KR20120122847A - Noble photosensitizer for photovoltaic cell and photovoltaic cell prepared from the same - Google Patents

Abstract

PURPOSE: A dye is provided to increase combination with oxide semiconductor particles and to increase combination with oxide semiconductor particles, to provide excellent mole-absorptivity, and to remarkably improve efficiency of solar battery. CONSTITUTION: A dye comprises a compound indicated by chemical formula F. A dye-sensitized solar cell comprises a first electrode comprising a substrate with conductivity and transparency; a light-absorbing layer formed on any one side of the first electrode; a second electrode arranged to face with the first electrode; and an electrolyte; and an electrolyte arranged between the first electrode and the second electrode. The light-absorbing layer comprises a semiconductor particle and the dye.

Description

Novel dye-sensitized solar cell dyes and dye-sensitized solar cells produced therefrom {NOBLE PHOTOSENSITIZER FOR PHOTOVOLTAIC CELL AND PHOTOVOLTAIC CELL PREPARED FROM THE SAME}

The present invention relates to novel indoloindole-based dyes used as dyes in dye-sensitized solar cells and dye-sensitized solar cells prepared therefrom.

Since the development of the dye-sensitized nanoparticle titanium oxide solar cell by the team of Michael Gratzel of the Swiss National Lausanne Institute of Advanced Technology (EPFL) in 1991, much work has been done in this area. Dye-sensitized solar cells have the potential to replace conventional amorphous silicon solar cells because their manufacturing costs are significantly lower than conventional silicon-based solar cells. Unlike silicon solar cells, dye-sensitized solar cells absorb visible light It is a photoelectrochemical solar cell whose main constituent material is a dye molecule capable of generating hole pairs and a transition metal oxide that transfers generated electrons.

Typical dyes used in dye-sensitized solar cells include the following compounds.

However, it is still required to increase the efficiency and durability of solar cells by increasing the bonding force with the oxide semiconductor fine particles, the photoelectric conversion efficiency, the shortcircuit photocurrent density (Jsc) and the molar extinction coefficient compared to the above dyes. Is needed

In order to solve the problems of the prior art as described above, the present invention shows a remarkably improved photoelectric conversion efficiency than the conventional dye, enhances the bonding force with the oxide semiconductor fine particles, JSC (short circuit photocurrent density) and the molar extinction coefficient is excellent It is an object of the present invention to provide a dye and a method for producing the same that can greatly improve the efficiency of a solar cell.

In addition, the present invention exhibits a remarkably improved photoelectric conversion efficiency, including the dye, the bonding strength with the oxide semiconductor fine particles, the dye-sensitized photoelectric conversion element and excellent efficiency of the short circuit photocurrent density (Jsc) and the molar extinction coefficient is significantly improved It aims to provide solar cell

Dyes for dye-sensitized solar cells and dye-sensitized solar cells according to the present invention include compounds having the structure of Formula F:

<Formula F>

In Formula F

Each of R1 and R2 is an aromatic ring of C4 to C7,

A is

,

,

,

,

또는

이고,

,

,

,

,

or

ego,

B is

C1 ~ C40 alkyl group, C5 ~ C40 aryl group, C3 ~ C40 heteroaryl group, C5 ~ C40 aryloxy group, C1 ~ C40 alkyloxy group, C5 ~ C40 arylamino group, C5 ~ C40 diaryl Amino group, C6 ~ C40 arylalkyl group, C3 ~ C40 cycloalkyl group and C3 ~ C40 heterocycloalkyl group; Or a group which forms a fused aliphatic ring, a fused aromatic ring, a fused heteroaliphatic ring or a fused heteroaromatic ring with an adjacent group,

C is

H, D, F, C1-C40 alkyl group, C5-C40 aryl group, C3-C40 heteroaryl group, C5-C40 aryloxy group, C1-C40 alkyloxy group, C5-C40 arylamino group, C5 ~ C40 diarylamino group, C6 ~ C40 arylalkyl group, C3 ~ C40 cycloalkyl group and C3 ~ C40 heterocycloalkyl group; Or a group which forms a fused aliphatic ring, a fused aromatic ring, a fused heteroaliphatic ring or a fused heteroaromatic ring with an adjacent group.

In addition, to achieve another object of the present invention, there is provided a dye-sensitized solar cell prepared from the dye represented by the formula (F).

In addition, the dye for the dye-sensitized solar cell and the dye-sensitized solar cell according to the present invention according to the present invention is based on the corresponding compounds represented by the formula (1) to 57.

The novel dyes and dye-sensitized solar cells prepared therefrom exhibit significantly improved photovoltaic conversion efficiencies, enhance bonding with oxide semiconductor particulates, and have excellent short circuit photocurrent density (Jsc) and molar extinction coefficients. The efficiency of the battery can be greatly improved.

Hereinafter, the present invention will be described in detail.

The present invention may be modified in various ways and may have various forms, and thus embodiments (or embodiments) will be described in detail in the text. However, this is not intended to limit the present invention to the specific form disclosed, it should be understood to include all modifications, equivalents, and substitutes included in the spirit and scope of the present invention.

The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. Singular expressions include plural expressions unless the context clearly indicates otherwise. In the present application, the term &quot; comprising &quot; or &quot; consisting of &quot;, or the like, refers to the presence of a feature, a number, a step, an operation, an element, a component, But do not preclude the presence or addition of one or more other features, integers, steps, operations, components, parts, or combinations thereof.

Unless defined otherwise, all terms used herein, including technical or scientific terms, have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. Terms such as those defined in commonly used dictionaries are to be interpreted as having a meaning consistent with the contextual meaning of the related art and are to be interpreted as either ideal or overly formal in the sense of the present application Do not.

Dyes for dye-sensitized solar cells according to the present invention include compounds having the structure of Formula F:

<Formula F>

In Formula F

Each of R1 and R2 is a C4-C7 aromatic ring (i.e., a heteroaromatic ring),

A is

,

,

,

,

또는

이고,

,

,

,

,

or

ego,

B is

C1 ~ C40 alkyl group, C5 ~ C40 aryl group, C3 ~ C40 heteroaryl group, C5 ~ C40 aryloxy group, C1 ~ C40 alkyloxy group, C5 ~ C40 arylamino group, C5 ~ C40 diaryl Amino group, C6 ~ C40 arylalkyl group, C3 ~ C40 cycloalkyl group and C3 ~ C40 heterocycloalkyl group; Or a group which forms a fused aliphatic ring, a fused aromatic ring, a fused heteroaliphatic ring or a fused heteroaromatic ring with an adjacent group,

C is

H, D, F, C1-C40 alkyl group, C5-C40 aryl group, C3-C40 heteroaryl group, C5-C40 aryloxy group, C1-C40 alkyloxy group, C5-C40 arylamino group, C5 ~ C40 diarylamino group, C6 ~ C40 arylalkyl group, C3 ~ C40 cycloalkyl group and C3 ~ C40 heterocycloalkyl group; Or a group which forms a fused aliphatic ring, a fused aromatic ring, a fused heteroaliphatic ring or a fused heteroaromatic ring with an adjacent group.

The inventor of the present invention selects A, B, C, and R1 and R2 from the compound represented by Formula F, and develops specific, various derivatives, especially indoloindole derivatives and applied to solar cells, and is significantly improved in photovoltaic cells. Indicative of the conversion efficiency, it was found that the short circuit photocurrent density (Jsc) and the molar extinction coefficient were improved.

In Formula F, R1 and R2 each preferably correspond to the structure of Formula Fa.

<Formula Fa

In Formula F or Formula Fa, B is

C5 ~ C40 aryl group, C3 ~ C40 heteroaryl group, C5 ~ C40 aryloxy group, C1 ~ C40 alkyloxy group, C5 ~ C40 arylamino group, C5 ~ C40 diarylamino group and C6 ~ C40 An arylalkyl group; Or a group forming a fused aliphatic ring, a fused aromatic ring, a fused heteroaliphatic ring or a fused heteroaromatic ring with an adjacent group.

C and C40 alkyl group, C5 to C40 aryl group, C3 to C40 heteroaryl group, C5 to C40 aryloxy group, C1 to C40 alkyloxy group, C5 C40-C40 arylamino group, C5-C40 diarylamino group, C6-C40 arylalkyl group, C3-C40 cycloalkyl group and C3-C40 heterocycloalkyl group

Deuterium, halogen, nitrile group, nitro group, C1-C40 alkyl group, C2-C40 alkenyl group, C1-C40 alkoxy group, C1-C40 amino group, C3-C40 cycloalkyl group, C3-C40 It is preferably substituted or unsubstituted with one or more selected from the group consisting of a heterocycloalkyl group, an aryl group of C6 to C40, a heteroaryl group of C5 to C40, and a silane group.

C and C40 alkyl group, C5 to C40 aryl group, C3 to C40 heteroaryl group, C5 to C40 aryloxy group, C1 to C40 alkyloxy group, C5 to C40 arylamino group, Among the substituents introduced into a C5 to C40 diarylamino group, a C6 to C40 arylalkyl group, a C3 to C40 cycloalkyl group, and a C3 to C40 heterocycloalkyl group

C1-C40 alkyl group, C1-C40 amino group, C3-C40 cycloalkyl group, C3-C40 heterocycloalkyl group, C6-C40 aryl group, and C5-C40 heteroaryl group

Each independently D, F, halogen, nitrile group, nitro group, C1 ~ C40 alkyl group, C2 ~ C40 alkenyl group, C1 ~ C40 alkoxy group, C1 ~ C40 amino group, C3 ~ C40 cycloalkyl group, C3 ~ Further substituted with at least one second substituent selected from the group consisting of C40 heterocycloalkyl group, C6 ~ C40 aryl group and C5 ~ C40 heteroaryl group; Or it is preferable to form a condensed aliphatic ring, a condensed aromatic ring, a condensed heteroaliphatic ring or a condensed heteroaromatic ring with an adjacent group or to form a spiro bond.

Furthermore, said C1-C40 alkyl group of said B and C, C5-C40 aryl group, C5-C40 heteroaryl group, C5-C40 aryloxy group, C1-C40 alkyloxy group, C5-C40 arylamino group Substituents to be introduced into a C5 to C40 diarylamino group, a C6 to C40 arylalkyl group, a C3 to C40 cycloalkyl group, and a C3 to C40 heterocycloalkyl group

D, F, phenyl group, tolyl group, biphenyl group, pentalenyl group, indenyl group, naphthyl group, biphenylenyl group, anthracenyl group, benzoanthracenyl group, azurenyl group, heptarenyl group, acenaphthylyl group, phenna Renyl group, methyl anthryl group, phenanthrenyl group, triphenylenyl group, pyrenyl group, chrysenyl group, pisenyl group, perrylenyl group, chloroperylenyl group, pentaphenyl group, pentaxenyl group, tetraphenylenyl group, hexa Phenyl group, hexasenyl group, rubisenyl group, coronyl group, trinaphthylenyl group, heptaphenyl group, heptasenyl group, fluorenyl group, pyrantrenyl group, obarenyl group, carbazolyl group, dibenzofuranyl group, dibenzo Thiophenyl group, thiophenyl group, indolyl group, furinyl group, benzimidazolyl group, quinolinyl group, benzothiophenyl group, parathiazinyl group, pyrroylyl group, pyrazolyl group, imidazolyl group, imidazolinyl group, oxazolyl group , Thiazolyl group, triazolyl group, tetrazolyl group, oxadiazolyl group, Pyridinyl, pyridazinyl, pyrimidinyl, pyrazinyl, thianthrenyl, cyclopentyl, cyclohexyl, oxiranyl, pyrrolidinyl, pyrazolidinyl, imidazolidi It is preferable to select from the group consisting of a silyl group, a piperidinyl group, a piperazinyl group, a morpholinyl group, a di (C6-C50 aryl) amino group, a silane group and derivatives thereof.

The aryl group is a monovalent group having an aromatic ring system, and may include two or more ring systems, and the two or more ring systems may exist in a bonded or condensed form with each other. The heteroaryl group refers to a group in which at least one carbon of the aryl group is substituted with at least one selected from the group consisting of N, O, S, P, Si, and Se.

Meanwhile, a cycloalkyl group refers to an alkyl group having a ring system, and the heterocycloalkyl group refers to a group in which at least one carbon of the cycloalkyl group is substituted with at least one selected from the group consisting of N, O, S, P, Si, and Se. .

When one or more hydrogen of the aryl group and heteroaryl group is substituted, their substituents are C1-C50 alkyl group; C1-C50 alkoxy group; A C6-C50 aryl group unsubstituted or substituted with a C1-C50 alkyl group or a C1-C50 alkoxy group; C2-C50 heteroaryl group unsubstituted or substituted with a C1-C50 alkyl group or a C1-C50 alkoxy group; A C5-C50 cycloalkyl group which is unsubstituted or substituted by a C1-C50 alkyl group or a C1-C50 alkoxy group and a C5-C50 heterocycloalkyl group which is unsubstituted or substituted by a C1-C20 alkyl group or a C1-C20 alkoxy group, &Lt; / RTI &gt;

The present invention also provides a first electrode comprising a substrate having conductivity and light transmittance, a light absorbing layer formed on one surface of the first electrode, a second electrode disposed opposite to the first electrode on which the light absorbing layer is formed, and the It includes an electrolyte located between the first electrode and the second electrode, the light absorbing layer provides a dye-sensitized solar cell comprising a semiconductor fine particle, and the dye.

In dye-sensitized solar cells, the first step in driving solar cells is the process of generating photocharges from light energy. Typically, a dye material is used to generate photocharges, and the dye material is excited by absorbing light transmitted through the conductive transparent substrate.

When sunlight enters the dye-sensitized solar cell, the photons are absorbed by the dye molecules in the light absorbing layer, whereby the dye molecules electron-transfer from the ground state to the excited state to form electron-hole pairs. Electrons in the excited state are injected into the conduction band of the semiconductor fine particle interface, and the injected electrons are transferred to the first electrode through the interface. After that, it moves to the second electrode which is the counter electrode through the external circuit. On the other hand, the dye oxidized as a result of the electron transfer is reduced by the ions of the redox couple in the electrolyte layer, and the oxidized ions undergo a reduction reaction with the electrons reaching the interface of the second electrode to achieve charge neutrality. The dye-sensitized solar cell is thereby operated.

As the first electrode, any conductive transparent substrate having conductivity and transparency (more broadly transmissive) can be used without particular limitation.

The light absorbing layer includes semiconductor fine particles and a dye according to one embodiment of the present invention in which electrons are excited by absorbing visible light and absorbed by the semiconductor fine particles.

The semiconductor fine particles may be a metal oxide or a composite metal oxide having a perovskite structure, in addition to the single semiconductor represented by silicon. The semiconductor is preferably an n-type semiconductor in which conduction band electrons become carriers under photo excitation to provide an anode current. Specifically, the semiconductor fine particles include Si, TiO 2, SnO 2, ZnO, WO 3, Nb 2 O 5, TiSrO 3, and the like, and more preferably, anatase type TiO 2 may be used.

On the other hand, the dye-sensitized solar cell dye according to the present invention can be represented by the formula F, and more specifically, the formula F is represented by the following formula 1 to 57 (in the following formulas omit the 'formula' in the formulas described only numbers) Can be expressed.

Hereinafter, the reaction examples and examples of the present invention are specifically illustrated, but the present invention is not limited to the following reaction examples and examples. In the following reaction, the intermediate compound is indicated by adding a serial number to the number of the final product. For example, compound 1 is represented by compound [1], and the intermediate compound of the said compound is described by [1-1] etc.

In the present specification, the chemical number is indicated as the chemical formula number. For example, the compound represented by the formula (1) is represented by compound 1.

[Reaction Example 1] Synthesis of Compound [34]

Preparation of Intermediate Compound [34-1]

In a 2 L flask, 30.0 g (0.256 mol) of indole, 92.6 g (0.384 mol) of 4-bromohexyl benzene, 14.6 g (76.8 mmol) of copper iodide (I) and 108 g (0.512 mol) of potassium phosphate were added to 800 mL of toluene in a nitrogen atmosphere. Stir. 25.6 mL (0.384 mol) of 1,2-ethylenediamine is added dropwise at room temperature, and the mixture is heated to reflux and stirred for 12 hours. The reaction solution was poured into 500 mL of saturated aqueous ammonium solution to separate the layers. The organic layer is separated and washed with 800 mL of saturated brine. The organic layer was separated and dried over anhydrous magnesium sulfate and filtered. The filtrate was concentrated under reduced pressure and purified by column chromatography to obtain 55.0 g (77%) of an intermediate compound [34-1] as a colorless liquid.

Preparation of Intermediate Compound [34-2], [34-3]

55 g (0.198 mol) of an intermediate compound [34-1] were dissolved in 1.2 L of tetrahydrofuran under a nitrogen stream in a 2 L reaction flask, and 95 mL (0.237 mol) of 2.5 M butyllithium was added dropwise at -78 ° C. After stirring for 10 minutes at the same temperature, 53.9 mL (0.237 mol) of tributyltin chloride was added dropwise. After heating up to 12 hours at room temperature, the organic layer obtained by layer separation with ethyl acetate / ammonium saturated aqueous solution was removed with anhydrous magnesium sulfate, and distilled under reduced pressure. The intermediate compound [34-2] was vacuum dried and then dissolved in 500 mL of dimethylformamide in a 2L reaction flask, and 28.0 g (0.138 mol) of 1-bromo-2-nitrobenzene and 6.38 g (5.52 mmol) of tetrakis triphenylphosphine palladium Is added in a nitrogen atmosphere and stirred under reflux for 3 hours. The reaction solution is cooled to room temperature, and then separated by ethyl acetate / ammonium saturated aqueous solution. The organic layer was washed three times with saturated brine, dried over anhydrous magnesium sulfate and filtered. The filtrate was concentrated under reduced pressure and purified by column chromatography to prepare 60.0 g (76%) of an intermediate compound [34-3].

Preparation of Intermediate Compound [34-4]

60.0 g (0.150 mol) of an intermediate compound and 104.8 mL (0.602 mol) of triethyl phosphite were added to a 2 L reaction flask, and the mixture was stirred under reflux at 900 mL for 24 hours under nitrogen atmosphere. After completion of the reaction, distillation under reduced pressure using a high vacuum. The concentrated solution was purified by silica gel chromatography to prepare 45.0 g (82%) of an intermediate compound [34-4] as a white solid.

Preparation of Intermediate Compound [34-5]

5.0 g (13.64 mmol) of the intermediate compound [34-4], 3.03 g (16.37 mmol) of 4-bromobenzaldehyde, 2.6 g (40.92 mmol) of copper powder, and 5.66 g (40.92 mmol) of potassium carbonate were added to a 250 mL reaction flask. 100 mL of dimethylformamide was stirred under reflux for 24 hours in a nitrogen atmosphere. The reaction solution is cooled to room temperature, and then separated by ethyl acetate / ammonium saturated aqueous solution. The organic layer was washed three times with saturated brine, dried over anhydrous magnesium sulfate and filtered. The filtrate was concentrated under reduced pressure and purified by column chromatography to prepare 4.5 g (70%) of the intermediate compound [34-5].

Preparation of Compound [34]

4.5 g (9.56 mmol) of the intermediate compound [34-5], 976 mg (11.47 mmol) of cyanoacetic acid, and 0.47 mL (4.78 mmol) of piperidine were refluxed and stirred at 100 mL of chloroform for 10 hours. After cooling to room temperature, poured into 1N aqueous hydrochloric acid solution and extracted and washed with saturated brine. The organic layer was separated, dried over anhydrous magnesium sulfate, filtered and concentrated under reduced pressure. The concentrated solution was purified by column chromatography to prepare 3.3 g (64%) of the title compound [34].

Compounds 1 to 57 were prepared in the same manner as in Reaction Example 1, and the results are shown in the following [Table 1].

[First vote group]

Comparative Example 1: Preparation of Dye-Sensitized Solar Cell

A titanium oxide dispersion having a particle size of 5 to 15 nm on a fluorine-doped tin oxide (FTO) was applied to a ² cm ² area by a doctor blade method, and a porous titanium oxide thick film having a thickness of 20 μm was formed through a heat-treatment calciner at 450 ° C. for 30 minutes. Produced. Thereafter, the specimen was immersed in a dye dispersion solution of Comparative Sample 1 dissolved in ethanol at a concentration of 0.3 mM at room temperature, and then the dye adsorption treatment was performed for 24 hours or more.

Thereafter, the porous titanium oxide thick film to which the dye was adsorbed was washed with ethanol and dried at room temperature to prepare a first electrode having a light absorption layer.

A platinum layer was formed to a thickness of about 200 nm on a fluorine-doped tin oxide (FTO) by screen printing, and a second electrode was prepared by making two micropores using a 0.75 mm diameter drill for electrolyte injection.

Next, the first electrode and the second electrode were disposed with a polymer partition wall having a thickness of about 40 to 60 μm made of SURLYN (thermoplastic polymer film), and then pressed at about 1 to 2 atm on a heating plate of about 150 ° C. A sealed space is formed between the first electrode and the second electrode.

0.6M 1-hexyl-2,3-methyl-imidazolium iodide, 0.1M LiI, 0.05MI ₂ and 0.5M 4-tert-butyl-pyridine (TBP) were injected into the micropores of the second electrode. A solar cell was prepared by injecting an electrolyte solution of I ₃ / I dissolved in a reel.

Evaluation Example: Comparative Sample 1

The photocurrent voltage of the dye-sensitized solar cell manufactured in Comparative Example 1 was measured, and an open-circuit voltage (Voc), a short-circuit current (Jsc), and a fill factor were measured from the measured photocurrent curve. : FF) was calculated and the light conversion efficiency was calculated using the above values.

In this case, a xenon lamp (xenon lamp, Newport, 66142 500W) was used as the light source, and the solar condition (AM 1.5) of the xenon lamp was a standard solar cell (National Renewable Energy Laboratory, A2LA accreditation certificate # 2236.01, Type of material: Mono -Si + BK7 filter).

The current density Is, the voltage Voc, the fill factor (FF), and the photoelectric conversion efficiency (η) calculated therefrom are shown in the following [Table 2].

[Table 2]

Example 1 Preparation of Dye-Sensitized Solar Cells

A titanium oxide dispersion having a particle size of 5 to 15 nm on a fluorine-doped tin oxide (FTO) was applied to a ² cm ² area by a doctor blade method, and a porous titanium oxide thick film having a thickness of 20 μm was formed through a heat-treatment calciner at 450 ° C. for 30 minutes. Produced. Thereafter, the specimens were immersed in a dye dispersion in which the following Chemical Formulas 1 to 62 were dissolved in ethanol at a concentration of 0.3 mM, and then the dye adsorption treatment was performed for 24 hours or more.

Thereafter, the porous titanium oxide thick film to which the dye was adsorbed was washed with ethanol and dried at room temperature to prepare a first electrode having a light absorption layer.

A platinum layer was formed to a thickness of about 200 nm on a fluorine-doped tin oxide (FTO) by screen printing, and a second electrode was prepared by making two micropores using a 0.75 mm diameter drill for electrolyte injection.

Next, the first electrode and the second electrode were disposed with a polymer partition wall having a thickness of about 40 to 60 μm made of SURLYN (thermoplastic polymer film), and then pressed at about 1 to 2 atm on a heating plate of about 150 ° C. A sealed space is formed between the first electrode and the second electrode.

0.6M 1-hexyl-2,3-methyl-imidazolium iodide, 0.1M LiI, 0.05MI ₂ and 0.5M 4-tert-butyl-pyridine (TBP) were injected into the micropores of the second electrode. A solar cell was prepared by injecting an electrolyte solution of I ₃ / I dissolved in a reel.

Evaluation Example: Evaluation of Properties of Chemical Formulas 1-57

The photocurrent voltages of the dye-sensitized solar cells prepared in Examples 1 to 57 were measured, and the open-circuit voltage (Voc), the short-circuit current (Jsc) and the filling factor (from the measured photocurrent curve) were measured. fill factor (FF) was calculated, and the light conversion efficiency was calculated using the above values.

In this case, a xenon lamp (xenon lamp, Newport, 66142 500W) was used as the light source, and the solar condition (AM 1.5) of the xenon lamp was a standard solar cell (National Renewable Energy Laboratory, A2LA accreditation certificate # 2236.01, Type of material: Mono -Si + BK7 filter).

The current density Is, the voltage Voc, the fill factor (FF), and the photoelectric conversion efficiency (η) calculated therefrom are shown in the following [Table 3].

[Third vote group]

<Evaluation Example 46>

<Evaluation Example 50>

Although the well-known techniques are omitted in the above description, those skilled in the art can easily infer, infer, and reproduce them.

Claims (5)

Dyes for dye-sensitized solar cells comprising a compound having the structure of Formula F:
<Formula F>

In Formula F
Each of R1 and R2 is an aromatic ring of C4 to C7,


A is

,

,

,

,

or

ego,


B is
C1 ~ C40 alkyl group, C5 ~ C40 aryl group, C3 ~ C40 heteroaryl group, C5 ~ C40 aryloxy group, C1 ~ C40 alkyloxy group, C5 ~ C40 arylamino group, C5 ~ C40 diaryl Amino group, C6 ~ C40 arylalkyl group, C3 ~ C40 cycloalkyl group and C3 ~ C40 heterocycloalkyl group; Or a group which forms a fused aliphatic ring, a fused aromatic ring, a fused heteroaliphatic ring or a fused heteroaromatic ring with an adjacent group,


C is
H, D, F, C1-C40 alkyl group, C5-C40 aryl group, C3-C40 heteroaryl group, C5-C40 aryloxy group, C1-C40 alkyloxy group, C5-C40 arylamino group, C5 ~ C40 diarylamino group, C6 ~ C40 arylalkyl group, C3 ~ C40 cycloalkyl group and C3 ~ C40 heterocycloalkyl group; Or a group which forms a fused aliphatic ring, a fused aromatic ring, a fused heteroaliphatic ring or a fused heteroaromatic ring with an adjacent group. The method of claim 1,
Chemical Formula F is a dye for solar cells, characterized in that each compound having a structure of the formula Fa:
<Formula Fa>

The method of claim 1,
B is
C5 ~ C40 aryl group, C3 ~ C40 heteroaryl group, C5 ~ C40 aryloxy group, C1 ~ C40 alkyloxy group, C5 ~ C40 arylamino group, C5 ~ C40 diarylamino group and C6 ~ C40 An arylalkyl group; Or a group forming a condensed aliphatic ring, a condensed aromatic ring, a condensed heteroaliphatic ring or a condensed heteroaromatic ring with an adjacent group. The method of claim 1,
Chemical Formula F is a dye-sensitized solar cell dye, characterized in that represented by the following formula 1 to 57:

A first electrode comprising a substrate having conductivity and light transmission;
A light absorbing layer formed on one surface of the first electrode;
A second electrode disposed to face the first electrode on which the light absorption layer is formed; And
An electrolyte located between the first electrode and the second electrode,
The light-sensing layer is a dye-sensitized solar cell comprising a semiconductor fine particle, and the dye according to any one of claims 1 to 4.