KR20110105060A - Detergent composition containing seed oil of turnip - Google Patents

Abstract

The present invention relates to a turnip detergent composition containing turnip seed oil, by using turnip seed oil obtained by sedimenting and ripening turnip seeds in jojoba oil, and filtering them, thereby replacing eco-friendly plant high-quality raw materials of imported aroma oil Lower prices have enabled them to secure economic feasibility, increase incomes from local agricultural products, and motivate them to start agricultural ventures.

Description

Detergent composition containing seed oil of Turnip

The present invention relates to a turnip detergent composition containing turnip seed oil.

Turnip in the country (Brassica rapa L) is cultivated as a vegetable in some specific areas such as Gimpo, and research on turnips is being conducted in these areas.

Turnips are known to have been introduced to Korea through China from countries such as Russia and Uzbekistan.

Unlike ordinary radishes, turnips have a unique scent, strong texture and sweet taste, and are used as foods such as kimchi, pickles, and takju.It contains minerals and vitamins, amino acids such as tryptophan and lysine, and isothiocyanate Anticancer ingredients such as sulfoaphane are known, and are known to have an effect of preventing esophageal cancer, liver cancer, lung cancer, colon cancer, and the like.

Korean Patent No. 0718163 (a method for separating turnip concentrates that inhibit cirrhosis from turnips) discloses that turnip concentrates have an inhibitory effect on cirrhosis, and Korean Patent No. 010818 (prevention of diabetes containing turnip extracts and Therapeutic compositions) turnip extract is known to treat and prevent diabetes. In addition, Korean Patent No. 0514111 discloses a mass harvesting method of turnip seed.

On the other hand, turnip seeds contain a large amount of oil and are known to have the function of softening the skin even in the Joseon Dynasty. However, there is little research on turnips even in the origin, and research on turnip seeds is rarely conducted. to be.

Therefore, if industrial potential is evaluated by investigating and analyzing the availability of turnip seeds, we believe that there is a great possibility of industrialization, technologicalization and economic creation through technology marketing.

Therefore, the present invention intends to develop high value-added processed products by actively utilizing the seed oil of turnip which is a special product of Gimpo.

Accordingly, an object of the present invention is to preserve agricultural income and create new demand by utilizing rural abundant resources by developing functional processed products using turnip seeds, a special product of Gimpo, for the realization of environmental conservation agriculture, which is a 21st century life industry.

Accordingly, an object of the present invention is to provide a high value-added functional processed products such as soap and detergent using turnip seed oil through the development of processing technology for turnip seeds.

In order to achieve the above object, the present invention provides a turnip detergent composition containing a turnip seed oil as an active ingredient in a natural detergent composition.

Hereinafter, the present invention will be described in detail.

At this time, if there is no other definition in the technical terms and scientific terms used, it has a meaning commonly understood by those of ordinary skill in the art.

Repeated descriptions of the same technical constitution and operation as those of the conventional art will be omitted.

Detergent composition of the present invention refers to a liquid soap for washing face and soap, dishwashing and kitchen containers in general.

The present invention is to develop functional processed products such as soap and detergent using oil derived from turnip seeds, so that agricultural income can be increased by utilizing rural resources.

The turnip detergent composition of the present invention preferably contains 5-15% (v / v) of turnip seed oil based on 100% by volume of the total detergent composition. It is lower than 5% (v / v), so that the properties of the turnip seed oil are halved, which is not suitable for the purpose of the present invention, and if it exceeds 15% (v / v), other essential soap components are sufficient. Since it cannot be used, it is preferable to use it within the use range mentioned above. However, the content of turnip seed oil used in the turnip detergent composition of the present invention is not limited within the above-mentioned range of use, and if it meets the object of the present invention, the upper limit of turnip seed oil described above is within the limit of maintaining the characteristics of the detergent. The above can also be used.

In the present invention, turnip seed oil contains abundant fatty acids such as oleic acid, linoleic acid, ecoenoic acid and tannins together with tannins, and these fatty acids have excellent oxidation stability and good skin feel. It has excellent skin affinity and is suitable for use in detergent compositions. In particular, it is known that oleic acid is excellent in moisturizing effect and linoleic acid is excellent in skin moisturizing effect, and it is therefore very suitable to use turnip seed oil as a functional ingredient in the detergent composition of the present invention.

In addition, the present invention has developed a novel milking method that is simple and efficient so that turnip seeds can be used in functional products.

However, the turnip seed oil used in the present invention can be used as the turnip seed oil obtained by a method other than the milking method disclosed in the present invention as long as it meets the object of the present invention.

The preferred milking process of turnip seed oil according to the present invention is as follows.

(1) Jojoba oil precipitation

Pour jojoba oil into turnip seeds in a container, age for 30-90 days, and filter to obtain oil.

At this time, in the present invention, it is preferable to precipitate and milk 30-60% (w / v) turnip seeds based on 100 ml of jojoba oil. If less than 30% of turnip seeds is used, the content of beneficial fatty acids oleic acid and linoleic acid in the turnip seed oil will be lowered, and the properties of jojoba oil will be stronger. Since efficiency falls, it is preferable to use it within the use range mentioned above.

In the present invention, if the milking period of turnip seeds is less than 30 days, the active ingredient of turnip seeds is not sufficiently leached, and if it exceeds 90 days, no more active ingredients are leached. desirable.

In addition, in order to suppress the rancidity of fatty acids during the aging period, it is preferable to avoid direct sunlight and leaching in a cool place, specifically, it is preferably carried out at 5 ~ 20 ℃.

In addition, since the structure of jojoba oil is similar to the sebum structure of the skin, it is easy to penetrate the skin, and it is colorless, odorless, and insensitive, and it is known that there is no big trouble and anti-inflammatory effect even when used on all skin. It is preferable to use jojoba oil which provides a synergistic effect as a leaching solvent for turnip seeds.

(2) compression extraction method

Hot-dried seedlings are hot-air-dried and roasted at 150 ° C. for 15 minutes, and the oil is extracted with a press.

(3) Organic Solvent Extraction

Dry the turnip seeds in hot air, fry at 150 ° C. for 15 minutes, go to a mixer, extract the oil using hexane, and centrifuge to extract and concentrate the supernatant under reduced pressure.

(4) Supercritical Fluid Extraction Method

 Dry the turnip seeds in hot air, fry at 150 ° C. for 15 minutes, go to a mixer, and extract oil using a supercritical fluid extractor.

In addition to turnip seed oil, the turnip detergent composition of the present invention includes materials commonly used for natural soaps, liquid soaps, kitchen detergents, shampoo compositions, and the like. For example, it refers to various additives such as functional oils, humectants, preservatives (preservatives), pigments, and flavorings based on fatty acids of fatty acids and fatty acid salts of alkali metal salts (sodium salts, potassium salts, etc.). You can choose oil, glycerin, moisturizer, essence oil or fragrance oil according to your preference, and liquid soap can choose pure soap powder, purified water, etc., kitchen detergent and shampoo The composition may be selected from additives such as surfactants, thickeners, thickeners, preservatives, fungicides, chelating agents, softening agents and pH adjusting agents.

When the detergent composition of the present invention is a liquid, it may be prepared in the form of a liquid, aerosol and spray formulations.

At this time, in the present invention in order to further enhance the functionality of the turnip detergent composition 100% by volume of the detergent composition Cypress (Cypress), Grapefruit (Grapefruit), Jupiter (Jupiter) and lemongrass (Lemongrass) selected from the group consisting of It is preferable to further contain 2-5% (v / v).

Cypress is generally known for antiseptic, antispasmodic, deodorant and tonic effects, grapefruit for disinfection and tonic effects, jupiter for disinfection, antispasmodic, astringent and lemongrass. It is known to have analgesic, astringent, bactericidal, fungal, tonic effects, and can be included in the turnip detergent composition of the present invention to provide a positive functional effect on the skin or washing effect.

The present invention develops a milking method of turnip seeds that can be milked simply and efficiently and demonstrates the utilization value of turnip seed oil, which has not been used in the past, and can replace high-quality raw materials of eco-friendly plants to lower the high price of imported aroma oil. It is to secure economic feasibility, to increase the income of local agricultural products, and to provide motivation for starting agricultural ventures.

1 is a graph showing the moisturizing power of turnip seed oil according to an embodiment of the present invention.
Figure 2 is a questionnaire using a turnip cleaning composition prepared in one embodiment of the present invention, the questionnaire reviews.

Hereinafter, the present invention will be described in more detail with reference to specific examples. However, the present invention is not limited to the following examples, and it will be apparent to those skilled in the art that various changes or modifications can be made within the spirit and scope of the present invention.

[ Example ]

1. Turnip Seed oil  Milking

Test Material

Spring Vegetable Turnip Seed, Autumn Vegetable Turnip Seed

end. turnip Seed oil Jojoba oil  Precipitation method infuge method )

<Material>

500 g of turnip seeds, 1,000 ml of jojoba oil, black shading container, beaker, gauge, strainer

<Manufacturing Method>

500 g of turnip seeds were placed in a shading vessel, 1,000 ml of jojoba oil was slowly poured into a shading vessel, aged for 30 days in a cool place, and the oil was filtered using a strainer to obtain a turnip seed oil according to the present invention.

I. Compression extraction

The turnip seeds were hot-air dried and roasted at 150 ° C. for 15 minutes, after which the oil was extracted by a press to obtain turnip seed oil. At this time, the fall rape turnip milking yielded about 12.5% by milking 250 ml of seed oil in 2 kg of seed, and the spring rape turnip milking yielded about 11.7% by milking 250 ml of seed oil in 2.9 kg of seed.

All. Organic Solvent Extraction

Dry the turnip seeds with hot air, fry at 150 ° C for 15 minutes, grind with a mixer, separate into 20 mesh sieves, add hexane 20 times the amount of turnip seeds, extract the oil at room temperature for 6 hours, filter with gauze, and centrifuge. The supernatant was concentrated under reduced pressure to obtain turnip seed oil from which hexane was completely removed. At this time, the fall cultivated turnip seeds milked 60 ml of seed oil in 170 g of seed and yielded about 35%, and the spring rapeseed seed milked 67 ml of seed oil in 170 g of seed to yield about 39%. Indicated.

la. Supercritical Fluid Extraction

The turnip seeds were hot-air dried, roasted at 150 ° C. for 15 minutes, ground in a mixer, separated into 20 mesh sieves, and hot-air dried at 40 ° C., and then extracted with an oil using a supercritical fluid extractor to obtain turnip seed oil. At this time, the fall rapeseed seed milk yielded about 3.3% by milking 50 ml of seed oil in 1.5 kg of seed, and the spring rapeseed seed milked 45 ml of seed oil in 1.2 kg of seed, yielding about 3.7%. Indicated.

2. Turnip Seed oil  Manufacture of natural detergent

<Material>

Palm oil, coconut, jojoba oil, essence oil (grayfruit: juniper berry: lemongrass: cypress = 1: 1: 1: 1), potassium hydroxide, 5,000 ml beaker, measuring instrument, hand blender, pipette, eyedropper , Hot plate

<Method>

Prepare a base of oil by placing a 5,000 ml stainless beaker on the weighing machine and setting it to zero, immersing the beer beaker with 750 g of palm oil and 750 g of coconut oil, then completely dissolving the mixture on a hot plate until the temperature of the mixture reaches 70 ° C. It was.

Add 397 g of quantitative potassium hydroxide to a beaker containing 1,050 ml of purified water in small portions and stir with a glass rod to prevent suddenly high heat generation by chemical action and dissolve completely, then 70 ° C. in cold water flowing the beaker containing the potassium hydroxide solution. At the temperature, a potassium hydroxide solution was prepared.

Then, the potassium hydroxide solution was added to a 5,000 ml stainless steel beaker containing the oil base and mixed uniformly with a hand blender. 3% (v / v) of essential oil (3% of the total volume) and 10% (v / v) After the turnip seed oil of) was added, the mixture was mixed evenly with a blender until the mixture was rounded and completely combined.

The mixture was added 1.5 times the amount of purified water to the mixture, mixed with a blender, and then an appropriate amount was dispensed into a soap container (bubble container) to prepare a liquid turnip natural detergent according to the present invention.

[ Experimental Example ]

1. Turnip Seed oil  Substance analysis

end. GC Of MSD Turnips with Turnip Free  Fatty Acid Analysis

Fatty acids of turnip seed oil were analyzed using GC / MSD. Each turnip seed oil sample obtained in Example 1 was extracted with dichloromethane, concentrated with nitrogen, filtered using a cellulose acetate 0.45um filter, and then 0.8 ml per minute using helium. Analysis at a rate of / min.

The results are shown in Tables 1 and 2 below.

I. Turnip seed GC Of MSD  Anticancer component quantitative analysis

Dimethyl trisulfide, valero-nitrile, 3-indoleacetonitrile, and 3-methylindole for turnip seed oil were prepared using GC / MSD. Quantitative analysis. Each turnip seed oil sample obtained in Example 1 was extracted with dichloromethane, concentrated with nitrogen, filtered using a cellulose acetate 0.45 um filter, and analyzed at a rate of 0.8 ml / min per minute using helium.

The results are shown in Table 3 below.

All. Jojoba  Precipitated in oil and filtered Turnip seed  Functional substance analysis

C-1. Fatty Acid and Mineral Analysis

The analysis was performed in the same manner as in Experimental Example 1-A. However, in order to compare with the fatty acid contained in jojoba oil, the fatty acid composition and content contained in the jojoba oil well-known by the oil and fat chemical manual (Japan Oil and Chemical Society) were shown.

The results are shown in Table 4 below.

From the above results, jojoba oil (later in literature) and turnip seed oil compared the fatty acid composition, jojoba oil had the highest eicosenoic acid (Eicosenoic acid), turnip seed oil was the highest in oleic acid (Oleic acid). This confirmed that the active ingredient of turnip seed was extracted by jojoba oil. The fatty acid composition of turnip seed oil was higher in order of oleic acid, linoleic acid, and eicosenoic acid. Oleic acid is a fatty acid found in olives that lowers LDL and increases HDL to help cardiovascular disease. Linoleic acid is known to be effective for atherosclerosis and hypertension.

In addition, the turnip seed oil obtained by the jojoba oil precipitation method according to the invention was confirmed that the erucic acid (Eruic acid) is less toxic than the turnip seed oil extracted by other extraction methods.

As a result, turnip seed oil extracted using jojoba oil extracts many beneficial fatty acids and does not extract harmful fatty acids, so it can be confirmed that it is very efficient and simple milking method. Jojoba oil itself is an advanced functional ingredient in detergent composition. It has been used, turnip detergent composition according to the present invention is considered to be very beneficial as a skin or environmentally friendly component.

Also, in turnip seed oil, the highest content of calcium (Ca) in minerals was 33.53 mg / L, followed by sodium (Na) 4.59 mg / L, potassium (K) 3.01 mg / L, and copper (Cu) 0.08 mg / L but no heavy metals and vitamins were detected (not shown).

C-2. Whitening activity probe

Filtered turnip seed oil was dissolved in 70% ethanol at 1 g / 10 ml, and extracted at 70 ° C. for 1 hour, and then the analyzed sample was extracted (20,000 μg / ml) and 1/2 diluted (10,000 μg / ml). , 1/4 dilution (5,000 μg / ml), 1/8 dilution (2,500 μg / ml) and 1/16 dilution (1,250 μg / ml).

① Tyrosinase ( Tyrosinase Inhibitory activity

120 μl of 0.1N phosphate buffer solution, 40 μl of L-DOPA and 20 μl of sample were mixed, and 40 μl of tyrosinase was added and reacted at 25 ° C. for 10 minutes, and then the absorbance was measured at 475 nm. The tyrosinase inhibitory effect of seed oil was measured. In this case, kojic acid (Kojic acid), which is known to have excellent whitening effect, was used as a positive control.

The results are shown in Table 5 below.

② Tannins  content

0.5 ml of sample, 0.5 ml of 95% ethanol, 2.5 ml of distilled water and 0.5 ml of 5% sodium carbonate solution and 0.25 ml of Foln- Ciocalteu reagent were mixed vigorously and reacted for 60 minutes, and then absorbance was measured at 725 nm to analyze the content of tannin. It was.

The results are shown in Table 6 below.

As a result, as a result of extracting turnip seed oil with 70% ethanol and measuring the physiological activity, there was no antioxidant activity, and the whitening activity was about 24% inhibitory activity at 20,000 ㎍ / ml and the tannin content related to the whitening efficacy As a result, it was confirmed that it contained about 191 ug per gram of turnip seed oil.

2. Turnip seed  Natural detergent Moisturizing  And quality inspection

end. Moisturizing  Research

As a control group, general detergent and natural ingredient detergent were used, and the test method was to measure the moisture on the back of the hand before the experiment, apply each sample for 1 minute and wipe off, and after 1 minute, 2 minutes, 5 minutes, 10 minutes, 15 minutes, 20 minutes, The moisture content was measured and compared with the water on the back of the first hand, and the difference was used to indicate the moisturizing power after using the detergent.

The results are shown in Table 7 and FIG. 1.

As such, it was found that the turnip seed oil of the present invention also has a moisturizing power, and it was confirmed that the moisturizing power was superior to the general detergent until the initial 2 minutes. Therefore, when the detergent composition is prepared by using additives such as moisturizing power in addition to turnip seed oil in the detergent composition together with turnip seed oil, it may be possible to produce a detergent composition having improved moisturizing power more than conventional general detergents or natural ingredient detergents.

I. Quality test score

Prototypes of natural detergents were analyzed by the Korea Testing and Research Institute based on the quality of liquid kitchen soap, and the quality and stability as detergents were confirmed.

As a result, the quality as a detergent could be confirmed as shown in Table 8 below.

All. Natural detergent prototype use survey

Through a panel of 122 people using the prototypes prepared according to the present embodiment, a questionnaire was used to determine the effect of the turnip detergent composition of the present invention.

<Survey target>

Participants: A total of 122 men, 20 men and 102 women

Regional Distribution: 78 Seoul (63.9%), Gyeonggi 42 (34.4%), Chungcheong 2 (1.6%)

Age breakdown: 26 in 20s (21.3%), 42 in 30s (34.4%), 40 in 40s (32.7%),

                14 people over 50 (11.4%)

<Survey Form>

Grade: Very satisfied (5 points), Satisfied (4 points), Normal (3 points), Not satisfied (2 points), Not very satisfied (1 point)

Contents: Scientific aspects of the prototype (Efficacy, Functionality, Non-irritating, Allergy-free), Emotional aspect (feeling, skin compatibility, odor-uniqueness, odor-persistence, odor-personal taste, container-convenience, container- 16 questions in total: palatability, container-economics, container-fashionable), and product evaluation (degree of washing power, evaluation of bowl condition after cleaning) (see FIG. 2).

The results are shown in Table 9 below.

The results of the analysis are as follows.

① Scientific aspect

88% were satisfied in efficacy, 87% were satisfied in functionality, which is an indicator of safety, and 96% were satisfied in non-irritant. In addition, allergy, an indicator of stability, was 92%.

② emotional side

The texture is satisfactory. 84% and 82% of skin suitability are satisfied. The odor is differentiated from commercial products by adding aroma oil to turnip seed oil, which is satisfactory in uniqueness and durability. Accounted for, and satisfied with personal preferences. The container used a foam container, which scored over 70% in terms of ease of use, uniqueness and epidemic, and more than 50% in palatability and economy.

None

Claims (7)

In the natural detergent composition,
Turnip detergent composition containing turnip seed oil. The method of claim 1,
The turnip seed oil is obtained by sedimenting and ripening turnip seeds in jojoba oil, and then filtering them. The method of claim 2,
Turnip detergent composition characterized in that it is obtained by precipitating 30-60% (w / v) turnip seeds on a 100 ml volume of jojoba oil, ripening for 30-90 days, and then filtering them. The method of claim 1,
The turnip seed oil is hot-air dried hot-dried seeds and roasted at 150 ℃ for 15 minutes, and then went to the mixer, extracting the oil using hexane (hexane) and centrifuged to obtain a turnip detergent composition, characterized in that obtained by concentrated under reduced pressure. The method of claim 1,
The turnip seed oil is a turnip detergent composition, characterized in that obtained by hot air drying the turnip seed and roasted for 15 minutes at 150 ℃ extracted oil by a press. The method of claim 1,
Turnip detergent composition, characterized in that it further comprises 2 ~ 5% (v / v) of the essence oil selected from the group consisting of cypress, grapefruit, jupiter and lemongrass on a basis of 100% by volume detergent composition. The method according to any one of claims 1 to 4,
Turnip seed oil is based on 100% by volume of the detergent composition, turnip detergent composition, characterized in that 5 to 15% (v / v).

Images