KR20120085696A - Clean substitute energy of Hydrogen and apparatus thereof - Google Patents

Abstract

PURPOSE: A method and an apparatus for generating hydrogen as clean substitute energy are provided to efficiently generate hydrogen energy without harmful materials by implementing operational processes without a fossil energy and atomic power. CONSTITUTION: An apparatus for generating hydrogen as clean substitute energy includes a hydrogenation reactor(10), thermal media dowtherm(20), a water storing container(30), a gas-water separator(40), a hydrogen cell(50), and a wet steam pipe(60). A plurality of plastic balls(A) is stored in the hydrogenation reactor to generate hydrogen. The thermal media dowtherm is in connection with the internal part of the hydrogenation reactor by water circulating pipes(11, 11') to implement thermal conduction. The water storing container is in connection with the hydrogenation reactor by water circulating pipes(12, 12'). The gas-water separator is in connection with the pipe(13) and a steam pressure container(14) of the hydrogenation reactor to separate gas and water. The hydrogen cell is in connection with the upper part of the gas-water separator to generate power. The wet steam pipe is connected between the lower part of the gas-water separator and the water storing container.

Description

Clean substitute energy of hydrogen and apparatus

The present invention relates to a method and apparatus for producing alternative energy dry hydrogen from water using a high-density polymer material, and more particularly, by colliding a plastic ball, a high-density polymer material having a melting point of 230 to 700 ° C, sikimeuroseo occurrence, heated to high temperature the temperature was increased to 80% of the polymer material the melting point and, by direct injection of water (H ₂ O) to the material of the high temperature the water (H ₂ O) to hydrogen (H) atoms and oxygen (O molecules After dissociation of the atom into hydrogen, it is converted into hydrogen (H ₂ ) molecule and oxygen (O ₂ ) molecule, and the remaining water vapor (H ₂ O) is recycled and clean alternative energy that mass-produces hydrogen (H ₂ ) as a clean alternative energy. A method for producing dry hydrogen and a device therefor.

According to Einstein's theory of mass and energy equivalence in the theory of relativity, mass and energy are the same and can be interchanged. His special theory of relativity also suggests that nuclear and nuclear reactions may not necessarily coincide with material and energy conversion.

The material and energy reaction inside the sun are four hydrogen (H) nuclei and four hydrogen nuclei emit one helium nucleus and two positrons (semi-particle material), depending on the principle of mass and energy equivalence. Depending on the affinity temperature, material energy conversion occurs in a way that does not conform to the theory of special relativity.

In the fusion reaction of hydrogen material, the sum of the masses of the helium nuclei and the two positrons (anti-particle material) produced after the reaction is reduced by about 0.7% compared to the mass of the four hydrogen atoms nuclei before the fusion reaction. Mass is converted into enormous energy according to the principle of mass energy equivalence.

On the other hand, in the nuclear fission reaction, for example, in nuclear power generation, in the nuclear uranium (MW235) nuclear fission reaction, unlike the nuclear fusion reaction, there is a 0.1% mass loss of the uranium atomic nucleus mass, which is converted into energy by the mass, and various radioactive materials are produced.

The rapid development of the petroleum industry after World War II provided various conveniences to humankind. Among them C ₆ H ₆ And C ₂ H ₄ The development of technology to convert such materials into styrene monomers (C ₆ H ₅ CHCH ₂ ) has made mankind enjoy the fossil energy and plastic age, and the recent development of nuclear energy has enriched mankind.

However, modern abundant material life has given humanity a fatal difficulty that cannot be overcome, and the use of carcinogen dioxins and automobiles in the process of incineration of garbage, which is a huge amount of daily waste that comes out daily, amid the depletion of oil resources. In the fossil energy combustion process, soot, especially carbon dioxide, and various harmful gases emitted from thermal power plants and oxygen shortages in the atmosphere are mentioned. As a result, it significantly disrupts the balance of nature through changes in global climate, soil pollution, water pollution, marine pollution, ozone depletion, and thawing of the Antarctica and alpine ice caps, causing varieties of humans and plants, deadly incurable diseases and incurable diseases. At the same time, it is putting ecosystems, including humans, into the crisis. These disaster scenarios require fundamental changes in human consciousness, and the development of innovative new technologies and further development of fossil energy substitutes is urgently needed.

Moreover, the urgent task of modern humans is to immediately stop the use of fossil fuels and waste incineration in order to protect the ozone layer (O ₃ ) from destruction and prevent the "back effect" of global climate change.

In addition, in order to prevent resource depletion, it is urgent to develop a technology that converts the materials used first, recovers them by component, and converts them into "beneficial materials" and "harmless materials".

In this regard, countries around the world are striving to produce hydrogen energy in preparation for the depletion of fossil fuels and to reduce the emissions of harmful gases. Among them, water (H ₂ O) was electrolyzed and replaced with clean energy hydrogen (H ₂ ), but the value of H ₂ 1L is more than 10 times higher than the production price fossil fuel, Since there is no way to avoid occurrence, the practical use is very long.

Therefore, as far as the conventional technology of generating clean alternative energy hydrogen (H ₂ ), "waste plastic processing method and apparatus" of Patent Registration No. 10-O855608, the inventors have applied for a patent, as the only alternative method disclosed have.

The waste plastics processing method and apparatus of Patent Registration No. 10-O855608 are mixed with the waste plastics without separating them into low-density, flame-retardant and high-density materials according to the molecular weight, and mixed with them. In addition, by applying the molecular affinity of plastics, 3kW high-voltage electricity and 2,450MHz ultra-high frequency are applied through dielectric heating to generate frictional heat of hydrogen molecules to liquefy the waste plastic mixture at the same time and resynthesize it into liquid mixture. A method of reciling to produce a clean alternative energy hydrogen (H ₂ ) gas from plastic resinous materials and by-products is disclosed.

The patent invention is the only alternative to the material-based circulation treatment technology under the current environmental industry structure, and it can fundamentally eradicate the generation of various harmful gases causing the depletion of fossil energy, ozone layer destruction, and global climate change. As a result, it has an excellent effect of preserving the ecosystem and preventing serious damage to the natural environment.

Accordingly, the invention of the patent is internationally recognized by the International Search and Technical Examining Authority (WOSA) and the International Search Institution (ISA) established by the WIPO International Bureau (IB) in accordance with Article 103 of the US Patent Act and Article 27 of the TRIPS Patent Act, "non-obvious patent requirements." It was confirmed as "non-obvious green technology" after investigation, and was registered as International Book Catalog No. 1 as WIPO International Registration No .: WO / 2009/048312 A1 (2009.4.16.).

The patent invention is an invention that corresponds to a case where a non-commercial implementation is necessary for the benefit of the public, and all WTO member governments are treated as the most favored nations in Article 2 of Article 3 of the Framework Act on Low Carbon Green Growth: (International Standard Green Technology). Regardless of the patent owner's intention, it is an invention that pays compensation according to the compulsory decree and makes it mandatory for the government or a third party.

However, on the other side of the patent invention, without using a separate energy source such as fossil fuel, if only the artificial energy can be thermally induced by chemical reaction inside the polymer material, this thermal energy can be used for harmful substances. It is possible to provide an engine for producing alternative energy materials, that is, a type 2 permanent engine, without the occurrence of.

On the other hand, the conventional prior art for generating alternative energy (H ₂ ) other than the above patent invention is disclosed in "Hydrogen generator using chemical hydride" of Patent Publication No. 2009-0114559. Patent Publication No. 2009-0114559 discloses a "hydrogen generator using a chemical hydride" has been disclosed, the publication has a hydrogen outlet 102 having a check valve 103a as shown in FIG. A cell module in which unit cells 110 including an electrolyte containing a chemical hydride and a catalyst are inserted between the housing 101 and the electrode 122 are stacked, and the electrodes 122 of the unit cells 110 are paralleled. In the hydrogen generating apparatus using a chemical hydride comprising a common conductor (122a) for connecting, and a switch (124) installed in the conductor for opening and closing the circuit between the electrodes (122) of the unit cells (110); The housing 110 is configured to be opened and closed by being separated into a main body housing 101a and a cap housing 101b so as to easily remove the reaction by-products; In the housing 101, a temporary storage space 104, a water storage space 131, and a water permeable membrane 134 are provided, and a check valve is provided to allow external water to enter the water storage space 131. A water supply pipe 132 having a 133 is connected thereto, and a switch 124 is installed on a conductive line 123 connected to the common conductive line 122a, and each thread line 101a is provided on an inner circumferential surface of a lower end portion that is a coupling portion of the cap housing 101b. -1,101b-1) is a device for generating hydrogen that hydrolyzes chemical hydrides.

However, the hydrogen generating apparatus using the chemical hydride has the advantage that the hydrogen production can be easily controlled by hydrolyzing the hydride, but the drawback of using a catalyst in the apparatus and the amount of hydrogen compared to chemical hydrides Not only is it inefficient, it is inefficient, and by-products are generated and additional expenses are incurred in the by-products treatment, which makes it economically inefficient.

The present inventors have made diligent studies to solve various defects and problems that occur in the conventional "hydrogen generator using chemical hydride" and "the waste plastic processing method and apparatus" of the inventors patent No. 10-0855608. Subsequently, the plastic ball, which is a high-density polymer material, is heated to 80% of its melting point and heated to high temperature, and there is no harmful substance from the water by directly injecting water (H ₂ O). The breakthrough method and apparatus for mass production of dry hydrogen (H ₂ ) has been completed and the present invention has been filed.

Accordingly, it is an object of the present invention to provide a method for mass production of clean alternative energy hydrogen (H ₂ ) without generation of harmful substances using high density polymer material and water.

Another object of the present invention by using the high heat energy generated during the collision of the high-density polymer plastic ball, explodes water (H ₂ O) to produce a dry energy alternative material dry hydrogen (H ₂ ) and oxygen (O ₂ ) In addition, the remaining water (H ₂ O) is to provide a hydrogen production apparatus that can be recycled without generating harmful gases or other by-products.

The apparatus for producing clean alternative energy hydrogen of the present invention for achieving the above object comprises a hydrogenation reactor (10) for storing a plurality of plastic balls (A) to produce hydrogen (H ₂ ); A dowtherm (20; dowtherm) connected to a water circulation pipe (11, 11 ') inside the hydrogenation reactor (10) for heat conduction; A water reservoir 30 connected to the hydrogenation reactor 10 by a water circulation pipe 12 and 12 'to supply water; A water separator (40; 氣 水 分離 器) connected to the hydrogenation reactor (10) via a pipe (13) and a steam pressure tube (14) to separate gas and water; A hydrogen cell 50 connected to an upper portion of the water separator 40 through a pipe 15 and a hydrogen pressure cylinder 16 to generate electric power; Consists of a pipe (60) connected between the lower portion of the water separator (40) and the water reservoir (30) to move oxygen and water vapor (H ₂ O) from the water separator (40) to the water reservoir (30). It features.

On the other hand, the production method of the clean alternative energy hydrogen of the present invention, the plastic ball preparing step (S1 step) to melt the high-density polymer material to make the plastic ball (A); A plastic ball input step (S2 step) of inserting the plastic ball (A) into the hydrogenation reactor (10); The plastic ball A is rotated by the rotation of the rotating plate 10a by a motor while heating the inside of the hydrogenation reactor 10 by the heat medium 10b in the wall of the hydrogenation reactor 10 and the heat medium of the dowtherm. As a result of the chaos movement, the plastic balls (A) rub against each other, causing the sparks to collide with positive (+) and negative (-) collisions according to the hydrogen (H ₂ ) molecular rotational movement inside the plastic balls (A). Plastic ball friction step (S3 step) to generate; The heat temperature rising step of raising the temperature of the water (H ₂ O) passing through the water circulation pipe (10c) to the heat medium (10b) in the wall of the hydrogenation reactor 10 to the 90 ° C or more ( Step S4); Water molecules while being blown at the moment when the hot water (H ₂ O) of 90 ℃ or more is injected into the top of the hydrogenation reactor 10 in the plastic ball (A) of 150 ℃ ~ 560 ℃ big bang (Big Bang) Dissociating and dissociating the water (H ₂ O) material into the hydrogen (H) atom and the oxygen (O) atom material and fusion step (step S5); The hydrogen (H) atom, oxygen (O) atom and the remaining water vapor dissociated from the water (H ₂ O) generated in the H atomic material generation step (step S5) move to the steam pressure cylinder 14 and again hydrogen ( H ₂ ) Molecules and oxygen (O ₂ ) molecules are converted to the material at this time is moved to the separator (40) H at the affinity temperature of the water H atoms are fused to dry hydrogen (H ₂ ) molecules H ₂ Characterized in that it consists of a fusion step (S6 step).

According to the experimental results of the present inventors, 0.11% of the H atomic material generated in the hydrogenation reactor 10 passes through the steam pressure cylinder 14 and fused with hydrogen in the water separator 40 to be delivered in the hydrogen pressure cylinder 16. The thermal efficiency is stored as hydrogen (H ₂ ) gas is 40% and produced 0.915kW / h of power from the hydrogen cell (50). At this time, dry hydrogen (H ₂ ) gas is not introduced because oxygen (O ₂ ) molecules are completely separated from the separator (40), so there is no risk of hydrogen (H ₂ ) explosion in the hydrogen pressure cylinder (14) and thus without safety accidents. Could use for save.

The present invention does not use fossil energy and nuclear power, can efficiently generate hydrogen (H ₂ ) energy without generating various harmful substances, and uses high heat energy generated inside the ball by collision of plastic balls, which are high density polymer materials. Water (H ₂ O) to explode (big bang) to obtain dry hydrogen (H ₂ ) and to recycle the rest of the water, while producing a large amount of alternative material clean energy hydrogen (H ₂ ) has the effect that no by-products at all. .

In addition, according to the present invention not only solve the problem of depletion of fossil energy, drinking water (H ₂ O) faced by humanity, but also solve the adverse effects of global climate change, hydrogen (H ₂ ) in a way that is eco-friendly and excellent economic efficiency By mass production of not only replaces thermal power plants and nuclear power plants, but also has the effect of infinitely using hydrogen (H ₂ ) electricity as a clean alternative energy.

In addition, the use of the clean alternative energy production method of the present invention, in the future, the desalination of seawater can achieve the greening of the Yellow Sands of Gobi Desert and the farming of the Sahara Desert, thereby solving global food shortages and sustaining the world. It will bring about possible economic development, eradicate the generation of various harmful gases that cause global depletion of fossil energy, ozone layer destruction and global climate change, thereby protecting the lives and health of humans, animals and plants, and protecting nature and the environment. There is an excellent effect that can be prevented.

1 is a configuration diagram showing an embodiment of a hydrogen (H ₂ ) gas production apparatus by a conventional electrolysis method.
2 is a photograph showing a shape of a ball of a high density polymer prepared and prepared according to an embodiment of the present invention.
3 is a block diagram of a hydrogen (H ₂ ) gas production apparatus using the present invention plastic ball,
4 is a detailed configuration of the hydrogen production apparatus using the plastic ball of the present invention,
5 is a flowchart illustrating a method of producing hydrogen using the plastic ball of the present invention.

Hereinafter, with reference to the accompanying drawings will be described in detail a preferred embodiment of the hydrogen production method and apparatus using the present invention plastic ball.

Figure 2 is a photograph showing the shape of the ball of the high-density polymer material prepared according to an embodiment of the present invention, Figure 3 is a block diagram of a hydrogen production apparatus using the plastic ball of the present invention, Figure 4 is hydrogen using the plastic ball of the present invention Detailed configuration diagram of the production apparatus, Figure 5 is a flow chart of the execution of the hydrogen production method using the plastic ball of the present invention, the production apparatus of the clean alternative energy hydrogen of the present invention, a number of plastic balls (A) are stored hydrogen (H ₂ ) A hydrogenation reactor 10 for producing a; Dow Island (20; dowtherm) is connected to the water circulation pipe (11, 11 ') inside the hydrogenation reactor (10) for heat conduction; A water reservoir 30 connected to the hydrogenation reactor 10 by a water circulation pipe 12 and 12 'to supply water; A water separator (40; 氣 水 分離 器) connected to the hydrogenation reactor (10) via a pipe (13) and a steam pressure tube (14) to separate gas and water; A hydrogen cell 50 connected to an upper portion of the water separator 40 through a pipe 15 and a hydrogen pressure cylinder 16 to generate electric power; Is connected between the lower portion of the water separator 40 and the water reservoir 30 is composed of a pipe 60 for moving oxygen and water vapor (H ₂ O) from the water separator 40 to the water reservoir (30). .

The hydrogenation reactor 10 is wound between the rotating plate 10a coupled to the rotary shaft 17 of the motor installed in the lower portion, the heat medium 10b embedded in the wall, and the inner and outer cylinders along the wall to circulate water. It is composed of a water circulation pipe (10c), the lower one side is further provided with a water inlet 10d to inject water into the water circulation pipe (10c).

The water separator 40 has a plurality of diaphragms 40a are horizontally separated over the upper and lower portions thereof, and the steam pressure vessel 14 and the hydrogen pressure vessel 16 adjust the pressure of steam and hydrogen, respectively. It is to.

On the other hand, the production method of the clean alternative energy hydrogen of the present invention is a plastic ball preparation step (S1 step) of melting the high-density polymer material to make the plastic ball (A); A plastic ball input step (S2 step) of inserting the plastic ball (A) into the hydrogenation reactor (10); The plastic ball A is rotated by the rotation of the rotating plate 10a by a motor while heating the inside of the hydrogenation reactor 10 by the heat medium 10b in the wall of the hydrogenation reactor 10 and the heat medium of the dowtherm. Disruptive movement of the plastic balls (A) friction with each other to generate a spark with a positive charge (+) and a negative charge (-) in accordance with the rotation of hydrogen molecules in the plastic ball (A) to the temperature of the ball 150 ℃ ~ 560 ℃ Plastic ball friction step of increasing the temperature (step S3); A water temperature raising step (S4 step) of raising the temperature of water (H ₂ O) passing through the water circulation copper pipe (10c) to the heat medium (10b) in the wall of the hydrogenation reactor (10); H atom material generation step (S5 step) of producing a H atom material by dissociating the explosion of water of 90 ℃ high temperature to the plastic ball (A); H ₂ gas synthesis step (S6 step) of nuclear fusion of the H atom material with oxygen (O) atom-free dry hydrogen (H ₂ ) molecular material at the affinity temperature in the synthesis step (S5 step) to fuse the nucleus of the H atomic material Consists of.

In the plastic ball friction step (step S3), the temperature around the plastic ball (A) should be in the range of 150 ° C to 560 ° C, and the water in the hydrogenation reactor 10 in the step of increasing the water temperature (step S4) (H ₂ O) The temperature around the molecule should also be in the range 150 ° C to 560 ° C.

The steam generated in the hydrogenation reactor 10 in the H atomic material generation step (S5 step) is a dry hydrogen (H ₂ ) gas in the water separator (40; 氣 水 分離 器) through a steam pressure cylinder (14), Separated into oxygen (O ₂ ) and water vapor (H ₂ O).

At this time, the dry hydrogen (H ₂ ) synthesized by fusion is applied to the hydrogen cell 50 to produce electric power, and the wet steam (H ₂ O) and oxygen (O ₂ ) molecules are two water (H ₂ O) molecules. The switch is introduced into the water reservoir 30 and recycled.

In this case, the power production efficiency of the hydrogen battery 50 was 0.915 kW / h per 1 g of dry hydrogen (H ₂ ).

The high-density polymer material constituting the plastic ball (A) used in the present invention is prepared by vacuum fusion preparation of polyester, and generally, a high-density polymer material having a molecular weight (MW) of 20,000 or more is preferable.

When the polymer material is rotated at high speed to artificially friction and collision with each other, the hydrogen atom (H) material constituting the polymer material starts a rotational movement, and as a result, a chemical exothermic reaction causes heat to be released in the molecule. It is generated and applied as a high temperature material, and the temperature is elevated to a surface temperature of 180 ° C. or higher to generate heat conduction with other materials.

The thermally conductive medium used in the present invention is characterized by low pressure at a high temperature in a liquid phase, and a dowtherm capable of heat transportation even at a high temperature of 260 to 400 ° C is preferable.

In the present invention, the diameter of the plastic ball obtained by melting the polyester is preferably 10 to 15 mm.

According to the apparatus of the present invention, when rotating the speed of the rotating plate 150 ~ 800rpm plastic ball diameter 10mm ~ 15mm material is made of resin (ball) consisting of a molecular weight of 20,000 or more is a rotating plate (10a) in the reactor (10) When 10a collides with each other while rolling violently between balls, the hydrogen (H ₂ ) molecules constituting the polymer material first start disorderly rotational movement. At this time, when the plastic ball diameter is 10mm or less in the hydrogenation reactor, the melting point is lowered, but the heat of friction is increased. On the other hand, in the case of more than 15mm in size, the melting point increases but the rolling frictional heat is reduced. Therefore, when the ball diameter is lowered, when heat energy is released from the inside of the ball, the ball melts from the center of the ball, the hole is drilled out of the ball, and the reactor of the present invention is broken to stop operation.

On the other hand, in the present invention, the most preferable rotation speed of the rotating plate 10a of the reactor is 150 ~ 800rpm. If the rotation speed of the rotating plate is 800rpm or more is not preferable because the polymer material used in the present invention is dissolved. On the other hand, when the rotational speed of the rotating plate 10a is 150rpm or less, the water (H ₂ O) does not explode and thus does not dissociate water molecules and separate hydrogen atoms (H) and oxygen atoms (O). The expected effects of the present invention cannot be achieved.

The molecular motion of many molecules that make up a material is a function of the frictional forces between the materials and the magnitude of the disordered motion of the molecules. In addition, the polymer material rises to a temperature higher than 180 ℃ with free energy increase, and the intermolecular impact friction heat released from the polymer material generates infinite free thermal energy without supplying energy fuel, thereby increasing entropy.

In addition, the polymer material itself absorbs high-temperature energy due to the flame phenomenon, while the polymer material heats the inner plate and the outer plate of the rotating plate and the reactor. The temperature rises to 200 ° C, and the temperature of the water passing through the water circulation copper pipe composed of copper material having a diameter of 5mm to 20mm installed on the inner and outer walls of the hydrogenation reactor is raised to a temperature of 80 to 90 ° C. The water heated to 80 ~ 90 ℃ is directly injected into the plastic ball through the water reservoir through the water circulation copper pipe, the water is exploded by the temperature of the high temperature plastic ball, the steam exploded at this time In water (H ₂ O) is dissociated and hydrogen atom (H) and oxygen atom (O) and then hydrogen (H) is fused to produce dry steam hydrogen gas (H ₂ ).

According to the present invention, when the high-density polymer material introduced into the hydrogenation reactor collides with friction by the rotation of the rotating plate in the reactor of the present invention, impact friction occurs between molecules in the material system, and then thermal energy is generated and static electricity is generated, and the surface of the polymer material Temperature rises to 100 degreeC-200 degreeC, and becomes high temperature. The temperature of the water in the water circulation copper pipe generated inside and outside the reactor cylinder is increased to 80 ~ 90 ℃ and the saturated water vapor by the heat energy generated from the polymer material in the reactor at the moment the water of the temperature is introduced from the top to the bottom of the reactor The water (H ₂ O) is a big bang. At this time, saturated steam reaches the affinity temperature 100 ~ 884.36 ℃ after evaporation, and water vapor (H ₂ O) is dissociated into hydrogen atom (H) and oxygen (O ₂ ) molecules, and then ionized in the polymer material and released with thermal energy. Oxygen (O ₂ ) molecules react as shown in the following reaction formula (1) until thermal parallelism is achieved by positive and negative charges (−).

3H₂[3(H:H)] + O₂[O::O] + O[O] ------------------------ (1)
3 (H ₂ O)

3H ₂ [3 (H: H)] + O ₂ [O :: O] + O [O] ------------------------ (1 )

In the formula (1), when the friction of the molecules inside the molecular material due to the collision of the plastic ball (A) used in the present invention is too large, the free thermal energy is large and oxygen exceeds the vaporization point of water (100 ℃, absolute temperature 373.15K) And dissociation of water molecules in which hydrogen and hydrogen are separated, and accordingly, according to the present invention, a technique of producing electrical energy by producing hydrogen (H ₂ ) material is provided, which is caused by static electricity due to mutual impact friction of high density polymer materials. As static electricity is generated, sparks are generated and the surface temperature of high-density polymer material rises by more than 180 ℃, and the temperature of water in the water circulation pipe wound around the outer wall of the reactor is wound up to 90 ℃ as the temperature of polymer material rises. To be raised. On the other hand, when a water explosion (big bang) occurs due to a flame reaction, hydrogen atoms and oxygen atoms are continuously separated, thus producing hydrogen electric energy using water vapor, causing depletion of fossil energy, ozone layer destruction, and global climate change. By fundamentally eradicating the occurrence of various harmful gases, the green industry is very effective in maintaining and preserving the global crisis and the life and health of animals, plants, and human beings, and preventing serious damages to the natural environment. It is to provide a useful invention.

< Example  1>

The hydrogen production method and apparatus using the plastic ball of the present invention was carried out in July 2007 in Gwangju.

As a high density polymer material, a resin (Resins) was added to a mold and melted at 230 ° C. to prepare a plastic ball (A) having a diameter of 10 mm.

The plastic ball (A) 30kg put into the hydrogenation reactor 10 of the present invention by rotating the rotary plate (10a) by a motor to displace the plastic ball (A) by plastic ball (A) friction with each other plastic ball It took 90 minutes for the temperature of (A) to reach 147 ° C. Hydrogen (H ₂ ) molecular material was continuously produced by spraying water at 90 ° C. directly on the plastic ball (A) at the temperature.

Steam and H atomic material generated in the hydrogenation reactor 10 is passed through a water separator (40; 氣 水 分離 器) to dry hydrogen (H ₂ ) molecules, oxygen (O ₂ ) molecules and wet steam (2H ₂ O ) And dry hydrogen (H ₂ ) molecules are applied to the hydrogen cell 50 to generate electricity, and wet steam (2H ₂ O) and oxygen (O ₂ ) molecules are combined with water (H ₂ O). 30).

As a result of the implementation of the present invention, the amount of electricity produced in the hydrogen cell 50 is confirmed that the increase in thermal efficiency with respect to the amount of electricity delivered to the rotating shaft 17 is increased by 29 times. In other words, it can be confirmed from the experiment results that the fossil fuel in power generation efficiency increases 29 times than the power generation using raw materials.

< Example  2>

The hydrogen production method and apparatus using the plastic ball of the present invention was conducted in May 2011 in Seoul.

In the same manner as in Example 1, a resin, which is a high-density polymer material, was added to a mold and melted at 300, thereby preparing a plastic ball (A) having a diameter of 10 mm.

The plastic ball 30A is put into the hydrogenation reactor 10 of the present invention, and the rotary plate 10a is rotated by a motor to cause the plastic ball A to be disordered. It took 120 minutes for the temperature of A) to reach 200 ° C. Hydrogen (H ₂ ) molecular material was continuously produced by spraying water at 90 ° C. directly on the plastic ball (A) at the temperature.

The steam and H molecules produced within the hydrogenation reactor (10) Separator (40;氣水分離器) by passing a case separated into hydrogen (H ₂₎ molecules and the oxygen and water vapor gun hydrogen (H ₂₎ molecule Was applied to the hydrogen cell 50 to generate electricity, and water vapor and oxygen were introduced into the water reservoir 30 together with water (H ₂ O).

As a result of the implementation of the present invention, the amount of electricity produced by the hydrogen cell 50 was confirmed that the increase in thermal efficiency with respect to the amount of electricity delivered to the rotating shaft 17 of the motor increases by 29 times.

While the present invention has been described as a preferred embodiment, the present invention is not limited thereto, and various modifications can be made without departing from the spirit of the invention.

10: hydrogenation reactor 10a: rotating plate
10b: heat medium 10c: water circulation pipe
10d: Water inlet 11, 11 ': Water circulation pipe
12, 12 ': water circulation piping 13: piping
14: steam pressure vessel 15: piping
16: hydrogen pressure cylinder 17: rotating shaft
20: dowtherm 30: water reservoir
40: water separator 40a: diaphragm
50: hydrogen battery 60: wet steam piping
A: Plastic Ball

Claims (11)

A hydrogenation reactor 10 in which a plurality of plastic balls A are stored to produce hydrogen (H ₂ ); A heat medium Dow Island (20; dowtherm) connected to the water circulation pipes (11, 11 ') inside the hydrogenation reactor (10) for heat conduction; A water reservoir 30 connected to the hydrogenation reactor 10 by a water circulation pipe 12 and 12 'to supply water; A water separator (40; 氣 水 分離 器) connected through a pipe (13) and a steam pressure tube (14) of the hydrogenation reactor (10) to separate gas and water; A hydrogen cell 50 connected to an upper portion of the water separator 40 through a pipe 15 and a hydrogen pressure cylinder 16 to generate electric power; Wet steam pipe connected between the lower portion of the water separator 40 and the water reservoir 30 to move oxygen (O ₂ ) and water vapor (H ₂ O) from the water separator 40 to the water reservoir 30 ( 60) Production apparatus of clean alternative energy hydrogen.
According to claim 1, wherein the hydrogenation reactor 10 has a rotating plate 10a coupled to the rotary shaft 17 of the motor on the lower surface, the heat medium (10b) built into the wall, and wound along the inner wall to circulate water Comprising a water circulation pipe (10c), the lower one side of the water inlet for injecting water into the water circulation pipe (10c) 10d, characterized in that the apparatus for producing clean alternative energy hydrogen.
The apparatus of claim 1, wherein the water separator (40) is provided with a plurality of diaphragms (40a) at regular intervals across the upper and lower parts to separate gas and water.
Plastic ball preparation step (S1 step) to melt the high-density polymer material to make a plastic ball (A); A plastic ball input step (S2 step) of inserting the plastic ball (A) into the hydrogenation reactor (10); The plastic ball A is rotated by the rotation of the rotating plate 10a by a motor while heating the inside of the hydrogenation reactor 10 by the heat medium 10b in the wall of the hydrogenation reactor 10 and the heat medium of the dowtherm. When the plastic balls (A) are rubbed with each other to cause a disordered movement of the plastic balls (A), when the sparks are generated with positive and negative charges in accordance with the rotational movement of the hydrogen molecules inside the plastic balls (A), the thermal energy is 150 ° C to 560 ° C. Friction plastic step (S3 step) to the high temperature; A water temperature raising step (S4 step) of raising the temperature of water (H ₂ O) passing through the water circulation copper pipe (10c) to the heat medium (10b) in the wall of the hydrogenation reactor (10); A hydrogen atom (H) material generation step (S5 step) of dissociating water by injecting the hot water into the plastic ball (A) and generating a hydrogen atom (H) material; Hydrogen gas (H) for nuclear fusion of hydrogen atom (H) material produced in the hydrogen atom (H) material generation step (step S5) with dry hydrogen (H ₂ ) molecular material without oxygen atom (O) at water affinity temperature ₂ ) A method of producing clean alternative energy hydrogen, characterized in that consisting of a synthesis step (S6 step).
The method of claim 4, wherein the plastic ball (A) in the preparing step (S1 step) of the material of the plastic ball is a resin (resin) having a molecular weight of 20,000 or more and the size of the diameter is 10 to 15mm.
The method according to claim 4, wherein the liquid heat medium in the wall of the hydrogenation reactor in the rubbing step (S2 step) of the plastic ball (A) is Dow.
The temperature of the plastic ball (A) in the friction step (S3 step) of the plastic ball is 150 ℃? Method for producing clean alternative energy hydrogen, characterized in that in the range of 560 ℃.
The method of claim 4, wherein the rotational speed of the rotating plate installed in the lower portion of the reactor and rotated by a motor is 150 ~ 800rpm.
The method of claim 4, wherein the temperature of the water (H ₂ O) in the step of raising the water temperature (S4 step) is 80 ~ 90 ℃ characterized in that the production of hydrogen hydrogen.
The steam and hydrogen atom (H) material generated in the hydrogenation reactor (10) in the hydrogen atom (H) material generation step (S5 step) is a water separator (40) Hydrogen (H ₂ ) molecules are separated into oxygen (O ₂ ) molecules and water vapor (H ₂ O), and hydrogen (H ₂ ) molecules are applied to the hydrogen cell 50 to produce electric power. Method of producing a clean alternative energy hydrogen, characterized in that moved to the reservoir (30).
The method of claim 10, wherein the power production efficiency of the hydrogen battery (50) is a method of producing a clean alternative energy hydrogen, characterized in that 0.915kW / h per 1g of hydrogen (H ₂ ) molecules.

Images