KR20100053495A - Slurry transfer by freshwater and recirculation system for utilization of ashes from coal firing plant - Google Patents

Slurry transfer by freshwater and recirculation system for utilization of ashes from coal firing plant Download PDF

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KR20100053495A
KR20100053495A KR1020100038308A KR20100038308A KR20100053495A KR 20100053495 A KR20100053495 A KR 20100053495A KR 1020100038308 A KR1020100038308 A KR 1020100038308A KR 20100038308 A KR20100038308 A KR 20100038308A KR 20100053495 A KR20100053495 A KR 20100053495A
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ash
water
slurry
coal
fly ash
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Korean (ko)
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류선영
유상우
유봉호
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류선영
유상우
유봉호
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D17/00Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
    • B01D17/08Thickening liquid suspensions by filtration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D47/00Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65GTRANSPORT OR STORAGE DEVICES, e.g. CONVEYORS FOR LOADING OR TIPPING, SHOP CONVEYOR SYSTEMS OR PNEUMATIC TUBE CONVEYORS
    • B65G2201/00Indexing codes relating to handling devices, e.g. conveyors, characterised by the type of product or load being conveyed or handled
    • B65G2201/04Bulk
    • B65G2201/045Sand, soil and mineral ore
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/16Nature of the water, waste water, sewage or sludge to be treated from metallurgical processes, i.e. from the production, refining or treatment of metals, e.g. galvanic wastes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete
    • Y02W30/92

Abstract

PURPOSE: A system for transferring slurry using the fresh water and recycling water to utilize fly ash which is exhausted in coal combustion is provided to minimize the use of industrial water, collect fly ash from an ash pond, and use the fly ash as aggregate. CONSTITUTION: A system for transferring slurry using the fresh water and recycling water to utilize fly ash which is exhausted in coal combustion is constituted as follows. Bottom ash and fly ash which have different constituent particles are separated. The slurry using the fresh water is transferred to an ash pond. Leachate is filtered, neutralized within PH 7~9 range, and recirculated.

Description

석탄 연소 시 배출되는 석탄회를 활용하기 위한 담수 사용의 슬러리 이송 및 용수의 재순환 시스템{Slurry Transfer by Freshwater and Recirculation System for Utilization of Ashes from Coal Firing Plant}Slurry Transfer by Freshwater and Recirculation System for Utilization of Ashes from Coal Firing Plant}

본 발명은 석탄회가 배출되는 발전소나 제철, 제련소 등의 습식공정의 회처리 설비에서 해수가 아닌 담수를 사용하여 저회(Bottom Ash) 및 비회(Fly Ash) 슬러리(Slurry)로 분리 생성하고 이송시켜 회처리장에서 별도의 선별 공정이나 염분 제거 공정 없이 석탄회를 용이하게 반출하기 위한 방법으로, 소내 폐수정화 설비의 배출수와 우수관 배수 및 회처리장 침출수의 여과 및 중화설비 배출수를 재순환시켜 석탄회 슬러리 생성과 이송을 위해 사용하기 위한 공정이다.The present invention separates the ash ash and fly ash slurry into the ash ash and fly ash slurry by using fresh water, not seawater, in a power plant or a wet process such as a steelmaking or smelting plant where coal ash is discharged. It is a method to easily take out coal ash without separate sorting process or desalination process in the treatment plant. It is a process to use.

석탄의 연소열을 이용하는 발전소나 제철, 제련소에서 배출되는 석탄회는 연소 보일러 하부로 낙하하는 저회(Bottom Ash)와 배기가스에 혼입되어 절탄기나 공기예열기 그리고 전기집진기 등에서 포집되는 비회(Fly Ash)로 대별되는데 일부, 건조 상태에서 추출, 재활용하는 경우도 있으나 상당량의 석탄회는 해수를 사용한 슬러리를 회처리장으로 이송시켜 침전, 매립하고 있어서 넒은 회처리장이 필요하고 또한 회를 재사용할 경우 염분의 제거나 선별공정이 필요하여 적지않은 비용이 발생하기 때문에 일반 골재로의 활용이 여의치 않다.Coal ash discharged from power plants, steelmaking, and smelters using coal's combustion heat is classified into bottom ash falling to the bottom of the combustion boiler and fly ash, which is mixed in the exhaust gas and collected by a coal cutter, an air preheater, and an electrostatic precipitator. Although some of them are extracted and recycled in a dry state, a significant amount of coal ash is deposited and reclaimed by transporting slurry using seawater to the treatment plant, which requires a large treatment plant. It is not suitable to use as general aggregate because it requires a lot of cost.

발전소나 제철, 제련소에 공급되는 공업용수는 보충수로만 사용하고 우수관 배수와 소내 폐수정화 설비의 배출수, 회처리장에서 슬러리 침출수에 대한 여과와 중화 공정에 따른 적정의 PH 유지 중화수를 재순환 시켜 슬러리 생성과 이송용으로 사용하면 공업 용수의 절감은 물론, 오염물질의 배출을 최대한 억제하게 되어 친환경 설비로 운용될 수 있다. Industrial water supplied to power plants, steelworks, and smelters is used only as supplemental water. Slurry is generated by recycling the drainage of rainwater pipes, effluents from in-house wastewater purification facilities, and filtration of slurry leachate in the ash treatment plant and recycling the neutralized water in proper pH according to the neutralization process. When used for the transfer and transport, as well as the reduction of industrial water, and to minimize the emission of pollutants can be operated as an environmentally friendly facility.

해당내용이 없습니다.There is no corresponding information.

해당내용이 없습니다.There is no corresponding information.

해수를 사용한 저회(Bottom Ash)와 비회(Fly Ash)의 슬러리를 회처리장으로 보내는 경우 넓은 면적의 매립용 회처리장이 건설되어야 하고 또한 회의 재사용 시 염분 제거설비가 추가되어야 하므로 비 경제적임을 알 수 있는데, 본 발명은 소내 폐수 정화설비 배출수와 우수관 배수 및 회처리장 침출 여과.중화수를 재순환시켜 석탄회 슬러리 생성과 이송으로 사용하므로 공업용수의 사용을 최소화하면서 회처리장에서 용이하게 석탄회를 채취, 골재로 활용할 수 있게 한 공정이다.When the slurry of bottom ash and fly ash using seawater is sent to the ash processing plant, it can be seen that it is uneconomical because a large landfill ash processing plant has to be constructed and the salt removal equipment must be added when the ash is reused. In the present invention, the wastewater purification facility effluent and rainwater pipe drainage and leachate leaching filtration. The recycled neutralized water is used for coal ash slurry generation and transport, so coal ash is easily collected and recycled in the ash processing plant while minimizing the use of industrial water. It is the process that made it possible.

습식 회처리 방식에서 슬러리 생성 및 이송에 해수가 아닌 담수를 사용하는 방법으로, 외부에서 공급되는 공업용수는 보충수로 한정하고, 소내 폐수 정화설비의 배출수와 우수관 배수 및 회처리장에서의 침출수 여과 및 중화수를 재 순환시켜 용수로 사용한다.In the wet ashing method, fresh water, not seawater, is used to generate and transport slurry, and the industrial water supplied from outside is limited to supplemental water. Recirculate the neutralized water and use it as water.

일반적으로 분쇄기를 통과한 저회(Bottom Ash)의 입자는 10~20mm 크기로 비회(Fly Ash)에 비해 매우 큰 편이므로 회처리장에서 섞이지 않도록 별도의 슬러리 펌프와 이송관을 사용하여 회처리장으로 보내고, 비회용 슬러리와 혼합되지 않도록 격벽을 설치하되, 두 종류의 슬러리에서 배출되는 침출수는 합쳐져서 여과 및 중화설비를 경유하도록 한다.In general, the bottom ash particles passed through the grinder are 10-20 mm in size and are much larger than fly ash, so they are sent to the ash processing plant using a separate slurry pump and transfer pipe so as not to mix in the ash processing plant. Bulkheads are to be provided so as not to mix with non-recyclable slurries, but the leachate discharged from both slurries is combined to pass through filtration and neutralization facilities.

보일러 하부에 있는 외부 공기 흡입 차단을 위한 수조에는 해수가 아닌 공업용수나 재순환 용수로 채워서 저회(Bottom Ash)에 염분이 섞이지 않도록 한다.The tank to block external air intake at the bottom of the boiler is filled with industrial or recycled water, not sea water, to prevent salt from mixing in bottom ash.

소내 폐수 정화 설비의 배출수와 우수관 배수는 별도의 저수조(Pond)에 모이도록 하여 펌프를 사용, 재순환 시키는데, 장마철이나 우기에 다량의 우수가 유입될 경우 바다로 배출될 수 있는 Overflow Weir를 설치한다.The discharge water and rainwater pipe drainage of the facility's wastewater purification facility are collected in a separate pond to use and recycle the pump. An overflow weir, which can be discharged to the sea when a large amount of rainwater enters during the rainy season or rainy season, is installed.

회처리장의 저회 슬러리와 비회 슬러리에서 배출되는 침출수는 한군데로 모이도록 하고 이를 여과 후 PH 7~9 범위로 중화시켜 별도의 저수조에 모아, 펌프로 재 순환 시키는데, 만약 우수로 인해 다량이 배출수가 발생할 경우 바다로 배출되도록 Overflow Weir를 설치한다.  Leachate discharged from the low ash slurry and ash ash of the treatment plant is collected in one place, and after filtration, it is neutralized to the pH range of 7-9 and collected in a separate reservoir to be recycled to the pump. In this case, install overflow weir to discharge to the sea.

발전소나 제철,제련소에서 석탄 연소 후 생성되는 저회 및 비회를 단순한 매립용이 아닌 골재로 재활용할 수 있을 뿐만 아니라 회처리장의 규모를 소형화할 수 있으며, 소내의 폐수 정화설비 배출수와 우수관 배수 및 회처리장에서의 여과,중화수를 재순환시켜 슬러리 생성 및 이송용으로 사용하게 되므로 석탄회의 골재 활용이 수월하고 소내에서 예상되는 오염 발생을 최소화시킬 수 있어서 친환경적인 공정으로 운용할 수 있다.The low ash and fly ash produced after burning coal in power plants, steel and smelters can be recycled into aggregates, not just landfills, and the size of ash treatment plants can be reduced. It is used for slurry generation and transport by recycling filtration and neutralized water in coal, so it is easy to utilize coal ash aggregates and minimize the expected generation of pollution in the plant, so it can be operated as an environmentally friendly process.

[도 1]은 담수사용에 의한 저회 및 비회 슬러리 생성과 이송으로 회처리장에서 골재용으로 사용될 석탄회 반출의 용이성과 각종 배출수 및 여과,중화수를 재 순환시켜 용수로 활용하기 때문에 공업용수의 사용을 줄이게 되어 오.폐수발생을 최소화시킬 수 있는 친환경적인 공정을 보여주고 있음.[1] shows the use of fresh water to reduce the use of industrial water because it is easy to take out the coal ash to be used for the aggregate in the ash processing plant and recycled various effluents, filtration and neutralized water by using fresh water. It shows an eco-friendly process that can minimize the generation of waste water.

제철, 제련소를 비롯, 대형 화력 발전소의 경우 석탄을 사용, 화로에서 연소시켜 그 열을 이용한 고온 고압의 증기로 터빈,발전기를 돌려 전력을 생산하거나 증기가 필요한 공정에 사용하고 있어서 다량의 석탄회가 발생, 이들의 처리공정이 반드시 갖추어져야 하는 중요한 설비중의 하나로 간주하고 있다.In the case of steel and smelters, large coal-fired power plants use coal to burn in a furnace and use high temperature and high pressure steam using the heat to turn turbines and generators to produce electricity or to use steam in processes that require large amounts of coal ash. It is regarded as one of the important facilities that these treatment processes must be equipped with.

석탄회는 일반적으로 보일러 하부로 낙하하는 저회(Bottom Ash)와 공기예열기나 전기집진기 등에서 미세한 입자로 포집되는 비회(Fly Ash)로 대별되는데, 이들을 건조한 상태로 소내에서 반출, 활용하는 경우도 있으나 다량의 석탄회를 연속적으로 처리하는 데는 한계가 있어서 석탄을 사용한 발전소나 제철, 제련소의 경우 이들 회를 슬러리로 만들어 별도의 회처리장으로 이송시키고 침전시키는 공정을 갖추고 있어야 한다.Coal ash is generally classified into bottom ash falling to the bottom of the boiler and fly ash which is collected as fine particles in an air preheater or electrostatic precipitator, which are often taken out and used in a dry state. There is a limit to the continuous treatment of coal ash, and in the case of coal-fired power plants, steelworks, and smelters, it is necessary to have a process for slurrying these ashes into slurry and transferring them to a separate ash processing plant.

사용되는 석탄의 10~20% 정도가 저회와 비회로 배출되어 대부분 해수를 사용한 슬러리 생성 후 회처리장으로 이송을 하게 되는데, 회처리장에서 석탄회를 골재용으로 활용하기 위해서는 염분을 제거하는 공정이 필요하고 또한 저회와 비회 부분으로 분류하는 공정을 갖추어야 하기 때문에 그 활용에는 한계가 있다.About 10 ~ 20% of the coal used is discharged to low ash and non-circle, and most of them produce slurry using sea water and then transfer to ash processing plant.In order to utilize coal ash for aggregate, it is necessary to remove salt. In addition, there is a limit to its use because it must have a process to classify it into the low and the non-hoe.

따라서 이번 발명은 회처리장에서의 염분 제거 공정과 회 입자 크기에 따른 선별공정 없이 곧바로 채취, 골재로 활용할 수 있도록 해수가 아닌 담수를 사용하고, 저회 및 비회를 분리시켜 슬러리를 생성하며, 분리된 회처리장으로 이송하는 방법으로, 여기에 필요한 다량의 용수는 회처리장 침출수의 여과,중화수를 포함, 소내 폐수 정화 설비의 배출수 및 우수관 배수를 재순환시켜 사용하므로 공업용수의 사용을 최소화하는 공정으로 설계한 것이다.Therefore, the present invention uses freshwater, not seawater, to collect and aggregate as salt without removing the salt and ashing process in ash processing plant. The large amount of water required for this process is designed to minimize the use of industrial water because the large amount of water required for this is recycled by effluent from the treatment plant and neutralized water. will be.

결국 해수가 아닌 담수를 사용한 석탄회의 이송은 골재로 재활용될 수 있는 석탄회의 채취를 용이하게 할 뿐만 아니라 공업용수의 사용을 줄이면서 소내에서 발생하는 오.폐수의 양을 줄이고 바다로 배출되는 각종 오염물질을 없앨 수 있어서 친환경적인 공정으로 운용할 수 있다. As a result, the transfer of coal ash using fresh water rather than seawater not only facilitates the collection of coal ash, which can be recycled as aggregate, but also reduces the amount of wastewater generated in the site while reducing the use of industrial water and various pollutions emitted to the sea. The material can be eliminated and operated in an environmentally friendly process.

습식방식에 따른 석탄회를 처리하는 대부분의 화력 발전소나 제철, 제련소의 회처리장에서 골재로 활용할 수 있는 석탄회의 용이한 채취 및 공업용수의 사용을 줄이고 오.폐수 발생을 최소화할 수 있는 공정으로의 전환. Coal ash, which can be used as aggregate in most coal-fired power plants, or in steel and smelters, which process wet coal, is converted to a process that can reduce the use of industrial water and minimize the generation of wastewater. .

Claims (2)

해수를 사용하지 않고, 소내 폐수 정화설비 배출수와 우수관 배수 및 회처리장 침출수의 여과,중화 배출수를 재순환시켜 공업용수 사용을 최소화하면서 담수를 사용한 석탄회 슬러리 생성 및 이송하는 방법. A method of producing and transporting coal ash slurry using fresh water while minimizing the use of industrial water by circulating effluent from the wastewater purification facility and rainwater pipe drainage and leachate leachate without neutralizing seawater. [청구항 1]에 따른 공정에 의해 운반되는 슬러리를 저회(Bottom Ash)와 비해(Fly Ash)용으로 분리, 개별 이송 파이프를 통해 분리벽을 사용한 저회-비회 처리장으로 보내서 침전 후 염분제거나 선별공정 없이 석탄회 채취를 용이하게 하는 방법.The slurry transported by the process according to [Claim 1] is separated for fly ash and bottom ash, and is sent to a low ash fly ash treatment plant using a separation wall through a separate transfer pipe to be salted or sorted after precipitation. How to facilitate coal ash harvesting without.
KR1020100038308A 2010-04-26 2010-04-26 Slurry transfer by freshwater and recirculation system for utilization of ashes from coal firing plant KR20100053495A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019231092A1 (en) * 2018-06-01 2019-12-05 현대건설주식회사 Method for neutralizing dredged soil washed with acid

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019231092A1 (en) * 2018-06-01 2019-12-05 현대건설주식회사 Method for neutralizing dredged soil washed with acid
CN112334241A (en) * 2018-06-01 2021-02-05 现代建筑工程有限公司 Method for neutralizing acid-washed dredged soil

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