KR20130033902A - Manufacture method of loess nano latex foam and loess nano latex foam thereof - Google Patents

Manufacture method of loess nano latex foam and loess nano latex foam thereof Download PDF

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KR20130033902A
KR20130033902A KR1020110097866A KR20110097866A KR20130033902A KR 20130033902 A KR20130033902 A KR 20130033902A KR 1020110097866 A KR1020110097866 A KR 1020110097866A KR 20110097866 A KR20110097866 A KR 20110097866A KR 20130033902 A KR20130033902 A KR 20130033902A
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latex
ocher
nano
weight
mixed
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KR1020110097866A
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Korean (ko)
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KR101378491B1 (en
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신현덕
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주식회사 코라텍스
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34—Auxiliary operations
    • B29C44/3442—Mixing, kneading or conveying the foamable material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/80—Component parts, details or accessories; Auxiliary operations
    • B29B7/88—Adding charges, i.e. additives
    • B29B7/94—Liquid charges
    • B29B7/945—Liquid charges involving coating particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/02—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0005—Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
    • B29K2105/0044—Stabilisers, e.g. against oxydation, light or heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0058—Liquid or visquous
    • B29K2105/0064—Latex, emulsion or dispersion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/16—Fillers
    • B29K2105/162—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2503/00—Use of resin-bonded materials as filler
    • B29K2503/04—Inorganic materials
    • B29K2503/08—Mineral aggregates, e.g. sand, clay or the like

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

PURPOSE: A manufacturing method of red clay nano latex foam and red clay nano latex foam thereof are provided to prevent red clay nano particle from staining to be distributed to the latex foam. CONSTITUTION: A manufacturing method of red clay nano latex foam comprises: a step of mixing the red clay with water or mixture of liquid by processing the red clay to a particle size of 40-50nm(S100), a step of liquefying after absorbing the red clay nano to the surface of the curing agent or a catalyst by mixing the red clay nano with the curing agent(S200), and a step of impregnating by stirring the latex undiluted solution mixing additive including vulcanizing and curing agent, surfactant, antioxidant, anti-aging agent, and filler with red clay nano additive(S300), a step of molding mixed red clay nano latex mixture by a latex mold(S400), and a step of producing red clay nano latex finished product of far-infrared radiation by drying the red clay nano latex(S500). [Reference numerals] (S100) First liquid mixing step, Red clay nano + Water(distilled water); (S200) Second liquid mixing step, The mixture of the first liquid mixing step + Curing agent, catalyst; (S300) Stirring and impregnating step, The mixture of the second liquid mixing step + Vulcanizing agent, surfactant, additive; (S400) Foaming step; (S500) Finished product producing step, Far-infrared radiation red clay nano latex foam;

Description

황토나노 라텍스폼 제조방법 및 그에 따른 황토나노 라텍스폼{MANUFACTURE METHOD OF LOESS NANO LATEX FOAM AND LOESS NANO LATEX FOAM THEREOF}Manufacture method of yellow earth nano latex foam and yellow earth latex foam according to it

본 발명은 황토나노 라텍스폼 제조방법 및 그에 따른 황토나노 라텍스폼에 관한 것으로, 더욱 상세하게는 나노 입자의 황토를 라텍스원료와 균일하게 함침혼합하여 라텍스의 쿠션기능의 향상과 황토의 원적외선 방사에 따른 기능성 향상 및 라텍스폼의 내구성과 안전성이 우수한 황토나노 라텍스폼 제조방법 및 그에 따른 황토나노 라텍스폼에 관한 것이다.
The present invention relates to a method for manufacturing ocher nano latex foam and the ocher nano latex foam according to the present invention. More specifically, the ocher of nanoparticles is uniformly impregnated and mixed with latex raw material to improve the cushioning function of latex and the far-infrared radiation of ocher. The present invention relates to a process for producing ocher nano latex foam having excellent functionality and durability and safety of latex foam, and to an ocher nano latex foam according to the present invention.

일반적으로 최근 가정에서 서구식 잠자리를 선호하고 있는 경향이고, 이는 우리나라의 온돌문화에서 서구의 침대문화로 변천하고 있는 모습에서 이를 대변할 수 있다. 이러한, 침대문화는 사용자의 몸을 받쳐주고 편안한 잠자리를 마련할 수 있는 매트리스와 머리를 받칠 수 있는 베개를 들 수 있다.
In general, it is a tendency that western families prefer western-style dragonflies, which can be represented by the transition from Korean ondol culture to western bed culture. The bed culture includes a mattress that can support the user's body and provide a comfortable bed, and a pillow that can support the head.

이러한, 매트리스와 베개는 종래에는 단순히 솜 베개, 스프링 매트리스 등을 사용하고 있지만 최근 경향으로 생활문화의 향상으로 인해 고무를 원료로 하여 제조되는 라텍스폼을 선호하고 있다. 보통 종래의 스프링 매트리스나 솜 베개 등은 솜이나 스프링의 탄성력이 떨어져 눌려진 부위가 회복되지 않는 문제점이 있었으나 라텍스폼으로 성형된 매트리스나 베개의 경우, 라텍스 고유의 반영구적 탄성력에 의해 수면 시 인체를 균형적으로 지지하고, 라텍스 매트리스는 인체의 곡선을 따라서 균형적으로 인체를 지지함으로써, 인체의 척추, 둔부 등의 특정부위에 체중이 부담되는 것을 최적화하는 자세를 유지시킬 수 있어 목디스크, 허리디스크나 거북 목의 예방 및 코골이 예방 및 숙면에 도움이 된다.
Such mattresses and pillows are conventionally simply used cotton pillows, spring mattresses, etc., but lately, the latent foams are manufactured using rubber as a raw material due to the improvement of living culture. Conventional spring mattresses or cotton pillows have a problem in that the elasticity of the cotton or the spring is reduced and the pressed part cannot be recovered.However, in the case of a mattress or pillow formed of latex foam, the human body is balanced by sleep due to the semi-permanent elasticity of latex. Latex mattress supports the human body in a balanced manner along the curve of the human body, thereby maintaining a posture that optimizes the weight burden on specific parts of the human spine, buttocks, neck disc, waist disc or turtle. Prevention of the throat and snoring can help prevent and sleep better.

또한, 제조공정상에서 라텍스폼 내부에 에어셀이 형성되기 때문에 통기성이 탁월하며, 탄력 및 신축성이 우수하여 원형복원기능이 우수한 장점이 있다.
In addition, since the air cell is formed inside the latex foam in the manufacturing process, it is excellent in breathability, excellent elasticity and elasticity has the advantage of excellent circular restoration function.

따라서, 이러한 라텍스의 우수한 장점을 이용하여 최근 고급 베개 및 침대를 중심으로 사용이 확산되고 있는 추세에 있다. 이러한, 종래의 라텍스는 천연라텍스와 합성라텍스로 구분할 수 있는데 천연라텍스는 천연고무 유액을 사용하여 제조되는 제품이고, 합성라텍스는 합성고무를 이용하여 제조되는 것으로, 보통 합성고무에 천연고무로 일정량 혼합하여 사용한다.
Therefore, there is a trend that the use of these latex has been spreading around high-end pillows and beds in recent years. Such a latex can be classified into a natural latex and a synthetic latex. The natural latex is a product manufactured by using a natural rubber latex, and the synthetic latex is manufactured by using a synthetic rubber, usually mixed with a predetermined amount of synthetic rubber with natural rubber. Use it.

이러한, 천연라텍스와 합성라텍스 중 천연라텍스는 합성라텍스에 비해 인장강도나 교질강도(gel strength)가 좋고 탄력성이 우수하다. 그러나, 원재료가 비싸고 대량 생산이 어려우며 구입이 용이하지 못하다. 반면 합성라텍스는 그 물성이 천연라텍스와 유사하면서도 원재료가 싸고 구하기가 용이하여 일반적으로 널리 사용되어지고 있다.
Among these natural and synthetic latexes, natural latexes have better tensile strength or gel strength and superior elasticity than synthetic latexes. However, raw materials are expensive, mass production is difficult and not easy to purchase. Synthetic latexes, on the other hand, are similar to natural latexes, but are widely used because they are cheap and easy to obtain.

이러한, 라텍스는 최근에는 건강에 대한 관심이 증가되면서, 침구에 숯, 옥 및 각종 기능성 물질 및 원적외선 방사물질을 라텍스에 도포한 형태의 매트리스나 베개가 개시되고 있으나 이는 라텍스 표면에 단순히 도포하는 정도에 그쳐 그 효과가 미미하고, 사용시 외부로 도포된 물질이 묻어나오거나 라텍스 표면에 커버된 베개커버나 매트리스 커버에 묻어 오염되는 문제점이 있었다.
In recent years, latex has been increasing interest in health, has been disclosed mattresses or pillows in the form of latex coated with charcoal, jade and various functional materials and far-infrared radiation on the bedding, but this is to the extent that the latex simply applied to the surface Only the effect is insignificant, and when used, there is a problem that the material applied to the outside or stained on the pillow cover or mattress cover covered on the latex surface.

더욱이, 외부에 도포된 형태를 취하고 있어 사용자가 매트리스나 베개를 사용시 라텍스의 탄성변형에 따라 도포된 물질이 라텍스와 이형되어 그 기능 등을 올바르게 수행하지 못하는 문제점이 있었다. 또한, 이러한 문제를 해결하기 위해 도포되는 층을 두껍게 형성하면 라텍스의 탄성력의 저하로 인해 라텍스의 장점이 인체의 굴곡에 따른 균형적 탄성변형자체가 힘들어져 라텍스 본연의 기능을 수행하지 못하는 결과를 초래하는 문제점이 있었다.
In addition, it takes a form that is applied to the outside, there is a problem that the user does not correctly perform the function, such as the release of the applied material according to the elastic deformation of the latex when the user uses the mattress or pillow. In addition, forming a thick layer applied to solve this problem, due to the deterioration of the elastic force of the latex, the advantage of latex is difficult to balance elastic deformation itself due to the bending of the human body, which results in the latex does not perform its original functions There was a problem.

따라서, 본 발명은 상술한 바와 같은 문제점을 해결하기 위해 창출한 것으로, 원적외선 방사를 통해 인체에 유익하고, 각종 아토피 등의 피부질환에 대해 우수한 자정효과가 있는 황토를 나노입도로 형성함으로써, 라텍스 발포에 따른 균질한 발포성형이 가능하면서 원적외선 방사의 기능이 추가된 우수한 황토나노 라텍스폼 제조방법 및 그에 따른 황토나노 라텍스폼을 제공하는 데 그 목적이 있다.
Therefore, the present invention was created to solve the problems described above, by forming latex foam by forming nanoparticles in the nanoparticles, which is beneficial to the human body through far-infrared radiation and has excellent self-cleaning effect against skin diseases such as various atopies. The purpose is to provide an excellent ocher nano latex foam manufacturing method and the ocher nano latex foam according to the homogeneous foam molding possible according to the addition of the function of far infrared radiation.

또한, 본 발명은 라텍스폼의 발포 및 성형시, 황토나노 입자를 고르게 분포하도록 발포함에 따라 황토입자가 외부로 묻어나지 않아 청결하고 깨끗한 라텍스폼의 구현이 가능하고, 내구성이 증대되며 라텍스 본연의 탄성력을 그대로 유지가 가능한 황토나노 라텍스폼 제조방법 및 그에 따른 황토나노 라텍스폼을 제공하는 데 목적이 있다.
In addition, the present invention in the foaming and molding of latex foam, as the foam is distributed evenly to the ocher nanoparticles are not buried to the outside, it is possible to implement a clean and clean latex foam, the durability is increased and the natural latex It is an object of the present invention to provide an ocher nano latex foam manufacturing method and an ocher nano latex foam that can maintain the elastic force as it is.

상술한 바와 같은 목적을 해결하기 위한 본 발명에 따른 황토나노 라텍스폼 제조방법은 황토입자크기가 40~50nm인 황토나노로 미세 가공하여 물 또는 액상의 혼합제와 혼합하는 액상혼합1단계(S100)와; 상기 물 또는 액상의 혼합제와 혼합된 황토나노를 가류제 및 촉진제와 혼합 가공함으로써, 가류제 및 촉진제의 표면에 상기 황토나노를 흡착시켜 액상화하는 액상혼합2단계(S200)와; 라텍스 원액에 탄성, 신장성을 향상시키고 경화하기 위한 가황제, 라텍스폼의 입자수 및 입자 크기의 분포조절을 위한 계면활성제와, 라텍스폼의 산화방지를 위한 산화방지제, 노화방지제, 충진제를 포함하는 첨가제를 투입, 혼합한 상기 라텍스 원액에 상기 액상화된 황토나노 첨가물을 교반혼합하여 함침하는 교반함침단계(S300)와; 상기 혼합된 황토나노 라텍스 혼합물을 라텍스 성형금형으로 발포 및 성형하는 발포성형단계(S400)와; 상기 발포 및 성형된 황토나노 라텍스를 건조하여 원적외선 방사 황토나노 라텍스 완제품을 생산하는 완제품생산단계(S500);를 포함한다.
The ocher nano latex foam manufacturing method according to the present invention for solving the object as described above is a liquid mixing step 1 (S100) and finely processed with ocher nanoparticles of the ocher particle size 40 ~ 50nm and mixed with water or liquid mixture ; A liquid phase mixing step (S200) of adsorbing the yellow earth nanoparticles on the surface of the vulcanizing agent and the accelerator to liquefy by mixing the yellow clay mixed with the water or liquid mixture with a vulcanizing agent and an accelerator; Vulcanizing agent for improving elasticity and extensibility and curing in latex stock solution, surfactant for controlling distribution of particle number and particle size of latex foam, antioxidant for antioxidant of latex foam, antioxidant and filler A stirring impregnation step (S300) of impregnating and mixing the liquid liquefied ocher nano additives into the latex stock solution to which an additive is added and mixed; Foaming and molding the mixed ocher nano latex mixture into a latex molding mold (S400); A finished product production step (S500) of producing the finished product of far-infrared radiation ocher nano latex by drying the foamed and molded ocher nano latex;

여기서, 상기 황토나노 라텍스 혼합물은 라텍스 80중량%, 가황제 9.0중량%, 계면활성제 10.0중량%, 첨가제 1.0중량%로 혼합된 원액 100중량부를 기준으로 황토나노 0.5~20중량% 만큼 사용되는 것을 특징으로 한다.
Here, the yellow clay latex mixture is used by 0.5 to 20% by weight of yellow clay based on 100 parts by weight of the stock solution mixed with 80% by weight of latex, 9.0% by weight of vulcanizing agent, 10.0% by weight of surfactant, and 1.0% by weight of additive. It is done.

한편, 물 또는 액상의 혼합제와 혼합된 액상의 상기 황토나노는 황토나노 고형분이 30중량%, PH 8~9, 입자크기 40~50nm 인 것을 특징으로 한다.
On the other hand, the ocher nanoparticles in the liquid phase mixed with water or a liquid mixture is characterized in that the ocher nano solids content of 30% by weight, PH 8-9, particle size 40 ~ 50nm.

나아가, 본 발명에 따른 황토나노 라텍스폼 제조방법을 통해 생산되는 황토나노 라텍스폼은 황토입자크기가 40~50nm인 황토나노로 미세 가공하여 액상의 혼합제와 혼합하고, 상기 액상의 혼합제과 혼합된 황토나노를 가류제 및 촉진제와 혼합 가공함으로써, 가류제 및 촉진제의 표면에 상기 황토나노를 흡착시켜 액상화하며, 라텍스 원액에 가황제, 계면활성제, 첨가제를 투입 혼합한 상기 라텍스 원액에 상기 액상화된 황토나노 첨가물을 교반혼합하여 함침한 후, 상기 혼합된 황토나노 라텍스 혼합물을 라텍스 성형금형으로 발포 및 성형, 건조하여 원적외선 방사가 가능한 것을 특징으로 한다.
Furthermore, the ocher nano latex foam produced through the ocher nano latex foam manufacturing method according to the present invention is finely processed into ocher nanoparticles having an ocher particle size of 40 to 50 nm, mixed with a liquid mixture, and the ocher mixed with the liquid mixture. By mixing and processing nano with a vulcanizing agent and an accelerator, the yellow clay is liquefied by adsorbing the ocher nanoparticles on the surface of the vulcanizing agent and the accelerator, and the liquefied ocher nanoparticles are added to the latex stock solution containing a mixture of a vulcanizing agent, a surfactant, and an additive in a latex stock solution. After impregnating the additives by mixing and mixing, the mixed ocher nano latex mixture is foamed, molded, and dried into a latex molding mold, so that far-infrared radiation is possible.

여기서, 상기 황토나노 라텍스 혼합물은 라텍스 80중량%, 가황제 9.0중량%, 계면활성제 10.0중량%, 첨가제 1.0중량%로 혼합된 원액 100중량부를 기준으로 황토나노 0.5~20중량% 만큼 사용되는 것을 특징으로 하고, 물 또는 액상의 혼합제와 혼합된 액상의 상기 황토나노는 황토나노 고형분이 30중량%, PH 8~9, 입자크기 40~50nm 인 것을 특징으로 한다.
Here, the yellow clay latex mixture is used by 0.5 to 20% by weight of yellow clay based on 100 parts by weight of the stock solution mixed with 80% by weight of latex, 9.0% by weight of vulcanizing agent, 10.0% by weight of surfactant, and 1.0% by weight of additive. The ocher nanoparticles in the liquid phase mixed with water or a liquid mixture is characterized in that the ocher nano solid content is 30% by weight, PH 8-9, particle size 40-50nm.

본 발명은 원적외선 방사를 통해 인체에 유익하고, 각종 아토피 등의 피부질환에 대해 우수한 자정효과가 있는 황토를 나노입도로 형성함으로써, 라텍스 발포에 따른 균질한 발포성형이 가능하면서 원적외선 방사의 기능이 추가되고, 라텍스폼의 발포 및 성형시, 황토나노 입자를 고르게 분포하도록 발포함에 따라 황토입자가 외부로 묻어나지 않아 청결하고 깨끗한 라텍스폼의 구현이 가능하며, 내구성이 증대되고, 라텍스 본연의 탄성력을 그대로 유지가 가능한 효과가 있다.
The present invention is beneficial to the human body through the far-infrared radiation, and by forming the ocher with nanoparticles having excellent self-cleaning effect against various skin diseases such as atopic dermatitis, homogeneous foam molding according to latex foaming is possible while the function of far-infrared radiation is added. When foaming and forming latex foam, the ocher nanoparticles are foamed so as to distribute the ocher nanoparticles evenly so that clean and clean latex foam can be realized, durability is increased, and natural elasticity of latex is improved. The effect can be maintained as it is.

도 1은 본 발명에 따른 황토나노 라텍스폼 제조방법 블럭도이다.1 is a block diagram of a manufacturing method of ocher nano latex foam according to the present invention.

이하, 첨부된 도면을 참조로 본 발명에 따른 황토나노 라텍스폼 제조방법 및 그에 따른 황토나노 라텍스폼에 대하여 상세히 설명한다.
Hereinafter, with reference to the accompanying drawings will be described in detail with respect to the ocher nano latex foam manufacturing method and the ocher nano latex foam according to the present invention.

본 발명에 따른 황토나노 라텍스폼 제조방법은 도 1에 나타난 바와 같이, 액상혼합1단계(S100), 액상혼합2단계(S200), 교반함침단계(S300), 발포성형단계(S400), 완제품생산단계(S500)를 통해 원적외선 방사가 가능하고, 라텍스 본연의 탄성복원력이 뛰어나 인체의 곡선에 대응하여 숙면을 취할 수 있을 뿐만 아니라 황토입자가 묻어나지 않아 침구류 등의 오염을 방지할 수 있어 주변환경이 청결하고, 내구성이 우수한 황토나노 라텍스폼의 생산이 가능하다.
As shown in Figure 1, the ocher nano latex foam manufacturing method according to the present invention, liquid mixing step 1 (S100), liquid mixing step 2 (S200), stirring impregnation step (S300), foam molding step (S400), finished product production Far-infrared radiation is possible through the step (S500), excellent elastic resilience of latex, can not only take a good night's sleep in response to the curve of the human body, but also prevent the contamination of bedding, etc., because the ocher particles are not buried It is possible to produce this clean, durable yellow earth nano latex foam.

여기서, 상기 황토나노 라텍스폼을 생산하기 위한 방법은 위 상술한 바와 같은 순서를 통해 생산이 되는 것으로, 상기 액상혼합1단계(S100)는 황토입자크기가 40~50nm인 황토나노로 미세 가공하여 물 또는 액상의 혼합제와 혼합하는 것으로, 상기 황토나노는 황토나노 고형분이 30중량%, PH 8~9, 입자크기 40~50nm 이다.
Here, the method for producing the ocher nano latex foam is to be produced through the order as described above, the liquid mixing step 1 (S100) is finely processed into ocher nanoparticles of the ocher particle size 40 ~ 50nm water Or by mixing with a liquid mixture, the ocher nano is the ocher nano solid content of 30% by weight, PH 8 ~ 9, particle size 40 ~ 50nm.

상기 액상혼합2단계(S200)는 앞서 액상혼합1단계를 통해 물 또는 용액과 함께 희석된 나노입자의 황토나노 용액을 가류제 및 촉진제와 혼합가공하여 가류제 및 촉진제의 표면에 황토나노 입자가 흡착되어 혼합되도록 한다. 여기서, 라텍스 원액의 탄성력과 내구성을 부여하는 가류제와 가류시 발생되는 온도를 낮추고 가류시간을 단축하기 위한 촉진제는 통상의 것으로, 폴리머계열의 폴리머바운드를 가류제로 사용하고, 촉진제로는 엠비티(MBT ; Mercapto benzo thiazole), 디티(DT ; Di-toly guanidine) 등이 주로 사용된다.
In the liquid phase mixing step (S200), the ocher nanoparticles are adsorbed onto the surface of the vulcanizing agent and the accelerator by mixing and processing the yellow earth nano solution of the nanoparticles diluted with water or the solution through the liquid phase mixing step 1 with the vulcanizing agent and the accelerator. To mix. Here, the vulcanizing agent which gives elasticity and durability of the latex stock solution and the accelerator for lowering the temperature and the vulcanization time generated during the vulcanization are conventional, and the polymer-based polymer bound is used as the vulcanizing agent. MBT; Mercapto benzo thiazole) and DT (Di-toly guanidine) are mainly used.

상기 교반함침단계(S300)는 라텍스원액과 황토나노입자가 외부로 묻어나지 않고, 황토의 기능과 라텍스의 기능을 올바르게 수행하도록 교반혼합하는 것으로, 라텍스 원액에 탄성, 신장성을 향상시키고 경화하기 위한 가황제, 라텍스폼의 입자수 및 입자 크기의 분포조절을 위한 계면활성제와 라텍스폼의 산화방지를 위한 산화방지제, 노화방지제, 충진제를 포함하는 첨가제를 투입, 혼합한 상기 라텍스 원액에 상기 액상화된 황토나노 첨가물을 교반혼합하여 라텍스 원액 내부에 황토나노입자가 고르게 함침된다.
The stirring impregnation step (S300) is to mix the stirring so that the latex stock solution and the ocher nanoparticles do not bury the outside, and correctly perform the function of the ocher and the latex, to improve the elasticity, stretchability and curing in the latex stock solution The liquefied loess was added to the latex stock solution containing a mixture of a vulcanizing agent, a surfactant for controlling the distribution of particle number and particle size of the latex foam, and an antioxidant, an antioxidant, and a filler to prevent oxidation of the latex foam. By stirring and mixing the nano additives, the ocher nanoparticles are evenly impregnated into the latex stock solution.

이와 같이 교반함에 따라 상기 황토나노 라텍스 혼합물은 라텍스 80중량%, 가황제 9.0중량%, 계면활성제 10.0중량%, 첨가제 1.0중량%로 혼합된 원액 100중량부를 기준으로 황토나노 0.5~20중량% 만큼 사용되는 것으로, 황토나노 사용량이 20중량% 이상의 경우에는 황토나노의 함량이 높아 원적외선 방사능력이 뛰어나나 라텍스의 에어셀 생성이 떨어지고, 이에 따라 통풍성 및 탄성복원력이 떨어지는 문제점이 있어 인체를 고르게 받치기 위한 라텍스의 쿠션기능이 저하되는 반면 황토나노가 0.5중량%미만이 사용될 경우 라텍스 본연의 기능은 우수하나 황토나노의 원적외선 방사율은 현저히 떨어진다.
As such, the yellow clay nano latex mixture is used by 0.5 to 20% by weight of yellow clay based on 100 parts by weight of the stock solution mixed with 80% by weight of latex, 9.0% by weight of vulcanizing agent, 10.0% by weight of surfactant, and 1.0% by weight of additive. If the amount of ocher nano is more than 20% by weight, the content of ocher nano is high and the far infrared radiation ability is excellent, but the air cell generation of latex is deteriorated, and thus the air permeability and elastic restoring force are deteriorated. While the cushion function of the yellow ocher nano less than 0.5% by weight is used, the latex intrinsic function is excellent, but the far-infrared emissivity of ocher nano remarkably falls.

상기 발포성형단계(S400)는 통상의 라텍스폼 발포성형과 동일한 과정을 거치게 되는 것으로, 상기 혼합된 황토나노 라텍스 혼합물을 적절한 양의 거품을 생성시키기 위한 발포기를 이용하여 발포한 후, 라텍스 성형금형 내에 주입하여 성형한다.
The foam molding step (S400) is to go through the same process as a conventional latex foam foam molding, and then foamed the mixed ocher nano latex mixture by using a foamer to generate an appropriate amount of foam, into a latex molding mold Inject and mold.

상기 완제품생산단계(S500)는 성형금형을 통해 성형된 황토나노 라텍스를 건조하여 원적외선 방사 황토나노 라텍스 완제품을 생산한다.
The finished product production step (S500) is to dry the ocher nano latex molded through a molding mold to produce a far-infrared radiation ocher nano latex finished product.

이와 같은 과정을 통해 생산되는 황토나노 라텍스폼은 황토입자크기가 40~50nm인 황토나노로 미세 가공하여 액상의 혼합제와 혼합하고, 상기 액상의 혼합제과 혼합된 황토나노를 가류제 및 촉진제와 혼합 가공함으로써, 가류제 및 촉진제의 표면에 상기 황토나노를 흡착시켜 액상화하며, 라텍스 원액에 가황제, 계면활성제, 첨가제를 투입 혼합한 상기 라텍스 원액에 상기 액상화된 황토나노 첨가물을 교반혼합하여 함침한 후, 상기 혼합된 황토나노 라텍스 혼합물을 라텍스 성형금형 으로 발포 및 성형, 건조하여 원적외선 방사가 가능한 것으로, 황토나노 라텍스폼을 대량 생산하는 것이 가능함은 물론, 황토의 원적외선 방사능력에 의해 인체에 이로운 효과, 혈액순환 및 세포활성화가 가능함은 물론, 통기성기능, 탄성복원능력에 의한 인체곡선에 대응되어 숙면을 취할 수 있고, 함침을 통한 라텍스와 황토의 혼합에 의해 외부로 황토가 묻어나지 않아 깨끗하고 청결한 황토나노 라텍스폼의 제공이 가능한 것은 자명하다.
The ocher nano latex foam produced through the above process is finely processed into ocher nanoparticles having an ocher particle size of 40 to 50 nm, mixed with a liquid mixture, and mixed with ocher nanoparticles and a promoter with a vulcanizing agent and an accelerator. By adsorbing and liquefying the yellow earth nanoparticles on the surface of the vulcanizing agent and the accelerator, the latex stock solution containing the vulcanizing agent, the surfactant, and the additive is added to the latex stock solution by stirring and impregnating the liquefied yellow earth nano additives. It is possible to produce far-infrared radiation by foaming, molding and drying the mixed ocher nano latex mixture into a latex molding mold, and it is possible to mass produce the ocher nano latex foam, as well as the beneficial effect to the human body by the far-infrared radiation ability of ocher, blood Circulation and cell activation are possible, as well as responding to the human curve by breathable function and elastic restoring ability Air and sound sleep to take, is by mixing the latex with yellow earth impregnated with not born loess is possible to bury a clear, clean ocher provide nano-latex form to the outside is evident.

한편, 본 발명의 상세한 설명에서는 구체적인 실시예에 관해서 설명하였으나, 본 발명의 범위에서 벗어나지 않는 한도 내에서 여러가지 변형이 가능함을 당해 분야에서 통상의 지식을 가진자에게 있어서, 그와 같은 변형은 청구 범위 기재의 범위 내에 있는 것이다.
While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it will be understood by those skilled in the art that various changes and modifications may be made without departing from the scope of the invention as defined in the appended claims. Is within the scope of the description.

S100 : 액상혼합1단계 S200 : 액상혼합2단계
S300 : 교반함침단계 S400 : 발포성형단계
S500 : 완제품생산단계S100: liquid phase mixing step 1 S200: liquid phase mixing step 2
S300: stirring impregnation step S400: foam molding step
S500: Finished product production stage

Claims (6)

황토입자크기가 40~50nm인 황토나노로 미세 가공하여 물 또는 액상의 혼합제와 혼합하는 액상혼합1단계(S100)와;
상기 물 또는 액상의 혼합제과 혼합된 황토나노를 가류제 및 촉진제와 혼합 가공함으로써, 가류제 및 촉진제의 표면에 상기 황토나노를 흡착시켜 액상화하는 액상혼합2단계(S200)와;
라텍스 원액에 탄성, 신장성을 향상시키고 경화하기 위한 가황제, 라텍스폼의 입자수 및 입자 크기의 분포조절을 위한 계면활성제와 라텍스폼의 산화방지를 위한 산화방지제, 노화방지제, 충진제를 포함하는 첨가제를 투입, 혼합한 상기 라텍스 원액에 상기 액상화된 황토나노 첨가물을 교반혼합하여 함침하는 교반함침단계(S300)와;
상기 혼합된 황토나노 라텍스 혼합물을 라텍스 성형금형으로 발포 및 성형하는 발포성형단계(S400)와;
상기 발포 및 성형된 황토나노 라텍스를 건조하여 원적외선 방사 황토나노 라텍스 완제품을 생산하는 완제품생산단계(S500);를 포함하는 것을 특징으로 하는 황토나노 라텍스폼 제조방법.
A liquid mixing step 1 (S100) for fine processing into ocher nanoparticles having an ocher particle size of 40 to 50 nm and mixing with a water or liquid mixture;
A liquid phase mixing step (S200) of adsorbing the yellow earth nanoparticles on the surface of the vulcanizing agent and the accelerator to liquefy by mixing and processing the yellow clay mixed with the water or liquid phase mixing agent with a vulcanizing agent and an accelerator;
Additives including vulcanizing agents for improving and curing elasticity and extensibility in latex stocks, surfactants for controlling particle number and particle size distribution of latex foams, and antioxidants, antioxidants, and fillers for preventing oxidation of latex foams. A stirring impregnation step (S300) of impregnating by mixing the liquid liquefied yellow earth nano additives into the mixed latex stock solution;
Foaming and molding the mixed ocher nano latex mixture into a latex molding mold (S400);
A process for producing ocher nano latex foam, comprising: a finished product producing step (S500) of producing the finished product of far-infrared radiation ocher nano latex by drying the foamed and molded ocher nano latex.
제 1항에 있어서,
상기 황토나노 라텍스 혼합물은 라텍스 80.0중량%, 가황제 9.0중량%, 계면활성제 10.0중량%, 첨가제 1.0중량%로 혼합된 원액 100중량부를 기준으로 황토나노가 0.5~20중량% 만큼 포함사용되는 것을 특징으로 하는 황토나노 라텍스폼 제조방법.
The method of claim 1,
The yellow clay nano latex mixture is based on 100% by weight of the stock solution mixed with 80.0% by weight of latex, 9.0% by weight of vulcanizing agent, 10.0% by weight of surfactant, 1.0% by weight of additives, characterized in that it is used by 0.5 to 20% by weight. Ocher nano latex foam manufacturing method.
제 1항에 있어서,
물 또는 액상의 혼합제와 혼합된 액상의 상기 황토나노는 황토나노 고형분이 30중량%, PH 8~9, 입자크기 40~50nm 인 것을 특징으로 하는 황토나노 라텍스폼 제조방법.
The method of claim 1,
The ocher nanoparticles in the liquid phase mixed with water or a liquid mixture is ocher nano latex foam, characterized in that the ocher nano solids content of 30% by weight, PH 8-9, particle size 40 ~ 50nm.
황토입자크기가 40~50nm인 황토나노로 미세 가공하여 액상의 혼합제와 혼합하고, 상기 액상의 혼합제과 혼합된 황토나노를 가류제 및 촉진제와 혼합 가공함으로써, 가류제 및 촉진제의 표면에 상기 황토나노를 흡착시켜 액상화하며, 라텍스 원액에 가황제, 계면활성제, 첨가제를 투입 혼합한 상기 라텍스 원액에 상기 액상화된 황토나노 첨가물을 교반혼합하여 함침한 후, 상기 혼합된 황토나노 라텍스 혼합물을 라텍스 성형금형 내에서 발포 및 성형, 건조하여 원적외선 방사가 가능한 것을 특징으로 하는 황토나노 라텍스폼.
The ocher particles are finely processed into ocher nanoparticles having a particle size of 40 to 50 nm and mixed with the liquid mixture, and the ocher nanoparticles mixed with the liquid mixture are mixed with the vulcanizing agent and the accelerator to form the ocher nanoparticles on the surface of the vulcanizing agent and the accelerator. After adsorbing and liquefying, the latex stock solution containing a vulcanizing agent, a surfactant, and an additive was mixed and immersed in the latex stock solution by stirring and impregnating the liquefied yellow earth nanoadditive, and then mixing the mixed yellow earth latex mixture in a latex molding mold. Yellow earth nano latex foam, characterized in that the far-infrared radiation is possible by foaming, molding, and drying.
제 4항에 있어서,
상기 황토나노 라텍스 혼합물은 라텍스 80중량%, 가황제 9.0중량%, 계면활성제 10.0중량%, 첨가제 1.0중량%로 혼합된 원액 100중량부를 기준으로 황토나노 0.5~20중량% 만큼 사용되는 것을 특징으로 하는 황토나노 라텍스폼.
5. The method of claim 4,
The yellow clay nano latex mixture is used by 0.5 to 20% by weight of yellow clay based on 100 parts by weight of the stock solution mixed with 80% by weight latex, 9.0% by weight vulcanizing agent, 10.0% by weight surfactant, 1.0% by weight additive. Yellow earth nano latex foam.
제 1항에 있어서,
물 또는 액상의 혼합제와 혼합된 액상의 상기 황토나노는 황토나노 고형분이 30중량%, PH 8~9, 입자크기 40~50nm 인 것을 특징으로 하는 황토나노 라텍스폼.
The method of claim 1,
The ocher nanoparticles in the liquid phase mixed with water or a liquid mixture is ocher nano latex foam, characterized in that the ocher nano solid content is 30% by weight, PH 8-9, particle size 40 ~ 50nm.
KR1020110097866A 2011-09-27 2011-09-27 Manufacture method of loess nano latex foam and loess nano latex foam thereof KR101378491B1 (en)

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