KR20120133104A - Mixing method of coal for making cokes - Google Patents

Mixing method of coal for making cokes Download PDF

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KR20120133104A
KR20120133104A KR1020110051611A KR20110051611A KR20120133104A KR 20120133104 A KR20120133104 A KR 20120133104A KR 1020110051611 A KR1020110051611 A KR 1020110051611A KR 20110051611 A KR20110051611 A KR 20110051611A KR 20120133104 A KR20120133104 A KR 20120133104A
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coal
content
ash
ash content
volatile
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KR101267686B1 (en
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이종협
안진영
최주희
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현대제철 주식회사
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/04Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition

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  • Oil, Petroleum & Natural Gas (AREA)
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Abstract

PURPOSE: A coal blending method for manufacturing cokes is provided to stabilize a furnace process by blending different kinds of coal while managing the volatile matter and ash contents of coal according to stack height. CONSTITUTION: A coal blending method for manufacturing cokes is characterized in that coal comprising a plurality of kinds of coal is blended according to stack height while managing the blending index to satisfy predetermined ranges of volatile matter content and ash content. The blending index is set by surveying the gain size of coal according to stack height and the variation of physical properties according to the grain size and calculating weight average values of volatile matter content and ash content based on the physical property variation. [Reference numerals] (AA) Coal type A; (BB) Coal type B; (CC) Coal type C; (DD) Grain size(mm); (EE) Stack height(m)

Description

코크스 제조용 원료탄 배합방법{Mixing method of coal for making cokes}Mixing method of coal for making cokes

본 발명은 코크스 제조용 원료탄 배합방법에 관한 것으로, 더욱 상세하게는 코크스 품질 향상을 위한 코크스 제조용 원료탄 배합방법에 관한 것이다.The present invention relates to a raw coal blending method for coke production, and more particularly to a raw coal blending method for coke production for improving coke quality.

코크스는 고로의 열원으로 사용되는 연료인 동시에 철광석을 환원시키는 환원제의 역할을 한다. 코크스는 석탄을 코크스 오븐 설비에서 가열 건류하여 제조한다. Coke is a fuel used as a heat source for blast furnaces and also serves as a reducing agent for reducing iron ore. Coke is produced by heating and coal drying coal in a coke oven plant.

코크스 제조용 석탄은 건류시에 점결이 잘 이루어질 수 있는 점결성을 가져야하므로 원료로는 역청탄이 많이 사용된다. 코크스 제조에 이용되는 석탄을 일반적인 연료용과 구분하여 원료탄이라 칭한다. Coal making coal has a coking property that can be caking well during dry distillation, so bituminous coal is used as a raw material. Coal used in the coke production is called raw coal separately from general fuels.

본 발명의 목적은 다수의 탄종을 배합하여 코크스를 제조시 코크스 품질 향상을 위해 휘발분과 회분 함량을 기초로 배합지수를 관리하는 코크스 제조용 원료탄 배합방법을 제공하는 것이다.It is an object of the present invention to provide a method for blending coking coal for preparing coke, which manages a blending index based on volatile matter and ash content in order to improve coke quality by preparing a plurality of coal species.

상기한 바와 같은 목적을 달성하기 위한 본 발명의 특징에 따르면, 본 발명은 다수의 석탄 탄종으로 된 원료탄의 배합시 적치높이별로 배합하되, 휘발분 함량, 회분 함량이 설정 범위를 만족하도록 상기 석탄 탄종의 배합지수를 관리한다.According to a feature of the present invention for achieving the object as described above, the present invention is formulated by the stacking height when mixing the raw coal consisting of a plurality of coal coal species, the volatile content, ash content of the coal coal species so as to satisfy the set range Manage the blending index.

상기 배합지수는 적치높이에 따른 각 원료탄의 입도를 조사하는 단계와, 상기 입도에 따른 물성변화를 조사하는 단계와, 상기 조사한 물성변화를 기초로 각 원료탄의 휘발분 함량 및 회분 함량의 가중 평균치를 산출하는 단계를 통해 도출된다.The blending index is a step of investigating the particle size of each raw coal according to the pile height, the step of investigating the change in physical properties according to the particle size, and calculating the weighted average value of the volatile content and ash content of each raw coal based on the investigated physical property change It is derived through the steps.

상기 가중 평균치는 상기 휘발분 함량 및 회분 함량이 설정 범위를 만족하도록 하는 각 탄종의 적치높이별 배합비율이다.The weighted average value is a compounding ratio for each pile type by which the volatile matter content and the ash content satisfy a setting range.

상기 휘발분 함량의 설정 범위는 24~26%이고, 상기 회분 함량의 설정 범위는 0 초과 11.5% 이하이다.The setting range of the volatile matter content is 24 to 26%, and the setting range of the ash content is more than 0 and 11.5% or less.

본 발명의 코크스 제조용 원료탄 배합방법은 다수의 석탄 탄종으로 된 원료탄의 배합시 적치높이별로 휘발분 함량, 회분 함량을 관리하여 석탄 탄종을 배합하므로 코크스 품질 향상 및 유지를 가능하게 하여 고로 공정 안정화를 도모할 수 있는 효과가 있다.The raw coal blending method for coke production of the present invention is to mix the coal coal species by managing the volatile content, ash content according to the appropriate height during the mixing of the raw coal composed of a plurality of coal coal species, so that the coke quality improvement and maintenance can be achieved to stabilize the blast furnace process It can be effective.

도 1은 석탄 탄종(A탄종, B탄종, C탄종)의 적치높이에 따른 입도 변화를 보인 그래프.
도 2는 석탄 탄종(A탄종, B탄종, C탄종)의 적치높이에 따른 휘발분 함량을 보인 그래프.
도 3은 석탄 탄종(A탄종, B탄종, C탄종)의 적치높이에 따른 회분 함량을 보인 그래프.
1 is a graph showing the particle size change according to the stacking height of coal coal species (A coal species, B coal species, C coal species).
Figure 2 is a graph showing the volatile content according to the loading height of coal coal species (A coal species, B coal species, C coal species).
Figure 3 is a graph showing the ash content according to the loading height of coal coal species (A coal species, B coal species, C coal species).

이하, 본 발명의 실시예를 첨부된 도면을 참조하여 상세하게 설명한다. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.

본 발명의 코크스 제조용 원료탄 배합방법은, 다수의 석탄 탄종으로 된 원료탄의 배합시 적치높이별로 배합하되, 휘발분 함량, 회분 함량이 설정 범위를 만족하도록 석탄 탄종의 배합지수를 관리한다.The raw coal blending method for coke production of the present invention is blended for each stacking height at the time of blending the raw coal composed of a plurality of coal coal species, and manages the blending index of coal coal species so that the volatile content, ash content satisfies the setting range.

고로에 사용하는 코크스를 제조하기 위하여 일반적으로 다수 탄종의 석탄이 배합되며, 이 배합탄을 고로 조업에 적합한 코크스로 제조하기 위해서 적치높이별로 휘발분 함량이 24~26%, 회분 함량이 0 초과 11.5% 이하가 되도록 배합지수를 관리한다.In order to manufacture coke for blast furnace, a large number of coals are generally blended, and in order to produce this coal into a coke suitable for blast furnace operation, volatile matter content of 24 to 26% by ash level and ash content exceeding 0 to 11.5% The blending index is controlled to be below.

코크스 품질에 영향을 미치는 인자는 크게 배합탄의 성상과 조업조건으로 구분된다. 배합탄의 성상으로는 유동도, 팽창률, 반사율 등이 대표적이고, 조업조건으로는 파쇄입도, 수분, 장입밀도, 건류온도, 시간 등이 있다.Factors affecting the coke quality are largely divided into the characteristics of coal coal and operating conditions. Typical properties of the coal blend include fluidity, expansion rate, reflectance, and the like, and the operating conditions include crushing degree, moisture, loading density, dry temperature, and time.

배합탄의 성상은 원료 수급 상황에 따라 기준 범위 내에서 조정 가능하고, 조업조건 중 수분함량은 각 공장의 설비에 따라 차이가 있으며, 건류온도와 시간은 코크스 오븐의 구조에 따라 차이가 있다.The properties of blended coal can be adjusted within the standard range according to the supply and demand situation of the raw materials. The water content of the operating conditions varies according to the facilities of each plant, and the dry distillation temperature and time vary depending on the structure of the coke oven.

특히, 석탄을 해외에서 수입하는 우리나라의 경우 통상적으로 10~18탄종의 석탄을 배합하여 코크스를 제조한다. 석탄은 탄종에 따라 성상 및 특성이 차이가 있고 적치높이에 따라서 입도 편석이 발생하고 입도에 따른 물성변화가 크다.In particular, in the case of importing coal from abroad, coke is usually manufactured by mixing 10-18 coal species. Coal has different properties and characteristics according to the type of coal. Particle segregation occurs according to the pile height, and physical property changes according to the particle size.

따라서, 다수의 탄종을 배합할 경우 품질 조건이 우수한 코크스를 제조할 수 있도록 각 석탄의 휘발분과 회분 함량을 기초로 배합지수를 관리한다.Therefore, when blending a plurality of coal species, the blending index is managed based on the volatile and ash content of each coal to produce coke with excellent quality conditions.

석탄은 수분, 회분, 휘발분, 고정탄소 등을 백분율로 나타낸다.Coal represents water, ash, volatiles, fixed carbon, etc. as a percentage.

이 중 휘발분은 석탄의 성분 중 건류가스가 되는 성분으로서 휘발성인 것을 의미한다. 휘발분의 측정은 건조한 석탄을 공기를 차단하고 900±℃로 7분간 가열한 다음 그 감량으로부터 수분을 뺀 나머지를 휘발분으로 간주한다. 휘발분은 코크스 품질과 직접적인 관련이 있는데, 배합탄의 휘발분 함량이 24% 미만이거나 26%를 초과하면 코크스 강도가 저하되고 코크스 품질이 저하된다.Among these, volatile matter means volatile as a component which becomes dry gas among the components of coal. The measurement of volatile matter is regarded as volatile matter, after which dry coal is cut off from air, heated at 900 6 0 C for 7 minutes, and the moisture is subtracted from the loss. Volatilization is directly related to the coke quality. If the volatile content of the coal blend is less than 24% or more than 26%, the coke strength is lowered and the coke quality is reduced.

회분은 석탄을 태우고 남는 부분(재)를 의미한다. 회분은 고로 후공정에 영향을 미치는데, 배합탄의 회분 함량이 11.5%를 초과하면 재가 많아지면서 고로 내에서 분화가 일어나고 고로에 통기성을 제공하지 못하게 되어 수율이 떨어진다.Ash means the ash (burning) remaining after burning coal. Ash affects the blast furnace post-process. If the ash content of the coal blend exceeds 11.5%, the ash content increases and the yield decreases because it does not provide breathability to the blast furnace.

배합지수는 적치높이에 따른 각 원료탄의 입도를 조사하는 단계와, 입도에 따른 물성변화를 조사하는 단계와, 조사한 물성변화를 기초로 각 원료탄의 휘발분 함량 및 회분 함량의 가중 평균치를 도출하는 단계를 통해 산출된다.The blending index includes the steps of investigating the particle size of each raw coal according to the pile height, examining the change of physical properties according to the particle size, and deriving the weighted average of the volatile content and ash content of each raw coal based on the changed physical properties. Is calculated through.

가중 평균치는 휘발분 함량 및 회분 함량이 각각 24~26%, 11.5% 이하를 만족하도록 하는 각 탄종의 배합비율이다.The weighted average is the blending ratio of each type of carbon such that the volatile content and the ash content satisfy 24 to 26% and 11.5% or less, respectively.

각 원료탄은 적치높이에 따라 입도 변화가 있으며, 이러한 입도 변화는 석탄에 포함된 휘발분과 회분의 함량비에 의한 것이다.Each raw coal has a change in particle size according to the accumulation level, and this change in particle size is due to the content ratio of volatile ash and ash contained in coal.

도 1에 도시된 바에 의하면, 적치높이 20m에서 A탄종의 입도가 작고, C탄종, B탄종 순으로 입도가 크다. 또한, 도 2 및 도 3에 도시된 바에 의하면, 석탄 탄종의 적치높이가 높을수록 휘발분은 높아지고 회분은 감소하는 경향을 보인다. 이러한 경향은 입도가 클수록 회분이 증가하고 반대로 휘발분은 감소하는 석탄의 특성 때문이다.As shown in FIG. 1, the particle size of the A type of coal is small at the pile height 20m, and the particle size is larger in the order of the C type and the B type. In addition, as shown in Figures 2 and 3, the higher the stacking height of coal coal species, the higher the volatile content and the ash tends to decrease. This tendency is due to the characteristics of coal, where the ash content increases with larger particle size and volatile content decreases.

이러한 특성을 고려하여 적치높이별로 휘발분과 회분의 함량을 관리하여 석탄을 배합함으로써 코크스의 품질을 향상시키고 유지시킨다.
In consideration of these characteristics, the quality of coke is improved and maintained by mixing coal by controlling the contents of volatile matter and ash by the pile height.

이하에서는 본 발명의 실시예를 실험을 통해 설명한다. 그러나 하기 실시예는 본 발명을 예시하는 것일 뿐, 본 발명이 하기 실시예에 의해 한정되는 것은 아니다.Hereinafter, the embodiment of the present invention will be described by experiment. However, the following examples are merely to illustrate the invention, the present invention is not limited by the following examples.

<실시예><Examples>

A, B, C 3종류의 석탄 탄종을 적치 높이에 따라 입도 변화를 측정하였다. 다음으로, A, B, C 3종류의 석탄 탄종의 적치 높이에 따른 휘발분 함량과 회분 함량을 측정하였다. Particle size change was measured for A, B, and C types of coal coal species according to the pile height. Next, the volatile content and ash content of the A, B, C three kinds of coal coal species according to the pile height of the coal was measured.

A, B, C 3종류의 석탄 탄종의 적치 높이에 따른 휘발분 함량과 회분 함량은 아래의 표 1에 나타내었다.Volatile content and ash content according to the pile height of coal coal species of A, B and C are shown in Table 1 below.

구분
division
휘발분Volatility 회분Ash
20m20m 10m10m 0m0m 20m20m 10m10m 0m0m A탄종A bullet type 33.7%33.7% 32.0%32.0% 30.2%30.2% 5.7%5.7% 6.9%6.9% 8.1%8.1% B탄종B type 24.8%24.8% 22.6%22.6% 20.4%20.4% 6.3%6.3% 9.8%9.8% 13.2%13.2% C탄종C type 22.7%22.7% 21%21% 19.3%19.3% 8.2%8.2% 11.2%11.2% 14.2%14.2%

표 1의 측정 결과는 도 2 및 도 3의 그래프에 도시된 데이터와 동일하다.The measurement results of Table 1 are the same as the data shown in the graphs of FIGS. 2 and 3.

표 1의 측정 결과 적치높이가 높을수록 휘발분은 증가하고 회분은 반대로 감소하는 경향을 보였다. 또한 휘발분 증가에 따라 회분이 감소하는 경향이 유사한 경향을 보였다.As a result of the measurement in Table 1, the higher the pile height, the volatile content increased and the ash content decreased. In addition, the ash tends to decrease with increasing volatilization, showing a similar tendency.

표 1의 측정 결과를 토대로 20m 적치높이의 A탄종, B탄종, C탄종의 배합비율 즉, 가중 평균치를 산출하면 대략 20%, 40%, 40%가 된다. 이는 A탄종, B탄종, C탄종을 배합한 배합탄의 휘발분 함량이 24~26% 범위를 만족하도록 산출한 것으로 20m 적치높이에서 휘발분 함량이 높은 A탄종의 함량을 줄이고 휘발분 함량이 낮은 B탄종, C탄종의 함량을 높여 조정하는 것에서 가능하다. Based on the measurement results in Table 1, the compounding ratios of A, B and C types of 20m pile heights, that is, weighted average values, are approximately 20%, 40% and 40%. This is calculated to satisfy the range of 24 ~ 26% of volatile matter content of coals containing A, B, and C types, and reduce the content of A, which has high volatile content at 20m height, and B, which has low volatile content, It is possible to adjust by increasing the content of C coal species.

이 경우 적치높이별로 증가하는 휘발분 함량에 비례하여 회분 함량이 감소하는 경향을 보이므로 휘발분 함량을 고려하여 A탄종, B탄종, C탄종의 가중 평균치를 산출하면 회분의 함량도 설정된 범위를 만족하게 된다.
In this case, the ash content tends to decrease in proportion to the volatile content that increases with the pile height. Therefore, if the weighted average value of the A, B and C types is calculated in consideration of the volatile content, the ash content also satisfies the set range. .

표 2는 표 1의 휘발분 함량 및 회분 함량을 고려하여 적치높이별로 A탄종, B탄종, C탄종의 가중 평균치를 산출한 것이다.Table 2 calculates the weighted average of the A, B, and C types by stacking height in consideration of the volatile content and ash content of Table 1.

구분division A탄종A bullet type B탄종B type C탄종C type 휘발분Volatility 회분Ash 열간강도
(기준:67.6↑)
Hot strength
(Aim: 67.6 ↑)
배합탄1
(20m)
Mixed coal 1
(20m)
20%20% 40%40% 40%40% 25.7%25.7% 7.0%7.0% 67.867.8
배합탄2
(10m)
Mixed coal 2
(10m)
40%40% 30%30% 30%30% 25.9%25.9% 9.0%9.0% 67.667.6
배합탄3
(0m)
Mixed coal 3
(0m)
50%50% 25%25% 25%25% 25.0%25.0% 10.9%10.9% 67.767.7

표 2에 의하면, 적치높이별로 휘발분 함량과 회분 함량을 고려하여 A탄종, B탄종, C탄종의 가중 평균치를 산출하는 경우 배합탄의 휘발분 함량이 24~26% 범위를 만족하고, 회분 함량도 11.5% 이하를 만족하였다.  According to Table 2, when calculating the weighted average value of A, B and C types in consideration of the volatile content and ash content for each pile height, the volatile content of the coal blend satisfies the range of 24 to 26%, and the ash content is 11.5. % Or less was satisfied.

A탄종 20%, B탄종 40%, C탄종 40%의 가중 평균치로 배합한 배합탄1의 경우 휘발분 함량과 회분 함량을 계산해보면, In the case of blended coal 1, which is composed of a weighted average of 20% A, 40% B, and 40% C, the volatile content and ash content are calculated.

휘발분 함량:(33.7×0.2+24.8×0.4+22.7×0.4)×100=25.7%Volatile Content: (33.7 × 0.2 + 24.8 × 0.4 + 22.7 × 0.4) × 100 = 25.7%

회분 함량:(5.7×0.2+6.3×0.4+8.2×0.4)×100=7.0%로 휘발분 함량과 회분 함량의 설정범위를 만족함을 확인할 수 있다. Ash content: (5.7 × 0.2 + 6.3 × 0.4 + 8.2 × 0.4) × 100 = 7.0%, satisfying the setting range of volatile content and ash content.

또한, 상기 조건을 만족할 경우 제조한 코크스도 열간강도 기준 67.6 이상을 만족함을 확인할 수 있다.
In addition, when the above conditions are satisfied, the manufactured coke may also satisfy the hot strength standard of 67.6 or more.

표 3은 표 2와 비교하기 위한 것으로, 적치높이를 고려하지 않고 A탄종, B탄종, C탄종을 배합한 것이다.Table 3 compares with Table 2, and combines A coal type, B coal type, and C coal type without considering pile height.

구분division A탄종A bullet type B탄종B type C탄종C type 휘발분Volatility 회분Ash 열간강도
(기준:67.6↑)
Hot strength
(Aim: 67.6 ↑)
배합탄4
Mixed coal 4
20%20% 40%40% 40%40% 23.8%23.8% 9.8%9.8% 67.567.5
배합탄5
Mixed coal 5
40%40% 30%30% 30%30% 25.9%25.9% 9.1%9.1% 67.667.6
배합탄6
Mixed coal 6
50%50% 25%25% 25%25% 26.9%26.9% 8.7%8.7% 67.467.4

표 3은 A탄종, B탄종, C탄종의 각각 높이별 평균 데이터를 사용하여 배합비를 도출한 것이다.Table 3 shows the compounding ratio by using the average data for each height of the A type, B type, and C type.

표 3에 의하면, 적치높이를 고려하지 않고 A탄종, B탄종, C탄종을 배합한 경우 배합탄4 및 배합탄6의 경우처럼 휘발분 함량이 설정 범위를 만족하지 않는 경우가 발생하고 제조한 코크스의 열간강도도 기준을 만족하지 못하는 경우가 발생할 수 있음이 확인된다.According to Table 3, when the A, B, and C types are combined without considering the stowage height, the volatile content does not satisfy the setting range as in the case of the coal 4 and coal 6, and the It is confirmed that cases where the hot strength criteria are not met may occur.

이를 통해, 각 석탄 탄종의 적치높이, 휘발분 함량, 회분 함량을 고려하여 석탄 탄종을 배합하는 것이 코크스 품질을 향상시킬 수 있는 방법임을 알 수 있다.Through this, it can be seen that combining coal coal species in consideration of the pile height, volatile content, and ash content of each coal coal species is a method of improving coke quality.

이는 코크스 품질에 영향을 미치는 변수를 줄여 코크스 품질을 향상시키고 나아가 제조원가를 절감시키고 코크스 생산성도 향상시키는 이점이 있다.This has the advantage of reducing the variables affecting the coke quality to improve the coke quality, further reduce the manufacturing cost and also improve the coke productivity.

본 발명은 상기한 실시 예에 한정되는 것이 아니라, 본 발명의 요지에 벗어나지 않는 범위에서 다양하게 변경하여 실시할 수 있으며 이는 본 발명의 구성에 포함됨을 밝혀둔다.The present invention is not limited to the above-described embodiments, and various changes can be made without departing from the gist of the present invention, which is understood to be included in the configuration of the present invention.

Claims (4)

다수의 석탄 탄종으로 된 원료탄의 배합시 적치높이별로 배합하되, 휘발분 함량, 회분 함량이 설정 범위를 만족하도록 상기 석탄 탄종의 배합지수를 관리하는 것을 특징으로 하는 코크스 제조용 원료탄 배합방법.A method of mixing raw coal for coke production, characterized in that the mixing of the raw coal made of a plurality of coal coal species by compounding height, but the mixture index of the coal coal species such that the volatile content, ash content satisfies the set range. 청구항 1에 있어서,
상기 배합지수는
적치높이에 따른 각 원료탄의 입도를 조사하는 단계와,
상기 입도에 따른 물성변화를 조사하는 단계와,
상기 조사한 물성변화를 기초로 각 원료탄의 휘발분 함량 및 회분 함량의 가중 평균치를 산출하는 단계를 통해 도출된 것을 특징으로 하는 코크스 제조용 원료탄 배합방법.
The method according to claim 1,
The compounding index is
Investigating the particle size of each raw coal according to the pile height;
Examining a change in physical properties according to the particle size;
Raw material coal blending method for producing coke, characterized in that derived through the step of calculating the weighted average value of the volatile content and ash content of each raw coal based on the investigated physical property changes.
청구항 2에 있어서,
상기 가중 평균치는
상기 휘발분 함량 및 회분 함량이 설정 범위를 만족하도록 하는 각 탄종의 적치높이별 배합비율인 것을 특징으로 하는 코크스 제조용 원료탄 배합방법.
The method according to claim 2,
The weighted average
Raw material coal blending method for producing coke, characterized in that the volatile content and ash content is a compounding ratio for each pile type height so as to satisfy the set range.
청구항 1에 있어서,
상기 휘발분 함량의 설정 범위는 24~26%이고, 상기 회분 함량의 설정 범위는 0 초과 11.5% 이하인 것을 특징으로 하는 코크스 제조용 원료탄 배합방법.
The method according to claim 1,
The setting range of the volatile matter content is 24 to 26%, and the setting range of the ash content is more than 0 and 11.5% or less.
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KR102122678B1 (en) * 2019-03-25 2020-06-12 현대제철 주식회사 Prediction method for hot strength of coke
CN113956896A (en) * 2020-07-20 2022-01-21 山西潞安煤基清洁能源有限责任公司 Method for improving chemical coal blending qualification rate
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KR102122678B1 (en) * 2019-03-25 2020-06-12 현대제철 주식회사 Prediction method for hot strength of coke
CN113956896A (en) * 2020-07-20 2022-01-21 山西潞安煤基清洁能源有限责任公司 Method for improving chemical coal blending qualification rate
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