KR20110088762A - Food preservative containing sterilization ingredients and process for preparing thereof - Google Patents

Food preservative containing sterilization ingredients and process for preparing thereof Download PDF

Info

Publication number
KR20110088762A
KR20110088762A KR1020100008418A KR20100008418A KR20110088762A KR 20110088762 A KR20110088762 A KR 20110088762A KR 1020100008418 A KR1020100008418 A KR 1020100008418A KR 20100008418 A KR20100008418 A KR 20100008418A KR 20110088762 A KR20110088762 A KR 20110088762A
Authority
KR
South Korea
Prior art keywords
food
alcohol
weight
carrier
aqueous solution
Prior art date
Application number
KR1020100008418A
Other languages
Korean (ko)
Other versions
KR101168049B1 (en
Inventor
서윤덕
Original Assignee
주식회사 립멘
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 주식회사 립멘 filed Critical 주식회사 립멘
Priority to KR1020100008418A priority Critical patent/KR101168049B1/en
Publication of KR20110088762A publication Critical patent/KR20110088762A/en
Application granted granted Critical
Publication of KR101168049B1 publication Critical patent/KR101168049B1/en

Links

Images

Classifications

    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
    • A23L3/3409—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor
    • A23L3/3418—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere, e.g. partial vacuum, comprising only CO2, N2, O2 or H2O
    • A23L3/3427—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere, e.g. partial vacuum, comprising only CO2, N2, O2 or H2O in which an absorbent is placed or used
    • A23L3/3436—Oxygen absorbent
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00—Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)

Abstract

PURPOSE: A food preservative and a producing method thereof are provided to prevent the change of the taste and the flavor of food by alcoholic components generated from an alcohol carrier. CONSTITUTION: A producing method of a food preservative comprises the following steps: producing an alcohol carrier by mixing 40wt% of porous silica with 60wt% of aqueous solution containing ethyl alcohol and salt water; inserting 50wt% of oxygen absorber(104) and 50wt% of alcohol carrier(102) into an air-permeable package; and inserting the package into a food container before sealing. The oxygen absorber contains 70wt% of iron powder with the particle size of 90meshes, and 30wt% of calcium chloride aqueous solution.

Description

살균성분을 갖는 식품 보존제와 그 제조방법{ Food Preservative Containing Sterilization Ingredients And Process for Preparing thereof} Food Preservative Containing Sterilization Ingredients And Process for Preparing Technical}

본 발명은 식품의 신선도(新鮮度)를 장시간 유지하는데 사용하는 식품 보존제와 그 제조방법에 관한 것이다.The present invention relates to a food preservative used to maintain the freshness of food for a long time and a manufacturing method thereof.

특히 산소흡수제와 주정담체(酒精擔體)를 통기성이 있는 포장 체에 적정비율로 혼합되게 충진하여, 식품 포장용기 내에 넣어 밀봉 사용시, 산소흡수제에 의한 산화작용으로는 식품의 직접적인 부패 요인이 되는 산소를 흡수하게 하고, 이와 동시에 산소흡수제와의 화학반응에 의하여 주정담체로부터 증기(蒸氣)로 비산(飛散)되는 알코올 성분에 의해서는 식품의 맛과 향의 변화를 방지하는 주정 처리 및 미생물의 증식 억제 작용을 발휘하게 하여, 식품의 신선도를 보 다 오래 동안 유지할 수 있게 한 식품 보존제와 그 제조방법에 관한 것이다.In particular, the oxygen absorbent and the alcohol carrier are filled in a permeable package at an appropriate ratio, and the oxygen absorber is oxidized by the oxygen absorbent when used in the food packaging container for sealing. Alcohol at the same time as alcohol is scattered from the alcohol carrier by chemical reaction with oxygen absorber, and alcohol treatment to prevent the change of taste and aroma of food and inhibit the growth of microorganisms. The present invention relates to a food preservative and a method for producing the same, wherein the food preservative can be maintained for a longer time than the freshness of the food.

일반적으로 식품회사에서 제조한 식품은 유통기한 연장을 목적으로 식품에 방부제, 보존제, 방충제 등을 직접혼합 하거나 혹은 함침 후, 포장지(나일론, 폴리에틸렌 필름 및 플라스틱 재질의 용기 등)에 넣어서 시중에 유통, 판매하고 있다.Generally, food manufactured by a food company is directly mixed with food, or impregnated with preservatives, preservatives, or insect repellents for the purpose of extending the shelf life, and then placed in a wrapping paper (nylon, polyethylene film, plastic container, etc.) for distribution. Selling.

그러나 방부제, 보존제, 방충제의 경우 사람들이 먹을 경우 건강에 유해한 요소로 작용하게 된다는 사실은 익히 널리 알려져 있다.However, it is well known that preservatives, preservatives, and insect repellents act as harmful factors to health when people eat.

더욱이 식품 현장에서는 식품에 에틸알코올(주정,酒精)에 직접 함침 혹은 분무하여 사용하고 있는데, 이는 에틸 알코올의 반복적인 사용으로 2차 오염원을 만 드는 폐단이 있으며, 또한 분무로 인한 알코올이 식품에 직접 들어가게 되면 식품의 맛과 향의 변질로 인한 냄새 등의 발생으로 일반 소비자들로부터 외면시 당하고 있음이 현실정이다. Moreover, the food field is directly impregnated or sprayed with ethyl alcohol (alcohol, 酒精) in the food, which is the end of the secondary pollution by repeated use of ethyl alcohol, and the alcohol from the spray directly into the food If you enter, it is a fact that you are being disregarded by consumers because of the smell caused by the deterioration of taste and flavor of food.

이와 같은 문제를 해결하기 위한 방법으로 철분 분말에 산화촉진제를 혼합하여 식품과 함께 포장하는 산소 흡수제가 개발되어 있으나, 이 산소흡수제 또한 혐기성 미생물의 발생으로 인하여 신선도를 떨어 지게 하는 요인이 되고 있다.In order to solve such a problem, an oxygen absorbent has been developed in which iron powder is mixed with an oxidation promoter and packaged together with food, but this oxygen absorber has also been a factor in reducing freshness due to the generation of anaerobic microorganisms.

한편 산소흡수제와 관련하여 하기와 같은 선행특허자료들로부터도, 에틸알코올의 흡착조성물에 의한 것과 증기발생의 충진제에 관한 내용이 공표되어 있으나, 증기발생의 촉진으로서 보존제의 생산과정의 공정에 의한 기체의 손실로 하여금 에틸알코올의 농도의 편차가 크며 포장지에 알코올의 기체가 흡착함으로 생산에 어려움이 많이 따르고 있다. On the other hand, related to the oxygen absorbent is disclosed in the following patent data, the adsorption composition of ethyl alcohol and the filler for the generation of steam, but the gas by the process of the production process of the preservative as a promotion of steam generation Due to the large variation in the concentration of ethyl alcohol and the adsorption of alcohol gas on the wrapping paper is difficult to produce a lot.

일본공개특허공개번호소55-10944,51-136845,57-22680,59-16811,61-111675,평성3-48786,일본특허공고번호평성3-58266,3-16106및3-73267.Japanese Patent Application Laid-Open Nos. 55-10944, 51-136845, 57-22680, 59-16811, 61-111675, Pyeong 3-48786, Japanese Patent Publication Nos. Pyeong 3-58266, 3-16106, and 3-73267.

따라서, 본 발명의 목적은 상기 제반 결점들을 해소하고자 예의(銳意) 연구결과 개발한 것으로, 산소흡수제와 주정담체와의 적정비율로 혼용함에 의해, 산소흡수제에 의해서는 식품의 직접적인 부패 요인이 되는 산소를 흡수하는 산화 작용을 그리고 산소흡수제와의 화학반응에 의하여 주정 담체로 부터 발생되는 알코올 성분에 의해서는 식품의 맛과 향의 변화를 방지하는 간접적인 주정처리 및 혐기성 세균을 억제하는 살균 작용을 동시에 발휘하여, 식품의 맛과 향의 변화를 방지하는 신선도가 장시간 유지되는 식품 보존성을 향상시킨 식품보존제와 그 제조방법을 제공하는 데 있다.Therefore, the object of the present invention was to develop the results of a careful study to solve the above-mentioned shortcomings, and by mixing the oxygen absorbent and the alcohol carrier at an appropriate ratio, oxygen absorber is a direct decay factor of food. The oxidative action of absorbing and the alcohol component generated from the alcohol carrier by the chemical reaction with the oxygen absorbent simultaneously indirect spirit treatment to prevent the change of taste and aroma of the food and the sterilization action to inhibit anaerobic bacteria. The present invention provides a food preservative and a method for producing the same, wherein the food preservative improves food preservation, which maintains freshness for a long time to prevent changes in taste and aroma of food.

상기 목적을 달성하기 위한 본 발명의 살균성분을 갖는 식품 보존제는, 청구항1 기재의 산소 흡수제 50중량%와, 다공질 실리카에 에틸알코올과 염수를 혼합하여 만든 수용액을 흡착시킨 주정담체(酒精擔體) 50중량%와를 통기성 포장체에 충진후 식품 포장용기 내에 넣어 밀봉하여, 상기 산소 흡수제로부터는 산화반응이 그리고 상기 주정담체로부터는 상기 산소흡수제와의 화학 반응에 의한 알코올 성분의 비산으로 식품의 신선도를 유지하는 살균작용이 실행되게 한 것을 특징으로 한다.Food preservatives having a bactericidal component of the present invention for achieving the above object, the alcohol carrier adsorbed 50% by weight of the oxygen absorbent according to claim 1 and the aqueous solution made by mixing ethyl alcohol and brine on the porous silica (酒精 擔 體) Filled with 50% by weight in a permeable package and sealed in a food packaging container, the freshness of the food by the oxidative reaction from the oxygen absorbent and the chemical reaction with the oxygen absorbent from the alcohol carrier to improve the freshness of the food. It is characterized in that the sterilization action to be carried out.

또, 상기 목적을 달성하기 위한 본 발명의 살균성분을 갖는 식품 보존제는, 청구항2 기재의 제1항에 있어서, 상기 산소흡수제는 90메쉬의 입도를 갖는 철분(Fe)70중량%와 물과 염화칼슘을 혼합한 수용액30 중량%를 혼합하여 조성한 것을 특징으로 한다.In addition, the food preservative having a bactericidal component of the present invention for achieving the above object, according to claim 1, wherein the oxygen absorbent is 70% by weight of iron (Fe) having a particle size of 90 mesh, water and calcium chloride It is characterized in that the composition by mixing 30% by weight of the mixed aqueous solution.

또한, 상기 목적을 달성하기 위한 본 발명의 살균성분을 갖는 식품 보존제는, 청구항3 기재의 제1항 또는 제2항에 있어서, 상기 주정담체는 다공질 실리카 40중량%에 에틸알콜과 염수를 혼합한 60중량%의 수용액을 흡착시킨 것을 특징으로 한다.In addition, the food preservative having a bactericidal component of the present invention for achieving the above object, according to claim 1 or claim 2, wherein the alcohol carrier is 40% by weight of porous silica mixed with ethyl alcohol and brine It is characterized by adsorbing 60% by weight of an aqueous solution.

또, 상기 목적을 달성하기 위한 본 발명의 살균성분을 갖는 식품 보존제는, 청구항4 기재의 제3항에 있어서, 상기 염수는 에틸알콜에 대하여 30중량% 혼합되게 한 것을 특징으로 한다.In addition, the food preservative having a bactericidal component of the present invention for achieving the above object, characterized in that the brine is mixed with 30% by weight of ethyl alcohol according to claim 3.

상기 목적을 달성하기 위한 본 발명의 살균성분을 갖는 식품 보존제의 제조방법은, 청구항5 기재의 90메쉬의 입도를 갖는 철분(Fe)70중량%와 물과 염화칼슘을 혼합한 수용액30 중량%를 혼합하여 된 산소흡수제를 제조하는 단계; 다공질 실리카 40중량%에 에틸알코올과 염수를 혼합하여 만든 수용액60중량%를 흡착시킨 주정담체(酒精擔體)를 제조하는 단계; 상기 단계에서 제조된 산소흡수제 주정담체를 각각 50 : 50중량%의 비율로 통기성 포장체에 충진후 식품 포장용기 내에 넣어 밀봉하는 단계를 포함하고, 상기 산소 흡수제에 의한 산화반응과 함께 상기 주정담체에 의한 알코올 성분이 식품 주위로 증기화 되어 비산되게 한 것을 특징으로 한다.Method for producing a food preservative having a bactericidal component of the present invention for achieving the above object, 70% by weight of iron (Fe) having a particle size of 90 mesh of claim 5 and 30% by weight of an aqueous solution mixed with water and calcium chloride Preparing an oxygen absorbent; Preparing a spirit carrier obtained by adsorbing 60% by weight of an aqueous solution made by mixing 40% by weight of porous silica with ethyl alcohol and brine; The oxygen absorbent alcohol carrier prepared in the above step is filled in a breathable package at a ratio of 50: 50% by weight, each of which is sealed in the food packaging container, and the oxidation support by the oxygen absorbent to the alcohol carrier Alcohol component is vaporized around the food is characterized in that it is scattered.

상기 목적을 달성하기 위한 본 발명의 살균성분을 갖는 식품 보존제의 제조방법은 청구항6 기재의 제5항에 있어서, 상기 염수는 에틸알콜에 대하여 30중량% 혼합되게 한 것을 특징으로 한다.The method for preparing a food preservative having a bactericidal component of the present invention for achieving the above object is characterized in that the brine is mixed 30% by weight with respect to ethyl alcohol.

본 발명에 의하면, 산소흡수제와 그리고 주정담체(酒精擔體)를 적정비율로 혼용하여 조성한 것에 의해, 산소흡수제에 의한 산화작용으로는 식품의 직접적인 부패 요인이 되는 산소를 흡수하게 하고, 동시에 주정담체와 산소흡수제와의 화학반응에 의하여 증기상태로 비산되는 주정담체의 알코올 성분에 의해서는 식품의 맛과 향의 변화를 방지하는 간접적인 주정처리 효과와 혐기성 세균을 억제 효과를 발휘하게 하여, 식품의 신선도를 장기간 유지할 수 있는 식품의 보존성을 향상시킨 효과가 있다.According to the present invention, the oxygen absorbent and the alcohol carrier are mixed and formed at an appropriate ratio, so that the oxygen absorbing agent absorbs oxygen, which is a direct decay factor of the food. Alcoholic components of alcohol carriers scattered in the vapor state by chemical reactions with oxygen absorbers make indirect alcoholic treatments to prevent changes in taste and aroma of foods and inhibit anaerobic bacteria. There is an effect of improving the preservation of foods that can maintain the freshness for a long time.

또, 항균 성분과의 혼합이 우수하여 제조와 포장 공정이 간단하여 생산성이 좋고, 특히 분진(粉塵) 발생이 없고 파손의 위험성이 없어 경제성이 좋다는 효과가 있다. In addition, it is excellent in mixing with the antibacterial component, the production and packaging process is simple, the productivity is good, there is no effect of dust generation, especially there is no risk of damage, it is effective economical.

도 1는 본 발명에 따른 식품 보존제의 제조 공정도이고,
도 2는 본 발명의 식품 보존제로 사용하는 주정 담체의 내부를 보인 단면도이다. 1 is a manufacturing process diagram of a food preservative according to the present invention,
Figure 2 is a cross-sectional view showing the interior of the spirit carrier used as a food preservative of the present invention.

이하, 첨부된 도면을 참조하여 본 발명의 보다 바람직한 실시예를 상세하게 설명한다.Hereinafter, with reference to the accompanying drawings will be described in detail a more preferred embodiment of the present invention.

<제조예><Production Example>

<산소흡수제 제조단계: 102><Oxygen Absorber Manufacturing Step: 102>

도면1의 표시와 같이, 산소흡수제는 90 메쉬의 입도를 갖는 철분(Fe)70중량%와, 물과 염화칼슘을 혼합한 수용액 30중량%를 서로 혼합하여 제조한다.As shown in FIG. 1, the oxygen absorbent is prepared by mixing 70% by weight of iron (Fe) having a particle size of 90 mesh and 30% by weight of an aqueous solution of water and calcium chloride.

산소흡수제는 식품의 보존제 작용을 하는 것인데, 식품의 보존제로 사용시 식품포장용기의 내부에 존재하는 공기와 만나게 되면, 철분 분말이 공기 중의 산소를 흡수하면서 연속적으로 산화되어 산소를 제거하는 것에 의해, 산소에 의한 식품의 부패율을 최소화하여 결과적으로는 식품의 보존 력을 길게 하는 작용을 한다. 상기 염화칼슘의 첨가 이유는 철분 분말의 산화작용을 촉진하기 위한 촉진제 작용을 하도록 하기 위함이다. 또한 상기 산소 흡수제는 후술하는 주정담체와의 혼용시 주정담체에 함유된 수분을 공급받으면서 산화작용을 실행하게 하다.Oxygen absorbers act as food preservatives. When used as food preservatives, when oxygen meets the air present inside the food packaging container, the iron powder is continuously oxidized while absorbing oxygen in the air to remove oxygen. By minimizing the corruption rate of the food by the result, it acts to lengthen the food preservation capacity. The reason for adding the calcium chloride is to act as an accelerator for promoting the oxidation of iron powder. In addition, the oxygen absorbent is allowed to perform the oxidation while receiving the water contained in the spirit carrier when mixed with the spirit carrier to be described later.

<주정담체(酒精擔體)의 제조단계: 104><Step of manufacturing alcohol carrier: 104>

상기 단계(102)를 통하여 산소흡수제가 완료된 후에는, 다공질 실리카 50중량%에 에틸알코올과 염화나트륨과 물을 혼합하여 만든 혼합 수용액 50중량%를 기 준비한 혼합기에 넣고 회전수 40~200RPM으로 20분간 고속 혼합시킴에 의해, 다공질 실리카에 수용액을 단(短) 시간에 흡착시켜 주정담체를 제조한다.After the oxygen absorbent is completed through the step 102, 50% by weight of a mixed aqueous solution made by mixing ethyl alcohol, sodium chloride, and water in 50% by weight of porous silica is placed in a pre-prepared mixer at a high speed of 40 to 200 RPM for 20 minutes. By mixing, the aqueous solution is adsorbed to the porous silica in a short time to prepare a spirit carrier.

상기 혼합 수용액과 다공질 실리카와의 혼합에 대하여 상기에서는 50:50중량%의 비율로 혼합하여 제조하는 것을 설명하였으나, 20 ~50 : 50 ~80중량%의 비율로 혼합할 수도 있다. 또한 염화나트륨과 물을 혼합하여 만든 염수는 에틸알코올에 대하여 30중량% 혼합되게 한다. 그 이유는 알코올 성분의 약화를 방지하면서도 염수의 효능이 유지하도록 하기 위함이다. The mixing of the mixed aqueous solution and the porous silica was described in the above to be prepared by mixing at a ratio of 50: 50% by weight, but may be mixed at a ratio of 20 to 50:50 to 80% by weight. In addition, the brine made by mixing sodium chloride and water is mixed with 30% by weight of ethyl alcohol. The reason is to prevent the weakening of the alcohol component while maintaining the efficacy of the saline.

혼합이 완료된 주정담체는 도면 2의 표시와 같다. 즉, 실리카(110)의 알코올 의 흡수력이 뛰어나 세공구조에서 알코올(112)을 먼저 흡수하고 수분인 염수(114)가 표면으로 붙게되는 구조를 이루게 된다. 주정 담체는 다공질 실리카의 단위당 에틸알코올의 보지량(保持量)은 1g당 2cc~5cc를 흡착하게 함이 바람직하다.After completion of mixing, the alcohol carrier is shown in FIG. That is, the silica 110 is excellent in the absorption power of alcohol to form a structure in which the alcohol 112 is first absorbed in the pore structure and the brine 114, which is water, adheres to the surface. It is preferable that the alcohol carrier adsorbs 2cc to 5cc of 1g of ethyl alcohol holding amount per porous silica.

<식품보존제 제조 단계: 106><Food preservative manufacturing step: 106>

상기 단계에서 제조된 산소흡수제와 주정담체는 각각 50:50중량%의 비율로 혼용되게 기 준비한 포장체의 내부에 충진하여 밀봉됨에 의해, 본 발명의 식품 보존제가 완성된다. 식품 보존제가 밀봉되는 포장체의 크기는 식품 포장용기의 크기에 따라서 달라지겠지만, 예컨대 500cc의 식품 포장용기라면 5cm x 6c의 체적을 갖는 포장체가 바람직하며, 포장체에 밀봉된 식품보존제는, 식품 포장용기의 내부에 식품과 같이 넣어져서 밀봉된다.The oxygen absorbent and alcohol carrier prepared in the above step is filled and sealed in a package prepared beforehand to be mixed at a ratio of 50: 50% by weight, respectively, thereby completing the food preservative of the present invention. The size of the package in which the food preservative is sealed will vary depending on the size of the food package. For example, if the container is 500cc, the package having a volume of 5 cm x 6c is preferable, and the food preservative sealed in the package is a food package. Inside the container, it is sealed with food.

이렇게 제조된 식품 보존제가 식품용기 내에 밀봉되어 사용하게 되면, 산소흡수제의 산소흡수에 의한 화학 반응(산화반응)시, 도면 2의 표시와 같이, 주정담체의 표면에 함유된 수분이 산소흡수제에 흡착되는 반면, 다공질 실리카에 함유되어 있던 에틸알코올이 증기로 비산된다. 증기로 비산되는 에틸알코올은 통기성의 포장체를 통과후 포장 용기의 내부로 분산되어 살균작용을 실행하게 된다.When the food preservative thus prepared is sealed and used in the food container, during the chemical reaction (oxidation reaction) by the oxygen absorption of the oxygen absorbent, moisture contained in the surface of the alcohol carrier is adsorbed to the oxygen absorbent, as shown in FIG. On the other hand, ethyl alcohol contained in the porous silica is scattered by steam. Ethyl alcohol scattered by steam passes through the breathable package and is dispersed into the packaging container to perform sterilization.

따라서 산소흡수제에 의해서는 식품을 부패시키는 산소를 흡착함과 아울러 다공질 실리카로부터 비산되는 에틸알코올은 식품 부패의 직접적인 요소로 작용하는 미생물의 번식을 억제하는 주정처리에 의한 살균 작용을 실시하여 보다 장시간 동안 식품의 신선도를 유지하여 준다.Therefore, the oxygen absorbent adsorbs the oxygen that rots the food, and the ethyl alcohol scattered from the porous silica performs sterilization by alcohol treatment that inhibits the growth of microorganisms acting as a direct factor of food rot. Keep food fresh.

<실시예><Examples>

90 메쉬의 입도를 갖는 철분(Fe)70중량%와, 물과 염화칼슘을 혼합한 수용액 30중량%를 서로 혼합하여 제조한 산소흡수제 50중량%와, 다공질 실리카 40중량%에 에틸알코올과 염화나트륨과 물을 혼합하여 만든 혼합 수용액 60중량%를 혼합하여 제조한 주정담체 50중량%를, 5cm x 6cm의 체적을 갖는 기 준비한 포장체의 내부에 충진하여 밀봉한 후, 이를 1000cc의 폴리에틸렌필름 재질로 만든 식품 포장용기의 내부에 식품과 같이 넣어져서 밀봉하였다.70% by weight of iron (Fe) having a particle size of 90 mesh, 50% by weight of an oxygen absorbent prepared by mixing 30% by weight of an aqueous solution of water and calcium chloride, 40% by weight of porous silica, ethyl alcohol, sodium chloride, and water 50 wt% of the alcohol carrier prepared by mixing 60 wt% of the mixed aqueous solution prepared by mixing the mixture into the inside of the prepared package having a volume of 5 cm x 6 cm and then sealed, and then made of 1000 cc polyethylene film. The inside of the packaging container was put together with food and sealed.

이렇게 밀봉된 식품 포장용기는 25~27℃의 항온기에 넣어 산소흡수량과 에틸알코올의 농도를 경시적으로 관찰함과 아울러 후각 관능 결과는 하기 표1 내지 표4에 표시하였다.The sealed food packaging container was placed in a thermostat at 25-27 ° C. to observe oxygen concentration and ethyl alcohol concentration over time, and olfactory sensory results are shown in Tables 1 to 4 below.

<산소 흡수 알코올 휘산제(실리카)의 산소 흡수량과 알코올 휘산농도><Oxygen absorption amount and alcohol volatilization concentration of oxygen absorbing alcohol volatilizer (silica)>
6시간
6 hours
12시간
12 hours
24시간
24 hours
48시간
48 hours
산소흡수량(cc)
Oxygen absorption (cc)
90
90
160
160
209
209
알코올 휘산농도(%)
Alcohol volatility (%)
1.0
1.0
2.0
2.0
3.0
3.0
3.0
3.0

<어묵에 대한 7일 후의 각각의 미생물(대장균)발생량(상온 90%RH 보관)> <Emitted amount of microorganisms (E. coli) after 7 days for fish paste (90% RH storage at room temperature)>
시험종류
Test Type
7일후의 각각의 미생물(대장균)발생량
Production amount of each microorganism (E. coli) after 7 days
산소흡수제
Oxygen absorber 2.0 * 108 2.0 * 10 8
알코올 (주정)침지(浸漬)
Alcohol immersion 3.0 * 107 3.0 * 10 7
산소흡수 알코올 휘산제(실리카)
Oxygen-absorbing alcohol volatiles (silica) 9.0 * 106 9.0 * 10 6
공시료
Official Fee 4.0 * 109 4.0 * 10 9

<식빵에 대한 포장에 핀홀이 있을 때 곰팡이발생(상온 90%RH 보관)><Mold occurs when there is a pinhole in the package for bread (store at room temperature 90% RH)>

1일
1 day
2일
2 days
3일
3 days
4일
4 days
5일
5 days
6일
6 days
7일
7 days
10일
10 days
산소흡수제
Oxygen absorber -- -- -- -- -- -- ++ ++
알코올(주정)침지
Alcohol immersion -- -- -- -- -- -- -- ++
산소흡수알코올휘산제
(실리카)
Oxygen Absorption Alcoholic Acid
(Silica) -- -- -- -- -- -- -- --
공시료
Official Fee -- -- -- -- -- ++ ++ ++

상기 표에서 "-"는 곰팡이 발생이 없음을, 그리고 "+"는 곰팡이 발생했음을 각각 표시한 것임.In the table, "-" indicates that no mold occurred, and "+" indicates that mold occurred.

<후각 관능검사(알코올 냄새)>Olfactory sensory test (alcohol odor)
시험종류
Test Type
알코올 냄새
Alcohol smell
산소흡수제
Oxygen absorber
없음
none
알코올(주정)침지(浸漬)
Alcohol immersion
많이남
Many
산소흡수 알코올 휘산제(실리카)
Oxygen-absorbing alcohol volatiles (silica)
거의 없음
Almost none

이 실험예에 의하면 본 발명은 각종 식품의 보존에 유용하고 특히 식품 가공품인 햄과 어묵 등의 보존제로 사용함에 적합함을 알 수 있다. 상기 실험은 어묵에 각각 시료를 투입하여 10일 후 어묵의 냄새를 검사한 것으로, 항온기 내의 25~27℃에서 10일간 실험한 것이다.According to this experimental example, it can be seen that the present invention is useful for preservation of various foods, and particularly suitable for use as a preservative such as ham and fish cakes, which are food products. The experiment was to test the smell of the fish cake after 10 days by putting the sample in each fish cake, 10 days at 25 ~ 27 ℃ in a thermostat.

본 제품은 식품을 신선도를 유지하면서 장시간 보존할 수 있게 하여, 식품의 보존성 향상에 유용한 이용성이 있다.This product enables food to be stored for a long time while maintaining freshness, and thus has useful utility for improving food preservation.

본 발명의 바람직한 실시 예를 참조하여 설명하였지만 해당 기술 분야의 숙련된 당업자라면 하기의 특허 청구 범위에 기재된 본 발명의 사상 및 영역으로부터 벗어나지 않는 범위 내에서 본 발명을 다양하게 수정 및 변경시킬 수 있음을 이해할 수 있을 것이다.Although described with reference to a preferred embodiment of the present invention, those skilled in the art that various modifications and changes can be made within the scope of the present invention without departing from the spirit and scope of the invention described in the claims below. I can understand.

110 : 실리카 112: 주정알코올 114 : 염수(鹽水)110 silica 112 alcohol alcohol 114 brine

Claims (6)

산소 흡수제 50중량%와, 그리고 다공질 실리카에 에틸알코올과 염수를 혼합하여 만든 수용액을 흡착시킨 주정담체(酒精擔體) 50중량%를 통기성 포장체에 충진후 식품 포장용기 내에 넣어 밀봉하여, 상기 산소 흡수제로부터는 산화반응이 그리고 상기 주정담체로부터는 상기 산소흡수제와의 화학 반응에 의한 알코올 성분의 비산으로 식품의 신선도를 유지하는 살균작용이 실행되게 한 살균성분을 갖는 식품 보존제.50% by weight of an oxygen absorbent and 50% by weight of an alcohol carrier adsorbed with an aqueous solution made by mixing ethyl alcohol and brine in porous silica were filled in a breathable package, and then sealed in a food packaging container and sealed. A food preservative having a bactericidal component such that an oxidizing reaction is carried out from the absorbent and an alcohol component is scattered from the alcohol carrier by the chemical reaction with the oxygen absorbent to maintain the freshness of the food. 제1항에 있어서, 상기 산소흡수제는 90메쉬의 입도를 갖는 철분(Fe)70중량%와 물과 염화칼슘을 혼합한 수용액30 중량%를 혼합하여 조성한 것을 특징으로 하는 살균성분을 갖는 식품 보존제.The food preservative of claim 1, wherein the oxygen absorbent is formed by mixing 70% by weight of iron (Fe) having a particle size of 90 mesh and 30% by weight of an aqueous solution of water and calcium chloride. 제1항 또는 제2항에 있어서, 상기 주정담체는 다공질 실리카 40중량%에 에틸알콜과 염수를 혼합한 60중량%의 수용액을 흡착시킨 것을 특징으로 하는 살균성분을 갖는 식품 보존제.The food preservative of claim 1 or 2, wherein the alcohol carrier is made by adsorbing 60 wt% of an aqueous solution of ethyl alcohol and saline mixed with 40 wt% of porous silica. 제3항에 있어서, 상기 염수는 에틸알콜에 대하여 30중량% 혼합되게 한 것을 특징으로 하는 살균성분을 갖는 식품 보존제.The food preservative of claim 3, wherein the brine is mixed with 30 wt% of ethyl alcohol. 90메쉬의 입도를 갖는 철분(Fe)70중량%와 물과 염화칼슘을 혼합한 수용액30 중량%를 혼합하여 된 산소흡수제를 제조하는 단계;
다공질 실리카 40중량%에 에틸알콜과 염수를 혼합하여 만든 수용액 60중량%를 흡착시킨 주정담체(酒精擔體)를 제조하는 단계; 및
상기 단계에서 제조된 산소흡수제 주정담체를 각각 50 : 50중량%의 비율로 통기성 포장체에 충진후 식품 포장용기 내에 넣어 밀봉하는 단계를 포함하고, 상기 산소 흡수제에 의한 산화반응과 함께 상기 주정담체에 의한 알코올 성분이 식품 주위로 증기(蒸氣)로 비산되게 한 것을 특징으로 하는 살균성분을 갖는 식품 보존제의 제조방법.Preparing an oxygen absorbent obtained by mixing 70% by weight of iron (Fe) having a particle size of 90 mesh and 30% by weight of an aqueous solution in which water and calcium chloride are mixed;
Preparing a spirit carrier obtained by adsorbing 60% by weight of an aqueous solution made by mixing 40% by weight of porous silica with ethyl alcohol and brine; And
Filling the oxygen absorbent alcohol carrier prepared in the step in a breathable package at a ratio of 50: 50% by weight in each of the food packaging container and sealing, and the oxidation support by the oxygen absorbent to the alcohol carrier A method of producing a food preservative having a bactericidal component, wherein the alcohol component is scattered by steam around the food. 제5항에 있어서, 상기 염수는 에틸알콜에 대하여 30중량% 혼합되게 한 것을 특징으로 하는 살균성분을 갖는 식품 보존제의 제조방법.
The method according to claim 5, wherein the brine is mixed with 30% by weight of ethyl alcohol.
KR1020100008418A 2010-01-29 2010-01-29 Food Preservative Containing Sterilization Ingredients And Process for Preparing thereof KR101168049B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020100008418A KR101168049B1 (en) 2010-01-29 2010-01-29 Food Preservative Containing Sterilization Ingredients And Process for Preparing thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020100008418A KR101168049B1 (en) 2010-01-29 2010-01-29 Food Preservative Containing Sterilization Ingredients And Process for Preparing thereof

Publications (2)

Publication Number Publication Date
KR20110088762A true KR20110088762A (en) 2011-08-04
KR101168049B1 KR101168049B1 (en) 2012-07-24

Family

ID=44927164

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020100008418A KR101168049B1 (en) 2010-01-29 2010-01-29 Food Preservative Containing Sterilization Ingredients And Process for Preparing thereof

Country Status (1)

Country Link
KR (1) KR101168049B1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107173433A (en) * 2017-07-04 2017-09-19 苏州农业职业技术学院 A kind of fruit antistaling agent containing capsaicine
KR20210001602A (en) * 2019-06-28 2021-01-06 경상남도 A Storing Assembly of Zanthoxylum schinifolium Seeds for Zanthoxylum schinifolium Oil

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101615003B1 (en) * 2014-03-20 2016-04-22 주식회사 티피지 Absorption agent of oxygen and producing process thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6287079A (en) 1985-10-14 1987-04-21 Seiwa Kasei Kk Food preservative and preservation of food using said preservative
EP1550506B1 (en) 2002-10-08 2016-03-09 Mitsubishi Gas Chemical Company, Inc. Oxygen scavenger composition
JP2008109856A (en) 2005-01-28 2008-05-15 Freunt Ind Co Ltd Food quality retaining agent

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107173433A (en) * 2017-07-04 2017-09-19 苏州农业职业技术学院 A kind of fruit antistaling agent containing capsaicine
KR20210001602A (en) * 2019-06-28 2021-01-06 경상남도 A Storing Assembly of Zanthoxylum schinifolium Seeds for Zanthoxylum schinifolium Oil

Also Published As

Publication number Publication date
KR101168049B1 (en) 2012-07-24

Similar Documents

Publication Publication Date Title
CN1234283C (en) Fruit and evgetable fresh-keeping agent and its production method
JPWO2017135433A1 (en) Functional film, functional container, and freshness holding method
CN101861890A (en) Slow-release solid chlorine dioxide preservative
CN108246046B (en) Sterilizing air purifying agent and preparation method and application thereof
JP5218300B2 (en) Food preservative and its package
CN112042640B (en) Slow-release long-acting chlorine dioxide disinfection powder and preparation method thereof
KR101168049B1 (en) Food Preservative Containing Sterilization Ingredients And Process for Preparing thereof
RU2436401C2 (en) Appropriate technology for production of guacamole fit for long-term storage
CN108607483B (en) Traditional Chinese medicinal material curing agent with oxygen slow release function and preparation method and use method thereof
CN113662004A (en) Slow-release chlorine dioxide disinfection card using zeolite as carrier
CN101755895B (en) Sheet-type chlorine dioxide gas generant
JPH0115271B2 (en)
KR101168640B1 (en) Deoxidizing agent with antibiosis and method for preparation thereof
JP4879051B2 (en) Oxygen absorber
KR100269664B1 (en) Food preservative and process for preparing thereof
US5955004A (en) Composition of a product to preserve perishable foodstuffs
JPS63233748A (en) Freshness preservative and deethylating agent
KR101023018B1 (en) Controlling formulations against microorganism of food using mixed carrier and methods for the preparation thereof
JP2006288270A (en) Method for packaging &#39;ampo&#39; persimmon
KR20120045918A (en) Fresh-cut fruit container or packing containing multi-functional packing material
JP2022022479A (en) Freshness-preserving film and freshness-preserving container
KR102541263B1 (en) Method for producing freshness preservation agent of food containing water using chemically treated zeolite
CN113892678B (en) Curing agent for tobacco leaf storage and alcoholization process and use method thereof
JPH11207177A (en) Deoxidizer
KR102479389B1 (en) Antimicrobial preservative containing biopolymer

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20150717

Year of fee payment: 4

FPAY Annual fee payment

Payment date: 20170717

Year of fee payment: 6

FPAY Annual fee payment

Payment date: 20180717

Year of fee payment: 7

FPAY Annual fee payment

Payment date: 20190731

Year of fee payment: 8