KR20130030696A - Soap powder composition having effect of improving skin - Google Patents
Soap powder composition having effect of improving skin Download PDFInfo
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- KR20130030696A KR20130030696A KR1020110094336A KR20110094336A KR20130030696A KR 20130030696 A KR20130030696 A KR 20130030696A KR 1020110094336 A KR1020110094336 A KR 1020110094336A KR 20110094336 A KR20110094336 A KR 20110094336A KR 20130030696 A KR20130030696 A KR 20130030696A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
- A61K8/022—Powders; Compacted Powders
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/06—Inorganic compounds
- C11D9/08—Water-soluble compounds
- C11D9/10—Salts
- C11D9/12—Carbonates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/26—Organic compounds, e.g. vitamins containing oxygen
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
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Abstract
Description
본 발명은 피부개선 효과가 우수한 가루비누 조성물에 관한 것으로, 더욱 상세하게는 탄산수소나트륨 분말, 분말형 산 및 비누분말로 이루어진다.
The present invention relates to a powdered soap composition having an excellent skin improvement effect, and more particularly, consisting of sodium bicarbonate powder, powdered acid and soap powder.
본 발명은 피부개선 효과가 우수한 가루비누 조성물에 관한 것으로, 더욱 상세하게는 탄산수소나트륨 분말, 분말형 산 및 비누분말로 이루어진다.The present invention relates to a powdered soap composition having an excellent skin improvement effect, and more particularly, consisting of sodium bicarbonate powder, powdered acid and soap powder.
비누란 주로 세정에 사용되는 고급지방산의 수용성 알칼리 금속염을 총칭하는 것으로, 원료유지를 수산화 알칼리로 비누화하든가, 적당한 방법으로 얻은 지방산을 알칼리로 중화시켜 만든다. 알칼리비누의 주체는 소비량으로 보아 나트륨염인데, 소다비누 또는 경성비누라고 하며, 칼륨염은 칼륨비누 또는 연성비누라 한다. 알칼리비누는 무수 상태에서는 일반적으로 에탄올 이외의 유기용제에는 잘 녹지 않으나, 함수비누는 벤진, 크레졸 등에 녹는 것도 있고, 함수량, 대기의 상대습도, 온도 등에 따라 습기를 흡수하기도 하고 건조하기도 한다. 이 성질은 구성 지방산의 종류에 따라 현저하게 다른데, 일반적으로 저급 지방산과 불포화 지방산인 경우와 칼륨염인 경우에 습기를 흡수하기 쉽다. 비누는 수용액 속에서 농도가 낮으면 분자상태로 분산되어 있으나, 농도가 높아지면 분자와 회합하여 미셀을 형성하고 콜로이드와 같은 행동을 한다. 미셀을 형성하기 시작하는 농도를 임계 미셀 농도라고 하는데, 비누 분자의 종류, 온도, 공존물 등에 따라 약간 변동하며, 물 속에서 가수분해하며 용액의 pH는 일반적으로 9가 넘는다. 수용액에 알칼리나 알칼리염을 가하면 비누분이위층으로 분리되는 데 이 조작을 염석이라 하며, 경성비누의 제조공정상 중요하다. 또, 비누 분자는 친수기와 소수기를 동시에 가지고 있기 때문에 큰 계면활성을 지닌다.Soap is a general term for water-soluble alkali metal salts of higher fatty acids mainly used for washing, and is made by saponifying raw material oils with alkali hydroxides or neutralizing fatty acids obtained by appropriate methods with alkalis. Alkaline soap is mainly consumed in terms of sodium salt, soda soap or hard soap, and potassium salt is called potassium soap or soft soap. Alkali soap is generally insoluble in organic solvents other than ethanol in anhydrous state, but water-soluble soap is soluble in benzine, cresol, etc., and absorbs moisture and dries depending on moisture content, relative humidity of air, temperature and so on. This property is remarkably different depending on the kind of constituent fatty acids. In general, it is easy to absorb moisture in the case of lower and unsaturated fatty acids and potassium salts. Soap is dispersed in aqueous state at low concentration in aqueous solution, but at higher concentration it is associated with molecules to form micelles and behaves like colloid. The concentration at which micelles begin to form is called the critical micelle concentration, which varies slightly depending on the type, temperature and coexistence of soap molecules, hydrolyzes in water, and the pH of the solution is generally above 9. When alkali or alkali salt is added to the aqueous solution, the soap powder is separated into the stomach layer. This operation is called salting stone, and is important for the manufacturing process of hard soap. In addition, since the soap molecule has both hydrophilic and hydrophobic groups at the same time, it has a large surfactant.
그러나, 전술한 종래에 비누 조성물 들은 피부표면에 잔존하는 노폐물을 세척하는 기능을 주로 하기 때문에, 비누로 세척된 피부에 주름개선 화장품과 같은 별도의 조성물을 처리해야 하는 번거로움이 있었다.
However, since the soap compositions in the related art have a function of washing the wastes remaining on the skin surface, there has been a need to treat a separate composition such as an antiwrinkle cosmetic on the soap-washed skin.
본 발명의 목적은 물과 반응하면 이산화탄소를 발생시켜, 보어효과로 인한 주름개선 기능을 제공하는 피부개선 효과가 우수한 가루비누 조성물을 제공하는 것이다.An object of the present invention is to provide a powdered soap composition excellent in skin improvement effect to generate a carbon dioxide when reacted with water, thereby providing a wrinkle improvement function due to the bore effect.
본 발명의 다른 목적은 물과 반응하면 이산화탄소를 발생시켜, 보어효과로 인해 피부 모세혈관의 혈액순환을 원활하게 하여 피부트러블을 예방할 수 있는 피부개선 효과가 우수한 가루비누 조성물을 제공하는 것이다.
Another object of the present invention is to provide a powdered soap composition excellent in skin improvement effect to prevent skin troubles by generating carbon dioxide when reacted with water, thereby smoothing the blood circulation of the skin capillaries due to the bore effect.
본 발명의 목적은 탄산수소나트륨 분말, 분말형 산 및 비누분말로 이루어지는 것을 특징으로 하는 피부개선 효과가 우수한 가루비누 조성물을 제공함에 의해 달성된다.An object of the present invention is achieved by providing a powder soap composition excellent in skin improvement effect, characterized in that consisting of sodium hydrogen carbonate powder, powdered acid and soap powder.
본 발명의 바람직한 특징에 따르면, 상기 피부개선 효과가 우수한 가루비누 조성물은 탄산수소나트륨 분말 1 내지 10 중량부, 분말형 산 1 내지 10 중량부 및 비누분말 90 내지 98 중량부로 이루어지는 것으로 한다.According to a preferred feature of the present invention, the powder soap composition excellent in skin improvement effect is composed of 1 to 10 parts by weight of sodium bicarbonate powder, 1 to 10 parts by weight of powdered acid and 90 to 98 parts by weight of soap powder.
본 발명의 더 바람직한 특징에 따르면, 상기 분말형 산은 구연산 및 숙신산으로 이루어진 그룹으로부터 선택된 하나 이상으로 이루어지는 것으로 한다.
According to a more preferred feature of the invention, the powdered acid is to be composed of one or more selected from the group consisting of citric acid and succinic acid.
본 발명에 따른 피부개선 효과가 우수한 가루비누 조성물은 물과 반응하면 이산화탄소를 발생시켜, 보어효과로 인한 주름개선 기능을 제공하는 탁월한 효과를 나타낸다.Powder soap composition excellent in skin improvement effect according to the present invention generates carbon dioxide when reacted with water, showing an excellent effect of providing a wrinkle improvement function due to the bore effect.
또한, 목적은 물과 반응하면 이산화탄소를 발생시켜, 보어효과로 인해 피부 모세혈관의 혈액순환을 원활하게 하여 피부트러블을 예방할 수 있는 탁월한 효과를 나타낸다.
In addition, the purpose is to produce carbon dioxide when reacted with water, and exhibits an excellent effect of preventing skin trouble by smoothing the blood circulation of skin capillaries due to the bore effect.
도 1은 본 발명에 따른 피부개선 효과가 우수한 가루비누 조성물의 적용부위별 세안 전후의 모공, 색소침착(PL) 및 주름을 나타낸 그래프이다.(31세 남성)
도 2는 본 발명에 따른 피부개선 효과가 우수한 가루비누 조성물의 적용부위별 세안 전후의 모공, 색소침착(PL) 및 주름을 나타낸 그래프이다.(32세 남성)
도 3은 본 발명에 따른 피부개선 효과가 우수한 가루비누 조성물의 적용부위별 세안 전후의 모공, 색소침착(PL) 및 주름을 나타낸 그래프이다.(38세 남성)
도 4는 본 발명에 따른 피부개선 효과가 우수한 가루비누 조성물의 세안 전후의 피부상태를 나타낸 사진이다.(31세 남성)
도 5는 본 발명에 따른 피부개선 효과가 우수한 가루비누 조성물의 세안 전후의 피부상태를 나타낸 사진이다.(32세 남성)
도 6은 본 발명에 따른 피부개선 효과가 우수한 가루비누 조성물의 세안 전후의 피부상태를 나타낸 사진이다.(38세 남성)1 is a graph showing pores, pigmentation (PL) and wrinkles before and after washing by application areas of the powder soap composition having excellent skin improvement effect according to the present invention.
Figure 2 is a graph showing pores, pigmentation (PL) and wrinkles before and after washing by application area of the powder soap composition excellent in skin improvement effect according to the present invention. (32-year-old male)
Figure 3 is a graph showing pores, pigmentation (PL) and wrinkles before and after washing by application area of the powder soap composition excellent skin improvement effect according to the present invention. (38 year old male)
Figure 4 is a photograph showing the skin condition before and after washing of the powder soap composition excellent skin improvement effect according to the present invention.
Figure 5 is a photograph showing the skin condition before and after washing the powder soap composition excellent skin improvement effect according to the present invention. (32 year old male)
Figure 6 is a photograph showing the skin condition before and after washing the powder soap composition excellent skin improvement effect according to the present invention. (38 year old male)
이하에는, 본 발명의 바람직한 실시예와 각 성분의 물성을 상세하게 설명하되, 이는 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 발명을 용이하게 실시할 수 있을 정도로 상세하게 설명하기 위한 것이지, 이로 인해 본 발명의 기술적인 사상 및 범주가 한정되는 것을 의미하지는 않는다.
Hereinafter, preferred embodiments of the present invention and physical properties of the respective components will be described in detail with reference to the accompanying drawings. However, the present invention is not limited thereto, And this does not mean that the technical idea and scope of the present invention are limited.
본 발명에 따른 피부개선 효과가 우수한 가루비누 조성물은 탄산수소나트륨 분말, 분말형 산 및 분말가루비누로 이루어지며, 탄산수소나트륨 분말 1 내지 10 중량부, 분말형 산 1 내지 10 중량부 및 비누분말 80 내지 98 중량부로 이루어지는 것이 더욱 바람직하다.
Powder soap composition excellent in skin improvement effect according to the present invention consists of sodium hydrogen carbonate powder, powdered acid and powdered soap, 1 to 10 parts by weight of sodium hydrogen carbonate powder, 1 to 10 parts by weight of powdered acid and soap powder More preferably, it consists of 80-98 weight part.
전술한 탄산수소나트륨 분말은 1 내지 10 중량부가 함유되며, 본 발명에 따른 피부개선 효과가 우수한 가루비누 조성물을 물과 혼합하여 피부에 적용하면, 전술한 분말형 산과 반응하여 이산화탄소를 발생시키는데, 이러한 과정을 통해 발생된 이산화탄소는 피부 내부로 보내져 진피층의 보어효과를 유도하여 모세혈관으로부터 산소의 원활한 공급으로 인해 진피층 피부세포가 분화하는 효율을 향상시켜준다.The above-mentioned sodium hydrogen carbonate powder contains 1 to 10 parts by weight, and when applied to the skin by mixing the powdered soap composition excellent in skin improvement effect according to the present invention with water, it reacts with the powdered acid described above to generate carbon dioxide. Carbon dioxide generated through the process is sent to the inside of the skin to induce a bore effect of the dermal layer to improve the efficiency of differentiation of the dermal skin cells due to the smooth supply of oxygen from the capillaries.
전술한 보어효과는 헤모글로비과 같은 산소운반기능을 갖는 물질이 수용액 또는 혈액 속에 있을 때, 이산화탄소 분압이 상승하거나 또는 pH가 저하되면 산소분압에 변화가 없어도 산소포화도가 감소하여 산소가 전달체에서 쉽게 분리되는 현상으로, B.Bohr가 발견하여 헤모글로빈이 산소와 결합하면 혈액을 유지하는 이산화탄소량이 정하되는 Haldane 효과와 더블어 Bohr-Haldane effect라고 한다.The bore effect described above is that when a substance having an oxygen transport function such as hemoglobi is in an aqueous solution or blood, when the carbon dioxide partial pressure rises or the pH decreases, the oxygen saturation decreases even though there is no change in the oxygen partial pressure, and oxygen is easily separated from the carrier. It is known that B.Bohr discovered that when hemoglobin combines with oxygen, it is called Haldane effect and double Bohr-Haldane effect that regulates the amount of carbon dioxide that maintains blood.
이 효과는 산소를 운반하는 헤모글로빈이 이산화탄소가 많은 체내에 조직으로 산소를 운반하고, 폐에서는 헤모글로빈이 산소와 같이 이산화탄소를 방출하는데 유리하다.This effect is beneficial for the oxygen-carrying hemoglobin to transport oxygen to the tissue in the carbon dioxide-rich body, and in the lungs, hemoglobin releases carbon dioxide like oxygen.
산소포화도가 50%가 될 때의 산소분압을 P50으로 나타내면 보어효과의 크기는 DlogP50/DpH로 나타낼 수 있다.
When the oxygen partial pressure at 50% oxygen saturation is expressed as P50, the magnitude of the bore effect can be expressed as DlogP50 / DpH.
전수한 분말형 산은 1 내지 10 중량부가 함유되며, 구연산 및 숙신산으로 이루어진 그룹으로부터 선택된 하나 이상으로 이루어지는데, 본 발명에 따른 피부개선 효과가 우수한 가루비누 조성물을 물과 혼합하여 피부에 적용하면, 전술한 탄산칼슘분말과 반응하여 이산화탄소를 발생시키는데, 이러한 과정을 통해 발생된 이산화탄소는 피부 내부로 보내져 진피층의 보어효과를 유도하여 모세혈관으로부터 산소의 원활한 공급으로 인해 진피층 피부세포가 분화하는 효율을 향상시켜준다.
The transferred powdered acid contains 1 to 10 parts by weight, and is composed of one or more selected from the group consisting of citric acid and succinic acid. When the powdered soap composition having excellent skin improvement effect according to the present invention is mixed with water and applied to the skin, It reacts with calcium carbonate powder to produce carbon dioxide. The carbon dioxide generated through this process is sent to the inside of the skin to induce a bore effect on the dermis, which improves the efficiency of differentiation of dermal skin cells due to the smooth supply of oxygen from capillaries. .
전술한 탄산수소나트륨 분말과 분말형 산이 함유된 피부개선 효과가 우수한 가루비누 조성물이 물과 반응했을 때, 이산화탄소가 발생하는 과정을 아래 반응식으로 나타내었다.When the powdered soap composition having excellent skin improvement effect containing the aforementioned sodium bicarbonate powder and powdered acid reacted with water, a process of generating carbon dioxide is shown by the following reaction formula.
NaHCO3 + H2O → Na+ + HCO3 - NaHCO 3 + H 2 O → Na + + HCO 3 -
RCOOH + H2O → RCOO- + H+ RCOOH + H 2 O → RCOO - + H +
H+ + HCO3 - → H2CO3 →H2O + CO2(g)
H + + HCO 3 - → H 2 CO 3 → H 2 O + CO 2 (g)
전술한 비누분말은 80 내지 98 중량부가 함유되는데, 전술한 비누분말은 비누의 원료로 많이 사용되는 것으로서, 당업자에게는 용이하게 구입하여 사용할 수 있을 정도로 공지된 것이면 어떠한 것이든 사용가능하다.The above-mentioned soap powder contains 80 to 98 parts by weight, and the above-mentioned soap powder is used as a raw material of soap, and any one can be used as long as it is known enough to be easily purchased and used by those skilled in the art.
더욱 바람직하게는, 전술한 비누분말은 공지의 비누화반응을 통하여 팜유를 이용하여 비누화시켜 수득되는 것을 사용할 수 있으며, 본 발명에 따른 피부개선 효과가 우수한 가루비누 조성물의 기본적인 주성분의 하나로서, 그 자체로서 세정작용 등 비누로서의 기능을 나타내는데, 전술한 세정작용 이외에도 탄산수소나트륨 분말 및 분말형 산을 수용하는 담체의 역할을 한다.
More preferably, the above-described soap powder can be used by saponification using palm oil through a known saponification reaction, and as one of the basic main components of the powder soap composition excellent in the skin improvement effect according to the present invention, It functions as a soap, such as a washing action, and serves as a carrier for receiving sodium bicarbonate powder and powdered acid in addition to the washing action described above.
이하에서는, 본 발명에 따른 피부개선 효과가 우수한 가루비누 조성물의 제조방법 및 물성을 실시예를 들어 설명한다.
Hereinafter, the production method and physical properties of the powder soap composition excellent in the skin improvement effect according to the present invention will be described with reference to Examples.
<실시예><Examples>
탄산수소나트륨 분말 5 중량부, 구연산 5 중량부 및 비누분말 80 중량부를 교반기로 30 분간 혼합하여 피부개선 효과가 우수한 가루비누 조성물을 제조하였다.
5 parts by weight of sodium bicarbonate powder, 5 parts by weight of citric acid and 80 parts by weight of soap powder were mixed with a stirrer for 30 minutes to prepare a powder soap composition excellent in skin improvement effect.
전술한 실시예를 통해 제조된 피부개선 효과가 우수한 가루비누 조성물을 이용하여 피부를 세안한 후에 모공, 색소침착(PL) 및 주름을 T존, 눈가 및 볼 등과 같이 부위별로 측정하여 그 평균값을 아래 표 1에 나타내었다.After washing the skin using the powder soap composition having excellent skin improvement effect prepared through the above-described embodiments, pores, pigmentation (PL) and wrinkles are measured for each part such as T zone, eyes and cheeks, and the average value is below. Table 1 shows.
(단, 모공, 색소침착 및 주름의 측정은 채영수피부과의원에서 측정하였으며, 31살, 32살 및 38살 남성 3인을 피실험대상으로 실시하였다.)
(However, pores, pigmentation and wrinkles were measured by Chae Young-su Dermatology Clinic, and three men aged 31, 32, and 38 were tested.)
<표 1>TABLE 1
위에 표 1에 나타낸 것처럼 본 발명에 따른 피부개선 효과가 우수한 가루비누 조성물로 세안한 피 실험자들은 모공, 색소침착 및 주름 등이 개선된 것을 알 수 있다.As shown in Table 1 above, the test subjects washed with the powder soap composition having excellent skin improvement effect according to the present invention can see that pores, pigmentation and wrinkles are improved.
또한, 전술한 실험결과에 따른 피 실험대상자들의 피부를 부위별로 측정한 결과를 아래 도 1 내지 3에 나타내었으며, 피 실험대상자들의 피부를 사진 촬영하여 아래 도 4 내지 6에 나타내었다.In addition, the results of measuring the skin of the test subjects according to the above-described test results by region are shown in FIGS. 1 to 3 below, and photographed the skin of the test subjects is shown in FIGS. 4 to 6 below.
아래 도 1 내지 도 6에 나타낸 것처럼 본 발명에 따른 피부개선 효과가 우수한 가루비누 조성물은 피 실험대상자들의 피부를 개선하는 것을 알 수 있다.1 to 6 below, the powder soap composition having excellent skin improvement effect according to the present invention can be seen to improve the skin of the test subjects.
Claims (3)
Powdered soap composition excellent in skin improvement effect, characterized in that consisting of sodium hydrogen carbonate powder, powdered acid and soap powder.
상기 피부개선 효과가 우수한 가루비누 조성물은 탄산수소나트륨 분말 1 내지 10 중량부, 분말형 산 1 내지 10 중량부 및 비누분말 80 내지 98 중량부로 이루어지는 것을 특징으로 하는 피부개선 효과가 우수한 가루비누 조성물.
The method according to claim 1,
The powder soap composition having excellent skin improvement effect is a powder soap composition having excellent skin improvement effect, comprising 1 to 10 parts by weight of sodium bicarbonate powder, 1 to 10 parts by weight of powdered acid, and 80 to 98 parts by weight of soap powder.
상기 분말형 산은 구연산 및 숙신산으로 이루어진 그룹으로부터 선택된 하나 이상으로 이루어지는 것을 특징으로 하는 피부개선 효과가 우수한 가루비누 조성물.The method according to claim 1,
The powdered acid composition is excellent powder soap composition, characterized in that made of one or more selected from the group consisting of citric acid and succinic acid.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20180068522A (en) | 2016-12-14 | 2018-06-22 | 손승호 | Method for producing multipurpose powdered soap and multipurpose powdered soap produced by the method |
| CN109294771A (en) * | 2018-11-30 | 2019-02-01 | 薛冰寒 | Handmade soap and handmade soap prepare mold |
| WO2021132783A1 (en) * | 2019-12-27 | 2021-07-01 | 요시모토알앤디가부시키가이샤 | Foamable cosmetic |
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| JP2005298454A (en) * | 2004-04-16 | 2005-10-27 | Kanebo Ltd | Powdery bath preparation composition |
| JP4970824B2 (en) * | 2006-04-03 | 2012-07-11 | ジョンソン株式会社 | Foaming type powder cleaning composition |
| JP2009126796A (en) * | 2007-11-21 | 2009-06-11 | Shoichi Nakamura | Bath agent for carbon dioxide bath |
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- 2011-09-19 KR KR1020110094336A patent/KR101284753B1/en active IP Right Grant
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20180068522A (en) | 2016-12-14 | 2018-06-22 | 손승호 | Method for producing multipurpose powdered soap and multipurpose powdered soap produced by the method |
| CN109294771A (en) * | 2018-11-30 | 2019-02-01 | 薛冰寒 | Handmade soap and handmade soap prepare mold |
| WO2021132783A1 (en) * | 2019-12-27 | 2021-07-01 | 요시모토알앤디가부시키가이샤 | Foamable cosmetic |
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