KR20110085128A - Rice grain syrup mixture and method for manufacturing of the same - Google Patents

Rice grain syrup mixture and method for manufacturing of the same Download PDF

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KR20110085128A
KR20110085128A KR1020100004742A KR20100004742A KR20110085128A KR 20110085128 A KR20110085128 A KR 20110085128A KR 1020100004742 A KR1020100004742 A KR 1020100004742A KR 20100004742 A KR20100004742 A KR 20100004742A KR 20110085128 A KR20110085128 A KR 20110085128A
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syrup
weight
crude
mixture
parts
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KR1020100004742A
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KR101131763B1 (en
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강봉석
강철
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강봉석
강철
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C17/00Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces
    • B05C17/005Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes
    • B05C17/015Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes with pneumatically or hydraulically actuated piston or the like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C11/00Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
    • B05C11/10Storage, supply or control of liquid or other fluent material; Recovery of excess liquid or other fluent material
    • B05C11/1002Means for controlling supply, i.e. flow or pressure, of liquid or other fluent material to the applying apparatus, e.g. valves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C17/00Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces
    • B05C17/005Hand tools or apparatus using hand held tools, for applying liquids or other fluent materials to, for spreading applied liquids or other fluent materials on, or for partially removing applied liquids or other fluent materials from, surfaces for discharging material from a reservoir or container located in or on the hand tool through an outlet orifice by pressure without using surface contacting members like pads or brushes
    • B05C17/00503Details of the outlet element
    • B05C17/00506Means for connecting the outlet element to, or for disconnecting it from, the hand tool or its container
    • B05C17/00509Means for connecting the outlet element to, or for disconnecting it from, the hand tool or its container of the bayonet type

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Jellies, Jams, And Syrups (AREA)

Abstract

PURPOSE: A grain syrup mixture and a producing method thereof are provided to prevent the degeneration of the mixture after storing for a long time by adding additives. CONSTITUTION: A producing method of a grain syrup mixture comprises the following steps: mixing starch, water, a liquefying enzyme, an enzyme stabilizer, and adding malt into the mixture for saccharifying the mixture to obtain grain syrup(S100); mixing corn starch, the water, the liquefying enzyme, and the enzyme stabilizer, and adding acid into the mixture for obtaining low-sugar starch syrup(S110); mixing the obtained grain syrup and the low-sugar starch syrup in the constant rate to obtain the grain syrup mixtures(S120); and adding additives including an antioxidant into the mixture(S130).

Description

조청 혼합물 및 그 제조방법{RICE GRAIN SYRUP MIXTURE AND METHOD FOR MANUFACTURING OF THE SAME}Crude mixture and its manufacturing method {RICE GRAIN SYRUP MIXTURE AND METHOD FOR MANUFACTURING OF THE SAME}

본 발명은 조청 혼합물 및 그 제조방법에 관한 것으로, 보다 상세하게는 조청과 저당물엿의 제조과정을 각각 개선하고, 개선된 공정에 의하여 제조된 조청과 저당물엿을 서로 혼합하고, 이 혼합물에 첨가제를 첨가함으로써 유과에 적합한 맛과 물성을 발휘할 수 있는 조청 혼합물 및 그 제조방법에 관한 것이다.The present invention relates to a crude syrup mixture and a method of preparing the same, and more particularly, to improve the manufacturing process of the crude syrup and the low sugar syrup, respectively, the crude syrup and the low sugar syrup prepared by the improved process are mixed with each other, and an additive is added to the mixture. The present invention relates to a crude syrup mixture capable of exhibiting a taste and physical properties suitable for milk fruit by adding the same and a method for producing the same.

일반적으로 유과는 찹쌀가루에 청주, 설탕, 콩물 및 물을 넣고 반죽하여 찜통에서 증기로 찌고 꽈리가 생길 정도로 반죽을 쳐서, 이 반죽을 얇게 밀어 편후 적당한 크기로 절단하여 건조 후 기름에 튀겨 조청을 발라 고명을 묻히는 과정을 통하여 제조된다.In general, confectionery is made with glutinous rice flour, sake, sugar, soybeans, and water, kneaded, steamed in a steamer and steamed to make a rice cake. Then, the dough is thinly sliced, cut into a suitable size, dried, fried in oil and applied. It is manufactured through the process of embedding garnish.

그리고, 상기 조청은 우리나라의 전통식품이며, 전분질 원료(쌀, 옥수수)를 호화시키고, 엿기름을 첨가하여 당화한 후 농축하여 제조한 점조성의 액체로 수분이 20%정도이다. In addition, the chungcheong is a traditional food of Korea, is a viscous liquid prepared by gelatinizing starch raw material (rice, corn), saccharified by the addition of malt and is about 20% moisture.

이러한 조청은 유과를 제조할 때, 유과에 단맛과 풍미를 주고, 고명을 붙여주는 역활을 하므로 상당히 중요한 성분이다.This syrup is a very important ingredient in the production of confectionery, it gives a sweetness and flavor to the confection, and acts to give a garnish.

그리고, 상기 조청은 외기의 온도가 상승하면 조청이 녹아 흘러내림으로써 유과의 내부로 스며들어 유과의 독특한 바삭거림을 저해한다.In addition, when the temperature of the outside air rises, the crude syrup melts and flows into the interior of the fruit, thereby inhibiting the unique crispness of the fruit.

반면에, 외기의 온도가 내려가면 조청이 경화되어 유과가 너무 딱딱하게 되므로 씹힘성이 좋지 않아서 장기간 보존하여 판매하는 것이 어렵다.On the other hand, when the temperature of the outside air is lowered, the syrup is hardened and the confectionery becomes too hard, so it is difficult to chew and sell for a long time.

또한, 전분질 원료를 엿기름으로 가수분해하였을 때, 생산되는 당의 조성, 즉 단당류(포도당,과당), 이당류(맥아당) 및 다당류의 함량과 분자량 크기에 따라 당도와 점도가 상이하다.In addition, when the starch raw material is hydrolyzed with malt, the sugar and viscosity are different depending on the content and molecular weight size of the sugars produced, that is, monosaccharides (glucose, fructose), disaccharides (maltose) and polysaccharides.

따라서, 상기한 문제를 극복하고, 상품성이 좋은 유과를 생산하기 위해서는 조청의 물성이 중요한 요소이다.Therefore, in order to overcome the above-mentioned problems and to produce a good quality of fruit, the physical properties of crude syrup are an important factor.

그러나, 종래의 조청은 제조과정에 있어서 아밀라제 효소에 의하여 생성된 포도당과 맥아당 및 덱스트린 비율이 상이해 맛과, 감미도가 다르며, 또한, 기온차이에 의하여 점도와 수분과 같은 물성이 변질 됨으로써 유과에 적합한 안정된 물성을 갖춘 조청이 제조되기 어려운 문제점이 있다.However, in the conventional preparations, the ratios of glucose, maltose and dextrin produced by the amylase enzyme in the manufacturing process are different, so that taste and sweetness are different. There is a problem that is difficult to produce a crude syrup with stable physical properties.

따라서, 본 발명은 이러한 문제를 해결하기 위하여 안출된 것으로, 본 발명의 목적은 개선된 공정에 의하여 제조된 조청과 저당 물엿이 일정 비율로 서로 혼합되고, 첨가제가 첨가됨으로써 장기간 보관시에도 물성의 변질이 방지될 수 있어서 유과에 적합한 조청 혼합물 및 그 제조방법을 제공하는 것이다.Accordingly, the present invention has been made to solve such a problem, the object of the present invention is to improve the physical properties even when stored for a long time by the addition of the additives and mortar syrup prepared by an improved process in a certain ratio, additives are added This can be prevented to provide a fresh syrup mixture and a method for producing the same.

상기와 같은 본 발명의 목적을 달성하기 위하여, 본 발명은 전분질과, 물과, 액화효소와, 효소안정제가 혼합되어 호화와 액화가 진행되고, 엿기름이 첨가되어 당화됨으로써 조청이 제조되는 단계; 옥수수 전분과, 물과, 액화효소와, 효소안정제가 혼합되어 호화와 액화가 진행되고, 산이 첨가됨으로써 저당물엿이 제조되는 단계; 상기 조청이 제조되는 단계를 통하여 제조된 조청과, 상기 저장물엿이 제조되는 단계를 통하여 제조된 저당물엿을 일정 비율로 혼합하여 조청 혼합물을 제조하는 단계; 그리고 상기 조청 혼합물에 항산화제가 함유된 첨가제가 첨가되는 단계를 포함하는 조청 혼합물 제조방법을 제공한다.In order to achieve the object of the present invention as described above, the present invention comprises the steps of preparing starch syrup, water, liquefaction enzymes, enzyme stabilizers are mixed and gelatinization and liquefaction, malt is added to saccharified by mixing; Corn starch, water, liquefied enzyme, and enzyme stabilizers are mixed to gelatinize and liquefy, and acid is added to prepare low sugar syrup; Preparing a crude syrup mixture by mixing the crude syrup prepared through the step of preparing the crude syrup and the low sugar syrup prepared by the preparation of the stored syrup in a predetermined ratio; And it provides a method for preparing a crude syrup mixture comprising the step of adding an additive containing an antioxidant to the crude syrup mixture.

상기한 바와 같이, 본 발명에 따른 조청 혼합물 및 그 제조방법은 다음과 같은 장점이 있다.As described above, the present invention mixture and the preparation method according to the present invention has the following advantages.

첫째, 개선된 공정에 의하여 제조된 조청과 저당 물엿이 일정 비율로 혼합되어 조청 혼합물이 제조됨으로써, 상기 조청 혼합물은 조청의 특성인 높은 감미도가 그대로 유지될 수 있고, 동시에 저당 물엿의 특성인 높은 점성과, 높은 동결온도와, 산이나 열에 의하여 침전이나 분리가 어려운 성질이 추가됨으로써 기온차이 혹은 시간의 경과에 불구하고 물성이 안정적으로 유지될 수 있는 장점이 있다.First, the syrup prepared by the improved process is mixed with a certain ratio of syrup and mortgage syrup to prepare a syrup mixture, so that the syrup mixture can maintain high sweetness, which is a characteristic of syrup, and at the same time, high viscosity, which is a characteristic of mortar And, because of the high freezing temperature, and difficult to settle or separate by acid or heat, there is an advantage that the physical properties can be stably maintained despite the temperature difference or the passage of time.

둘째, 조청 혼합물에, 항산화제와 유기산과 유화제와 검류 등이 포함된 첨가제가 추가됨으로써, 조직감이 개선되고, 수분의 이동이 억제되고, 맛과 색깔이 우수한 장점이 있다.Second, by adding an additive containing an antioxidant, an organic acid, an emulsifier, gum and the like to the crude mixture, the texture is improved, the movement of moisture is suppressed, and the taste and color are excellent.

도 1은 본 발명의 실시예에 따른 조청 혼합물의 제조방법을 보여주는 순서도이다.1 is a flowchart showing a method for preparing a crude syrup mixture according to an embodiment of the present invention.

이하, 본 발명의 실시예에 따른 조청 혼합물 및 그 제조방법이 첨부된 도면에 의하여 상세하게 설명된다.Hereinafter, the crude syrup mixture according to an embodiment of the present invention and a manufacturing method thereof will be described in detail with reference to the accompanying drawings.

도 1에 도시된 바와 같이, 본 발명이 제안하는 조청 혼합물의 제조방법은 전분질과, 물과, 액화효소와, 효소안정제가 혼합되어 호화와 액화가 진행되고, 엿기름이 첨가되어 당화됨으로써 조청이 제조되는 단계(S100)와; 옥수수 전분과, 물과, 액화효소와, 효소안정제가 혼합되어 호화와 액화가 진행되고, 산이 첨가됨으로써 저당물엿이 제조되는 단계(S110)와; 상기 조청제조단계(S100)를 통하여 제조된 조청과, 상기 저장물엿 제조단계(S110)를 통하여 제조된 저당물엿이 일정 비율로 혼합됨으로써 조청 혼합물이 제조되는 단계(S120)와; 그리고 상기 조청 혼합물에 첨가제가 첨가되는 단계(S130)를 포함한다.As shown in Figure 1, the preparation method of the crude syrup mixture according to the present invention is prepared by mixing starch, water, liquefied enzyme, and enzyme stabilizer, gelatinization and liquefaction, malt is added to saccharification Step S100; Corn starch, water, liquefied enzymes, and enzyme stabilizers are mixed, gelatinization and liquefaction proceed, and acid is added to prepare low sugar syrup (S110); A step in which a crude syrup mixture is prepared by mixing the crude syrup prepared in the crude syrup manufacturing step (S100) and the low sugar syrup prepared in the stored syrup preparation step (S110) at a predetermined ratio (S120); And adding an additive to the crude mixture (S130).

이러한 단계로 진행되는 조청의 제조방법에 있어서, 상기 조청을 제조하는 단계(S100)는 반응조에 상기 물과, 액화효소, 및 효소 안정제를 공급하여 혼합함으로써 반응액을 제조하는 제 1단계와; 상기 제 1단계에서 제조된 상기 반응액에 전분질을 투여하여 호화 및 액화시키는 제 2단계와; 상기 제 2단계를 통하여 호화 및 액화된 반응액에 엿기름을 첨가하여 당화시킴으로써 당화액을 제조하는 제 3단계와; 그리고 상기 제 3단계를 통하여 제조된 상기 당화액이 압착, 분리되어 농축됨으로써 조청이 제조되는 제 4단계를 포함한다.In the preparation method of the crude syrup proceeding to such a step, the preparing of the crude syrup (S100) includes a first stage of preparing a reaction solution by supplying and mixing the water, a liquefied enzyme, and an enzyme stabilizer to a reaction tank; A second step of gelatinization and liquefaction by administering starch to the reaction solution prepared in the first step; A third step of preparing a saccharified liquid by adding malt to the gelatinized and liquefied reaction liquid through the second step to saccharify it; And a fourth step in which the crude syrup is prepared by pressing, separating and concentrating the saccharified solution prepared through the third step.

상기 제 1단계에서는, 상기 액화효소는 다양한 종류의 가수분해 효소를 포함할 수 있지만, 바람직하게는 α-아밀라아제(α-amylase)를 포함한다. 특히, α-아밀라아제의 한 종류인 써마밀(Termamyl)일 수 있다. In the first step, the liquefied enzyme may include various kinds of hydrolase, but preferably includes α-amylase. In particular, it may be Thermomil, which is a type of α-amylase.

그리고, 이러한 액화효소를 안정시키기 위한 효소 안정제는 염류를 포함하며, 바람직하게는 염화칼슘(CaCl2) 혹은 탄산칼슘(CaCO3)이다.And, the enzyme stabilizer for stabilizing such a liquefied enzyme includes salts, preferably calcium chloride (CaCl 2 ) Or calcium carbonate (CaCO 3 ).

이때, 상기 CaCl2 혹은 CaCO3에 대하여 액화와 당화 및 엿박에 대한 비율을 실험한 결과 효소 안정제로서 CaCl2가 더 바람직한 것으로 나타났다.At this time, the CaCl 2 Or CaCl 2 was found to be more preferable as an enzyme stabilizer when the ratio of liquefaction, saccharification and malt was tested for CaCO 3 .

상기 1단계가 완료된 후, 전분질을 반응조에 투입하는 제 2단계가 진행된다.After the first step is completed, a second step of introducing the starch into the reactor is carried out.

이때, 상기 전분질 재료로는 멥쌀 혹은 옥수수 가루를 포함한다. 이러한 전분질이 반응조에 투입되어 물과, 효소와, 효소 안정제와 일정 비율로 혼합된다. 그리고, 반응조가 40 내지 70℃로 가열됨으로써 호화반응이 진행될 수 있다. 따라서, 상기 멥쌀은 열에 의한 호화반응에 의하여 점성도가 증가하여 반투명 콜로이드 상태로 된다.In this case, the starch material includes rice or corn flour. This starch is introduced into the reaction tank and mixed with water, enzymes and enzyme stabilizers at a constant ratio. In addition, the gelatinization reaction may proceed by heating the reactor to 40 to 70 ℃. Therefore, the non-glutinous rice is increased in viscosity due to gelatinization reaction by heat to a translucent colloidal state.

그리고, 멥쌀이 호화반응에 의하여 콜로이드 상태로 제조된 후, 80 내지 98℃ 상태에서 30분 내지 3시간 동안 가열됨으로써 액화된다.Then, after the non-glutinous rice is prepared in a colloidal state by gelatinization reaction, it is liquefied by heating for 30 minutes to 3 hours at 80 to 98 ℃ state.

상기에서는 전분질 재료로서 멥쌀 혹은 옥수수 가루에 의하여 설명하였지만, 본 발명은 이에 한정되는 것은 아니고 멥쌀과 옥수수 가루를 혼합하여 사용할 수도 있다.In the above described as starch material as non-glutinous rice or corn flour, the present invention is not limited to this, and may be used by mixing non-rice and corn flour.

즉, 옥수수 가루와 멧쌀이 일정 비율로 혼합됨으로써 전분질 재료로 사용될 수 있다. 이때, 멥쌀과 옥수수 가루는 무게비율 1:9의 비율로 혼합되는 것이 바람직하다.That is, corn flour and rice are mixed in a certain ratio can be used as a starch material. At this time, non-rice and corn flour is preferably mixed in a ratio of 1: 9 weight ratio.

이와 같이, 제 2단계가 진행된 후, 액상의 멥쌀 가루가 당화됨으로써 당화액이 제조되는 제 3단계가 진행된다.As such, after the second step is performed, the third step of preparing a saccharified liquid is performed by saccharifying liquid non-rice flour.

이러한 제 3단계에서는, 반응조의 내부에 엿기름이 투입됨으로써 반응액이 당화될 수 있다.즉, 반응액이 50 내지 73℃ 온도범위에서 6 내지 9시간 동안 가열됨으로써 당화되어 당화액이 제조될 수 있다.In this third step, the reaction solution may be saccharified by introducing malt into the reaction tank. That is, the reaction solution may be saccharified by heating for 6 to 9 hours in a temperature range of 50 to 73 ° C., thereby preparing a saccharified solution. .

이때, 상기 반응액의 반응온도가 50 내지 73℃ 온도범위 이하인 경우, 온도가 낮아서 충분한 당화반응이 진행되기 어렵고, 상기 온도범위 이상인 경우, 엿기름이 고온의 열에 의하여 손실될 수 있다. 따라서, 반응액의 온도는 상기 50 내지 73℃ 온도가 바람직하다.At this time, when the reaction temperature of the reaction solution is less than the temperature range of 50 to 73 ℃, it is difficult to proceed sufficient saccharification reaction because the temperature is low, and when the temperature is above the temperature range, malt may be lost by high temperature heat. Therefore, the temperature of the reaction solution is preferably 50 to 73 ℃ temperature.

이와 같이 제 3단계가 완료되면, 제 4단계가 진행된다. 즉, 제 4단계에서는 당화액이 여과되고, 진공농축된 후 냉각됨으로써 조청이 제조될 수 있다.As such, when the third step is completed, the fourth step proceeds. That is, in the fourth step, the saccharified solution is filtered, concentrated in vacuo, and the crude syrup may be prepared by cooling.

상기한 공정을 통하여 조청이 제조된 후, 저당 물엿이 제조되는 단계(S110)가 진행될 수 있다.After the crude syrup is manufactured through the above process, a step (S110) of preparing a mortgage syrup may be performed.

상기 저당물엿이 제조되는 단계(S110)는 물과, 액화효소와, 효소 안정제가 공급되어 혼합됨으로써 반응액이 제조되는 제 5단계와; 상기 제 5단계에서 제조된 상기 반응액에 옥수수 전분이 투입되어 호화 및 액화되는 제 6단계와; 상기 제 6단계를 통하여 호화 및 액화된 반응액에 산이 첨가되어 pH가 조절되는 제 7단계와; 그리고 상기 제 7단계를 통하여 제조된 반응액이 압착, 분리되어 농축됨으로써 저당물엿이 제조되는 제 8단계를 포함한다.The step of preparing the low sugar syrup (S110) includes a fifth step of preparing a reaction solution by supplying water, a liquefied enzyme, and an enzyme stabilizer; A sixth step of adding corn starch to the reaction solution prepared in the fifth step to gelatinize and liquefy; A seventh step of adjusting acid by adding an acid to the gelatinized and liquefied reaction solution through the sixth step; And an eighth step of preparing the low-sugar syrup by pressing, separating and concentrating the reaction solution prepared through the seventh step.

상기 제 5단계에서는, 상기 반응조의 내부에 물과, 옥수수 전분을 가수분해하기 위한 액화효소와, 상기 액화효소를 안정시키기 위하여 칼슘이온의 공급원인 효소 안정제가 투입되어 혼합된다.In the fifth step, water, a liquefied enzyme for hydrolyzing corn starch, and an enzyme stabilizer, which is a source of calcium ions, are added and mixed into the reactor to stabilize the liquefied enzyme.

이때, 상기 액화효소는 다양한 종류의 가수분해 효소를 포함할 수 있지만, 바람직하게는 α-아밀라아제(α-amylase)를 포함한다. 특히, α-아밀라아제의 한 종류인 써마밀(Termamyl)일 수 있다. In this case, the liquefied enzyme may include various kinds of hydrolase, but preferably includes α-amylase. In particular, it may be Thermomil, which is a type of α-amylase.

그리고, 이러한 효소를 안정시키기 위한 효소 안정제는 염류, 바람직하게는 염화칼슘(CaCl2) 혹은 탄산칼슘(CaCO3)가 적용가능하지만, 바람직하게는 CaCl2를 포함한다.In addition, enzyme stabilizers for stabilizing such enzymes are preferably salts, preferably calcium chloride (CaCl 2 ). Or calcium carbonate (CaCO 3 ) Applicable but preferably comprises CaCl 2 .

상기 5단계가 완료된 후, 옥수수 전분이 반응조에 투입되는 제 6단계가 진행된다.After the fifth step is completed, a sixth step of introducing the corn starch into the reactor is carried out.

보다 상세하게 설명하면, 상기 옥수수 전분이 반응조에 투입되어 물과, 효소와, 효소 안정제와 일정 비율로 혼합된다. 그리고, 반응조가 40 내지 70℃로 가열됨으로써 호화반응이 진행될 수 있다.In more detail, the corn starch is introduced into the reaction tank and mixed with water, an enzyme, and an enzyme stabilizer at a constant ratio. In addition, the gelatinization reaction may proceed by heating the reactor to 40 to 70 ℃.

이때, 상기 호화반응 온도가 40 내지 70℃ 범위 이하인 경우, 옥수수 전분의 점성도가 낮게 되고, 상기 온도 범위 이상인 경우, 옥수수 전분의 점성도가 높게 된다.At this time, when the gelatinization temperature is in the range of 40 to 70 ℃, the viscosity of the corn starch is low, and if the temperature range or more, the viscosity of the corn starch is high.

따라서, 상기 옥수수 전분은 바람직하게는 상기 40 내지 70℃ 범위에서 호화반응이 진행됨으로써 반투명 콜로이드 상태로 된다. Therefore, the corn starch is preferably translucent colloidal state by gelatinization in the range of 40 to 70 ℃.

그리고, 옥수수 전분이 호화반응에 의하여 콜로이드 상태로 제조된 후, 80 내지 98℃ 상태에서 4 내지 9시간 동안 가열됨으로써 액화될 수 있다.After the corn starch is prepared in a colloidal state by gelatinization, the corn starch may be liquefied by heating at 80 to 98 ° C. for 4 to 9 hours.

상기 액화온도가 80 내지 98℃ 이하인 경우에는 콜로이드 상태의 옥수수 전분이 충분히 액화되기 어렵고, 상기 온도 이상인 경우에는 옥수수 전분이 고열로 인하여 정상적인 조직을 유지하기 어려워 안정적인 액화가 이루어질 수 없다.When the liquefaction temperature is 80 to 98 ℃ or less, it is difficult to sufficiently liquefy the colloidal corn starch, when the liquefaction temperature is higher than the temperature it is difficult to maintain a normal tissue due to high heat can not be made a stable liquefaction.

이와 같이, 제 6단계에서는 옥수수 전분이 반응조에 투입되어 호화 및 액화반응이 진행될 수 있다.As such, in the sixth step, corn starch may be added to the reaction tank to proceed with gelatinization and liquefaction.

상기 제 6단계가 진행된 후, 반응액에 산이 첨가됨으로써 pH가 적절하게 조절되는 제 7단계가 진행된다.After the sixth step is performed, a seventh step of adjusting the pH appropriately is performed by adding acid to the reaction solution.

이러한 제 7단계에서는 산, 바람직하게는 염산(HCl)이 반응액에 첨가됨으로써 pH가 5.5로 유지된다.In this seventh step, an acid, preferably hydrochloric acid (HCl), is added to the reaction solution to maintain a pH of 5.5.

이와 같이 제 7단계가 완료되면, 제 8단계가 진행된다. 즉, 산이 첨가된 반응액이 여과되고, 진공 농축된 후, 냉각됨으로써 저당 물엿이 제조될 수 있다.As such, when the seventh step is completed, the eighth step proceeds. That is, the sugar-containing syrup can be prepared by filtering the acid-added reaction solution, concentrating in vacuo, and cooling.

상기와 같이, 조청제조단계(S100)와 물엿제조단계(S110)를 통하여 조청과 물엿이 각각 제조된 후, 상기 조청과 물엿을 서로 혼합하여 조청 혼합물을 제조하는 단계(S120)가 진행된다.As described above, after the crude syrup and syrup were prepared through the preparation of syrup (S100) and the syrup preparation stage (S110), the preparation of the syrup mixture was performed by mixing the syrup and syrup to each other (S120).

상기 조청 혼합물 제조단계(S120)에서는 조청 30 내지 60중량%와, 물엿 40 내지 70중량%가 혼합된다.In the preparation of the crude syrup mixture (S120), 30 to 60 wt% of the crude syrup and 40 to 70 wt% of starch syrup are mixed.

조청과 물엿과 첨가제를 상기의 비율로 서로 혼합하였을 경우, 아래의 실험예에서 볼 수 있듯이, 맛, 기온차 변화, 조직감 등의 물성이 우수함을 알 수 있다.When the crude syrup, starch syrup and the additives are mixed with each other in the above ratio, as can be seen in the following experimental example, it can be seen that the physical properties such as taste, temperature difference change, texture.

상기 조청 혼합물의 제조 단계(S120) 후, 첨가제가 첨가되는 단계(S130)가 진행된다.After the step of preparing the crude mixture (S120), the step of adding an additive (S130) proceeds.

상기 첨가제는 항산화제와, 유기산과, 유화제와, 검류와, 조직 개량제를 포함한다.The additives include antioxidants, organic acids, emulsifiers, gums, and tissue improvers.

이때, 상기 첨가제의 각 성분들은 서로 일정 비율로 혼합된다. 바람직하게는 조청 혼합물 100중량부에 대하여 항산화제 0.1 내지 0.9중량부와, 유기산 0.1 내지 0.9중량부와, 유화제 0.1 내지 0.9중량부와, 검류 0.1 내지 0.9중량부와, 조직 개량제 2.1 내지 6중량부의 비율로 혼합된다. At this time, each component of the additive is mixed with each other in a predetermined ratio. Preferably 0.1 to 0.9 parts by weight of antioxidant, 0.1 to 0.9 parts by weight of organic acid, 0.1 to 0.9 parts by weight of emulsifier, 0.1 to 0.9 parts by weight of gum, and 2.1 to 6 parts by weight of tissue modifier Mixed in proportions.

이러한 첨가제에 있어서, 상기 항산화제는 디부틸히드록시톨루엔(BHT: dibutyl hydroxy toluene)과, 부틸히드록시아니솔(BHA: butyl hydroxy anisole)과, 터셔리부틸히드로퀴논(TBHQ: tert-butyl hydroquinone)과, DL-a- 토코페놀(AL-a_tocopherol)과, 에리소르빈산(Erythorbc acid) 및 에리소르빈산나트륨(Sodium erythorbc acid)과, L- 아스코르빈산(L-ascorbic acid), L-아스코르빈산나트륨(Sodium L-ascorbate),아스코르빈산칼슘(Calcium L-ascorbate) 등을 포함한다.In such additives, the antioxidant is dibutyl hydroxy toluene (BHT), butyl hydroxy anisole (BHA), tert-butyl hydroquinone (TBHQ) and , DL-a-tocopherol (AL-a_tocopherol), erythorbc acid and sodium erythorbc acid, L-ascorbic acid, and L-ascorbic acid ( Sodium L-ascorbate), calcium ascorbate (Calcium L-ascorbate) and the like.

따라서, 상기 항산화제는 조청 혼합물의 산화 및 변색을 방지함으로써 유과의 장기간 보관이 가능한 효과가 있다.Therefore, the antioxidant has an effect that can be stored for a long time by preventing the oxidation and discoloration of the crude mixture.

그리고, 상기 유기산은 카르복시산(RCOOH), 설폰산(RSO3H), 페놀(ArOH) 등 여러 종류의 화합물을 포함한다.The organic acid may include various kinds of compounds such as carboxylic acid (RCOOH), sulfonic acid (RSO 3 H), and phenol (ArOH).

이러한 유기산은 상기 항산화제와 더블어 조청 혼합물이 장기간 보관이 가능하도록 한다.These organic acids allow the long term storage of the antioxidant and doubler crude texture.

상기 유화제는 레시틴과(Lecithin), 폴리소르 베이트(Polysorbate)와, 글리세린 지방산 에스테르(Glycerin Esters of Fatty Acids)와, 자당 지방산 에스테르(Sucrose fatty acid ester)와, 폴리 인산나트륨(Sodiumpolyphosphate)과, 카제인 나트륨(Sodium Caseinate)과, 구연산 나트륨(Sodium Citrate) 등 여러 종류의 화합물을 포함한다.The emulsifier is lecithin, polysorbate, glycerin fatty acid esters, sucrose fatty acid esters, sodium polyphosphate, casein sodium And various kinds of compounds such as sodium caseinate and sodium citrate.

이러한 유화제가 조청 혼합물에 첨가됨으로써 각 성분들이 균일하게 혼합될 수 있다.Such emulsifiers may be added to the crude mixture to ensure that each component is mixed evenly.

그리고, 상기 검류는 물과 결합하여 점성용액이나 겔을 형성하는 친수성 물질이다. 이러한 검류는 아라비아검(Gum arabic), 트라가칸트검(Tragacanth gum), 카라야검(Gum karaya), 로커스트콩검(Locust bean gum), 크산탄검(Xanthan gum), 구아검(Gum guar), 한천, 알긴산(Alginic acid), 카라기난(Carageenan), 덱스트란(Dextran)등, 여러 종류를 포함한다.The gum is a hydrophilic substance that binds to water to form a viscous solution or gel. These gums include gum arabic, tragacanth gum, gum karaya, locust bean gum, xanthan gum, gum guar, and agar. , Alginic acid, carageenan, dextran, etc.

상기 유화제와 검류가 조청 혼합물에 첨가됨으로써 수분의 이동억제 및 조직감의 개선이 이루어질 수 있다.By adding the emulsifier and gum to the crude syrup mixture, it is possible to suppress the migration of moisture and to improve the texture.

또한, 상기 조직 개량제(Texturizers)는 각 성분들의 결착력을 증대시키고, 맛과 식감을 향상시키며, 탄력성 및 팽창성 등 조직을 개량시키고, 식품의 변색 및 변질을 방지할 수 있다. In addition, the texture improvers (Texturizers) can increase the binding capacity of each component, improve the taste and texture, improve the tissue such as elasticity and swelling, and can prevent discoloration and deterioration of food.

이러한 조직 개량제는 피로인산염(Pyrophosphate)과, 폴리인산염(Polyphosphate)과, 메타인산염(Metaphosphate)과, 인산염(Phosphate)과, 폴리 덱스트로오스(Ploydextrose) 등을 포함한다.Such tissue modifiers include pyrophosphate, polyphosphate, metaphosphate, phosphate, polydextrose, and the like.

이와 같이, 조청과 저당물엿의 혼합물에 첨가제가 일정 비율로 혼합됨으로써 산화방지와, 조직감과, 수분 이동억제 등의 물성이 개선될 수 있다.As such, by adding an additive to the mixture of the crude syrup and the low sugar syrup, the physical properties such as oxidation prevention, texture, and moisture migration inhibition may be improved.

또한, 조청과 저당 물엿이 서로 혼합되어 조청 혼합물을 구성함으로써 조청과 저장물엿의 장점이 모두 구현될 수 있다. In addition, the benefits of the crude syrup and the stored syrup may be realized by mixing the crude syrup and the mortgage syrup to form a syrup mixture.

즉, 상기 조청의 특성인 높은 감미도와, 저당물엿의 특성인 높은 점성과, 높은 동결온도와, 산이나 열에 의하여 침전이나 분리가 어려운 성질이 추가됨으로써 기온차이 혹은 시간의 경과에 불구하고 물성이 안정적으로 유지될 수 있다.In other words, the high sweetness characteristic of the crude syrup, the high viscosity characteristic of the low sugar syrup, the high freezing temperature, and the difficulty of sedimentation or separation by acid or heat are added, thereby making the physical properties stable despite the temperature difference or the passage of time. Can be maintained.

또한, 상기 첨가제가 첨가됨으로써, 조직감이 개선되고, 수분의 이동이 억제되고, 맛과 색깔이 우수한 효과가 있다.In addition, by the addition of the additive, the texture is improved, the movement of moisture is suppressed, there is an effect excellent in taste and color.

따라서, 상기의 비율로 혼합된 조청 혼합물은 조청의 당조성의 변화가 적으며, 유과 제조에 적합한 물성을 갖는다.Therefore, the crude syrup mixture mixed at the above ratio has little change in the sugar composition of the crude syrup, and has suitable physical properties for the production of fruit.

〈실시예〉<Example>

1. 조청 제조1. manufacturer of syrup

반응조에 물과, 액화효소로서 써마밀과, 효소 안정제로서 염화칼슘(CaCl2)을 공급하여 혼합함으로써 반응액을 제조하고, 제조된 상기 반응액에 멥쌀가루를 투여하고 반응조를 60℃로 가열하여 호화시키고, 92℃로 2시간 액화시키고, 호화 및 액화된 반응액을 63℃로 냉각시킨 후 엿기름을 첨가하고, 반응액을 60 내지 63℃ 온도범위에서 8시간 동안 가열하고, 염산을 첨가하여 당화액을 제조하고, 상기 당화액을 압착, 분리하여 102℃에서 5시간 동안 진공농축함으로써 조청을 제조한다. The reaction solution was prepared by supplying water to the reaction tank, thermomil as a liquefied enzyme, and calcium chloride (CaCl 2 ) as an enzyme stabilizer, and mixing the mixture, administering non-glutinous rice flour to the prepared reaction solution, and heating the reaction tank to 60 ° C. , 2 hours liquefied, the gelatinized and liquefied reaction solution was cooled to 63 ℃, malt is added, the reaction solution was heated for 8 hours in the temperature range of 60 to 63 ℃, hydrochloric acid was added to the saccharified solution To prepare the crude syrup by pressing and separating the saccharified solution and vacuum concentrating at 102 ° C. for 5 hours.

이때, 상기 물은 멥쌀 가루 대비 1.5배의 중량비이고, Ca 농도는 80ppm, 액화pH는 6.2, 효소농도는 2.4㎏/corn grits, 엿기름 0.75%/corn grits, 당화 pH는 5.5를 유지한다.
At this time, the water is 1.5 times the weight ratio of non-rice flour, Ca concentration is 80ppm, liquefied pH is 6.2, enzyme concentration is 2.4kg / corn grits, malt 0.75% / corn grits, saccharification pH is maintained at 5.5.

2. 저당물엿 제조2. Manufacture of mortgage syrup

반응조에 옥수수 전분과, 물과, 액화효소로서 써마밀과, 효소 안정제로서 염화칼슘(CaCl2)을 혼합하여 반응액을 제조하고, 상기 반응액에 옥수수 전분을 투입하여 60℃에서 가열하여 호화시키고, 92℃로 6시간 액화시키고, 호화 및 액화된 반응액에 산을 첨가하여 pH를 조절하고, 반응액을 압착, 분리하여 농축시킴으로써 저당물엿이 제조된다.Corn starch, water, thermomil as a liquefied enzyme and calcium chloride (CaCl 2 ) as an enzyme stabilizer were mixed to prepare a reaction solution. Corn starch was added to the reaction solution and heated at 60 ° C. for gelatinization. 92 Lactose syrup is prepared by liquefying at 6 ° C. for 6 hours, adding acid to the gelatinized and liquefied reaction solution to adjust pH, and compressing and separating the reaction solution.

이때, 물은 옥수수 전분 대비 중량비 1.33로 혼합하고, 전분농도는 75%이고, 효소농도는 1㎏/corn grits, Ca 농도는 70ppm, 액화pH는 6.2를 유지한다.
At this time, the water is mixed with a weight ratio of 1.33 to corn starch, starch concentration is 75%, enzyme concentration is 1kg / corn grits, Ca concentration is 70ppm, liquefied pH is maintained at 6.2.

3. 조청과 저장물엿의 혼합3. Mixing of syrup and stored syrup

이와 같이 제조된 조청과 저장물엿을 서로 혼합한다. 즉, 저당물엿 60%와, 조청 35%의 비율로 서로 혼합한다.
The crude syrup and the stock syrup thus prepared are mixed with each other. That is, 60% of the mortgage syrup and 35% of the crude syrup are mixed with each other.

4. 첨가제의 혼합4. Mixing of additives

상기 조청 혼합물에 첨가제를 혼합하며, 상기 첨가제는 조청 혼합물 100중량부에 대하여 항산화제 0.2중량부와, 유기산 0.2중량부와, 유화제 0.2중량부와, 검류 0.3중량부와, 조직 개량제 4.1중량부의 비율로 혼합한다.
The additive is mixed with the crude syrup mixture, wherein the additive is a ratio of 0.2 parts by weight of antioxidant, 0.2 parts by weight of organic acid, 0.2 parts by weight of emulsifier, 0.3 parts by weight of gum, and 4.1 parts by weight of tissue modifier. Mix with.

〈비교예1∼2〉<Comparative Examples 1 and 2>

상기 실시예의 조청제조단계와 동일한 성분 및 과정으로 제조하였고, 다만, Ca농도와, 액화pH와, 당화도와 엿박의 조건을 아래의 표1과 같이 각각 달리하여 비교하였다.
Prepared with the same ingredients and processes as the preparation of the present preparation of the above example, except that Ca concentration, liquefied pH, and saccharification and malt condition were compared to each other as shown in Table 1 below.

〈비교예3 ∼4〉<Comparative Examples 3 to 4>

상기 실시예의 저당 물엿 제조단계와 동일한 과정으로 제조하였고, 다만, 전분농도와, 효소농도와, Ca 농도와, 액화pH의 조건을 아래의 표2와 같이 달리하여 비교하였다.
It was prepared in the same process as the preparation step of mortgage syrup of the above embodiment, except that starch concentration, enzyme concentration, Ca concentration, and liquefied pH conditions were compared as shown in Table 2 below.

〈비교예5〉〈Comparative Example 5〉

상기 실시예에 의하여 제조된 조청과 저장 물엿을 서로 혼합한 후, 첨가제를 첨가한 경우와, 종래의 제조공정에 의하여 제조되고 첨가제가 첨가되지 않은 조청에 대하여 점도와 수분의 변화를 아래의 표3과 같이 비교하였다.The changes in viscosity and moisture of the crude syrup prepared according to the above example and the crude syrup prepared by adding the additive after the mixing of the syrup and the stored starch syrup were prepared by the conventional manufacturing process and the additive was not added. Comparison was made as follows.

〈실험예1〉Experimental Example 1

본 실험예 1에서는 상기 실시예의 제조공정에 의하여 제조된 조청과 비교예1의 제조공정에 의하여 제조된 조청의 Ca농도와, 액화 pH와, 당화 pH를 달리하여 당화율과 엿박을 비교하였다.In Experimental Example 1, the concentration of Ca and the saccharification of the crude syrup prepared by the manufacturing process of Example 1 and the prepared syrup prepared by Comparative Example 1 were compared, and the saccharification rate and the sugar content were compared.

Ca 농도Ca concentration 액화효소
pH
Liquefied enzyme
pH
액화liquefaction 엿기름
pH
malt
pH
당화도Glycation degree 엿박Fucked
pHpH BrixBrix pHpH BrixBrix 실험예1Experimental Example 1 8080 6.206.20 6.116.11 3636 5.55.5 5.245.24 3737 15.3015.30 비교예1Comparative Example 1 5050 6.206.20 6.106.10 3535 5.55.5 5.215.21 3636 16.3016.30 비교예2Comparative Example 2 110110 6.206.20 6.116.11 3636 5.55.5 5.285.28 3636 16.5016.50

즉, 상기 표1에서 알 수 있는 바와 같이, Ca농도를 80ppm과, 액화 pH 6.2, 당화 pH를 5.5로 설정한 경우, 다른 대조군 1 및 2와 비교하여 당화율이 37브릭스로 양호하였고, 엿박도 15.3%로 가장 낮았다. 따라서, 상기 실시예의 경우, 상기 조건으로 조청을 제조하였다.
That is, as can be seen in Table 1, when the Ca concentration is set to 80ppm, liquefaction pH 6.2, saccharification pH is set to 5.5, the saccharification rate was 37 brix good compared to the other controls 1 and 2, and the degree of morbidity The lowest was 15.3%. Thus, in the case of the above embodiment, the crude syrup was prepared under the above conditions.

〈실험예2〉Experimental Example 2

본 실험예 2에서는 상기 실시예의 제조공정에 의하여 제조된 저당물엿과 비교예2의 제조공정에 의하여 제조된 저장물엿의 전분농도와, 효소농도와, Ca 농도와, 액화pH를 달리하여 비교하였다.In Experimental Example 2, starch concentration, enzyme concentration, Ca concentration, and liquefied pH of the low sugar starch syrup prepared by the manufacturing process of Example and the storage starch prepared by the manufacturing process of Comparative Example 2 were compared.


옥수수전분농도
Corn Starch Concentration
효소농도Enzyme concentration 효소 반응
온도
Enzyme reaction
Temperature
Ca농도Ca concentration 액화 pHLiquefaction pH 액상Liquid
BrixBrix DEDE 실험예2Experimental Example 2 75%75% 1.01.0 92℃92 ℃ 7070 6.26.2 5656 2323 비교예3Comparative Example 3 60%60% 0.80.8 8585 6060 6.26.2 5252 2121 비교예4Comparative Example 4 50%50% 0.60.6 7575 5050 6.26.2 5050 1616

상기 표2에서 알 수 있는 바와 같이, 옥수수 전분농도를 75%로, 효소농도를 1.0으로, 효소반응온도를 92℃로, Ca농도를 70ppm으로, 액화 pH를 6.2로 설정한 경우, 다른 조건과 비교하여 당화율이 56브릭스로 양호하였고, DE(Dextrose Equivalent)도 23으로 적절하였다. 따라서, 상기 실시예의 저당물엿은 상기한 조건으로 제조하였다.
As can be seen in Table 2 above, when the corn starch concentration is 75%, the enzyme concentration is 1.0, the enzyme reaction temperature is 92 ° C, the Ca concentration is 70 ppm, and the liquefaction pH is set to 6.2, In comparison, saccharification was good at 56 brix and DE (Dextrose Equivalent) at 23. Therefore, the mortgage syrup of the above example was prepared under the above conditions.

〈실험예3〉Experimental Example 3

본 실험예 3에서는 상기 실시예에 의하여 제조된 저당 물엿과 조청을 저장 물엿 60%와, 조청 35%의 비율로 서로 혼합하고, 첨가물 5%를 첨가하여 제조된 조청 혼합물과 종래의 조청을 비교하여, 온도에 따른 점도의 변화를 측정하였다.In Experimental Example 3, the mortgage syrup prepared by the above example and the crude syrup were mixed with each other at a ratio of 60% of the stored syrup and 35% of the syrup. The change of viscosity with temperature was measured.

점도의 측정은 Brookfield 점도계에 의하여 측정하였다. 즉, 조청 혼합물에 스핀들을 담그고 회전시킴으로써 토르크(torque)를 측정하였으며, 점도는 cps로 나타내었다. The measurement of the viscosity was measured with a Brookfield viscometer. That is, the torque was measured by dipping and rotating the spindle in the crude mixture, and the viscosity was expressed in cps.

-5℃-5 ℃ 10℃10 ℃ 15℃15 ℃ 20℃20 ℃ 25℃25 ℃ 30℃30 ℃ 35℃35 ℃ 실험예3Experimental Example 3 941941 972972 982982 997997 10021002 10051005 10121012 비교예5Comparative Example 5 11241124 10891089 10511051 975975 920920 908908 887887

상기 표 3에서 알 수 있는 바와 같이, 본 실시예에 따른 조청 혼합물은 온도의 변화에 따라 점도의 변화가 적었다. 즉, 여름과 같이 고온인 경우와, 겨울과 같이 저온인 경우 점도의 변화가 적음을 알 수 있다.As can be seen in Table 3, the crude syrup mixture according to this embodiment had a small change in viscosity with a change in temperature. That is, it can be seen that the change in viscosity is small when the temperature is high as in summer and when the temperature is low as in winter.

반면에, 종래에 따른 조청의 경우, 여름과 겨울에 있어서 점도의 변화가 큰 것을 알 수 있다.On the other hand, it can be seen that in the case of the conventional syrup, the change in viscosity is large in summer and winter.

따라서, 종래의 유과는 여름철에 조청이 흘러내리고, 겨울에는 경화되어 딱딱해지는 반면에, 본 실시예에 따른 조청 혼합물은 여름이나 겨울에도 큰 차이가 없다.
Therefore, while the conventional yoghurt in the summer season, the fresh syrup flows down, and in winter, hardened and hardened, whereas the fresh syrup mixture according to the present embodiment does not have a big difference in summer or winter.

〈실험예4〉Experimental Example 4

본 실험예 4에서는 상기 실시예에 의하여 제조된 저당물엿과 조청을 저당물엿 60%와, 조청 35%의 비율로 서로 혼합하고, 첨가물 5%를 첨가하여 제조된 조청 혼합물과, 종래의 제조공정에 의하여 제조된 조청에 있어서, 시간 경과에 따른 수분함량을 측정하였다.In Experimental Example 4, the molasses syrup and the crude syrup prepared according to the above example were mixed with each other at a ratio of 60% mortgage syrup and the crude syrup 35%, and the crude syrup mixture prepared by adding an additive 5% to the conventional manufacturing process In the prepared syrup, the moisture content was measured over time.

수분의 함량 측정방법은 증발접시에 정제해사를 5-10g놓고 초자봉(길이 약 5cm)과 같이 105℃에서 항량을 구한 후 시료 약 5g을 물 중탕위에서 건조시킨 다음 105℃의 항온 건조기에 항량을 구하여 백분율(%)로 나타내었다. To measure the water content, place 5-10 g of purified nasa on an evaporating dish, obtain a constant dose at 105 ° C, such as chojabong (about 5 cm in length), and then dry about 5 g of the sample in a water bath. Obtained as a percentage (%).

0일0 days 7일7 days 14일14 days 21일21st 28일28 days 35일35 days 42일42 days 실험예4Experimental Example 4 20.0220.02 20.0120.01 19.5819.58 19.5719.57 19.5319.53 18.5118.51 18.5018.50 비교예5Comparative Example 5 49.1549.15 42.1142.11 39.2539.25 35.1435.14 31.0131.01 30.0930.09 30.0130.01

상기 표 4에서 알 수 있는 바와 같이, 본 실시예에 따른 조청 혼합물은 초기의 수분함량도 적고, 시간이 경과함에 따른 수분함량의 변화도 영향이 없었다. As can be seen in Table 4, the crude syrup mixture according to the present embodiment had a small initial moisture content, and there was no change in moisture content with time.

반면에, 종래의 조청은 초기의 수분함량이 많고, 시간이 경과함에 따라 수분의 함량도 현저하게 감소함을 알 수 있다.On the other hand, it can be seen that the conventional syrup contains a large amount of initial moisture and significantly decreases the moisture content as time passes.

즉, 본 실시예에 따른 조청 혼합물은 초기 수분함량이 적고, 유과의 표면에 도포된 경우에도 시간이 경과에 따라 수분이 증감되지 않음으로, 수분의 이동이 억제됨으로써 유과의 물성을 오래도록 유지할 수 있다.That is, the crude syrup mixture according to the present embodiment has a low initial moisture content, and even when applied to the surface of the fruit, the moisture does not increase or decrease with time, and thus the movement of moisture is suppressed, thereby maintaining the physical properties of the fruit. .

반면, 종래 조청의 경우에는 초기 수분함량이 많음으로 유과의 표면에 도포하는 경우, 흘러내리기 쉽고, 또한, 시간이 경과함에 따라 급속하게 경화가 진행됨으로써 유과의 물성이 변질될 수 있다.
On the other hand, in the case of conventional syrup, when it is applied to the surface of the fruit fruit due to the high initial moisture content, it is easy to flow down, and the physical properties of the fruit fruit may be changed by rapid curing as time passes.

〈실험예5〉<Experiment 5>

본 실험예 5에서는 상기 실시예에 의하여 제조된 저당물엿 60%와, 조청을 35%의 비율로 서로 혼합한 후, 첨가제를 첨가하여 제조된 조청 혼합물과, 종래의 조청에 있어서, 관능검사에 의하여 시간의 경과에 따른 조직감과, 색깔과, 맛을 측정하였다.In Experimental Example 5, 60% of the molten sugar syrup prepared according to the above example and the crude syrup were mixed with each other at a ratio of 35%, and the crude syrup mixture prepared by adding an additive, and in the conventional syrup, The texture, color and taste were measured over time.

측정방법은 일반 성인 100명을 대상으로 조직감과, 색깔과, 맛을 기호도 검사법의 이점 기호검사법으로 측정하여 그 평균값을 하기 표 5에 나타내었다.The measurement method is the texture, color, and taste of 100 general adults measured by the preference test method advantage of taste test method The average value is shown in Table 5 below.

구분division 실험예5Experimental Example 5 비교예5Comparative Example 5 14일14 days 조직감Organization 4.24.2 3.53.5 color 4.34.3 4.24.2 flavor 4.54.5 4.14.1 28일28 days 조직감Organization 4.64.6 3.73.7 color 4.54.5 4.14.1 flavor 4.84.8 3.93.9 42일42 days 조직감Organization 4.64.6 3.43.4 color 4.14.1 4.04.0 flavor 4.24.2 3.53.5

(1:매우 나쁨, 2:나쁨, 3:보통, 4:좋음, 5:매우 좋음)(1: very bad, 2: bad, 3: medium, 4: good, 5: very good)

상기 표 5에서 알 수 있는 바와 같이, 본 실시예에 따른 조청 혼합물은 첨가제를 첨가함으로써 유화제와 검류 성분에 의하여 조직감과 색과 맛이 좋음을 알 수 있다.As can be seen in Table 5, it is seen that the texture of the texture of the present preparation is good texture, color and taste by the emulsifier and gum components by adding the additive.

반면에, 종래의 조청은 첨가제가 첨가되지 않음으로써 조직감과, 색과, 맛에 있어서 본 실시예에 비교하여 열등함을 알 수 있다.On the other hand, it can be seen that the conventional syrup is inferior to the present embodiment in texture, color, and taste because no additive is added.

S100: 조청 제조단계 S110: 저당물엿 제조단계
S120: 조청 혼합물 제조단계 S130: 첨가제 첨가단계
S100: crude syrup manufacturing step S110: mortgage syrup manufacturing step
S120: preparation of the crude syrup mixture S130: additive addition

Claims (9)

전분질과, 물과, 액화효소와, 효소안정제가 혼합되어 호화와 액화가 진행되고, 엿기름이 첨가되어 당화됨으로써 조청이 제조되는 단계;
옥수수 전분과, 물과, 액화효소와, 효소안정제가 혼합되어 호화와 액화가 진행되고, 산이 첨가됨으로써 저당물엿이 제조되는 단계;
상기 조청이 제조되는 단계를 통하여 제조된 조청과, 상기 저장물엿이 제조되는 단계를 통하여 제조된 저당물엿을 일정 비율로 혼합하여 조청 혼합물을 제조하는 단계; 그리고
상기 조청 혼합물에 항산화제가 함유된 첨가제가 첨가되는 단계를 포함하는 조청 혼합물 제조방법.
Preparing starch syrup by mixing starch, water, liquefied enzyme, and enzyme stabilizer to gelatinization and liquefaction, and malt added to saccharify it;
Corn starch, water, liquefied enzyme, and enzyme stabilizers are mixed to gelatinize and liquefy, and acid is added to prepare low sugar syrup;
Preparing a crude syrup mixture by mixing the crude syrup prepared through the step of preparing the crude syrup and the low sugar syrup prepared by the preparation of the stored syrup in a predetermined ratio; And
A method of preparing a syrup mixture comprising adding an additive containing an antioxidant to the syrup mixture.
멥쌀가루와, 물과, 아밀라제와, 염화칼슘(CaCl2)가 혼합되어 호화와 액화가 진행되고, 엿기름이 첨가되어 당화됨으로써 조청이 제조되는 단계;
옥수수 전분과, 물과, 아밀라제와, 염화칼슘(CaCl2)가 혼합되어 호화와 액화가 진행되고, 산이 첨가됨으로써 저당물엿이 제조되는 단계;
상기 조청 제조단계를 통하여 제조된 조청과, 상기 저장물엿 제조단계를 통하여 제조된 저당물엿이 조청 30 내지 60중량%와, 물엿 40 내지 70중량%의 비율로 혼합되어 조청 혼합물이 제조되는 단계;
상기 조청 혼합물 100중량부에 대하여 첨가제로서 항산화제 0.1 내지 0.9중량부와, 유기산 0.1 내지 0.9중량부와, 유화제 0.1 내지 0.9중량부와, 검류 0.1 내지 0.9중량부와, 조직 개량제 2.1 내지 6중량부의 비율로 혼합되는 단계를 포함하는 것을 특징으로 하는 조청 제조방법.
Non-glutinous rice, water, amylase, and calcium chloride (CaCl 2 ) are mixed to gelatinize and liquefy, and maltose is added to saccharification to prepare crude syrup;
Corn starch, water, amylase, calcium chloride (CaCl 2 ) is mixed and gelatinization and liquefaction proceed, the acid is added to prepare a low sugar syrup;
Preparing a crude syrup mixture by mixing the crude syrup prepared through the preparation of the crude syrup and the low sugar syrup which is prepared through the preparation of the stored syrup, in a ratio of 30 to 60% by weight of syrup and 40 to 70% by weight of syrup;
0.1 to 0.9 parts by weight of antioxidant, 0.1 to 0.9 parts by weight of organic acid, 0.1 to 0.9 parts by weight of emulsifier, 0.1 to 0.9 parts by weight of gum, and 2.1 to 6 parts by weight of tissue modifier as additives based on 100 parts by weight of the crude syrup mixture Method for producing a bird syrup comprising the step of mixing at a ratio.
제 1항에 있어서,
상기 조청을 제조하는 단계는 반응조에 상기 물과, 액화효소, 및 효소 안정제가 공급되어 혼합됨으로써 반응액이 제조되는 제 1단계와;
상기 제 1단계에서 제조된 상기 반응액에 멥쌀가루가 투입되어 호화 및 액화반응이 진행되는 제 2단계와;
상기 제 2단계를 통하여 호화 및 액화된 상기 반응액에 엿기름이 첨가되어당화됨으로써 당화액이 제조되는 제 3단계와; 그리고
상기 제 3단계를 통하여 제조된 상기 당화액이 압착, 분리되어 농축됨으로써 조청 혼합물이 제조되는 제 4단계를 포함하는 조청 혼합물 제조방법.
The method of claim 1,
The step of preparing the crude syrup comprises a first step in which a reaction solution is prepared by supplying and mixing the water, the liquefied enzyme, and the enzyme stabilizer to a reaction tank;
A second step in which non-glutinous rice powder is added to the reaction solution prepared in the first step to conduct gelatinization and liquefaction;
A third step of preparing a saccharified liquid by adding malt to the reaction liquid that is gelatinized and liquefied through the second step; And
A method of preparing a syrup mixture comprising a fourth stage of preparing a syrup mixture by compressing, separating, and concentrating the saccharified solution prepared through the third stage.
제 1항에 있어서,
상기 저당물엿을 제조하는 단계는 상기 옥수수 전분과, 물과, 액화효소와, 효소 안정제가 공급되어 혼합됨으로써 반응액이 제조되는 제 5단계와;
상기 제 5단계의 상기 반응액에 옥수수 전분이 투입되어 호화 및 액화되는 제 6단계와;
상기 제 6단계를 통하여 호화 및 액화된 반응액에 산이 첨가되어 pH가 조절되는 제 7단계와; 그리고
상기 제 7단계를 통하여 제조된 반응액이 압착, 분리되어 농축됨으로써 조청 혼합물이 제조되는 제 8단계를 포함하는 조청 혼합물 제조방법.
The method of claim 1,
The step of preparing the low-sugar starch syrup comprises a fifth step in which the reaction solution is prepared by supplying and mixing the corn starch, water, liquefied enzyme and enzyme stabilizer;
A sixth step of adding corn starch to the reaction solution of the fifth step to gelatinize and liquefy;
A seventh step of adjusting acid by adding an acid to the gelatinized and liquefied reaction solution through the sixth step; And
A method of preparing a crude syrup mixture comprising an eighth stage of preparing a crude syrup mixture by compressing, separating, and concentrating a reaction solution prepared through the seventh stage.
제 1항에 있어서,
상기 액화효소는 α-아밀라제를 포함하며, 상기 효소 안정제는 염화칼슘(CaCl2)을 포함하는 조청 혼합물 제조방법.
The method of claim 1,
Said liquefied enzyme comprises α-amylase, and said enzyme stabilizer comprises calcium chloride (CaCl2).
제 2항에 있어서,
상기 조청제조단계에서, 물은 멥쌀가루 대비 중량비 1.5로 혼합하고, 상기 효소 안정제의 농도는 80ppm, 액화pH는 6.2, 상기 α-아밀라제는 2.4㎏/corn grits, 액화온도는 92℃, 액화시간은 2시간, 상기 엿기름의 당화도는 0.75%/corn grits, 당화 pH는 5.5, 당화온도는 60-63℃, 당화시간은 8시간을 유지하여 조청을 제조하는 것을 특징으로 하는 조청 제조방법.
The method of claim 2,
In the preparation of the syrup, water was mixed at a weight ratio of 1.5 to non-glutinous rice flour, the concentration of the enzyme stabilizer was 80 ppm, the liquefied pH was 6.2, the α-amylase was 2.4 kg / corn grits, the liquefaction temperature was 92 ° C, and the liquefaction time was 2 hours, saccharification of the malt is 0.75% / corn grits, saccharification pH is 5.5, saccharification temperature is 60-63 ℃, saccharification time characterized in that to prepare the crude syrup to maintain the 8 hours.
제 4항에 있어서,
상기 물은 옥수수 전분 중량비 1.33로 혼합하고, 전분농도는 75%이고, 효소농도는 1㎏/corn grits, α-아밀라제는 70ppm, 액화pH는 6.2, 액화온도는 92℃를 유지하여 저당물엿을 제조하는 것을 특징으로 하는 조청 제조방법.
The method of claim 4, wherein
The water was mixed with a corn starch weight ratio of 1.33, the starch concentration was 75%, the enzyme concentration was 1 kg / corn grits, α-amylase was 70 ppm, the liquefied pH was 6.2, and the liquefaction temperature was maintained at 92 ° C. to prepare a low sugar syrup. Method for producing a bird syrup characterized in that.
제 1항에 있어서,
상기 조청 혼합물 제조단계에서는 상기 조청 30 내지 60중량%와, 상기 물엿 40 내지 70중량%의 비율로 혼합되어 조청 혼합물이 제조되고, 상기 조청 혼합물 100중량부에 대하여 첨가제로서 항산화제 0.1 내지 0.9중량부와, 유기산 0.1 내지 0.9중량부와, 유화제 0.1 내지 0.9중량부와, 검류 0.1 내지 0.9중량부와, 조직 개량제 2.1 내지 6중량부의 비율로 혼합되는 것을 특징으로 하는 조청 제조방법.
The method of claim 1,
In the preparation of the crude syrup mixture, the crude syrup mixture is prepared by mixing 30 to 60 wt% of the crude syrup and 40 to 70 wt% of the starch syrup, and 0.1 to 0.9 parts by weight of an antioxidant as an additive based on 100 parts by weight of the crude syrup mixture. And 0.1 to 0.9 parts by weight of an organic acid, 0.1 to 0.9 parts by weight of an emulsifier, 0.1 to 0.9 parts by weight of gum, and 2.1 to 6 parts by weight of a tissue improving agent.
전분질과, 물과, 액화효소와, 효소안정제가 혼합되어 호화와 액화가 진행되고, 엿기름이 첨가되어 당화됨으로써 조청이 제조되고,
옥수수 전분과, 물과, 액화효소와, 효소안정제가 혼합되어 호화와 액화가 진행되고, 산이 첨가됨으로써 저당물엿이 제조되고,
상기 조청 제조단계를 통하여 제조된 조청과, 상기 저장물엿 제조단계를 통하여 제조된 저당물엿이 조청 30 내지 60중량%와, 물엿 40 내지 70중량%의 비율로 혼합되어 조청 혼합물이 제조되고,
상기 조청 혼합물 100중량부에 대하여 첨가제로서 항산화제 0.1 내지 0.9중량부와, 유기산 0.1 내지 0.9중량부와, 유화제 0.1 내지 0.9중량부와, 검류 0.1 내지 0.9중량부와, 조직 개량제 2.1 내지 6중량부의 비율로 혼합되는 것을 특징으로 하는 조청 혼합물.
Starch, water, liquefied enzyme, and enzyme stabilizer are mixed to gelatinize and liquefy, and maltose is added to saccharify to prepare crude syrup.
Corn starch, water, liquefied enzyme and enzyme stabilizer are mixed, gelatinization and liquefaction proceed, acid is added, and low sugar syrup is produced.
The crude syrup mixture is prepared by mixing the crude syrup prepared through the preparation of the crude syrup and the low sugar syrup which is prepared through the preparation of the stored syrup, in a ratio of 30 to 60% by weight of syrup and 40 to 70% by weight of syrup.
0.1 to 0.9 parts by weight of antioxidant, 0.1 to 0.9 parts by weight of organic acid, 0.1 to 0.9 parts by weight of emulsifier, 0.1 to 0.9 parts by weight of gum, and 2.1 to 6 parts by weight of tissue modifier as additives based on 100 parts by weight of the crude syrup mixture A crude syrup mixture, characterized in that mixed in proportion.
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KR20170084770A (en) * 2016-01-13 2017-07-21 농업회사법인 주식회사 두레촌 Red-pepper Paste Using Grain Syrup, and Method for Manufacturing the Same
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