KR20110007564U - chemical heat generated body coercion heated regenerative a heating apparatus - Google Patents

Abstract

The present invention has a lid (7) formed with an exhaust port (7a), the opening 11 is opened to the upper portion is formed and the receiving space portion (A) formed therein, the heating element (A) to the heating element When the exothermic reaction is received and chemically exothermic, and the heat of reaction generated at this time is transferred to the outside of the body, and the exothermic reaction is completed, the waste heat generating solution is led to the solution discharge pipe 12 provided at the lower side and discharged to the outside. A reaction vessel (10) comprising (13); An auxiliary container 20 which is inserted and detachably inserted into the accommodation space A, and has a plurality of through holes 20a formed on the side and bottom of the container, and accommodates the heat generating metal body; A heating element (30) comprising a heat generating metal body (30a) and a heat generating material (30S) for heating the low temperature water contained in the water storage tank (50) by being accommodated in the accommodation space (A); The solution inlet tube 41 and the solution are connected to the assembly hole (10a) formed on the upper end side of the body of the reaction vessel 10 and the solution storage tank (T) so that the exothermic material 30S in the solution state is introduced into the reaction vessel. On and off valve 40 for opening and closing the inlet pipe 41; The reaction vessel 10 includes a body, and forms a closed space outside the reaction vessel 10 to fill and store the low temperature water introduced into the drain pipe 51 provided at the bottom, and stores the stored low temperature water in the reaction vessel. A water tank 50 heated to a high temperature by 10 and discharged to the outside through a water supply pipe 52 provided at an upper portion thereof; A bypass pipe 61 connected from the upper portion U of the water storage tank 50 to the lower portion L; And a circulation pump 62 connected to the bypass pipe 61 for forcibly circulating high temperature hot water present in the upper portion U of the reservoir 50 to the lower portion L of the reservoir 50. A circulation member 60; It provides a regenerative heater that is heated by the heat of chemical reaction that is made of a structure comprising more.
Furthermore, a hot water heater (70) (80) for introducing a portion of the low temperature water stored in the water storage tank (50) to the structure, and rapidly heating the isolated low temperature water; is provided.
According to the above technology, heat can be generated through chemical reaction without fire, and heat loss can be minimized, and thermal efficiency can be maximized. By being able to use the same, the effect of shortening the time required to heat and heat the low temperature water is provided.

Description

Chemical heat generated body coercion heated regenerative a heating apparatus}

The present invention is built in the container formed so as to heat the low-temperature water filled in the water tank of the heating facility to replace the heat generating metal body as a heating element, and chemically exothermic reaction by supplying a heating material from the outside to contact each other when necessary It is possible to heat and accumulate the water in the reservoir by the reaction heat generated at this time, and furthermore, by forcibly circulating the heated water of the reservoir to shorten the heat storage time, and to isolate a part of the low temperature water in one place and rapidly heat it. It is to provide a regenerative heater that is heated by the heat of the chemical reaction to enable the room to be heated.

In general, a regenerative boiler or a blower is a heater that heats a space in various facilities or a general home, and the boiler uses a fossil fuel such as briquettes, oil, and gas, or heat and heat to heat the medium and heat the heated heat transfer medium. In addition to circulating and blowing air, the indoor heating is performed by using latent heat of the heated heat transfer medium.

In related technology, in Korean Patent Registration No. 20-0216374, the oil boiler and the electric boiler are connected in parallel so as to share one heating water pipe, so as to configure one boiler device, and also the two heterogeneous boilers, the electric boiler and the oil. A boiler for electric and oil combined heating, which has a structure in which a boiler becomes a boiler having a single body, reheats hot water introduced through an oil boiler inlet to a higher temperature than the inside of an electric boiler, and flows out through an outlet of the electric boiler. In the Republic of Korea Patent Registration No. 20-0241525 and a firewood boiler equipped with a combustion chamber and blister; It is connected to a supply line for supplying a liquid heat medium such as heated water or heat medium oil in a blister of the firewood boiler and a circulation line in which a circulation pump for supplying a liquid heat medium requiring heating to a blister is provided. A heat storage tank to which a heating line is connected; An external controller for controlling the circulation pump between the firewood boiler and the heat storage tank according to the heat medium temperature of the blister; A regenerative firewood boiler comprising an internal controller for controlling a circulation pump of the heating line is disclosed. In Korean Patent Publication No. 20-2011-0002161, a boiler using livestock waste fuel is a mixture of livestock waste and sawdust. Fuel is introduced into the combustion chamber, and the injected fuel burns inside, the burner mounted in the combustion chamber to ignite the injected fuel, the storage unit for storing the fuel, and the storage unit and the combustion chamber are connected to each other to discharge the fuel discharged from the storage unit. There is disclosed a boiler using livestock excrement fuel composed of a conveying unit which is transferred to a combustion chamber. In Korean Patent Registration No. 20-0438245, a heating unit is installed to heat the heating water inside the heat storage tank body frame using the heat medium of the solar collector. Heat exchange with the hot heating water heated in the heating unit In the heat storage tank structure of the solar boiler including a heat exchanger consisting of a heat exchanger for heating and hot water on the upper side of the inside, the heating unit, the coil tube is wound around the heat exchanger configured on the upper side of the body frame to heat the heating water hot A heat storage tank structure of a solar boiler including a first heating part and a second heating part for heating a heating water by winding a coiled tube in an inner lower side of the body frame is disclosed, and in Korean Patent Registration No. 20-0350591 The electric power is usually charged in the battery, and the DC motor is rotated using it. The electric power obtained by driving the quantitative generator with this rotational power is used to accumulate a plurality of heating coils to increase the temperature of the hot water and the heating water, thereby heating the heating pipe and the water supply pipe. By supplying hot water, you can economically solve the heating and hot water supply of the building An electric boiler which suppresses waste of energy and prevents a power outage due to overload is disclosed. In Korean Patent Registration No. 0223088, cold and hot water storage heated by an electric heater operated by a midnight electricity or cooled by an ice storage device is provided. A temperature controller is installed between the tank and the cold and heating pipe (heat radiator) to circulate the room. It is supplied with cold and heating piping (heat radiator) after being adjusted to. Also, the cold and hot water inside the cold and hot water storage tanks can be cooled and heated by using the same piping and heat radiating device to reduce facility costs and reduce maintenance costs. A regenerative cooling and heating device using a late-night electric power is disclosed. In Korea Patent Registration Room No. 20-0339349, the It is equipped with a plurality of geothermal heat exchange pipes to use geothermal heat from the geothermal heat exchange pipes in the heating and cooling heat pump as a heat source of the evaporator to supply the hot water produced in the condenser to the heating and cooling place, the cooling and heating heat pump A heat exchange circuit unit configured to discharge the condenser generated in the ground to the geothermal heat exchange pipes; The heat exchange circuit unit is installed between the heating and cooling heat pump and the heating and cooling place, and the cold or hot water from the heating and cooling heat pump to warm or cool with a predetermined cold and hot heat at midnight power to store and supply to the cooling and heating place without interruption. Disclosed is a heat storage heat pump system using geothermal heat including a cold / hot water heat storage tank.

As such, various heat sources are used as energy for heating the inside of the facility, and research is being conducted on developing another heat source.

Therefore, the present inventors focus on the heating element technology used for heating food by generating heat by chemical reaction without fire, and research on the application of the heating element to heat storage type heaters such as boilers and blowers under optimized conditions. Proceed to, the present invention was completed by confirming that heat can be generated by heating the reservoir water of the heater by generating heat through a chemical reaction without fire.

The present invention is built in the container formed to heat the low-temperature water filled in the reservoir of the heating facility to replace the exothermic metal body as a heating element, supplying the heating material whenever needed to chemically exothermic reaction It is an object of the present invention to provide a regenerative heater that is heated by the heat of chemical reaction to heat the water of the reservoir by the generated reaction heat.

Another object of the present invention is to provide a regenerative heater heated by chemical reaction heat in which a mechanism for forcibly supplying and circulating heated hot water present in an upper portion of a reservoir is provided.

Another object of the present invention is to heat a separate portion of the low-temperature water in one place, the heat storage by the heat of chemical reaction that the mechanism is provided to diffuse the hot water is rapidly heated in an isolated state in the top of the reservoir To provide.

The present invention for achieving the above object is built in the container formed so as to heat the low-temperature water filled in the reservoir of the heating facility to replace the heat generating metal body as a heating element, supplying a heating material from the outside whenever necessary By providing a chemical exothermic reaction to heat the water in the reservoir by the reaction heat generated at this time to provide a heat storage heater that is heated by the heat of chemical reaction.

Another object of the present invention is to provide a regenerative heater heated by chemical reaction heat provided with a mechanism for forcibly supplying and circulating heated hot water present in an upper portion of a reservoir.

Another object of the present invention is to provide a regenerative heater that can be heated by isolating a portion of the cold water in one place, and is heated by chemical reaction heat provided a mechanism for diffusing hot water heated in isolation into the upper part of the reservoir. .

By implementing the technology of the regenerative heater heated by the chemical reaction heat of the present invention, the heat loss is minimized and the thermal efficiency is maximized, so that the low temperature water of the reservoir can be heated to high temperature hot water in a short time and can be immediately used for heating. By being able to continue to use it provides the effect of reducing the time required to heat and heat the cold water.

1 is a longitudinal cross-sectional view and an operation diagram showing a regenerative heater heated by chemical reaction heat according to an embodiment of the present invention.
Figure 2 is an exploded perspective view schematically showing a process for embedding the auxiliary vessel and the exothermic metal body applied to the present invention into the reaction vessel.
Figure 3 is an exploded perspective view schematically showing a process for further mounting the network container into the auxiliary container applied to the present invention.
Figure 4 is an exploded perspective view schematically showing a process for forming an absorbent fabric between the auxiliary container and the heat generating metal body applied to the present invention.
5 is an exploded perspective view schematically illustrating a process of inserting and sealing a heat generating metal body applied to the present invention into an absorbent fabric bag;
Figure 6 is a perspective view schematically showing to explain the incision of a portion of the sealed packaging container by inserting the heating material applied to the present invention.
7 is a perspective view schematically showing the cutting line formed between each cell after the insertion and sealing the heating material applied to the present invention in a packaging container consisting of a plurality of cells.
Figure 8 is a longitudinal cross-sectional view and an operation diagram showing a regenerative heater is heated by the heat of chemical reaction according to another embodiment of the present invention.
Figure 9 is a longitudinal cross-sectional view showing the operation of the heat storage heater is heated by the heat of chemical reaction according to another embodiment of the present invention.

Hereinafter, the configuration of the present invention based on the accompanying drawings.

First, referring to the attached Figures 1 to 12,

1 is a longitudinal sectional view showing a heat storage type heater heated by chemical reaction heat according to an embodiment of the present invention and its operation, Figure 2 is a secondary vessel and a heat generating metal body applied to the present invention built into the reaction vessel 3 is an exploded perspective view schematically illustrating a process of performing the same, FIG. 3 is an exploded perspective view schematically illustrating a process of additionally mounting a network container into an auxiliary container applied to the present invention, and FIG. 5 is an exploded perspective view schematically illustrating a process of forming an absorbent fabric between the auxiliary container and the heat generating metal body, and FIG. 5 is a process of inserting and sealing the heat generating metal body applied to the present invention in an absorbent fabric bag. Is an exploded perspective view schematically shown to explain, Figure 6 is inserted into the heating material applied to the present invention is sealed 7 is a perspective view schematically showing to cut a part of the entertaining container, Figure 7 illustrates the cutting edge of the cutting line formed between each cell after inserting and sealing the heating material applied to the present invention in a packaging container consisting of a plurality of cells form Figure 8 is a perspective view schematically shown for the purpose, Figure 8 is a longitudinal cross-sectional view and operation diagram showing a regenerative heater is heated by the heat of chemical reaction according to another embodiment of the present invention, Figure 9 is another embodiment of the present invention The longitudinal cross-sectional view which shows the regenerative heater heated by the chemical reaction heat by is also an operation figure.

First, as shown in Fig. 1, 2, the regenerative heater heated by the heat of chemical reaction according to the embodiment of the present invention has a lid (7) formed with an exhaust port (7a), the opening 11 opened to the top Is formed and forms an accommodating space portion (A) therein, and receives the heating element into the accommodating space portion (A) to cause a chemical exothermic reaction, and transfers the heat of reaction generated to the outside of the body, and exothermic reaction When finished, the waste heat generating solution is a reaction vessel 10 including a solution opening and closing valve 13 to be guided to the solution discharge pipe 12 provided in the lower portion to the outside;

An auxiliary container 20 which is inserted and detachably inserted into the accommodation space A, and has a plurality of through holes 20a formed on the side and bottom of the container, and accommodates the heat generating metal body;

A heating element (30) comprising a heat generating metal body (30a) and a heat generating material (30S) for heating the low temperature water contained in the water storage tank (50) by being accommodated in the accommodation space (A);

The solution inlet tube 41 and the solution are connected to the assembly hole (10a) formed on the upper end side of the body of the reaction vessel 10 and the solution storage tank (T) so that the exothermic material 30S in the solution state is introduced into the reaction vessel. On and off valve 40 for opening and closing the inlet pipe 41;

The reaction vessel 10 includes a body, and forms a closed space outside the reaction vessel 10 to fill and store the low temperature water introduced into the drain pipe 51 provided at the bottom, and stores the stored low temperature water in the reaction vessel. A water tank 50 heated to a high temperature by 10 and discharged to the outside through a water supply pipe 52 provided at an upper portion thereof;

A bypass pipe 61 connected from the upper portion U of the water storage tank 50 to the lower portion L; And a circulation pump 62 connected to the bypass pipe 61 for forcibly circulating high temperature hot water present in the upper portion U of the reservoir 50 to the lower portion L of the reservoir 50. A circulation member 60; It is made of a structure comprising more.

The accommodating space part A is formed inside the reaction vessel 10 to serve as a space for accommodating the auxiliary container 20 and the exothermic metal body 30a and the exothermic material 30S supplied from the outside whenever necessary. . Reference numeral 1, which is not described, is a heat insulating member, 3 is a circulation pump applied to the circulation heating pipe, and 51a is a water supply opening and closing valve.

In the present invention, the reaction vessel 10 according to an embodiment is formed as an apparatus for heating the low temperature water filled in the reservoir 50, the opening 11 is opened to the upper portion is formed and received inside Form a space (A), and receives the heating element 30 in the receiving space (A) to cause a chemical exothermic reaction, and transfer the heat generated at this time to the outside of the body, discarded when the exothermic reaction is finished Sexual heating solution is a structure including a solution opening and closing valve 13 to be discharged to the outside is guided to the solution discharge pipe 12 provided in the lower.

The accommodating space portion A of the reaction vessel 10 is provided as a space in which the auxiliary vessel 20, the heating element 30, and the like are accommodated inside the reaction vessel.

Therefore, the auxiliary container 20 and the heating element 30, that is, the heat generating metal body 30a, are inserted into and detachably inserted into the container through the opening 11 of the upper portion, and the heat generating metal body 30a and The exothermic material 30S supplied from the outside is accommodated whenever a material for reacting and generating heat of reaction is needed.

In addition, by receiving the heat generating material (30S) supplied from the outside to cause a chemical exothermic reaction with the heat generating metal body (30a), the heat generated at this time transfer heat to the outside of the body, the low temperature water of the reservoir 50 When heated and the exothermic reaction is completed, the waste heat generating solution is provided in a structure including a solution opening / closing valve 13 having a function of guiding the solution discharge pipe 12 provided below and discharging to the outside.

The material of the reaction vessel 10, including the solution discharge pipe 12, if the heat generating element 30 can be applied to the present invention as a material having good heat resistance, moldability and durability that can withstand the reaction heat generated during the chemical reaction Although not limited, preferably, it is particularly preferably formed of a metal, such as stainless steel, which is hardly affected by the heat generating material 30S in the heat generating element and which is easy to handle with robustness.

For reference, metals such as aluminum, zinc, and magnesium may be prohibited from being used because they may react with a heating material (also called a heat generating solution) 30S to corrode the container in a short time. Of course, these metals may form a coating layer by applying a coating material that prevents corrosion, but it should be refrained from using because the metal reacts with the heating material 30S even when the coating layer is minutely damaged during handling. In addition, iron (Fe) is also less corrosive than the metal, but should be refrained because its life is shortened by the generation of rust that corrodes every time it is used.

In addition, the shape of the reaction vessel 10 is preferably an oval at the lower side, but is not limited so long as it does not interfere to achieve the purpose of the present invention, such as oval, cylindrical, polygonal cylindrical, triangular, square, pentagonal, hexagonal, the material The pressure of the accommodating space portion (A) by the reactor body generated when the heat generated to react the heat generated by contacting the exothermic metal body and the exothermic material (30S) at the same time to withstand the internal pressure of the water tank (50) It should be chosen to withstand this rise sufficiently. For example, it is possible to select a material that can withstand the vacuum pressure in the closed receiving space (A) of the application container 10 sufficiently from 0.01 to 5 kgf / ㎠, the thickness of the stainless steel sheet is 0.01 ~ 2kgf / ㎠ The thickness of about 3mm can be used. At 2 ~ 4kgf / ㎠, the thickness of the stainless steel sheet is about 3 to 5mm, and the higher the vacuum pressure of 5kgf / ㎠ or more, the thickness of the stainless steel sheet is 5mm or more, so it is preferable to select the one having high strength. .

In addition, the size of the reaction vessel 10 may be configured as shown in FIG. 2 illustrated so that the other side of the opening 11, that is, the lower part of the body of the reaction vessel is located close to the bottom surface of the reservoir 50, and the reaction vessel 10. The area of is preferably designed within the 1/3 range of the reservoir (50).

If the area of the reaction vessel 10 is too small, the heat generating metal body 30a and the heat generating material 30S contained in the receiving space portion A are reduced, so that the reaction heat is also lowered. This is followed by the inconvenience of having to replace and supply several times until it is heated with hot water. On the contrary, if the area of the reaction vessel 10 is too large, the heating element 30 is sufficiently accommodated to heat the low temperature water of the reservoir 50 even with one reaction heat, but the heating element 30 is excessively consumed, The filling space of the reservoir 50 can be reduced.

In the reaction vessel 10 having the structure as described above, when a heat source is generated by the heating element 30 in the accommodation space A, the heat is transferred to the reaction vessel body (for example, stainless steel plate), and the reaction vessel. The heat transferred to the body is then transferred to the low temperature water of the reservoir 50 existing outside the reaction vessel body on the back of the receiving space (A) to be heated.

Of course, in the present invention, two or more reaction vessels as described above may be installed.

In the present invention, the auxiliary container 20 according to an embodiment will be described with reference to FIGS. 2, 3, and 4 as follows.

2, 3, and 4, the reaction container 10 is inserted into and detachably inserted into the reaction container 10, and a plurality of through holes 20a are formed at the side and bottom of the container, and at least one storage part. A heat generating metal body 30a is housed as a structure in which 21 is formed, and the reaction vessel 10 and the auxiliary vessel 20 are provided separately.

The storage unit 21 of the auxiliary container refers to the internal space of the auxiliary container itself, or refers to a structure installed in the internal space, or another container housed in the internal space. And the heat generating metal body 30a is accommodated in the accommodating part 21.

The structure installed in the interior space, or another container embedded in the interior space is not limited as long as it can be applied to the present invention, another container housed in the interior space is, for example, a network structure as shown in FIG. It may be a container 22 of.

In addition, the auxiliary container 20 may be provided with a lid. However, the auxiliary container lid is not necessarily provided, and thus the description of the auxiliary container lid will be omitted.

As shown in the drawing, when the housing portion 21 is one, the heat-generating metal body 30a is filled with a plate-like body or an absorbent fabric bag pressurized with a plate, sheet metal, powder, chips, small lumps, etc. It is good to apply to one housing part, and the several storage parts are easy to receive evenly distributed in several storage parts with relatively few particles, such as powder, a flake, and a small lump.

The plurality of through-holes 20a formed on the side and bottom of the auxiliary container 20 are intended to freely flow in the receiving space portion A of the heating material 30S supplied from the outside, and the heating material 30S is Easily flows into the accommodating space A and into the accommodating portion 21 of the auxiliary vessel 20 to facilitate contact with the exothermic metal body 30a housed in the accommodating portion 21, and also generates the exothermic metal body. The body of the exothermic metal body 30a is oxidized and dissolved in the exothermic material 30S by the reaction of the 30a and the exothermic material 30S. When the oxide oxidized in the exothermic material 30S is induced outside and disposed of, It is provided to perform a function to easily exit from the housing (21).

The through hole 20a may have a diameter of about 1 mm to about 5 mm. However, when the shape of the heat generating metal body 30a accommodated in the accommodating portion 21 is powder, small grains, flakes, or the like, the through-hole 20a may exit.

Thus, the present invention may further constitute an absorbent fabric layer to prevent the heat generating metal body 30a from being lost from the accommodating portion 21.

Forming the absorbent fabric layer may constitute an absorbent fabric layer in the form of an auxiliary container 20, or as shown in FIG. 4, much wider than the auxiliary container 20, and may sufficiently cover the through hole 20a formed in the auxiliary container. The absorbent fabric layer 22 may be formed by inserting a sufficient size into the auxiliary container.

The absorbent fabric layer 23 may be selected from a flexible material such as a natural fiber nonwoven fabric, a natural pulp nonwoven fabric or a foamed resin sheet, and the absorbent fabric layer 23 may be inserted into an auxiliary container in which a through hole 20a is formed. By forming the layer 23 to block the through hole 20a, the exothermic metal 30a in the form of powder, granules, or small pieces existing on the fabric layer 23 flows out of the housing 21. Can be blocked. In addition, the fabric layer 23 transmits the heat generating material 30S, causes the heat generating metal body 30a and the heat generating material 30S stored in the accommodating portion 21 to react with heat, and generates the heat generating metal body 30a. ) And the oxidized dregs of the exothermic metal body 30a generated when reacting with the exothermic material 30S can be prevented from blocking the solution discharge pipe 12 of the reaction vessel 10. .

After the reaction with the exothermic material 30S, the exothermic metal residue whose value is lost as the exothermic metal body may be provided by the auxiliary container 20 to be easily taken out and disposed.

If it is necessary to take out the exothermic metal residue under the reaction vessel 10 without an auxiliary container to the outside, it should be performed by a hand or a means for pulling out the exothermic metal residue, and the exothermic metal residue It takes a lot of time to take it out.

Therefore, the auxiliary container 20 can be easily used to receive the heat generating metal body 30a and discard the used heat generating metal body waste.

For reference, the auxiliary container 20 has a handle portion (not shown) to the upper side of the auxiliary container for easy handling or connected to the handle portion (not shown) to expose to the outside, and pull the connecting line up when necessary By placing the upper portion of the reaction vessel 10 in the accommodating space (A) may be applied to the purpose of preventing the exothermic metal body 30a and the exothermic material 30S contact each other. For example, when the water in the water tank 50 is sufficiently heated by the reaction vessel 10, the heat generating metal body 30a is pulled out by pulling a string to stop the reaction heat of the reaction vessel 10 temporarily or temporarily. The auxiliary container 20 to be accommodated is positioned above the reaction container 10 in the accommodation space A to be separated from the heat generating material 30S to stop the exothermic reaction. When the exothermic reaction is requested again, the auxiliary vessel 20 may be positioned below the reaction vessel 10 in which the exothermic material 30S2 is located. The connecting line may be exposed to the outside through the exhaust port 7a.

The auxiliary container 20 is made of a material having good heat resistance, moldability, and durability that can withstand the heat of reaction generated during the chemical reaction of the heating element 30. For example; Plastic, glass, earthenware, porcelain, stainless steel, synthetic metal, ceramic, synthetic resin having high gas barrier properties, and the like, and are preferably hardly affected by the heating material (30S), and are easily handled with robustness, It is preferable to be formed of a synthetic resin, such as stainless steel.

However, the auxiliary vessel 20 is selectively applied as necessary. That is, since the heat generating metal body 30a may be accommodated in the reaction vessel 10 without the auxiliary vessel 20, or the accommodation portion may be configured in the reaction vessel 10, it may be omitted.

In the present invention, the heating element 30 according to an embodiment will be described with reference to FIGS. 2, 5, 5, and 7 as follows.

As shown in FIG. 2, FIG. 5, FIG. 5, and FIG. 7, the heating element 30 is composed of a heat generating metal body 30a and a heat generating material 30S, and a sufficient amount of heat is generated inside the auxiliary container 20. The built-in metallic body 30a is replaceable so that it can be recycled until the end of its life, and the heat generating material 30S is supplied from the outside to the inside of the reaction vessel 10 as soon as necessary to the receiving space A. Exothermic reaction with the exothermic metal body (30a) is to perform the function of providing the reaction heat.

Specifically, the exothermic metal body 30a is a metal for continuously generating heat by reacting with the exothermic material 30S, and has a size sufficient to be recycled in at least one exothermic reaction as shown in FIG. 1. It is preferable to be built in the auxiliary container 20 so as to be replaceable as a body, and to be accommodated in the accommodation space A formed in the reaction container 10.

Of course, the auxiliary container 20 in which the exothermic metal body 30a is inserted is accommodated by being inserted into the bottom portion of the accommodation space A through the opening 11 of the reaction vessel 10 with the top open.

As the heat generating metal body 30a, any one selected from aluminum (Al), zinc (Zn), magnesium (Mg), an alloy containing at least one of the metals, or a mixed metal containing at least one is used. do. In particular, the exothermic metal body is excellent in terms of handleability, storage, stability, economy, etc., but is well soluble in the exothermic material 30S, and then easily from the reaction vessel 10 to the outside through the solution opening / closing valve 13 after use. Recommended because it is easy to drain and dispose of.

Of course, in addition to the metal may be used without limitation if it can play the same or similar role in carrying out the object of the present invention.

In addition, the form of the heat generating metal body 30a as the heat generating metal body 30a is not limited, for example; It may be a lump, a plate, a sheet, a powder, a flake, a grain, a mixture thereof, or a plate-like body pressurized with a powder, a flake, a grain, or the like. The thickness may be as thick and wide as possible without increasing the number of recycling cycles within the range of the accommodation space A.

In particular, the pyrogenic metal body 30a is housed in the auxiliary container 20 as wide as possible and accommodated in the accommodation space A, and having a thickness of at least 2 mm or more is also excellent in recyclability, but the water tank ( 50) is used to heat low temperature water, that is, the heating element 30 is required, that is, it can be maximized to generate a high temperature reaction heat while maintaining the exothermic reaction retention time when chemically reacted in contact with the exothermic material (30S) More preferred.

In general, a conventional heating element that generates heat by a hydration reaction is housed in a package of a heat generating material complex, the heating element in the package during the hydration reaction is approximately exothermic reaction in the form of lumps, the thermal efficiency generated at this time The heat generated in the vicinity of the heating element in the form of agglomerate, but the disadvantage is that the temperature is significantly lower as the heating element somewhat falls.

However, as described above, the heating element 30 according to the present invention selects the heating metal body 30a having a thickness of at least 2 mm or more and is housed as wide as possible in the auxiliary container 20 to be accommodated in the accommodation space A. By doing so, it is possible to improve the recyclability when reacting with the exothermic material (30S2), to generate a high temperature reaction heat, and to maintain the exothermic reaction holding time to maximize the thermal efficiency.

The exothermic metal body 30a is oxidized and melts in the exothermic material 30S when the exothermic reaction comes into contact with the exothermic material 30S supplied from the outside. This means that the lifetime of the heat generating metal body is determined by the amount of the heat generating material 30S. When the amount of the heat generating material 30S is supplied less, the amount of oxidation of the heat generating metal body appears less. On the contrary, when the amount of the heat generating material 30S is supplied, the amount of oxidizing the heat generating metal body also appears high.

Accordingly, when the exothermic reaction with the exothermic material 30S is stopped, the oxidation of the exothermic metal body is almost stopped, and remains on the bottom of the accommodating part 21 of the auxiliary container. And this is recycled until the oxidation is completed to repeat the exothermic reaction with the exothermic material (30S).

In this process, the thicker the heat generating metal body, the longer its life and the longer the replacement time is. On the contrary, the thinner the metal body or the finer particles, the shorter or one-time the life of the metal body is shortened.

Therefore, in order to be recycled more than once, the heat generating metal body 30a can be selected to have a maximum thickness and a wide surface area within a range allowed by the accommodation space A. For example, ; A plurality of aluminum plates having a diameter of 1Cm or more and a diameter of 10Cm or more may be able to be recycled several times to several tens of times by preferably embedded in the receiving space A.

In addition, in order to prevent the exothermic metal body 30a from being lost to the outside, for example, as shown in FIG. 5, it is preferable to perform sealing after insertion into the absorbent fabric bag G. In particular, it will be easy to handle the pyrogenic metal body 30a such as small particles, powders, grains, and the like.

The absorptive textile bag G into which the heat generating metal body 30a is inserted is manufactured to have flexibility in storage or mobile phase, and a natural fiber nonwoven fabric, a natural pulp nonwoven fabric or a foamed resin sheet can be used.

In particular, the heat generating metal body 30a is preferably formed in a plurality of cell types so that heat can be generated simultaneously within a predetermined area without being biased to one side in the absorbent fabric. The heat generating metal body 30a is inserted into each of the divided cells and sealed, and the heat generating material 30S penetrates into each cell at a time when heat is required so that heat can be maintained evenly.

The exothermic material 30S according to the present invention may select sodium hydroxide (NaOH) as a premise to obtain reaction heat by reacting with the exothermic metal body 30a.

Sodium hydroxide (NaOH) as a heat generating material (30S) is advantageous in showing a high thermal efficiency when reacting with the heat generating metal body (30a) while having a low economic cost and excellent economical cost.

Sodium hydroxide (NaOH) is sealed after being inserted into a synthetic resin bag (H) as shown in FIG. 6, or after sealing it into an absorbent fabric bag, to prevent it from being oxidized upon contact with oxygen. It is more preferable that the sealing process is inserted into a container or a bag made of a waterproof material such as plastic or resin which can block air. The absorbent fabric encapsulation may be made flexible using natural fiber nonwoven fabric, natural pulp nonwoven fabric or foamed resin sheet, etc. in order to have the advantages of storage or mobile phase.

Sodium hydroxide (NaOH) as the heating material (30S) can be sealed by inserting a predetermined amount into a bag of synthetic resin or absorbent fabric, in particular, these bags are, for example, as shown in FIG. It is preferable to form the cells separately. Further, it is more preferable to insert sodium hydroxide (NaOH) into each of the divided cells to seal the cells, and to form a cutting line between the cells and the cells so that the necessary amount can be cut and used along the cutting line H1. .

As described above, blocking sodium hydroxide (NaOH) from contacting with oxygen as the heating material (30S) may cause a synthetic resin containing sodium hydroxide (NaOH) to come into contact with air when heat is required from the reaction vessel 10 or Take out the absorbent fabric bag from the container or bag of waterproof material, and put the auxiliary container 20 in which the heat-generating metal body 30a is embedded into the storage space A with the required amount with water to react with sodium hydroxide (NaOH). ) Dissolves and rapidly generates high heat of dissolution. The heat of dissolution preserves the initial calorific value of the reaction, and immediately after the solution is in contact with the exothermic metal body 30a accommodated in the accommodating space (A), a continuous reaction connection is possible to release a high temperature reaction force.

Preferably, however, it is preferable to use sodium hydroxide aqueous solution in which sodium hydroxide (NaOH) is dissolved in water to form a liquid in an aqueous solution as the heating material 30S.

Sodium hydroxide (NaOH) has a problem that a large amount of harmful gas is generated in a short time with the heat of melting when in contact with water.

Because so; The sodium hydroxide (NaOH) is added together with water in the receiving space portion (A) or water is supplied after dissolution of sodium hydroxide (NaOH) to dissolve and at the same time obtain a heat of dissolution, and at the same time exothermic metal body (30a) and exothermic Rather than obtaining heat of reaction with a large amount of harmful gases harmful to the human body by reacting, it is stored in the solution tank (T) by using a liquid composition formed by dissolving sodium hydroxide (NaOH) in water and piping facilities (40, 41, 12, 13) and the like, and the harmful gas is significantly reduced when reacting with the pyrogenic metal body (30a), the effect that only a small amount that is not easy to be detected in the human sense of smell in the outdoors have.

The composition of the aqueous sodium hydroxide solution as the heating material (30S) is 10 to 80 parts by weight, preferably 15 to 50 parts by weight, more preferably 20 to 40 parts by weight of sodium hydroxide (NaOH) in the whole composition It can be dissolved in to provide a heating material (30S).

If sodium hydroxide (NaOH) is added in less than 10 parts by weight of the heating element does not generate enough heat during the reaction with the pyrogenic metal body (30a), while if the sodium hydroxide (NaOH) contains more than 80 parts by weight of pyrogenic metal body (30a) ), It does not melt enough due to the lack of oxygen in the water to give a sufficient amount of heat compared to the amount contained.

The composition of the aqueous sodium hydroxide solution may contain 1 to 70 parts by weight of calcium hydroxide (TOH). Calcium hydroxide shows a similar heating power as sodium hydroxide (NaOH).

In addition, the composition of the aqueous sodium hydroxide solution may contain a fragrance in order to allow the fragrance to diverge together with the reactive gas flowing out of the receiving space (A) by an exothermic reaction. Of course, the fragrances applied to the composition should be contained in a way that does not interfere with the purpose and effect of the composition.

As such a fragrance, for example; Linden flower, licorice, pereirian, peppermint, lavender, lemongrass, mint, lemon verbena, thyme thyme, rosemary, mate, marigold, orange peel, wild strawberry, orange blossom, sage, basil ), RosepinT, marrow, blacT tea, jasmine, valerian, bergamot, chamomile, cedarwood virginia, cinnamon ( cinnamon, clary sage, cypress, eucalyptus, funnel, frankincense, geranium, grapefruit, grapefruit, hyssop, Juniper, lemon, lime, marjoram, mirrh, palmarosa, patchouli, rose absolute, sandalwood ( Spices such as sandalwood, tea ~ tree, ylang ylang, ginger, rose, cardamom, scentella, bamboo, pine needles, cucurbita, juniper Incense, chrysanthemum, fir, scented, cypress, cypress, cinnamon, peppermint, vinegar, citrus extract can be mixed with any one or two or more. The content is 0.001-20 weight part of the whole composition, and when it contains, sodium hydroxide (NaOH) dissolves in water completely and it is desirable to contain it after heat of dissolution is lost completely.

Almost all of the fragrances except bamboo, pine needles, juniper, cypress, and cypress have a repelling effect that mosquitoes do not like, and the mosquito avoiding effect will be appropriate in summer. .

As the liquid heating material prepared as described above, the composition 30S is extremely low in the amount of harmful gas generated upon contact with the heat generating metal body 30a, and is also generated by rapid heat generation with the heat generating metal body 30a. The heat of the reaction is such that the heat efficiency of the low temperature water in the storage tank 50 can be heated to accumulate.

Specifically, the liquid heating material (30S) is filled in a large-capacity container (T) made of a material such as plastic, stainless steel, heat resistance, moldability and durability that can withstand the heat of reaction generated during the chemical reaction with the pyrogenic metal body. By supplying the required amount into the receiving space portion (A) by the on-off valve 40 to react with the heat generating metal body (30a) it can be preferably used to heat the low-temperature water of the reservoir 50 with the reaction heat.

In addition, the heat generating material (30S) is a built-in amount of a sufficient amount so that the heat generating metal material (30a) is recycled at least once in the auxiliary container 20, can be continuously replenished whenever necessary, the heat generating material ( 30S) can be used to heat the low temperature water of the water storage tank 50 with high thermal efficiency by continuously exothermic reaction with the exothermic metal body 30a until the exothermicity of the 30S is ended.

In addition, the exothermic material 30S may be maintained in a solution state suitable for disposal when the exothermic reaction with the exothermic metal body 30a is terminated, so that the solution discharge tube 12 and the solution provided below the reaction vessel 10 may be maintained. Through the discharge valve 13, the waste heat generation solution in which the exothermic reaction is completed may be easily discharged to the outside.

Furthermore, the waste heat generating solution applied to the present invention can be recycled. For example; A sodium hydroxide aqueous solution was supplied as the heat generating material 30S into the receiving space portion A to react with aluminum as a heat generating metal body to heat the low temperature water of the reservoir 50, and then the waste heat generating solution was collected and After filtering to filter out hydroxide ions (OH-) and undissolved impurities, the filtered solution is cooled to form a supersaturated state and recrystallized, whereby pure hydrated aluminum oxide (Al 2 O 3 · 3H 2 O) precipitates.

Formula 2Al (OH) 4 <up>-</ up> (aq) → Al 2 O 3 .3H 2 O (s) + 2OH- (aq)

When the precipitated hydrated aluminum oxide is heated at 1,300 ° C, the hydrated water is removed and pure aluminum oxide (Al) is obtained. The aluminum oxide purified by Bayer treatment is electrolyzed by hole-hert treatment to obtain pure aluminum ( Al).

As such, after being used as a fuel of a regenerative heater heated by the chemical reaction heat of the present invention, the waste heat generating solution has an advantage that can be applied to recycling by a known technique in the related art.

In the present invention, the on-off valve 40 according to the embodiment is a control device for supplying the external solution-like heating material (30S1) to the receiving space (A) of the reaction vessel 10, the reaction vessel (10) Reaction assembly 10 is configured to open and close the solution inlet pipe 41 connected to the assembly hole (10a) and the solution storage tank (T) formed on the upper side of the reaction container (10S1) present in the solution storage tank (T) It is to provide a function to adjust the supply to the appropriate amount of the receiving space (A).

The assembly hole (10a) is preferably formed in the upper side of the reaction vessel 10, the body of the reaction vessel 10 is exposed to the outside.

The material used for the on-off valve 40 and the solution inlet tube 41 is the same as that of the reaction vessel 10, or a plastic, resin, or the like, which exhibits good rigidity, durability, and heat resistance.

On the other hand, the reservoir 50 according to an embodiment of the present invention includes a reaction vessel 10 body, as shown in Figure 1 and 2, forming a closed space to the outside of the reaction vessel 10 The cold water flowing into the drain pipe 51 provided in the reservoir is filled with water, and the stored cold water is heated to a high temperature by the reaction vessel 10 and discharged to the outside through the water supply pipe 52 provided on the upper portion.

As shown, including a body of the reaction vessel 10, by forming a sealed space outside the reaction vessel 10 is formed a water tank that can store water, the reservoir 50 having a sealed space therein is shown in FIG. It can be designed in the same square as 1, or in various forms such as cylindrical, polygonal cylindrical, triangular, pentagonal, hexagonal, and made of materials such as stainless steel, iron and synthetic metals thereof.

In addition, the water reservoir filled with cold water is stored in the lower portion (L) and the upper portion (U), the drain pipe 51 and the water supply pipe 52 are respectively included in the same body. The reservoir 50 is connected to the circulation pipe of the closed loop type not shown in the drain pipe 51 and the water supply pipe 52.

Therefore, the reservoir 50 discharges the hot water of the high temperature heated by the reaction vessel 10 through the water supply pipe 52 connected to the heating pipe, and the low temperature water used for heating is discharged to the drain pipe 51 connected to the heating pipe. It is supplied through

In addition, the heating pipe is circulated by receiving hot water of high temperature through the water supply pipe 52, and supplies the hot water cooled while being circulated again to the drain pipe 51. That is, the heating pipe is re-supply the hot water used for heating to the drain pipe 51 so that the hot water of the hot water is converted to low temperature water while being used for heating is heated again by the reaction vessel 10 and recycled through the water supply pipe (52). Will be.

For reference, a closed loop type circulating heating pipe is a heating line for supplying heating water to a heat storage boiler connected to a heat storage boiler, and a circulation pump for returning the heating water through the water heating pipe back to the heat storage boiler. It is a piping structure of boiler consisting of installed return line. Of course, this structure can also be applied to the indoor blower.

On the other hand, the water supply pipe 52 provided in the upper portion (U) of the reservoir 50 is discharged hot water heated to a high temperature by the reaction vessel 10 for continuously heating the low temperature water is not shown connected to the water supply pipe 52 The heating pipe heats the room while circulating high temperature hot water.

Since the hot water cooled while being used for heating flows into the lower portion L through the drain pipe 51, the temperature of the upper portion U is shown to be much higher than the temperature of the lower portion L.

In addition, the hot water heated while being used for heating through the drain pipe 51 is continuously supplied to the upper portion U of the water storage tank 50 by the hot water heated again by the reaction vessel 10.

Accordingly, the hot water of the high temperature supplied to the upper portion (U) of the reservoir 50 performs heat exchange while moving to the lower portion of the reservoir 50 by convection caused by the temperature difference. In addition, the hot water of the high temperature moving to the lower portion (L) of the reservoir 50 is heated again to the high temperature by the reaction vessel 10, while the circulation process of diffusion to the upper portion (U) of the reservoir 50 is repeated, the reservoir The water stored in (50) is heated and regenerated as a whole.

Furthermore, as shown in FIGS. 1 and 2, a bypass pipe 61 connected from the upper portion U to the lower portion L of the reservoir 50; And a circulation member 60 including a circulation pump 62 connected to the bypass pipe 61, thereby being heated by the reaction vessel 10 and stored in the upper portion U of the reservoir 50. The high temperature hot water is forcedly circulated to the lower portion L of the reservoir 50, and the low temperature water stored in the lower portion L of the reservoir 50 is heated again and circulated to the upper portion U of the reservoir 50. The high temperature hot water may shorten the time for the heat storage by diffusing the entire reservoir 50.

Here, as shown in the bypass pipe 61 of the circulation member 60, both ends are respectively connected to the drain pipe 51 and the water supply pipe 52 of the reservoir 50.

Therefore, the bypass pipe 61 is supplied with the hot water of the high temperature guided to the upper portion (U) of the reservoir tank 50 through the water supply pipe 52, through the drain pipe 51 to the lower portion (L) of the reservoir tank 50. Bypass.

At this time, the circulation pump 62 is connected to the bypass pipe 61 as shown, pumping hot water of high temperature flowing through the bypass pipe 61 to the lower portion (L) of the reservoir 50.

Thus, the circulation member 60 is to be thermally stored while being heated in a short time by forcibly circulating the hot water of the hot water present in the upper portion (U) of the reservoir (50) to the lower portion (L) of the reservoir (50).

However, the circulation member 60, which is a mechanism for forcibly supplying and circulating the heated hot water present in the upper portion U of the reservoir 50 to the lower portion L of the reservoir, is selectively applied as necessary. That is, the circulation member 60 for forcibly circulating the hot water of the hot water present in the upper portion U of the reservoir 50 to the lower portion L of the reservoir 50 has a large capacity in which the storage capacity of the reservoir 50 is relatively large. It is preferable to apply, and it can abbreviate | omit to the small capacity | capacitance which the low capacity | capacitance of the water storage tank 50 is comparatively small.

The operation of the regenerative heater 100 heated by the chemical reaction heat according to the embodiment of the present invention configured as described above will be described with reference to FIG. 1.

As shown, the regenerative heater 100 is heated by the chemical reaction heat according to the embodiment of the present invention is supplied with low-temperature water through the drain pipe (51). At this time, the reservoir 50 is filled with the cold water supplied from the drain pipe 51 to store up to the upper end.

In addition, the auxiliary container 20 is inserted into the lower side of the reaction vessel 10 through the opening 11 of the reaction vessel 10.

In addition, at least one metal body belonging to the heat generating metal body 30 group is selected and accommodated in the housing 21 of the auxiliary container 20. At this time, it is preferable that the heat generating metal body 30 accommodate a sufficient amount such that it is recycled several times or more. For example, it is more preferable to select agglomerates of aluminum.

Then, the opening 11 of the reaction vessel 10 is sealed with the lid 1.

Next, the exothermic material 30S1 present in the solution storage tank T is supplied to the accommodation space portion A of the reaction vessel 10 through the solution inlet pipe 41 by the on / off valve 40. The heating material 30S1 may be repeatedly supplied in small amounts several times or more depending on the situation, but it is preferable to supply a predetermined amount.

The heating material 30S2 supplied by the on / off valve 40 is chemically broken and reacts with the heat generating metal body 30 in the receiving space A to generate reaction heat. When the heat of reaction is assuming that a sufficient amount exists so that the exothermic metal body 30 accommodated in the reaction vessel 10 can be repeatedly recycled several times, until the exothermic property of the exothermic material 30S2 ends. The heating material is continuously generated, and the heating material 30S1 may be supplied with the required amount from the bleed valve 40 according to the need of the reaction container 10 so that the reaction heat is continuously generated.

In addition, the reactor body generated by the exothermic reaction of the exothermic material 30S2 and the exothermic metal body 30 in the receiving space portion A of the reaction vessel 10 is led to the upper portion of the reaction vessel 10 to cover the lid ( It is discharged to the atmosphere through the exhaust port 7a formed in 7).

As such, the reaction heat generated by the chemical reaction between the exothermic material 30S2 and the exothermic metal body 30 in the reaction vessel 10 is transferred to the body of the reaction vessel 10, and the heat transferred to the reaction vessel body is Immediately transferred to the low temperature water of the reservoir 50 exists around the reaction vessel body shell on the back of the receiving space (A) to heat the low temperature water.

In addition, the waste heat dissipation solution of the heat generating material 30S2 is terminated through the solution discharge pipe 12 and the solution opening and closing valve 13 provided in the lower portion of the reaction vessel (10).

On the other hand, when the low temperature water is converted into hot water by the reaction vessel 10 (usually about 70 ~ 95 ℃), the reservoir 50 is discharged through the water supply pipe 52 connected to the heating pipe, and used for heating While being cooled down the low temperature water is supplied through the drain pipe 51 connected to the heating pipe.

In addition, the heating pipe not shown is supplied with hot water circulated through the water supply pipe 52 and circulated, and supplies hot water cooled while being circulated again to the drain pipe 51. That is, the heating pipe is re-supply the hot water used for heating to the drain pipe 51 so that the hot water of the hot water is converted to low temperature water while being used for heating is heated again by the reaction vessel 10 and recycled through the water supply pipe (52). do.

In addition, the water supply pipe 52 provided in the upper portion (U) of the reservoir 50 discharges hot water heated to a high temperature by the reaction vessel 10 that continuously heats the low temperature water, and is not shown heating connected to the water supply pipe 52. The piping heats up the room while circulating hot water.

Since the hot water cooled while being used for heating flows into the lower portion L through the drain pipe 51, the temperature of the upper portion U is shown to be much higher than the temperature of the lower portion L.

In addition, the hot water heated while being used for heating through the drain pipe 51 is continuously supplied to the upper portion U of the water storage tank 50 by the hot water heated again by the reaction vessel 10.

Accordingly, the hot water of the high temperature supplied to the upper portion (U) of the reservoir 50 performs heat exchange while moving to the lower portion of the reservoir 50 by convection caused by the temperature difference. Then, the hot water of the high temperature moving to the lower portion (L) of the reservoir 50 is heated again to the high temperature by the reaction vessel 10, while the circulation process of diffusion to the upper portion (U) of the reservoir 50 is repeated, the reservoir The water stored in (50) is heated and regenerated as a whole.

In addition, the circulation member 60 is heated by the reaction vessel 10 as shown, the hot water of the hot water stored in the upper portion (U) of the reservoir 50 to the circulation pipe (61a, 61b) circulation pump 62 Forced circulation to the lower portion (L) of the reservoir (50) by using, and the cold water stored in the lower portion (L) of the reservoir 50 is heated again and circulated to the upper portion (U) of the reservoir (50), such As the circulation process is repeated, high temperature hot water in a short time is shortened to be accumulated and accumulated in the reservoir 50.

Of course, the thermal circulation method for applying high temperature hot water in the reservoir 50 to a heater (boiler and hot air fan including a closed loop type circulating heating pipe) is a well-known heat storage heater such as Korean Patent Registration No. 10-0751485. It is the same.

Therefore, in the present invention, the control device for controlling the temperature of the reservoir 50 and the circulating pump of the heating pipe line is the same as that applied to a conventional heater, and thus the description is omitted in the present invention. It should be understood that it should be understood.

On the other hand, the low-temperature water filled in the storage tank 50 of the heat storage type heater 100 heated by the chemical reaction heat of the above-described embodiment takes about 1 to 3 hours to be heated to a temperature suitable for heating.

As part of improving the problem, the heat storage type heater 100 is heated by isolating a part of the low temperature water in one place in the heat storage type heater 100 which is heated by the chemical reaction heat of the above-described embodiment, and the hot water rapidly heated in the isolation state (U) The water heater may further include a hot water heater to supply hot water to the heating pipe in the shortest time.

Referring to Figure 8 attached to the hot water heater according to the present invention.

8 is a longitudinal sectional view showing the regenerative heater 100 heated by chemical reaction heat according to another embodiment of the present invention, and an operation thereof.

This embodiment is in addition to the regenerative heater 100 heated by the heat of chemical reaction of the above-described embodiment. Therefore, all configurations are the same as the regenerative heater 100 heated by the chemical reaction heat of the above-described embodiment, except that the hot water heater 70 is installed as shown in the drawings.

Accordingly, only these differences will be described with reference to the accompanying drawings.

As shown in FIG. 8, the hot water heater includes a reaction body 10 embedded in the water reservoir 50, and accommodates the heating element 30, and the water tank 50 outside the reaction vessel 10. A hot water supply body (70) integrally embedded to isolate a portion of the cold water stored in the water storage tank (50); The hot water of the hot state rapidly heated to a high temperature by the reaction vessel 10 by the low temperature water isolated in the hot water supply body 70 is led to the upper portion of the water storage tank 50, and the discharge provided on the hot water supply body 70. Through-holes formed at the lower side of the hot water supply body 70 to supply hot water of high temperature to the water supply pipe 52 provided in the upper portion of the reservoir tank 50 and the upper portion of the reservoir tank 50 through the tube 71 A portion of the cold water stored in the lower portion of the water storage tank 50 is introduced and separated through the 70a, and the isolated cold water is rapidly heated by the reaction vessel 10, and the heated hot water is heated to the top of the hot water heater. Induction, it is provided in a structure to diffuse to the upper portion of the reservoir 50 through the discharge hole (70b) and the discharge tube 71 formed in the hot water heater.

The hot water heater 70 having the above structure is built in the inside of the water storage tank 50 with the same material as the water storage tank 50 as shown, and isolates a part of the low temperature water stored in the water storage tank 50 to the reaction vessel 10. Rapid heating to high temperature using). The hot water heater 70 is preferably installed so that the reaction vessel 10 of the water storage tank 50 is positioned therein so that the low temperature low temperature water is heated and rises due to the temperature difference to allow natural convection.

Here, the above-described hot water heater 70 has a through hole 70a formed at one lower side of the hot water body 70 as shown. In addition, a discharge hole 70b is formed at an upper side of the hot water supply body 70, and a discharge tube 71 is formed at the other side of the discharge hole 70b.

The discharge pipe 71 is preferably disposed close to the water supply pipe 52 so that hot water of high temperature can be supplied to the water supply pipe 52.

Therefore, the hot water heater 70 inflows and isolates a part of the low temperature water stored in the lower portion L of the water storage tank 50 through the through hole 70a. Then, the isolated low temperature water is rapidly heated by the built-in reaction vessel 10, and hot water heated to a high temperature in the hot water heater 70 is led to the upper portion U of the water storage tank 50. That is, the hot water of the hot water rapidly heated in the hot water heater 70 is discharged through the discharge pipe 71 provided in the hot water heater 70 is supplied to the water supply pipe 52 provided in the upper portion (U) of the reservoir 50, as well as , The entire upper portion (U) of the reservoir (50).

The operation of the regenerative heater heated by the chemical reaction heat according to the embodiment of the present invention configured as described above will be described with reference to FIG. 8.

As shown, the regenerative heater heated by the chemical reaction heat according to the embodiment of the present invention is supplied with low-temperature water through the drain pipe (51). At this time, the reservoir 50 is filled with the cold water supplied from the drain pipe 51 to store up to the upper end.

The water tank 50 supplies a part of the low temperature water stored in the lower portion L to the inside of the water heater 70 through the through hole 70a provided in the lower portion of the water heater.

The hot water heater 70 receives a portion of the low temperature water of the reservoir 50 to isolate from the outside. At this time, the low temperature water isolated in the hot water heater 70 is heated to a high temperature while generating heat by the reaction heat of the heating element 30 accommodated in the reaction vessel 10. Therefore, all the cold water isolated by the hot water heater 70 is heated by hot water of high temperature. Of course, the hot water heater 70 heats the low-temperature water present in the vicinity of the outer surface because the hot water inside the heat exchange with the low-temperature water present around the outer surface. That is, the low temperature water surrounding the outer surface of the hot water heater 70 is slightly heated by the hot water of high temperature isolated inside the hot water heater 70.

In this way, the hot water of high temperature isolated in the water heater 70 is supplied to the upper portion (U) of the reservoir 50 by the convection phenomenon. As the low temperature water used for heating continues to flow into the drain pipe 51 of the water tank 50 due to this natural convection phenomenon, the hot water of the hot water isolated from the water heater 70 is supplied to the upper portion U of the water tank 50. . That is, the low temperature water supplied to the drain pipe 51 flows into the hot water heater 70 by the discharge pressure, and the hot water of high temperature separated by the hot water heater 70 moves along the natural convection phenomenon by the pressure of the low temperature water introduced. .

On the other hand, the water supply pipe 52 provided in the upper portion (U) of the reservoir 50 discharges the hot water of high temperature ejected from the discharge pipe (71).

Therefore, the heating pipe not shown connected to the water supply pipe 52 heats the room while circulating the hot water of the high temperature rapidly heated by the hot water heater 70 immediately.

On the other hand, the discharge hole (70a) provided in the upper portion of the hot water heater (70) is supplied with hot water heated at the bottom immediately blows and diffuses to the upper portion (U) of the reservoir (50).

The hot water diffused in the upper portion U of the water storage tank 50 moves to the lower portion L of the water storage tank 50 by the convection caused by the temperature difference, and then again, a part of the hot water through the through hole 70a of the water heater. Is isolated by inflow. And it is rapidly heated by the reaction vessel 10.

Therefore, the hot water isolated in the hot water heater 70 is rapidly heated by the reaction vessel 10 to be heated to a higher hot water. Of course, the hot water heated to a high temperature is supplied to the water supply pipe 52 of the reservoir 50 through the discharge pipe (71).

In the heat storage type heater 100 by the chemical reaction heat according to the embodiment of the present invention as described above, the hot water heater 70 rapidly heats the low temperature water, thereby rapidly generating a high temperature hot water to heat the room.

In addition, since the low-temperature water is heated again by the reaction vessel 10, hot water heated to a very high temperature is supplied to a heating pipe not shown.

On the contrary, the heat storage type heater 100 by the heat of chemical reaction according to the embodiment of the present invention heats up the water stored in the water storage tank 50 through the reaction vessel 10 when the heating is not performed. At this time, the hot water heater 70 continuously supplies the hot water of the high temperature heated by the reaction vessel 10 to the upper portion (U) of the reservoir (50). Accordingly, the hot water of the high temperature supplied to the upper portion (U) of the reservoir 50 performs heat exchange while moving to the lower portion of the reservoir 50 by convection caused by the temperature difference.

And the hot water of high temperature which moves to the lower part L of the water storage tank 50 flows back into the through-hole 70a of the water heater 70, is heated to high temperature, and circulates again.

Therefore, the water stored in the storage tank 50 is to be thermally stored while being heated to a high temperature in a short time.

Such a hot water heater 70 can be implemented more usefully in a large-capacity water tank 50.

In addition, the hot water heater may be configured to supply the hot water to the heating pipe in a very short time faster than the effect illustrated in FIG. 3 by configuring the hot water heater to pass through the reaction vessel.

Referring to Figure 9 attached to the hot water heater according to another embodiment of the present invention as follows.

9 is a longitudinal sectional view showing the regenerative heater 100 heated by chemical reaction heat according to another embodiment of the present invention.

This embodiment is in addition to the embodiment of FIG. 1 described above. Therefore, all configurations are the same as the heat storage type heater 100 which is heated by the heat of chemical reaction of the above-described embodiment, except that the hot water heater 80 is installed as shown, which is different from the above-described embodiment.

Accordingly, only these differences will be described with reference to the accompanying drawings.

As shown in FIG. 9, the hot water heater is configured to pass through the inside of the reaction vessel 10, and is disposed inside the reaction vessel 10 to isolate a portion of the cold water stored in the water storage tank 50. 80 and; The hot water of the state in which the hot water is isolated in the hot water supply body 80 is rapidly heated to a high temperature by the reaction vessel 10 to guide the upper portion of the water storage tank 50, and extends from the hot water supply body 80. The hot water of high temperature is supplied to the water supply pipe 52 provided in the upper portion of the water storage tank 50 and the upper portion U of the water storage tank 50 through the discharge pipe 85 formed to be exposed to the outside of the reaction vessel 10, A portion of the low temperature water stored in the lower portion of the water storage tank 50 is introduced and separated through the through hole 80a formed at one lower side of the main body 80, and the isolated low temperature water is rapidly heated by the reaction vessel 10. The heated hot water is guided to the upper portion of the hot water heater, and is provided in a structure in which the hot water is diffused to the upper portion of the water storage tank 50 through the discharge tube 85 and the discharge hole 85a provided at the upper portion of the hot water heater.

The hot water heater 80 having the structure as described above is configured to pass through the inside of the reaction vessel 10 with the same material as the reaction vessel 10 as illustrated, and is disposed inside the reaction vessel 10, and the water tank ( A portion of the cold water stored in 50) is isolated and rapidly heated to a high temperature using the reaction vessel 10. The hot water heater 80 is preferably installed so that the reaction vessel 10 of the water storage tank 50 is located outside thereof, so that the low temperature low temperature water is heated and rises due to the temperature difference so as to naturally convection.

Here, the above-described hot water heater 80 has a through hole 80a formed at one side of the lower portion of the hot water body 80 as shown. Then, the discharge pipe 85 is formed on one side of the hot water supply body 80.

The discharge pipe 85 is preferably disposed close to the water supply pipe 52 so that hot water of high temperature can be supplied to the water supply pipe 52.

Therefore, the hot water heater 80 inflows and isolates a part of the low temperature water stored in the lower portion L of the reservoir 50 through the through hole 80a. Then, the isolated low-temperature water is rapidly heated by the built-in reaction vessel 10, and the hot water heated to a high temperature in the hot water heater 80 through the discharge tube 85, the upper (U) water supply pipe of the reservoir 50 ( To the inlet of 52). That is, the hot water of the hot water rapidly heated in the hot water heater 80 is discharged through the discharge pipe 85 provided in the hot water heater 80 is supplied to the water supply pipe 52 provided in the upper portion (U) of the reservoir 50, of course. , The entire upper portion (U) of the reservoir (50).

The operation of the regenerative heater heated by the chemical reaction heat according to the embodiment of the present invention configured as described above will be described with reference to FIG. 9.

As shown, the regenerative heater heated by the chemical reaction heat according to the embodiment of the present invention is supplied with low-temperature water through the water supply pipe (52). At this time, the reservoir 50 is filled with the cold water supplied from the water supply pipe 52 to store up to the upper end.

The water tank 50 supplies a part of the low temperature water stored in the lower portion L to the inside of the water heater 80 through the through hole 80a provided in the lower portion of the water heater.

The hot water heater 80 receives a portion of the low temperature water of the reservoir 50 to isolate from the outside. At this time, the low-temperature water isolated in the hot water heater 80 is heated to a high temperature while generating heat by the reaction heat of the heating element 30 accommodated in the reaction vessel 10.

This heats the cold water isolated much faster than the embodiment of FIG. 8 with high temperature hot water. In the embodiment of FIG. 8, since the low temperature water isolated from the hot water heater is heated with hot water, the hot water inside the hot water heater exchanges heat with the low temperature water present at the periphery of the outer surface, so that the low temperature water surrounding the outer surface is heated together. have. Therefore, the isolated hot water inside the hot water heater is affected by the cold water existing outside the hot water heater, so that the isolated hot water inside the hot water heater loses heat to the outside.

On the contrary, in the structure of FIG. 9, since the hot water heater 80 is isolated from the outside, the hot water of the hot water heater is not affected by the loss of heat loss to the outside. ) Can supply hot water of high temperature.

And the hot water of high temperature isolated in the water heater 80 is supplied to the upper portion (U) of the reservoir 50 by the convection phenomenon. As the low temperature water used for heating continues to flow into the water supply pipe 52 of the water storage tank 50 due to this natural convection phenomenon, the hot water, which is isolated from the water heater 80, is supplied to the upper portion U of the water storage tank 50. . That is, the low temperature water supplied to the water supply pipe 52 flows into the hot water heater 80 by the discharge pressure, and the hot water of high temperature separated by the hot water heater 80 moves along the natural convection phenomenon by the pressure of the low temperature water introduced. .

On the other hand, the water supply pipe 52 provided in the upper portion (U) of the reservoir 50 discharges the hot water of the hot water discharged from the discharge pipe (85).

Therefore, the heating pipe not shown connected to the water supply pipe 52 heats the room while circulating the hot water of the hot water rapidly heated by the hot water heater 80 immediately.

On the other hand, the upper portion (U) of the reservoir 50 receives the hot water of the hot water discharged from the discharge tube 85 immediately blows and diffuses to the upper portion (U) of the reservoir (50).

The hot water diffused in the upper portion U of the water storage tank 50 moves to the lower portion L of the water storage tank 50 by convection caused by a temperature difference, and again, a part of the hot water through the through hole 80a of the water heater. Is isolated by inflow. And it is rapidly heated by the reaction vessel 10.

Therefore, the hot water isolated in the hot water heater 80 is rapidly heated by the heating element 30 accommodated in the reaction vessel 10 to be heated to higher hot water. Of course, the hot water heated to a high temperature is supplied to the water supply pipe 52 of the reservoir 50 through the discharge pipe (85).

In the heat storage type heater 100 by the chemical reaction heat according to the embodiment of the present invention as described above, the hot water heater 80 rapidly heats the low temperature water, thereby instantly generating a high temperature hot water to heat the room.

In addition, since the low-temperature water is heated again by the reaction vessel 10, hot water heated to a very high temperature is supplied to a heating pipe not shown.

On the contrary, the heat storage type heater 100 by the heat of chemical reaction according to the embodiment of the present invention heats up the water stored in the water storage tank 50 through the reaction vessel 10 when the heating is not performed. At this time, the hot water heater 80 continuously supplies the hot water of the high temperature heated by the heating element 30 accommodated in the reaction vessel 10 to the upper portion (U) of the reservoir (50). Accordingly, the hot water of the high temperature supplied to the upper portion (U) of the reservoir 50 performs heat exchange while moving to the lower portion of the reservoir 50 by convection caused by the temperature difference.

And the hot water of high temperature which moves to the lower part L of the water storage tank 50 flows back into the through-hole 80a of the hot water heater 80, is heated to high temperature, and circulates again.

Therefore, the water stored in the water storage tank 50 is heat-reduced while being heated to high temperature in a very short time.

Such a hot water heater 80 can be implemented more usefully in a large-capacity water tank (50).

By further including the hot water heaters 70 and 80 in the regenerative heater 100 by the heat of chemical reaction illustrated in FIG. 1, the low-temperature water can be heated to high-temperature hot water for a short time and used immediately for heating. By being able to continue using it can provide the advantage of reducing the time required to heat the low temperature water.

As described above, specific embodiments of the regenerative heater by the heat of chemical reaction belonging to the present invention as described above are illustrated and described, but the present invention is not limited to the above-described embodiments and examples, and the spirit of the present invention. It will be apparent to those skilled in the art that various other changes and modifications can be made without departing from the scope and scope of the present invention. Therefore, it is intended that such changes and modifications be included within the scope of the appended claims.

It is possible to produce the product for the regenerative heater heated by the chemical reaction heat of the present invention, and thus it can be strategically used to target the niche market in the field of heating products such as boilers and blowers, so the industrial significance of the field is extremely large.

A: receiving space
T: Solution Storage Tank
7: lid 7a: exhaust vent
10: reaction vessel 10a: assembly hole
11: opening
12: solution discharge pipe 13: solution opening and closing valve
20: auxiliary container 21: storage
30: heating element 30a: heating element 30S: heating element
40: opening and closing valve 41: solution inlet pipe
50: reservoir 51: water pipe 52: drain pipe
60: circulation member
70, 80: hot water heater 70a, 80a: through hole 70b, 85a: discharge hole
71,85: discharge tube
100: heat storage heater heated by chemical reaction heat

Claims (11)

It has a lid (7) formed with an exhaust port (7a), the opening 11 is formed in the upper portion is formed and the receiving space portion (A) formed therein, and the heating element is accommodated in the receiving space portion (A) Exothermic reaction, and transfers the heat of reaction generated at this time to the outside of the body, and when the exothermic reaction is completed, the waste heat generating solution is guided to the solution discharge pipe 12 provided in the lower part to discharge the solution to the outside (13) Reaction vessel 10 comprising a;

An auxiliary container 20 which is inserted and detachably inserted into the accommodation space A, and has a plurality of through holes 20a formed on the side and bottom of the container, and accommodates the heat generating metal body;

A heating element (30) comprising a heat generating metal body (30a) and a heat generating material (30S) for heating the low temperature water contained in the water storage tank (50) by being accommodated in the accommodation space (A);

The solution inlet tube 41 and the solution are connected to the assembly hole (10a) formed on the upper end side of the body of the reaction vessel 10 and the solution storage tank (T) so that the exothermic material 30S in the solution state is introduced into the reaction vessel. On and off valve 40 for opening and closing the inlet pipe 41;

The reaction vessel 10 includes a body, and forms a closed space outside the reaction vessel 10 to fill and store the low temperature water introduced into the drain pipe 51 provided at the bottom, and stores the stored low temperature water in the reaction vessel. A water tank 50 heated to a high temperature by 10 and discharged to the outside through a water supply pipe 52 provided at an upper portion thereof;

A bypass pipe 61 connected from the upper portion U of the water storage tank 50 to the lower portion L; And a circulation pump 62 connected to the bypass pipe 61 for forcibly circulating high temperature hot water present in the upper portion U of the reservoir 50 to the lower portion L of the reservoir 50. A circulation member 60; A regenerative heater that is heated by chemical reaction heat, which further comprises a structure. The method of claim 1,
The heating element is composed of a heat generating metal body and a heating material, and a sufficient amount of heat generating metal body inside the auxiliary container so as to be replaced so that it can be recycled until the end of life, and the heating material is reacted from the outside whenever necessary. A regenerative heater heated by chemical reaction heat, characterized in that for exothermic reaction with the exothermic metal body by supplying it inside. The regenerative heater of claim 1 or 2, wherein an absorbent fabric layer is formed inside the auxiliary container to prevent the exothermic metal body from being lost to the outside. The method of claim 1, wherein the pyrogenic metal body is any one selected from aluminum (Al), zinc (Zn), magnesium (Mg), or at least one of the metals. Regenerative heater heated by the heat of chemical reaction, characterized in that the alloy containing or at least one mixed metal containing. The regenerative heater according to any one of claims 1 to 4, wherein the exothermic metal body is plated by pressurizing and plating any one or more metals selected from powder, granular and granular particles. The heat storage type heater according to any one of claims 1 to 5, wherein the heat generating metal body is heated by chemical reaction heat and inserted into an absorbent fabric bag for preventing loss of the exothermic metal body to the outside. The method of claim 1, wherein the heating material is sodium hydroxide (NaOH), the content of which is heated by the heat of chemical reaction, characterized in that the content of 10 to 80 parts by weight based on the whole composition. Regenerative radiators. 8. The heat storage type according to any one of claims 1, 2, and 7, wherein the exothermic material contains a fragrance in an amount of 0.001 to 20% by weight of the whole composition. fire. The method according to claim 8, wherein the fragrance is a linden flower, licorice, pereirian, peppermint, lavender, lemongrass, mint, Lemon verbena, thyme, rosemary, mate, marigold, orange peel, wild strawberry, orange blossom ), Sage, basil, rosepinT, marrow, blacT tea, jasmine, valerian, bergamot, chamomile Cedarwood virginia, cinnamon, clary sage, cypress, eucalyptus, funnel, frankincense, geranium, grapefruit Fruitfruit, hyssop, juniper, lemon, lime, marjoram, myrrh, palmarosa, patchy fragrances and strings such as ouli, rose absolute, sandalwood, sandalwood, tea-tree, ylang ylang, ginger, rose, cardamom Nella, bamboo, pine needles, mugwort, cedar, chrysanthemum, fir, cherries, cypress, cypress, cinnamon, peppermint, citrus extract, or vinegar solution A regenerative heater heated by chemical reaction heat, characterized in that the mixture. It has a lid (7) formed with an exhaust port (7a), the opening 11 is formed in the upper portion is formed and the receiving space portion (A) formed therein, and the heating element is accommodated in the receiving space portion (A) Exothermic reaction, and transfers the heat of reaction generated at this time to the outside of the body, and when the exothermic reaction is completed, the waste heat generating solution is guided to the solution discharge pipe 12 provided in the lower part to discharge the solution to the outside (13) Reaction vessel 10 comprising a;

An auxiliary container 20 which is inserted and detachably inserted into the accommodation space A, and has a plurality of through holes 20a formed on the side and bottom of the container, and accommodates the heat generating metal body;

A heating element (30) comprising a heat generating metal body (30a) and a heat generating material (30S) for heating the low temperature water contained in the water storage tank (50) by being accommodated in the accommodation space (A);

The solution inlet tube 41 and the solution are connected to the assembly hole (10a) formed on the upper end side of the body of the reaction vessel 10 and the solution storage tank (T) so that the exothermic material 30S in the solution state is introduced into the reaction vessel. On and off valve 40 for opening and closing the inlet pipe 41;

The reaction vessel 10 includes a body, and forms a closed space outside the reaction vessel 10 to fill and store the low temperature water introduced into the drain pipe 51 provided at the bottom, and stores the stored low temperature water in the reaction vessel. A water tank 50 heated to a high temperature by 10 and discharged to the outside through a water supply pipe 52 provided at an upper portion thereof;

A bypass pipe 61 connected from the upper portion U of the water storage tank 50 to the lower portion L; And a circulation pump 62 connected to the bypass pipe 61 for forcibly circulating high temperature hot water present in the upper portion U of the reservoir 50 to the lower portion L of the reservoir 50. Circulating member 60,

And a reaction base 10 embedded in the storage tank 50 and incorporating a heating element 30, and integrally integrated with the storage tank 50 to the outside of the reaction vessel 10 to store the water tank ( A hot water supply body 70 for isolating a portion of the cold water stored in 50); The hot water of the hot state rapidly heated to a high temperature by the reaction vessel 10 in the state of being separated in the hot water supply body 70 is led to the upper portion of the water storage tank 50, the discharge formed on the hot water supply body 70 Through-holes formed at the lower side of the hot water supply body 70 to supply hot water of high temperature to the water supply pipe 52 provided in the upper portion of the reservoir tank 50 and the upper portion of the reservoir tank 50 through the tube 71 A portion of the cold water stored in the lower portion of the water storage tank 50 is introduced and separated through the 70a, and the isolated cold water is rapidly heated by the reaction vessel 10, and the heated hot water is heated to the top of the hot water heater. Regenerative type heated by chemical reaction heat, further comprising; a hot water heater (70) for inducing, to diffuse to the upper portion of the water tank (50) through the discharge hole (70b) and the discharge tube 71 formed on the hot water heater fire. It has a lid (7) formed with an exhaust port (7a), the opening 11 is formed in the upper portion is formed and the receiving space portion (A) formed therein, and the heating element is accommodated in the receiving space portion (A) Exothermic reaction, and transfers the heat of reaction generated at this time to the outside of the body, and when the exothermic reaction is completed, the waste heat generating solution is guided to the solution discharge pipe 12 provided in the lower part to discharge the solution to the outside (13) Reaction vessel 10 comprising a;

An auxiliary container 20 which is inserted and detachably inserted into the accommodation space A, and has a plurality of through holes 20a formed on the side and bottom of the container, and accommodates the heat generating metal body;

A heating element (30) comprising a heat generating metal body (30a) and a heat generating material (30S) for heating the low temperature water contained in the water storage tank (50) by being accommodated in the accommodation space (A);

The solution inlet tube 41 and the solution are connected to the assembly hole (10a) formed on the upper end side of the body of the reaction vessel 10 and the solution storage tank (T) so that the exothermic material 30S in the solution state is introduced into the reaction vessel. On and off valve 40 for opening and closing the inlet pipe 41;

The reaction vessel 10 includes a body, and forms a closed space outside the reaction vessel 10 to fill and store the low temperature water introduced into the drain pipe 51 provided at the bottom, and stores the stored low temperature water in the reaction vessel. A water tank 50 heated to a high temperature by 10 and discharged to the outside through a water supply pipe 52 provided at an upper portion thereof;

A bypass pipe 61 connected from the upper portion U of the water storage tank 50 to the lower portion L; And a circulation pump 62 connected to the bypass pipe 61 for forcibly circulating high temperature hot water present in the upper portion U of the reservoir 50 to the lower portion L of the reservoir 50. Circulating member 60,

And a hot water supply body 80 configured to pass through the inside of the reaction vessel 10 and arranged inside the reaction vessel 10 to isolate a part of the low temperature water stored in the water storage tank 50; The hot water of the hot water rapidly heated at a high temperature by the heat generating element 30 accommodated in the reaction vessel 10 is insulated from the hot water main body 80 to the upper portion of the water storage tank 50, and the hot water main body 80 Hot water of high temperature is supplied to the water supply pipe 52 provided in the upper portion of the reservoir 50 and the upper portion of the reservoir 50 through a discharge tube 85 formed to extend from the upper portion to be exposed to the outside of the reaction vessel 10. The supply and supply of a portion of the low-temperature water stored in the lower portion of the reservoir 50 through the through hole (80a) formed in the lower side of the hot water supply body 80, and isolates the isolated low-temperature water reaction vessel (10) The rapid heating by the heating element 30 accommodated in the), the heated hot water is led to the upper portion of the hot water heater, through the discharge tube 85 and the discharge hole (85a) provided in the upper portion of the water heater to the upper portion of the water tank (50) In the heat of chemical reaction, characterized in that it further comprises a hot water heater 80 for diffusing Regenerative radiators heated by.

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