KR20110077835A - Method of manufacturing functional master batch - Google Patents
Method of manufacturing functional master batch Download PDFInfo
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- KR20110077835A KR20110077835A KR1020090134500A KR20090134500A KR20110077835A KR 20110077835 A KR20110077835 A KR 20110077835A KR 1020090134500 A KR1020090134500 A KR 1020090134500A KR 20090134500 A KR20090134500 A KR 20090134500A KR 20110077835 A KR20110077835 A KR 20110077835A
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- A—HUMAN NECESSITIES
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- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/20—Fabaceae or Leguminosae [Pea or Legume family], e.g. pea, lentil, soybean, clover, acacia, honey locust, derris or millettia
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- A—HUMAN NECESSITIES
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- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
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- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/06—Coniferophyta [gymnosperms], e.g. cypress
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- A—HUMAN NECESSITIES
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- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/12—Asteraceae or Compositae [Aster or Sunflower family], e.g. daisy, pyrethrum, artichoke, lettuce, sunflower, wormwood or tarragon
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/22—Lamiaceae or Labiatae [Mint family], e.g. thyme, rosemary, skullcap, selfheal, lavender, perilla, pennyroyal, peppermint or spearmint
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/24—Lauraceae [Laurel family], e.g. laurel, avocado, sassafras, cinnamon or camphor
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/26—Meliaceae [Chinaberry or Mahogany family], e.g. mahogany, langsat or neem
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/28—Myrtaceae [Myrtle family], e.g. teatree or clove
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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Abstract
Description
본 발명은 병해충방제와 유해동물 퇴치기능이 있는 기능성 마스터배치 (master batch)의 제조방법에 관한 것이다.The present invention relates to a method for preparing a functional master batch having pest control and pest control function.
현재 전국 시군구의 지방자치단체에서 각각 색상별로 제공하고 있는 쓰레기종량제봉투는 일반적으로 주원료인 폴리에틸렌(PE)수지에 착색안료인 마스터배치를 첨가제로 혼합하여 쓰레기종량제봉투를 제조하였는데 이는 마스터배치가 단순히 칼라색상만을 내는데 불과하기 때문에 이러한 쓰레기봉투에 생활쓰레기와 음식물이 섞여 담겨져 버려질 경우 여름철에 음식물찌꺼기가 쉽게 부패되어 파리, 모기, 바퀴벌레 등의 해충이 쓰레기봉투 안에 들끓게 되고 파리가 산란한 구더기로 인해 악취가 심하게 나는 문제점이 있었고, 또한 고양이, 쥐, 들개 등 야생동물이 쓰레기종량제봉투를 찢고 들어가 봉투 내의 음식물을 먹음으로 해서 주변환경이 오염되고 위생상 청결하지 못한 문제점이 있었으며, 찢겨진 봉투에서 나온 생활쓰레기와 각종 오물 등이 길바닥에 흩어져 있게 되어 이를 수거해야 하는 환경미화원들은 쓰레기수거에 항상 큰 어려움을 겪어야 하는 문제점이 있었다.Currently, the municipal waste-based bags, which are provided by the local municipalities in each country, are produced by mixing the master batches, which are colored pigments, with additives in polyethylene (PE) resin, which is the main raw material. Since only the color is produced, when garbage and food are mixed in the garbage bags, food waste easily rots in summer, causing pests such as flies, mosquitoes, and cockroaches to soak in the garbage bags, and the odor from the maggots scattered. There was a problem that I had a severe problem, and also the wild animals such as cats, mice, dogs, etc., torn into the trash bag and ate food in the bags, contaminating the surrounding environment and sanitary cleanliness, and living garbage from the torn bags. And various dirts Street cleaners have been able to collect scattered on the floor, it had a problem that always suffer great difficulties in waste collection.
종래 착색제로 사용되고 있는 마스터배치(master batch)는 착색하려고 하는 폴리에틸렌수지(LDPE, LLDPE, HDPE, PP, ABS, PVC 등)에 분말이나 액상상태의 칼라안료를 혼합하여 쓰레기종량제봉투를 제조하게 되는데, 여기에 사용되는 마스터배치는 자체수분이 많아 주원료인 수지와 혼합성형이 어려울 뿐만 아니라 혼련성(混練性)도 좋지 않아 원하는 색상의 폴리에틸렌(PE) 제품을 제조할 수가 없었고, 특히 병해충방제와 유해동물 퇴치기능이 있는 하나의 복합적인 마스터배치는 제공된 바가 없었다. The master batch used as a conventional colorant (batch) is to produce a waste-based bag by mixing the color pigments of powder or liquid state with polyethylene resin (LDPE, LLDPE, HDPE, PP, ABS, PVC, etc.) to be colored, The masterbatch used here has a lot of moisture in itself, which makes it difficult to form and mix with the main raw resin, and also has poor kneading properties, making it impossible to produce polyethylene (PE) products of desired color, especially pest control and harmful animals. There was no single masterbatch with combat function provided.
이에 따라, 최근에는 쓰레기종량제봉투 제조시 주원료인 폴리에틸렌(PE)수지에 첨가 혼합되는 마스터배치는 칼라착색제로서의 혼련성이 좋고 병해충방제와 유해동물 퇴치기능을 갖는 친환경적인 복합적 기능의 마스터배치가 제공되어야 하는 것이 절실히 요구되고 있는 것이다.Accordingly, in recent years, the master batch added to the polyethylene (PE) resin, which is the main raw material in the manufacture of the waste-based encapsulation bag, has to be provided with a masterbatch of an eco-friendly complex function having good kneading as a color coloring agent and controlling pests and harmful animals. It is desperately required.
본 발명은 이와 같은 종래 쓰레기종량제봉투의 문제점을 해결하기 위하여 개발된 것으로서 본 발명에 의해 제조되는 마스터배치 중 병해충방제용 마스터배치는 식물성추출물(고삼, 제충국, 님, 로테논, 어성초 등)에서 한 가지와 칼라착색제(흑색, 적색, 청색, 황색, 녹색 등)에서 한 가지를 선택하여 선택된 이들 두 가지 첨가제를 주원료인 폴리에틸렌(PE)수지에 일정비율로 혼합을 하여 입상형태의 팁(원주형, 각주형, 원형)으로 성형된 마스터배치로 제조를 하고, 유해동물 퇴치용 마스 터배치는 식물성추출물(유카리투스향, 민트향, 계피향, 솔잎향, 편백향 등)에서 한 가지와 칼라착색제(연두색, 청색, 녹색, 주황색, 흑색, 유백색)에서 한 가지를 선택하여 선택된 이들 두 가지의 첨가제를 주원료인 폴리에틸렌(PE)수지에 일정 비율로 혼합을 하여 입상형태의 팁(원주형, 각주형, 원형)으로 성형된 마스터배치로 제조하는 것이다.The present invention was developed in order to solve the problems of the conventional waste-based weighing bag, the master batch prepared for pest control in the masterbatch prepared by the present invention is made from vegetable extracts (gosam, worm, nip, rotenone, eoseongcho, etc.) Branches and color pigments (black, red, blue, yellow, green, etc.) are selected by mixing one of these two additives in a certain proportion to the polyethylene (PE) resin, the main raw material, the shape of the tip (cylindrical, Manufactured with masterbatch molded into square shape, round shape, and masterbatch for combating harmful animals is made from vegetable extract (Eucaritus flavor, mint flavor, cinnamon flavor, pine needle flavor, cypress flavor, etc.) and color pigment ( Yellow, Blue, Green, Orange, Black, Milky White) .The two additives are selected and mixed in proportion to the main raw polyethylene (PE) resin. It is made of a masterbatch molded into the tip of the fetus (cylindrical, prismatic, circular).
이와 같은 본 발명의 마스터배치가 혼합되어 제조되는 병해충방제 기능이 있는 쓰레기종량제봉투는 곰팡이, 세균, 바이러스의 살균 및 항균효과가 있는 식물성추출물 첨가제(고삼, 제충국, 님, 로테논, 어성초 등)가 첨가되어 제조되기 때문에 쓰레기봉투에 담겨진 음식물찌꺼기와 각종 오물로 인한 악취 및 병해충의 기생과 서식을 방제하고 병해충의 접근을 기피하게 하는 효과가 있어 쓰레기집하장의 주변환경오염을 방지할 수가 있는 것이며, 또한 유해동물 퇴치기능이 있는 쓰레기종량제봉투는 유해동물의 접근을 기피하게 하는 식물성추출물 첨가제(유카리투스향, 민트향, 계피향, 솔잎향, 편백향 등)가 첨가되어 제조되기 때문에 유해동물이 접근하여 음식물찌꺼기와 각종 오물이 담겨져 있는 쓰레기종량제봉투를 찢고 훼손시키는 것을 방지할 수가 있어 쓰레기집하장과 주변환경을 항상 청결히 할 수 있는 효과가 있는 것으로서, 본 발명은 비닐하우스에 사용되는 농업용 필름에도 적용시켜 병해충방제와 유해동물 퇴치기능이 있는 농업용 필름으로 널리 공급할 수가 있는 것이다.Such a waste pesticide bag with a pest control function produced by mixing the master batch of the present invention is a plant extract additive (Ginseng, Pyrethrum, Nim, Rotenone, Eochocho, etc.) having fungicides, bacteria and viruses. It is added and manufactured to prevent the parasitic and habitat of odors and pests caused by food waste and various wastes contained in garbage bags, and to avoid the access of pests and to prevent the environmental pollution of garbage dumps. Waste quantitative bags with the ability to combat harmful animals are manufactured by adding vegetable extract additives (eucaritus, mint, cinnamon, pine needle, cypress, etc.) to avoid the access of harmful animals. Prevent tearing and damaging the garbage-based bag containing food waste and various wastes. As it is in effect can always clean the litter carrier hub and the surrounding environment, the present invention is to apply to agricultural films used for greenhouses that can be widely used to supply agricultural films with Vermin extermination and pest control function.
이하 본 발명의 제조방법을 실시예에 의하여 상세히 설명하면 다음과 같다.Hereinafter, the manufacturing method of the present invention will be described in detail with reference to Examples.
[실시예][Example]
1. 병해충방제 기능이 있는 마스터배치 제조방법1. Master batch production method with pest control function
(실시예 1)(Example 1)
폴리에틸렌(PE)수지 55중량%에 식물성추출물 첨가제(고삼, 제충국, 님, 로테논, 어성초 중 한가지 선택) 20중량%와 칼라착색제(흑색, 적색, 청색, 황색, 녹색 중 한가지 선택) 25중량%를 혼합한 후 압출기 호퍼에 투입하여 호퍼 내의 온도를 50~70℃로 유지한 상태에서 4~6분간 혼련시킨 후 혼련된 혼합물을 160~180℃의 마스터배치 성형용 압출기에 투입하여 다이를 통해 압출시킨 다음 20~40℃의 냉각수조에서 냉각시키고 회전식 절단기에 의해 2~5mm 정도의 원주형, 각주형, 원형의 기능성 복합첨가제인 병해충방제 기능이 있는 마스터배치(master batch)를 제조한다.55% by weight of polyethylene (PE) resin, 20% by weight of vegetable extract additives (choose of red ginseng, wormwood, nymph, rotenone, fishery) and 25% by weight of colorant (black, red, blue, yellow, green) After mixing the mixture into the extruder hopper and kneaded for 4-6 minutes while maintaining the temperature in the hopper at 50 ~ 70 ℃, the kneaded mixture is put into the master batch molding extruder of 160 ~ 180 ℃ extruded through the die After cooling in a 20 ~ 40 ℃ cooling water tank, a master batch having a pest control function, which is a cylindrical, square, and circular functional compound additive of about 2-5 mm, is prepared by a rotary cutter.
(실시예 2)(Example 2)
폴리에틸렌(PE)수지 70중량%에 식물성추출물 첨가제(고삼, 제충국, 님, 로테논, 어성초 중 한가지 선택) 10중량%와 칼라착색제(흑색, 적색, 청색, 황색, 녹색 중 한가지 선택) 20중량%를 혼합한 후 압출기 호퍼에 투입하여 호퍼 내의 온도를 50~70℃로 유지한 상태에서 4~6분간 혼련시킨 후 혼련된 혼합물을 160~180℃의 마스터배치 성형용 압출기에 투입하여 다이를 통해 압출시킨 다음 20~40℃의 냉각수조에서 냉각시키고 회전식 절단기에 의해 2~5mm정도의 원주형, 각주형, 원형의 기능성 복합첨가제인 병해충방제 기능이 있는 마스터배치(master batch)를 제조한다.70% by weight of polyethylene (PE) resin, 10% by weight of vegetable extract additives (choose from red ginseng, wormwood, nymph, rotenone, fishery) and 20% by weight of colorant (choice of black, red, blue, yellow, green) After mixing the mixture into the extruder hopper and kneaded for 4-6 minutes while maintaining the temperature in the hopper at 50 ~ 70 ℃, the kneaded mixture is put into the master batch molding extruder of 160 ~ 180 ℃ extruded through the die After cooling in a 20 ~ 40 ℃ cooling water tank, a master batch with pest control function, which is a cylindrical, square, and circular functional compound additive of about 2 ~ 5 mm, is prepared by a rotary cutter.
2. 유해동물 퇴치기능이 있는 마스터배치 제조방법2. Manufacturing method of masterbatch with harmful animal fighting function
(실시예 1)(Example 1)
폴리에틸렌(PE)수지 55중량%에 식물성추출물 첨가제(유카리투스향, 민트향, 계피향, 솔잎향, 편백향 중 한가지 선택) 20중량%와 칼라착색제(흑색, 적색, 청색, 황색, 녹색 중 한가지 선택) 25중량%를 혼합한 후 압출기 호퍼에 투입하여 호퍼 내의 온도를 50~70℃로 유지한 상태에서 4~6분간 혼련시킨 후 혼련된 혼합물을 160~180℃의 마스터배치 성형용 압출기에 투입하여 다이를 통해 압출시킨 다음 20~40℃의 냉각수조에서 냉각시키고 회전식 절단기에 의해 2~5mm 정도의 원주형, 각주형, 원형의 기능성 복합첨가제인 유해동물 퇴치기능이 있는 마스터배치(master batch)를 제조한다.55% by weight of polyethylene (PE) resin, 20% by weight of vegetable extract additives (choose one of eucalyptus, mint, cinnamon, pine needles, and cypress) and colorant (black, red, blue, yellow, green) Optional) After mixing 25% by weight, add the mixture into the extruder hopper for 4-6 minutes while maintaining the temperature in the hopper at 50-70 ° C, and then add the kneaded mixture to the master batch molding extruder of 160-180 ° C. Extruded through a die and then cooled in a 20 ~ 40 ℃ cooling water tank, and a master batch with the elimination of harmful animals, which is a cylindrical, square, and circular functional compound additive of about 2 ~ 5mm by a rotary cutter. To prepare.
(실시예 2)(Example 2)
폴리에틸렌(PE)수지 70중량%에 식물성추출물 첨가제(유카리투스향, 민트향, 계피향, 솔잎향, 편백향 중 한가지 선택) 10중량%와 칼라착색제(흑색, 적색, 청색, 황색, 녹색 중 한가지 선택) 20중량%를 혼합한 후 압출기 호퍼에 투입하여 호퍼 내의 온도를 50~70℃로 유지한 상태에서 4~6분간 혼련시킨 후 혼련된 혼합물을 160~180℃의 마스터배치 성형용 압출기에 투입하여 다이를 통해 압출시킨 다음 20~40℃의 냉각수조에서 냉각시키고 회전식 절단기에 의해 2~5mm 정도의 원주형, 각주형, 원형의 기능성 복합첨가제인 유해동물 퇴치기능이 있는 마스터배치(master batch)를 제조한다.70% by weight of polyethylene (PE) resin, 10% by weight of vegetable extract additives (choose one of eucharitus, mint, cinnamon, pine needles, and cypress) and colorant (black, red, blue, yellow, green) Optional) After mixing 20% by weight, add the mixture to the extruder hopper and knead for 4 to 6 minutes while maintaining the temperature in the hopper at 50 to 70 ° C., and then add the kneaded mixture to the master batch molding extruder at 160 to 180 ° C. Extruded through a die and then cooled in a 20 ~ 40 ℃ cooling water tank, and a master batch with the elimination of harmful animals, which is a cylindrical, square, and circular functional compound additive of about 2 ~ 5mm by a rotary cutter. To prepare.
상기와 같이 제조되는 본 발명의 마스터배치는 폴리에틸렌(PE)수지에 식물성 추출물 첨가제와 칼라착색제의 3가지 원료를 혼합하여 기능성 복합첨가제인 하나의 마스터배치로 제조하는 것이므로, 쓰레기종량제봉투나 농업용 필름 제조시 주원료인 폴리에틸렌(PE)수지에 일정량의 마스터배치를 첨가하여 압출이나 사출공법으로 병해충방제 기능과 유해동물 퇴치기능이 있는 친환경적인 쓰레기종량제봉투를 제조하는 것이다.Since the master batch of the present invention prepared as described above is prepared by mixing three raw materials of a vegetable extract additive and a color coloring agent in a polyethylene (PE) resin to produce a single masterbatch which is a functional compound additive, so as to produce a waste weighing bag or agricultural film It is to produce eco-friendly garbage-based bags with pest control function and pest control function by extruding or injection method by adding a certain amount of masterbatch to polyethylene (PE) resin which is the main raw material of city.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2014010769A1 (en) * | 2012-07-13 | 2014-01-16 | 주식회사 티엘론 | Mat having function of repelling pest insects, and method for manufacturing same |
KR20190011930A (en) * | 2017-07-26 | 2019-02-08 | 주식회사 포이엔 | Vegetation base material product having pest control function |
KR20190011928A (en) * | 2017-07-26 | 2019-02-08 | 주식회사 포이엔 | Synthetic resin composition having pest control function and manufacturing method thereof |
KR102006309B1 (en) | 2018-08-08 | 2019-08-01 | 김영희 | Repellent and manufacturing method thereof |
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2009
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2014010769A1 (en) * | 2012-07-13 | 2014-01-16 | 주식회사 티엘론 | Mat having function of repelling pest insects, and method for manufacturing same |
CN104321179A (en) * | 2012-07-13 | 2015-01-28 | 天论株式会社 | Mat having function of repelling pest insects, and method for manufacturing same |
KR20190011930A (en) * | 2017-07-26 | 2019-02-08 | 주식회사 포이엔 | Vegetation base material product having pest control function |
KR20190011928A (en) * | 2017-07-26 | 2019-02-08 | 주식회사 포이엔 | Synthetic resin composition having pest control function and manufacturing method thereof |
KR102006309B1 (en) | 2018-08-08 | 2019-08-01 | 김영희 | Repellent and manufacturing method thereof |
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