The
The
The
The
The transparent
The transparent
In addition, in order to improve electrical conductivity, the transparent
For example, the transparent
Hereinafter, preferred examples are provided to help understanding of the present invention, but the following examples are provided only to more easily understand the present invention, and the present invention is not limited thereto.
Example One
After repeatedly transferring the single layer graphene grown on the copper thin film to form a multi-layer graphene, using a corrosion solution to remove the copper thin film to produce a surface heating element made of pure (pristine) multilayer graphene.
Example 2
After graphene was grown on the copper thin film, a cupric chloride (AuCl 3 ) was deposited on the graphene, and graphene was grown on it. Next, the copper thin film was removed using a corrosive solution to prepare a graphene plane heating element doped with ferric chloride.
Example 3
A graphene plane heating element was prepared in the same manner as in Example 2, but a surface heating element was prepared using HNO 3 as an organic dopant.
Example 4
Graphene was repeatedly transferred to one surface of a transparent glass substrate having a 4 *
Example 5
In the same manner as in Example 4, the heating glass was manufactured, but in the process of forming the transparent heat generating film, a graphene plane heating element was deposited by intercalation doping with chloride (AuCl 3 ) with an organic dopant between graphene and graphene. To produce a heating glass comprising a.
Experimental Example One
The sheet resistance was measured by repeatedly bending and releasing the graphene plane heating elements of Examples 1 to 3 over 1000 cycles, and the results are shown in FIG. 3.
Experimental Example 2
In Examples 4 and 5, the sheet resistance of the transparent heating film (graphene surface heating element) was measured before bonding the glass substrate using the PVB film, and the sheet resistance of the transparent heating film changed after the bonding process using the PVB film was measured. The results are shown in Figure 4 and Table 1.
Experimental Example 3
The surface temperature change of the exothermic glass of Example 5 was measured for the voltage applied to the transparent heat generating film and the power supplied under the same conditions as shown in FIG. 5, and the results are shown in FIG. 5.
As shown in FIG. 3, the measurement results of Experimental Example 1 showed that the graphene plane heating element doped with ferric chloride showed the lowest sheet resistance value and the lowest sheet resistance value even after the bending cycle over 1000 cycles. .
As shown in FIG. 4 and Table 1 below, in the measurement result of Experimental Example 2, in the case of the exothermic glass using the doped graphene plane heating element (transparent heating film), the sheet resistance was increased after the bonding process using the PVB film, but was purely undoped. It was confirmed that the graphene plane heating element had less than half sheet resistance compared to the heating glass.
And, as shown in Figure 5, the measurement results of Experimental Example 3, it was confirmed that the surface temperature of the heating glass including the doped graphene plane heating element is increased to about 90 ℃ Celsius power consumption of 2.24W.
Accordingly, the heat generating glass according to the present invention has excellent electrical and thermal conductivity by using a surface heating element (transparent heating film) using graphene having excellent sheet resistance and thermal conductivity even in a large area instead of the surface heating element using carbon nanotubes. It can be seen that the heat-generating performance can be secured and the stable structure and low sheet resistance can be maintained even when bending.
In addition, the heat generating glass of the present invention is excellent in transparency and light transmittance can be applied as the front, rear, and side glass of the vehicle.
While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the scope of the present invention is not limited to the disclosed exemplary embodiments. Modified forms are also included within the scope of the present invention.
10: heating glass
11: first glass substrate
12: second glass substrate
13: transparent heating film
14: Electrode
15: transparent bonding film
Claims (8)
A transparent heat generating film 13 laminated on the first glass substrate 11 among the glass substrates and generating heat on the entire surface when power is applied;
A pair of electrodes 14 for applying external power to the transparent heat generating film;
And a transparent bonding film 15 for bonding between the glass substrates 11 and 12, wherein the transparent heat generating film 13 is made of graphene.
The transparent heat generating film 13 is a heat generating glass using graphene, characterized in that the single layer graphene or multilayer graphene.
The transparent heat generating film 13 is a heat generating glass using graphene, characterized in that the multilayered graphene containing an organic dopant between the layers.
The organic dopant is a ferric chloride glass (AuCl 3 ) characterized in that the heating glass using graphene.
The transparent bonding film 15 is a heat generating glass using graphene, characterized in that the PVB (Polyvinyl Butyral).
Forming a pair of electrodes for applying power to both ends of the transparent heat generating film;
Stacking a second glass substrate on the transparent heat generating film and bonding the first and second glass substrates using a transparent bonding film;
Method for producing a heating glass using a graphene, characterized in that it comprises a.
Forming the transparent heat film,
Coating graphene grown on a copper thin film substrate with a polymer;
Immersing the thin film substrate having the graphene in a corrosion solution in the container;
Repeatedly removing the thin film substrate by immersing the graphene in the container into a new container containing clean water;
Immersing a first glass substrate in water in the container, stacking graphene on the surface, and drying the first glass substrate to transfer the graphene onto the first glass substrate;
Method of manufacturing a heat generating glass using graphene, characterized in that to form a transparent heating film made of a single layer graphene or multilayer graphene by repeating one or more times.
Forming the transparent heat film,
The method of manufacturing a heating glass using a graphene, comprising the step of doping the organic dopant between the single layer graphene or multilayer graphene transferred between the first glass substrate or between the single layer graphene and the multilayer graphene.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020120043668A KR101337960B1 (en) | 2012-04-26 | 2012-04-26 | Heating glass using graphene and manufacturing method for the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020120043668A KR101337960B1 (en) | 2012-04-26 | 2012-04-26 | Heating glass using graphene and manufacturing method for the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20130120627A true KR20130120627A (en) | 2013-11-05 |
| KR101337960B1 KR101337960B1 (en) | 2013-12-09 |
Family
ID=49851166
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020120043668A KR101337960B1 (en) | 2012-04-26 | 2012-04-26 | Heating glass using graphene and manufacturing method for the same |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR101337960B1 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101530442B1 (en) * | 2013-12-09 | 2015-06-22 | 최원희 | Heating wall panel assembly using solar cell |
| CN105873246A (en) * | 2016-06-16 | 2016-08-17 | 济南圣泉集团股份有限公司 | Electric thermal film, engine oil preheating device with electric thermal film and engine |
| CN106170157A (en) * | 2016-08-25 | 2016-11-30 | 青岛科技大学 | Camera lens heater based on graphene film |
| ITUA20163907A1 (en) * | 2016-05-30 | 2017-11-30 | Fs Solution S R L S | Anti-fog glass for vehicles and construction method. |
| KR20180007102A (en) * | 2016-07-12 | 2018-01-22 | 강계수 | The heating glass manufacturing method and heating glass containing graphene |
| CN110650560A (en) * | 2019-10-23 | 2020-01-03 | 成都石墨烯应用产业技术研究院有限公司 | Double-layer mirror surface plate heating body |
| CN111556598A (en) * | 2020-05-27 | 2020-08-18 | 佛山(华南)新材料研究院 | Flexible low-voltage infrared electrothermal film and preparation method thereof |
| EP4294123A4 (en) * | 2021-02-10 | 2024-08-28 | Graphene Square Inc | Variable heating device |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101993301B1 (en) | 2018-02-27 | 2019-06-26 | 주식회사 오성 | Transparent nano-mat with plane heating and manufacturing method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004075400A (en) * | 2002-08-09 | 2004-03-11 | Sekisui Chem Co Ltd | Interlayer film for laminated glass, and laminated glass |
| WO2010126199A1 (en) * | 2009-05-01 | 2010-11-04 | 주식회사 한국아이티엘 | Double glazing window |
| WO2011081440A2 (en) * | 2009-12-30 | 2011-07-07 | 성균관대학교산학협력단 | Roll-to-roll doping method of graphene film, and doped graphene film |
| US8431869B2 (en) * | 2010-06-02 | 2013-04-30 | GM Global Technology Operations LLC | Defrosting, defogging and de-icing structures |
-
2012
- 2012-04-26 KR KR1020120043668A patent/KR101337960B1/en active IP Right Grant
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101530442B1 (en) * | 2013-12-09 | 2015-06-22 | 최원희 | Heating wall panel assembly using solar cell |
| ITUA20163907A1 (en) * | 2016-05-30 | 2017-11-30 | Fs Solution S R L S | Anti-fog glass for vehicles and construction method. |
| CN105873246A (en) * | 2016-06-16 | 2016-08-17 | 济南圣泉集团股份有限公司 | Electric thermal film, engine oil preheating device with electric thermal film and engine |
| CN105873246B (en) * | 2016-06-16 | 2022-08-30 | 济南圣泉集团股份有限公司 | Electric heating film, engine oil preheating device comprising same and engine |
| KR20180007102A (en) * | 2016-07-12 | 2018-01-22 | 강계수 | The heating glass manufacturing method and heating glass containing graphene |
| CN106170157A (en) * | 2016-08-25 | 2016-11-30 | 青岛科技大学 | Camera lens heater based on graphene film |
| CN110650560A (en) * | 2019-10-23 | 2020-01-03 | 成都石墨烯应用产业技术研究院有限公司 | Double-layer mirror surface plate heating body |
| CN111556598A (en) * | 2020-05-27 | 2020-08-18 | 佛山(华南)新材料研究院 | Flexible low-voltage infrared electrothermal film and preparation method thereof |
| CN111556598B (en) * | 2020-05-27 | 2022-05-27 | 佛山(华南)新材料研究院 | Flexible low-voltage infrared electrothermal film and preparation method thereof |
| EP4294123A4 (en) * | 2021-02-10 | 2024-08-28 | Graphene Square Inc | Variable heating device |
Also Published As
| Publication number | Publication date |
|---|---|
| KR101337960B1 (en) | 2013-12-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101337960B1 (en) | Heating glass using graphene and manufacturing method for the same | |
| Ma et al. | Graphene‐based transparent conductive films: material systems, preparation and applications | |
| JP5995976B2 (en) | One-dimensional conductive nanomaterial-based conductive film with improved conductivity by two-dimensional nanomaterial | |
| Kim et al. | Highly transparent low resistance ZnO/Ag nanowire/ZnO composite electrode for thin film solar cells | |
| Kulkarni et al. | Towards low cost materials and methods for transparent electrodes | |
| KR100797094B1 (en) | Trasparent heater and fabricating method thereof | |
| Hu et al. | Metal nanogrids, nanowires, and nanofibers for transparent electrodes | |
| Huang et al. | Self-limited nanosoldering of silver nanowires for high-performance flexible transparent heaters | |
| KR100955540B1 (en) | heat generation sheet and fabrication method thereof | |
| JP6488017B2 (en) | Thermoelectric conversion module, thermoelectric conversion module manufacturing method, and heat conductive substrate | |
| US20160304352A1 (en) | Graphene tape | |
| TWI530965B (en) | Graphene transparent conductive film | |
| CN101654784B (en) | Method for preparing flexible carbon nano tube transparent conductive thin-film material | |
| WO2017054265A1 (en) | Low-resistance transparent conductive thin film and preparation method therefor | |
| JP2018504749A (en) | Transparent sheet heating element | |
| KR20090099502A (en) | Heating element and method for manufacturing the same | |
| JP2013211212A (en) | Laminated electrode, manufacturing method therefor and photoelectric conversion element | |
| JP6438980B2 (en) | SOLAR CELL, MANUFACTURING METHOD THEREOF, AND SOLAR CELL MODULE | |
| TW200939484A (en) | Conductive glass for dye sensitive solar cell and method of preparing the same | |
| KR20140008607A (en) | Method using sacrificial substrate for manufacturing flexible substrate with buried metal trace and flexible substrate manufactured thereby | |
| Seok et al. | Transparent Conducting Electrodes for Quantum Dots Light Emitting Diodes | |
| KR20150135639A (en) | Hybrid compliant electrode with patterned graphene and matal-nanowire, and method of manufacturing thereof | |
| KR100979278B1 (en) | Heat generation sheet and fabrication method thereof | |
| KR20140133317A (en) | Transparent conductor comprising silver nanowire and silver grid complex pattern and method of manufacturing the same | |
| CN113012856A (en) | Metal grid flexible transparent conductive electrode based on cellulose nanofiber and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| E902 | Notification of reason for refusal | ||
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant | ||
| FPAY | Annual fee payment |
Payment date: 20171129 Year of fee payment: 5 |
|
| FPAY | Annual fee payment |
Payment date: 20191127 Year of fee payment: 7 |