KR20100035025A - Fuctional wall paper and its manufacturing method - Google Patents

Fuctional wall paper and its manufacturing method Download PDF

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KR20100035025A
KR20100035025A KR1020080094311A KR20080094311A KR20100035025A KR 20100035025 A KR20100035025 A KR 20100035025A KR 1020080094311 A KR1020080094311 A KR 1020080094311A KR 20080094311 A KR20080094311 A KR 20080094311A KR 20100035025 A KR20100035025 A KR 20100035025A
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South Korea
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powder
weight
wallpaper
mixture
functional
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KR1020080094311A
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Korean (ko)
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백우현
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(주)디에스산업
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/346Clay
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J103/00Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
    • C09J103/02Starch; Degradation products thereof, e.g. dextrin
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Paper (AREA)

Abstract

The present invention relates to a functional wallpaper for wallpaper and a method for manufacturing the same, and more particularly, to suppress the generation of wallpaper mold by moisture, has antibacterial and deodorizing functions, radiates far infrared rays and anions, and excludes the use of chemical adhesives. By doing so, the present invention relates to a functional wallpaper for wallpaper that can more comfortably maintain the indoor space of a house, and a manufacturing method thereof.

The present invention comprises a crushing step of crushing the bark and bentonite mineral to be processed into a powder; A powder mixture of 30 to 70% by weight of starch powder, 10 to 30% by weight of koi powder, 1 to 10% by weight of pine needle powder, 10 to 20% by weight of bentonite mineral powder, and 1 to 10% by weight of brown root powder, A mixing step of mixing at a volume ratio of 1: 4 to 1: 6; A stirring step of heating the mixture of Jiji water and the powder to 100 ° C. and stirring for 15 to 30 minutes; Aging step of naturally aging the heated and stirred mixture at room temperature for 18 to 20 hours; by including, to suppress the occurrence of mold in the wallpaper, antibacterial and deodorizing function, to keep the room pleasant by radiating far infrared rays and anions Can be.

Description

Functional paper for wallpaper and its manufacturing method {Fuctional wall paper and its manufacturing method}

The present invention relates to a functional wallpaper for wallpaper and a method for manufacturing the same, and more particularly, to suppress the generation of wallpaper mold by moisture, has antibacterial and deodorizing functions, radiates far infrared rays and anions, and excludes the use of chemical adhesives. By doing so, the present invention relates to a functional wallpaper for wallpaper that can more comfortably maintain the indoor space of a house, and a manufacturing method thereof.

In general, the interior walls or floors of residential or office buildings, such as apartments and houses, are finished with cement mortar, and then painted with a medium or wallpaper.

Conventionally, starch-based dopant pools in which chemical adhesives such as formalin, hydrochloric acid, and other chemicals are used as the main components when used on the wall surface are mainly used. The chemical adhesives have strong adhesive strength and can be quickly cured. Most commonly used as starch starch pools.

However, the glueing paste containing the chemical adhesive has a bad effect on the human body, such as dermatitis and respiratory diseases as the harmful ingredients and smells are severely generated in the human body, as well as a lot of time to neutralize the toxicity generated from the adhesive even after the coating. Because of this, there was a limit to creating a pleasant living environment.

 In addition, there is a problem that the inhabitants are caused by respiratory diseases and dermatitis due to the toxic continuously generated from the concrete, as well as harmful components and odors generated by the chemical adhesive.

In addition, starch seedling paste is produced in a gel state by kneading starch with water, so when the starch paste is distributed for a long time, the seedling paste is easily decayed, and in winter, mold on the wallpaper due to condensation occurs. In the summer, there was a problem that mold occurs on the wallpaper due to moisture. In order to prevent the occurrence of mold on the wallpaper, antiseptics are added to prevent the occurrence of mold on the wallpaper. There were problems that occurred.

The present invention has been made in order to solve the above problems, excludes the use of chemical adhesives and preservatives that cause harmful components and odors to the human body, and manufactures wallpaper papers using natural materials harmless to the human body Construction prevents the release of harmful substances to the human body, prevents the occurrence of mold on the wallpaper, neutralizes the pollutants generated in concrete, etc. It is an object of the present invention to provide.

In order to achieve the above object, the present invention comprises a crushing step of crushing the bark and bentonite mineral processing into powder; A powder mixture of 30 to 70% by weight of starch powder, 10 to 30% by weight of koi powder, 1 to 10% by weight of pine needle powder, 10 to 20% by weight of bentonite mineral powder, and 1 to 10% by weight of brown root powder, A mixing step of mixing at a volume ratio of 1: 4 to 1: 6; A stirring step of heating the mixture of Jiji water and the powder to 100 ° C. and stirring for 15 to 30 minutes; It comprises a aging step of naturally aging the heated and stirred mixture at room temperature for 18 to 20 hours; and comprises a method of producing a functional wallpaper for wallpaper.

In this case, the kerchi shell powder is preferably prepared by crushing the kerchi shell in a crusher after washing and drying the kerchi shell in an electric furnace at a temperature of 900 ~ 950 ℃ for 1 to 2 hours.

In addition, the functional paper for wallpaper according to the present invention is 30 to 70% by weight of starch powder, 10 to 30% by weight of pinot powder, 1 to 10% by weight of pine needle powder, 10 to 20% by weight of bentonite mineral powder and 1 to brown root powder. It consists of a powder mixture containing 10% by weight mixed.

The functional wallpaper for wallpaper according to the present invention configured as described above is harmless to the human body by constituting the wallpaper, excluding the use of chemicals, to suppress the occurrence of mold on the wallpaper, and to remove various contaminants in the room.

Hereinafter, the wallpaper for the wallpaper according to the present invention and a manufacturing method thereof will be described in detail.

The method for producing wallpaper for the wallpaper according to the present invention is largely composed of a crushing step, mixing step, stirring step and aging step.

First, the crushed bark and bentonite minerals mined in Yeongil Bay are crushed with a crusher and then processed into a particle size powder of about starch-based powder to be mixed.

10 ~ 30% by weight of the oyster shell powder crushed through the crushing step, 10 ~ 20% by weight bentonite mineral powder, 30 ~ 70% by weight starch powder, 1 ~ 10% by weight pine needle powder and 1 ~ 10% by weight of brown root powder A mixing step of mixing the mixed powder mixture and jijangsu at a volume ratio of 1: 5 is performed.

[Table 1] Main ingredient list of cockle shell powder

Test Items result calcium 37601.35mg / 100g moisture 0.03% Escherichia coli voice salt 257.02mg / 100g magnesium 158.8mg / 100g zinc Not detected manganese 1.83mg / 100g Crude protein 0.42% lead Not detected

The cockle shell powder consisting of the main components as shown in Table 1 is prepared by the following method.

After inserting the bark taken from the clean water into the washer and washing it, the bark is calcined for 1 ~ 2 hours at 900 ~ 950 ℃ in an electric furnace, and then the bark is crushed in a crusher to prepare the bark powder. .

At this time, it is preferable to bake at an temperature of 900 ℃ in the electric furnace, the pore bark fired at the temperature of 800 ℃ was a state that the entire surface of the organic matter was not removed, as shown in Figure 1 of the pores that can exhibit the adsorption function There was not enough development. In addition, since the pore was calcined at a temperature of 1,000 ℃ as shown in Figure 2 pores are so developed that the strength of the shell is too difficult during the manufacturing process was difficult to use. On the other hand, the pore shell calcined at a temperature of 900 ℃ was satisfactory in the pore development and the removal of organic matter on the surface, as shown in Figure 3, the pores capable of the adsorption function was properly generated. Therefore, the most suitable firing temperature of the cortex is the temperature of 900-950 degreeC.

[Table 2] Main ingredient table of bentonite mineral powder

Element Result SiO 2 48.3644 (%) Al 2 O 3 26.9149 (%) Fe 2 O 3 18.1222 (%) K 2 O 2.8490 (%) TiO 2 1.5483 (%) MgO 0.8699 (%) MnO 0.2897 (%) SO 3 0.2422 (%) BaO 0.1492 (%) P 2 O 5 0.1372 (%) Na 2 O 0.0939 (%) ZrO 2 0.0929 (%) Cr 2 O 3 0.0711 (%) ZnO 0.0642 (%) Rb 2 O 0.0480 (%) SrO 0.0467 (%) NiO 0.0380 (%) CaO 0.0322 (%) Co 2 O 3 0.0261 (%)

The main constituent mineral of the bentonite mineral composed of the main components shown in Table 2 is Montmorillonite, and a general chemical formula is [(Al.Fe) 1.67 , Mg 0.33 ] Si 4 O 10 (OH) 2 (Na 0.33 ) It is composed of a little difference depending on the crystal structure. The crystal structure of montmorillonite has a layered structure as shown in FIG. 4, and is a 2: 1 type structure having one octahedral layer between two tetrahedral layers as a three-layer structure.

In the tetrahedral Si +4 ions of the bentonite as described above, the negative charges are co-substituted by Al 3+ ions and Mg +2 and Fe 2+ ions instead of Al 3+ and Fe +3 ions in the octahedron. Negative change occurs and Na + , Ca +2 , Mg +2 , H + ions are weakly attached to neutralize harmful substances.

As described above, the bentonite molecular structure is a multilayer structure, and spaces are formed at both ends of the multilayer structure, which are called both pores, and the far-infrared region in the empty space is processed by processing the bentonite to create more empty space inside the bentonite. Can store energy, and the empty space makes the adsorption force stronger.

Physical and chemical properties of the bentonite mineral powder as described above are shown in Table 3 below.

Table 3 Physicochemical Properties of Bentonite Minerals

division Bentonite Mineral structure 2: 1 gud Specific surface area (BET type) 35.3-48.15 importance 2-3 (hydration degree) Surface charge density (eq.) 1.33 Cation exchange capacity (meg / 100g) 80-150

In addition, pine needle powder and brown root powder used in the functional wallpaper for wallpaper of the present invention was purchased and used on the Chinese herbal medicine and the ingredient table of each powder is shown in Tables 4 and 5.

[Table 4] Main ingredient list of pine needle powder

ingredient content CuO 18.2002% K 2 O 18.0291% NiO 16.8781% CaO 15.9228% ZnO 5.05286% SO 3 5.03512% P 2 O 5 4.05998% SiO 2 3.0129% MnO 2.7188% MgO 2.4923% Cl 2.1932% PbO 1.8696% Fe 2 O 3 1.4653% Al 2 O 3 0.9870% Na 2 O 0.4399% SrO 0.3110%

[Table 5] Major Ingredients of Brown Root Powder

ingredient content CaO 37.7597% K 2 O 16.0076% MgO 9.9545% CuO 8.3227% P 2 O 5 7.0211% NiO 5.08832% SO 3 4.7490% ZnO 2.6117% SiO 2 1.8267% SrO 1.5975% Fe 2 O 3 1.2402% PbO 0.9978% BaO 0.8491% Al 2 O 3 0.5916% Cl 0.4425% MnO 0.1452%

In addition, the starch-based powder may be used flour, potato powder or rubber powder commonly used in the market.

In addition, the number of jijangs added to the powder mixture of the starch powder, chokje powder, pine needle powder, bentonite mineral powder and brown root powder can be used a general Jijisu, preferably Jijisu purified in the water purification system of Patent No. 565162 It is preferable to use because it can reduce the number of bacteria.

As described above, a mixture of the powder mixture and Jiji water is gradually heated to a temperature of 100 ° C., followed by a stirring step of heating and stirring for 15 minutes so that the mixture is in a gel state, and the mixture in the gel state is 18 to 20. By performing the step of aging in a natural state for 18 to 20 hours at a temperature or room temperature of ℃ ℃ functional functional grass of the present invention is prepared.

In the process of heating and stirring as described above, the jijangsu mixed with the powder mixture is evaporated to reduce the amount of the jijangsu mixed.

(Example)

A powder mixture of 70% by weight of wheat flour, 10% by weight of pinnacle powder, 5% by weight of pine needle powder, 5% by weight of brown root and 10% by weight of bentonite mineral powder, and the powder mixture and jijangsu at a volume ratio of 1: 5 After stirring and heating for 30 minutes at a temperature of 100 ℃ in a stirred tank to prepare a paper paste aged for 20 hours.

Far-infrared emissivity, anion test, deodorization test, antimicrobial test and antifungal test of Dobae grass prepared as described above and the results are shown in the following table.

[Table 6] Measurement results of far-infrared emissivity and radiation energy

Figure 112008067538438-PAT00001

Table 7 Anion Test Result

Figure 112008067538438-PAT00002

[Table 8] Ammonia deodorization test results

Figure 112008067538438-PAT00003

[Table 9] Antibacterial test results

Figure 112008067538438-PAT00004

Table 10 Antifungal Test Results

Figure 112008067538438-PAT00005

As in the above experimental results, the functional dopantul according to the present invention has far-infrared rays and anions radiated, has a deodorizing function, and has an antibacterial and antifungal function to keep the room comfortable.

The functional wallpaper for wallpaper according to the present invention and its manufacturing method have been described above. It will be understood by those skilled in the art that the technical features of the present invention may be embodied in other specific forms without departing from the spirit or essential characteristics thereof.

Therefore, the above-described embodiments are to be understood in all respects as illustrative and not restrictive, and the scope of the present invention is indicated by the following claims rather than the foregoing description, and the meanings of the claims and All changes or modifications derived from the scope and equivalent concepts thereof should be construed as being included in the scope of the present invention.

BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is an enlarged view of the bark of bark baked at a temperature of 800 ° C.

Fig. 2 is an enlarged view of the corticobark fired at a temperature of 1,000 ° C.

Fig. 3 is an enlarged view of the scab shell baked at a temperature of 900 ° C.

4 is a structural diagram of bentonite mineral;

Claims (3)

A crushing step of crushing the bark and bentonite mineral into a powder; A powder mixture of 30 to 70% by weight of starch powder, 10 to 30% by weight of koi powder, 1 to 10% by weight of pine needle powder, 10 to 20% by weight of bentonite mineral powder, and 1 to 10% by weight of brown root powder, A mixing step of mixing at a volume ratio of 1: 4 to 1: 6; A stirring step of heating the mixture of Jiji water and the powder to 100 ° C. and stirring for 15 to 30 minutes; A method of producing a functional wallpaper for wallpaper, comprising: a aging step of naturally aging the stirred mixture at room temperature for 18-20 hours. The method of claim 1, The cockle shell powder is washed and dried by putting in a washing machine, and then the cockle shell is calcined for 1 to 2 hours at a temperature of 900 ~ 950 ℃ in an electric furnace, and then the cockle shell is crushed in a crusher, characterized in that the functional for wallpaper How to prepare seedling paste. It contains a powder mixture of 30 to 70% by weight of starch powder, 10 to 30% by weight of koi powder, 1 to 10% by weight of pine needle powder, 10 to 20% by weight of bentonite mineral powder and 1 to 10% by weight of brown root powder. A functional wallpaper for the wallpaper.
KR1020080094311A 2008-09-25 2008-09-25 Fuctional wall paper and its manufacturing method KR20100035025A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106916551A (en) * 2017-04-06 2017-07-04 合肥欧克斯新型建材有限公司 A kind of Wall paper adhesive and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106916551A (en) * 2017-04-06 2017-07-04 合肥欧克斯新型建材有限公司 A kind of Wall paper adhesive and preparation method thereof

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