KR101324783B1 - Noble photosensitizer for photovoltaic cell and photovoltaic cell prepared from the same - Google Patents
Noble photosensitizer for photovoltaic cell and photovoltaic cell prepared from the same Download PDFInfo
- Publication number
- KR101324783B1 KR101324783B1 KR1020110058839A KR20110058839A KR101324783B1 KR 101324783 B1 KR101324783 B1 KR 101324783B1 KR 1020110058839 A KR1020110058839 A KR 1020110058839A KR 20110058839 A KR20110058839 A KR 20110058839A KR 101324783 B1 KR101324783 B1 KR 101324783B1
- Authority
- KR
- South Korea
- Prior art keywords
- group
- dye
- electrode
- sensitized solar
- solar cell
- Prior art date
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/542—Dye sensitized solar cells
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Hybrid Cells (AREA)
- Photovoltaic Devices (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
Abstract
The present invention relates to a novel thiazole-based dye used as a dye in a dye-sensitized solar cell and a dye-sensitized solar cell prepared therefrom.
The dye according to the present invention exhibits a markedly improved photovoltaic conversion efficiency, a bond with oxide semiconductor fine particles, a dye-sensitized photoelectric conversion device having excellent short circuit photocurrent density (Jsc) and a molar extinction coefficient, and a solar cell having a markedly improved efficiency. Contribute to the offering.
Description
The present invention relates to a novel thiazole-based dye used as a dye in a dye-sensitized solar cell and a dye-sensitized solar cell prepared therefrom.
Much research has been done in this area since the development of dye-sensitized nanoparticle titanium dioxide solar cells by Michael Gratzel of the Swiss National Lozan Institute for Technology (EPFL) in 1991. Dye-sensitized solar cells have the potential to replace conventional amorphous silicon solar cells because their manufacturing costs are significantly lower than conventional silicon-based solar cells. Unlike silicon solar cells, dye-sensitized solar cells absorb visible light It is a photoelectrochemical solar cell whose main constituent material is a dye molecule capable of generating hole pairs and a transition metal oxide that transfers generated electrons.
Typical dyes used in dye-sensitized solar cells include the following compounds.
However, it is still required to increase the efficiency and durability of solar cells by increasing the bonding force with the oxide semiconductor fine particles, the photoelectric conversion efficiency, the shortcircuit photocurrent density (Jsc) and the molar extinction coefficient compared to the above dyes. Is needed
In order to solve the problems of the prior art as described above, the present invention shows a remarkably improved photoelectric conversion efficiency than the conventional dye, enhances the bonding force with the oxide semiconductor fine particles, JSC (short circuit photocurrent density) and the molar extinction coefficient is excellent It is an object of the present invention to provide a dye and a method for producing the same that can greatly improve the efficiency of a solar cell.
In addition, the present invention exhibits a remarkably improved photoelectric conversion efficiency, including the dye, the bonding strength with the oxide semiconductor fine particles, the dye-sensitized photoelectric conversion element and excellent efficiency of the short circuit photocurrent density (Jsc) and the molar extinction coefficient is significantly improved It aims to provide solar cell
Dyes for dye-sensitized solar cells and dye-sensitized solar cells according to the present invention include compounds having the structure of Formula F:
<Formula F>
In the above formula (F)
n is 0 (zero), 1, 2 or 3,
A is
, , , , or ego,
B is
0 (zero),
, or ego,C1 and C2 are each independently
C5 ~ C40 aryl group, C5 ~ C40 heteroaryl group and C3 ~ C40 heterocycloalkyl group; Or adjacent groups to form a fused aliphatic ring, a fused aromatic ring, a fused heteroaliphatic ring, or a fused heteroaromatic ring.
In addition, to achieve another object of the present invention, there is provided a dye-sensitized solar cell prepared from the dye represented by the formula (F).
In addition, the dye for the dye-sensitized solar cell and the dye-sensitized solar cell according to the present invention according to the present invention is based on the compound corresponding to the formula (1) to 46.
The novel dyes and dye-sensitized solar cells prepared therefrom exhibit significantly improved photovoltaic conversion efficiencies, enhance bonding with oxide semiconductor particulates, and have excellent short circuit photocurrent density (Jsc) and molar extinction coefficients. The efficiency of the battery can be greatly improved.
Hereinafter, the present invention will be described in detail.
The present invention may be modified in various ways and may have various forms, and thus embodiments (or embodiments) will be described in detail in the text. However, this is not intended to limit the present invention to the specific form disclosed, it should be understood to include all modifications, equivalents, and substitutes included in the spirit and scope of the present invention.
The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. Singular expressions include plural expressions unless the context clearly indicates otherwise. In the present application, the term " comprising " or " consisting of ", or the like, refers to the presence of a feature, a number, a step, an operation, an element, a component, But do not preclude the presence or addition of one or more other features, integers, steps, operations, components, parts, or combinations thereof.
Unless defined otherwise, all terms used herein, including technical or scientific terms, have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. Terms such as those defined in commonly used dictionaries are to be interpreted as having a meaning consistent with the contextual meaning of the related art and are to be interpreted as either ideal or overly formal in the sense of the present application Do not.
Dyes for dye-sensitized solar cells according to the present invention include compounds having the structure of Formula F:
Dyes for dye-sensitized solar cells comprising a compound having the structure of Formula F:
<Formula F>
In the above formula (F)
n is 0 (zero), 1, 2 or 3,
A is
, , , , or ego,
B is
0 (zero),
, or ego,C1 and C2 are each independently
C5 ~ C40 aryl group, C5 ~ C40 heteroaryl group and C3 ~ C40 heterocycloalkyl group; Or adjacent groups to form a fused aliphatic ring, a fused aromatic ring, a fused heteroaliphatic ring, or a fused heteroaromatic ring.
The inventor of the present invention shows a significantly improved photovoltaic conversion efficiency as a result of developing various derivatives specific to C1 and C2 and n in the compound represented by the above formula F, and applying them to solar cells. Found to be improved.
C1 and C2 are each independently
or ego,
here,
D1, D2 and D3 are each independently
H, D, F, C1-C40 alkyl group, C5-C40 aryl group, C5-C40 heteroaryl group, C5-C40 aryloxy group, C1-C40 alkyloxy group, C5-C40 arylamino group, C5 ~ C40 diarylamino group, C6 ~ C40 arylalkyl group, C3 ~ C40 cycloalkyl group and C3 ~ C40 heterocycloalkyl group; Or a group forming an adjacent group and a fused aliphatic ring, a condensed aromatic ring, a condensed heteroaliphatic ring or a condensed heteroaromatic ring.
Moreover, it is more preferable that said D1, D2, and D3 are respectively independently an alkyl group of H, D, F, C1-C40.
When n is 0 (zero) in Formula F of Compounds 1 to 46, Compounds 1, 4, 7, 12, 15, 18, 23, 26, 31, 34, 39, 42, 43, and 46 correspond to ,
When n is 1, compounds 2, 5, 8, 10, 13, 16, 19, 21, 24, 27, 29, 32, 35, 37, 40, 41, 44, 45 correspond,
When n is 2, other remaining compounds correspond.
In the above formula (F)
C1 to C40 alkyl group, C5 to C40 aryl group, C5 to C40 aryl group, C5 to C40 heteroaryl group, C5 to C40 aryloxy group, C1 to C40 alkyl group of C1 and C2, D1, D2 and D3 Oxy group, C5 ~ C40 arylamino group, C5 ~ C40 diarylamino group, C6 ~ C40 arylalkyl group, C3 ~ C40 cycloalkyl group and C3 ~ C40 heterocycloalkyl group
Deuterium, halogen, nitrile group, nitro group, C1-C40 alkyl group, C2-C40 alkenyl group, C1-C40 alkoxy group, C1-C40 amino group, C3-C40 cycloalkyl group, C3-C40 It is preferably substituted or unsubstituted with one or more selected from the group consisting of a heterocycloalkyl group, an aryl group of C6 to C40, a heteroaryl group of C5 to C40, and a silane group.
C1 and C2, D1, D2 and D3, C1 to C40, C1 to C40 alkyl group, C5 to C40 aryl group, C5 to C40 heteroaryl group, C5 to C40 aryloxy group, C1 to C40 Among substituents introduced into an alkyloxy group, a C5 to C40 arylamino group, a C5 to C40 diarylamino group, a C6 to C40 arylalkyl group, a C3 to C40 cycloalkyl group, and a C3 to C40 heterocycloalkyl group
A substituted or unsubstituted C1 to C40 alkyl group, a substituted or unsubstituted C2 to C40 alkenyl group, a substituted or unsubstituted C1 to C40 alkoxy group, a substituted or unsubstituted C1 to C40 amino group, a C3 to C40 cycloalkyl group, a C3 to C40 heterocycloalkyl group, The heteroaryl group of C <
A substituted or unsubstituted C1 to C40 alkyl group, a substituted or unsubstituted C1 to C40 alkoxy group, a substituted or unsubstituted C1 to C40 amino group, a substituted or unsubstituted C3 to C40 cycloalkyl group, At least one second substituent selected from the group consisting of a heterocycloalkyl group of C40, an aryl group of C6 to C40, and a heteroaryl group of C5 to C40; Or to form adjacent condensed aliphatic rings, condensed aromatic rings, condensed heteroaliphatic rings or condensed heteroaromatic rings or spiro bonds.
Furthermore, the C1 to C40 alkyl group, C5 to C40 aryl group, C5 to C40 heteroaryl group, C5 to C40 aryloxy group, C1 to C40 alkyloxy group, Substituents to be introduced into the C5 to C40 arylamino group, the C5 to C40 diarylamino group, the C6 to C40 arylalkyl group, the C3 to C40 cycloalkyl group, and the C3 to C40 heterocycloalkyl group
A phenanthryl group, a phenanthryl group, an anthracenyl group, a benzoanthracenyl group, an azranyl group, an acenaphthylenyl group, a phenanthryl group, a phenanthryl group, a phenanthryl group, A phenanthryl group, a phenanthrenyl group, a phenanthrenyl group, a phenanthrenyl group, a pyrenyl group, a chrysenyl group, a picenyl group, a perylenyl group, a chloroperylenyl group, a pentaphenyl group, A phenyl group, a hexacenyl group, a rubicenyl group, a coronenyl group, a trinaphthylenyl group, a heptaphenyl group, a heptacenyl group, a fluorenyl group, a pyranthrenyl group, an obenyl group, a carbazolyl group, a dibenzofuranyl group, A thiophenyl group, a thiophenyl group, an indolyl group, a purinyl group, a benzimidazolyl group, a quinolizinyl group, a quinolinyl group, a benzothiophenyl group, a parathiazinyl group, a pyrrolyl group, a pyrazolyl group, an imidazolyl group, , Thiazolyl group, triazolyl group, tetrazolyl group, oxadiazolyl group, A pyridinyl group, a pyridazinyl group, a pyrimidinyl group, a pyrazinyl group, a thianthrenyl group, a cyclopentyl group, a cyclohexyl group, an oxiranyl group, a pyrrolidinyl group, a pyrazolidinyl group, (C6-C50 aryl) amino group, silyl group, and derivatives thereof are preferable.
The aryl group is a monovalent group having an aromatic ring system and may include two or more ring systems, and the two or more ring systems may exist in a bonded or condensed form to each other. The heteroaryl group refers to a group in which at least one carbon of the aryl group is substituted with at least one member selected from the group consisting of N, O, S, P, Si and Se.
On the other hand, the cycloalkyl group refers to an alkyl group having a ring system, and the heterocycloalkyl group refers to a group in which at least one carbon in the cycloalkyl group is substituted with at least one member selected from the group consisting of N, O, S, P, Si and Se .
When at least one hydrogen of the aryl group and the heteroaryl group is substituted, the substituent is a C1-C50 alkyl group; A C1-C50 alkoxy group; A C6-C50 aryl group unsubstituted or substituted with a C1-C50 alkyl group or a C1-C50 alkoxy group; A C2-C50 heteroaryl group unsubstituted or substituted with a C1-C50 alkyl group or a C1-C50 alkoxy group; A C5-C50 cycloalkyl group which is unsubstituted or substituted by a C1-C50 alkyl group or a C1-C50 alkoxy group and a C5-C50 heterocycloalkyl group which is unsubstituted or substituted by a C1-C20 alkyl group or a C1-C20 alkoxy group, ≪ / RTI >
The present invention also provides a first electrode comprising a substrate having conductivity and light transmittance, a light absorbing layer formed on one surface of the first electrode, a second electrode disposed opposite to the first electrode on which the light absorbing layer is formed, and the It includes an electrolyte located between the first electrode and the second electrode, the light absorbing layer provides a dye-sensitized solar cell comprising a semiconductor fine particle, and the dye.
In dye-sensitized solar cells, the first step in driving solar cells is the process of generating photocharges from light energy. Typically, a dye material is used to generate photocharges, and the dye material is excited by absorbing light transmitted through the conductive transparent substrate.
When sunlight enters the dye-sensitized solar cell, the photons are absorbed by the dye molecules in the light absorbing layer, whereby the dye molecules electron-transfer from the ground state to the excited state to form electron-hole pairs. Electrons in the excited state are injected into the conduction band of the semiconductor fine particle interface, and the injected electrons are transferred to the first electrode through the interface. After that, it moves to the second electrode which is the counter electrode through the external circuit. On the other hand, the dye oxidized as a result of the electron transfer is reduced by the ions of the redox couple in the electrolyte layer, and the oxidized ions undergo a reduction reaction with the electrons reaching the interface of the second electrode to achieve charge neutrality. The dye-sensitized solar cell is thereby operated.
As the first electrode, any conductive transparent substrate having conductivity and transparency (more broadly transmissive) can be used without particular limitation.
The light absorbing layer includes semiconductor fine particles and a dye according to one embodiment of the present invention in which electrons are excited by absorbing visible light and absorbed by the semiconductor fine particles.
The semiconductor fine particles may be a metal oxide or a composite metal oxide having a perovskite structure, in addition to the single semiconductor represented by silicon. The semiconductor is preferably an n-type semiconductor in which conduction band electrons become carriers under photo excitation to provide an anode current. Specifically, the semiconductor fine particles include Si, TiO 2, SnO 2, ZnO, WO 3, Nb 2 O 5, TiSrO 3, and the like, and more preferably, anatase type TiO 2 may be used.
On the other hand, the dye-sensitized solar cell dye according to the present invention can be represented by the formula F, and more specifically, the formula F is represented by the following formula 1 to 46 ('Formula' is omitted in the formula below, only numbers) Can be expressed.
Hereinafter, Synthesis Examples and Examples of the present invention will be specifically described, but the present invention is not limited to the following Synthesis Examples and Examples. In the following synthesis examples, the intermediate compounds are indicated by adding the serial number to the final product number. For example, compound 1 is represented by compound [1], and the intermediate compound of the said compound is described by [1-1] etc.
In the present specification, the chemical number is represented by the chemical number. For example, the compound represented by the formula (1) is represented by the compound (1).
[Reaction Example 1] Preparation of Compound [4]
Preparation of Intermediate Compound [4-1]
10.0 g (33.33 mmol) of 2,5-dibromothiazolo [5,4-d] thiazole, 6.2 g (36.66 mol) of diphenylamine, 1.9 g (1.00 mmol) of copper iodide (I) in a 500 mL reaction flask And 14.1 g (66.66 mmol) of potassium phosphate are stirred with 400 mL of toluene in a nitrogen atmosphere. 3.34 mL (50.0 mmol) of 1,2-diethylamine was added dropwise at room temperature, and the temperature was raised to reflux for 12 hours. The reaction solution was poured into 500 mL of saturated aqueous ammonium solution to separate the layers. The organic layer is separated and washed with 400 mL of saturated brine. The organic layer is separated, dried over anhydrous magnesium sulfate and filtered. The filtrate was concentrated under reduced pressure and purified by column chromatography to prepare 5.5 g (42%) of the intermediate compound [4-1].
Preparation of Intermediate Compounds [4-2] and [4-3]
5.5 g (14.16 mmol) of the intermediate compound [4-1] were dissolved in 120 mL of tetrahydrofuran under a nitrogen stream in a 250 mL reaction flask, and 6.8 mL (16.99 mmol) of 2.5M butyllithium was added dropwise at -78 ° C. After stirring for 10 minutes at the same temperature, 4.58 mL (16.99 mmol) of tributyltin chloride was added dropwise. After heating up to room temperature for 8 hours, the organic layer obtained by layer separation with ethyl acetate / ammonium saturated aqueous solution was removed by anhydrous magnesium sulfate, distilled under reduced pressure, and the intermediate compound [4-2] was vacuum-dried and dimethylformamide was added to the reaction flask. Dissolve in 100 mL and add 1.83 g (9.91 mol) of 4-bromobenzaldehyde and 570 mg (0.494 mmol) of tetrakis triphenylphosphine palladium in a nitrogen atmosphere and stir at reflux for 1 hour. The reaction solution is cooled to room temperature, and then separated by ethyl acetate / ammonium saturated aqueous solution. The organic layer was washed three times with saturated brine, dried over anhydrous magnesium sulfate and filtered. The filtrate was concentrated under reduced pressure and purified by column chromatography to prepare 2.8 g (68%) of an intermediate compound [4-3].
Preparation of Compound [4]
2.8 g (6.77 mmol) of the intermediate compound [4-3], 691 mg (8.12 mmol) of cyanoacetic acid, and 0.33 mL (3.38 mmol) of piperidine were refluxed and stirred under 100 mL of chloroform for 10 hours. After cooling to room temperature, poured into 1N aqueous hydrochloric acid solution and extracted and washed with saturated brine. The organic layer was separated, dried over anhydrous magnesium sulfate, filtered and concentrated under reduced pressure. The concentrated solution was purified by column chromatography to prepare 1.4 g (43%) of the title compound [4].
Compounds 1 to 46 were prepared in the same manner as in Reaction Example 1, and the results are shown in the following [Table 1].
[First group (group)]
Comparative Example 1: Preparation of Dye-Sensitized Solar Cell
A titanium oxide dispersion having a particle size of 5 to 15 nm on a fluorine-doped tin oxide (FTO) was applied to a 2 cm 2 area by a doctor blade method, and a porous titanium oxide thick film having a thickness of 20 μm was formed through a heat-treatment calciner at 450 ° C. for 30 minutes. Produced. Thereafter, the specimen was immersed in a dye dispersion solution of Comparative Sample 1 dissolved in ethanol at a concentration of 0.3 mM at room temperature, and then the dye adsorption treatment was performed for 24 hours or more.
Thereafter, the porous titanium oxide thick film to which the dye was adsorbed was washed with ethanol and dried at room temperature to prepare a first electrode having a light absorption layer.
A platinum layer was formed to a thickness of about 200 nm on a fluorine-doped tin oxide (FTO) by screen printing, and a second electrode was prepared by making two micropores using a 0.75 mm diameter drill for electrolyte injection.
Next, the first electrode and the second electrode were disposed with a polymer partition wall having a thickness of about 40 to 60 μm made of SURLYN (thermoplastic polymer film), and then pressed at about 1 to 2 atm on a heating plate of about 150 ° C. A sealed space is formed between the first electrode and the second electrode.
0.6M 1-hexyl-2,3-methyl-imidazolium iodide, 0.1M LiI, 0.05MI 2 and 0.5M 4-tert-butyl-pyridine (TBP) were injected into the micropores of the second electrode. A solar cell was prepared by injecting an electrolyte solution of I 3 / I dissolved in a reel.
Evaluation Example: Comparative Sample 1
The photocurrent voltage of the dye-sensitized solar cell manufactured in Comparative Example 1 was measured, and an open-circuit voltage (Voc), a short-circuit current (Jsc), and a fill factor were measured from the measured photocurrent curve. : FF) was calculated and the light conversion efficiency was calculated using the above values.
In this case, a xenon lamp (xenon lamp, Newport, 66142 500W) was used as the light source, and the solar condition (AM 1.5) of the xenon lamp was a standard solar cell (National Renewable Energy Laboratory, A2LA accreditation certificate # 2236.01, Type of material: Mono -Si + BK7 filter).
The current density Is, the voltage Voc, the fill factor (FF), and the photoelectric conversion efficiency (η) calculated therefrom are shown in the following [Table 2].
[Table 2]
Example 1 Preparation of Dye-Sensitized Solar Cells
A titanium oxide dispersion having a particle size of 5 to 15 nm on a fluorine-doped tin oxide (FTO) was applied to a 2 cm 2 area by a doctor blade method, and a porous titanium oxide thick film having a thickness of 20 μm was formed through a heat-treatment calciner at 450 ° C. for 30 minutes. Produced. Thereafter, the specimens were immersed in a dye dispersion in which the following Chemical Formulas 1 to 62 were dissolved in ethanol at a concentration of 0.3 mM, and then the dye adsorption treatment was performed for 24 hours or more.
Thereafter, the porous titanium oxide thick film to which the dye was adsorbed was washed with ethanol and dried at room temperature to prepare a first electrode having a light absorption layer.
A platinum layer was formed to a thickness of about 200 nm on a fluorine-doped tin oxide (FTO) by screen printing, and a second electrode was prepared by making two micropores using a 0.75 mm diameter drill for electrolyte injection.
Next, the first electrode and the second electrode were disposed with a polymer partition wall having a thickness of about 40 to 60 μm made of SURLYN (thermoplastic polymer film), and then pressed at about 1 to 2 atm on a heating plate of about 150 ° C. A sealed space is formed between the first electrode and the second electrode.
0.6M 1-hexyl-2,3-methyl-imidazolium iodide, 0.1M LiI, 0.05MI 2 and 0.5M 4-tert-butyl-pyridine (TBP) were injected into the micropores of the second electrode. A solar cell was prepared by injecting an electrolyte solution of I 3 / I dissolved in a reel.
Evaluation Example: Characterization of Chemical Formulas 1 to 46
The photocurrent voltages of the dye-sensitized solar cells prepared in Examples 1 to 46 were measured, and the open-circuit voltage (Voc), the short-circuit current (Jsc), and the filling factor (from the measured photocurrent curve) were measured. fill factor (FF) was calculated, and the light conversion efficiency was calculated using the above values.
In this case, a xenon lamp (xenon lamp, Newport, 66142 500W) was used as the light source, and the solar condition (AM 1.5) of the xenon lamp was a standard solar cell (National Renewable Energy Laboratory, A2LA accreditation certificate # 2236.01, Type of material: Mono -Si + BK7 filter).
The current density Is, the voltage Voc, the fill factor (FF), and the photoelectric conversion efficiency (η) calculated therefrom are shown in the following [Table 3].
<Evaluation Example 2>
<Evaluation Example 26>
In the above description, the conventional well-known technique is omitted, but a person skilled in the art can easily guess, deduce and reproduce it.
Claims (5)
<Formula F>
In Formula F
n is 0 (zero), 1, 2 or 3,
A is
, , , , or ego,
B is
0 (zero), , or ego,
C1 and C2 are each independently
C5 ~ C40 aryl group, C5 ~ C40 heteroaryl group and C3 ~ C40 heterocycloalkyl group; Or adjacent groups to form a fused aliphatic ring, a fused aromatic ring, a fused heteroaliphatic ring, or a fused heteroaromatic ring.
C1 and C2 are each independently
or ego,
here,
D1, D2 and D3 are each independently
H, D, F, C1-C40 alkyl group, C5-C40 aryl group, C5-C40 heteroaryl group, C5-C40 aryloxy group, C1-C40 alkyloxy group, C5-C40 arylamino group, C5 ~ C40 diarylamino group, C6 ~ C40 arylalkyl group, C3 ~ C40 cycloalkyl group and C3 ~ C40 heterocycloalkyl group; Or a group forming a condensed aliphatic ring, a condensed aromatic ring, a condensed heteroaliphatic ring or a condensed heteroaromatic ring with an adjacent group.
D1, D2 and D3 are each independently a dye for sensitized solar cell, characterized in that H, D, F, C1 ~ C40 alkyl group.
Chemical Formula F is a dye for solar cells, characterized in that represented by any one of the following Formulas 1 to 46:
A light absorbing layer formed on one surface of the first electrode;
A second electrode disposed to face the first electrode on which the light absorption layer is formed; And
An electrolyte located between the first electrode and the second electrode,
The light-sensing layer is a dye-sensitized solar cell comprising a semiconductor fine particle, and the dye according to any one of claims 1 to 4.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR20110040732 | 2011-04-29 | ||
KR1020110040732 | 2011-04-29 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20120122844A KR20120122844A (en) | 2012-11-07 |
KR101324783B1 true KR101324783B1 (en) | 2013-10-31 |
Family
ID=47509042
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020110058839A KR101324783B1 (en) | 2011-04-29 | 2011-06-17 | Noble photosensitizer for photovoltaic cell and photovoltaic cell prepared from the same |
Country Status (1)
Country | Link |
---|---|
KR (1) | KR101324783B1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102838881B (en) * | 2012-10-07 | 2014-12-03 | 复旦大学 | Pure organic dye containing thiazole derivatives, synthetic method and application thereof |
JP7013163B2 (en) * | 2017-08-07 | 2022-01-31 | キヤノン株式会社 | Organic compounds and photoelectric conversion elements |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10340786A (en) * | 1997-06-09 | 1998-12-22 | Toyo Ink Mfg Co Ltd | Organic electroluminecent element material and organic electroluminescent element using it |
JP2005082703A (en) | 2003-09-09 | 2005-03-31 | Toyo Ink Mfg Co Ltd | Material for organic electroluminescent device and organic electroluminescent device using the same |
KR20070102821A (en) * | 2006-04-17 | 2007-10-22 | 삼성에스디아이 주식회사 | Photosensitizer for photovoltaic cell, and photovoltaic cell prepared from same |
-
2011
- 2011-06-17 KR KR1020110058839A patent/KR101324783B1/en active IP Right Grant
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10340786A (en) * | 1997-06-09 | 1998-12-22 | Toyo Ink Mfg Co Ltd | Organic electroluminecent element material and organic electroluminescent element using it |
JP2005082703A (en) | 2003-09-09 | 2005-03-31 | Toyo Ink Mfg Co Ltd | Material for organic electroluminescent device and organic electroluminescent device using the same |
KR20070102821A (en) * | 2006-04-17 | 2007-10-22 | 삼성에스디아이 주식회사 | Photosensitizer for photovoltaic cell, and photovoltaic cell prepared from same |
Also Published As
Publication number | Publication date |
---|---|
KR20120122844A (en) | 2012-11-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Tang et al. | New starburst sensitizer with carbazole antennas for efficient and stable dye-sensitized solar cells | |
Hagberg et al. | Symmetric and unsymmetric donor functionalization. comparing structural and spectral benefits of chromophores for dye-sensitized solar cells | |
CN101235214B (en) | Organic ruthenium dye and dye sensitization solar battery | |
AU2009310805B2 (en) | Dye, photoelectric conversion element using the same, photoelectrochemical cell, and method of producing dye | |
KR101324781B1 (en) | Noble photosensitizer for photovoltaic cell and photovoltaic cell prepared from the same | |
Yu et al. | Novel pyrene-based donor–acceptor organic dyes for solar cell application | |
KR102571879B1 (en) | Sensitizing dye, sensitizing dye composition for photoelectric conversion, photoelectric conversion device using the same, and dye-sensitized solar cell | |
Maeda et al. | Unsymmetrical squarylium dyes with π-extended heterocyclic components and their application to organic dye-sensitized solar cells | |
Iqbal et al. | Impact of hydroxy and octyloxy substituents of phenothiazine based dyes on the photovoltaic performance | |
JP5706846B2 (en) | Dye, photoelectric conversion element and photoelectrochemical cell using the same | |
EP2272920B1 (en) | Dye for dye-sensitized solar cell and dye-sensitized solar cell including the same | |
JP2014043401A (en) | Metal complex and dye-sensitized solar cell using the same | |
KR101791161B1 (en) | Organic Dye and Dye-Sensitized Solar Cell | |
KR101324783B1 (en) | Noble photosensitizer for photovoltaic cell and photovoltaic cell prepared from the same | |
CN101412855B (en) | Bipyridine ruthenium dye containing S, Se or Te as donating electron group and use thereof in dye sensitization solar cell | |
KR101323866B1 (en) | Noble photosensitizer for photovoltaic cell and photovoltaic cell prepared from the same | |
KR102448440B1 (en) | A sensitizing dye, a sensitizing dye for photoelectric conversion, a photoelectric conversion element using the same, and a dye-sensitized solar cell | |
KR101264082B1 (en) | Photosensitizer containing benzothiazole for photovoltaic cell, and photovoltaic cell including the same | |
KR101323867B1 (en) | Noble photosensitizer for photovoltaic cell and photovoltaic cell prepared from the same | |
KR101218318B1 (en) | NOBLE Ru-TYPE PHOTOSENSITIZER FOR PHOTOVOLTAIC CELL AND PHOTOVOLTAIC CELL PREPARED FROM THE SAME | |
CN101497745B (en) | Organic dye and dye-sensitized solar cell prepared thereby | |
KR20110127026A (en) | Organic dye and dye-sensitized solar cell | |
Pei et al. | Application of triphenylamine-based sensitizers with two carboxylic acid groups to dye-sensitized solar cells | |
KR20130089024A (en) | Phenothiazine derivatives and dye-sensitized solar cell having the same | |
KR101806162B1 (en) | Dye sensitized solar cell and solar cell using the same |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A201 | Request for examination | ||
E902 | Notification of reason for refusal | ||
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant | ||
FPAY | Annual fee payment |
Payment date: 20161007 Year of fee payment: 4 |
|
FPAY | Annual fee payment |
Payment date: 20181004 Year of fee payment: 6 |
|
FPAY | Annual fee payment |
Payment date: 20191002 Year of fee payment: 7 |