KR20120066476A - Ti added ferritic stainless steel with improved ridging property and method of manufacturing the same - Google Patents

Abstract

PURPOSE: A titanium-containing ferritic stainless steel with superior ridging resistance and a manufacturing method thereof are provided to reduce the size of grains and ridging by controlling annealing temperatures and to shorten the polishing time of end products. CONSTITUTION: Titanium-containing ferritic stainless steel with superior ridging resistance comprises C of 0.05 weight% or less(except 0), Si of 1.0 weight% or less(except 0), Mn of 1.0 weight% or less(except 0), P of 0.050 weight% or less(except 0), S of 0.020 weight% or less(except 0), Ni of 2.0 weight% or less(except 0), Cr of 15.0-25 weight%, Cu of 1.0 weight% or less, Nb of 0.1-0.5 weight%, Ti of 0.01-0.3 weight%, Al of 0.10 weight% or less(except 0), N of 0.05 weight% or less(except 0), one or more selected from Mo of 1.0 weight% or less(except 0), V of 0.01-0.30 weight%, Zr of 0.01-0.30 weight%, and B of 0.0010-0.0100 weight%, and Fe and inevitable impurities of the remaining amount.

Description

Ti-added ferritic stainless steel with excellent dropping property and manufacturing method thereof {TI added ferritic stainless steel with improved ridging property and method of manufacturing the same}

The present invention relates to a Ti-added ferritic stainless steel and a method for manufacturing the same, and more particularly, to a ferritic stainless steel and a method for producing the same for improving the ridging characteristics.

Among stainless steels, especially ferritic stainless steel is mainly used in automobile exhaust system parts, building materials, kitchen containers, home appliances, etc., and the parts are manufactured by deep drawing, so the formability is one of the important quality characteristics. It is also important to reduce the defects formed on the surface after molding.

In the case of ferritic stainless steel, wrinkle-like surface defects occur parallel to the rolling direction during molding, and this phenomenon is called ridging. The cause of leasing is primarily due to the coarse cast structure. That is, when the cast structure remains as a coarse band structure without breaking in the rolling or annealing process, it is expressed as a ridging defect due to the width and thickness deformation behavior different from the surrounding recrystallized structure during tensile processing. If such ridging defects occur severely, an additional polishing process is required after molding, which increases the manufacturing cost of the final product.

Many researchers have proposed various manufacturing methods for improving the formability and ridging properties of ferritic stainless steel. For example, there is a method of improving the ridging property by improving the equiaxed crystal ratio and reducing the fraction of the columnar tablet. This isotropic rate control is a method of solving the root cause causing the leasing, the lower limit of the equiaxed rate should be 60% level in order to obtain a steel sheet excellent in ridging resistance by ordinary rolling.

In addition, as a representative example of improving moldability and controlling ridging by controlling process variables in the manufacturing process, in order to promote recrystallization, it is appropriate to optimize the hot rolling temperature, hot rolling rolling reduction rate, hot rolling rolling reduction rate, annealing temperature, cold rolling recrystallization, etc. Various methods have been known, such as the addition of cold annealing processes to increase recovery.

Recently, a number of patents have been proposed regarding the relationship between the strength of crystal orientation components and manufacturing process factors with respect to texture control.

The present invention has been made in accordance with the above requirements, in order to lower the ridging height of the final cold-rolled material, to provide a ferritic stainless steel and a manufacturing method for improving the ridging characteristics by adjusting the annealing temperature to improve the grain size The purpose.

In order to achieve the above object, the present invention provides a weight percentage of C: greater than 0 and 0.05% or less, Si: greater than 0 and 1.0% or less, Mn: greater than 0 and 1.0% or less, P: greater than 0 and 0.050% or less, and S: greater than 0 and 0.020. % Or less, Ni: more than 0 and 2.0% or less, Cr: 15.0 to 25%, Cu: 1.0% or less, Nb: 0.1 to 0.5%, Ti: 0.01 to 0.3%, Al: more than 0 and 0.10% or less, N: more than 0 It is composed of 0.05% or less and optionally contains one or two or more of Mo: more than 0 and 1.0% or less, V: 0.01 to 0.30%, Zr: 0.01 to 0.30% and B: 0.0010 to 0.0100%, and the rest is Fe And cold rolling and annealing after annealing the stainless steel hot rolled sheet made of other unavoidable impurities, and after the cold rolling, the annealing temperature is controlled to be in the range of 950 ° C. to 1000 ° C. to provide an excellent ferritic stainless steel manufacturing method. do.

In the present invention, the cold rolling is performed at least twice.

In the present invention, the annealing after cold rolling is carried out at least two times, preferably two times.

In the present invention, the stainless steel has a grain size of 20 µm or less and a ridging height of 10 µm or less after the tensile test.

According to another embodiment of the present invention, in weight percent, C: greater than 0 and 0.05% or less, Si: greater than 0 and 1.0% or less, Mn: greater than 0 and 1.0% or less, P: greater than 0 and 0.050% or less, S: greater than 0 and 0.020 % Or less, Ni: more than 0 and 2.0% or less, Cr: 15.0 to 25%, Cu: 1.0% or less, Nb: 0.1 to 0.5%, Ti: 0.01 to 0.3%, Al: more than 0 and 0.10% or less, N: more than 0 It is composed of 0.05% or less and optionally contains one or two or more of Mo: more than 0 and 1.0% or less, V: 0.01 to 0.30%, Zr: 0.01 to 0.30% and B: 0.0010 to 0.0100%, and the rest is Fe And it provides a ferritic stainless steel excellent in the lowering property consisting of other unavoidable impurities and a grain size of 20㎛ or less.

 In the present invention, the annealing temperature after the cold rolling is controlled to 950 ℃ ~ 1000 ℃.

In the present invention, the stainless steel has a ridging height of 10 μm or less after the tensile test.

In the present invention, the stainless steel is cold rolled and annealed at least twice.

In the ferritic stainless steel provided by the present invention, in performing the cold rolling and subsequent annealing of the hot rolled sheet after annealing after hot rolling, the annealing temperature can be controlled to reduce the ridging defect of the surface through the refinement of grains. have.

Therefore, according to the present invention can be expected to reduce the manufacturing cost by reducing the polishing process time of the final product.

1 is a graph showing surface roughness measurement results according to the present embodiment.
Figure 2 is a graph showing the grain size and leasing height of the ferritic stainless steel used in this embodiment.

DETAILED DESCRIPTION Hereinafter, exemplary embodiments of the present invention and other matters required by those skilled in the art will be described in detail with reference to the accompanying drawings. However, the present invention may be embodied in various different forms within the scope of the claims, and thus the embodiments described below are merely exemplary, regardless of expression.

In the following description of the present invention, a detailed description of known functions and configurations incorporated herein will be omitted when it may make the subject matter of the present invention rather unclear. It should be noted that the same elements in the drawings are represented by the same reference numerals and symbols as much as possible even though they are shown in different drawings. In addition, the thickness and size of each layer in the drawings may be exaggerated for convenience and clarity, and may differ from actual layer thicknesses and sizes.

In the present invention, by weight%, C: greater than 0 and 0.05% or less, Si: greater than 0 and 1.0% or less, Mn: greater than 0 and 1.0% or less, P: greater than 0 and 0.050% or less, S: greater than 0 and 0.020% or less, Ni: 0 More than 2.0% or less, Cr: 15.0 to 25%, Cu: 1.0% or less, Nb: 0.1 to 0.5%, Ti: 0.01 to 0.3%, Al: more than 0 and 0.10% or less, N: more than 0 and 0.05% or less Optionally more than 1 or more of Mo: more than 0 and 1.0% or less, V: 0.01 to 0.30%, Zr: 0.01 to 0.30% and B: 0.0010 to 0.0100%, and the rest is substantially Fe and other conventional It relates to a stainless steel consisting of impurities. The present invention is subjected to cold rolling and cold rolling annealing after annealing the hot rolled stainless steel sheet in a conventional manner. At this time, the annealing after cold rolling is preferably carried out at least twice. Then, the annealing temperature after the cold rolling is controlled to 950 ℃ ~ 1000 ℃ to obtain a ferritic stainless steel having a grain size of 20㎛ or less and a leasing height of 10㎛ or less after the tensile test for the ferritic stainless steel manufactured by .

The mechanism of leasing in the present invention is due to the difference in plastic anisotropy between the region where the grains having the {001} crystal orientation with a low r value are clustered and the matrix having the {111} <uvw> crystal orientation with a high r value. Is being reported. Therefore, when the grain group having the {001} <110> crystal orientation is present, the ridging height is high. According to the rolling reduction rate and the number of rolling during cold rolling, the texture is changed. In other words, by performing two times of cold rolling and annealing, the fraction of the {001} <uvw> crystal orientation causing leasing is lowered.

The present invention not only suppresses the occurrence of leasing by lowering the fraction of the {001} <uvw> crystal orientation causing leasing by performing two times cold rolling and annealing, but also hot rolling, primary cold rolling and secondary cold rolling. It is characterized by reducing the surface roughness by minimizing the grain size by appropriately adjusting the annealing temperature.

(Example)

The present invention will be described using the following examples.

Commercially produced ferritic stainless steel was used for the experiment and Table 1 shows the alloying components of the ferritic stainless steel used in this example. Cold rolling was performed twice from a 4-5 mm thick hot rolled sheet hot rolled from a continuously cast slab. The annealing was performed by changing the temperature for each manufacturing process.

In order to evaluate the ridging, the tensile strength was measured by cutting the specimen in the 0 degree direction with respect to the rolling direction, processing the tensile specimen, and performing 15% tensile deformation, and then measuring the roughness with the surface roughness.

division C Si Mn Cr Ni Cu Al Nb Ti N Inventory 1 0.014 0.3 0.28 19.4 0.31 0.48 0.025 0.40 0.097 0.0139 Inventory 2 0.006 0.11 0.17 21.4 0.28 0.46 0.52 0.08 0.279 0.0087

1 is a graph showing the surface roughness measurement results according to the present embodiment. As shown in the figure, the surface roughness is 10 μm or less.

On the other hand, Table 2 shows the grain size and leasing height of the cold-rolled annealing plate according to the change in the annealing conditions. According to the table, it can be seen that the lower the annealing temperature, the smaller the grain size and the lower the ridging height.

Annealing Temperature (℃) Inventory 1 Inventory 2 Hot rolled Primary cold rolling Secondary Cold Rolling Grain size
(Μm) Surface roughness
(Μm) Grain size
(Μm) Surface roughness
(Μm) 950 950 15.2 7.63 1000 16.9 8.35 1050 19.2 9.37 1000 950 17.1 8.43 1000 19.2 8.19 1050 21.2 9.52 1050 950 17.8 8.83 1000 21.1 9.76 1050 20.5 11.69 950 950 950 17.1 7.6 19.3 9.9 1000 19.2 9.0 24.4 11.8 1050 23.2 10.6 31.9 15.9 1000 950 18.9 8.5 18.4 9.8 1000 19.3 8.4 26.0 13.9 1050 22.6 10.2 38.4 16.3 1050 950 18.9 8.6 22.4 11.9 1000 21.6 9.4 31.7 15.3 1050 22.6 11.2 41.6 15.6 1000 950 950 17.4 7.2 20.0 11.1 1000 20.3 9.3 28.3 13.1 1050 21.4 9.9 37.4 17.1 1000 950 16.8 7.7 20.1 10.8 1000 20.2 8.6 28.7 11.9 1050 23.3 9.8 36.7 16.4 1050 950 17.9 8.3 21.6 10.5 1000 19.8 10.4 29.4 12.2 1050 22.9 11.4 39.5 16.6 1050 950 950 17.7 8.1 20.5 11.3 1000 21.0 9.2 28.9 10.8 1050 26.3 10.9 41.9 13.2 1000 950 19.4 8.5 21.5 10.0 1000 23.2 10.4 33.3 12.0 1050 24.4 11.3 38.6 15.6 1050 950 19.7 8.7 24.9 11.4 1000 22.5 10.2 32.8 13.4 1050 25.9 11.4 34.0 14.9

In addition, Figure 2 shows the grain size and the leasing height of the ferritic stainless steel used in this embodiment. According to Figure 2 well shown the correlation between the grain size and the ridging height in the present invention. In other words, the smaller the grain size, the lower the ridging height. Therefore, in order to satisfy the ridging height of 10 mu m or less, it is preferable that the grain size is as small as 20 mu m or less. In order to satisfy the above conditions, it was found that in performing hot rolling, cold rolling, and subsequent annealing twice, the annealing temperature should be 950 ° C to 1000 ° C.

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the disclosed exemplary embodiments. It will be apparent to those skilled in the art that various modifications may be made without departing from the scope of the present invention.

Claims (9)

By weight%, C: greater than 0 and 0.05% or less, Si: greater than 0 and 1.0% or less, Mn: greater than 0 and 1.0% or less, P: greater than 0 and 0.050% or less, S: greater than 0 and 0.020% or less, Ni: greater than 0 and 2.0% Or less, Cr: 15.0 to 25%, Cu: 1.0% or less, Nb: 0.1 to 0.5%, Ti: 0.01 to 0.3%, Al: more than 0 and less than 0.10%, N: more than 0 and 0.05% or less, and optionally Mo : More than 0 and 1.0% or less, V: 0.01 to 0.30%, Zr: 0.01 to 0.30% and B: 0.0010 to 0.01%, further containing one or two or more of the stainless steel hot rolled steel made of Fe and other unavoidable impurities Cold annealing and annealing after annealing the plate, the annealing temperature after the cold rolling is a Ti-added ferritic stainless steel manufacturing method excellent in the controllability of the controllability in the range of 950 ℃ ~ 1000 ℃. The method of claim 1,
The cold rolling is a Ti-added ferritic stainless steel manufacturing method excellent in the leachability performed at least twice. The method of claim 2,
An annealing method of Ti-added ferritic stainless steel excellent in the lowering well which is performed after the cold rolling at least twice. The method of claim 3,
The stainless steel is a Ti-added ferritic stainless steel manufacturing method having excellent clarity of grain size of 20㎛ or less. The method of claim 4, wherein
The stainless steel is a method of manufacturing a Ti-added ferritic stainless steel excellent in the leachability of the ridging height 10㎛ or less after the tensile test By weight%, C: greater than 0 and 0.05% or less, Si: greater than 0 and 1.0% or less, Mn: greater than 0 and 1.0% or less, P: greater than 0 and 0.050% or less, S: greater than 0 and 0.020% or less, Ni: greater than 0 and 2.0% Or less, Cr: 15.0 to 25%, Cu: 1.0% or less, Nb: 0.1 to 0.5%, Ti: 0.01 to 0.3%, Al: more than 0 and less than 0.10%, N: more than 0 and 0.05% or less, and optionally Mo : More than 0 and 1.0% or less, V: 0.01 ~ 0.30%, Zr: 0.01 ~ 0.30% and B: 0.0010 ~ 0.0100%, one or more of them are contained, and the rest is composed of Fe and other unavoidable impurities, and the grain size Ti-containing ferritic stainless steel having excellent leachability of 20 µm or less. The method of claim 6,
After the annealing the stainless steel hot rolled sheet is subjected to cold rolling and annealing, the annealing temperature after the cold rolling is controlled by the range of 950 ℃ ~ 1000 ℃ Ti-added ferritic stainless steel excellent in leachability excellent. The method of claim 6,
The stainless steel is a Ti-added ferritic stainless steel excellent in the leachability of the ridging height 10㎛ or less after the tensile test. The method of claim 6,
The stainless steel is a Ti-added ferritic stainless steel excellent in the easing ability after cold rolling and annealing at least twice, respectively.

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