KR20120009548A - Gel-type antibacterial and deodorant composition comprising stablized chlorine dioxide - Google Patents

Gel-type antibacterial and deodorant composition comprising stablized chlorine dioxide Download PDF

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KR20120009548A
KR20120009548A KR1020100069371A KR20100069371A KR20120009548A KR 20120009548 A KR20120009548 A KR 20120009548A KR 1020100069371 A KR1020100069371 A KR 1020100069371A KR 20100069371 A KR20100069371 A KR 20100069371A KR 20120009548 A KR20120009548 A KR 20120009548A
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gel
chlorine dioxide
gelling agent
weight
deodorant composition
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KR1020100069371A
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Korean (ko)
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KR101137381B1 (en
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신동호
강영임
김홍선
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신동호
김홍선
강영임
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/01—Deodorant compositions
    • A61L9/012—Deodorant compositions characterised by being in a special form, e.g. gels, emulsions
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
    • A61L2209/20—Method-related aspects
    • A61L2209/21—Use of chemical compounds for treating air or the like

Abstract

PURPOSE: A gel-type antibacterial and deodorant composition is provided to facilitate the use thereof and to maintain sterilization effect for a long time. CONSTITUTION: A gel-type antibacterial and deodorant composition contains stable chlorine dioxide 20-55 weight%, an organic gelling agent 4.5-15 weight%, an inorganic gelling agent 3.5-8 weight%, and water 30-70 weight% is contain. The organic gelling agent is selected among acrylic acid polymer, maleic acid polymer, tragacanth gum, and cellulose.

Description

안정화 이산화염소를 함유한 겔상의 살균 및 소취제 조성물{GEL-TYPE ANTIBACTERIAL AND DEODORANT COMPOSITION COMPRISING STABLIZED CHLORINE DIOXIDE} Gel-containing bactericidal and deodorant composition containing stabilized chlorine dioxide {GEL-TYPE ANTIBACTERIAL AND DEODORANT COMPOSITION COMPRISING STABLIZED CHLORINE DIOXIDE}

본 발명은 안정화 이산화염소를 함유한 겔상의 살균 및 소취제 조성물에 관한 것이다.
The present invention relates to gelled bactericidal and deodorant compositions containing stabilized chlorine dioxide.

이산화염소 가스는 강력한 산화제이며, 그 산화 작용에 의해 멸균하거나 악취 성분을 분해하거나 하는 것이 알려져 있다. 그 때문에, 이산화염소는 살균제, 소취제 등으로 사용되고 있다. 이산화염소는 물에 대해 그 용적의 20배 용해하여 황갈색의 수용액으로 되므로, 취급의 용이성의 관점에서 수용액의 형태로 사용하는 것이 요망되지만, 이산화염소 수용액은 공기에 접촉하면 이산화염소 가스를 급격히 발생시킨다. 따라서, 이산화염소 가스를 과산화 탄산나트륨(Na2C2O6) 수용액에 용해시켜서 아염소산나트륨(NaClO2)을 주성분으로 하는 pH9로 유지한 수용액, 이른바 안정화 이산화염소 수용액으로 함으로써 안정성을 유지하면서 이산화염소 가스를 지속적으로 발생시키는 것이 제안되고 있다. Chlorine dioxide gas is a strong oxidizing agent, and it is known to sterilize or decompose bad smell components by its oxidizing action. Therefore, chlorine dioxide is used as a disinfectant, deodorant, and the like. Since chlorine dioxide dissolves 20 times of its volume in water and becomes an aqueous solution of yellowish brown, it is desired to use it in the form of an aqueous solution from the viewpoint of ease of handling. . Therefore, chlorine dioxide while maintaining stability by dissolving chlorine dioxide gas in an aqueous solution of sodium percarbonate (Na 2 C 2 O 6 ) and maintaining a pH 9 containing sodium chlorite (NaClO 2 ) as a main ingredient, or a stabilized chlorine dioxide solution. It is proposed to generate gas continuously.

또한, 안정화 이산화염소 수용액을 카라기난, 구아검 등의 겔화제로 겔화하여 겔상 조성물로 하는 것이 제안되어 왔고, 이러한 기술로는 일본 특개소 57-22102호에서 제안한 안정화 이산화염소 수용액을 한천 또는 젤라틴으로 젤화한 이산화염소 발생 조성물, 일본 특개소 61-181532호에서 제안한 안정화 이산화염소 수용액을 카르복실기가 함유된 고흡성 수지로 젤화한 이산화염소 발생 조성물, 일본 특개소 61-40803호에서 제안한 안정화 이산화염소 수용액을 고흡성 수지 및 접착제로 젤화한 이산화염소 발생 조성물, 그리고 일본 특개평 11-278808호에서 제안한 용존 이산화염소 가스, 아염소산 및 pH조정제로 구성된 순수이산화염소 수용액의 혼합물과 발포성 조성물을 부분 가교된 아크릴계 고흡습성 수지로 젤화한 이산화염소 조성물 및 발포 조성물이 있었다.In addition, it has been proposed to gel a stabilized chlorine dioxide aqueous solution with a gelling agent such as carrageenan or guar gum to obtain a gel-like composition. Chlorine dioxide generating composition, a stabilized chlorine dioxide aqueous solution proposed in Japanese Patent Application Laid-Open No. 61-181532 gelled with a super absorbent resin containing a carboxyl group, a stabilized chlorine dioxide aqueous solution proposed in Japanese Patent Application Laid-Open No. 61-40803 A chlorine dioxide generating composition gelled with a resin and an adhesive, and a mixture of a pure chlorine dioxide aqueous solution consisting of a dissolved chlorine dioxide gas, chlorine acid and a pH adjuster proposed in Japanese Patent Application Laid-Open No. 11-278808, and an acrylic superhygroscopic resin partially crosslinked with a foamable composition. Chlorine dioxide composition and foaming composition gelled with All.

그러나, 상기 제안된 조성물들은 이산화염소를 식물 또는 동물성 젤 화제에 적용 및 겔화 하기 위해서는 겔화제를 팽윤하기 위해 가열이 필요하고, 가열에 의해 안정화 이산화염소가 분해되어 첨가량에 비해 살균력과 소취력이 떨어지고, 가열에 의한 경제성이 떨어지는 문제점이 있다. 또한, 유기화합물 고흡습성 수지 겔화제를 적용하여 강력한 산화제인 이산화염소를 겔화하기 위해서는 겔화제에 함유된 이산화염소 함유량에 한계가 있는 문제점이 있다. 즉, 이산화염소 농도가 100,000ppm 이상에서는 상기 겔화제의 결합력이 약해져 보관 및 사용 중에 이수가 다량 발생하여 취급 안정에 문제가 있다.
However, the proposed compositions require heating to swell the gelling agent in order to apply and gel chlorine dioxide to a plant or animal gelling agent, and stabilizing chlorine dioxide is decomposed by heating, resulting in less sterilizing and deodorizing power compared to the added amount. There is a problem in that the economy is poor due to heating. In addition, there is a problem in that the chlorine dioxide content contained in the gelling agent is limited in order to gel the chlorine dioxide which is a strong oxidizing agent by applying the organic compound high hygroscopic resin gelling agent. That is, when the concentration of chlorine dioxide is 100,000ppm or more, the binding strength of the gelling agent is weakened, and a large amount of dihydrate is generated during storage and use, resulting in a problem in handling stability.

본 발명은 상기 종래기술의 문제점을 해결하고, 보다 사용이 편리하고 경제적이며, 고농도 안정화 이산화염소가 함유된 안정한 젤상의 조성물을 제공하는 것이다.
The present invention solves the problems of the prior art, and is more convenient and economical to provide a stable gel-like composition containing high concentration stabilized chlorine dioxide.

본 발명의 겔상의 살균 및 소취제 조성물은 이산화염소의 농도 5 ? 8 중량%인 안정화 이산화염소 20 ~ 55 중량%, 유기겔화제 4.5 ~ 15 중량%, 무기겔화제3.5 ~ 8 중량% 및 물 30 ~ 70 중량%를 함유한다.The bactericidal and deodorant compositions of the present invention have a concentration of 5? 8 to 20 wt% of stabilized chlorine dioxide, 4.5 to 15 wt% of an organic gelling agent, 3.5 to 8 wt% of an inorganic gelling agent and 30 to 70 wt% of water.

본 발명의 겔상의 살균 및 소취제 조성물에서 상기 안정화 이산화염소는 증기압이 20℃에서 1기압 이상, 증기 밀도가 25℃에서 2.3 이상, 비점이 10℃ 이상 및 안정도가 95.5% 이상인 것을 특징으로 한다.The stabilizing chlorine dioxide in the gel-like sterilizing and deodorant composition of the present invention is characterized in that the vapor pressure is at least 1 atm at 20 ° C, the vapor density is at least 2.3 at 25 ° C, the boiling point is at least 10 ° C, and the stability is at least 95.5%.

본 발명의 겔상의 살균 및 소취제 조성물에서 상기 유기겔화제는 아크릴산 폴리머, 말레인산 폴리머, 트라가칸스검 및 셀룰로오스 중에서 선택된 어느 하나의 유기겔화제인 것을 특징으로 한다.In the bactericidal and deodorant composition of the present invention, the organic gelling agent is any one of an organic gelling agent selected from acrylic acid polymer, maleic acid polymer, tragacanth gum and cellulose.

본 발명의 겔상의 살균 및 소취제 조성물에서 상기 무기겔화제는 제올라이트, 실리카, 석회석, 산화티타늄, 화이트 카본, 점토 및 칼슘카보네이트 중에서 선택된 어느 하나의 무기겔화제인 것을 특징으로 한다.In the germicidal and deodorant composition of the present invention, the inorganic gelling agent is any one of an inorganic gelling agent selected from zeolite, silica, limestone, titanium oxide, white carbon, clay and calcium carbonate.

본 발명의 겔상의 살균 및 소취제 조성물은 살리실산염, 주석산염, 벤조산염, 구연산염 및 에틸렌디아민 테트라 포스페이트 중에서 선택된 어느 하나 이상의 pH안정제를 0.05 ~ 1 중량% 더 함유하는 것을 특징으로 한다.
The bactericidal and deodorant composition of the present invention is characterized in that it further contains 0.05 to 1% by weight of at least one pH stabilizer selected from salicylate, tartarate, benzoate, citrate and ethylenediamine tetra phosphate.

본 발명은 고농도의 안정화 이산화염소를 함유하면서도 안정적인 겔을 형성하여 장기간 살균 및 소취 활성을 지속할 수 있고 사용이 편리한 겔상 살균 및 소취제 조성물을 제공한다.
The present invention provides a gel-type disinfectant and deodorant composition which can contain a high concentration of stabilized chlorine dioxide while forming a stable gel, which can sustain long-term sterilization and deodorizing activity and is easy to use.

본 발명의 겔상의 살균 및 소취제 조성물은 이산화염소의 농도 5 ? 8 중량%인 안정화 이산화염소 20 ~ 55 중량%, 유기겔화제 4.5 ~ 15 중량%, 무기겔화제 3.5 ~ 8 중량% 및 물 30 ~ 70 중량%를 함유한다.The bactericidal and deodorant compositions of the present invention have a concentration of 5? 8 to 20 wt% of stabilized chlorine dioxide, 4.5 to 15 wt% of an organic gelling agent, 3.5 to 8 wt% of an inorganic gelling agent and 30 to 70 wt% of water.

본 발명의 안정화 이산화염소는 이산화염소 농도가 5 ? 8 중량%, 보다 바람직하게는 6.5 ~ 7.5 중량%이고, 취급안정성을 위해 구토제를 첨가할 수 있다. 안정화 이산화염소에서 이산화염소의 농도가 5 중량% 미만인 경우에는 살균력과 소취력이 떨어지는 문제점이 있고, 8 중량%를 초과하는 경우 겔화제 소요량이 많아 경제성이 저하되고 또한 보관 안정성이 우수하지 않은 문제점이 있다.Stabilized chlorine dioxide of the present invention has a chlorine dioxide concentration of 5? 8% by weight, more preferably 6.5 to 7.5% by weight, and an adjuvant may be added for handling stability. If the concentration of chlorine dioxide in the stabilized chlorine dioxide is less than 5% by weight, there is a problem that the sterilizing power and deodorizing power is lowered, and when the concentration of chlorine is more than 8% by weight, the amount of gelling agent is required, so the economic efficiency is low and the storage stability is not excellent. have.

보다 바람직하게는 본 발명의 안정화 이산화염소는 증기압이 1기압 이상, 증기 밀도가 2.3 이상이고, 25℃에서 안정성이 95.0% 이상인 것이 바람직하다. More preferably, the stabilized chlorine dioxide of the present invention has a vapor pressure of at least 1 atm, a vapor density of at least 2.3, and a stability at 25 ° C of at least 95.0%.

안정화 이산화염소는 본 발명의 겔상의 살균 및 소취제 조성물에서 20 ~ 55 중량%, 바람직하게는 40 ~ 50 중량% 함유된다. 20 중량% 미만에서는 살균 및 소취력이 저하되고, 55 중량%를 초과하는 경우에는 유기겔화제의 결합이 약해져 이수가 다량 발생하고, 또한 염소 가스 냄새가 심하게 나는 문제점이 있다.Stabilized chlorine dioxide is contained 20 to 55% by weight, preferably 40 to 50% by weight in the gel-like sterilizing and deodorant composition of the present invention. If it is less than 20% by weight, the sterilization and deodorizing power is lowered, and if it exceeds 55% by weight, the organic gelling agent is weakly bound, so that a large amount of dihydrate is generated, and the chlorine gas smell is severe.

본 발명의 안정화 이산화염소는 차아염소산나트륨에 포도당과 구연산을 서서히 첨가 및 교반하여 제조할 수 있고, 일반적으로 pH 7.5 일 때 가장 안정하다.Stabilized chlorine dioxide of the present invention can be prepared by slowly adding and stirring glucose and citric acid to sodium hypochlorite, and is most stable at pH 7.5 in general.

본 발명에서는 안정화 이산화염소를 안정적으로 겔화시키기 위해 강력한 산화제인 이산화염소와 반응성이 낮은 고흡습성 유기겔화제를 사용하고, 특히 무기겔화제와 복합 사용하여야 한다. 유기겔화제와 무기겔화제의 비율은 중량비로 0.5 : 1 내지 2 : 1, 보다 바람직하게는 0.8 : 1 내지 1.6 : 1로서, 유기겔화제 비율이 상기 비율을 초과하여 사용될 경우 겔은 형성되지만 보관 중 유기겔화제의 결합력이 저하되어 다량의 이수가 발생하고, 무기 화합물의 비율이 상기 비율을 초과할 경우 사용 후 잔류량이 많고 경제적 가치가 떨어진다. In the present invention, in order to stably gel stabilized chlorine dioxide, a highly hygroscopic organic gelling agent having low reactivity with chlorine dioxide, which is a strong oxidizing agent, should be used in combination with an inorganic gelling agent. The ratio of the organogelling agent to the inorganic gelling agent is 0.5: 1 to 2: 1 by weight, more preferably 0.8: 1 to 1.6: 1, and when the organogelling agent ratio is used in excess of the above ratio, the gel is formed but stored. When the binding strength of the organic gelling agent is reduced, a large amount of water is generated, and when the ratio of the inorganic compound exceeds the above ratio, the residual amount after use is large and the economic value is lowered.

본 발명의 유기겔화제는 고흡습성의 것으로 g당 물흡수율이 10g 이상인 것, 바람직하게는 12 ~ 30g인 것이 사용된다. 유기겔화제의 입자크기는 2mm 이하, 바람직하게는 0.01 ~ 1 mm이다.The organic gelling agent of the present invention is a highly hygroscopic one having a water absorption of 10 g or more, preferably 12 to 30 g per g. The particle size of the organogelling agent is 2 mm or less, preferably 0.01 to 1 mm.

유기겔화제는 본 발명의 겔상의 살균 및 소취제 조성물에서 4.5 ~ 15 중량%, 바람직하게는 5 ~ 10 중량%, 더욱 바람직하게는 5.5 ~ 7 중량% 함유된다. 상기 하한치 미만에서는 겔이 형성되지 않고, 상한치를 초과하는 경우에는 경제적인 문제점과 장기 보관 시 젤의 결합력이 떨어져 이수가 발생하는 문제점이 있다.The organogelling agent is contained 4.5 to 15% by weight, preferably 5 to 10% by weight, more preferably 5.5 to 7% by weight in the gel-like sterilizing and deodorant composition of the present invention. If the gel is not formed below the lower limit, and if the upper limit is exceeded, there is an economic problem and a problem in that dilution occurs due to the low adhesive strength of the gel during long-term storage.

유기겔화제로는 아크릴산 폴리머, 말레인산 폴리머, 트라가칸스검 및 셀룰로오스 등이 사용될 수 있고, 이산화염소와 반응성이 낮은 아크릴산 폴리머가 바람직하다. As the organic gelling agent, an acrylic acid polymer, maleic acid polymer, tragacanth gum, cellulose and the like can be used, and an acrylic acid polymer having low reactivity with chlorine dioxide is preferable.

본 발명의 무기겔화제는 g당 물흡수율이 1g 이상인 것, 바람직하게는 1.2 ~ 4g인 것이 사용된다. 무기겔화제의 입자크기는 2mm 이하, 바람직하게는 0.01 ~ 1 mm이다.As the inorganic gelling agent of the present invention, one having a water absorption of 1 g or more per g, preferably one having 1.2 to 4 g is used. The particle size of the inorganic gelling agent is 2 mm or less, preferably 0.01 to 1 mm.

무기겔화제는 본 발명의 겔상의 살균 및 소취제 조성물에서 3.5 ~ 8 중량%, 바람직하게는 4 ~ 7 중량%, 더욱 바람직하게는 4.5 ~ 6 중량% 함유된다. 상기 하한치 미만에서는 겔이 잘 형성되지 않고, 상한치를 초과하는 경우에는 경제적인 문제점과 사용 후 잔류물이 남는 문제점이 있다.The inorganic gelling agent is contained 3.5 to 8% by weight, preferably 4 to 7% by weight, more preferably 4.5 to 6% by weight in the gel-like sterilizing and deodorant composition of the present invention. If the gel is not formed well below the lower limit, and if the upper limit is exceeded, there is an economic problem and a problem that remains after use.

무기겔화제로는 제올라이트, 실리카, 석회석, 산화티타늄, 화이트 카본, 점토 및 칼슘카보네이트 등이 사용될 수 있다.Zeolite, silica, limestone, titanium oxide, white carbon, clay and calcium carbonate may be used as the inorganic gelling agent.

또한 본 발명의 겔상의 살균 및 소취제 조성물에는 강력한 산화제인 이산화염소에 안정하고, 이산화염소의 분해를 촉진하는 금속 물질의 활동을 봉쇄하는 기능을 지니면서 제품의 pH를 일정하게 유지하는 완충 작용을 하는 pH안정제가 사용되는 것이 바람직하다. 전체 조성물에서 pH안정제의 함량은 0.05 ~ 1 중량%, 더욱 바람직하게는 0.1 ~ 0.5 중량%가 바람직하다.In addition, the gel-like bactericidal and deodorant composition of the present invention is stable to chlorine dioxide, which is a strong oxidizing agent, and has a function of blocking the activity of metal substances that promote the decomposition of chlorine dioxide while having a buffering function to maintain a constant pH of the product. It is preferred that pH stabilizers be used. The content of the pH stabilizer in the total composition is preferably 0.05 to 1% by weight, more preferably 0.1 to 0.5% by weight.

pH안정제로는 살리실산염, 주석산염, 벤조산염, 구연산염 및 에틸렌디아민 테트라 포스페이트 등이 사용될 수 있고, 특히 금속 이온 봉쇄력이 250mg/g 이상인 물질이 바람직하다.As the pH stabilizer, salicylate, tartarate, benzoate, citrate, ethylenediamine tetra phosphate, and the like may be used. Particularly, a material having a metal ion blocking power of 250 mg / g or more is preferable.

이하, 본 발명을 실시예, 비교예, 실험예를 통하여 보다 상세히 설명한다. Hereinafter, the present invention will be described in more detail through Examples, Comparative Examples, and Experimental Examples.

하기 실시예는 본 발명을 설명하기 위한 예시적인 것일 뿐 이에 의해 본 발명의 기술적 사상의 범위가 한정되는 것은 아니다.
The following examples are only illustrative for the purpose of illustrating the present invention, and the scope of the technical spirit of the present invention is not limited thereto.

제조예 1Preparation Example 1

평균입자크기 1.2 mm, 물흡수율 g당 15 g인 소듐 폴리아크릴레이트(JIBOSHI in China, PU-103 Golden yellow 비정형 비드) 4.5 중량%, 평균입자크기 1.2 mm, 물흡수율 g당 2 g인 마이크로 실리케이트(동양제철화학, ML389) 5 중량%를, 이산화염소를 5 ~ 10 중량% 함유하는 안정화 이산화염소 45 중량%와 물 45.5 중량%의 혼합액을 첨가하고, 하루 동안 보관하여 겔상 살균 및 소취제 조성물을 제조하였다. Sodium polyacrylate (JIBOSHI in China, PU-103 Golden yellow amorphous beads) with an average particle size of 1.2 mm and 15 g per g water absorption rate, 4.5% by weight, micro silicate with an average particle size of 1.2 mm and 2 g per g water absorption rate Dongyang Steel Chemical, ML389) 5% by weight, a mixture of 45% by weight of stabilized chlorine dioxide containing 4-10% by weight of chlorine dioxide and 45.5% by weight of water was added and stored for one day to prepare a gel sterilization and deodorant composition. .

이산화염소를 5 ~ 10 중량% 함유하는 안정화 이산화염소는 이산화염소 15 중량%를 함유하는 안정화 이산화염소(금성이엔씨, ClO2-15%)를 희석하여 사용하였다.
Stabilized chlorine dioxide containing 5 to 10% by weight of chlorine dioxide was used by diluting stabilizing chlorine dioxide (Venus NC, ClO2-15%) containing 15% by weight of chlorine dioxide.

실험예 1Experimental Example 1

제조예 1에서 제조된 이산화염소의 함유량이 다른 안정화 이산화염소를 함유하는 겔상의 살균 및 소취제 조성물의 살균력을 할로 테스트(halo test)법, 소취력을 검지관법, 겔의 상태는 이수량을 기준으로 비교하였다. 겔의 상태는 이수 발생이 0.1 중량% 미만인 매우 우수를 ○, 5 중량% 이하의 이수가 발생한 경우를 우수 △, 10 중량% 이상의 이수가 발생한 경우를 ×로 나타내었다.The halo test method, the deodorizing power detection tube method, and the state of the gel of the bactericidal and deodorant compositions of the gel phase containing stabilizing chlorine dioxide having different chlorine dioxide contents prepared in Preparation Example 1 Compared. The state of the gel was marked by x for the case where the water generation was less than 0.1% by weight, and the case where water was generated with less than 0.1% by weight, and the water with less than 5% by weight occurred.

이산화염소
함량(중량%)Chlorine Dioxide
Content (% by weight) 살균력Bactericidal power 소취력Deodorant 겔 상태Gel state 5.05.0 89.589.5 90.590.5 OO 6.56.5 98.598.5 97.897.8 OO 7.57.5 99.999.9 99.999.9 OO 8.58.5 99.999.9 99.999.9 △△ 10.010.0 99.999.9 99.999.9 XX

겔 상태는 이산화염소 8 중량% 이하 함유한 안정화 이산화염소를 사용한 조성물에서 매우 우수하였고, 살균력은 7.5 중량%이상에서 가장 우수하였다.
The gel state was very good in the composition using stabilized chlorine dioxide containing 8 wt% or less of chlorine dioxide, and the sterilizing power was the best at 7.5 wt% or more.

제조예 2Production Example 2

제조예 1의 이산화염소가 7.5 중량% 함유하는 안정화 이산화염소를 사용하되 안정화 이산화염소의 사용량을 30 ~ 70 중량%까지 변화시킨 후 겔 상태를 확인하였다. 유기겔화제 및 무기겔화제의 종류와 함량은 제조예 1과 동일하게 첨가하고 안정화 이산화염소의 함량에 따라 물의 함량을 변화시켜 겔상 살균 및 소취제 조성물을 제조하였다.
Using a stabilized chlorine dioxide containing 7.5% by weight of chlorine dioxide of Preparation Example 1 after changing the amount of the stabilized chlorine dioxide to 30 to 70% by weight was confirmed the gel state. The type and content of the organic gelling agent and the inorganic gelling agent were added in the same manner as in Preparation Example 1, and the gel content was prepared by changing the water content according to the content of stabilized chlorine dioxide.

실험예 2Experimental Example 2

제조예 2에서 제조된 안정화 이산화염소를 함유량이 다른 겔상의 살균 및 소취제 조성물의 겔 상태를 이수량을 기준으로 비교하였다. 겔의 상태는 이수 발생이 0.1 중량% 미만인 매우 우수를 ○, 5 중량% 이하의 이수가 발생한 경우를 우수 △, 10 중량% 이상의 이수가 발생한 경우를 ×로 나타내었다.The gel state of the bactericidal and deodorant compositions on gels having different stabilizing chlorine dioxide contents prepared in Preparation Example 2 was compared based on the amount of completion. The state of the gel was marked by x for the case where the water generation was less than 0.1% by weight, and the case where water was generated with less than 0.1% by weight, and the water with less than 5% by weight occurred.

안정화 이산화염소
함량(중량%)Stabilized Chlorine Dioxide
Content (% by weight) 3030 4040 4545 5050 5555 6060 7070 겔 상태Gel state OO OO OO OO △△ XX XX

이산화염소 함량이 50.0 중량 % 이하인 조성물에서 우수한 겔을 형성하였다.
Excellent gels were formed in compositions having a chlorine dioxide content of up to 50.0% by weight.

제조예 3Production Example 3

제조예 1의 이산화염소를 7.5 중량% 함유하는 안정화 이산화염소 45 중량%를 함유하고, 제조예 1에서 사용한 유기겔화제 및 무기겔화제를 사용하되 그 함량을 달리하여 첨가하고, 나머지를 물을 첨가하여 겔상 살균 및 소취제 조성물을 제조하였다.
45 wt% of stabilized chlorine dioxide containing 7.5 wt% of chlorine dioxide of Preparation Example 1, using the organic gelling agent and inorganic gelling agent used in Preparation Example 1, varying the content of the addition, and the remainder is added water Gel sterilization and deodorant compositions were prepared.

실험예 3Experimental Example 3

제조예 3에서 제조된 유기겔화제 및 무기겔화제의 함량을 달리한 겔상의 살균 및 소취제 조성물의 겔 상태를 이수량을 기준으로 비교하였다. 겔의 상태는 이수 발생이 0.1 중량% 미만인 매우 우수를 ○, 5 중량% 이하의 이수가 발생한 경우를 우수 △, 10 중량% 이상의 이수가 발생한 경우를 ×로 나타내었다.The gel state of the gel sterilizing and deodorant composition having different contents of the organic gelling agent and the inorganic gelling agent prepared in Preparation Example 3 was compared based on the amount of completion. The state of the gel was marked by x for the case where the water generation was less than 0.1% by weight, and the case where water was generated with less than 0.1% by weight, and the water with less than 5% by weight occurred.

유기화합물(중량%)Organic Compound (wt%) 3.03.0 3.53.5 4.54.5 6.06.0 무기화합물(중량%)Inorganic Compounds (wt%) 3.03.0 4.54.5 6.06.0 8.08.0 3.03.0 4.54.5 6.06.0 8.08.0 3.03.0 4.54.5 6.06.0 8.08.0 3.03.0 4.54.5 6.06.0 8.08.0 겔 상태Gel state XX XX XX △△ △△ △△ △△ △△ △△ OO OO OO OO OO OO OO

유기화합물(중량%)Organic Compound (wt%) 7.57.5 9.09.0 12.012.0 15.015.0 무기화합물(중량%)Inorganic Compounds (wt%) 3.03.0 4.54.5 6.06.0 8.08.0 3.03.0 4.54.5 6.06.0 8.08.0 3.03.0 4.54.5 6.06.0 8.08.0 3.03.0 4.54.5 6.06.0 8.08.0 겔 상태Gel state OO OO OO OO OO OO OO OO OO OO OO OO OO OO OO OO

이수가 없고, 겔의 분리되지 않는 젤화제의 함유량이 유기 화합물 젤화제 4.5중량% 이상과 무기화합물 젤화제 3.5중량% 이상에서 우수한 젤을 형성하였다.
The gel was excellent in the content of the gelling agent without the dilution, and the content of the gelling agent that was not separated from the gel was 4.5 wt% or more of the organic compound gelling agent and 3.5 wt% or more of the inorganic compound gelling agent.

제조예 4Preparation Example 4

제조예 1의 이산화염소를 7.5 중량% 함유하는 안정화 이산화염소 45 중량%를 함유하고, 제조예 1에서 사용한 유기겔화제 4.5 중량%, 무기겔화제 5 중량%를 사용하되, 추가로 pH안정제로 (구연산나트륨, 신원산업)를 함량을 달리하여 첨가하고, 나머지를 물을 첨가하여 겔상 살균 및 소취제 조성물을 제조하였다. pH안정제는 금속이온 봉쇄능력이 250 mg/g인 것이다.
45 wt% of stabilized chlorine dioxide containing 7.5 wt% of chlorine dioxide of Preparation Example 1, 4.5 wt% of the organic gelling agent used in Preparation Example 1, and 5 wt% of the inorganic gelling agent were used, and further, as a pH stabilizer ( Sodium citrate, Sinwon Industries) was added with varying contents, and the remainder was added water to prepare a gel sterilization and deodorant composition. The pH stabilizer is 250 mg / g of metal ion sequestration capacity.

실험예 4Experimental Example 4

제조예 4에서 pH안정제를 함량을 달리하여 첨가한 겔상의 살균 및 소취제 조성물의 겔 안정성을 비교하였다. 겔의 안정성은 50℃의 항온조에서 30일 보관 후 이산화염소의 농도를 측정하고 그 잔존 함량의 백분율로 나타내었다.In the preparation example 4, the gel stability of the gel-like bactericidal and deodorant composition to which the pH stabilizer was added with different contents was compared. The stability of the gel was measured by the concentration of chlorine dioxide after storage for 30 days in a thermostat at 50 ℃ and expressed as a percentage of the residual content.

pH안정제
함량(중량%)pH stabilizer
Content (% by weight) 00 0.050.05 0.100.10 0.150.15 0.300.30 0.500.50 1.001.00 1.501.50 안정성(%) stability(%) 88.488.4 95.595.5 95.895.8 96.496.4 96.296.2 95.595.5 93.893.8 90.690.6 pH(at 25℃)pH (at 25 ° C) 7.57.5 7.57.5 7.57.5 7.57.5 7.37.3 6.36.3 5.45.4 4.84.8

pH안정제가 첨가되지 않은 조성물에 비해 pH안정제를 첨가한 경우 겔의 안정성이 뛰어났고 pH안정제의 함량이 0.05 ~ 0.5 중량% 범위에서 특히 우수하였다.
When the pH stabilizer was added, the stability of the gel was excellent and the content of the pH stabilizer was particularly excellent in the range of 0.05 to 0.5 wt%.

Claims (5)

이산화염소의 농도 5 ? 8 중량%인 안정화 이산화염소 20 ~ 55 중량%, 유기겔화제 4.5 ~ 15 중량%, 무기겔화제 3.5 ~ 8 중량% 및 물 30 ~ 70 중량%를 함유하는 겔상의 살균 및 소취제 조성물.
Chlorine Dioxide Concentration 5? A disinfectant and deodorant composition on a gel comprising 8 to 20 wt% of stabilized chlorine dioxide, 4.5 to 15 wt% of an organic gelling agent, 3.5 to 8 wt% of an inorganic gelling agent and 30 to 70 wt% of water.
제 1 항에 있어서, 상기 안정화 이산화염소는 증기압이 20℃에서 1기압 이상, 증기 밀도가 25℃에서 2.3 이상, 비점이 10℃ 이상 및 안정도가 95.5% 이상인 것을 특징으로 하는 겔상의 살균 및 소취제 조성물.
The method of claim 1 wherein the stabilized chlorine dioxide is a gel sterilizing and deodorant composition, characterized in that the vapor pressure is 1 atm or more at 20 ℃, the vapor density is 2.3 or more at 25 ℃, the boiling point is at least 10 ℃ and the stability is at least 95.5%. .
제 1 항에 있어서, 상기 유기겔화제는 아크릴산 폴리머, 말레인산 폴리머, 트라가칸스검 및 셀룰로오스 중에서 선택된 어느 하나의 유기겔화제인 것을 특징으로 하는 겔상의 살균 및 소취제 조성물.
The gel-like bactericidal and deodorant composition according to claim 1, wherein the organogelling agent is any one of an organic gelling agent selected from acrylic acid polymer, maleic acid polymer, tragacanth gum and cellulose.
제 1 항에 있어서, 상기 무기겔화제는 제올라이트, 실리카, 석회석, 산화티타늄, 화이트 카본, 점토 및 칼슘카보네이트 중에서 선택된 어느 하나의 무기겔화제인 것을 특징으로 하는 겔상의 살균 및 소취제 조성물.
The gel-like bactericidal and deodorant composition according to claim 1, wherein the inorganic gelling agent is any one inorganic gelling agent selected from zeolite, silica, limestone, titanium oxide, white carbon, clay and calcium carbonate.
제 1 항에 있어서, 살리실산염, 주석산염, 벤조산염, 구연산염 및 에틸렌디아민 테트라 포스페이트 중에서 선택된 어느 하나 이상의 pH안정제를 0.05 ~ 1 중량% 더 함유하는 것을 특징으로 하는 겔상의 살균 및 소취제 조성물.The gel-like bactericidal and deodorant composition according to claim 1, further comprising 0.05 to 1% by weight of at least one pH stabilizer selected from salicylate, tartarate, benzoate, citrate, and ethylenediamine tetra phosphate.
KR1020100069371A 2010-07-19 2010-07-19 Gel-type antibacterial and deodorant composition comprising stablized chlorine dioxide KR101137381B1 (en)

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JP2017061395A (en) * 2015-09-24 2017-03-30 パスタライズ株式会社 Method for generating chlorine dioxide gas
KR20170102676A (en) * 2016-03-02 2017-09-12 주식회사 효림에코플라즈마 Sterilization Apparatus by Hydrogen-Peroxide Plasma
KR102149117B1 (en) * 2020-01-17 2020-08-27 진남섭 Chlorine Dioxide Fumigation Kit
KR102273189B1 (en) * 2020-02-13 2021-07-02 안성운 Method for removing mildew of air conditioners
KR20210142903A (en) * 2020-05-19 2021-11-26 유숙정 Chlorine dioxide diffusing gel
CN114158566A (en) * 2021-08-09 2022-03-11 山东大学 Single-component gel slow-release chlorine dioxide disinfectant and preparation method and application thereof

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