KR20130065179A - a - Google Patents
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- KR20130065179A KR20130065179A KR1020110131920A KR20110131920A KR20130065179A KR 20130065179 A KR20130065179 A KR 20130065179A KR 1020110131920 A KR1020110131920 A KR 1020110131920A KR 20110131920 A KR20110131920 A KR 20110131920A KR 20130065179 A KR20130065179 A KR 20130065179A
- Authority
- KR
- South Korea
- Prior art keywords
- titanium
- antibacterial
- antifungal
- woven fabric
- deodorant
- Prior art date
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- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 37
- 230000000843 anti-fungal effect Effects 0.000 claims abstract description 36
- 239000002759 woven fabric Substances 0.000 claims abstract description 34
- 229940121375 antifungal agent Drugs 0.000 claims abstract description 25
- 230000001877 deodorizing effect Effects 0.000 claims abstract description 17
- 150000001875 compounds Chemical class 0.000 claims abstract description 14
- 239000003054 catalyst Substances 0.000 claims abstract description 13
- 239000010936 titanium Substances 0.000 claims abstract description 6
- 229920002994 synthetic fiber Polymers 0.000 claims abstract description 5
- 239000012209 synthetic fiber Substances 0.000 claims abstract description 5
- 229920000742 Cotton Polymers 0.000 claims abstract description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052719 titanium Inorganic materials 0.000 claims abstract 2
- 239000002781 deodorant agent Substances 0.000 claims description 31
- -1 titanium phosphate compound Chemical class 0.000 claims description 21
- 230000000845 anti-microbial effect Effects 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000008213 purified water Substances 0.000 claims description 8
- 239000004744 fabric Substances 0.000 claims description 7
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 5
- 101100283604 Caenorhabditis elegans pigk-1 gene Proteins 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 claims description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 239000005049 silicon tetrachloride Substances 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 239000004599 antimicrobial Substances 0.000 claims 1
- 238000007865 diluting Methods 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
- 238000001035 drying Methods 0.000 abstract description 4
- KRDJTDULHZPJPB-UHFFFAOYSA-N titanium(4+);tetraborate Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] KRDJTDULHZPJPB-UHFFFAOYSA-N 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 239000007859 condensation product Substances 0.000 abstract 1
- ADDWXBZCQABCGO-UHFFFAOYSA-N titanium(iii) phosphide Chemical compound [Ti]#P ADDWXBZCQABCGO-UHFFFAOYSA-N 0.000 abstract 1
- 201000004624 Dermatitis Diseases 0.000 description 6
- 239000000835 fiber Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 241000894006 Bacteria Species 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000008878 coupling Effects 0.000 description 3
- 238000010168 coupling process Methods 0.000 description 3
- 238000005859 coupling reaction Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 description 3
- 238000009941 weaving Methods 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- RJQXTJLFIWVMTO-TYNCELHUSA-N Methicillin Chemical compound COC1=CC=CC(OC)=C1C(=O)N[C@@H]1C(=O)N2[C@@H](C(O)=O)C(C)(C)S[C@@H]21 RJQXTJLFIWVMTO-TYNCELHUSA-N 0.000 description 1
- 229930182559 Natural dye Natural products 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 241000607142 Salmonella Species 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 241000191940 Staphylococcus Species 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- GNKTZDSRQHMHLZ-UHFFFAOYSA-N [Si].[Si].[Si].[Ti].[Ti].[Ti].[Ti].[Ti] Chemical compound [Si].[Si].[Si].[Ti].[Ti].[Ti].[Ti].[Ti] GNKTZDSRQHMHLZ-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 235000020710 ginseng extract Nutrition 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229960003085 meticillin Drugs 0.000 description 1
- 239000000978 natural dye Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006306 polyurethane fiber Polymers 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/80—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
- D06M11/82—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides with boron oxides; with boric, meta- or perboric acids or their salts, e.g. with borax
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2501/00—Wearing apparel
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2501/00—Wearing apparel
- D10B2501/02—Underwear
- D10B2501/021—Hosiery; Panti-hose
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2501/00—Wearing apparel
- D10B2501/04—Outerwear; Protective garments
- D10B2501/043—Footwear
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2503/00—Domestic or personal
- D10B2503/06—Bed linen
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2503/00—Domestic or personal
- D10B2503/06—Bed linen
- D10B2503/062—Fitted bedsheets
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2509/00—Medical; Hygiene
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Catalysts (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
Abstract
Description
본 발명은 피부염 예방 및 치료기능을 가지는 무광촉매로서 항균 및 항곰팡이제와 소취제를 직포에 부착하여 세탁견뢰도를 내구적으로 유지시키고 광선이 없는 환경에서 항균 및 항곰팡이 소취작용을 하여 피부염 예방 및 치료기능을 발휘하도록 만든 항균 및 항곰팡이 소취작용부를 구비한 기능성 직포에 관한 것인데, 구체적인 것은, 화학식이 Ti(OH)x(PO4)y(HPO4)z(H2PO4)m(OR)n(R은 탄소수 1~4개의 알킬기, x, y, z, m, n은 각각 0이상의 수이며, x+3y+2z+m+n = 4를 만족한다)로 표시되는 인산 티타늄계 화합물 또는 그 축합체와, 규산 티타늄계 화합물과 붕산 티타늄계 화합물 중에서 선택한 최소한 한 가지를 포함하여 구성하는 것을 특징으로 하는 무광촉매제 항균 및 항곰팡이 소취제를 천연섬유 또는 합성섬유로 제직한 직포 표면에 부착시켜서 직포 표면에 항균 및 항곰팡이 소취작용부를 형성한 것을 특징으로 하는 기능성 직포이다.
The present invention is a matte catalyst having the function of preventing and treating dermatitis, attaching antibacterial and antifungal agent and deodorant to the woven fabric to maintain the wash fastness durable and to prevent and treat dermatitis by antibacterial and antifungal deodorant in a light-free environment The present invention relates to a functional woven fabric having an antibacterial and antifungal deodorizing function made to function. Specifically, the formula is Ti (OH) x (PO4) y (HPO4) z (H2PO4) m (OR) n (R is carbon number). A titanium phosphate compound or a condensate thereof represented by 1 to 4 alkyl groups, x, y, z, m and n, each of which is 0 or more and satisfies x + 3y + 2z + m + n = 4; Matte catalyst antimicrobial and antifungal deodorant comprising at least one selected from a titanium silicate compound and a titanium borate compound is attached to the surface of the woven fabric made of natural or synthetic fibers to prevent antibacterial and A functional fabric, characterized in that the mold form a deodorant action.
일반적으로 항균섬유를 이용하여 항균,소취기능이 있는 직포를 제직하는 것은 다양한 방법이 알려져 있으나 항균,소취작용을 하는 기능성 섬유를 제조하는 것이 어렵고 비용이 많이 들어서 섬유가격이 고가로 되기 때문에 상기 섬유로 제직한 직포나 의류가 고가로 될 수밖에 없는 불편이 있었다.
In general, weaving a woven fabric with antibacterial and deodorant function using antibacterial fiber is known, but it is difficult to manufacture a functional fiber with antibacterial and deodorant function, and it is difficult and expensive, so the fiber price becomes expensive. Weaving woven fabrics and clothing was inconvenient to be expensive.
본 발명은 상기 불편을 해소하기 위하여 개발한 것이다.
The present invention has been developed to solve the above inconvenience.
본 발명은 화학식이 Ti(OH)x(PO4)y(HPO4)z(H2PO4)m(OR)n(R은 탄소수 1~4개의 알킬기, x, y, z, m, n은 각각 0이상의 수이며, x+3y+2z+m+n = 4를 만족한다)로 표시되는 인산 티타늄계 화합물 또는 그 축합체에 규산 티타늄계 화합물과 붕산 티타늄계 화합물 중에서 선택한 최소한 한 가지 화합물을 더 포함하여 구성한 무광촉매제인 항균 및 항곰팡이 소취제를 선택하고 이를 자연섬유로 제직한 직포 또는 합성섬유 직포에 스프레이 하거나 도포하거나 상기 항균, 항곰팡이 소취제가 혼합된 액체속에 직포를 투입한 후 건져내어 저온에서 장시간 건조시키는 방법으로 직포에 부착시켜 항균, 항곰팡이 소취작용부를 형성한 기능성 직포를 제조하고 이를 사용하여 의류, 침구, 양말, 신발, 행주, 의료용품을 제조할 수 있도록 한 것이다.
In the present invention, the formula is Ti (OH) x (PO4) y (HPO4) z (H2PO4) m (OR) n (R is an alkyl group having 1 to 4 carbon atoms, and x, y, z, m, n are each 0 or more. And at least one compound selected from a titanium silicate compound and a titanium borate compound is further included in the titanium phosphate compound or its condensate represented by x + 3y + 2z + m + n = 4). Selecting antibacterial and antifungal deodorant as a catalyst and spraying or applying it on a woven or synthetic fiber woven fabric made of natural fiber, or putting the woven cloth in a liquid mixed with the antibacterial and antifungal deodorant and drying it for a long time at low temperature By attaching to the woven fabric to produce a functional woven fabric that formed antibacterial, anti-fungal deodorizing action portion and to use it to manufacture clothing, bedding, socks, shoes, cloth, medical supplies.
이와 같이 구성된 본 발명은 인체에 나쁜 영향을 주지 않고 항균 및 항곰팡이 소취작용을 하는 인산티타늄계 화합물 또는 그 축합물에 규산 티타늄계 화합물 또는 붕산 티타늄제 화합물 중에서 선택한 최소한 한가지를 더 포함하여 항균 및 항곰팡이 소취기능을 향상시키고 자연섬유로 제직한 직포 또는 합성섬유로 제직한 직포에 스프레이 하거나 도포하거나 상기 항균 및 항곰팡이 소취제를 혼합한 물에 담근후, 건져내어 저온에서 장시간 건조시키는 방법으로 부착시켜서 항균 및 항곰팡이 소취작용부(2)를 형성시킨 기능성 직포를 제조하는 것이며, 이를 사용하여 피복, 침구,신발, 양말, 행주, 의료용품을 제조함으로써, 항균, 항곰팡이 소취작용이 월등한 기능성 피복, 침구, 신발, 의료용품을 제조할 수 있고, 피부염의 치료는 물론 예방이 가능케 되며, 특히 본 발명은 상기 화학식으로 표시된 인산티타늄계 화합물 또는 그 축합체에 규산 티타늄계 화합물 또는 붕산 티타늄계 화합물중에서 선택한 하나 이상의 화합물을 더 추가하여 구성함으로써, 항균 소취와 더불어 항곰팡이 작용이 더 높은 항균 및 항곰팡이 소취제를 제조할 수 있어서 신발제조에까지 사용할 수 있으며, 본 발명에 사용되는 무광촉매인 항균, 항곰팡이 소취제는 대기중의 수분과 산소가 접촉하면 활성기라는 물질이 만들어지고 활성기는 유기물에서 산소를 뺏어가는 강한 힘을 가지고 있기 때문에 악취를 내는 세균의산소를 뺏어 분해하므로 항균 및 항곰팡이 작용효과 소취 작용이 강력하고 빛의 조사 없이도 항균 및 항곰팡이 소취 작용이 가능하여 수분과 산소가 있는 한 상기 작용이 지속적으로 계속되는 효과가 있고,The present invention configured as described above further comprises at least one selected from the titanium phosphate compound or the titanium borate compound in the titanium phosphate-based compound or its condensate that has antibacterial and anti-fungal deodorizing effect without adversely affecting the human body. It improves mold deodorizing function and sprays or applies to woven fabric made of natural fiber or woven fabric made of synthetic fiber or soaked in water mixed with the above antibacterial and antifungal deodorant, and then dried and attached at a low temperature for a long time. And to produce a functional woven fabric formed anti-deodorant deodorizing action (2), by using the coating, bedding, shoes, socks, dishcloths, medical supplies, functional antibacterial, anti-fungal deodorant functional coating, Can make bedding, shoes, medical supplies, and can prevent and prevent dermatitis. In particular, the present invention by adding at least one compound selected from a titanium silicate compound or a titanium borate compound to the titanium phosphate-based compound or a condensate thereof represented by the above formula, the antibacterial deodorant and antifungal action is higher Antimicrobial and antifungal deodorant can be used to manufacture shoes, and the antimicrobial and antifungal deodorant, which is a matte catalyst used in the present invention, is made of a substance called active group in contact with moisture and oxygen in the air. As it has strong power to take oxygen, it takes away the oxygen of bacteria that makes bad smell and decomposes it, so it has strong antibacterial and antifungal effect. As long as there is moisture and oxygen, it has strong antibacterial and antifungal deodorization effect without light irradiation. There is an effect that the action continues continuously,
또한, 본 발명은 인산티타늄계 화합물 또는 그 축합체에 규산 티타늄계 화합물 또는 붕산 티타늄계 화합물 중에서 한가지를 포함하는 항균, 항곰팡이 소취제를 구성함으로써, 항균, 항곰팡이 소취성능이 더 높아지고 별도의 바인더가 필요 없이 직물에 부착시킬 수 있기 때문에 직포의 유연성을 저하시키지 않고 강력하고 지속적인 부착이 될 수 있고, 이로인해 직포의 내구적인 항균 및 항곰팡이 소취작용부를 구성하여 유지시킬 수 있으며,In addition, the present invention by forming an antibacterial, anti-fungal deodorant comprising one of a titanium silicate-based compound or a titanium borate-based compound in the titanium phosphate-based compound or a condensate thereof, the antibacterial, anti-fungal deodorant performance is higher and a separate binder Because it can be attached to the fabric without the need for strong and durable adhesion without reducing the flexibility of the woven fabric, thereby making it possible to construct and maintain the durable antibacterial and anti-fungal deodorizing action of the woven fabric,
또, 본 발명의 항균, 소취제가 부착된 직포는 상기와 같은 작용으로 유해물질을 계속 분해시켜서 유해균의 증식을 막고 세균을 사멸시키며 곰팡이균을 제거하고 방지하는 효과를 내게 된다.In addition, the antimicrobial, deodorant is attached to the woven fabric of the present invention continues to decompose harmful substances by the same action to prevent the growth of harmful bacteria, kill bacteria and remove and prevent fungi.
또, 본 발명은 직포의 조직을 이중조직으로 하여 피부와 접촉하는 앞면부(10)와 뒷면부(11)사이에 통기간격부(12)를 형성하여 공기함유량이 높은 조직을 구성함으로써, 무광촉매의 항균 소취작용을 더욱 높이는 효과도 얻을 수 있다.In addition, the present invention forms a tissue having a high air content by forming a
또, 본 발명은 세탁에 의하여 성능이 쉽게 저하되지 않으므로 세탁하여 계속 사용할 수 있는 이점이 있으며,In addition, the present invention has the advantage that can continue to be washed because the performance is not easily degraded by washing,
본 발명의 항균 및 항곰팡이 소취제는 피부염이 발생한 부위에 접촉하여 피부염 유발 세균을 사멸시킬 뿐 아니라 대장균, 포도상구균, 대장균 0157, 메치시진 내성 황색 도포상구균, 살모넬라균 등에도 유효하므로 입원환자에게서 발생하는 피부염을 보다 효과적으로 치료하고 감염을 예방하여 보다 더 안전하게 치료 예방할 수 있는 이점이 있어서 환자복이나 환자용 침구제작에 활용될 수 있으며, 상기 항균 및 항곰팡이 소취제는 음이온까지 발산하므로 착용자에게 기분을 상쾌하게 하는 효과까지 낼 수 있도록 된다.
The antimicrobial and antifungal deodorant of the present invention is effective in coli, staphylococcus, E. coli 0157, methicillin-resistant yellow coating bacteria, Salmonella, etc. in addition to killing dermatitis-inducing bacteria in contact with the dermatitis. It has the advantage of treating the dermatitis more effectively and preventing the infection to be safer and more safely.It can be used in the production of patient clothes or bedding for patients.The antibacterial and anti-fungal deodorant also emits negative ions so that the wearer feels refreshed. It will be able to produce the effect.
도 1은 본 발명의 표면 예시도
도 2는 본 발명의 단면도
도 3은 본 발명의 또 다른 직포 예시도
도 4는 도 3의 단면도이다.1 is an exemplary view of the surface of the present invention
2 is a cross-sectional view of the present invention
3 is another exemplary woven fabric of the present invention
4 is a cross-sectional view of FIG. 3.
본 발명은 면직물지로 제조되는 직포 또는 합성섬유(아크릴사, 폴리에스텔사, 폴리우레탄섬유, 나일론사)로 제조되는 직포(1)에 무광촉매로된 항균 및 항곰팡이, 소취제를 분무하거나 도포하거나 상기 화합물이 혼합된 액체속에 침지한 후 건져내어 25∼30℃에서 48시간 동안 건조시키는 방법으로 부착시킨 항균 및 항곰팡이, 소취작용부(2)를 형성시키는 것을 특징으로 하는 기능성 직포이다.The present invention is sprayed or applied to the antimicrobial and anti-fungal, deodorant made of a matte catalyst on a woven fabric (1) made of cotton fabric or woven fabric (acrylic yarn, polyester yarn, polyurethane fiber, nylon yarn) It is a functional woven fabric characterized in that the antimicrobial and antifungal, deodorizing action (2) attached to the method by immersing in the mixed liquid mixed with the compound and dried by drying for 25 hours at 25 ~ 30 ℃.
또한, 본 발명은 화학식이 Ti(OH)x(PO4)y(HPO4)z(H2PO4)m(OR)n(R은 탄소수 1~4개의 알킬기, x, y, z, m, n은 각각 0이상의 수이며, x+3y+2z+m+n = 4를 만족한다)로 표시되는 인산 티타늄계 화합물 또는 그 축합체와 규산 티타늄계 화합물과 붕산 티타늄계 화합물 중에서 선택한 최소한 한 가지를 더 포함하여 구성하는 무광촉매인 항균 및 항곰팡이 소취제이고,In the present invention, the formula is Ti (OH) x (PO 4) y (HPO 4) z (
구체적으로는 이소플로필 알코올 25㎖와 정제수 25㎖의 혼합액에 교반하면서 5~35℃에서 4염화티탄 5㎖를 혼합하여 반응시키고 PH 1에서 반응을 종료시킨 다음 정제수로 10~100배 희석하고 85% 인산수용액 5㎖를 더하여 반응시키는 제조방법으로 얻어지는 인산티타늄계 화합물 또는 이들의 축합물을 유효성분으로 하는 항균, 소취제에 정제수 100ml와 이소프로알코올100ml의 혼합용액에 4염화규소 30g을 첨가하고 20~30℃에서 반응시킨 다음 4염화티탄50g을 첨가하고 20~30℃에서 반응시키는 방법으로 얻어진 규산티타늄계 화합물(TiO2 SiO2의 화학조성을 가지게 됨)Specifically, 5 ml of titanium tetrachloride was reacted at 5 to 35 ° C. with stirring in a mixed solution of 25 ml of isoflophyl alcohol and 25 ml of purified water, and the reaction was terminated at
또는 정제수 50ml에 붕산분말 50g을 첨가하고 실온에서 용해시킨다음 염화티탄 10g을 첨가하고 실온에서 반응시킨 방법으로 얻어진 붕산티타늄계 화합물(TiO2 B2O3의 화합조성을 가지게 됨)중에서 선택한 한가지 이상의 화합물을 더 혼합하여 항균 및 항곰팡이, 소취제를 선택하고 이를 직포(1)에 묻혀서 25~35℃에서 건조시키는 방법으로 직포에 항균 및 항곰팡이, 소취 작용부(2)를 형성시켜서 되는 것이다.Alternatively, 50 g of borate powder is added to 50 ml of purified water and dissolved at room temperature, and then one or more compounds selected from titanium borate compounds (which have a composition of TiO2 B2O3) are further mixed by adding 10 g of titanium chloride and reacting at room temperature. By selecting the antibacterial and antifungal, deodorant and buried it in the woven fabric (1) by drying at 25 ~ 35 ℃ by forming an antibacterial and antifungal, deodorizing action (2) on the woven fabric.
또한, 본 발명은 상기 항균, 소취 작용부를 구비한 직포를 사용하여 피복, 침구, 신발, 의료용품을 제조하게 된다.In addition, the present invention is to manufacture a cloth, bedding, shoes, medical supplies using the woven fabric having the antibacterial, deodorant action.
또한, 본 발명의 직포는 천연섬유직포로 하는 것이 원칙이며, 환자의 피부와 접촉하는 앞면부(10)와 반대측인 뒷면부(11)사이에 통기간격부(12)가 형성되도록 일정간격에 가로방향결합부(1a)와 세로방향결합부(1b)를 형성하는 직조 방법으로 제직되는 직포로 구성되는 것이 바람직하다.In addition, the woven fabric of the present invention is made of a natural fiber woven fabric in principle, so that a
한편, 본 발명은 상기 직포를 염색할 때 항균 작용이 있는 고삼추출물을 천연염료에 혼합하여 염색처리 함으로써 항균 및 항진균 효과를 더 높일 수 있는 방법이 포함 된다.On the other hand, the present invention includes a method that can further increase the antibacterial and antifungal effect by dyeing the woven fabric dyed by mixing the high ginseng extract with an antibacterial action in a natural dye.
1 : 직포 1a : 가로방향결합부
1b : 세로방향결합부 2 : 항균, 소취 작용부
10 : 앞면부 11 : 뒷면부
12 : 통기간격부1:
1b: longitudinally coupled portion 2: antibacterial, deodorant action portion
10: front part 11: back part
12: interval period
Claims (2)
The antimicrobial and antifungal deodorizing part (2) dried at 25 to 30 ° C. for 48 hours by attaching antimicrobial and antifungal and deodorant made of a matte catalyst to a woven fabric made of cotton fabric or synthetic fiber (1). Functional woven fabric forming antibacterial and anti-fungal deodorizing part with matte catalyst
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| US10912856B2 (en) | 2017-01-10 | 2021-02-09 | Sambo Advanced Materials Inc. | Bacterial adsorption dressing with nonphotocatalyst and method of manufacturing the same |
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| KR101896920B1 (en) | 2018-09-11 |
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