KR20110098675A - Artificial leather - Google Patents
Artificial leather Download PDFInfo
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- KR20110098675A KR20110098675A KR1020110017147A KR20110017147A KR20110098675A KR 20110098675 A KR20110098675 A KR 20110098675A KR 1020110017147 A KR1020110017147 A KR 1020110017147A KR 20110017147 A KR20110017147 A KR 20110017147A KR 20110098675 A KR20110098675 A KR 20110098675A
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- artificial leather
- flame retardant
- retardant composition
- preliminary
- composition layer
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/16—Processes for the non-uniform application of treating agents, e.g. one-sided treatment; Differential treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0004—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using ultra-fine two-component fibres, e.g. island/sea, or ultra-fine one component fibres (< 1 denier)
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
- D06N7/0092—Non-continuous polymer coating on the fibrous substrate, e.g. plastic dots on fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/06—Properties of the materials having thermal properties
- D06N2209/067—Flame resistant, fire resistant
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/12—Permeability or impermeability properties
- D06N2209/121—Permeability to gases, adsorption
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/26—Vehicles, transportation
- D06N2211/263—Cars
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/28—Artificial leather
Abstract
The present invention relates to an artificial leather that has a flame retardancy of the level required by the industry by applying the flame retardant composition on the preliminary artificial leather, and at the same time, the soft touch of the ultrafine fibers is not degraded and the breathability can be greatly improved. Artificial leather of the present invention, a pre-artificial leather comprising a nonwoven fabric made of ultrafine fibers and an elastic polymer resin impregnated in the nonwoven fabric; And a flame retardant composition layer formed by partially applying a flame retardant composition on the preliminary artificial leather at an area ratio of 60 to 90% of the total surface area of the preliminary artificial leather.
Description
The present invention relates to artificial leather, and more particularly to artificial leather comprising a flame retardant composition layer.
Artificial leather is made by impregnating a polymer elastic body in a nonwoven fabric formed by interweaving microfibers three-dimensionally, and has a soft texture and a unique appearance similar to that of natural leather, thereby making shoes, clothing, gloves, sundries, furniture, and automobiles. It is widely used in various fields such as interior materials.
Such artificial leathers are required to have higher functionality in terms of flexibility, surface quality, wear resistance, light resistance, or elongation, depending on the intended use, and various properties may be required at the same time.
For example, when artificial leather is applied to the skin material attached to a car seat among automotive interior materials, as the eye level of the consumer increases, quality characteristics of the surface, specifically, excellent appearance, breathability, and tactile properties are required, There is a difficulty in satisfying the flame retardancy specified in the statutory items among the physical properties.
In other words, in order to impart flame retardancy required by the industry to artificial leather, a large amount of flame retardant must be used. Thus, when a large amount of flame retardant is treated to artificial leather, there is a problem that the touch of the artificial leather becomes hard and the breathability is lowered.
Therefore, the present invention relates to artificial leather that can prevent problems caused by the above limitations and disadvantages of the related art.
That is, the present invention is to provide an artificial leather that can be greatly improved breathability without deteriorating the soft touch of the ultrafine fibers and at the same time by the application of the flame retardant composition on the pre-artificial leather in part The purpose.
In order to achieve the above object, the present invention is a preliminary artificial leather including a nonwoven fabric made of ultrafine fibers and an elastic polymer resin impregnated in the nonwoven fabric; And a flame retardant composition layer formed by partially applying a flame retardant composition on the preliminary artificial leather at an area ratio of 60 to 90% of the total surface area of the preliminary artificial leather.
The present invention has the following effects.
First, the artificial leather according to the present invention has an effect of improving the economics as well as having a level of flame retardancy required in the industry by having a flame retardant composition layer partially applied in an optimum form and content.
Second, the artificial leather according to the present invention may have excellent touch and breathability as the flame retardant composition layer is partially applied.
Such artificial leather can be used for automobile seats that require excellent flame retardancy and appearance and feel.
1 is a plan view of an artificial leather according to an embodiment of the present invention.
2 is a cross-sectional view of the artificial leather along the AA 'line of FIG.
3 to 5 are plan views of artificial leather according to another embodiment of the present invention.
It will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the spirit and scope of the invention. Therefore, the present invention encompasses all changes and modifications that come within the scope of the invention as defined in the appended claims and equivalents thereof.
As used herein, the term 'preliminary artificial leather' refers to artificial leather including a nonwoven fabric and an elastic polymer resin impregnated on the nonwoven fabric, and means an artificial leather immediately before a flame retardant composition is added.
Hereinafter, embodiments of the artificial leather of the present invention will be described in detail with reference to the accompanying drawings.
1 is a plan view of an artificial leather according to an embodiment of the present invention.
2 is a cross-sectional view of the artificial leather along the AA ′ line of FIG. 1.
1 and 2, the artificial leather of the present invention includes a preliminary
In addition, since the flame retardant composition is only partially applied on the preliminary
On the other hand, when the flame-retardant composition is completely coated on the preliminary
The artificial leather of the present invention has a flame
The flame
For example, as shown in FIG. 5, the flame
However, when one
On the contrary, as illustrated in FIGS. 1, 3 and 4, respectively, the artificial leather of the present invention has a plurality of discontinuously distributed corresponding to the uncoated regions of the preliminary
The flame
When the flame retardancy test is performed on an artificial leather having a plurality of
Therefore, when the same amount of flame retardant composition is applied to the preliminary
The plurality of
Each of the plurality of
On the other hand, in order to improve both flame retardancy and breathability, the flame
In order to produce an artificial leather having a horizontal combustion rate of 100 mm / min or less flame retardancy and a breathability of 20 to 50 L / min / 100 cm 2, the upper thickness a is the thickness c of the preliminary
The penetration depth (b) may be preferably in the range of 5 to 50% of the thickness (c) of the preliminary artificial leather (30). If the ratio of the penetration depth (b) is less than 5%, the adhesive strength is lowered and durability is reduced, while if the ratio of the penetration depth (b) exceeds 50%, the touch of artificial leather may be hard.
The top thickness (a) and depth of penetration (b) of the flame
The flame retardant composition may comprise a flame retardant and a binder. As the flame retardant, it may be preferable to use a phosphorus flame retardant rather than a halogen flame retardant which is a carcinogen. The binder is for improving the adhesive force, and various kinds of binders may be used as the binder. In particular, since the urethane-based binder including silicon is excellent in heat resistance, the decomposition of silicon is suppressed during combustion and crosslinking with urethane can be formed, thereby improving the flame resistance of artificial leather. On the other hand, the urethane-based binder not only has a strong adhesive strength with the preliminary
The flame retardant composition may include various additives in addition to the flame retardant and binder described above. As the additive, an antioxidant, an antistatic agent, an ultraviolet absorber, a hydrolysis inhibitor, a softening agent, or the like may be used.
The preliminary
First, a sea island type fiber is manufactured through a composite spinning process. The island-in-the-sea fiber component may be nylon or polyester, and the polyester may be polyethylene terephthalate (PET), polytrimethylene terephthalate (PTT), or polybutylene terephthalate (PBT).
Subsequently, the island-in-the-sea fibers are cut into short fibers such as staple fibers through a cutting process. The island-in-the-sea fibers in the form of short fibers undergo a carding process and a cross lapping process to form a web. Alternatively, a spun bonding process may be used to form a web directly without a cutting process using island-in-the-sea fibers in the form of long fibers.
The plurality of webs thus formed are bonded to each other using a needle punch or a water jet punch to complete a nonwoven fabric.
Subsequently, the preliminary
The process of impregnating the elastic polymer resin in the nonwoven fabric may be performed by a coating process or a dipping process. Among these, a simple and easy dipping process will be described below.
First, a polyurethane resin or a silicone resin may be used as the elastic polymer resin. As the polyurethane resin, polycarbonate diol resin, polyester diol resin or polyetherdiol resin alone or a mixture thereof may be used.
The impregnation process of the elastic polymer resin may be completed by sequentially performing a step of immersing the nonwoven fabric in the composition including the elastic polymer resin, a solidification process of solidifying the elastic polymer resin in a coagulation bath, and a process of washing with water in a washing tank. . The coagulation solution contained in the coagulation bath may be a mixed solution containing water and dimethylformamide.
In more detail, the ultrafine process is performed by using an alkaline solution such as an aqueous caustic soda solution to elute and remove the sea component from the composite fiber composed of the island component and the sea component. As the sea component is removed, the remaining island components form microfibers. The microfibers produced by the micronization process may have a fineness of 0.3 denier or less in terms of touch.
In the above, the method for manufacturing the preliminary
Artificial leather as described above has excellent flame retardancy and excellent breathability at the same time. That is, the horizontal combustion speed of artificial leather measured in accordance with the automotive interior combustion test regulation of FMVSS.No.302 is 100 mm / min or less, and at the same time, the breathability of artificial leather is in the range of 20 to 50 L / min / 100 cm2. Can be.
The horizontal combustion speed is a method of measuring flame retardancy mainly when artificial leather is used as interior materials such as automobile seats. If the horizontal burning rate of artificial leather exceeds 100 mm / min, it may be difficult to use as interior materials for automobiles because it may not have the level of flame retardancy required by the industry.
The breathability of the artificial leather indicates the degree of passage of air into and out of the car seat when the artificial leather is used in the car seat. As the breathability increases, the driver feels comfortable, while the breathability decreases, the driver feels uncomfortable. However, if the breathability is excessively increased, as the content of the flame
Hereinafter, the present invention will be described in detail through Examples and Comparative Examples. The present invention is only to aid the understanding by the following examples, and is not intended to limit the protection scope of the claims.
Example 1
A molten solution of a sea component is prepared by melting a copolymerized polyester obtained by copolymerizing 5 mol% of a polyester unit containing a metal sulfonate in a polyethylene terephthalate, which is a main component, and melting polyethylene terephthalate (PET). Prepare a melt of the components. Thereafter, using a 50% by weight of the molten solution of the sea component and 50% by weight of the melt of the island component composite spinning to obtain a filament consisting of three denier single yarn and 16 island components in cross section, the filament at a draw ratio of 3.5 After stretching to prepare a island-in-the-sea filament-shaped fibers. Thereafter, the crimp process was performed to have a crimp number of 15 pieces / inch using the island-in-the-sea fibers, heat-set at 130 ° C., and cut into 51 mm to prepare an island-in-the-sea-type fiber in staple form.
Then, after forming the web through the carding process and the cross-lapping process of the island-in-the-sea fibers in the form of staples, the webs were subjected to a needle punch process to prepare a nonwoven fabric.
Thereafter, the nonwoven fabric was padded with an aqueous polyvinyl alcohol solution having a concentration of 5% by weight, followed by drying. The dried nonwoven fabric was obtained by dissolving the polyurethane in a dimethylformamide (DMF) solvent. Immerse in solution for 3 minutes. Thereafter, the nonwoven fabric impregnated with the polyurethane solution was coagulated in an aqueous dimethylformamide solution at a concentration of 15% by weight and washed with water to obtain a nonwoven fabric impregnated with polyurethane.
Subsequently, the polyurethane-impregnated nonwoven fabric was treated with an aqueous solution of caustic soda at a concentration of 5% by weight to elute the sea component in the composite fiber to perform an ultra-fine process to obtain a unit weight of 346.3 g / m 2, a thickness of 0.95 mm, A preliminary artificial leather (30) having a breathability of 56.4 L / min / 100 cm 2 was obtained.
Next, using a rotary screen coating method, a flame-retardant composition having a viscosity of 7,800 cps blended with 40 wt% water, 40 wt% ammonium polyphosphate phosphorus flame retardant, and 20 wt% polyurethane binder was used. On one surface of the preliminary
Examples 2 and 3
In Example 1 described above, artificial leathers were obtained in the same manner as in Example 1, except that the area ratios of the flame
Example 4
In Example 1 described above, artificial leather was obtained in the same manner as in Example 1 except that the flame-retardant composition was applied in the shape as shown in FIG. 4.
Examples 5 and 6
In Example 4 described above, artificial leather was obtained in the same manner as in Example 4, except that the area ratio of the flame
Example 7
In Example 1 described above, artificial leather was obtained in the same manner as in Example 1 except that the flame-retardant composition was applied in the shape as shown in FIG. 5.
Comparative Example 1
In Example 1 described above, artificial leather was obtained in the same manner as in Example 1 except that the flame-retardant composition was applied to the entire surface of the preliminary
Comparative Example 2
In Example 1 described above, artificial leather was obtained in the same manner as in Example 1 except that the area ratio of the flame
Next, the physical properties of artificial leather obtained by the above examples and comparative examples, respectively, were measured by the following method, and the measurement results are shown in Table 1 below.
% Of area of flame
The area ratio (%) of the flame
Specifically, a sample having a size of 50 × 50 cm is selected by selecting an arbitrary point of artificial leather, and a sample prepared by using an image analyzer (using the JVC Digital Camera KY-F70B in the software of Image-Pro Plus) After photographing the surface, the area ratio of the flame
[Equation]
Area ratio (%) of the flame
% Of upper thickness of flame
As shown in FIG. 2, the upper thickness ratio (%) of the flame
Specifically, any two points are selected so that the interval is 1000 μm in the cross-sectional SEM photograph of the artificial leather, and the thickness c of the preliminary
% Penetration depth of flame
The penetration depth (b) ratio (%) of the flame
Specifically, any two points are selected so that the interval is 1000 μm in the cross-sectional SEM image of the artificial leather, and the thickness (c) of the preliminary
Application amount measurement of the flame
The application amount (g / m 2) of the flame retardant composition was obtained from the difference between the weight of the preliminary
Horizontal burning rate measurement of artificial leather
The horizontal combustion speed (mm / min), which indirectly indicates the degree of flame retardancy of artificial leather, was measured according to the automotive interior combustion test regulations of FMVSS.
Breathability Measurement of Artificial Leather
Breathability (L / min / 100 cm 2) was measured according to the Frazier test specified in ASTM D 737.
ratio
(%)
ratio(%)
ratio(%)
(g / ㎡)
speed
(Mm / min)
(L / min / 100㎠)
10: flame retardant composition layer 20: groove
30: preliminary artificial leather
Claims (9)
An artificial leather comprising a flame retardant composition layer formed by partially applying a flame retardant composition on the preliminary artificial leather at an area ratio of 60 to 90% of the total surface area of the preliminary artificial leather.
And wherein said artificial leather has a plurality of grooves discontinuously distributed corresponding to uncoated areas of said preliminary artificial leather to which said flame retardant composition is not applied.
And the flame retardant composition layer is one body surrounding the grooves.
Each of the grooves is artificial leather, characterized in that the circular or polygonal shape.
The horizontal combustion speed of the artificial leather measured according to the FMVSS. Artificial leather
The flame retardant composition layer is artificial leather, characterized in that it has an upper thickness of 0.1 ~ 4% range compared to the thickness of the preliminary artificial leather and a penetration depth of 5 ~ 50% range of the thickness of the preliminary artificial leather.
The flame retardant composition layer is artificial leather comprising a phosphorus-based flame retardant.
The flame retardant composition layer is artificial leather including a urethane-based binder containing silicon.
Fineness of the ultrafine fibers is artificial leather, characterized in that less than 0.3 denier.
Applications Claiming Priority (2)
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KR1020100017732 | 2010-02-26 | ||
KR20100017732 | 2010-02-26 |
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KR20110098675A true KR20110098675A (en) | 2011-09-01 |
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EP (1) | EP2540909B1 (en) |
JP (1) | JP5956351B2 (en) |
KR (1) | KR101680533B1 (en) |
WO (1) | WO2011105851A2 (en) |
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EP2726667B1 (en) * | 2011-06-28 | 2018-04-04 | E. I. du Pont de Nemours and Company | Patterned flame retardant flexible substrates and process of manufacture thereof |
US9592661B2 (en) | 2013-03-15 | 2017-03-14 | Church & Dwight Co., Inc. | System for depositing an imprint onto a substrate |
CA2906601A1 (en) * | 2013-03-15 | 2014-09-25 | Church & Dwight Co., Inc. | Method and composition for depositing textured imprints onto a substrate surface |
JP6186405B2 (en) * | 2015-04-23 | 2017-08-23 | 株式会社加平 | Patterned sheet, patterned sheet manufacturing method, and manufacturing apparatus |
CN112192912B (en) * | 2020-08-18 | 2023-05-02 | 浙江梅盛新材料有限公司 | Artificial leather with flame retardant property and preparation method and preparation device thereof |
CN116018439A (en) | 2020-09-29 | 2023-04-25 | 东丽株式会社 | Artificial leather, method for producing the same, and artificial leather substrate |
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DE111076C (en) * | 1899-05-14 | 1900-06-12 | ||
JPS5428443B2 (en) * | 1972-01-31 | 1979-09-17 | ||
DE3241820C2 (en) * | 1982-11-11 | 1994-04-21 | Bluecher Hubert | Flame retardant, flexible textile material or the like |
JPS6237155A (en) * | 1985-08-12 | 1987-02-18 | 平岡織染株式会社 | Uninflammable fiber sheet material |
FR2637919B1 (en) * | 1988-10-14 | 1991-06-28 | Picardie Lainiere | COMPOSITE FIREPROOF TEXTILE CLOTHING AND SEAT COMPRISING SUCH A TEXTILE |
JPH0465580A (en) * | 1990-07-02 | 1992-03-02 | Kitasen:Kk | Flexible coated cloth |
JPH11350363A (en) * | 1998-06-03 | 1999-12-21 | Toray Ind Inc | Nonwoven fabric sheet for acoustic material |
JP2001295176A (en) * | 2000-04-11 | 2001-10-26 | Nisshinbo Ind Inc | Flame retardant electroconductive cloth and method for producing the same |
JP2002103495A (en) * | 2000-09-27 | 2002-04-09 | Toyo Cloth Co Ltd | Functional material |
JP2003089986A (en) * | 2001-09-19 | 2003-03-28 | Kuraray Co Ltd | Flame-retardant grained artificial leather and method for producing the same |
DE10239631A1 (en) * | 2002-08-23 | 2004-03-04 | Carcoustics Tech Center Gmbh | Insulating structural part for heat and noise insulation, has fire resistant coating, ceramic adhesive, expandable microhollow ceramic spheres and heat expanding propellant |
JP4376734B2 (en) * | 2004-08-26 | 2009-12-02 | 帝人コードレ株式会社 | Manufacturing method of artificial leather |
JP4655740B2 (en) * | 2005-04-25 | 2011-03-23 | 東レ株式会社 | Method for producing napped flame-retardant leather-like sheet |
JP4664135B2 (en) * | 2005-07-08 | 2011-04-06 | 大京化学株式会社 | Suede-like artificial leather with excellent flame retardancy and method for producing the same |
JP4681986B2 (en) * | 2005-08-25 | 2011-05-11 | 東レコーテックス株式会社 | Down-proof fabric |
JP4708262B2 (en) * | 2006-05-31 | 2011-06-22 | 株式会社クラレ | Flame retardant napping artificial leather |
JP2008081916A (en) * | 2006-08-31 | 2008-04-10 | Kuraray Co Ltd | Flame-retardant leather-like sheet and method for producing the same |
WO2008026653A1 (en) * | 2006-08-31 | 2008-03-06 | Kuraray Co., Ltd. | Flame-retardant leather-like sheet and process for producing the same |
JP2009072986A (en) | 2007-09-19 | 2009-04-09 | Idemitsu Technofine Co Ltd | Laminated body |
KR101173798B1 (en) * | 2009-06-30 | 2012-08-16 | 코오롱인더스트리 주식회사 | Artificial leather and method for manufacturing the same |
-
2011
- 2011-02-25 EP EP11747741.4A patent/EP2540909B1/en active Active
- 2011-02-25 KR KR1020110017147A patent/KR101680533B1/en active IP Right Grant
- 2011-02-25 WO PCT/KR2011/001335 patent/WO2011105851A2/en active Application Filing
- 2011-02-25 JP JP2012554938A patent/JP5956351B2/en active Active
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Publication number | Publication date |
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WO2011105851A3 (en) | 2012-01-19 |
WO2011105851A2 (en) | 2011-09-01 |
JP5956351B2 (en) | 2016-07-27 |
EP2540909A2 (en) | 2013-01-02 |
JP2013520581A (en) | 2013-06-06 |
EP2540909A4 (en) | 2013-10-09 |
EP2540909B1 (en) | 2016-09-07 |
KR101680533B1 (en) | 2016-11-29 |
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