KR20100014314A - Method of applying a composition - Google Patents

Abstract

There is provided herein, in one specific embodiment, a method of applying a trisiloxane-contaim'ng composition to the surface of a substrate comprising: applying to a surface of a substrate a composition comprising a trisiloxane of the general formula (1): MDM wherein M = RRRSi0, D = RRSiOin which Rand Reach independently is a monovalent, divalent or trivalent hydrocarbon radical possessing from 2 to 8 carbon atoms or a monovalent, divalent or trivalent hydrocarbon radical possessing from one to sixty carbon atoms other than from 2 to 8 carbon atoms, provided that at least one of Rand Ris a monovalent, divalent or trivalent hydrocarbon radical possessing from 2 to 8 carbon atoms, and R, R, Reach independently is a monovalent, divalent or trivalent hydrocarbon radical possessing from one to sixty carbon atoms other than from 2 to 8 carbon atoms.

Description

Composition application method {METHOD OF APPLYING A COMPOSITION}

Background of the Invention

(1) Field of invention

The present invention relates to a method of applying the composition.

(2) Detailed description of related technologies

Many industries and markets grow with the ability to supply multiple performance products made from mixtures of different components, each of which contains some final product package. Have a performance and compatibility profile that can lend important or desirable properties to final product formulations. In methods of applying the compositions, some desirable properties can be derived by using cyclic siloxanes in the formulation. Although cyclic siloxanes can provide some of these desirable properties, they are low viscosity, highly flowable liquids. Thus, the cyclic siloxanes are not easily fixed in the formulation, but rather are likely to flow across the skin and / or other substrates uncontrollably when separated from a given container or flow out of it, or when used for a particular application.

Cyclic siloxanes have limitations in terms of their performance and compatibility profile. Preferred performance and / or compatibility profiles with various desirable properties are not necessarily achievable by using cyclic siloxanes. Some applications may require other properties that cannot be met by using cyclic siloxanes.

For example, one of the drawbacks of the current state of the art is that numerous sprayable formulations can result in clogging of the spraying system, poor or coarse droplet formation, and non-uniform or poor With one coverage, they experience too much run-down on non-horizontal surfaces. Flowing down, for example, results in an unfavorable distribution of the beneficial components carried on any substrate, thereby transporting those components into areas that may be undesirable and / or resulting in an uneven distribution where they are needed. Can be. In addition, blockage of spraying nozzles can impose too much mechanical stress and lead to early wear down of the spraying systems. Coarse drops will result in nonuniform actives distribution. The resulting poor coverage will in turn result in lower performance attributes. Often ethanol is used as a dispersant, but it suffers from ancillary drying effects that can cause skin flakiness or inflammation in certain applications such as personal care. Therefore, there is a need for sprayable formulations that do not have the disadvantages described above.

Brief Description of the Invention

In this brief description, the present inventors, in one particular embodiment, comprise a trisiloxane (s) comprising certain trisiloxane (s) that can provide greatly improved physical properties to the trisiloxane-containing composition (s). Note that a method of applying the containing composition was unexpectedly found. In one embodiment of the invention, applying a trisiloxane-containing composition to the surface of the substrate, comprising applying to the surface of the substrate a composition comprising trisiloxane of formula (1) The method is provided:

MDM (1)

Where

M = R ^A R ^B R ^C SiO _1/2 ,

D = R ^D R ^F SiO _1/2 ,

Wherein R ^D and R ^F are each independently a monovalent, divalent or trivalent hydrocarbon radical having 2 to 8 carbon atoms, or at least one of R ^D and R ^F has 2 to 8 carbon atoms A monovalent, divalent or trivalent hydrocarbon radical having 1 to 60 carbon atoms, not 2 to 8 carbon atoms provided that it is a monovalent, divalent or trivalent hydrocarbon radical, and R ^A , R ^B , R ^C is independently a monovalent, divalent or trivalent hydrocarbon radical having 1 to 60 carbon atoms, not independently 2 to 8 carbon atoms.

1-4 show the results of application of compositions within the scope of the invention (Examples I and II) and other compositions outside the scope of the invention (Comparative Examples I and Comparative Example II). Xerographic reproductions of pictures of the patterns obtained as are taken immediately after application of the compositions (1 second-6 seconds).

Detailed description of the invention

Unexpectedly, Applicants have found a method of applying a trisiloxane-containing composition, in one specific embodiment of the invention, wherein the trisiloxane-containing composition, when sprayed onto the surface of the substrate, is such a trisiloxane- The containing compositions impart excellent physical properties to formulations and / or applications comprising such trisiloxane-containing compositions, resulting in the advantageous properties referred to herein, such as reduced flushing. And certain trisiloxanes.

As used herein, the terms polyorganosiloxane and organopolysiloxane may be used interchangeably.

As used herein, the terms formulation and application are interchangeable.

It will be understood that all cases where the term centistokes is used herein are measured at 25 degrees Celsius.

All specific, more specific and most specific ranges described herein will be understood to include all sub-ranges therebetween.

All percentage ranges herein are to be understood as weight percentages relative to the total weight of the formulation comprising the trisiloxane-containing composition, unless otherwise indicated.

The expression "run-down" is to be understood as meaning the visually observed extent of the downward flow of the trisiloxane-containing composition applied to the cellulose paper. Measured on a scale of 1 to 3 as follows:

0 = no downward extension of the incident spray;

1 = little downward expansion of the incident spray;

2 = easily recognizable, but moderate, downward extension of the incident spray; And

3 = incidence of the spray, clearly apparent, and extensive, downstream expansion.

In one particular embodiment of the invention, the trisiloxane-containing composition is specifically less than about 100 weight percent, more specifically less than about 10 weight percent, relative to the total weight of the trisiloxane-containing composition, And most specifically, less than about 1 weight percent of water. In another particular embodiment, the trisiloxane-containing composition may not include water such that the trisiloxane-containing composition does not include atmospheric water and / or added water.

In another particular embodiment of the invention, the substrate is a skin, hair, nail (s), eyelash (s), eyebrow (s), lip (s), leaf (s) of plant (s), paper, leather, Metal, plastic, fiber (s), glass, fabric (s), wood, woven (s) and non-woven (s) and combinations thereof. Can be.

In another specific embodiment, the hydrocarbon radical (s) of the trisiloxane of formula (1) may be any hydrocarbon radical generally associated with such polymers, including, but not limited to, methyl, ethyl, Alkyl radicals of 1 to about 60 carbon atoms such as propyl; Cycloalkyl radicals such as cyclohexyl, cycloheptyl, cyclooctyl; Monouclear aryl radicals such as phenyl, methylphenyl, ethylphenyl; Alkenyl radicals such as vinyl and allyl; Alkylene oxide radicals such as ethylene oxide, propylene oxide and mixtures thereof; And can be selected from haloalkyl radicals such as 3,3,3, trifluoropropyl. In another specific embodiment, the hydrocarbon radicals of the trisiloxane of general formula (1) are alkyl radicals of 1 to 8 carbon atoms, most specifically methyl or ethyl. In one embodiment, the trisiloxane of general formula (1) has several hydroxyl groups in the polymer. In another specific embodiment, the hydrocarbon radical (s) of the trisiloxane of formula (1) may be any organic functional group described in US Pat. No. 6,531,540, the entire contents of which are incorporated herein by reference. . Any hydrocarbon radical described in US Pat. No. 6,531,540 is described herein so that the terms hydrocarbon radicals described in US Pat. No. 6,531,540 and the hydrocarbon radicals used herein are interchangeable. In the sense that it can be used as a radical, it will be understood that the nomenclature used in US Pat. No. 6,531,540 with respect to hydrocarbon radicals is considered to correspond to the hydrocarbon radical (s) described herein. In one embodiment of the invention, any hydrocarbon radical described herein may be present in the trisiloxane of general formula (1), or is a non-limiting example, such as olefins, specifically alpha-olefins It will be appreciated that it can be bound to the trisiloxane via reaction with an organic compound.

In certain embodiments of the invention, the trisiloxane of formula (1) can be prepared by any known method. In another specific embodiment of the invention, the trisiloxane-containing composition is an alkyl-substituted trisiloxane described by the general formula (1) above. In one embodiment, the term "alkyl" refers to a saturated straight or branched monovalent hydrocarbon radical, such as the hydrocarbon radicals described above. In one specific embodiment, monovalent alkyl groups are non-limiting examples of methyl, ethyl, propyl, iso-propyl, n-butyl, iso-butyl, sec-butyl, tert-butyl And linear or branched alkyl groups containing 1 to 60 carbon atoms per group, such as pentyl, hexyl, heptyl, decyl, and dodecyl. In another specific embodiment, the trisiloxane of formula (1) is a linear alkyltrisiloxane, which is a high purity material obtained as a result of alkylation of a polyorganosiloxane having formula (A):

M ¹ D ² M ¹ (A)

Where

M ¹ = R ^G R ^J R ^K SiO _1/2 ; And

D ² = R ^L R ^M SiO _2/2 ;

Wherein R ^G , R ^J , R ^K , R ^L and R ^M are independently monovalent hydrocarbon radicals having 1 to 60 carbon atoms or hydrogen, wherein R ^G , R ^J , R ^K , R ^L and R ^M It is conditioned that at least one is hydrogen. In other specific embodiments, R ^L and / or R ^M is hydrogen. In one embodiment, the high purity material described herein is defined to consist substantially of an alkylated polyorganosiloxane [formula (A)]. In one specific embodiment of the invention, alkylation of the polyorganosiloxane having formula (A) is carried out by reacting the polyorganosiloxane having formula (A) with an alkene compound such as ethylene, which is a non-limiting example. Can be. In another specific embodiment, the high purity material comprises more than about 90 weight percent alkylated polyorganosiloxane [formula (A)], relative to the total weight of the high purity material. In another specific embodiment, the high purity material comprises more than about 95 weight percent alkylated polyorganosiloxane [formula (A)], relative to the total weight of the high purity material. In the most particular embodiment, the high purity material comprises more than about 97 weight percent alkylated polyorganosiloxane [formula (A)], relative to the total weight of the high purity material. In another specific embodiment of the present invention, trisiloxane of formula (1) is described in US patent application Ser. No. 11 / 274,450, filed Nov. 15, 2005, the entire contents of which are incorporated herein by reference. Can be made as a result of alkylation of polyorganosiloxanes. In another embodiment of the present invention, the trisiloxane of formula (1) may be made by any known or commonly used method known to those of ordinary skill in the art.

In another specific embodiment of the invention, the trisiloxane of formula (1) is more specifically a monovalent, divalent or trivalent hydrocarbon radical wherein R ^D and / or R ^F have 2 to 6 carbon atoms. It may be configured to include. In another specific embodiment of the invention, the trisiloxane of the general formula (1) includes when R ^D and / or R ^F is a monovalent, divalent or trivalent hydrocarbon radical having 2 to 4 carbon atoms. It can be configured. In another specific embodiment, the trisiloxane of general formula (1) may be constituted even more specifically including when R ^D and / or R ^F is ethyl. In the most particular embodiment, trisiloxane of general formula (1) may be comprised including the case where R ^D is ethyl and R ^F is methyl.

In certain embodiments of the invention, some non-limiting examples of trisiloxanes of general formula (1) include, but are not limited to, 1,1,1,3,5,5,5-heptamethyl-3-ethyltri Ethyltrisiloxane, such as siloxane; Octyltrisiloxane, such as non-limiting examples, 1,1,1,3,5,5,5-heptamethyl-3-octyltrisiloxane; Non-limiting examples are linear alkyltrisiloxanes selected from the group consisting of hexyltrisiloxanes such as 1,1,1,3,5,5,5-heptamethyl-3-hexyltrisiloxane, and combinations thereof. In certain embodiments of the invention, the trisiloxanes of formula (1) are of trisiloxanes, such as those described in US Patent Application Publication No. 2004 / 0197284A1, the entire contents of which are incorporated herein by reference. There may be at least one. In another specific embodiment of the invention, the trisiloxanes of formula (1) are of trisiloxanes, such as those described in US Patent Application Publication 2005 / 0069564A1, the entire contents of which are incorporated herein by reference. There may be at least one. In another specific embodiment, trisiloxane of the general formula (1) is 3-pentyl-1,1,1,3,5,5,5-heptamethyltrisiloxane; For example, 1,1,1,3,5,5,5-heptamethyl-3-octyltrisiloxane sold by the company "General Electric" under the name "Silsoft 034"; 1,1,1,3,5,5,5-heptamethyl-3-hexyltrisiloxane; 3- (1-ethylbutyl) -1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (1-methylpentyl) trisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (1-methylpropyl) trisiloxane; 3- (1,1-dimethylethyl) -1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,5,5,5-hexamethyl-3,3-bis (1-methylethyl) trisiloxane; 3- (3,3-dimethylbutyl) -1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (3-methylbutyl) trisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (3-methylpentyl) trisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (2-methylpropyl) trisiloxane; 1,1,1,3,5,5,5-heptamethyl-3-propyltrisiloxane; 3-isohexyl-1,1,1,3,5,5,5-heptamethyltrisiloxane; 3-tert-pentyl-1,1,1,3,5,5,5-heptamethyltrisiloxane; 3-neo-pentyl-1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,5,5,5-hexamethyl-3,3-dipropyltrisiloxane; 3,3-diethyl-1,1,1,5,5,5-hexamethyltrisiloxane; 3,3-dibutyl-1,1,1,5,5,5-hexamethyltrisiloxane; 3-ethyl-1,1,1,3,5,5,5-heptamethyltrisiloxane; 3-heptyl-1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,5,5,5-hexamethyl-3,3-diethyltrisiloxane; It can be selected from the group consisting of 1,1,1,3,5,5,5-heptamethyl-3-butyltrisiloxane and combinations thereof.

In one specific embodiment, trisiloxane of formula (1) may comprise two or more of the trisiloxanes of formula (1) described herein.

The amount of trisiloxane of the general formula (1) described above used in the trisiloxane-containing composition is determined by the use of the trisiloxane-containing composition, the other components, the desired result, and the like. It will depend on the like considerations and can be readily determined by those skilled in the art. In another specific embodiment, the trisiloxane of formula (1) is specifically in an amount of from about 0.001 to about 99 weight percent relative to the total weight of the trisiloxane-containing composition, more specifically of the trisiloxane-containing composition In an amount of about 0.01 to about 85 weight percent based on the total weight, even more specifically in an amount of about 0.1 to about 50 weight percent relative to the total weight of the trisiloxane-containing composition, and most specifically trisiloxane-containing Present in the trisiloxane-containing composition in an amount of about 0.2 to about 20 weight percent, based on the total weight of the composition. In another specific embodiment, trisiloxane of formula (1) is specifically present in the trisiloxane-containing composition in an amount of from 10 to about 2 weight percent based on the total weight of the trisiloxane-containing composition.

The specific formulations comprised of the trisiloxane-containing compositions described herein will vary from industry to industry and will be determined by one of ordinary skill in the art. In another specific embodiment of the invention, the trisiloxane-containing composition comprises a formulation component, specifically in an amount of about 99 to about 0.001 weight percent, based on the total weight of the trisiloxane-containing composition, More specifically in an amount of about 85 to about 0.01 weight percent based on the total weight of the trisiloxane-containing composition, and even more specifically in an amount of about 50 to about 0.1 weight percent relative to the total weight of the trisiloxane-containing composition And most specifically in an amount from about 20 to about 2 weight percent based on the total weight of the trisiloxane-containing composition. In another specific embodiment of the invention, the trisiloxane-containing composition further comprises the formulation component in an amount of about 10 to about 2 weight percent relative to the total weight of the trisiloxane-containing composition.

In one embodiment, the formulation components can comprise conventional and known formulation components, as they are known in various industries by those of ordinary skill in the art. In another specific embodiment of the present invention, the formulation component is a propellant, surfactant, emulsifier, solvent, emollient, moisturizer, wetting agent, pigment, colorant, fragrance, Biocide, preservative, antioxidant, anti-microbial agent, anti-fungal agent, insecticide, paint, antiperspirant agent, aerosol-driver , Exfoliants, alcohols, hormones, enzymes, medical compounds, vitamins, alpha-hydroxy acids, beta-hydroxy acids and / or other hydroxy acids, retinol ) And derivatives thereof, niacinamide, skin lightening agent, salts, electrolytes, polyols, absorbing agents for ultraviolet radiation, non-limiting Herbal extracts (herbal ext) plant extracts such as racts and tea tree oils, organic oils, waxes, film formers, thickening agents, particulate fillers, clays ), Plasticizers, occlusives, sensory enhancers, esters, resins and film formers, spherical or other, including, but not limited to, silicone spheres Optically active particles, and combinations thereof.

In another specific embodiment, silicone oil, silicone gum, silicone solid, silicone emulsion of the trisiloxane of formula (1); Silicone resins, silicone copolyols, alkyl silicones, silicone waxes, silicone amines, silicone ammonium salts, quaternary silicone amines, spherical silicones, silicone gels, silicone Combinations with other types of silicon selected from the group consisting of crosspolymer networks, polyether silicons, and combinations thereof are provided. In order to optimize the industrial specific characteristics of the trisiloxane-containing composition, for example, specifically for (but not limited to) sprayable personal care compositions, To reduce runoff, the relative amounts of each silicon can be adjusted. In another specific embodiment of the present invention, the trisiloxane-containing composition may further comprise a silicone fluid which is not the trisiloxane of formula (1). In another specific embodiment, the silicone fluid that is not trisiloxane of formula (1) is a cyclic siloxane and / or linear silicone fluid, such as a decamethylcyclopentasiloxane fluid and / or a high molecular weight polyorganosiloxane fluid, respectively. Can be. In the most particular embodiment of the invention, the high molecular weight polyorganosiloxane fluid has a higher viscosity than trisiloxane of general formula (1), specifically about 1 to about 400, more specifically about 3 To about 350, and most specifically organo polydimethylsiloxanes having a viscosity of about 5 to about 300 centistokes, wherein the organo groups are described above. Are any hydrocarbon radicals. In one particular embodiment, the organo polydimethylsiloxane may have a viscosity of about 1 to about 1000 centistokes, more specifically 2 to about 500 centistokes and most specifically 5 to about 10 centistokes. . In very particular embodiments, the polydimethylsiloxane may have a viscosity of 5 centistokes. In very particular embodiments, the polydimethylsiloxane may have a viscosity of 50 centistokes.

In one embodiment of the invention, the trisiloxane-containing compositions described herein are described in US Pat. No. 6,531,540, the disclosure of which is incorporated herein by reference in its entirety; Like those described in US Pat. Nos. 6,060,546 and 6,271,295, they can be used as prepared or as silicone component in emulsions of emulsions.

In another embodiment of the present invention, noble metal catalysts suitable for preparing trisiloxanes of general formula (1) and non-trisiloxane silicones of general formula (1) described herein are well known in the art and And complexes of rhodium, ruthenium, palladium, osmium, iridium and / or platinum. For example, numerous types of platinum catalysts for such SiH olefin addition reactions are known, including Karstedt catalysts, and such platinum catalysts can be used to make the compositions of the present invention. An additional background in this field is J.L. Spier, "Homogeneous Catalysis of Hydrosilation by Transition Metals" by Advances in Organometallic Chemistry, volume 17, pages 407-447, F.G.A. Stone and R. West editors, "Academic Press" (New York, 1979). Those skilled in the art can easily determine the effective amount of platinum catalyst. In general, the effective amount is in the range of about 0.1 to 50 ppm (parts per million) of the total trisiloxane-containing composition. In other specific embodiments, the effective amount is more specifically about 1 to about 20 parts per million of the total trisiloxane-containing composition, and most specifically about 4 to about 15 ppm of the total trisiloxane-containing composition (parts per million).

In another specific embodiment of the invention, applying the trisiloxane-containing composition comprises using at least one of a spraying, dispensing, diffusing or mistyfying process. And using a spray. In another specific embodiment, the spraying, dispensing, diffusing or misting processes include industrial typical flow rates, droplet sizes and pressure build-ups. It may be any such commonly known processes, but not limited to this.

In another specific embodiment of the present invention, the application of the trisiloxane-containing composition comprises perfume and lotion pumps, fine mist sprayers, specialty pumps, anti-clog pumps, Spray-through cap, nozzle, airless pump, airless dispenser, dual dispensing pump, fine mist pump, trigger pump, foam It comprises the use of a spray selected from the group consisting of a pump, trigger sprayer, aerosol sprayer, squeeze foamer and combinations thereof to provide an application of the spray.

In certain embodiments of the invention, the process of spraying, dispensing, diffusing or misting is a non-limiting example, such as a) atomization process, ie a fluid or emulsion, often by passage of nozzles of particles. Reduction of the microparticles of the thing into a fine spray or mist; b) sprinkling processes involving irrigation and fire sprinkling, ie the distribution of water by spraying water into the air; c) the flow of fluid created by a jet streaming process, i.e., through an orifice or a small opening and / or a nozzle (nozzles are used from an enclosed chamber And a swift sudden stream of discharged liquid or fluid, including a mechanical device for controlling the properties of fluid flow as it exits into some medium. Often here, the kinetic energy of the flowing medium is increased at the expense of any pressure energy of the fluid before passing through the nozzle.

In another specific embodiment, applying the trisiloxane-containing composition is specifically about 0.001 milliliter to about 50 milliliters per application of spray, more specifically about 0.01 milliliter to about 5 per application of spray Milliliters, and most specifically, further, spraying from about 0.1 milliliters to about 0.5 milliliters per application of the spray.

In another specific embodiment, applying the trisiloxane-containing composition is specifically about 0.01 centimeter to about 10,000 centimeters from the surface of the substrate, more specifically about 0.1 centimeter to about 100 centimeters from the surface of the substrate, and most Specifically, the method further comprises spraying at a distance of about 1 centimeter to about 50 centimeters from the surface of the substrate.

In another embodiment of the invention, the method of applying the trisiloxane-containing composition is such that the trisiloxane-containing composition is not a mold release composition, a cosmetic spray, a gel or an emulsion. It is configured to further include a case comprising the other.

In certain embodiments of the invention, a method of applying a trisiloxane-containing composition comprises a U.S. patent application filed on Nov. 15, 2005, the entire contents of which are incorporated herein by reference. It may be configured to include the case further comprises a silicone gel described in 11 / 274,450.

In another specific embodiment of the present invention, the method of applying the trisiloxane-containing composition is an improvement over sprayable compositions in which the trisiloxane-containing composition comprises something other than the composition of formula (1). It may be configured to further include a case showing the specified characteristics. In another specific embodiment, a method of applying a trisiloxane-containing composition, which exhibits improved properties over sprayable compositions comprising other than the composition of formula (1), is not a composition of formula (1) Others may be included, including but not limited to those that may comprise volatile siloxanes such as cyclic siloxanes. Cyclic siloxanes used as volatile siloxanes are well known in the art and will not be described in detail herein. In another specific embodiment of the present invention, the above properties which are significantly improved over sprayable compositions comprising something other than the composition of formula (1) include reduced downflow, good coverage, improved activity distribution. actives distribution and / or performance, rapid drying, less over-wetting, simple formulation, non-tackiness, improved spreadability, improved homogeneity, improved organic compatibility (organic compatibility), reduced skin inflammation, improved active delivery, improved skin feel, enhanced SPF, less or more shine as desired, smaller droplet size And at least one selected from the group consisting of smaller mechanical stresses on the spray system used. A synergistic effect can be obtained by improving one or more of the above characteristics. For example, rapid drying can result in less excessive wetting, which in some cases, for example, improves the substrate in the paper industry, such as but not limited to wet paper having less mechanical strength than dry paper. Mechanical stability can be brought. In another advantageous feature, the method of applying the trisiloxane-containing composition of the invention flows down sprayable formulations, such as sprayable cosmetic formulations or personal care formulations, applied in a number of different industries. There is an advantage that can be reduced only by adding the trisiloxane-containing composition described herein to such formulations.

In certain embodiments of the present invention, the formulation components described above do not adversely or substantially adversely affect the downflow of the trisiloxane-containing composition or any of the above described improved properties. In another particular embodiment of the present invention, the improved properties described above include an emulsifier; antiseptic; Polymers; Thixotropic and non-thixotropic film formers; Sunscreening agents; Sunblocking agents, colorants; Pigments; air freshener; Active ingredients such as, but not limited to, vitamins, alpha-hydroxy acids, beta-hydroxy acids and / or other hydroxy acids; Retinol and its derivatives; Niacinamide; Tocopherol and / or its derivatives, skin lightening agents; Wetting agents; Occlusive; Sensory enhancers; ester; Other resin and film forming agents; Other silicon, with spherical or other optically active particles comprising silicon spheres; Emollients; Surfactants; And a synergistic component selected from the group consisting of combinations thereof.

In another specific embodiment, a method of applying the trisiloxane-containing composition of the present invention comprises aerospace; Agriculture; Food &beverages; Tissue &non-wovens; Non-limiting examples include automotive body panels, automotive energy management, automotive headliners, automotive headrests and armrests, automotive instrument panels, An automobile including an automobile seating; Steering wheels; Tires; Coatings; Inks; Paints; Non-limiting examples include construction sealants, discontinuous panels, flexible face panels, windows and doors, pipes, etc. construction); Consumer, including, but not limited to, consumer appliances, shoes, furniture, bedding, carpets; Electronics including automotive electronics; Semiconductors; Health care; Homecare, including, but not limited to, hard surface cleaners, laundry and fabric care, varnishes and treatments; Industrial assembly; Industrial cleaning; Mold making; Packaging and labeling; Power & electric distribution; Process industries including, but not limited to, clothing & leather, oil & gas, pulp & paper, release; Transportation, including, but not limited to, insulated tanks, shipping containers; Pool &spa; A non-limiting example can be used in industries and markets selected from the group consisting of motorcycles, including motor scooters, personal care and combinations thereof.

In another specific embodiment, a method of applying the trisiloxane-containing composition of the present invention is directed to personal care industries and markets, including, but not limited to, sprays, sticks and ballpoint products in non-limiting forms. Deodorants, sweat inhibitors, sweat inhibitors / deodorants, which are roll-on products; Shaving products, skin lotions, moisturizers, toners, bath products, cleansing products, shampoos, conditioners, shampoo / conditioner combinations, mousses , Styling gels, hair sprays, hair dyes, hair color products, hair bleaches, waving products, hair straighteners, nail polishes, nail polishes Remover, nail creams and / or lotions, cuticle softeners, sunscreen, insect repellent, anti-aging products, lipsticks, foundations, face powders, eyeliner Fields, eye shadows, blushes, makeup, mascaras, moisturizing preparations, body and hand preparations, skin care preparations, face and neck preparations, tonics, de Dressings, hair grooming aids, aerosol fixatives, fragrance preparations, aftershaves, make-up preparations, soft focus applications, Day and night skin care preparations, non-coloring hair preparations, tanning preparations, synthetic and non-synthetic stick soaps, hand liquids, nose packs (nose strips), non-woven articles for personal care, baby lotions, baby bath products and / or shampoos, baby conditioners, shaving preparations, cucumber slices, skin pads skin pads, makeup removers, facial cleansing products, cold creams, sun protection products, spritzes, pasting masks and / or muds, face masks, colognes and lotions Hair cuticle coating (hair cuticle coats), shower gels, face and body washes, personal care rinse-off products, gels, bubble baths, scrubbing cleansers scrubbing cleansers, astringents, nail conditioners, eye shadow sticks, face or eye powders, lip balms, lip gloss, hair care pump sprays and other non-aerosol sprays, Hair-frizz-control gels, hair leave-in conditioners, hair pomades, hair de-tangling products, hair fixatives, hair Bleach products, skin lotions, pre-shaves and pre-electric shaves, anhydrous creams and / or lotions, oils / water, water / oil, Complex Macro and Micro Emulsions Multiple and macro and micro emulsions, picking emulsions, multiple-phase emulsions, waterproof creams and / or lotions, anti-acne preparations, mouthwashes, massage oils, Toothpastes, clear gels and sticks, ointment bases, topical wound healing products, aerosol talcs, barrier sprays, vitamins and anti-aging preparations Fields, herbal-extract preparations, bath salts, bath and body milks, hair styling aids, hair-, eye-, nail- and skin-soft solid products ( soft solid applications, controlled-release personal care products, hair conditioning mists, skin care moisturizing mists, skin wipes, pore skin wipes , Pore cleaners, blemish reducers, skin exfoliators, skin desquamation enhancers, skin towelettes and / or cloths, hair loss preparations Group, personal care lubricants, nail coloring preparations, drug delivery systems for topical application of medicinal compositions to the skin, and combinations thereof And may be configured to include using the trisiloxane-containing composition in a personal care application, selected from.

In another specific embodiment of the present invention, the method of applying the trisiloxane-containing composition is characterized in that the trisiloxane-containing composition is a non-limiting example, sunscreens, hair care products, cosmetics, anti-aging When used in applications requiring advantageous properties related to coatings, including but not limited to skin protection such as products, moisturizers, skin care products and combinations thereof It can be configured to include.

In another specific embodiment of the invention, the method of applying the trisiloxane-containing composition comprises combinations in which the personal care article comprises a UV blocking or UV absorbing sunscreen and at least one of the foregoing sunscreens. It may further comprise a case of a suncare formulation, which may further comprise a sunscreen selected from the group consisting of. In another particular embodiment, the sunscreens are generally non-limiting examples of inorganic materials such as silicon or other treated titanium dioxides, titanium dioxide, silicon or other treated zinc oxides, zinc oxide. to be. In another particular embodiment, absorbing sunscreening agents, which are generally organic species, are non-limiting examples, such as anthranilates, benzophenones, and dibenzoyl methanes. UV-A absorbers, which generally absorb radiation in the 320-400 nm region of the ultraviolet spectrum; And absorb radiation in the 280-320 nm region of the ultraviolet spectrum, generally, such as but not limited to, p-aminobenzoic acid derivatives, camphor derivatives, cinnamates, and salicylates UV-B absorbers are included as non-limiting examples. In one specific embodiment, some non-limiting examples of organic sunscreens include p-aminobenzoic acid, avobenzone synoxate, dioxybenzone, homosalate, menthyl anthranilate, octocrylene , Octyl methoxycinnamate, octyl salicylate, oxybenzone, padimate, phenylbenzimidazole sulfonic acids, sulfisobenzone, trolamine salicylate, aminobenzoic acid, amyldimethyl p-amino Benzoic acid, diethanolamine p-methoxycinnamate, digalloyl trioleate, 2-ethylhexyl-2-cyano-3,3-diphenylacrylate, ethylhexyl p-methoxycinna Mate, 2-ethylhexyl salicylate, glyceryl aminobenzoate, homomentyl salicylate, homosalate, 3-imidazol-4-ylacrylic acid and its ethyl esters, methyl anthranilate, octyldimethyl PABA, 2-phenylbenzi Midazole-5-sulfonic acid and salts, sulfisobenzone, triethanolamine salicylate, N, N, N-trimethyl-4- (2-oxoborn-3-ylidene methyl) anilinium methyl sulfate, aminobenzoate, 4-isopropylbenzyl salicylate, 2-ethylhexyl 4-methoxycinnamate, methyl diisopropylcinnamate, isoamyl 4-methoxycinnamate, diethanolamine 4-methoxycinnamate, 3- (4 '-Trimethylammonium) -benzylidene-bornan-2-one methyl sulfate, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 2, 4-dihydroxybenzophenone, 2,2 ', 4,4'-tetrahydroxybenzophenone, 2,2'-dihydroxy-4,4'dimethoxybenzophenone, 2-hydroxy-4- n-octoxybenzophenone, 2-hydroxy-4-methoxy-4'-methoxybenzophenone, car- (2-oxoborn-3-ylidene) -tolyl-4-sulfonic acid and soluble salts thereof, 3 -(4'-sulfo) benzylidene-bornan-2-one and its solubility Salts, 3- (4'-methylbenzylidene) -d, 1-camphor, 3-benzylidene-d, 1-camphor, benzene 1,4-di (3-methylidene-10-camphorsulphonic ) Acids and salts thereof, urocanic acid, 2,4,6-tris- (2'-ethylhexyl-1'-oxycarbonyl) -anilinol 1,3,5-triazine, 2- (p- (tert-butylamido) anilinol-4,6-bis- (p- (2'-ethylhexyl 1'-oxycarbonyl) anilinol 1,3,5-triazine, 2,4- Bis {l, 4- (2-ethylhexyloxy) -2-hydroxyl-phenyl} -6- (4-methoxyphenyl) -1,3,5-triazine, N- (2 et 4)- Polymer of (2-oxoborn-3-ylidene) methylbenzyl acrylamide, 1,4-bisbenzimidazolyl-phenylene-3,3 ', 5,5'-tetrasulfonic acid and salts thereof, benzalmalo Nate-substituted polyorganosiloxanes, benzotriazole-substituted polyorganosiloxanes (dromethazole trisiloxane), solubilized 2,2'-methylene-bis-1,6- (2H-benzo Triazol-2-yl) -4- (1,1,3,3-tetramethylbutyl) phenol, 2-methyldibenzoylme , 4-methyldibenzoylmethane, 4-isopropyldibenzoylmethane, 4-tert-butyldibenzoylmethane, 2,4-dimethyldibenzoylmethane, 2,5-dimethyldibenzoylmethane, 4,4'- Diisopropyldibenzoylmethane, 4,4'-dimethoxydibenzoylmethane, 4-tert-butyl-4'-methoxydibenzoylmethane, 2-methyl-5-isopropyl-4'-methoxydibenzoyl Methane, 2-methyl-5-tert-butyl-4'-methoxydibenzoylmethane, 2,4-dimethyl-4'-methoxydibenzoylmethane, 2,6-dimethyl-4-tert-butyl -4'-methoxydibenzoylmethane, and combinations comprising at least one of the foregoing sunscreens. In one embodiment, it has been found that a combination of at least three sunscreens is effective. In another embodiment, it has been found that a combination of four sunscreens is effective, especially when chemical sunscreens are used. In another embodiment, a formulation, comprising a combination of one or several sunscreens with one or several sunscreens, is effective.

In certain embodiments of the invention, when the trisiloxane-containing composition is formulated in a sunscreen formulation, the sunscreen formulation is a lamellar emulsion, microemulsion, or nanoemulsion. Or in the form of a picking emulsion. Moreover, the emulsions can be fluid simple emulsions, fluid multiple emulsions, rigid simple emulsions, or rigid multiple emulsions. A simple emulsion or complex emulsion is a continuous aqueous phase comprising dispersed lipid vesicles or oil droplets, or a continuous fatty phase comprising dispersed fatty vesicles or water droplets. It may be configured to include). In one embodiment, a sunscreen application is an emulsion with a continuous water soluble phase, which is generally a single phase, double- or multiple-phasic, emulsion, gel, lotion, and equivalents thereof. In the form of a sprayable composition.

In another specific embodiment of the present invention, reduced "flowing" includes any phenomenon in which the change in shape or size of the area moistened by the trisiloxane-containing composition sprayed on the surface of the substrate is reduced or eliminated. Will be understood. This includes gravity driven processes as well as processes induced by any other physical- or mechanical force, such as but not limited to capillary forces.

In another specific embodiment of the invention, the method of applying the trisiloxane-containing composition comprises a sucrose palmitate, wherein the personal care article is a non-ionic biopolymer blends, such as, but not limited to, examples. (And) glyceryl stearate (and) glyceryl stearate citrate (and) sucrose (and) mannan (and) xanthan gum (arlatone V-175) from Uniquema; Non-limiting examples of propylene glycol isocet-3 acetate (Hester PHA) from Bernel or Steareth-2 or Steareth-10 (Volpo S2 and Volpo S1-) from Croda, laureth-7, laureth Polyethoxylated emulsifiers such as -4 (Sepigel ^® 305) (available from SEPPIC); Modified polyacrylates such as, but not limited to, glycerin (and) glycerin polyacrylate (Hispagel 200) from Cognis; Non-limiting examples of oils such as vegetable and mineral oils; Non-limiting examples of animal and / or synthetic waxes such as beeswax, paraffin, rice bran wax, candelilla wax, carnauba wax and derivatives thereof; Hydrocarbon gels or bentone type gels such as, but not limited to, Gel SS71, Gel EA2786, Quaternium-18 Bentonite, 38 CE, Gel ISD V or Gel ISD; Non-limiting examples, cetyl dimethicone copolyol-polyglyceryl-4-isostearate-hexyllaurate (ABIL ^® WE 09) (available from "Goldschmidt Chemical Corporation"), behenate dimeth Ticone, cetyl dimethicone copolyol (ABIL ^® EM 90), (ABIL ^® EM 97), laurylmethicone copolyol (5200), cyclomethicone and dimethicone copolyols (DC 5225 C and DC 3225 C) [Available from "GE Silicones"], organosilicone emulsifiers such as cyclopentasiloxane and dimethicone copolyol (GE SF 1528 or GE 1540), PEG-20 / PPG- 23 dimethicone (GE Silsoft 440) ; And an emulsifier selected from the group consisting of combinations thereof.

In another specific embodiment of the invention, the method of applying the trisiloxane-containing composition may be used in the form of a product in which the trisiloxane-containing composition may be anhydrous to non-anhydrous. It may be configured to include. In other specific embodiments the product form may be a simple solid, particles, solution, gel-network-stabilized phase and combinations thereof. In another particular embodiment, the product form may be a gel, emulsion, dispersion, sludge, powder, bar, spray, spritz, mousse, stick It can be selected from the group consisting of stick, balm, foundation, and combinations thereof. In another particular embodiment, the emulsion product form may form a single-phase, bi-phase, tri-phase, or may be multi-phase, layered ( can be lamellar phased, and can form macro-, micro- or nanoemulsions, and also water-in-oil-in-water, Oil-in-water-in-oil emulsions, water in silicone emulsions or silicone in oil emulsions, or It may be anionic-, cationic-, amphoteric- or neutral emulsion, or picking emulsion, as well as other physical forms.

In another specific embodiment of the present invention, the method of applying the trisiloxane-containing composition comprises: the trisiloxane-containing composition comprises lecithin, polysorbates, dimethicone copolyol, glycols, citrate esters, And a plasticizer selected from the non-limiting group consisting of glycerin, dimethicone and combinations thereof.

In another embodiment of the present invention, the process for preparing the trisiloxane-containing composition comprises hand- or mechanical stirring, any type of high-, medium- or ambient- or low-temperature mixing ( to achieve small droplet sizes in emulsions, including but not limited to any cooling processes, including phase-inversion-processes, including mixing, homogenization, or heating. Process or combination of processes known to those of ordinary skill in the art, such as any technique of applying shear, including but not limited to other special procedures Is done by.

In another embodiment, the aforementioned method of making personal care applications comprises the above-described trisiloxane-containing composition with personal care ingredients known to those of ordinary skill in the art. ingredient and combination. Some non-limiting examples of personal care ingredients are described in US patent application Ser. No. 11 / 274,450, filed November 15, 2005, the entire contents of which are incorporated herein by reference.

In yet another embodiment, the disclosed personal care compositions can exhibit various advantages in personal care articles. One such non-limiting advantage is less downflow, either alone or in combination with any active ingredient. Other characteristics of each personal care article can be any specific trisiloxane (s) selected, such as the type (s) of hydrocarbyl radicals present, any silicone backbone or side chain (s). The remaining components of the sprayable personal care application, together with the presence and type (s) of the substitution (s), the molecular weight of the trisiloxane (s), and similar considerations, will vary. will be. Preferred properties of certain personal care products can be specifically determined by those of ordinary skill in the art. Some specific examples of properties provided by the use of trisiloxanes of the present invention include reduced adhesion, enhanced spreading, quick drying, less over-wetting, improved homogeneity, enhanced organic compatibility, improved skin feel, control Active delivery, improved gloss, and / or reduced skin inflammation. Test panels can be used to objectively determine reduced tack, improved homogeneity, enhanced organic compatibility and improved skin feel. The enhanced spreadability can be determined by measuring the coefficient of friction in one sample of the personal care composition. Skin inflammation can be determined by measuring the onset of erythema. Sun protection is assessed according to their ability to slow erythema or sunburn due to exposure to ultraviolet light. Gloss can be determined by measuring a refractive index using a gloss meter.

In another embodiment of the present invention, silicone prepared by any process described in US patent application Ser. No. 11 / 274,450, filed November 15, 2005, the entire contents of which are incorporated herein by reference. A personal care formulation is provided, such as those described above, comprising a gel.

The following examples are given for the purpose of illustrating the instant case of the present invention. They are not given for the purpose of setting limitations on the embodiments described herein. All weights are percentages by weight relative to the total weight of the trisiloxane-containing composition, unless otherwise indicated.

Examples

The preparation of the trisiloxane-containing compositions shown in Table 1 was carried out by hand-stirring and by adding the ingredients in the order described while continuing to stir between each addition of the next ingredient.

 Holy people  Comparative Example I  Example I  Comparative Example II  Example II   Diisostearoyl trimethylolpropane siloxy silicate C12-C15 alkylbenzoate phenyl trimethicone cyclopentasiloxane (and) trimethylsiloxysilicate octylmethoxycinnamate octocrylene cyclopentasiloxane 1,1,1,3, 5,5,5-heptamethyl-3-ethyltrisiloxane (ETS) octylsalicylate  8.00 10.00 15.00 5.00 7.00 8.00 47.00 0 0  8.00 10.00 15.00 5.00 7.00 8.00 0 47.00 0  0 0 0 0 0 0 80.00 0 20.00  0 0 0 0 0 0 0 80.00 20.00

When spraying Comparative Example I and Example I on the substrate surface, Comparative Example I shows a clear indication of run down, while Example I does not, as illustrated in Figures 1 and 2 of the drawing section below. not. Comparative Example I has a run down of the above-identified scale 2. Example I has the downflow of scale 0 described above.

As is evident, the formula containing cyclopentasiloxane begins to run down, while the formula containing ETS remains in place. In both cases, a well primed pump spraying system was used once to apply 10.16 centimeters away from the notebook paper substrate.

To prepare for the possibility that ETS-containing formulations will not flow down immediately due to depositing less materials on top of the substrate surface, and to eliminate the effect of variations from spray to spray. The following control experiments were performed:

The experiment was repeated by drawing a line and carefully weighing the notepad paper weighed with the balance in advance 10.16 centimeters apart. Five sprays of each of the formulations of Comparative Example I & Example I were delivered and the mass of the material so discharged was obtained by gravimetry:

Comparative Example I: 0.581 grams (g) were applied in 5 sprays (=> 0.581g / 5 = 0.1162g per applied spray). Since runoff can also depend on the volume applied, these results were corrected for the density of the formula measured as 0.9777 g / ml using the "Mettler / Paar DMA46 Calculating Digital Density Meter" (=> 0.1162). g / 0.9777 g / ml = 0.1189 ml per spray applied).

Example I: 0.622 g was applied in 5 sprays (=> 0.622g / 5 = 0.1244g per applied spray). With the density measured as described above, the following volume was applied: 0.1244 g / 0.9107 g / ml = 0.1366 ml per spray applied.

In addition, all experiments were carried out using a white spray sprayer equipped with different spray pumps of the same type (Qosmedix Corporation (Edwood, New York, USA), "clear overcap Model # 29717" to eliminate any possible effects of the pump itself. white spray mister), the spray pump is made of polypropylene, and the bottle is made of polyvinyl chloride.

As can be seen from the above, apparently, ETS formulas are not applied less than cyclopentasiloxane formulas, so the effect that no flushing occurs is due to the beneficial presence of ETS.

The UV protection index of 11 was determined by spraying Comparative Example I on hydrated in vitro-skin and measuring the resulting sun protection factor using the "Labsphere UV1000 Light Simulator". Example I, on the other hand, gives a UV protection index of 13 under the same conditions.

This is due to the variety of use of the trisiloxanes disclosed herein, illustrated by, but not limited to, 1,1,1,3,5,5,5-heptamethyl-3-ethyltrisiloxane (ETS). It serves as an important example of bringing measurably enhanced properties to sprayable applications.

3 and 4 in the drawing section below show that the no-rundown-effect when using ETS is not dependent on the formulation, but rather the general benefit of ETS. . 3 and 4 are included to show that the ETS component is the main factor that contributes to the reduction in runoff that is superior to the comparative examples in the examples. Comparative Example II has a run down of scale 3 described above. Example II has a flow down of scale 0 described above. All examples and comparative examples of the present invention were sprayed using a well-primed spray bottle. Comparative Examples II and II were applied at the same distance as Example I and Comparative Example I. All data in Table 1 were weight percent data relative to the total weight of the trisiloxane-containing composition in the respective examples and comparative examples. Example II and Comparative Example II were applied using the same number of sprays as shown in Example I and Comparative Example I.

Here again, the formula comprising cyclopentasiloxane shows significant downflow, while the formula comprising ETS remains in place. 1-4 show the results of application of compositions within the scope of the invention (Examples I and II) and other compositions outside the scope of the invention (Comparative Examples I and Comparative Example II). Xerographic reproductions of pictures of the patterns obtained as are taken immediately after application of the compositions (1 second-6 seconds).

The description includes many details, but these details should not be construed as limiting the invention, but should only be construed as illustrative of those specific embodiments. Those of ordinary skill in the art will envision many other embodiments within the scope and spirit of the invention as defined by the claims appended hereto.

Claims (34)

A method of applying a trisiloxane-containing composition to a surface of a substrate, comprising applying to the surface of a substrate a composition comprising trisiloxane of formula (1): MDM (1) (Wherein M = R ^A R ^B R ^C SiO _1/2 , And _{^{D = R D R F SiO 1}} /2, Wherein R ^D and R ^F are each independently a monovalent, divalent or trivalent hydrocarbon radical having 2 to 8 carbon atoms, or at least one of R ^D and R ^F has 2 to 8 carbon atoms A monovalent, divalent or trivalent hydrocarbon radical having 1 to 60 carbon atoms, not 2 to 8 carbon atoms provided that it is a monovalent, divalent or trivalent hydrocarbon radical, and R ^A , R ^B , R Each ^C is a monovalent, divalent, or trivalent hydrocarbon radical having 1 to 60 carbon atoms independently of 2 to 8 carbon atoms) The method of claim 1, wherein R ^D and / or R ^F is a monovalent, divalent, or trivalent hydrocarbon radical having 2 to 6 carbon atoms. The method of claim 1, wherein R ^D and / or R ^F is a monovalent, divalent, or trivalent hydrocarbon radical having 2 to 4 carbon atoms. The method of claim 1, wherein the trisiloxane-containing composition is R ¹ and / or R ^F is ethyl. The method of claim 1, wherein R ^D is ethyl, and R ^F is methyl, trisiloxane-method for coating the surface of a base material-containing composition. The surface of the substrate of claim 1, wherein the trisiloxane is selected from the group consisting of ethyl trisiloxanes, octyltrisiloxanes, hexyltrisiloxanes, and combinations thereof. How to apply on. The compound of claim 1, wherein the trisiloxane is selected from the group consisting of 3-pentyl-1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,3,5,5,5-heptamethyl-3-octyltrisiloxane; 1,1,1,3,5,5,5-heptamethyl-3-hexyl trisiloxane; 3- (1-ethylbutyl) -1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (1-methylpentyl) trisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (1-methylpropyl) trisiloxane; 3- (1,1-dimethylethyl) -1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,5,5,5-hexamethyl-3,3-bis (1-methylethyl) trisiloxane; 3- (3,3-dimethylbutyl) -1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (3-methylbutyl) trisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (3-methylpentyl) trisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (2-methylpropyl) trisiloxane; 1,1,1,3,5,5,5-heptamethyl-3-propyltrisiloxane; 3-isohexyl-1,1,1,3,5,5,5-heptamethyltrisiloxane; 3-tert-pentyl-1,1,1,3,5,5,5-heptamethyltrisiloxane; 3-neo-pentyl-1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,5,5,5-hexamethyl-3,3-dipropyltrisiloxane; 3,3-diethyl-1,1,1,5,5,5-hexamethyltrisiloxane; 3,3-dibutyl-1,1,1,5,5,5-hexamethyltrisiloxane; 3-ethyl-1,1,1,3,5,5,5-heptamethyltrisiloxane; 3-heptyl-1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,5,5,5-hexamethyl-3,3-diethyltrisiloxane; A method of applying a trisiloxane-containing composition to a surface of a substrate, wherein the trisiloxane-containing composition is selected from the group consisting of 1,1,1,3,5,5,5-heptamethyl-3-butyltrisiloxane and combinations thereof. 2. The method of claim 1, wherein the trisiloxane-containing composition may comprise less than about 100 weight percent of water relative to the total weight of the trisiloxane-containing composition. Way. The method of claim 1, wherein the trisiloxane of the trisiloxane-containing composition is present in an amount from about 0.001 to about 99 weight percent. The method of claim 1, wherein the trisiloxane-containing composition further comprises a formulation component in an amount of about 99 to about 0.001 weight percent. . The formulation of claim 10, wherein the formulation component is a propellant, surfactant, emulsifier, solvent, emollient, moisturizer, wetting agent, pigment, colorant, fragrance, biocide, preservative, antioxidant, antibacterial agent. anti-microbial agents, anti-fungal agents, insecticides, paints, antiperspirant agents, aerosol-drivers, exfoliants, alcohols, hormones, Enzymes, medical compounds, vitamins, alpha-hydroxy acids, beta-hydroxy acids and / or other hydroxy acids, retinol and derivatives thereof, niacinamide, skin Skin lightening agents, salts, electrolytes, polyols, absorbing agents for ultraviolet radiation, plant extracts, organic oils, waxes, film formers film former, thickener g agents, particulate fillers, clays, plasticizers, occlusives, sensory enhancers, esters, resins and film formers, spherical or other spherical or optically active particle), and combinations thereof, wherein the trisiloxane-containing composition is applied to the surface of the substrate. The method of claim 1 wherein the trisiloxane-containing composition is a silicone oil, silicone gum, silicone solid, silicone emulsion, silicone resin, silicone copolyol, alkyl silicones, silicone wax of the aforementioned trisiloxane of general formula (1). , Other types of silicones selected from the group consisting of silicone amines, silicone ammonium salts, quaternary silicone amines, spherical silicones, silicone gels, silicone crosspolymer networks, polyether silicones, and combinations thereof A method of applying a trisiloxane-containing composition to a surface of a substrate, which may further comprise a combination with a. The method of claim 1, wherein the trisiloxane-containing composition may further comprise a silicone fluid other than the trisiloxane of formula (1). The trisiloxane-containing composition of claim 13, wherein the trisiloxane of the trisiloxane-containing composition and / or the non-trisiloxane silicone fluid of formula (1) can be made using a noble metal catalyst. How to apply on the surface. The spray of claim 1, wherein the application of the trisiloxane-containing composition employs at least one of a spraying, dispensing or diffusing or mistyfying process. A method of applying a trisiloxane-containing composition to the surface of a substrate, comprising. The method of claim 1 wherein the application of the trisiloxane-containing composition comprises fragrance and lotion pumps, fine mist sprayers, specialty pumps, anti-clog pumps, spray-through caps ( spray-through caps, nozzles, airless pumps, airless dispensers, dual dispensing pumps, fine mist pumps, trigger pumps, foam pumps, A trisiloxane-containing composition, comprising using a spray selected from the group consisting of a trigger sprayer, an aerosol sprayer, a squeeze foamer, and combinations thereof, to provide an application of the spray The method of apply | coating to the surface of a base material. The trisiloxane-containing composition of claim 16, wherein applying the trisiloxane-containing composition further comprises spraying from about 0.001 milliliter to about 50 milliliters of per application of spray of the spray. The method of apply | coating to the surface of a base material. The trisiloxane-containing composition of claim 16, wherein applying the trisiloxane-containing composition further comprises using the spray at a distance of from about 0.01 centimeter to about 10,000 centimeters from the surface of the substrate. A method of applying the composition to the surface of a substrate. The method of applying a trisiloxane-containing composition to a surface of a substrate as claimed in claim 1, wherein the trisiloxane-containing composition comprises something other than a cosmetic spray, a gel, or an emulsion. . The composition of claim 1, wherein the applied trisiloxane-containing composition has improved properties, reduced downflow, good coverage over sprayable compositions comprising something other than the composition of Formula (1). Improved active distribution and / or performance, rapid drying, less over-wetting, simple formulation, non-tackiness, improved spreadability, improved homogeneity, Improved organic compatibility, reduced skin inflammation, improved active delivery, improved skin feel, enhanced SPF, desired gloss, smaller droplet size, and use A method of applying a trisiloxane-containing composition to the surface of a substrate, wherein the trisiloxane-containing composition exhibits at least one of the smaller mechanical stresses for a given spray system. The method of applying a trisiloxane-containing composition to a surface of a substrate according to claim 20, wherein the sprayable composition comprising a composition other than the composition of the general formula (1) is a volatile siloxane. The method of claim 21, wherein the volatile siloxane is a cyclic siloxane. The method of applying a trisiloxane-containing composition to a surface of a substrate as claimed in claim 20, wherein the flow shows little downward extension of the incident spray on the surface of the substrate. The method of claim 20, wherein the improvement in properties is synergistic. 21. The method of claim 20, wherein the properties are emulsifiers; antiseptic; Polymers; Thixotropic and non-thixotropic film formers; Sunscreening agents; Sunblocking agents, colorants; Pigments; air freshener; Active ingredient; Retinol and its derivatives; Niacinamide; Tocopherol and / or its derivatives, skin lightening agents; Wetting agents; Occlusive; Sensory enhancers; ester; Other resin and film forming agents; Spherical or other optically active particles; Other silicones; Emollients; Surfactants; And a method of applying the trisiloxane-containing composition to the surface of the substrate, which is the result of a synergistic effect caused by using a synergistic component selected from the group consisting of combinations thereof. The method of claim 1, wherein the application of the trisiloxane-containing composition can be configured including when the trisiloxane-containing composition is used in applications requiring any advantageous properties associated with the coating. And a trisiloxane-containing composition on the surface of the substrate. The composition of claim 1, wherein the trisiloxane-containing composition is aerospace, agricultural, food & beverage, tissue & non-wovens, automotive, tires, coatings, inks, paint Field, construction, consumer, electronics, semiconductors, healthcare, homecare, industrial assembly, industrial cleaning, mold making making, packaging and labeling, power & electric distribution, process industries, transportation, pool & spa, motorcycles A method of applying a trisiloxane-containing composition to the surface of a substrate, which can be used in markets and industries selected from the group consisting of motorcycles, personal care and combinations thereof. 29. The personal care markets and industries of claim 27, wherein deodorants, sweat inhibitors, sweat inhibitors / deodorants, shaving products, skin lotions, moisturizers, toners, bath products, cleansing products, shampoos Conditioners, shampoo / conditioner combinations, mousses, styling gels, hair sprays, hair dyes, hair color products, hair bleachs, waving products, hair straighteners , Nail polishes, nail polish removers, nail creams and / or lotions, cuticle softeners, sunscreens, insect repellents, anti-aging products, lipsticks, foundations, face powders, eye Liners, eye shadows, blushes, makeup, mascara, moisturizing preparations, body and hand preparations, skin care preparations, face and neck preparations, tonics, de Dressings, hair grooming aids, aerosol fixatives, fragrance preparations, aftershave, make-up preparations, soft focus applications, day and night skin care preparations, colorless hair preparations , Tanning preparations, synthetic and non-synthetic stick soaps, hand liquids, nose strips, non-woven applications for personal care, baby lotions, baby bath products And / or shampoos, baby conditioners, shaving preparations, cucumber slices, skin pads, makeup removers, facial cleansing products, cold creams, sun protection products, spritze, pasting masks and muds, face masks, Colognes and lotions, hair cuticle coats, shower gels, face and body washes, personal care rinse-off produ ct), gel, bubble bath, scrubbing cleanser, astringent, nail conditioner, eye shadow stick, face or eye powder, lip balm, lip gloss, hair care pump spray and aerosol method Non spray, curly hair care gel, hair leave-in conditioner, hair pomade, hair de-tangling product, hair fixative, hair bleach, skin lotion, pre- Pre-shaves and pre-electric shaves, anhydrous creams and / or lotions, oils / waters, water / oils, complex macro and micro emulsions, picking emulsions , Multiple-phase emulsions, waterproofing creams and / or lotions, anti-acne preparations, mouth-wash, massage oils, toothpastes, clear gels and sticks, ointment bases, topical wounds Products, aerosol talc, barrier sprays, vitamins and anti-aging preparations, herbal-extract preparations, bath salts, bath and body milk, hair styling aids, Hair, eye, nail, and skin-soft solids, controlled-release personal care products, hair conditioning mist, skin care moisturizing mist, skin wipes, pore skin wipes (pore skin wipes), pore cleaners, blemish reducers, skin exfoliators, skin desquamation enhancers, skin towelettes and / or cloths, Depilation preparations, personal care lubricants, nail coloring preparations, and drug delivery for topical application of skin-derived medicinal compositions Trisiloxane-containing, which may be configured to include using the trisiloxane-containing composition in a personal care application, selected from the group consisting of a stem delivery system, and combinations thereof A method of applying the composition to the surface of a substrate. The personal care article of claim 28, wherein the personal care article further comprises a sunscreen selected from the group consisting of UV blocking or UV absorbing sunscreen, and combinations comprising at least one of the foregoing sunscreens. A method of applying a trisiloxane-containing composition to a surface of a substrate, which may be a suncare formulation. The method of claim 28, wherein the personal care article comprises non-ionic biopolymer blends, polyethoxylated emulsifiers, modified polyacrylates, oils, animal and / or synthetic A trisiloxane-containing composition, which may further comprise an emulsifier selected from the group consisting of waxes, hydrocarbon gels or bentone type gels, organosilicon emulsifiers, and combinations thereof How to apply on the surface. The method of claim 1, wherein the trisiloxane-containing composition is applied to the surface of the substrate, which may be used in the form of a product which may be anhydrous to non-anhydrous. Way. The trisiloxane-containing composition of claim 31, wherein the product form may be a simple solid, particles, solution, gel-network-stabilized phase and combinations thereof. How to apply on the surface of the. The composition of claim 1, wherein the trisiloxane-containing composition comprises a gel, an emulsion, a dispersion, a sludge, a powder, a bar, a spray, a spritz, a mousse. A method of applying a trisiloxane-containing composition to a surface of a substrate, which can be used in the form of a product selected from the group consisting of stick, balm, foundation and combinations thereof. The compound of claim 1, wherein the trisiloxane-containing composition is selected from the group consisting of lecithin, polysorbates, dimethicone copolyols, glycols, citrate esters, glycerin, dimethicone and combinations thereof A method of applying a trisiloxane-containing composition to a surface of a substrate, which may further comprise a plasticizer.

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